Taller Masa
Taller Masa
Taller Masa
1. A device has been proposed that will serve as a ‘‘blood oxygenator’’ for a heart–lung bypass
machine. In this process, blood (which is mostly water, species B) containing no dissolved
oxygen (O2 species A) enters the top of the chamber and then falls vertically down as a liquid
film of uniform thickness, along a surface designed to appropriately wet blood. Contacting the
liquid surface is a 100% O2 gas phase.
Oxygen is soluble in blood, with the equilibrium
solubility described by Henry’s law, C A*= pA/H, where pA
is the partial pressure of oxygen (atm),His the Henry’s
law constant, and CA is the solubility concentration limit
of oxygen dissolved in blood (mmol/L) at p A. In analyzing
the mass transport of dissolved oxygen into the falling
film, you may assume the following: (1) the process is
dilute with respect to dissolved oxygen in the fluid; (2)
the falling liquid film has a flat velocity profile with
velocity Vmax; (3) the gas space always contains 100%
oxygen; (5) the width of the liquid film, W, is much
larger than the length of the liquid film, L.
a) Simplify the general differential equation for O2
transfer. If your analysis suggests more than one dimension for flux, provide a simplified flux
equation for each coordinate of interest.
b) List boundary conditions associated with the oxygen mass transfer process.
2. A hemispherical droplet of liquid water, lying on a flat surface, evaporates by molecular diffusion
through still air surrounding the droplet. The droplet initially has a radius R. As the liquid water
slowly evaporates, the droplet shrinks slowly with time, but the flux of the water vapor is at a
nominal steady state. The temperature of the droplet and the surrounding still air are kept
constant. The air contains water vapor at an infinitely long distance from the droplet’s surface.
a) After drawing a picture of the physical process, select a coordinate system that will best
describe this diffusion process, list at least five reasonable assumptions for the mass-
transfer aspects of the water-evaporation process and simplify the general differential
equation for mass transfer in terms of the flux NA.
b) What is the simplified differential form of Fick’s equationfor water vapor (species A)?