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Taller Masa

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Transport Phenomena - Mass Transfer Exercises

1. A device has been proposed that will serve as a ‘‘blood oxygenator’’ for a heart–lung bypass
machine. In this process, blood (which is mostly water, species B) containing no dissolved
oxygen (O2 species A) enters the top of the chamber and then falls vertically down as a liquid
film of uniform thickness, along a surface designed to appropriately wet blood. Contacting the
liquid surface is a 100% O2 gas phase.
Oxygen is soluble in blood, with the equilibrium
solubility described by Henry’s law, C A*= pA/H, where pA
is the partial pressure of oxygen (atm),His the Henry’s
law constant, and CA is the solubility concentration limit
of oxygen dissolved in blood (mmol/L) at p A. In analyzing
the mass transport of dissolved oxygen into the falling
film, you may assume the following: (1) the process is
dilute with respect to dissolved oxygen in the fluid; (2)
the falling liquid film has a flat velocity profile with
velocity Vmax; (3) the gas space always contains 100%
oxygen; (5) the width of the liquid film, W, is much
larger than the length of the liquid film, L.
a) Simplify the general differential equation for O2
transfer. If your analysis suggests more than one dimension for flux, provide a simplified flux
equation for each coordinate of interest.
b) List boundary conditions associated with the oxygen mass transfer process.

2. A hemispherical droplet of liquid water, lying on a flat surface, evaporates by molecular diffusion
through still air surrounding the droplet. The droplet initially has a radius R. As the liquid water
slowly evaporates, the droplet shrinks slowly with time, but the flux of the water vapor is at a
nominal steady state. The temperature of the droplet and the surrounding still air are kept
constant. The air contains water vapor at an infinitely long distance from the droplet’s surface.
a) After drawing a picture of the physical process, select a coordinate system that will best
describe this diffusion process, list at least five reasonable assumptions for the mass-
transfer aspects of the water-evaporation process and simplify the general differential
equation for mass transfer in terms of the flux NA.
b) What is the simplified differential form of Fick’s equationfor water vapor (species A)?

3. An ethanol/water vapor mixture is being distilled by contact with


an ethanol/water liquid solution. The ethanol is transferred from
the liquid to the vapor phase and the water is transferred in the
opposite direction. The condensation of water vapor provides the
energy for vaporization of ethanol. Both components are diffusing
through a gas film 0.1 mm thick. The temperature is 368 K and the
pressure is 1.013x105 Pa. At these conditions, the pure component
enthalpy of vaporization of the ethanol and water are 840 and 2300
kJ/kg, respectively. Develop the flux equation for ethanol vapor. Then develop the flux equation
assuming that the components have equimolar heats of vaporization.
4. A tank with its top open to the atmosphere contains liquid methanol (MeOH, molecular weight
32g/mol) at the bottom of the tank. The tank is maintained at 30°C. The diameter of the
cylindrical tank is 1.0 m, the total height of the tank is 3.0 m, and the liquid level at the bottom
of the tank is maintained at 0.5 m. The gas space inside the tank is stagnant and the MeOH
vapors are immediately dispersed once they exit the tank. At 30°C, the vapor pressure exerted
by liquid MeOH is 163 mmHg and at 40°C the MeOH vapor pressure is 265 mmHg. We are
concerned that this open tank may be emitting a considerable amount of MeOH vapor.
a) What is the emission rate of MeOH vapor from the tank in units of kg MeOH/day when the
tank is at a temperature of 30°C? State all assumptions and boundary conditions.
b) If the temperature of the tank is raised to 408C, what is the new methanol emission rate?

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