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    ln 520. torr 760. torr: P P ΔH R T T or ln P P ΔH R T T

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    samira
    1. By calculating the vapor pressure of water at 89°C using its heat of vaporization, the summary found the temperature corresponds to a vapor pressure of 520 torr. 2. Calculating the vapor pressure of water at 140°C using its heat of vaporization, the summary found the vapor pressure is 1.7 atm. 3. Calculating the heat of vaporization of an unknown substance using its vapor pressure curve, the summary determined the heat of vaporization is 28.3 kJ/mol.

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    ln 520. torr 760. torr: P P ΔH R T T or ln P P ΔH R T T

    Uploaded by

    samira
    17 views2 pages
    1. By calculating the vapor pressure of water at 89°C using its heat of vaporization, the summary found the temperature corresponds to a vapor pressure of 520 torr. 2. Calculating the vapor pressure of water at 140°C using its heat of vaporization, the summary found the vapor pressure is 1.7 atm. 3. Calculating the heat of vaporization of an unknown substance using its vapor pressure curve, the summary determined the heat of vaporization is 28.3 kJ/mol.

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    hw_6c_answers.docx

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    1. By calculating the vapor pressure of water at 89°C using its heat of vaporization, the summary found the temperature corresponds to a vapor pressure of 520 torr. 2. Calculating the vapor pressure of water at 140°C using its heat of vaporization, the summary found the vapor pressure is 1.7 atm. 3. Calculating the heat of vaporization of an unknown substance using its vapor pressure curve, the summary determined the heat of vaporization is 28.3 kJ/mol.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    17 views2 pages

    ln 520. torr 760. torr: P P ΔH R T T or ln P P ΔH R T T

    Uploaded by

    samira
    1. By calculating the vapor pressure of water at 89°C using its heat of vaporization, the summary found the temperature corresponds to a vapor pressure of 520 torr. 2. Calculating the vapor pressure of water at 140°C using its heat of vaporization, the summary found the vapor pressure is 1.7 atm. 3. Calculating the heat of vaporization of an unknown substance using its vapor pressure curve, the summary determined the heat of vaporization is 28.3 kJ/mol.

    Copyright:

    © All Rights Reserved
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    Download as docx, pdf, or txt
    of 2

    HW 6C Answers

    1. At 100.°C (373 K), the vapor pressure of H 2O is 1.00 atm = 760. torr. For water, ΔH vap = 40.7 kJ/mol.

    P1 ΔH vap 1 1 P ΔH vap 1 1
    ln
    ( ) P2
    =
    R T2 T1
    −
    (
    or ln 2 =
    P1 ) ( )
    R T1 T 2
    −
    ( )
    3
    520 . torr 40 . 7 × 10 J/mol 1 1 1 1
    ln ( 760 . torr ) =
    (
    8 .3145 J/K¿ mol 373 K
    −
    T2
    ,
    ) −7.75 × 105 =
    ( 373 K
    −
    T2 )
    1 1 1
    ,
    −7.75 × 105 = 2.68 × 103 −
    T2 T2 = 2.76 × 103, T2 = 2.76 × 10
    −3
    = 362 K or 89°C

    2. At 100.°C (373 K), the vapor pressure of H 2O is 1.00 atm. For water, ΔHvap = 40.7 kJ/mol.

    P1 ΔH vap 1 1 P2 ΔH vap 1 1
    ln
    ( ) P2
    =
    R T2
    −
    (
    T1 ) or ln
    ( )
    P1
    =
    R T1
    −
    T2 ( )
    P2 40. 7 × 103 J/mol 1 1
    ln (
    1 .00 atm
    = ) −
    8.3145 J/K¿mol 373 K 388 K
    , ( ) ln P2 = 0.51, P2 = e0.51 = 1.7 atm
    3
    3 .50 40 . 7 × 10 J/mol 1 1 1 1
    ln ( ) 1 .00
    =
    8 . 3145 J/K ¿mol 373 K
    −
    (T2
    , 2. 56 × 10−4 =
    )
    373 K
    −
    T2 ( )
    1 1 1
    ,
    2.56 × 104 = 2.68 × 103 
    T 2 T 2 = 2.42 × 103, T = 2.42 × 10−3 = 413 K or 140.°C
    2

    P ΔHvap 1 1 760 torr ΔHvap 1 1


    3.
    P2( )
    ln 1 =
    R T2 T1
    − , ln
    ( 400. torr
    =
    ) ( )
    8 . 3145 J/K ¿ mol 291 .1 K
    −
    307 . 8 K ( )
    Solving: DHvap = 2.83 × 104 J/mol = 28.3 kJ/mol

    4. a. The plateau at the lowest temperature signifies the melting/freezing of the substance.
    Hence the freezing point is 20C.
    b. The higher temperature plateau signifies the boiling/condensation of the substance. The temperature of
    this plateau is 120C.
    c. X(s)  X(l) H = Hfusion; X(l)  X(g) H = Hvaporization
    The heat of fusion and the heat of vaporization terms refer to enthalpy changes for the specific phase
    changes illustrated in the equations above. In a heating curve, energy is applied at a steady rate. So the
    longer, higher temperature plateau has a larger enthalpy change associated with it as compared to the
    shorter plateau. The higher temperature plateau occurs when a liquid is converting to a gas, so the heat of
    vaporization is greater than the heat of fusion. This is always the case because significantly more
    intermolecular forces are broken when a substance boils than when a substance melts.
    5. A: solid B: liquid C: vapor

    D: solid + vapor E: solid + liquid + vapor


    F: liquid + vapor G: liquid + vapor H: vapor
    triple point: E critical point: G

    Normal freezing point: Temperature at which solid-liquid line is at 1.0 atm (see following plot).

    Normal boiling point: Temperature at which liquid-vapor line is at 1.0 atm (see following plot ).

    1.0
    atm

    nfp nbp

    Because the solid-liquid line equilibrium has a positive slope, the solid phase is denser than the liquid
    phase.

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