Critical Materials Strategy
Critical Materials Strategy
Critical Materials Strategy
December 2010
FOREWORD ............................................................................................................................................ 4
ACKNOWLEDGEMENTS ........................................................................................................................... 5
EXECUTIVE SUMMARY ............................................................................................................................ 6
CHAPTER 3. HISTORICAL SUPPLY, DEMAND AND PRICES FOR THE KEY MATERIALS ................................... 27
CHAPTER 4. CURRENT DOE PROGRAMS .................................................................................................. 53
CHAPTER 5. OTHER U.S. GOVERNMENT PROGRAMS ............................................................................... 58
APPENDIX C: 111TH CONGRESS RARE EARTHS AND CRITICAL MATERIALS LEGISLATION ........................... 133
APPENDIX D: TREM CONFERENCE 2010 ADDRESS – ASSISTANT SECRETARY DAVID SANDALOW .............. 140
Steven Chu
Secretary of Energy
December 2010
Figure ES-3. Program and policy directions and the critical material supply chain
References
NAS (National Academy of the Sciences). 2008. Minerals, Critical Minerals and the U.S. Economy.
Figure 1-1. Key materials within the periodic table of the elements
Elemental materials are extracted from the earth via mining. Next, they are processed via separation
and refining to obtain the desired composition or purity. Materials may be extracted either as major
products, where ore is directly processed to extract the key materials or they may be coproducts or
byproducts of other mining operations. The coproduction and byproduction processes create
complex relationships between the availability and extraction costs of different materials, which
may cause supply curves and market prices to vary in ways not captured by simple supply and
demand relationships.
Processed materials are used to manufacture component parts that are ultimately assembled into
end-use technologies. The generic supply chain also shows the potential for recycling and reusing
materials from finished applications, though materials can be reclaimed at any stage of the supply
chain and reused either upstream or downstream.
2.1 Introduction
This chapter describes the use of key materials in the components of several clean energy
technologies. The chapter focuses on the following:
This chapter describes the four components (magnets, batteries, PV thin films and phosphors) in
more detail, with an emphasis on factors that influence the amount of key materials required for
each. These factors include product design choices (such as battery chemistry, motor specification,
phosphor composition and PV film thickness), technical innovations to reduce the amount of key
material within a product required for a given performance level and measures to reduce
manufacturing processing losses.
Material Content
The use of certain rare earth elements (REEs) in PMs significantly reduces the weight of the motor or
generator for a given power rating. Current hybrid-electric drive designs employ motors with
neodymium-iron-boron (NdFeB) magnets. 1 Large capacity wind turbines (with several megawatts
[MW] or more of power generation capacity) increasingly use rare earth PM generators. Although
these turbines still represent a relatively small portion of the wind market, their share is likely to
grow as purchasers increasingly choose larger turbines for wind projects.
The rare earth content of NdFeB magnets varies by manufacturer and application. An electric drive
vehicle may use up to a kilogram (kg) of Nd, while each wind turbine may contain several hundred
kilograms. Rare earth PMs may also incorporate praseodymium (Pr), which can be substituted for or
combined with Nd. Dysprosium (Dy) or terbium (Tb) may also be added to the intermetallic alloy to
increase the temperature at which the magnet can operate before losing its magnetic field (London
2010). Specific material intensity estimates for vehicle motors and wind turbine are discussed in
Chapter 7 and Appendix B. The cumulative demand for Nd and other REEs in these clean energy
technologies is a function of both the material content per individual product and the total number
of products sold. Therefore, aggressive technology penetration rates envisioned under many
worldwide clean energy strategies could significantly increase global demand for Nd, Pr, Dy and Tb.
1
Samarium cobalt (SmCo) rare earth PMs are used for certain niche applications, particularly in the defense
sector. They are slightly less powerful by size and weight than NdFeB magnets, although they continue to
operate effectively in higher temperatures (Electron Energy Corporation 2010). This high temperature
operating capability makes SmCo magnets the appropriate choice for some applications.
Figure 2-1. Supply chain for rare earth element permanent magnet technologies
2
Magnequench merged with Canadian based AMR Technologies in 2005 to form Neo Materials Technologies.
It now operates as a Canadian-based company with Chinese operations.
Material Content
The electric drive vehicles described above all require rechargeable (also called “secondary”)
batteries with the capacity to rapidly store and release electrical energy over multiple cycles. There
are a wide variety of battery chemistries available. Current generation HEVs use nickel metal hydride
(NiMH) batteries. The most common NiMH chemistries use a cathode material designated as AB5. A
is typically rare earth mischmetal containing lanthanum, cerium, neodymium and praseodymium;
while B is a combination of nickel, cobalt, manganese and/or aluminum (Kopera 2004). A current-
generation hybrid vehicle battery may contain several kg of REE material. Specific material intensity
estimates are discussed in Chapter 7 and Appendix B.
PHEVs and EVs require greater storage capacity and higher power ratings than HEVs and
consequently are likely to employ lithium-ion batteries (National Research Council 2010). Although
battery manufacturers are still working to address cost and safety issues, lithium-ion chemistries
offer better energy density, cold-weather performance, abuse tolerance and recharge rates than
NiMH batteries (Vehicle Technologies Program 2009). Thus, the demand for lithium and other
materials associated with lithium-ion battery chemistries will likely grow substantially with the wide-
scale deployment of EVs and PHEVs. Lithium-ion batteries that show promise for electric vehicle
applications typically use either graphite as the anode and some form of lithium salt in both the
cathode and electrolyte solution. The lithium content per vehicle battery varies widely depending on
manufacturer design choices. Researchers from Argonne National Laboratory have estimated that a
battery capable of providing 100 miles of range for an electric vehicle would contain between 3.4
and 12.7 kg of lithium, depending on the specific lithium-ion chemistry used and the battery range
(Gains and Nelson 2010).
3
Lithium titanate batteries use a lithium titanium oxide anode and have been mentioned as a potential
candidate for automotive use (Gains 2010), despite being limited by a low cell voltage compared to other
lithium-ion battery chemistries. Lithium titanate is used later in the strategy as the lithium-ion battery
chemistry with the highest lithium content in creating material demand projections.
Material Content
Three primary material formulations for PV thin films are on the market: amorphous silicon (a-Si),
copper-indium diselenide (CIS) and cadmium telluride (CdTe). While a-Si accounted for about 50% of
the thin-film market in 2008, the shares of both CIS and CdTe are increasing. A major subset of CIS
thin films are copper-indium gallium diselenide (CIGS) formulations, which are about 10% copper,
28% indium, 10% gallium and 52% selenium. About 2 tonnes 5 of copper, 4 tonnes of indium and 2
tonnes of gallium were purchased to produce 158 MW of CIGS solar cells in 2008. About 100 tonnes
of tellurium was purchased in 2008 to produce cadmium tellurium material for 358 MW of CdTe
cells (USGS 2009b). This total of about 500 MW in CIS and CdTe accounted for roughly 5% of the
global PV market in 2008. Other thin film technologies are being developed, such as copper zinc tin
sulfide.
4
Concentrating PV and nanotechnology-based films remain a negligible share of the market.
5
In this Strategy, we use tonnes rather than metric tons with which the reader might be more familiar.
1 tonne = 1 metric ton (Mt).
6
NREL, Email communication, September 17, 2010.
7
This discussion of lighting technologies does not consider niche lighting technologies such as high-intensity
discharge (HID) lamps, which are very efficient but are used almost exclusively outdoors or in very large indoor
areas.
In the short and medium terms, the demand for LFL and CFL fluorescent lamps using REEs in their
phosphor formulations is expected to increase. LFLs will continue to dominate the commercial
lighting market while CFLs will increasingly displace incandescent products in the residential lighting
sector. DOE standards for general service fluorescent lamps, issued in June 2009, mandate increased
8
Much higher purity than for the other REE applications described earlier.
Figure 2-5. Supply chain for rare earth phosphors in fluorescent lighting
9
Calculation assuming feed rates of 0.21 to 0.25 pounds of catalysts per barrel FCC feed and 2% REO content.
Cobalt Primary cobalt Ores, concentrates, or semi- Refined metals & DRC 51% 6.6 million
(15%) refined materials: chemicals: in cobalt
DRC 25,000 China 13 23,000 Australia 23% content
Byproduct of
nickel mining Australia 6,300 Finland 8,900 Cuba 8%
(50%)
China 6,200 Canada 4,900
Byproduct of Russia 6,200 U.S. 0
copper mining
(35%) U.S. 0
Indium Byproduct of zinc Global Not Metals, alloys, China 73% 14 Not
processing available etc.: available
U.S. 0 China 300 Others 16%
South 85 U.S. 3%
Korea
Japan 60
U.S. 0
10
Data in this table are from the most recent data available from USGS.
11
Approximately 20,000 additional REO from “unofficial” sources (Kingsnorth and Chegwidden 2010).
12
This 2009 production figure is from Molycorp (2010).
13
Cobalt Development Institute (2009).
14
This set of data on indium based on indium content is from 2008 (USGS 2008d); the breakdown of “Others”
is not available.
Sources: Eggert 2010, USGS 1994–2010a–e and Cobalt Development Institute 2009.
15
Others include Australia, Belgium, China, France, Germany, Kazakhstan, the Philippines, Russia and the UK
(USGS 2010f).
16
Mine production information for Ga is production capacity in 2008 rather than production in 2009 (USGS
2008g).
17
USGS, telephone communication, December 7, 2010.
18
Only part of the gallium present in bauxite and zinc ores is recoverable with existing technology, and the
factors controlling the recovery are proprietary. An estimate of current reserves of gallium comparable to the
definition of reserves of other minerals thus cannot be made (USGS 2010c).
19
Trace amounts (<1%) of heavy rare earths are also found in monazite mineral, except for yttrium, whose
abundance in monazite is higher (up to 2.5% in currently known projects) (USGS 2010, Roskill 2010, IMCOA
2010). A slightly larger concentration of heavy rare earths is also found in the fergusonite deposit at one of the
mines (Nechalacho) likely to come online in the next five years (Roskill 2010).
Table 3-2. Rare Earths Types and Contents of Major Contributing Source Minerals
Supplying REEs to the Global Market (Percentage of Total Rare Earth Oxides) 21
Neodymium (Nd)
Dysprosium (Dy)
Gadolinium (Gd)
Lanthanum (La)
Samarium (Sm)
Ytterbium (Yb)
Europium (Eu)
Holmium (Ho)
Thulium (Tm)
Terbium (Tb)
Lutetium(Lu)
Cerium (Ce)
Erbium (Er)
Yttrium(Y)
TYPE LOCATION(S)
Currently active:
Bayan Obo,
Bastnäsite Inner 23.0 50.0 6.2 18.5 0.8 0.2 0.7 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0
Mongolia
Lahat, Perak,
Xenotime 1.2 3.1 0.5 1.6 1.1 0.0 3.5 0.9 8.3 2.0 6.4 1.1 6.8 1.0 61.0
Malaysia
Xunwu, Jiangxi
Rare earth
Province, 43.4 2.4 9.0 31.7 3.9 0.5 3.0 0.0 0.0 0.0 0.0 0.0 0.3 0.1 8.0
laterite
China
Longnan,
Ion
Jiangxi
adsorption 1.8 0.4 0.7 3.0 2.8 0.1 6.9 1.3 6.7 1.6 4.9 0.7 2.5 0.4 65.0
Province,
clays
China
Lovozerskaya,
Loparite 28 57.5 3.8 8.8 0.0 0.1 0.0 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0
Russia
Various India 23 46 5 20 4 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Various Brazil N.A.
20
USGS, in-person meeting and multiple telephone communication, July–September, 2010.
21
Sum of concentrations may not total 100% due to matrix effect when analyzing various natural materials
that may differ in composition from the control standards used in calibration. Chart modified from USGS
Minerals Yearbook 2007 Volume I: Rare Earths chapter, Table 2, p. 60.11.
Much rare earth data is proprietary, yet public sources, including the United States Geological
Survey (USGS), routinely publish data on the rare earth deposits. 24,25 Table 3-2 combines data from
the USGS and others to summarize rare earth resources by source mineral type around the world.
The table is not an exhaustive account of all known rare earth deposits.
22
Currently the Mountain Pass site is limited to the reprocessing of rare earth ores from previously mined
stocks.
23
Ore, rather than the normally quoted mineral (Roskill 2010).
24
The paucity of data is also due to a lack of mineralogical studies or mine plan development for some of the
rare earth deposits.
25
Other prominent sources of rare earth data include industry consultants (e.g., Roskill Information Services
Ltd or Roskill, Industrial Minerals Company of Australia Pty Ltd or IMCOA, the Anchor House), major mining
firms, and General Electric.
150,000
100,000
50,000
0
1941
1945
1949
1953
1957
1961
1965
1969
1973
1977
1981
1985
1989
1993
1997
2001
2005
Figure 3-1. Historical production of rare earth oxides in the U.S. and the world in tonnes
Source: USGS 2010g
China currently produces at least 95 percent of global REEs (Roskill 2010). China introduced export
quotas on REEs in 1999, citing the need for environmental management and resource conservation
(see Table 3-3). 27 Between 2005 and 2009, REO exports fell by more than 20% from about 65,000
tonnes to about 50,000 tonnes. 28 In July 2010, China imposed the tightest quota thus far, leading to
a 40% annual drop of exports. 29 This latest set of export quotas were non-element specific and
applied to all exports of REEs, which in turn led to price spikes for the lower valued light rare earth
elements (LREEs) as traders favored exports of the more valuable HREEs. China’s Ministry of
26
India has reported an almost unchanging production level of REEs of 2,500-2,700 tonnes since 1994, and is
currently second to China globally in rare earth production. Brazil, which saw a rise in production in the late
1990s, has been producing in the 650 tonnes range. Malaysia has been producing around 380 tonnes per year
(USGS 1994-2010).
27
The production capacity outside of China for 2010 is 10,000–12,000 tonnes at best, indicating a shortfall in
2010 of at least 10,000–15,000 tonnes (Hatch 2010).
28
In this Strategy, we use tonnes rather than metric tons with which the reader might be more familiar. 1
tonne = 1 metric ton (Mt).
29
China issues export licenses for rare earths twice a year.
Table 3-3. China’s REE Export Quotas and Demand from Rest of the World (ROW):
2005–2010
Change
Export ROW
from ROW Supply 30
Quotas Demand
Previous (tonnes)
(tonnes REO) (tonnes)
Year
2005 65,609 - 46,000 3,850
2006 61,821 -6% 50,000 3,850
2007 59,643 -4% 50,000 3,730
2008 56,939 -5% 50,000 3,730
2009 50,145 -12% 25,000 3,730
2010 30,258 -40% 48,000 5,700–7,700
Sources: Kingsnorth 2010, Koven 2010 and Hatch 2010.
30
The production from the Commonwealth of Independent States is not available between 2005 and 2009,
and that from other countries not available between 2006 and 2009 according USGS data. The 2010
production capacity outside China is estimated based on the 10,000–12,000 tonnes shortfall predicted by
Hatch (2010).
31
Chile’s estimated reserve volume is at 7.5 million tonnes (USGS 2010a).
32
USGS 1994-2010a.
33
USGS, external review of earlier draft, November 17, 2010.
34
The global production does not include U.S. production data, information withheld by the USGS to avoid
disclosure of proprietary information (USGS 2010a).
35
These shares are based on global production not including U.S. production (see the previous footnote).
36
China is the only country in the world still converting lithium minerals into compounds from spodumene or
hard rocks, including imported lithium from spodumene in Australia (USGS, correspondence, August 24 2010).
In fact, its annual domestic production of lithium minerals from hard rock ores has been rising by
approximately 15% per year since 2000 (Roskill 2009).
37
USGS, 1994-2010a.
38
Australia holds the next largest reserves or approximately 23% of the worldwide total. The United States
possesses an estimated 33,000 tons of cobalt reserves or around 1% global reserves (USGS 2010b).
39
Cobalt production from the DRC occurs in the Copperbelt of Katanga Province, not in the conflict areas of
North and South Kivu provinces (USGS correspondence 10/25).
40
The Policy Potential Index (PPI), generated annually by the Canadian Frasier Institute, is based on a survey of
investors of mining ventures. It gauges the extent to which countries are putting up social and political barriers
to entry. The index takes into account public policy factors such as taxation and regulation affecting
exploration investment (McMahon and Cervantes 2010).
41
USGS, telephone communication, October 25 2010.
42
USGS, telephone communication, October 25, 2010.
43
USGS 1994-2010b.
44
Also based on multiple email exchanges and phone communication with USGS, October 4-7, 2010.
3.2 Demand
The two major drivers of demand for mineral commodities are the rate of overall economic growth,
(stable or decline) and the state of development for principal material applications (e.g., clean
energy technologies). Demand for key materials in clean energy technologies compete for available
supply with demand for the same materials in other applications. 46
Several additional pieces of information are helpful for understanding demand-supply mismatches
for the United States: domestic demand as a share of global demand, import dependence 47, stock
releases, substitutes, recycling and greater material use efficiency. Import dependence and supply
risks in general should be examined over the entire supply chain. A case in point is that around 40%
of global cobalt mine production occurs in DRC whereas only around 2% of global refining of cobalt
into metal occurs in DRC (USGS 2010f). This indicates that countries importing refined cobalt can still
be indirectly dependent on cobalt from DRC, a politically unstable country.
45
USGS 1994-2010d.
46
Generally and with respect to the key materials, demand for end-use items for building use (e.g., phosphors
for lighting) or construction tend to be more cyclical, whereas those that enter big-ticket consumer items such
as cars tend to be more volatile and sensitive to short-term economic movements. Uses that enter portable
devices and personal consumer goods (e.g., batteries for portable electronics) tend to experience more stable
demand (Humphreys, forthcoming). Regional factors are important also: China’s and India’s rapid economic
growth have had and will continue to have a huge impact on global demand for mineral commodities (Eggert
2010).
47
Import dependence by itself need not be considered a risk factor. Rather, the possibility of supply
disruptions is due to a combination of heavy import reliance and concentration of supply in a few companies
or countries that may be unreliable suppliers.
48
End use shares are from the most recent USGS data available; the shares are global for Li and Co; and
domestic for REEs, In, Te, and Ga. The data source for Te is Umicore (2010).
49
Based on information provided by USGS on September 14, 2010.
50
Canada, UK, U.S. and Taiwan are involved in gallium recycling (USGS, correspondence, December 7, 2010).
51
Estimated share of U.S. gallium consumption out of global total is based on the 2008 global production
number instead as global demand data for gallium is harder to determine and it is reasonable to assume that
global Ga supply is at a similar level as global Ga demand; data source is USGS (correspondence October 19,
2010).
52
Demand here refers to demand by manufacturers of materials for production rather than demand by
households for final products containing the material.
53
China’s total annual rare earth consumption in these sectors has grown from a mere 1% in 1987 to 60% in
2008 (Chen 2010).
54
USGS 1994-2010.
25000
20000
15000
10000
5000
0
1970
1972
1974
1976
1978
1980
1982
1984
1986
1988
1990
1992
1994
1996
1998
2000
2002
2004
2006
2008
Cobalt Lithium carbonate equ. REO equivalents
Figure 3-2. U.S. historical demand for REO equivalents, cobalt and lithium carbonate
equivalents (tonnes)
Source: USGS 2010g
55
Global end-use markets are estimated as follows: ceramics and glass, 31%; batteries, 23%; lubricating
greases, 10%; air treatment, 5%; continuous casting, 4%; primary aluminum production, 3%; and other uses,
24% (USGS 2010a).
56
The United States has been re-exporting around half of its lithium imports since 2003 (USGS1994–2010c).
57
USGS 1994-2010a.
58
Optoelectronic devices were used in aerospace, consumer goods, industrial equipment, medical equipment
and telecommunications. ICs were used in defense applications, high-performance computers and
telecommunications (USGS 2010c).
59
Gallium stocks have met an average of 8% of annual demand in the United States since 1982 (USGS 1994–
2010c).
60
The United States stopped exporting gallium in 1984 (USGS 1994-2010c).
140
120
100
80
60
40
20
0
1970
1972
1974
1976
1978
1980
1982
1984
1986
1988
1990
1992
1994
1996
1998
2000
2002
2004
2006
2008
Indium Gallium
Figure 3-3. U.S. historical demand for indium and gallium (tonnes)
Source: USGS 2010g
The United States has been 100% dependent on imports for indium since 1972, with current indium
imports coming from China, Japan and Canada. 61 In terms of secondary sources, indium is recycled
from manufacturing wastes in China, Japan and the Republic of Korea—the countries in which most
ITO production occurs. According to USGS, recovering indium from the tailings of zinc mining is
61
The United States had minimal stocks of indium from 1993 to 1998 and exported an average of 19% of its
annual imports between 1999 and 2002 (USGS 1994-2010d).
3.3 Prices
Supply risks, at least in the short-to-medium term, are less associated with the prospect of
increasing prices because in most cases the cost of these elements is a small part of the final product
manufacturing cost. However, in the last 6–12 months the price of many rare earth elements has
increased by approximately 300–700%, which in some cases has had a more significant impact on
the price of the final product (Lynas Corp. 2010). 62
62
For example, in August 2010 W.R. Grace established a rare earth surcharge that increased the price of its
fluid cracking catalysts and additives due to rapidly increasing rare earth prices (W.R. Grace 2010).
63
Examples cited in Humphreys (forthcoming 2011) include the power shortage concerns in Southern Africa
and Chile where mining is important; water, which is required in large quantities by mining and is becoming
scarcer and more expensive in some parts of the world; a move toward smaller and higher cost deposits and
resources; and increasing political barriers to entry.
Table 3-5. Purchase Option and Source of Price Information for Key Materials of Concern
64
In China, gallium is also traded through informal metals exchanges where transparent pricing and a spot
market are present.
65
USGS, external review of earlier draft, November 17, 2010.
700
Lanthanum
600
Cerium
500
$/kg REO
400 Neodymium
300 Praseodymium
200 Samarium
100 Dysprosium
0 Europium
Jun-01
Jun-02
Jun-03
Jun-04
Jun-05
Jun-06
Jun-07
Jun-08
Jun-09
Nov-10
Terbium
Figure 3-6 provides detailed historical price information for lithium carbonates, illustrating price
trends driven by the opening of new brine mines and closing of old spodumene mines as well as
continuous regional demand growth. In the early 1990’s, the United States was the largest producer
and consumer of lithium minerals and compounds worldwide. In the early 1990s the U.S.
66
In 2004, world demand for cobalt reportedly increased as a result of an increase in demand from the
aerospace and land-based gas turbine industries and growth of cobalt use in rechargeable batteries and
catalysts (USGS 2004a).
67
This period led up to the European Union’s (EU) enactment of a new chemical policy known as “REACH”
which affected all suppliers of cobalt as well as other materials to the European market by requiring them to
collect and submit risk assessment data on each material produced in or imported to the EU. The goals of
REACH included “Improved protection of human health and the environment,”
http://guidance.echa.europa.eu/about_reach_en.htm.
68
USGS 1994-2010b.
Figure 3-7 shows historical gallium price trends in the European market, which follows world gallium
prices closely. Gallium supplies were tight in 2000 because of continuously increasing demands for
wireless communication products. Until early 2001, supply remained tight and the price for high-
purity gallium reached $2,500 per kilogram (kg). By mid-2001, gallium spot prices dropped to about
$1,000 per kg, still higher than the average selling price of $500–$600 per kg. The U.S. economic
69
Total global mine production of lithium materials was 6,100 tonnes in 1994 (USGS 1996a); U.S. production
info which was withheld to protect proprietary information is not reflected in the global number.
70
USGS 1994-2010a.
Figure 3-8 shows historical indium prices. In the early 2000s, expanding LCD manufacturing in Asia
was more than matched by an adequate supply and highly efficient processing. Despite a strong
increase in LCD production, the ready availability of low-priced indium from China forced world
prices down. In 2003 and 2004, reduced production from mines that generated byproduct indium
and the closure of several smelters—due to environmental problems—created the perception that
supplies of indium from
71
USGS 1994-2010c.
China would decrease and drove world indium prices to historic highs. The indium price continued
its remarkable rise into the fall of 2005, driven by continued strong sales of flat-panel displays and
other LCD products that increased global consumption of ITO. Global secondary indium production
increased significantly during 2005–2007 and accounted for a greater share of indium production
than primary production by 2007. Global ITO demand continued to rise, leading to some price spikes
caused by supply deficits and the indium supply’s heavy dependence on the strength of the zinc
market (USGS 1994–2010d).
3.4 Conclusions
This chapter addressed the historical supply, demand and price data for materials important to clean
energy technologies. These materials have already seen a rise in demand driven by one or more
uses, and the United States is heavily import-dependent for most of them. These materials are also
predominantly co-produced with other metals, resulting in additional supply risks. Although there
are secondary sources for some of these materials from recovered scrap and stock releases, such
sources still meet a relatively small share of U.S. and/or global demand (except for indium). Among
the materials of interest, other than the rare earths, the United States appears to have some level of
diversity in terms of import sources. However, the complex supply chain could still lead to an
indirect reliance on these less stable sources. Information about future supply and demand, as well
as an assessment of the potential mismatch between supply and demand for each material, is
presented in Chapter 7.
References
Arnold Magnetic Technologies. 2010. “Response to DOE Request for Information.” June 5, 2010.
Baylis, R. 2009. “From Zhejiang to Zabuye: China’s Mountainous Path to A Self-sufficient, Integrated,
Lithium Industry,” Presented at the LSM Conference, Santiago, January.
Office of Science
At the basic science end of the pipeline, the Materials Sciences and Engineering (MSE) Division of
the Office of Basic Energy Sciences supports broad-based, fundamental materials research. MSE
seeks to illuminate the atomic basis of materials properties and behavior and improve materials
performance at acceptable costs through innovative design, synthesis and processing. This research
was funded at a level of about $5 million/year in FY2010.
Most of the supported work has been performed at Ames Laboratory. This work includes materials
synthesis and processing, phenomenological behavior investigations and characterization. The main
emphasis is on rare earth materials that change temperature, shape or electrical resistance upon
exposure to a magnetic field. The research focuses on the synthesis of highest quality polycrystals
and single crystals, advanced characterization methods, especially neutron and magnetic X-ray
scattering and first principles modeling. The ultimate goal of the research is to understand and
control the responsiveness of materials that are sufficiently complex to facilitate control at length
scales ranging from electronic interaction distances to atomic and microstructural scales.
A key component of the Ames Laboratory program is the Materials Preparation Center (MPC). The
MPC was established in 1981 to provide high purity metals (including the rare earths, uranium,
thorium, vanadium, chromium); and intermetallics, refractory, inorganic compounds and specialty
alloys; none of which are available commercially in the required purity or form/shape needed by the
requestor on a cost recovery basis. The Center is focused on establishing and maintaining materials
synthesis and processing capabilities crucial for the discovery and development of a wide variety of
Tax Credits
The ARRA authorizes the Secretary of the Treasury, in consultation with the Secretary of Energy, to
award tax credits for qualified investments in new, expanded or re-equipped domestic
manufacturing facilities for clean energy technologies. The goal of the Advanced Energy
Manufacturing Tax Credit—codified in Section 48c of the Internal Revenue Code—is to expand the
domestic manufacturing industry for clean energy. Tax credits have been issued to manufacturers in
a number of relevant energy technology areas, including solar thin film, LED lighting, wind turbine
components and electric vehicles.
Table 6-1. Policy Goals, Business Policies, Research and Development Policies and Materials of
Interest for Each Nation
Materials of
Nation Goal Business Policy R&D Policy Interest
Japan Secure a stable • Funding for international • Substitution research Ni, Mn, Co, W,
supply of raw mineral exploration funded through METI Mo, V**
materials for • Loan guarantees for high- and MEXT
Japanese industries risk mineral projects • Exploration,
• Stockpiling excavation, refining
• Information gathering and safety research
funded through
JOGMEC
European Limit the impact of • Mineral trade policy for • Increased material Sb, Be, Co, Ga,
Union potential material open international efficiency in Ge, In, Mg, Nb,
supply shortages on markets* applications REEs, Ta, W,
the European • Information gathering* • Identification of Fluorspar and
economy • Land permit streamlining* material substitutes Graphite
• Increased recycling • Improve end-of-life
regulations* product collection and
recycling processes
Netherlands Reduce material • Government-industry • Substitutes of Ag, As, Au, Be,
consumption to collaboration on material abundant or Bi, Cd, Co, Ga,
prevent global policy through the M2i renewable materials Ge, Hg, In, Li,
shortages by Institute • Processes for recycling Mo, Nb, Nd, Ni,
employing depleting materials Pb, Pd, PGMs,
“managed • Study consumption REEs, Re, Ru,
austerity” patterns as a result of Sb, Sc, Se, Sn,
policy Sr, Ta, Te, Ti, V,
W, Y, Zn, Zr
*proposed policy
**current reserves
6.1 Japan
Japan’s materials policy is based on the nation’s limited domestic resources and the importance of
many rare metals to the manufacturing of electronics and automobiles. The policy’s goals, as
outlined in the 2009 “Strategy for Ensuring Stable Supplies of Rare Metals,” include (i) maintaining a
stable supply of metals for Japanese industries by securing overseas sources of critical materials; (ii)
recycling rare scrap metals; (iii) developing alternative materials; and (iv) stockpiling some rare
• Providing partial funding for overseas field surveys through the Joint Basic Exploration
Scheme
• Providing loan guarantees and other financial assistance to high-risk mine development
projects
• Maintaining stockpiles of seven metals—nickel, chromium, manganese, cobalt, tungsten,
molybdenum and vanadium—while closely monitoring the availability of Indium, rare earth
elements, platinum, gallium, niobium, tantalum and strontium
• Gathering and disseminating information on mineral availability and policies in various
nations
• Funding and engaging in scientific research on new types of exploration, mining and
recycling (JOGMEC 2007)
According to a 2008 METI strategy statement in response to geopolitical developments in global
mineral supply, the Japanese government will also provide diplomatic assistance to Japanese
companies engaging in mining projects abroad by giving official development assistance to mining
and transportation infrastructure projects (METI 2008).
Japanese firms are actively securing the raw materials needed for their operations. Toyota Motor
Corporation established a rare earth task force to monitor its supply chain and, through its trading
company Toyota Tsusho, invested in a rare earth mining joint venture in Vietnam in 2008 to export
rare earths to Japan (AP 2010). Likewise, Japanese trading house Sumitomo Corporation established
a joint venture in Kazakhstan with the goal of producing 3,000 tons of rare earths per year (Japan
Looks Past 2010).
METI, the Ministry of Education, Culture, Sports, Science and Technology (MEXT) and the
government-affiliated New Energy and Industrial Technology Development Organization (NEDO)
also directly fund research projects on substitutes for and efficient use of rare metals. Recent
research projects have focused on reducing the material used in rare metals technologies and
substituting rare metals with more abundant ones. In October 2010, NEDO and Hokkaido University
announced the development of a motor for hybrid and electric vehicles that does not use rare earth
elements, instead utilizing magnets from less expensive and more common ferrite materials (Japan
Looks Past 2010, Tabuchi 2010).
6.3 Netherlands
The Netherlands, a member of the EU, is developing its own rare metals strategy based on its
concern that the rapid depletion of raw materials is partially due to over-consumption, and thus
“managed austerity” should be part of the remedy. According to a report published by M2ia public-
private partnership between the Dutch government, universities and industry—the fruitful
exploration for, and extraction of, rare metals will not continue to fulfill all of this century’s needs.
Instead, governments must prepare for material scarcity by promoting the substitution of plentiful
or renewable materials for rare metals, more efficient use of depleting metals and efficient and
productive recycling (M2i 2009). The rare metals strategy will be developed in collaboration
between government, universities, industry and research organizations.
6.4 China
As a major producer and rapidly increasing consumer of raw materials, China’s policy goals are to
maintain a stable supply of materials for the Chinese economy and reduce illegal mining,
overproduction and smuggling of its domestic resources. These goals specifically concern REEs, of
which China is the world’s leading producer.
In the past decade, China has moved toward supporting domestic markets for REEs. In 2007, the
Ministry of Commerce declared most rare earth elements and products to be strategic commodities
and the State Council placed new restrictions on foreign investment in the REE sector. These
developments prohibited outright foreign investment in REE mining—requiring that foreign
investors form joint ventures with domestic firms in the processing of rare earth ores—and officially
encouraged foreign investment in the more value-added manufacturing of rare earth magnets,
metal alloys and powders. China further restricted foreign access by abolishing export tax rebates in
2005 and introducing a new REE export tax in 2006. Export tax rates have since been raised and now
range from 15%–25% for different elements. Between 2004 and 2009, the overall REE export quota
was reduced by more than 20% from about 65,000 tons to about 50,000 tons rare earth oxides
(REOs). In July 2010, China further reduced its export quota to 30,258 tons REO, a 40%decrease from
2009.
While attempts to exert more control over the rare earth industry have recently gained momentum,
there remain a number of challenges. Illegal mining and smuggling, for instance, are major issues for
Chinese mining policy. In 2010, the Ministry of Land and Resources, responsible for issuing mining
licenses, decided to stop issuing new licenses until mid-2011 (Muyuan 2010). However, illegal
mining of REEs continues. Moreover, the enforcement of environmental and other mining
regulations varies by province, which can lead to severe environmental degradation associated with
rare earth mines. Poor environmental protection compliance across the industry often results in
thorium residues being disposed into unlined tailing facilities and insufficiently treated water
reaching nearby rivers.
To further protect domestic resources Chinese officials are planning to create sizable stockpiles as
well. In February 2010, the regional government of Inner Mongolia authorized a “strategic reserve”
of REEs to be established in the autonomous region (Yan and Yijun 2010). In October 2010, it was
reported that Bautou Steel‘s plan to acquire and set aside up to 300,000 tons of rare earths within
five years was approved by the Chinese government (China May Launch Rare 2010).
6.7 Canada
Canada is the world’s largest exporter of minerals and metals, with natural resource mining
accounting for 4% of its gross domestic product. National mining policy is managed by Natural
Resources Canada, but primary responsibility for mining oversight falls under provincial jurisdiction.
At the federal level, the government uses a mix of policies in finance and taxation, regulatory
efficiency and investment and export promotion to maintain a globally competitive industry (Natural
Resources Canada 1996). Canada also maintains a relatively flexible and favorable regulatory regime
that seeks to avoid duplication, minimize uncertainty and delays and harmonize federal and
provincial rules. While Canada has extensive mining and environmental regulations, it still ranks
ninth out of 25 nations in terms of permitting time by Behre Dolbear (Behre Dolbear 2010). Canada
stores copper, gold, lead, molybdenum, nickel, silver and zinc in quantities from 0.5%–4% of
national annual production levels.
References
AP (Associated Press). 2010. “Nations Wary of Dependence on China’s Rare Earths.” Associated
Press, October 4.
Bae, J. 2010. “Strategies and Perspectives for Securing Rare Metals in Korea.” Discussion white
paper.
Behre Dolbear. 2010. 2010 Ranking Of Countries for Mining Investment. s.l.: Behre Dolbear.
“China May Launch Rare Earth Strategic Reserve Mechanism Next Year – Source.” 2010. Business
China, October 27. Accessed November 3. http://en.21cbh.com/HTML/2010-10-
27/xNMDAwMDIwMzIxNA.html.
Commission of the European Communities. 2008. The Raw Materials Initiative—Meeting our Critical
Needs for Growth and Jobs in Europe. Brussels: Commission of the European Communities.
72
Some historical data and basic growth projections exist for non-clean energy applications; however, future
demand will be governed by complex market dynamics, including the extent to which increased clean energy
demand prompts innovations that reduce material requirements for all applications.
73
Vehicles with electric drives include hybrid gasoline-electric and diesel-electric vehicles, plug-in hybrid
electric vehicles and all-electric vehicles.
MARKET PENETRATION
Material intensity
Trajectory of Global Deployment Level of Market Share of Specific of the Clean
Demand the Generic Technology Clean Energy Technology Energy Component
Trajectory A Low Low Low
Trajectory B Low Low High
Trajectory C High High Low
Trajectory D High High High
None of the four trajectories analyzed in this report is intended to imply a prediction of future
demand for clean energy technologies or key materials used in making them. That demand will
depend on a number of factors, including technological progress, policy consistency and
macroeconomic conditions. Instead, the trajectories are intended to illustrate a range of future
possibilities and explore the impact of different assumptions concerning technology deployment
rates, market shares and material intensity on future requirements for rare earth elements and
other key materials. Trajectories A and D will represent the lower and upper extremes, respectively,
for probable material demand.
In the following sections, these four trajectories are calculated for each key material in clean energy
technologies. For key materials that are used in several clean energy technologies, the trajectories
of future demand are presented as an aggregate for all relevant technologies. The contribution of
each application is noted in the discussion of the figure. For example, Trajectory A demand for
neodymium represents the sum of non-clean energy demand plus the Trajectory A requirements for
magnets used in wind turbines plus the Trajectory A requirements for magnets used in vehicles with
electric drives.
Table 7-2. Current and Projected Future Rare Earth Supply by Element 74
Lanthanum 33,887 6,640 3,900 2,000 845 1,620 594 585 16,184 50,071
Cerium 49,935 9,820 7,650 4,820 2,070 2,520 1,368 1,101 29,349 79,284
Praseodymium 6,292 868 600 590 240 200 174 120 2,792 9,084
Neodymium 21,307 2,400 2,250 2,150 935 535 657 423 9,350 30,657
TOTAL 127,315 19,968 14,925 9,980 4,925 4,955 2,991 2,913 60,657 187,972
Sources: Kingsnorth (see footnote 76), Roskill (2010) and USGS (2010).
74
Data sources: estimated 2010 production based on personal communication with Kingsnorth, Roskill (2010)
for assumed additional production by 2015 with downward adjustments to Mt. Weld and Nolans Bore to
reflect expected supply by 2015, elemental breakdowns based on USGS (2010).
75
The mines and assumed respective supplies are (i) North Queensland Metals Baal Gamm mine in Australia
(15 tonnes/yr), (ii) South American Silver’s Malku Khota mine in Bolivia (15–20 tonnes/yr), (iii) Votorantim
Metais’ Juiz de For a mine in Brazil (15 tonnes/yr) and (iv) UMMC’s Electrozinc facility in Russia (2 tonnes/yr).
The estimated 2010 global tellurium production is based on the 2008 global primary production of
tellurium reported by USGS due to the fact that the 2010 estimate was not yet available and the
2009 global primary production number reflects conditions when the recent economic recession
had the most impact. Additional tellurium supply is based on the assumption that approximately
60% of the 1,200 tonnes/yr copper anode slimes based potential tellurium supply indicated by the
USGS in the 2008 Tellurium Yearbook will come online by 2015. Global tellurium production could
grow by about a factor of four from increased levels of extraction from copper anode slimes by
2020, but may grow more slowly if copper refiners move away from the electrolytic process as the
quality of copper ore declines. Additional supplies of tellurium also may be produced from tellurium
mining projects and from efforts to recover tellurium from gold concentrates. However, no specific
assumptions were made about these potential additional supplies due to insufficient information.
76
For indium, the additional amount is only the difference between the 2010 production and the maximum
current production capacity for mining and refining the material. No new capacity is projected by 2015.
77
Also based on multiple correspondences with USGS, October 4-7, 2010.
78
USGS, external review of earlier draft, November 17, 2010.
79
Currently and for the foreseeable future, Bolivia’s lithium is only an uneconomic resource. It is unknown if
Boliva will ever be able to turn its lithium resource into an economic reserve (USGS, , phone communication,
October 21, 2010).
80
The substitution of praseodymium for neodymium is not considered in the demand trajectories due to a lack
of available data on the extent to which it occurs.
Future deployment cases for vehicles with electric drives (HEVs, PHEVs and EVs) were based on the
International Energy Agency’s 2010 Energy Technology Perspectives (IEA ETP 2010) with its detailed
breakdown of annual deployment among various types of vehicles. The low deployment case is
based on the “2010 Baseline Case,” which like the IEA WEO “2009 Reference Case,” assumes that
governments introduce no new energy and climate policies after 2009. The high deployment case
for light-duty vehicles with electric drives is based on the IEA ETP 2010 “Blue Map Scenario.” The
IEA developed the “Blue Map Scenario” to illustrate a least-cost technology deployment scenario
designed to reduce global, energy-related CO2 emissions by 50% from 2005 levels in 2050 (IEA
2010).
The development of the market share and material intensity assumptions is presented in detail in
Appendix B.
Figure 7-2 contains projections of global requirements for neodymium oxide (Nd2O3) in all
technologies, including wind turbines and vehicles with electric drives, during the period 2010–2025,
as well as the 2010 and 2015 supply estimates. These amounts are given in terms of neodymium
oxide, because this is the commercial feedstock from which the neodymium metal is refined and
NdFeB magnets are fabricated. Also included in Figure 7-2 are supply estimates for 2010, 2010 plus
two individual mines that are close to ramping up operations and an estimate for 2015 supply.
Figure 7-3 illustrates the ranges of projections of global requirements for dysprosium oxide (Dy2O3)
in magnet for wind turbines and vehicles, as well as non-clean energy use during the period 2010–
2025. These amounts are given in terms of dysprosium oxide because this is the commercial
feedstock from which dysprosium metal is refined and NdFeB-AH magnets are fabricated. Also
included in Figure 7-3 are supply estimates for 2010, 2010 plus additional individual mines and an
estimate for 2015 supply.
Figure 7-3 shows that the basic availability of dysprosium oxide is tight in the short term. Electric
drive vehicles represent roughly four times the demand for dysprosium oxide than wind turbines in
2025 under Trajectory C. Anticipated new mines will provide relatively little new supply, an
additional 12% supply, by 2015. Global demand exceeds projected 2015 supply under all four
trajectories in the beginning of the medium term. Global clean energy demand as a percentage of
total demand for dysprosium increases dramatically from 16% in 2010 to 62% in 2025 under
Trajectory C. The developing supply-demand imbalance in the medium term under all trajectories
highlights the importance of R&D on alternative approaches to heat management (a main function
of the dysprosium content) in magnets or substitutes for NdFeB magnets in general in clean energy
technologies. Non-clean energy demand alone will lead to a supply-demand mismatch by the middle
of the medium term under the assumed trajectory, highlighting the need for corresponding material
intensity improvements or substitutes in non-clean energy technologies. Ceramic high-temperature
superconductors may be a competitive substitute for NdFeB permanent magnets in wind turbines
and this could lessen the demand for neodymium and dysprosium.
The International Energy Agency’s Energy Technology Perspectives (IEA ETP 2010) “2010 Baseline
Case” was selected as the basis for the Low Penetration case for light-duty vehicles with electric
drives. This “2010 Baseline Case” follows the outlines of the IEA WEO “2009 Reference Case,”
illustrates the total number of light-duty vehicles manufactured and sold each year and provides a
detailed breakdown of annual deployment among various types of vehicles with electric drives (IEA
2010). Like the IEA WEO “2009 Reference Case,” the IEA ETP “2010 Baseline Case” assumes that
governments introduce no new energy and climate policies after 2009.
The High Penetration case for light-duty vehicles with electric drives is based on the IEA ETP 2010
“Blue Map Scenario.” The IEA developed the “Blue Map Scenario” to illustrate a least-cost
technology deployment scenario designed to reduce global, energy-related CO2 emissions by 50%
Figure 7-4 shows that the basic availability of cobalt appears more than adequate in the short to
medium term, even where global clean energy demand increases dramatically under Trajectory D.
Non-clean energy technologies represent the vast majority of cobalt global demand in all but
Trajectory D. Additional supply capacity by 2015 appears to be more than sufficient to meet
demand, even without mines from the Congo.
Figure 7-5 shows that the basic availability of lithium carbonate appears to be adequate in the short
term. Global clean energy demand as a percentage of total demand increases dramatically from
near zero to 49% in 2025 under Trajectory C. This increase is attributable to the rapid deployment of
electric vehicles; 13 million plug-in hybrids and 4.6 million all-electric vehicles are sold in 2025 under
Trajectory C. Global demand exceeds expected 2015 supply before 2025, but with the high levels of
resources available, existing producers appear to be able to increase capacity beyond 2015 to meet
global demand. To meet global lithium carbonate demand in 2025 under Trajectory C, an additional
Figure 7-6 shows that the basic availability of lanthanum oxide is adequate in the short term. 2015
supply is able to meet demand under all trajectories until the middle of the medium term. Global
demand for lanthanum in electric drive vehicle batteries as a percentage of total demand increases
from 2% in 2010 to 19% in 2025 under Trajectory C. The clean energy demand trajectories also
include the demand for lanthanum in lighting phosphors that is less than 1,000 tonnes per year in all
years and trajectories (the assumptions behind lighting trajectories are described in more detail
later in this chapter). If supply does not continue to increase after 2015, non-clean energy demand
alone will exceed supply at the end of the medium term. Clean energy demand will exacerbate the
supply-demand mismatch in the medium term without significant additional production, suggesting
the importance of alternate battery technologies. To meet global lanthanum oxide demand in 2025
under Trajectory C, an additional 14,000 tonnes per year of supply is needed over 2015 estimated
supply.
Figure 7-7 illustrates that the basic availability of cerium oxide appears to be more than adequate to
meet demand for cerium in lighting phosphors and nickel metal hydride vehicle batteries. Demand
for cerium oxide in nickel metal hydride batteries is more than 10 times higher than in lighting
phosphors under Trajectory C in 2025. Non-clean energy dominates overall demand, accounting for
The IEA WEO “2009 Reference Case” was selected as the basis for the Low Penetration case for
photovoltaic power systems. Recall that this case assumes that no new policies will be implemented
to accelerate adoption of these technologies after 2009. The IEA WEO “450 Scenario,” meant to
stabilize greenhouse gas concentrations at 450 ppmv, was used as the basis for the High Penetration
case for PVs.
The development of the market share and material intensity assumptions is presented in detail in
Appendix B.
Figure 7-8 illustrates the range of projections for tellurium demand over the period 2010–2025,
considering both non-clean energy demands and demand for CdTe PV modules. Figure 7-9 and
Figure 7-10 illustrate the ranges of demand for indium and gallium respectively through non-clean
energy demand and for CIGS PV modules.
Figure 7-8 shows that the basic availability of tellurium appears more than adequate because
expected increased recovery from copper anode slime dramatically increases supply in the short
term. If anticipated new supplies become available, it appears that supply will be sufficient to meet
projected demand past 2020 in Trajectories A–C. Reducing material intensity provides significant
payoff for reducing overall material demand. If CdTe PV approaches the low material intensity of 43
tonnes per GW, only a minimal increase in supply in the medium term is necessary to accommodate
high PV penetration. Non-clean energy demand as a percentage of total demand shrinks significantly
over time under Trajectory C, but will still account for a large share of global demand in 2025. U.S.
clean energy demand for tellurium is about a sixth of global clean energy demand in 2025, under
Trajectory C. To meet global tellurium demand under Trajectory D, supply in 2025 must double
estimated 2015 supply.
Figure 7-9 shows that the basic availability of indium appears somewhat tight by 2015, particularly
for the trajectories with high material intensity. Without market adjustment, supply will need to
increase by more than 25% over the 2015 estimate to meet just non-clean energy demand in 2025.
Non-clean energy demand dominates indium consumption in Trajectories A–C. Clean energy
demand adds to this demand, at 11% of total demand in 2025 under Trajectory C. Reducing the
material intensity of indium in CIGS photovoltaic cells provides significant reductions of overall
material demand. Without expanded production after 2015, reductions in non-clean energy demand
will also be important to prevent shortages and price spikes.
Figure 7-10 shows that the basic availability of gallium appears more than adequate. Estimated 2015
supply is sufficient to meet projected demand beyond 2020 in all but Trajectory D. Continuing
industry trends of reducing material intensity provides significant payoff for reducing overall
material demand. While the share of clean energy demand relative to non-clean energy demand
increases from 5% in 2010 to 16% in 2025, non-clean energy demand still dominates across
Trajectories A–C. U.S. clean energy demand contributes about one-sixth of global clean energy
demand in 2025 under Trajectory C. High penetration of CIGS PV without advances in material
intensity, global supply of gallium would need to increase by roughly 85% between 2015 and 2025
to meet global demand.
81
Because REEs used in lighting need to be very pure (99.999%), the rare earth oxides (REOs) sold to phosphor
manufacturers are much more expensive than those used by manufacturers of other REE applications. In the
event of a material shortage, producers of REOs would likely divert the available supply of a given element
into phosphors rather than the other applications of this element due to the greater profit margins. Therefore,
the impact of shortages in overall REE supplies may have a limited effect on the availability of lighting
phosphors (Gschneidner, pers. comm.).
Figures 7-11 to 7-13 illustrate estimated supply and the range of demands projected in this study for
REEs used as phosphors in high-efficiency lighting technologies (except lanthanum and cerium,
which were discussed earlier). These three figures contain only Trajectories B and D because only
one set of material intensity values for phosphors was available. U.S. and global clean energy shares
of total demand are based on Trajectory D (equivalent to Trajectory C for these materials).
Figure 7-11 shows that the basic availability of europium oxide is more than adequate in the short
term and likely adequate in the medium term. Unlike most key materials, clean energy demand for
europium oxide in phosphors dominates the overall demand and accounts for approximately two-
thirds of global demand throughout the short and medium term. The addition of supplies from
Mount Weld mine increases global supply by 14% and represents a significant portion of the
increased production in 2015. Only demand under Trajectory D is projected to exceed 2015 supply
by the end of the medium term. Trajectories assume limited substitution of light emitting diodes
(LEDs) and organic light emitting diodes (OLEDs) for fluorescents, which could substantially mitigate
demand in the 2020–2025 timeframe.
Figure 7-12 shows that the basic availability of terbium oxide is adequate in the short term, but may
become tight early in the medium term without additional production after 2015. Both high- and
low-growth trajectories will exceed forecast 2015 supply by the middle of the medium term. Mount
Weld and Mountain Pass mines, which are projected to open in 2011 and 2012 respectively, have
limited capacity to produce terbium oxide, so increased supply by 2015 will come largely from
Nechalacho mine in Canada. To meet demand under Trajectory D in 2025, supply will need to
increase by 140 tonnes per year over 2015 estimated supply. Trajectories assume limited
substitution of LEDs and OLEDs for fluorescents, which could substantially mitigate demand in the
2020–2025 timeframe.
Figure 7-13 shows that the basic availability of yttrium oxide appears very tight in the short and
medium term. Global demand in 2010 exceeds current production. 83 Production is anticipated to
grow 10% by 2015. At this level, it will be unable to meet growing demand in the short and medium
terms. Significant additional production will be needed to meet short term demand. Production will
need to grow by more than 40% over the 2015 level by 2025 in order to meet even the low-growth
trajectory. Clean energy demand in phosphors accounts for approximately 50% of global demand
throughout the short and medium term. Trajectories assume limited substitution of LEDs and OLEDs
for fluorescents, which could substantially mitigate demand in the 2020–2025 timeframe. If high-
temperature superconductors, which generally contain yttrium, begin to capture market share from
permanent magnets for use in wind turbines, demand for yttrium may increase more rapidly.
82
Estimated clean energy demand in 2010 slightly exceeds data for total global demand. This is likely
explained by data uncertainty about total global demand and the dependency on a single set of phosphor
content assumptions. It is clear that non-clean energy demand is greater than zero currently and in the future.
83
The additional supply may come from existing stockpiles or may be due to data uncertainty.
7.7 Market Dynamics Affecting the Pricing and Availability of Rare Earth
Elements and Other Key materials
Market dynamics refer to the interactions between demand, supply and prices. The market
dynamics that affect REEs and other key materials vital to the commercialization of clean energy
technologies are not captured by traditional economic models or simple economic analyses. This
section discusses how factors associated with the extraction, processing and use of these materials
can lead to supply-demand imbalances that manifest either in shortages or large price fluctuations.
Also included is how the same factors make it difficult for supply and demand to respond to price
signals.
Supply-side Factors
In addition to the demand-side issues, there are several supply-side factors that influence the
market dynamics for REEs and other key materials. The main supply-side factors are coproduction,
concentrated market power, large capital requirements and long lead times for mining projects.
Foremost among supply-side factors is the complexity of coproduction with other materials. None of
the individual REEs or other key materials discussed above is mined individually or as the primary
focus of commercial extraction activities. Instead, they are produced as coproducts or secondary
products of other materials that may have entirely different applications, scale of use, prices and
The impact of coproduction on market dynamics is a function of the prices of the coproducts, their
abundance in the ore and the costs of separation and refining for each product. For example, the
iron produced as a primary product in the Baotou (China) mines is less valuable by weight than the
REE byproducts, but annual iron production represents more than 100 times the value of the
bastenite ore. The iron is also more easily separated from the ore and processed into a marketable
commodity. In cases like Baotou, mines may generate the majority of their revenue from extraction
of the primary product, ignoring considerations of the minor metal and making operational
decisions primarily based on the price and demand for the primary product.
Currently, China is the source of more than 95% of the world’s rare earth oxides. This concentrates
nearly all the supply-side market power in a single actor. This means that actions by China related to
REEs, such as the recent tightening of export quotas, directly influence the market. For example,
during the late summer and early fall of 2010, prices for many REEs increased 300%–700% (as shown
in Chapter 3) in the wake of a series of geopolitical developments involving China. In addition,
decisions concerning REE production in China may be motivated by factors beyond the REE market.
In addition to coproduction issues, producers of REEs and other key materials are limited in their
ability to increase supply. Even if the market demand for a particular element would make increased
production highly profitable on a tonnage basis, mining companies may be unable to rapidly
increase production or quickly open new mines. They are constrained by capital costs typically in the
billions of U.S. dollars and by long lead times required for exploration, permitting and facility
construction. Some industry experts estimate that a 10-year lead time from initial exploration to the
construction of new mines for rare earth elements is typical of the industry. Many of the enterprises
working to develop rare earth reserves are junior mining companies engaged in only one project and
do not have the financial resources to bring their ore bodies into production. As a consequence, for
the developer to achieve commercial viability the company in many cases must “lock in” a buyer for
the output of the mine even before the separation and refining process is fully operational. This
creates enormous management challenges for the developers and substantial uncertainty for both
7.8 Conclusion
Four clean energy technologies have been the principal focus of this analysis:
• Permanent magnets made from alloys of REEs used in wind turbines and advanced vehicles
with electric drives
• Advanced batteries that incorporate REEs in their electrodes or are based on lithium-ion
chemistries used in advanced vehicles with electric drives
• Photovoltaic power systems using thin-film semiconductors
• Rare earth phosphors used in high-efficiency fluorescent lighting systems
Efforts to accelerate the commercialization and deployment of these four clean energy technologies
face considerable risks of supply-demand imbalances that could lead to increased price volatility and
supply chain disruption. The character and severity of these risks varies among the REEs and other
key materials evaluated in this study. A number of options are available to the Department of
Energy to reduce or mitigate these risks. These options will be discussed and evaluated in the
following chapters of this study.
References
IEA (International Energy Agency). 2009. World Energy Outlook 2009.
IEA (International Energy Agency). 2010a. Energy Technology Perspectives 2010.
IEA (International Energy Agency). 2010b. Phasing Out Incandescent Lamps.
Indium Corp. 2010. “Indium, Gallium & Germanium Supply & Price Outlook.” Presented by Gregory
Evans to the TREM 2010 Conference, Washington, DC, April.
Roskill. 2010. “Rare Earths: An Evaluation of Current and Future Supply.” presentation by Judith
Chegwidden to the 2010 Rare Earth Summit, Beijing, August 4–5.
USGS (U.S. Geological Survey). 2008a. USGS Minerals Yearbook 2008: Indium. Reston, VA: USGS.
USGS (U.S. Geological Survey). 2008b. USGS Minerals Yearbook 2008: Bauxite and Alumina. Reston,
VA: USGS.
USGS (U.S. Geological Survey). 2008c. USGS Minerals Yearbook 2008: Tellurium. Reston, VA: USGS.
Supply Risk
The overall supply risk for each material is based on five categories of risk for the short and medium
term. For each category, key materials were assigned qualitative factor scores of 1 (least critical) to
4 (most critical). The categories are described in more detail below.
Basic Availability (40%): the extent to which global supply will be able to meet demand. Short-term
basic availability examines mine and other production relative to demand. Medium-term basic
availability examines the potential for other mines to begin producing the material relative to
anticipated increases in demand. The qualitative score is informed by the projections in Chapter 7,
but may also take into account other factors such as global reserves, mines projected to start up
after 2015 and additional supplies from recycling.
Competing Technology Demand (10%): captures whether non-energy sector demand is expected to
grow rapidly, thus constraining the supply of the material available for the energy sector.
Political, Regulatory and Social Factors (20%): risk associated with political, social and regulatory
factors within major producer countries. This includes the risk that political instability in a country
will threaten mining and processing projects; that countries will impose export quotas or other
restrictions; or that social pressures, permitting and regulatory processes will delay the start up of
new mines.
Co-dependence on other Markets (10%): covers instances where a mineral is coproduct or
byproduct of with other minerals found in the same ore deposit. Co-dependence can be an
advantage or a disadvantage, depending on which mineral is driving production levels overall. In
general, coproducts with lower revenue streams (i.e. production rate X price) will have higher scores
since they are less likely to drive production than coproducts with higher revenue.
Producer Diversity (20%): captures market risks due to the lack of diversity in producing countries
or companies (e.g., monopoly or oligopoly).
The criticality matrices in Figures 8-1 and 8-2 suggest three broad categories of criticality. Materials
in the upper quadrant of the chart (with scores of three or higher on both axes) are characterized as
critical. Materials with a score of three or higher on one axis but a two on the other axis are
characterized as near-critical. While they are not currently judged to be critical, small changes in one
or more risk category could put them at criticality. All other materials are judged not to be critical.
However, all of the assessments are based on the best available information, so even materials
judged not critical could be at risk due to significant unforeseen circumstances. The distribution of
materials by criticality categories in the short and medium term is shown in Table 8-1.
According to the analysis, indium and rare earth elements dysprosium, terbium, europium,
neodymium and yttrium are critical in the short term. The uses for the critical rare earth elements
are spread across magnets, batteries and phosphors and indium is used in PV films. Thus, each of
the clean energy technologies examined in the Strategy has at least one critical material in the short
term. Tellurium, cerium and lanthanum are near-critical, and gallium, lithium, cobalt, praseodymium
and samarium are not critical. Between the short and the medium term, importance to clean energy
and supply risk shift for some materials. For example, the supply risk for neodymium decreases,
while the importance to clean energy increases. The supply risk for dysprosium and yttrium both
decrease. On the other hand, both the importance to clean energy and the supply risk for lithium
increase to make lithium near critical in the medium term.
Lithium is the only key material that shifts into a higher criticality category from the short to
medium term. This change is due to the rapid increases in market penetration projected for vehicles
using lithium-ion batteries, which increases lithium’s importance to clean energy. This market
penetration would significantly increase demand even as lithium production capacity increases, thus
increasing supply risk slightly.
All other key materials either remain in the same category or become less critical in the short to
medium term. For the materials that shift to a lower category, this change generally reflects a
combination of expanded supply and increased alternatives for substitution at different levels of the
supply chain. Market dynamics, described in Chapter 7, will play a large role in these positive
criticality changes. However, that same discussion also highlighted the market complexities and
distortions that remain for many key materials, suggesting an important role for government. The
next chapter lays out the U.S. Department of Energy’s strategy for using targeted research and
development, combined with other policy options, to address material criticality.
References
NAS (National Academy of Sciences). 2008. Minerals, Critical Minerals and the U.S. Economy.
Figure 9-1 Policy options and the critical material supply chain
• Materials
• Nano-structured permanent magnets, including core-shell structures and composites
• Improved high-temperature performance of NeFeB magnets
• Enhanced magnetic coercivity for rare-earth, alnico and other magnets
• Fundamentals of anisotropy and new anisotropic mechanisms
• High-flux soft magnets
• Batteries
• Continued R&D supporting advanced technologies that utilize abundant elements, such as
iron and zinc
• Photovoltaics
• Improved deposition processes to reduce cadmium telluride (CdTe) and/or copper-indium
gallium diselenide (CIGS) active layer thickness and minimize deposition waste
• Materials research on polycrystalline PV alternatives
• Lighting
• Alternative phosphor materials, including the use of quantum dots that minimize or
eliminate the use of cadmium or rare earth elements—the most difficult materials issues in
lighting are likely to revolve around the supply of terbium (used for green phosphors) and
europium (used for red and blue phosphors)
• Organic LEDs, with improvements to luminous efficacy, cost and color rendering
• Non-traditional water source use (e.g., treated waste water, saline aquifer)
• Long-term interactions between groundwater and mine excavations
• Alternatives to tailing impoundments
• Optimized blasting and efficient crushing for lower energy consumption
Materials Processing
Innovations in the processing of ore into metals or other compounds are important for both the rare
earth element and lithium supply chains. Processes with improved oxide or carbonate recovery,
84
EPA, for example, has delegated federal regulatory authorities to states under the Clean Air Act, Clean
Water Act and Resource Conservation and Recovery Act. A mine or processing plant may be required to obtain
a series of permits under these acts before such a facility can begin operations. The securing of such permits
requires the submittal of complex environmental modeling results which must show that a facility can meet its
regulatory standards during operations. Further, if a mine or processing plant triggers a "major federal action"
as defined under the National Environmental Protection Act, the facility may also be required to prepare an
Environmental Impact Statement (EIS). Such an EIS can take up to two to five years to complete.
85
The Council for Environmental Quality is leading an interagency group for providing rapid response
capability to fix coordination problems between federal agencies on renewable and transmission permit
applications. A similar approach could apply to the mining permit process as well.
86
DOE also has limited authorities under the Defense Production Act (DPA) that could affect the production of
critical materials. Under Title I of the DPA, DOE can exercise priority rights over private parties in procurement
for projects that maximize domestic energy supplies, including those that maintain or further domestic energy
Price Supports
One barrier to establishing and sustaining domestic production capacity for critical materials may be
the ability of countries with considerable market share to cut prices, potentially driving mines in
other countries out of business. If there is a national interest in the United States developing the
capacity to produce rare earth metals and other critical materials domestically, it may be worth
analyzing whether some type of price support system is appropriate. More data collection and
analysis would be required to define the parameters of such a program, determine its potential
costs and consider conditions under which it might be in the national interest.
9.5 Stockpiles
Several countries have developed or are considering stockpiles for key materials, as described in
Chapter 6. In addition, the DoD has moved to include many of the materials considered in this
Strategy in a new Strategic Military Stockpile Program (SMSP), as described in Chapter 5. The SMSP
will help meet the DoD’s legal requirement to provide special monitoring and attention for all
strategic materials and ensure that those materials further deemed as critical to national security
are also sourced domestically (Defense Strategic Materials Protection Board 2008). 87
In theory, stockpiles could protect the United States from interruptions in supply from foreign
producers. The existence of a stockpile, whether or not used, could have geopolitical significance,
diminishing the leverage of monopoly suppliers in crisis situations. If coupled with purchase and
price guarantees, stockpiles might also promote investment in new domestic mines by providing
protection from commodity price swings.
exploration, production and refining. Title III of the DPA authorizes the President to provide incentives
including loan guarantees for the development, modernization or expansion of domestic defensive productive
capacity and supply. Recent Title III projects have included the development of a U.S.-owned domestic source
for prismatic lithium-ion cells and batteries for spacecraft use.
87
The DoD defines a “strategic material” as one 1) which is essential for important defense systems, 2) which
is unique in the function it performs and 3) for which there are no viable alternatives. A “critical material” is a
strategic material for which 1) the Department of Defense dominates the market for the material, 2) the
Department’s full and active involvement and support are necessary to sustain and shape the strategic
direction of the market and 3) there is significant and unacceptable risk of supply disruption due to vulnerable
U.S. or qualified non-U.S. suppliers.
9.8 Diplomacy
Many other countries are considering questions similar to those explored in this
Strategy. Cooperation with those countries can provide useful information and help improve
transparency in markets for critical materials. It can also help to optimize resources for research and
accelerate research and development on key topics. For these reasons and more, DOE will work
closely with counterparts in other governments in the years ahead.
More broadly, addressing these issues will require sustained U.S. diplomatic engagement. Working
closely with the State Department and other agencies, DOE will engage other countries through
dialogues and collaborative institutions. A primary objective will be to maintain frequent and open
communication with important stakeholders. Building on ongoing discussions with partners such as
the European Union and Japan, DOE will engage significant producers and consumers of critical
materials. DOE will participate in multilateral fora, such as the International Energy Agency, to
References
Ames Laboratory. 2010. “Responses to DOE Request for Information.” June 7.
Behre Dolbea. 2010. 2010 Ranking of Countries for Mining Investment.
Hamilton, T. “Lithium Battery Recycling Gets a Boost.” Technology Review. Accessed August 12.
http://www.technologyreview.com/energy/23215/
LaMonica, M. “E-Waste Showdown Unearths Deeper Questions.” Green Tech, Jan. 16.
http://news.cnet.com/8301-11128_3-10435193-54.html.
Matthews, R. G. “Permits Drag on U.S. Mining Projects.” Wall Street Journal, February 8, 2010.
NRC. 2008. “Minerals, Critical Minerals the U.S. Economy.” The National Academies Press.
Umicore. 2010. “Responses to DOE Request for Information.” June 7.
Table A-1. Short- and Medium-Term Criticality Scores for Key Materials
Weight: 0.75 0.25 Weight: 0.4 0.1 0.2 0.1 0.2
Importance to Political, Co-
Clean Energy Clean Supply Risk Competing Regulatory, dependence
(Rounded Energy Substitutabilty (Rounded Basic Technology and Social with other Producer
Atomic # Score) Demand Limitations Score) Availability Demand Factors markets Diversity
Short Term
lithium 3 2 2 2 1 1 1 1 1 1
cobalt 27 2 2 2 2 1 2 3 2 2
gallium 31 3 3 2 1 1 2 1 3 1
yttrium 39 3 3 4 4 4 2 4 2 4
indium 49 3 3 2 3 4 3 1 3 1
tellurium 52 3 3 2 2 3 2 1 3 1
lanthanum 57 3 3 3 2 2 2 3 2 3
cerium 58 3 3 2 2 1 2 3 2 3
praseodymium 59 2 2 1 2 2 1 3 3 3
neodymium 60 3 3 3 4 4 2 4 2 4
samarium 62 1 1 1 2 2 1 3 3 3
europium 63 3 3 4 3 3 2 4 3 4
terbium 65 3 3 3 4 4 2 4 4 4
dysprosium 66 4 4 3 4 4 2 4 3 4
Importance to Political, Co-
Clean Energy Clean Supply Risk Competing Regulatory, dependence
(Rounded Energy Substitutabilty (Rounded Basic Technology and Social with other Producer
Score) Demand Limitations Score) Availability Demand Factors markets Diversity
Medium Term
lithium 3 3 3 2 2 2 2 1 1 1
cobalt 27 2 2 2 2 1 2 2 2 2
gallium 31 3 3 2 1 1 3 1 3 1
yttrium 39 3 3 4 3 3 2 3 2 3
indium 49 3 3 2 2 3 4 1 3 1
tellurium 52 3 3 2 2 3 2 1 3 1
lanthanum 57 2 2 3 2 2 2 3 2 2
cerium 58 2 2 2 2 1 3 3 2 2
praseodymium 59 2 2 1 2 2 2 3 3 2
neodymium 60 4 4 3 3 3 2 4 2 3
samarium 62 1 1 1 2 2 2 3 3 2
europium 63 3 3 4 3 3 2 3 3 3
terbium 65 3 3 3 4 4 2 4 4 3
dysprosium 66 4 4 3 4 4 2 4 3 4
CO-DEPENDENCE ON • Moderate revenue stream due to low abundance and historically high prices.
• Revenue stream has remained flat compared to LREEs, whose prices have increased
OTHER MARKETS
dramatically due to recent export restrictions.
Short Term: 3
• Most abundant of the HREEs in many Chinese ores, but found in low concentrations
Medium Term: 3 elsewhere.
PRODUCER • Found in relatively small amounts in new Western mines scheduled to begin
DIVERSITY production in the short and medium term. Mountain Pass will produce minimal
Short Term: 4 amounts of dysprosium, and other new mines scheduled to begin production by 2015
Medium Term: 4 will increase production by less than 15% over current levels (see Figure 7-2).
References
GE (General Electric). 2010. “Response to U.S. Department of Energy’s Request for Information.” June 7.
Kingsnorth, D. 2010. “Rare Earths: Facing New Challenges in the New Decade.” Presented at the Society for Mining
Metallurgy and Exploration Annual Meeting. Phoenix.
Oakdene Hollins. 2010. “Lanthanide Resources and Alternatives.” Aylesbury, UK: Department for Transport and
Department for Business, Innovation and Skills. http://www.oakdenehollins.co.uk/.
Market Share
Market share assumptions for batteries used in each type of vehicle are:
• Positive electrode capacity: A total power rating of 1.3 kWh and 1.2 V/cell was assumed.
This yields a total positive electrode capacity of 1,083 Ah [=1.3kWh/1.2V*1000].
• Negative electrode capacity: This is calculated as negative electrode capacity = (positive
electrode capacity)*n/p, where n/p is the assumed ratio of negative to positive electrode
capacity. For the high material content case, an n/p ratio of 1.8 is assumed, which
represents a likely value for current generation technology. For low material content, an n/p
ratio of 1.2 is assumed, which represents a lower value that is technically feasible. These
assumptions yield negative electrode capacity values of 1,950 Ah (high material content)
and 1,300 Ah (low material content).
• Wind turbines: The low market share assumption is that 10% of both onshore and offshore
wind turbines will use NdFeB PM generators. The high market share assumption is that 25%
of onshore wind turbines and 75% of offshore wind turbines will use NdFeB PM generators.
Rationale: There is no publicly available data on current market share, but anecdotal
discussions with industry experts indicates that only a small percentage of the wind turbines
currently use rare earth permanent magnets. Therefore, the low market share represents a
continuation of current market share trends. The high market share assumption is based on
the preference for NdFeB permanent magnet generators in larger wind turbines (in the 2-3+
MW range) and the trend towards the use of larger turbines in new wind projects,
particularly for offshore applications.
• Electric Drive Vehicles: All electric drive vehicles (HEVs, PHEVs and EVs) are assumed to use
NdFeB PM motors.
Rationale: Due to their superior power to weight ratio, NdFeB PM motors are used in
current model HEVs, as well as the Chevy Volt PHEV and Nissan Leaf EV. These PM motors
are expected to dominate the electric drive vehicle market well into the medium term,
although new motors without rare earth materials are being developed (Aston 2010).
Material Intensity
Material intensity for NdFeB PM motors and generators is calculated as follows:
• Wind turbines: Material intensity for neodymium and dysprosium is calculated from the
estimated weight of total NdFeB magnet material per MW of turbine output. High and low
estimates for total magnet weight are 600 kg/MW and 400 kg/MW, respectively, based on
Arnold Magnetics RFI submission (2010). Neodymium and dysprosium content is estimated
to be 31% and 5.5% of magnet weight, respectively, assuming a NdFeB-AH magnet
composition (Electron Energy Corporation 2010).
• Electric Drive Vehicles: Material intensity for neodymium and dysprosium is calculated from
the estimated weight of total NdFeB magnet material per vehicle motor. The high weight
estimate for magnets is 2 kg per vehicle, based on General Electric (2010). The low estimate
is 1 kg/vehicle, based on Lifton (2009). Neodymium and dysprosium content is estimated to
be 31% and 5.5% of magnet weight, respectively, assuming a NdFeB-AH magnet
composition (Electron Energy Corporation 2010).
The difference between the high and low material content estimates for magnets accounts for
incremental improvements that are likely to occur in the short to medium term, as well as wide
variations in individual manufacturers specifications for magnets. Material content estimates also
assume that magnets do not contain praseodymium, which can reportedly be substituted for
neodymium (up to 25%) to reduce cost and increase corrosion resistance (Oakdene Hollins 2010).
The actual extent of this substitution is uncertain.
Material Intensity
Material intensity calculations for tellurium, gallium and indium used in CdTe and CIGS PV cells are:
• Tellurium intensity in CdTe: High materials intensity assumes 3.1 grams tellurium per cubic
centimeter (cc) of thin film, a 2.1 micron absorber layer and 10% cell efficiency. This yields a
material intensity of 0.145 g/W or 145 tonnes tellurium per GW. Low materials intensity
Lighting Phosphors
Due to a lack of available data on the deployment of high efficiency light bulbs, demand projections
for phosphors were not developed using the same type of market share or material intensity
calculations developed for batteries, magnets or PV cells. Instead, projections are based on high and
low rates of compound growth from estimated 2010 lighting phosphor demand, combined with
assumptions about average weight percentages of each rare earth used in phosphors.
Estimated total phosphor demand in 2010 is reported by Lynas Corporation as 7,900 tonnes rare
earth oxide (REO). Based on estimates from a number of lighting industry experts, eighty-five
percent of this phosphor demand is assumed to be for lighting, yielding a total 2010 lighting
phosphor demand of 6,715 tonnes REO.
Lighting phosphor demand for individual rare earth elements in 2010 was calculated based on
estimated percentage breakdowns of total phosphor demand by element provided by Lynas (2010).
The results are shown in table B-3.
References
Aston, A. 2010. “China's Rare-Earth Monopoly: The rest of the world is trying to find alternatives to
these crucial materials.” Technology Review, October 15.
http://www.technologyreview.com/energy/26538/?ref=rss.
DOE (U.S. Department of Energy) EERE (Energy Efficiency and Renewable Energy) .2009. “2010
Toyota Prius-6063 Hybrid BOT Battery Test Results.” U.S. Department of Energy. July 15.
http://avt.inel.gov/pdf/hev/batterygenIIIprius6063.pdf.
DOE (U.S. Department of Energy) EERE (Energy Efficiency and Renewable Energy). 2010. “Expert
judgment by vehicle battery specialist.”
Electron Energy Corporation. 2010. “Response to U.S. Department of Energy Request for
Information.” June 5.
Gains, L. and P. Nelson. 2009. “Lithium-Ion Batteries: Possible Material Demand Issues.” Argonne
National Laboratory. http://www.transportation.anl.gov/pdfs/B/584.PDF.
General Electric Corporation. 2010. “Response to U.S. Department of Energy Request for
Information.” June 7.
Grana, P. 2010. “The Efficiency Race: How do CdTe and CIGS Stack Up?”
Renewableenergyworld.com. http://www.renewableenergyworld.com/rea/blog/post/2010/11/the-
efficiency-race-how-to-cdte-and-cigs-stack-up.
International Energy Agency (IEA). 2010. Information Paper: Phase Out of Incandescent Lamps.
http://www.iea.org/papers/2010/phase_out.pdf.
Lifton, J. 2009. “The Rare Earth Crisis of 2009.” The Jack Lifton Report. October 15. In Oakdene
Hollins 2010.
Lynas Corporation. 2010. “Response to U.S. Department of Energy Request for Information.” June 7.
National Research Council. 2010. “Transitions to Alternative Transportation Technologies – Plug-in
Hybrid Electric Vehicles.” http://www.nap.edu/catalog.php?record_id=12826.
NREL (National Renewable Energy Laboratory). 2010. Email communication, September 17, 2010.
Oakdene Hollins. 2010. “Response to U.S. Department of Energy Request for Information.” May 26.
Reddy, Thomas R. ed. 2011. Linden’s Handbook of Batteries. New York: McGraw Hill.
Toyota. 2009. “Toyota Prius Emergency Response Manual, Hybrid 2010 Model 3rd Generation.”
https://techinfo.toyota.com/techInfoPortal/staticcontent/en/techinfo/html/prelogin/docs/3rdprius.
pdf
KEYNOTE ADDRESS
DAVID SANDALOW
ASSISTANT SECRETARY
FOR POLICY & INTERNATIONAL AFFAIRS
U.S. DEPARTMENT OF ENERGY
WASHINGTON, D.C.
MARCH 17, 2010
[Acknowledgements.]
1. INTRODUCTION
At energy conferences today, no topic is hotter than shale gas. The story is striking: recoverable
reserves of shale gas have increased six-fold in the past few years, thanks to new drilling
technologies. This increase has been transformational, with U.S. natural gas imports now
predicted to drop steadily in the next decade and beyond, whereas just a few years ago imports
were projected to climb for the foreseeable future. Large shale gas reserves are believed to exist
in other places around the world, including China and Eastern Europe, with potentially dramatic
implications for patterns of energy use in those regions as well.
Before answering that question, let me tell you about a much less well-known resource: rhenium.
Rhenium is the chemical element with atomic number 75. In part due to its very high melting
point, rhenium is a critical component in nickel-based “superalloys,” which are capable of
functioning under very high stress. These superalloys are used in the jet engines of military
aircraft and some of the world’s most energy-efficient gas turbines.
So metallurgists at General Electric have worked to develop alternative superalloys that use less
rhenium. GE has also partnered with the U.S. Navy and leading airlines to recycle turbine blades
that contain rhenium. These steps have helped mitigate the risk of future rhenium supply
disruptions or price spikes.
That supply constraints aren’t static. Strategies for addressing shortages of strategic resources
are available, if we act wisely. We can invest in additional sources of supply. We can develop
substitutes. We can re-use materials and find ways to use them more efficiently. We can
consider use of stockpiles and strategic reserves. Not every one of these strategies will work
every time. But taken together, they offer a set of approaches we should pursue as appropriate
whenever potential shortages of natural resources loom on the horizon.
That brings us to rare earth metals. As participants at this conference know, “rare earths” are
typically defined to include the 15 elements in the periodic table with atomic numbers 57
through 71, along with several other elements. They include elements unfamiliar to most people,
such as lanthanum, cerium, neodymium and europium.
Ironically, rare earth elements are not actually rare. Their misleading name probably comes from
early mining of these elements in Europe, which focused on extraction from minerals that were
quite uncommon. In fact, most rare earth elements are widely distributed in the Earth’s crust.
Indeed the abundance of rare earths in the Earth’s crust is higher than that of some major
industrial metals. Even the least abundant rare earths are found in greater quantities than, for
example, bismuth and cadmium.
Rare earth elements have many desirable properties, including the ability to form unusually
strong, lightweight magnetic materials when alloyed with other metals. They also have
distinctive and valuable optical properties including fluorescence and emission of coherent light
– important for lasers. Many of these properties result from the presence of an unfilled inner
electron shell in their atomic structure.
Although rare earth metals are found in many places on Earth, including the United States,
Canada, Australia, Brazil and South Africa, they are difficult to extract in profitable quantities
without substantial time and cost. This has led to geographically concentrated production.
Geographic concentration in the production of rare earth metals is not new. Prior to 1948, most
of the world’s rare earth production came from placer sand deposits in Brazil and India. In the
following decades, production shifted to monazite deposits in South Africa and elsewhere. In the
1970s and 1980s, global production was dominated by the output from the Mountain Pass mine
in California. Today, although production of rare earths still occurs in a number of countries,
more than 95 percent of global supply is produced in China.
It goes without saying that diversified sources of supply are important for any strategic material.
So too are substitutes and strategies for re-use and recycling. If rare earth metals are going to
play an increasing role in our economy, we need to pursue those strategies. And there’s every
reason to believe that rare earth metals could play an increasing role in the global economy as the
world transitions to clean energy.
This transition is already well underway. The world is on the cusp of a clean energy revolution.
Here in the United States, the Obama Administration is making historic investments in clean
energy.
The American Recovery and Reinvestment Act was the largest one-time investment in clean
energy in our nation’s history – more than $80 billion. At the Department of Energy, we’re
investing our $37 billion in Recovery funds in electric vehicles; batteries and advanced energy
storage; a smarter and more reliable electric grid; and wind and solar technologies, among many
other areas. Through this investment, we’ll at least double our renewable energy generation and
manufacturing capacities by 2012. We’ll also deploy hundreds of thousands of electric vehicles
Other countries are also seizing this opportunity. Indeed, the market for clean energy
technologies is growing rapidly all over the world.
Today, the Chinese government is launching programs to deploy electric cars in 13 major cities.
It’s connecting urban centers with high-speed rail. It’s building huge wind farms, ultra-
supercritical advanced coal plants and ultra-high-voltage long-distance transmission lines with
low line loss.
India has launched an ambitious National Solar Mission, with the goal of reaching 20 gigawatts
of installed solar capacity by 2020.
In Europe, strong public policies are driving sustained investments in clean energy. Denmark is
the world’s leading producer of wind turbines, earning more than $4 billion each year in that
industry. Germany and Spain are the world’s top installers of solar photovoltaic panels,
accounting for nearly three-quarters of a global market worth $37 billion last year.
Around the world, investments in clean energy technologies are growing, helping create jobs,
promote economic growth and fight climate change. These technologies will be a key part of the
transition to a clean energy future.
However today, many of these technologies rely on the special properties of rare-earth metals.
There’s no reason to panic, but there’s every reason to be smart and serious as we plan for
growing global demand for products that contain rare earth metals and other strategic materials.
For the clean energy economy to reach its full potential, we must work together to ensure stable
supplies of the materials required. That means working together to diversify global supply
chains, as well as investing in manufacturing and processing. It means research and
development into substitutes. It means finding ways to recycle and re-use scarce materials. U.S.
talent and innovative capacity in materials science can be harnessed to create the next generation
of rare earth applications and competing technologies.
To proactively address the availability of rare earths and other strategic materials required for the
clean energy economy, we must take a three-part approach:
The United States will explore investments at all stages of the supply chain, from
environmentally-sound material extraction, to purification and processing, to the manufacture of
chemicals and components, and finally to end uses. These investments will help the United
States strengthen our manufacturing base over the long term. And we will examine issues
related to strategic stockpiling of critical materials, especially those with dual-use potential, i.e.,
in both civilian and military applications.
Second, we must develop substitutes. Doing so will improve our flexibility as we address the
materials demands of the clean energy economy. This means investing in RD&D to develop
transformational magnet, battery terminal and other technologies that reduce our dependence on
rare earths. DOE’s Vehicle Technologies Program, the ARPA-E program, and our national labs
are all currently conducting research along these tracks. The ARPA-E program recently funded
a consortium of universities, laboratories and private companies to conduct research into high-
energy permanent magnets that will use domestically-available materials while more than
doubling magnetic energy density over current state-of-the-art technologies.
Third, we must promote recycling, re-use and more efficient use of strategic materials, to get
more economic value out of each ton of ore extracted and refined. As in the case of GE’s turbine
blade recycling program, re-use can help mitigate potential supply constraints. Widespread
recycling and re-use could significantly lower world demand for rare earths and other strategic
materials. And, importantly, recycling and re-use could also reduce the lifecycle environmental
footprint of these materials.
As a society, we have dealt with these types of issues before, mainly through smart policy and
R&D investments that reinforced efficient market mechanisms. We can and will do so again.
To help address these concerns, I am today announcing that the Department of Energy will
develop its first-ever strategic plan for addressing the role of rare earth and other strategic
materials in clean energy technologies. The plan will apply the approaches described above and
5. CONCLUSION
So in conclusion, as I said earlier: there’s no reason to panic, but every reason to be smart and
serious as we plan for growing global demand for products that contain rare earth metals.
The United States intends to be a world leader in clean energy technologies. Toward that end,
we are shaping the policies and approaches to help prevent disruptions in supply of the materials
needed for those technologies. This will involve careful and collaborative policy development.
The United States will develop and implement systematic approaches to building a stable,
geographically diverse supply chain; encourage technical innovations to identify substitutes as
well as minimize the requirements for these key materials; and encourage recycling and re-use
wherever possible. We will rely on the creative genius and entrepreneurial ingenuity of the
business community to meet an emerging market demand in a competitive fashion. Working
together, we can meet these challenges.
Agenda
U.S. – Japan Roundtable on Rare Earth Elements Research
and Development for Clean Energy Technologies
Thursday-Friday, November 18-19, 2010
Building 453, Black Diamond Conference Room 1012
U.S. Department of Energy
Lawrence Livermore National Laboratory
THURSDAY, November 18, 2010
7:30 Badging Westgate Badge Office
Met by Evelyn Laurant
8:30 – 9:00 Welcome and Introduction to the Roundtable
Al Ramponi, Lawrence Livermore National Laboratory
Kay Thompson and Diana Bauer, Department of Energy
9:00 – 9:30 A Brief Overview of the Rare Earths Crisis
Karl Gschneidner, Ames Laboratory
Discussant: Roderick Eggert, Colorado School of Mines
9:30 – 10:45 Geological Availability of Rare Earth Elements
Session Chair: Bill Bourcier, Lawrence Livermore National Laboratory
Keith Long, U.S. Geological Survey; New Sources of Primary REE Production:
When and at What Cost
Tetsuichi Takagi, National Institute of Advanced Industrial Science and
Technology, Japan
Bradley Van Gosen, U.S. Geological Survey; The Principal Rare Earth Elements
Deposits of the United States
10:45 – 11:00 Break
11:00 – 12:30 Recovery, Extraction and Separation of REE from Mineral Ores, Part I
Session Chair: Alex King, Ames Laboratory
Brock O’Kelley, Molycorp Minerals, LLC
Patrick Taylor and Corby Anderson, Colorado School of Mines; Mineral
Processing, Extraction and Refining of Rare Earth Minerals
Junji Shibata, Kansai University; Separation and Purification Technology for
REE
ARPA-E WORKSHOP
Rare Earth and Critical Materials
December 6, 2010 in Arlington, VA
BACKGROUND ................................................................................................................................................ 2
AGENDA .......................................................................................................................................................... 9
Contact Information....................................................................................................................... 10
The workshop will consist of five plenary talks and four breakout sessions. The breakout sessions
will be run concurrently in groups of two, with focuses on:
Supply / Material processing
Magnets and magnetic systems / motors and generators
Phosphors and general illumination
Catalysts and separators
Experts from across science and engineering will be brought together to identify possible new
approaches and pathways to addressing technical challenges in critical materials across these fields.
BACKGROUND
Existing availability of rare-earth materials is limited by the processing of these materials into usable
form (elemental metal, oxide etc) from known deposits. Existing process technologies are based on
acid-alkaline chemical processes followed by solvent extraction to yield elemental species
separation. Commercial scale acid-alkaline processes use large quantities of reagents. As a result,
environmental and cost considerations for processing rare-earth materials have been prohibitive,
particularly in developed nations. Environmental impacts are significant with more tangible costs in
developed nations. Pathways to new rare-earth materials processes, which have minimized
environmental impacts, are of high interest for discussion and examination in this workshop.
The rare earths are rather challenging to separate chemically as the latent heats of oxide formation
are nearly the same between rare-earth elements. Further, solubilities of rare-earth ions in solution
and separation coefficients are very similar for most solvents. Rare earths elements may often be
separated into light (lanthanum, cerium, neodymium, praseodymium) and heavy (terbium,
europium lutetium, gadolinium) elements based on characteristic ores. Light rare-earth element
deposits are by far more prevalent. In this workshop and break out session, we are interested in
completely new processes and approaches (physical, chemical or biological) to separation and
processing, particularly for heavy rare-earth elements of high importance to energy applications.
With the increased demand for neodymium and dysprosium for permanent magnets, new high-
selectivity separation technologies are needed. Neodymium has low separation selectivity relative
to praseodymium, and dysprosium occurs in very low concentration in most rare-earth ores. New
separation technologies might be based on chemical (species specific ionic liquids and solvents),
physical (species specific porous membranes) or biological (elementally specific geobacters) means
as possible mechanism for processing. New technology pathways to cost effective separation and
concentration of neodymium and dysprosium are of high interest for examination in this workshop.
QUESTIONS:
Are there completely new process pathways which may be used, and subsequently scaled, for the
processing of rare earths?
Can we leverage the knowledge base from the actinide materials processes realm to the lanthanide
/ rare-earth materials processes? For example, highly selective processes for the isolation of
Americium and for the separation of Thorium from water have been developed. Can the physical
and chemical methods used in these heavy-element separation technologies be applied to rare-
earths?
Geobacters have been studied over the past few years as microorganisms with metabolisms which
chemically interact with compounds and minerals. Can geobacters with strong affinity for specific
rare-earth elements be identified and developed in potentially industrially relevant processes?
BACKGROUND
Rare earth metals of Neodymium and Dysprosium are of high importance for highest energy product
permanent magnets, in the form of Nd2Fe14B material. Such magnets are of increased use in electric
motor and generator applications of the energy sector as the coupling means between torque and
electricity. Dysprosium is used in higher Curie temperature permanent magnets and as a result is of
increased importance for electric motors, particularly in the transportation sector. In this workshop,
magnetics will be addressed from two directions: identification of potential material alternatives at
the component level and of potential magnet replacements at the system level. Technologies for
either possible technical approach (component or system) are of high interest and possible
pathways will be investigated in this workshop.
Nanoscale magnetic material mixtures have been shown to have potential for high-energy product
in permanent magnets, with reduced rare earth material content, through spring-exchange coupling
of hard and soft magnetic phases in close proximity (< 50nm). ARPA-E has already initiated two
projects in this approach: University of Delaware project is focused on aligned nanoscale mixtures of
hard and soft magnetic materials; and General Electric project will demonstrate consolidated hard
and soft phases of core/shell nanoparticles
In this workshop and breakout session, we are looking for even newer / alternative approaches to
reduced rare-earth content permanent magnets in energy systems.
QUESTIONS:
Are there other non-rare earth content magnets which may exhibit high coercivity, particularly as a
potential hard-phase in nanoscale composites? For instance PtCo forms very high energy density
permanent magnets with no rare-earth content, although the cost is prohibitive. What new
magnets might exhibit high coercivity with low rare-earth content?
Alternatively, what are the technical barriers to the use of superconducting magnets in some
applications, such as high power wind turbines (>1 MW)?
Are permanent magnets necessary in high energy density electric motors for vehicles and what
alternatives exist? For instance, with recent advances in power electronics, can induction or
reluctance motorsefficiently couple torque and electric energy at acceptable cost and weight
requirements? What technology advances are required to use non-permanent magnet motors in
transportation or heavy industrial applications?
BACKGROUND
Rare earth materials are used as both dopant or compositional quantities for phosphors. Terbium,
Erbium, Yttrium and Europium are all used as red green and blue phosphors for white lighting. New
phosphors are used to downshift UV or blue emission from LEDs to form color corrected white LEDs.
Proposed strategies for dealing with reduced rare-earth availability include recycling programs
where the phosphors from older tubes form the supply for new high-efficiency lighting.
In this workshop and breakout session, we are most interested in identifying over-the-horizon new
technology opportunities for rare-earth free phosphors or alternative mechanisms for generation of
high color rendering index white emission for high efficiency general illumination. Technologies
which harnessing surface plasmon effects are of high interest.
QUESTIONS:
Are there high-efficiency optical transitions in non-rare-earth materials which can be used as an
alternative particularly for new LED or OLED sources of white light? For instance, can size and
shape of nanoparticle emitters be manipulated to control color in non-rare-earth phosphors as they
are in aqueous environments for biological applications? Can new phosphors be developed which
only use rare earths materials in dopant quantities (less than 0.1%)? For downshifted LED or OLED
emitters, what technology gaps are there in matching emission wavelength to phosphor absorption
to achieve high color rendering index white emission? What are the technology gaps for the
emission intensity from multiple wavelength LEDs to be controlled, at a low enough cost, such that
the resulting color remains consistent over time, even as individual emitters are subject to
degradation?
BACKGROUND
Rare earth oxides such as Ceria are used significantly in applications involving oxygen catalysis and
transport through ceramic separators. Examples include: Ceria stabilization on Na-Y Zeolite
catalysts are used for fluid catalytic cracking in most modern petroleum refining of gasoline for the
transportation sector; Ceria (as well as Pt and Rh) form the basis for the ‘three-way catalyst’ in
widespread use for post-combustion catalytic conversion for automobiles; and Ceria is used in
yttria-stabilized zirconia (YSZ) separators used for high temperature diffusion electrolyte separators
used in chemical processes and fuel cells.
In this workshop and breakout session, we are interested in exploring over-the-horizon new
technical solutions which would provide alternatives or completely new pathways, to the use of
rare-earth materials in catalysis and separator applications.
QUESTIONS:
Are there alternatives to the high use of rare-earths in fluid catalytic cracking? For instance
mesoporous zeolites have been shown to increase both the efficiency and mass transfer rates for
fluid catalytic cracking. What are the limits in controlling size and shape to dramatically increase
unit process efficiency and throughput? What are the ultimate limits and by what quantitative
amount could the process be improved while reducing rare-earth content? In high diffusivity
oxygen separators, what other solutions might provide the combination of oxygen permeability and
mechanical integrity at high temperatures, without rare-earth or critical materials? Finally, low or
reduced dimensional materials such as graphene or nanotubes exhibit interesting catalytic
properties, for instance on the edges and on the surfaces. Can these unique structures be
developed into new catalyst technologies of significant importance for the energy sector?
Four breakout sessions of 90 minute lengths will be held through the workshop, in two periods of
two concurrent sessions. Each participant is has been assigned a recommended breakout session
to attend with an open option to attend either session during the second time period.
Approximately 10 participants have been assigned to each session.
For the breakout session which a participant has been asked to attend, each participant is asked to
prepare an up to 5 minute and 3 PowerPoint slide contribution, intended to spur discussion.
Following two 15 minute stage-setting overview presentations, each participant will be asked for
their contribution, interspersed with technical dialog between participants. All contributions will be
accommodated, to the extent possible.
**** Any presentations created for the workshop should be publicly releasable ****
Private one-on-one sidebar meetings will be held with ARPA-E Program Directors both the night
before, Sunday night, and at the conclusion of the day in 15 minute increments in the hotel
restaurant area. The purpose of sidebar meetings is to share innovative technology concepts with
Program Directors in a more private venue. In order to accommodate travel schedules at the end of
the workshop, participants are encouraged to contact Angela Huffaker to schedule a time in
advanced of the workshop, or sign up at the time of meeting.
** Sunday Dec. 5 @ 6pm – Dinner in hotel with side-bar discussions for those arriving early. **
8:00 AM
Registration / Coffee / Breakfast
8:15 AM
8:30 AM Kick-Off
8:45 AM Overview of Day
9:00 AM US-Japan Rapporteur
9:15 AM US-EU Rapporteur
9:30 AM Current State of the Art for Supply
9:45 AM Current State of the Art for Applications Talk #1
10:00 AM Current State of the Art for Applications Talk #2
10:15 AM Break
10:30 AM SUPPLY Briefing #1 MAGNETS Briefing #1
10:45 AM SUPPLY Briefing #2 MAGNETS Briefing #2
11:00 AM
11:15 AM
SUPPLY MAGNETS
11:30 AM
Brainstorming / Dialog Brainstorming / Dialog
11:45 AM
12:00 PM
12:15 PM Break for Lunch
12:30 PM
Keynote
12:45 PM
1:00 PM Break
1:15 PM CATALYSTS Briefing #1 PHOSPHORS Briefing #1
1:30 PM CATALYSTS Briefing #2 PHOSPHORS Briefing #2
1:45 PM
2:00 PM
CATALYSTS PHOSPHORS
2:15 PM
Brainstorming / Dialog Brainstorming / Dialog
2:30 PM
2:45 PM
3:00 PM
Break
3:15 PM
3:30 PM
3:45 PM
Report Out
4:00 PM
4:15 PM
4:30 PM Conclusion of Day
4:45 PM Adjourn to "No Host" Happy Hour / Dinner (Hotel Bar)
5:00 PM Sidebar Discussions with ARPA-E Program Director (On Request)
MARK JOHNSON
ARPA-E Program Director
Mark.a.Johnson@hq.doe.gov
202-287-6084
ANGELA HUFFAKER
Contractor/Programmatic Support
Angela.Huffaker@hq.doe.gov
202-287-5998