CA 0

K 0.1
Cao 0.5
V 2
F 1
delta t 0.2

Analytical Numerical
No t Ca (t) Ca(t+1) No t
1 0 0 0 1 0
2 0.2 0.04727562 0.05 2 0.2
3 0.4 0.08918513 0.09477639 3 0.4
4 0.6 0.12633763 0.1347152 4 0.6
5 0.8 0.15927305 0.17025478 5 0.8
6 1 0.18847009 0.20182429 6 1
7 1.2 0.21435305 0.22982847 7 1.2
8 1.4 0.23729812 0.25464201 8 1.4
9 1.6 0.25763877 0.27660786 9 1.6
10 1.8 0.27567062 0.29603752 10 1.8
11 2 0.29165572 0.31321232 11 2
12 2.2 0.30582641 0.32838528 12 2.2
13 2.4 0.31838862 0.34178314 13 2.4
14 2.6 0.32952494 0.35360854 14 2.6
15 2.8 0.33939721 0.36404222 15 2.8
16 3 0.34814891 0.37324504 16 3
17 3.2 0.35590723 0.38135994 17 3.2
18 3.4 0.36278492 0.38851382 18 3.4
19 3.6 0.36888196 0.39481916 19 3.6
20 3.8 0.37428693 0.40037558 20 3.8
21 4 0.37907841 0.40527125 21 4
22 4.2 0.38332602 0.40958414 22 4.2
23 4.4 0.38709149 0.41338315 23 4.4
24 4.6 0.39042956 0.41672915 24 4.6
25 4.8 0.39338873 0.41967588 25 4.8
26 5 0.39601202 0.42227077 26 5
27 5.2 0.39833755 0.42455566 27 5.2
28 5.4 0.40039911 0.42656746 28 5.4
29 5.6 0.40222667 0.42833871 29 5.6
30 5.8 0.40384679 0.42989809 30 5.8
31 6 0.40528302 0.43127089 31 6
32 6.2 0.40655623 0.43247938 32 6.2
33 6.4 0.40768491 0.4335432 33 6.4
34 6.6 0.40868549 0.43447964 34 6.6
35 6.8 0.40957249 0.43530392 35 6.8
36 7 0.41035881 0.43602947 36 7
37 7.2 0.41105587 0.4366681 37 7.2
38 7.4 0.41167382 0.43723021 38 7.4
39 7.6 0.41222163 0.43772496 39 7.6
40 7.8 0.41270725 0.43816042 40 7.8
41 8 0.41313775 0.43854369 41 8
42 8.2 0.41351939 0.85206308 42 8.2
43 8.4 0.41385771 1.26592079 43 8.4
44 8.6 0.41415763 1.68007842 44 8.6
45 8.8 0.4144235 2.09450192 45 8.8
46 9 0.4146592 2.50916112 46 9
47 9.2 0.41486814 2.92402927 47 9.2
48 9.4 0.41505337 3.33908264 48 9.4
49 9.6 0.41521757 3.75430021 49 9.6
50 9.8 0.41536314 4.16966335 50 9.8
51 10 0.41549218 4.58515553 51 10
52 10.2 0.41560657 5.0007621 52 10.2
53 10.4 0.41570798 5.41647009 53 10.4
54 10.6 0.41579788 5.83226797 54 10.6
Numerical
F/V*Cao-F/V*Ca Ca(t+1) 0.5
0 0 0.45
0.05 0.05
0.4
0.04477639 0.09477639
0.35
0.03993881 0.1347152
Concentration

0.3
0.03553957 0.17025478
0.25
0.03156951 0.20182429
0.2
0.02800419 0.22982847
0.15
0.02481354 0.25464201
0.1
0.02196585 0.27660786
0.05 Analytical Numerical
0.01942966 0.29603752
0
0.01717481 0.31321232 0 1 2 3 4 5 6 7 8 9 10
0.01517296 0.32838528 Time
0.01339785 0.34178314
0.01182541 0.35360854
0.01043368 0.36404222
0.00920281 0.37324504
0.00811491 0.38135994
0.00715388 0.38851382
0.00630534 0.39481916
0.00555642 0.40037558
0.00489567 0.40527125
0.00431289 0.40958414
0.00379901 0.41338315
0.003346 0.41672915
0.00294673 0.41967588
0.00259489 0.42227077
0.00228489 0.42455566
0.0020118 0.42656746
0.00177125 0.42833871
0.00155938 0.42989809
0.0013728 0.43127089
0.00120849 0.43247938
0.00106382 0.4335432
0.00093644 0.43447964
0.00082428 0.43530392
0.00072555 0.43602947
0.00063863 0.4366681
0.00056211 0.43723021
0.00049475 0.43772496
0.00043546 0.43816042
0.00038327 0.43854369
0.00033733 0.43888101
0.00029689 0.43917791
0.0002613 0.43943921
0.00022998 0.43966918
0.0002024 0.43987159
0.00017814 0.44004972
0.00015678 0.4402065
0.00013798 0.44034448
0.00012144 0.44046592
0.00010687 0.44057279
9.40589E-05 0.44066685
8.278E-05 0.44074963
7.28534E-05 0.44082249
l Numerical

8 9 10
 CA 0 ∆Cao 0.5
K 0.1 Cao 0.5
V 2 New Cao 1
F 1 delta t 0.5

Analytical Numerical
No t Ca (t) Ca(t+1) No t
1 0 0 0 1 0
2 0.5 0.10832074 0.25 2 0.5
3 1 0.18847009 0.43125 3 1
4 1.5 0.24777469 0.55927749 4 1.5
5 2 0.29165572 0.64854537 5 2
6 2.5 0.32412445 0.7102946 6 2.5
7 3 0.34814891 0.7527895 7 3
8 3.5 0.36592524 0.78193482 8 3.5
9 4 0.37907841 0.80187901 9 4
10 4.5 0.38881078 0.81550605 10 4.5
11 5 0.39601202 0.82480725 11 5
12 5.5 0.40134041 0.83115139 12 5.5
13 6 0.40528302 0.83547654 13 6
14 6.5 0.40820026 0.83842429 14 6.5
15 7 0.41035881 0.84043284 15 7
16 7.5 0.41195597 0.84180124 16 7.5
17 8 0.41313775 0.84273341 17 8
18 8.5 0.41401219 0.84336838 18 8.5
19 9 0.4146592 0.84380088 19 9
20 9.5 0.41513794 0.84409546 20 9.5
21 10 0.41549218 0.8442961 21 10
22 10.5 0.41575429 0.84443275 22 10.5
23 11 0.41594823 0.84452583 23 11
24 11.5 0.41609173 0.84458922 24 11.5
25 12 0.41619791 0.84463239 25 12
26 12.5 0.41627648 0.84466179 26 12.5
27 13 0.41633461 0.84468182 27 13
28 13.5 0.41637762 0.84469546 28 13.5
29 14 0.41640945 0.84470475 29 14
30 14.5 0.416433 0.84471108 30 14.5
31 15 0.41645042 0.84471538 31 15
32 15.5 0.41646332 0.84471832 32 15.5
33 16 0.41647286 0.84472032 33 16
34 16.5 0.41647992 0.84472168 34 16.5
35 17 0.41648514 0.84472261 35 17
36 17.5 0.416489 0.84472324 36 17.5
37 18 0.41649186 0.84472367 37 18
38 18.5 0.41649398 0.84472396 38 18.5
39 19 0.41649555 0.84472416 39 19
40 19.5 0.4164967 0.8447243 40 19.5
41 20 0.41649756 0.84472439 41 20
42 20.5 0.4164982 1.26122258 42 20.5
43 21 0.41649866 1.67772125 43 21
44 21.5 0.41649901 2.09422026 44 21.5
45 22 0.41649927 2.51071953 45 22
46 22.5 0.41649946 2.92721899 46 22.5
47 23 0.4164996 3.34371859 47 23
48 23.5 0.4164997 3.76021829 48 23.5
49 24 0.41649978 4.17671807 49 24
50 24.5 0.41649984 4.59321791 50 24.5
51 25 0.41649988 5.00971779 51 25
52 25.5 0.41649991 5.4262177 52 25.5
53 26 0.41649993 5.84271764 53 26
54 26.5 0.41649995 6.25921759 54 26.5
Numerical
F/V*Cao-F/V*Ca Ca(t+1) 0.9
0 0
0.8
0.25 0.25
0.7
0.18125 0.43125
0.12802749 0.55927749 0.6
Concentration

0.08926788 0.64854537 0.5

0.06174923 0.7102946 0.4
0.0424949 0.7527895 0.3
0.02914532 0.78193482 0.2
0.01994419 0.80187901
0.1 Analytical Numerical
0.01362704 0.81550605
0
0.0093012 0.82480725 0 1 2 3 4 5 6 7 8 9 10
0.00634415 0.83115139 Time
0.00432515 0.83547654
0.00294775 0.83842429
0.00200855 0.84043284
0.0013684 0.84180124
0.00093217 0.84273341
0.00063497 0.84336838
0.0004325 0.84380088
0.00029458 0.84409546
0.00020064 0.8442961
0.00013665 0.84443275
9.30725E-05 0.84452583
6.33896E-05 0.84458922
4.31731E-05 0.84463239
2.9404E-05 0.84466179
2.00263E-05 0.84468182
1.36393E-05 0.84469546
9.28931E-06 0.84470475
6.32666E-06 0.84471108
4.30889E-06 0.84471538
2.93465E-06 0.84471832
1.9987E-06 0.84472032
1.36125E-06 0.84472168
9.27106E-07 0.84472261
6.31422E-07 0.84472324
4.30042E-07 0.84472367
2.92888E-07 0.84472396
1.99477E-07 0.84472416
1.35857E-07 0.8447243
9.25281E-08 0.84472439
6.30179E-08 0.84472445
4.29195E-08 0.84472449
2.92311E-08 0.84472452
1.99084E-08 0.84472454
1.3559E-08 0.84472456
9.23459E-09 0.84472457
6.28939E-09 0.84472457
4.2835E-09 0.84472458
2.91736E-09 0.84472458
1.98692E-09 0.84472458
1.35323E-09 0.84472458
9.21641E-10 0.84472458
6.277E-10 0.84472458
l Numerical

8 9 10
 CA 0 ∆Cao 0.4
K 0.1 Cao 0.5
V 2 New Cao 0.9
F 1 delta t 0.5

Analytical Numerical
No t Ca (t) Ca(t+1) No t
1 0 0 0 1 0
2 0.5 0.10832074 0.225 2 0.5
3 1 0.18847009 0.38841366 3 1
4 1.5 0.24777469 0.50420672 4 1.5
5 2 0.29165572 0.58525381 5 2
6 2.5 0.32412445 0.64155385 6 2.5
7 3 0.34814891 0.6804721 7 3
8 3.5 0.36592524 0.70728775 8 3.5
9 4 0.37907841 0.72572422 9 4
10 4.5 0.38881078 0.73838114 10 4.5
11 5 0.39601202 0.74706164 11 5
12 5.5 0.40134041 0.75301094 12 5.5
13 6 0.40528302 0.75708649 13 6
14 6.5 0.40820026 0.75987755 14 6.5
15 7 0.41035881 0.76178854 15 7
16 7.5 0.41195597 0.76309676 16 7.5
17 8 0.41313775 0.76399226 17 8
18 8.5 0.41401219 0.76460519 18 8.5
19 9 0.4146592 0.7650247 19 9
20 9.5 0.41513794 0.76531182 20 9.5
21 10 0.41549218 0.76550832 21 10
22 10.5 0.41575429 0.7656428 22 10.5
23 11 0.41594823 0.76573484 23 11
24 11.5 0.41609173 0.76579783 24 11.5
25 12 0.41619791 0.76584093 25 12
26 12.5 0.41627648 0.76587044 26 12.5
27 13 0.41633461 0.76589063 27 13
28 13.5 0.41637762 0.76590444 28 13.5
29 14 0.41640945 0.7659139 29 14
30 14.5 0.416433 0.76592037 30 14.5
31 15 0.41645042 0.7659248 31 15
32 15.5 0.41646332 0.76592783 32 15.5
33 16 0.41647286 0.7659299 33 16
34 16.5 0.41647992 0.76593132 34 16.5
35 17 0.41648514 0.76593229 35 17
36 17.5 0.416489 0.76593296 36 17.5
37 18 0.41649186 0.76593341 37 18
38 18.5 0.41649398 0.76593372 38 18.5
39 19 0.41649555 0.76593394 39 19
40 19.5 0.4164967 0.76593408 40 19.5
41 20 0.41649756 0.76593418 41 20
42 20.5 0.4164982 1.18243238 42 20.5
43 21 0.41649866 1.59893104 43 21
44 21.5 0.41649901 2.01543006 44 21.5
45 22 0.41649927 2.43192932 45 22
46 22.5 0.41649946 2.84842878 46 22.5
47 23 0.4164996 3.26492838 47 23
48 23.5 0.4164997 3.68142809 48 23.5
49 24 0.41649978 4.09792787 49 24
50 24.5 0.41649984 4.51442771 50 24.5
51 25 0.41649988 4.93092759 51 25
52 25.5 0.41649991 5.3474275 52 25.5
53 26 0.41649993 5.76392743 53 26
54 26.5 0.41649995 6.18042738 54 26.5
Numerical
F/V*Cao-F/V*Ca Ca(t+1) 0.9
0 0
0.8
0.225 0.225
0.7
0.16341366 0.38841366
0.11579306 0.50420672 0.6
Concentration

0.08104709 0.58525381 0.5

0.05630004 0.64155385 0.4
0.03891825 0.6804721 0.3
0.02681565 0.70728775 0.2
0.01843647 0.72572422
0.1 Analytical Numerical
0.01265692 0.73838114
0
0.0086805 0.74706164 0 1 2 3 4 5 6 7 8 9 10
0.0059493 0.75301094 Time
0.00407555 0.75708649
0.00279106 0.75987755
0.00191099 0.76178854
0.00130822 0.76309676
0.00089549 0.76399226
0.00061293 0.76460519
0.00041951 0.7650247
0.00028712 0.76531182
0.0001965 0.76550832
0.00013448 0.7656428
9.20369E-05 0.76573484
6.29875E-05 0.76579783
4.31067E-05 0.76584093
2.95008E-05 0.76587044
2.01893E-05 0.76589063
1.38168E-05 0.76590444
9.45574E-06 0.7659139
6.47116E-06 0.76592037
4.42862E-06 0.7659248
3.03078E-06 0.76592783
2.07415E-06 0.7659299
1.41947E-06 0.76593132
9.71431E-07 0.76593229
6.6481E-07 0.76593296
4.54971E-07 0.76593341
3.11365E-07 0.76593372
2.13086E-07 0.76593394
1.45828E-07 0.76593408
9.9799E-08 0.76593418
6.82986E-08 0.76593425
4.6741E-08 0.7659343
3.19877E-08 0.76593433
2.18912E-08 0.76593435
1.49815E-08 0.76593437
1.02528E-08 0.76593438
7.0166E-09 0.76593438
4.80189E-09 0.76593439
3.28623E-09 0.76593439
2.24897E-09 0.76593439
1.53911E-09 0.7659344
1.05331E-09 0.7659344
7.20843E-10 0.7659344
l Numerical

8 9 10