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Product and Company Identification: Safety Data Sheet

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Safety Data Sheet

Revision Number: 004.4 Issue date: 10/08/2018

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: BONDERITE M-CR 1132 AERO IDH number: 1445846
Product type: Chromating Products for Metals Item number: 1445856
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE CANCER.

HAZARD CLASS HAZARD CATEGORY


SKIN SENSITIZATION 1
CARCINOGENICITY 1B

PICTOGRAM(S)

Precautionary Statements

Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Avoid breathing vapors, mist, or spray. Contaminated work clothing
should not be allowed out of the workplace. Wear protective gloves, clothing, eye and face
protection.
Response: IF ON SKIN: Wash with plenty of water. IF exposed or concerned: Get medical attention. If skin
irritation or rash occurs: Get medical attention. Wash contaminated clothing before reuse.
Storage: Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous Component(s) CAS Number Percentage*
Chromium III chromate 24613-89-6 0.1 - 1
Chromium phosphate 7789-04-0 0.1 - 1

IDH number: 1445846 Product name: BONDERITE M-CR 1132 AERO


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* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES


Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh
air. Seek medical attention if symptoms develop or persist.

Skin contact: For skin contact, flush with large amounts of water. Seek immediate medical
attention. Remove contaminated clothing and footwear. Discard any shoes or
clothing items that cannot be decontaminated.

Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Get immediate medical attention. DO NOT induce vomiting unless directed to
do so by medical personnel.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES


Extinguishing media: Use media appropriate for surrounding material.

Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus.

Unusual fire or explosion hazards: This product is an aqueous mixture which will not burn.

Hazardous combustion products: Irritating and toxic gases or fumes may be released during a fire.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate
protective equipment and clothing during clean-up.

Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for
disposal. Dispose of according to Federal, State and local governmental
regulations.

7. HANDLING AND STORAGE


Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Do not reuse the empty container. For
industrial use only.

Storage: For safe storage, store between 40 °F (4.4 °C) and 104 °F (40°C)
Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials. Thaw and mix thoroughly if frozen.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

IDH number: 1445846 Product name: BONDERITE M-CR 1132 AERO


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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


0.0005 mg/m3 STEL
(as Cr(VI)) Inhalable
fraction.
0.0005 mg/m3 STEL
(as Cr(VI)) Inhalable
0.005 mg/m3 TWA
fraction.
0.0025 mg/m3
0.0002 mg/m3 TWA
Chromium III chromate OSHA_ACT None None
(as Cr(VI)) Inhalable
fraction.
0.1 mg/m3 Ceiling
(SKIN) (as Cr(VI))
Inhalable fraction.
(Dermal sensitization)
(Respiratory
sensitization)
0.003 mg/m3 TWA
(as Cr(III)) Inhalable
fraction.
1 mg/m3 PEL (as Cr)
0.003 mg/m3 TWA
Chromium phosphate 0.5 mg/m3 PEL (as None None
(as Cr(III)) Inhalable
Cr)
fraction. (Respiratory
sensitization)
(Dermal sensitization)

Engineering controls: Provide local and general exhaust ventilation to effectively remove and
prevent buildup of any vapors or mists generated from the handling of this
product.

Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or
vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

Eye/face protection: Wear chemical goggles; face shield (if splashing is possible).

Skin protection: Chemical resistant, impermeable gloves. Use of impervious apron and boots
are recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Liquid
Color: Yellow green
Odor: Mild
Odor threshold: Not available.
pH: 1.95 - 2.25
Vapor pressure: Not determined
Boiling point/range: > 100 °C (> 212°F)
Melting point/ range: Not determined
Specific gravity: 1.00 - 1.01 at 60 °F (15.56 °C)
Vapor density: Not determined
Flash point: Not applicable
Flammable/Explosive limits - lower: Not applicable
Flammable/Explosive limits - upper: Not applicable
Autoignition temperature: Not applicable
Flammability: Not applicable
Evaporation rate: Not determined
Solubility in water: Complete
Partition coefficient (n-octanol/water): Not available.
VOC content: 0 % (calculated)
Viscosity: Not available.
Decomposition temperature: Not available.

IDH number: 1445846 Product name: BONDERITE M-CR 1132 AERO


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10. STABILITY AND REACTIVITY
Stability: Stable at normal conditions.

Hazardous reactions: Will not occur.

Hazardous decomposition None identified.


products:

Incompatible materials: Avoid contact with organic materials, oils, greases, and any oxidizable materials.

Reactivity: Not available.

Conditions to avoid: Do not allow chemical to dry in the presence of organic materials.

11. TOXICOLOGICAL INFORMATION


Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects/Symptoms

Inhalation: This product is irritating to the respiratory system.


Skin contact: This product may cause irritation to the skin. Product contains chromium, which may cause an
allergic skin sensitization reaction. Massive overexposures may lead to kidney failure and
death. A component in this product may be absorbed through the skin in harmful amounts.
Eye contact: This product may be severely irritating to the eyes.
Ingestion: Acute ingestion may result in mild gastrointestinal distress. May be harmful if swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Chromium III chromate None Allergen, Irritant, Respiratory
Chromium phosphate None Allergen, Irritant, Metabolic, Respiratory

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Known To Be Human
Chromium III chromate Group 1 Yes
Carcinogen.
Chromium phosphate No No No

12. ECOLOGICAL INFORMATION


Ecological information: Do not empty into drains / surface water / ground water.

IDH number: 1445846 Product name: BONDERITE M-CR 1132 AERO


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13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.
This chemical contains phosphates. This chemical contains heavy metals.

Hazardous waste number: This product contains chromium which is a hazardous waste (D007).

14. TRANSPORT INFORMATION


The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
DOT Hazardous Substance(s): Chromic acid

International Air Transportation (ICAO/IATA)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. (Chromium(III)-chromate)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

Water Transportation (IMO/IMDG)


Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Chromium(III)-chromate)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
Marine pollutant: Chromium(III)-chromate

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: Chromium III chromate (CAS# 24613-89-6).

CERCLA/SARA Section 302 EHS: None above reporting de minimis.


CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Chromium III chromate (CAS# 24613-89-6).
CERCLA Reportable quantity: Chromic acid (CAS# 7738-94-5) 10 lbs. (4.54 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

IDH number: 1445846 Product name: BONDERITE M-CR 1132 AERO


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Prepared by: Regulatory Affairs

Issue date: 10/08/2018

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 1445846 Product name: BONDERITE M-CR 1132 AERO


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