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Boost Your Sustainability Profile: Sovermol - Natural Oil-Based, Performance Driven Polyols

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Boost your

sustainability profile
Sovermol ® – natural oil-based,
performance driven polyols
2 Boost your sustainability profile
Sovermol® – natural oil-based, performance driven polyols

Performance-driven polyols for


2K PU systems based on natural oil
Sovermol® by BASF

BASF’s Sovermol® range of green polyols has been specially designed


for use in coating, adhesive and putty applications. These natural oil-based
polyols help you to comply with environmental standards while meeting
even the toughest production regulations. What’s more, improving the
environmental profile of your processes will make you more attractive
to both existing and new customers. Sovermol® is part of our 2K PU offering
containing the crosslinker (Basonat® − NCO) and acrylic polyol (Joncryl®).

Natural-oil polyols are polyfunctional alcohols based on exhibit excellent hydrolysis resistance, chemical resistance
renewable raw materials like rapeseed oil, castor oil, soybean and UV resistance, as well as low viscosity. This latter
oil and palm kernel oil. The practical advantages of these characteristic is especially important in spraying applications.
products include good adhesion, excellent workability and The modular system of our Sovermol® product group includes
good weathering properties. They can also be used on a other important features, such as being 100 % solid, good
wide variety of different substrates. gloss development and good pigment wetting characteristics.
The latest generation of BASF Sovermol® products combines
Polyols based on natural oils have a very pronounced sustainability with performance, thus meeting the requirements
hydrophobic character. For this reason, oleochemical of today’s producers and consumers. Hardness can be
polyols create significantly less carbon dioxide as a result regulated without using plasticizers and they feature excellent
of the side reaction of the isocyanate. In high humidity UV stability and long-term weathering performance. Some
and high temperature conditions, these special polyols are markets where Sovermol® is being used include concrete
able to create networks without bubbles or foam formation. flooring, wind blades, pipeline coatings, protective coatings
Besides good hydrophobicity, polyols based on oleochemicals and adhesives.

Sovermol® – a chemical ”hybrid“ combining


Reaction scheme two singular good properties in one molecule

Polyether

hydrolysis stability Sovermol®


polyether/-ester

hydrophobic properties
hydrolysis stability

hydrophobic properties

Natural oil-based polyol + isocyanate hydrolysis stability


= high performance polyurethanes

hydrophobic properties

Polyester
Boost your sustainability profile
Sovermol® – natural oil-based, performance driven polyols 3

Natural oil-based polyols


for polyurethane manufacture
Sovermol® by BASF

Renewable Medium Medium


Medium
Product raw material Type Functionality OH-equivalent viscosity Applications / properties
OH-value
content weight mPa·s (25°C)

co-polyol for floorings (combined


with Sovermol® 750 UV stable),
adhesives and casting materials
Sovermol® 45 branched  improvement of glass transition
4.0 570 98 3,000
polyether temperature Tg
 high cross-linking density
 hydrophilic
 improvement of chemical resistance

co-polyol for floorings (combined


with Sovermol 750 UV stable),
adhesives and casting materials
 improve glass transition
branched temperature Tg
Sovermol® 100 3.0 880 64 6,000  high cross-linking density, hydrophilic
polyether
 improvement of chemical resistance
 drinking and potable water
application possible upon product
specific confirmation according to
local legislation

 drinking and potable water


application possible upon product
branched specific confirmation according to
Sovermol® 320  polyether 2.8 310 180 1,000
local legislation
 high shore D hardness (D~80)
 good mechanical properties

polyol for solvent-based


dimer diol/ printing inks
Sovermol® 650 NS  trimer triol 2.2 190 295 3,900
 high saponification stability
 tear resistance

polyol for UV stable and weathering


resistant coatings and floorings
 high shore D hardness (D~80)
branched 1,100  hydrophobic
Sovermol® 750  polyether/-ester 3.0 315 178 (20 °C)  high saponification stability
 excellent chemical resistance
 hydrolysis stable
 high Tg-polyol

polyol for UV stable and weathering


resistant coatings and floorings
 high shore D hardness (D~90)
branched  hydrophobic
Sovermol® 760  polyether/-ester 3.5 390 145 2,300  high saponification stability
 excellent chemical resistance
 hydrolysis stable
 extremely high Tg-polyol
 high heat resistance

 80 - 100 %  65 - 80 %  50 - 65 %  30 - 50 %


4 Boost your sustainability profile
Sovermol® – natural oil-based, performance driven polyols

Natural oil-based polyols


for polyurethane manufacture
Sovermol® by BASF

Renewable Medium Medium


Medium
Product raw material Type Functionality OH-equivalent viscosity Applications / properties
OH-value
content weight mPa·s (25°C)

universal polyol
branched
Sovermol® 805  polyether/-ester 3.5 170 330 3,500  excellent impact resistance
 shore D hardness (D~70)

polyol for encapsulation systems


branched  hydrolysis stable
Sovermol® 810  polyether/-ester 3.3 230 244 900  hydrophobic
 low viscosity
 high filler content possible

low viscosity universal polyol


 binder for pigment pastes
branched  crack-bridging floorings
Sovermol® 815  polyether/-ester 3.5 215 260 1,600
 good chemical resistance
 hydrophobic
 good elastic memory effect
low viscosity universal polyol
 extremely hydrophobic
fatty-chemistry  good self-leveling properties
Sovermol® 818  polyester 2.6 236 238 750
 excellent flexibility at temperatures
below 0 °C
 good bonding properties
low viscosity universal polyol
 extremely hydrophobic
 good self-leveling properties
fatty-chemistry  good bonding properties
Sovermol® 819  polyester 2.6 240 234 850
 drinking and potable water
application possible upon product
specific confirmation according to
local legislation

 gel time prolonger


 reactive diluent
 hydrophobic
530
Sovermol® 860  aliphatic polyol 2.5 210 270 (20 °C)  good adhesive properties on
metal surfaces
 contains epoxy groups
(Ep-O = 0.3 to 1.4 %)

 crack-bridging coatings
aliphatic dimer  good saponification stability
Sovermol® 908  alcohol 2.0 206 272 2,300
 hard elastic performance
 hydrophobic

polycarbonat
Sovermol® 920 diol 2.0 55 1,020 9,500  for TPU applications

 hydrophobic
 plasticizer for polyol
slightly  soft elastic performance
800
Sovermol® 1005  branched 2.2 122 460 (20 °C)  drinking and potable water
aliphatic diol application possible upon product
specific confirmation according to
local legislation

co-polyol for performance driven


PU coatings (e.g. sports floor),
Sovermol 1006
®
polyester diol 2.0 60 935 8,000 elastomers and sealants
(20 °C)
 good hydrolysis stability
 soft elastic performance
Boost your sustainability profile
Sovermol® – natural oil-based, performance driven polyols 5

Renewable Medium Medium


Medium
Product raw material Type Functionality OH-equivalent viscosity Applications / properties
OH-value
content weight mPa·s (25°C)

 soft elastic performance


 drinking and potable water
Sovermol® 1014  aliphatic triol 2.5 160 350 700 application possible upon product
specific confirmation according to
local legislation

co-polyol, in combination with


other Sovermol® grades like 805
Sovermol 1052
®
linear polyether 2 55 1,020 325 and 815 remarkably flexible
coatings can be achieved
 hydrophilic

non reactive diluent


fatty acid ester  non VOC acc. to 2004/42/EU
Ep-content 15
Sovermol 1055
®
 with epoxy - 4.6 - 5.0 % EEW = 333 (20 °C)  UV-stable performance
groups  plasticizer for polyols and
epoxy-resins

non-reactive diluent
5  non VOC acc. to 2004/42/EU
Sovermol® 1058  fatty acid ester - - - (20 °C)  hydrophobic
 plasticizer for polyols

universal polyol
branched
Sovermol® 1083  polyether/-ester 3.3 170 330 2,100  excellent impact resistance
 shore D hardness (D~60)

high performance polyol for


coatings, puttys and adhesives
branched  low viscosity
Sovermol® 1092  polyether/-ester 2.8 283 198 800  extremely hydrophobic
 hardness similar to epoxy systems
 hard elastic performance
 good self-leveling properties

branched  hardness similar to epoxy systems


Sovermol® 1093  polyether/-ester 2.8 229 245 2,500
 hard elastic performance

universal co-polyol
 gel time prolonger
slightly branched 400  reactive diluent
Sovermol® 1102  polyether/-ester 2.1 230 245 (20 °C)  hydrophobic
 UV-stable
 soft elastic performance

high reactive polyol


branched  high shore D hardness (D~80)
Sovermol® 1106 - 245 229 115  extremely short gel time
polyether/-ester
 usable as internal catalyst in
PU systems

universal polyol for adhesives


branched  gel time prolonger
Sovermol 1111
®
 polyether/-ester 3.0 160 350 500  soft flexible performance
 low viscosity
 hydrophobic

universal polyol for adhesives


fatty chemistry  gel time prolonger
Sovermol® 1140  polyester 2.7 210 267 1,000
 hard flexible performance
 hydrophobic

 80 - 100 %  65 - 80 %  50 - 65 %  30 - 50 %


6 Boost your sustainability profile
Sovermol® – natural oil-based, performance driven polyols

Properties of Sovermol®
PUR raw materials
after stoichiometric cross-linking with MDI polymer
(NCO = 31 %, Functionality = 2,4)

Gel time ASTM D 2471-88


Product 1st day 2nd day 14th day 28th day
(30g mass) (h:min)

shore hardness A/D (EN ISO 868)

Sovermol® 100 00:20 100 / 77 100 / 77 100 / 80 100 / 80

Sovermol® 320 00:46 71 / 22 98 / 64 100 / 81 100 / 83

Sovermol® 650 NS 00:10 85 / 39 90 / 48 94 / 51 94 / 54

Sovermol® 750 00:38 100 / 74 100 / 80 100 / 86 100 / 87

Sovermol® 760 00:19 100 / 86 100 / 88 100 / 90 100 / 90

Sovermol® 805 00:47 75 / 30 86 / 42 98 / 64 98 / 69

Sovermol® 810 00:55 77 / 32 86 / 42 98 / 66 98 / 67

Sovermol® 815 01:00 83 / 39 92 / 52 99 / 75 99 / 77

Sovermol® 818 01:24 60 / 18 78 / 31 94 / 50 96 / 60

Sovermol® 819 00:59 69 / 24 85 / 39 96 / 62 97 / 64

Sovermol® 860 06:10 n.m. n.m. 85 / n.m. 97 / 62

Sovermol® 908 00:12 66 / 24 78 / 34 84 / 40 84 / 42

Sovermol® 920 06:36 n.m. 9 / n.m. 41 / n.m. 55 / 20

Sovermol® 1005 01:47 n.m. 4 / n.m. 22 / n.m. 38 / 10

Sovermol® 1014 01:35 50 / 17 62 / 24 67 / 26 67 / 26

Sovermol® 1052 n.m. n.m. n.m. 2 / n.m. 3 / n.m.

Sovermol® 1083 01:00 65 / 23 74 / 32 92 / 52 94 / 57

Sovermol® 1092 01:09 90 / 45 97 / 65 100 / 84 100 / 86

Sovermol® 1093 00:59 96 / 60 n.m. 100 / 87 100 / 87

Sovermol® 1102 03:15 n.m. 39 / 10 89 / 45 94 / 56

Sovermol® 1106 00:03 100 / 82 100 / 82 100 / 82 100 / 84

Sovermol® 1111 07:57 52 / n.m. 56 / n.m. 62 / 13 79 / 26

Sovermol® 1040 06:07 n.m. 50 / n.m. 98 / 61 99 / 69


Boost your sustainability profile
Sovermol® – natural oil-based, performance driven polyols 7

Compression Impact Abrasion


Product Tensile strength Elongation Tear resistance strength Bending strength resistance (mg)
(MPa) (%) (N/mm) (MPa) (CS17 − 1000 g −
(MPa) (mJ/mm²) 1000 rounds)
ISO 527-3 Typ 5 ISO 527-3 Typ 5 ISO 34-1 ISO EN ISO 604 ISO EN ISO 178 DIN 53453 DIN 53754

Sovermol® 100 n.m. n.m. n.m. n.m. 107 2 n.m.

Sovermol® 320 30 4 30 n.m. 36 12 n.m.

Sovermol® 650 NS 13 64 83 n.m. 5 126 8

Sovermol® 750 45 3 9 36 53 6 34

Sovermol® 760 42 1 6 45 57 4 15

Sovermol® 805 17 65 88 n.m. 8 121 68

Sovermol® 810 18 39 60 n.m. 10 34 79

Sovermol® 815 21 34 70 n.m. 22 24 28

Sovermol® 818 18 58 64 n.m. 6 113 77

Sovermol® 819 18 66 70 n.m. 7 107 88

Sovermol® 860 13 17 48 n.m. 6 9 100

Sovermol® 908 14 122 38 n.m. 1 96 n.m.

Sovermol® 920 1 91 3 n.m. n.m. 7 n.m.

Sovermol® 1005 1 24 3 n.m. 0.3 n.m. n.m.

Sovermol® 1014 3 59 6 n.m. 1 3 7

Sovermol® 1052 n.m. n.m. n.m. n.m. n.m. n.m. n.m.

Sovermol® 1083 14 76 46 n.m. 3 132 25

Sovermol® 1092 39 3 21 31 43 34 61

Sovermol® 1093 43 4 25 n.m. 54 34 n.m.

Sovermol® 1102 13 52 47 n.m. 2 38 75

Sovermol® 1106 46 4 22 40 63 13 n.m.

Sovermol® 1111 5 36 12 n.m. 1 33 n.m.

Sovermol® 1140 10 1 14 9 16 10 n.m.

n.m. = not measured


Contacts

Asia Mexico
BASF East Asia Regional Headquarters Ltd. BASF Mexicana, S.A. de C.V.
45/F, Jardine House Av. Insurgentes Sur 975
No. 1 Connaught Place Col. Ciudad de los Deportes
Central 03710 Mexico, D.F.
Hong Kong Mexico
Tel.: +852 2731-0111 Tel.: +5255-5325-2756
Fax: +852 2731-5633 Fax: +5255-5723-3011

Europe, Africa, West Asia South America


BASF Personal Care and Nutrition GmbH BASF S.A.
E-EDC/RA Estrada do Rio Abaixo
Bld.Z04 - Room 0318 S/N - Rod. Pres. Dutra km 161
40589 Duesseldorf 12335-010 Jacareí – SP
Germany Brazil
Tel.: +49 211 7940-5666 Tel.: +55 12 2128-6292
Fax: +49 211 2006-15666 Fax: +55 12 2128-6449

North America
BASF Corporation
Resins & Performance Additives
1609 Biddle Avenue
Wyandotte, MI 48192
USA
Tel.: +1 800 231-7868
Fax +1 800 392-7429
polyorders@basf.com

BASF SE

EDC 0714 e
67056 Ludwigshafen
Germany
www.basf.com/resins

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not
relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any
descriptions, drawings, photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed
contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights
and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene
measures adequate for handling chemicals must be observed.

® = registered trademark of the BASF Group

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