General Instructions

1. The test is of 3 hours duration and the maximum marks are 300.

2. The question paper consists of 3 Parts (Part I: Mathematics, Part II: Physics, Part III: Chemistry). Each Part has
two sections (Section 1 & Section 2).

3. Section 1 contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.

4. Section 2 contains Five Integer value type questions. Each question has an integer value ranging from
0 – 999.

Marking Scheme
1. Section – 1: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.

2. Section – 2: +4 for correct answer, 0 for all other cases. There is no negative marking.

Syllabus:

Physics : Vectors

Chemistry : Atomic Structure

Mathematics : Quadratic Equation

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SUBJECT I : PHYSICS Suggested Time: 60 Minutes 100 MARKS

This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.

1. A force (3iˆ  4 ˆj ) newton acts on a body and displaces it by (3iˆ  4 ˆj ) metre. The work done by the
force is:
(A) 5J (B) 25 J (C) 10 J (D) 30 J

2. If a unit vector is represented by 0.5iˆ  0.8 ˆj  ckˆ the value of c is:

(A) 1 (B) 0.11 (C) 0.01 (D) 0.39

3. If a vector 2iˆ  3jˆ  8kˆ is perpendicular to the vector 4iˆ  4 ˆj  kˆ , then the value of  is:
1 1
(A) –1 (B) (C)  (D) 1
2 2

4. The angle between the two vector A  3iˆ  4 ˆj  5kˆ and B  3iˆ  4 ˆj  5kˆ is :
(A) 60° (B) 45° (C) 90° (D) 30°

5. Unit vector parallel to the resultant of vectors A  4iˆ  3 ˆj and B  8iˆ  8 ˆj will be:
24iˆ  5 ˆj 12iˆ  5 ˆj 6iˆ  5 ˆj
(A) (B) (C) (D) None of these
13 13 13

6. The component of vector A  2iˆ  3 ˆj along the vector iˆ  ˆj is:

5
(A) (B) 10 2 (C) 5 2 (D) 5
2

7. If A  B  3 A. B, then the value of | A  B | ? is :

1/2
 2 AB 
 
1/2
(A) A2  B 2  AB (B) A B 
2

 3

 A  B A 
1/3
(C) (D) 2
 B 2  3 A.B

8. The value of n so that vectors 2iˆ  3 ˆj  2kˆ,5iˆ  njˆ  kˆ and iˆ  2 ˆj  3kˆ may be coplanar, will be:
(A) 18 (B) 28 (C) 9 (D) 36

9. Three vectors satisfy the relation A. B  0 and A.C  0, then A is parallel to :

(A) C (B) B (C) B C (D) B.C

10. The angle which the vector A  2iˆ  3 ˆj makes with the y-axis, where iˆ and ĵ are unit vectors along
x- and y-axis, respectively, is:
(A) cos1  3 / 5 (B) cos1  2 / 3 (C) tan 1  2 / 3 (D) sin 1  2 / 3

11. The angle between A  B and A  B is:

(A) 0 (B) /4 (C) /2 (D) 

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12. What is the angle between A and B , if A and B are the adjacent sides of a parallelogram drawn
from a common point and the area of the parallelogram is AB/2?
(A) 15° (B) 30° (D) 45° (D) 60°

13. Find the normal reaction applied by block C on block B for the given
system Lying on a stationary horizontal surface. {g  10m/s2}
(A) 20 N
(B) 40 N
(C) 80 N
(D) 60 N

14. The pulley and strings shown in the figure are smooth and of
negligible mass. For the system to remain in equilibrium, the
angle  should be:
(A) 0° (B) 30°
(C) 45° (D) 60°

15. What is the maximum value of the force F such that the block
shown in the figure does not move?
(A) 20 N (B) 10 N
(C) 12 N (D) 15 N

16. In the figure a block of mass 10 kg is in equilibrium. Identify the string in which the tension is zero.

(A) B (B) C
(C) A (D) None of the above

17. A block of mass m is placed at rest on an inclined plane of inclination  to the horizontal. If the
coefficient of friction between the block and the plane is  , then the total force the inclined plane
exerts on the block is:
(A) mg (B)  mg cos  (C) mg sin  (D)  mg tan 

18. A horizontal force of 25N is necessary to just hold a block stationary against a wall. The coefficient of
friction between the block and the wall is 0.4. The weight of the block is:

(A) 2.5 N (B) 20 N (C) 10 N (D) 5N

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19. If A is perpendicular to B , then :

(A) A B  0 (B) A.  A  B   A2

(C) A. B  AB (D) A.  A  B   A2  AB

20. In going from one city to another, a car travel 75 km north, 60 km north-west and 20 km east. The
magnitude of displacement between the two cities is (take 1/ 2 = 0.7)
(A) 170 km (B) 137 km (C) 119 km (D) 140 km

SECTION 2
This section contains 5 Integer value type questions. Each question has an integer value ranging from 0 – 999.

21. The sum of the magnitudes of two forces acting at a point is 16N. The resultant of these forces is
perpendicular to the smaller force and has a magnitude of 8N. If the smaller force is of magnitude x,
then the value of x is (in Newton ) :

22. If | A  B | A  B , then the angle between A and B is (in degree):

23. Two vectors a and b are such that a  b  a  b . What is the angle between a and b (in degree)?

24. Given that A  B  C if A  4 , B  5 and C  61 , the angle between A and B is (in degree):

25. Maximum and minimum values of the resultant of two forces acting at a point are 7 N and 3 N
respectively. The smaller force will be equal to (in Newton):

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SUBJECT II: CHEMISTRY Suggested Time: 45 Minutes 120 MARKS

This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.

1. Which of the following statements does not describe Rutherford's atomic model ?
(A) Atom is mostly made of empty space
(B) The centre of the atom has positively charged nucleus
(C) The size of the nucleus is very small as compared to the size of the atom
(D) The electrons revolve around the nucleus only in certain orbits of fixed energy and radius.

2. To which of the following is the energy of electromagnetic radiation inversely proportional?

I. Frequency II. Wavelength III. Wave number
(A) Only I and III (B) Only II
(C) Only II and III (D) None of the above

3. Which of the following types of waves has the shortest wavelength?

(A) Radio waves (B) UV rays (C) X-rays (D) Microwaves

4. The energy of green light whose frequency is 6 1014 Hz is: (h  6.626 1034 Js)
(A) 39 1019 J (B) 3.9 1019 J (C) 1.104 1048 J (D) 11.04 1048 J

5. The threshold wavelength for photoelectric effect on sodium is 500 nm. Its work function is:
(C  3 108 m/s)
(A) 4 1019 J (B) 1J (C) 2 1019 J (D) 3 1019 J

6. Which of the following is correct? (rn is radius of nth Bohr’s Orbit)

n 2h n 2h 2
(A) rn  (B) rn 
42 KZme2 42 KZme2
nh nh 2
(C) rn  (D) rn 
4 KZme2
2
4KZme2

7. If the velocity of an electron in the first Bohr orbit in H-atom v. What will be the velocity of the
electron in the 2nd orbit of He ? (Atomic No. of He = 2)
(A) v (B) 2v (C) v/2 (D) 4v 2

8. What is the ionization energy of an electron present in the 4th excited state of a H-atom?
(A) – 0.544 eV (B) + 0.85 eV (C) +0.544 eV (D) +1.51 eV

9. The angular momentum of an electron in H-atom (according to Bohr's theory) present in the first
excited state is: (Given h  60626 1034 Js,   3.14)
(A) 2.111034 Jsec (B) 3 1034 Jsec
(C) 20 1034 Jsec (D) 0.5 1034 Jsec

10. Hydrogen atoms are excited to n = 4 energy state. In the spectrum of emitted radiation, ratio of number
of lines in the U.V. and visible regions are respectively:
(A) 3:1 (B) 1:3 (C) 2:3 (D) 3:2

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11. Which of the following is not a drawback of the Bohr's Model?
(A) His postulates combined two different concepts : one from classical physics and second from
modern theory of quantization.
(B) It could explain the spectra of atoms or ions having two or more electrons but not of
monoelectronic species.
(C) It could not provide a satisfactory picture of the chemical bond.
(D) None of the above

12. If the uncertainty in position and momentum are equal, the uncertainty in velocity is :
1 h
(A) h/ (B)
2m 
(C) h / 2 (D) Cannot be determined

13. Two particles of masses 'm' and '2m' have equal K.E. Their de-Broglie's wavelengths are in the ratio
of:
(A) 1:1 (B) 1: 2 (C) 1: 2 (D) 2 :1

14. Which of the following set of quantum numbers is not possible for sodium atom : (Atomic number =
11)
n m ms n m ms
1 1
(A) 2 1 –2  (B) 2 1 –1 
2 2
1
(C) 3 0 0  (D) None of these
2

15. The respective values of orbital angular momentum of an electron in 1s, 2s, 3d and 3p orbital are :
h h h h
(A) 0,0, 6 , 2 (B) 1,1, 4 , 2
2 2 2 2
h h h h
(C) 0,1, 6 , 3 (D) 0,0, 20 , 6
2 2 2 2
16. Which of the following is the correct order of energy of orbitals for H-atom ?
I. 1s < 2p II. 2s = 2p III. 3d < 4s
(A) Only I (B) Only II and III (C) I, II and III (D) None of the above

17. Which of the following is/are correctly matched ?

Orbital Number of radial nodes Number of angular nodes
I 2s 1 0
II 2p 1 1
III 3p 1 2

(A) Only II and III (B) Only I

(C) Only II (D) I, II and III

18. Which of the following is the correct outer most electronic configuration of V 2 ? (Atomic number of
V = 23)
(A) [Ar]3d3 4s2 (B) [Ar]3d1 4s2 (C) [Ar]3d3 4s0 (D) [Ar]3d5 4s0

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19. Find the number of waves made by electron in one complete revolution in third Bohr's orbit.
(A) six (B) Four (C) Three (D) Two
1
20. The maximum number of 3d electrons having spin quantum number s   are :
2
(A) 10 (B) 14
(C) 5 (D) any number from 1 to 10

SECTION 2
This section contains 5 Integer value type questions. Each question has an integer value ranging from 0 – 999.

21. What will be the total number of electrons having n   3 in Cr (Z  24) in its ground state?

22. Number of spectral lines in the visible region lines when an electron returns from 5th orbit to ground
state in H spectrum is x. Find the value of x.

23. The wave number of electromagnetic radiation emitted during the transition of electron in between two
levels of Li 2 ion whose principal quantum number sum is four and difference is 2, is n  R H . What is
the value of n ?

24. What is the degeneracy of fourth principal energy level of H atom?

25. Which Bohr’s orbit of Be3 has the same orbit radius as that of the ground state of hydrogen atom?
(Atomic number of Be = 4)

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SUBJECT III: MATHEMATICS Suggested Time: 75 Minutes 120 MARKS

This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1 1
1. If  and  are the roots of the equation ax2  bx  c  0 , then  is equal to:
a  b a  b
b b ac ac
(A) (B) (C) (D)
ac ac b b

2. The graph of y  ax2  bx  c is as shown. Which one of the following is NOT correct?

(A) a>0 (B) b2  4ac  0 (C) b0 (D) abc  0

3. Let P( x)  x2   2  P  x  P  2. If P( x) assumes both positive and negative values for x  R, then

the range of P is:
(A)  ,2   6,   (B)  2,6 
(C)  , 2 (D)  6, 
2 2
4. If , ,  are roots of equation 111x3  11x  1  0 m then ()2        equals
(A) 2332 (B) 1331 (C) 1210 (D) 2442

5. The zeroes of the quadratic polynomial f  x   2 x 2  3x  k 2  3k  4, k  R lie on both sides of the

origin then the set of the values of k is:
(A)  (B) (-4, 1) (C) (–1,4) (D)  , 4  1,  

6. If ,  are the roots of x2  p( x  1)  c  0, c  1, then the value of (  1)(  1) is equal to:

(A) 1 c (B) p+c (C) 1+c (D) 1 – 2p

7. If ,  are roots of the equation x2  ax  2  0 such that 65  32 , then the value of ' a ' is:
(A) –2 (B) 2 (C) –3 (D) 3

8. Let f  x   ax 2  bx  c ( x  R, a  0) such that f  2  is minimum value of f  x  , then :

(A) f  2  f 1  f  3 (B) f  2   f  0   f  5

(C) f  1  f  0  f 1 (D) f  2  f  0  f  3

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9. If roots of the equation lx2  mx  n  0 are (2) and      , roots of the equation px2  qx  r  0
D1
are (2) and      and D1 and D2 are the respective discriminants, then is equal to (where
D2
  ) :
2 2
lmn l  m n
2
(A) (B)   (C)   (D)  
pqr  p q r

10. For what value of ‘m’ roots of equation x2  x  m  0 are not real-
1   1  1 1
(A)  ,  (B)  ,  (C)  ,  (D) None of these
4   4  4 4

11. The expression y  ax2  bx  c has always the same sign as c if-
(A) 4ac  b2 (B) 4ac  b2 (C) ac  b2 (D) ac  b2

12. If c 2  4d and the two equations x2  ax  b  0 and x2  cx  d  0 have one common root, then the
value of 2  b  d  is equal to:
a
(A) (B) ac (C) 2ac (D) ac
c

 n
13. If the vertex of parabola y  2 x 2  4 x  6 is (m, n) , then the parabola whose vertex is  2m,  is:
 2
(A) y  x2  4 x  8 (B) y  x2  4x  6
(C) y  2 x 2  8x  6 (D) y  2 x2  8x  8

14. If m and n are real and different satisfying the relation m2  4m  4 and n2  4n  4 , then
(m2  n2  4mn) is equal to:
(A) 2 (B) 4 (C) 8 (D) 16

15. The value of ‘a’ for which one root of the equation (a2  5a  3) x2  (3a  1) x  2 is twice as large as
the other is-
1 2 2 1
(A)  (B) (C)  (D)
3 3 3 3

16. Two student attempted to solve a quadratic equation x2  bx  c  0. Although both student did work
correctly. One miscopied the middle term and obtained the solution set {2, 3}. While the other
miscopied the constant term and obtained solution set {2, 5} the correct solution set of quadratic
equation is-
(A) {1, 6} (B) {2, 5} (C) {3, 6} (D) {1, 4}

 1  1
17. If ,  are roots of x2  2 x  3  0 then equation whose roots are , will be:
 1  1
(A) 3x2  2 x  1  0 (B) 3x2  2 x  1  0 (C) 3x2  2 x  1  0 (D) x 2  3x  1  0

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The number of integral value of x satisfying the inequality 5x  1   x  1  7 x  3, is/are :

2
18.
(A) 0 (B) 1 (C) 2 (D) 3

19. If x2  11x  a  0, x2  14 x  2a  0 have one common root then sum of possible value of a is :
(A) 24 (B) 1 (C) 24 (D) 25

20. The graph of quadratic polynomial f  x   ax2  bx  c is shown below (|  ||  |)

which of the following is INCORRECT?

c
(A)  1 (B)   2
a
(C) f  x   0  x   0,   (D) abc  0

SECTION 2
This section contains 5 Integer value type questions. Each question has an integer value ranging from 0 – 999.

21. If x2  bx  b is a factor of x3  2 x2  2 x  c  c  0  , then the value b  c is equal to

2
22. If ,  are roots of the equation (5  2) x2  (4  5) x  8  2 5  0 then is equal to-
1 1

 

23.  and  are roots of the equation 2 x2  35x  2  0 . Find the value of  2  353  2  353 .
x 8 n
24. The number of all values of n, (where n is a whole number) for which the equation  has no
n  10 x
real solution for x.

x2  2x  2
25. For real x, then integer which does not lie in the range of f  x  , where f  x   .
2x  2

   End of MOT-1| JEE 2022   

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