SAFETY DATA SHEET

Section 1. Identification of the material and the supplier

Product: Orange Peel

Item Code: 3070
Product Use: Industrial strength paint stripper.
Restriction of Use: Refer to Section 15

Australian Supplier: Norglass Paints

Address: 59 Moxon Road
Punchbowl NSW 2196
Australia
Telephone: +61 2 9708 2200
Email: info@norglass.com.au

New Zealand Supplier: xxx

Address: xxx
xxx
Telephone: 0508 724687

Emergency Numbers:
Australia: 13 1126 (Poisons Information Centre)
New Zealand: 0800 764 766 (National Poison Centre)

Date of SDS Preparation: 10 December 2018 v2

Section 2. Hazards Identification

Australia:
Classified as Hazardous according to the Globally Harmonised System of Classification and
labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia

New Zealand:
This substance is hazardous according to the EPA Hazardous Substances (Classification)
Notice 2017

EPA Approval No:

Cleaning Products (combustible) – HSR002525

Pictograms

Irritant Chronic Ecotoxic

Signal Word: DANGER

Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 1
 HSNO Hazard
Hazard Statement GHS Category
Classification Code
3.1D H227 Combustible liquid. Flam. Liq. 4
6.1E (oral) H303 May be harmful if swallowed. Acute Tox. 5
6.3A H315 Causes skin irritation. Skin Irrit. 2
6.4A H319 Causes serious eye irritation. Eye Irrit. 2A
6.5B H317 May cause an allergic skin reaction. Skin Sens. 1
6.8A H360 May damage fertility or the unborn child. Repr. 1B
9.1A H400 Very toxic to aquatic life. Aquatic Acute 1
9.2B H422 Toxic to the soil environment.

Prevention Code Prevention Statement

P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, sparks, open flames or hot surfaces. No smoking.
P261 Avoid breathing fumes or vapours.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective clothing.
P281 Use personal protective equipment as required.

Response Code Response Statement

P101 If medical advice is needed, have product container or label at hand.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P362 Take off contaminated clothing and wash before re-use.
P391 Collect spillage.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + IF IN EYES: Rinse cautiously with water for several minutes. Remove
P351+P338 contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P370 + P378 In case of fire: Use dry chemical, carbon dioxide or foam for extinction.

Storage Code Storage Statement

P405 Store locked up.
P403 + P235 Store in a well-ventilated place. Keep cool.

Disposal Code Disposal Statement

P501 Dispose of according to Local Regulations or Authorities

Section 3. Composition / Information on Ingredients

Ingredients Wt% CAS NUMBER.

N-methyl-2-pyrrolidone >60 872-50-4
d-limonene 10-30 5989-27-5
Non-hazardous ingredients To bal

Section 4. First Aid Measures

Routes of Exposure:

If in Eyes Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice.
Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 2
If on Skin Wash with plenty of soap and water. Take off contaminated clothing and
wash before re-use. If skin irritation or rash occurs: get medical
advice/attention.

If Swallowed Rinse mouth. Do NOT induce vomiting. Give water to rinse out mouth,
then provide liquid slowly and as much as casualty can comfortably drink.
If vomiting occurs, place victim face downwards, with the head turned to
the side and lower than the hips to prevent vomit entering the lungs.
Seek immediate medical attention.

If Inhaled Remove person to fresh air. Remove contaminated clothing and loosen
remaining clothing. Allow person to assume most comfortable position
and keep warm. Keep at rest until fully recovered. Get medical advice if
breathing becomes difficult or if you feel unwell.

Most important symptoms and effects, both acute and delayed

Symptoms:
Ingestion: May be harmful if swallowed. The liquid may produce considerable
gastrointestinal discomfort and may be harmful or toxic if swallowed.
Ingestion may result in nausea, pain and vomiting. Vomit entering the
lungs by aspiration may cause potentially lethal chemical pneumonitis.
Inhalation: Not applicable.
Skin: Causes skin irritation. May cause an allergic skin reaction.
Eye: Causes serious eye irritation.
Chronic: May damage fertility or the unborn child.
Other: Any material aspirated during vomiting may produce lung injury. Therefore
emesis should not be induced mechanically or pharmacologically.
Mechanical means should be used if it is considered necessary to evacuate
the stomach contents; these include gastric lavage after endotracheal
intubation. If spontaneous vomiting has occurred after ingestion, the
patient should be monitored for difficult breathing, as adverse effects of
aspiration into the lungs may be delayed up to 48 hours.
Treat symptomatically.

Section 5. Fire Fighting Measures

Hazard Type Combustible

Hazards from Carbon Dioxide and nitrogen Oxides. Other pyrolysis products typical of
combustion burning organic material. WARNING: Long standing in contact with air
products and light may result in the formation of potentially explosive peroxides.
May emit poisonous fumes.
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result.
Suitable Dry chemical powder, BCF (where regulations permit), Carbon dioxide
Extinguishing and water spray or fog - Large fires only.
media
Precautions for Wear breathing apparatus plus protective gloves.
firefighters and Prevent, by any means available, spillage from entering drains or water
special protective course. Use water delivered as a fine spray to control fire and cool
clothing adjacent area. Avoid spraying water onto liquid pools.
Do not approach containers suspected to be hot. Cool fire exposed
containers with water spray from a protected location. If safe to do so,
remove containers from path of fire.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent
rupture of containers.
HAZCHEM CODE 3Z

Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 3
Section 6. Accidental Release Measures

Personal precautions:
Wear protective equipment as detailed in Section 8. Clear area of any unprotected personnel.
No smoking, naked lights or ignition sources. Increase ventilation.

Environmental precautions:
Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil.
Notify authorities if product enters sewers or public waters.

Spill and Disposal procedures:

Clean up spills immediately. Contain and absorb spill with sand, earth, inert material or
vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal. Dispose by
incineration by approved agent or local regulations.

Section 7. Handling and Storage

Precautions for Handling:

 Read label before use.
 Do not handle until all safety precautions have been read and understood.
 Keep away from heat, sparks, open flames or hot surfaces. No smoking.
 Avoid breathing fumes or vapours.
 Wash hands thoroughly after handling.
 Contaminated work clothing should not be allowed out of the workplace.
 Avoid release to the environment.
 Wear protective clothing.
 Use personal protective equipment as required.
 Do not allow wet clothing with material to stay in contact with skin.
 Use in well ventilated area.
 Prevent concentration in hollows and sumps.
 DO NOT enter confined spaces until atmosphere has been checked.

Precautions for Storage:
 Store away from incompatible materials listed in Section 10 eg oxidisers.
 Material is hygroscopic, i.e. absorbs moisture from the air.
 Keep containers well sealed in storage.
 Store in original containers.
 Keep containers securely sealed.
 Store in a cool, dry, well-ventilated area.
 Protect containers against physical damage and check regularly for leaks.
 Observe manufacturer's storage and handling recommendations contained within this
SDS.
 Suitable container: Glass, metal can or drum, packaging recommended by mfg. Check
all containers are clearly labelled and free from leaks.

Section 8 Exposure Controls / Personal Protection

WORKPLACE EXPOSURE STANDARDS (provided for guidance only)

TWA STEL
Substance ppm mg/m3 ppm mg/m3

1-Methyl-2-pyrrolidone (skin) [872-50-4] 25 103 75 309

Workplace Exposure Standard – Time Weighted Average (WES-TWA).The time-weighted average exposure standard
designed to protect the worker from the effects of long-term exposure. Workplace Exposure Standard – Short-Term
Exposure Limit (WESSTEL). The 15-minute average exposure standard. Applies to any 15- Minute period in the working
day and is designed to protect the worker against adverse effects of irritation, chronic or irreversible tissue change, or
narcosis that may increase the likelihood of accidents. The WES-STEL is not an alternative to the WES-TWA; both the
short-term and time-weighted average exposures apply. Workplace Exposure Standards and Biological Exposure
Indices NOV 2017 9TH EDITION.

Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 4
Engineering Controls
General exhaust is adequate under normal operating conditions. Local exhaust ventilation may
be required in specific circumstances. If risk of overexposure exists, wear approved respirator.
Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse
or closed storage areas. Air contaminants generated in the workplace possess varying "escape"
velocities which, in turn, determine the "capture velocities" of fresh circulating air required to
effectively remove the contaminant.

Type of Contaminant: Air Speed:

0.25-0.5 m/s (50-100
solvent, vapours, degreasing etc., evaporating from tank (in still air).
f/min)
aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, 0.5-1 m/s (100-200
plating acid fumes, pickling (released at low velocity into zone of active generation) f/min.)
direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation 1-2.5 m/s (200-500
into zone of rapid air motion) f/min.)
grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone of very high 2.5-10 m/s (500-2000
rapid air motion). f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range
1: Room air currents minimal or favourable to capture 1: Disturbing room air currents
2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity
2: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood-local control only

Personal Protection Equipment:

Eyes Wear safety goggles with side shields. Contact lenses may pose a special
hazard; soft contact lenses may absorb and concentrate irritants. A written
policy document, describing the wearing of lenses or restrictions on use,
should be created for each workplace or task. This should include a review of
lens absorption and adsorption for the class of chemicals in use and an
account of injury experience. Medical and first-aid personnel should be
trained in their removal and suitable equipment should be readily available.
In the event of chemical exposure, begin eye irrigation immediately and
remove contact lens as soon as practicable. Lens should be removed at the
first signs of eye redness or irritation - lens should be removed in a clean
environment only after workers have washed hands thoroughly.
Hands and Wear chemical protective gloves, e.g. PVC.
Skin Wear safety footwear or safety gumboots, e.g. Rubber
Overalls, PVC apron, barrier cream, skin cleaning cream and eye wash unit.
Respiratory Type AK Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
149:2001, ANSI Z88 or national equivalent)
Where the concentration of gas/particulates in the breathing zone,
approaches or exceeds the "Exposure Standard" (or ES), respiratory
protection is required.
Degree of protection varies with both face-piece and Class of filter; the
nature of protection varies with Type of filter.
Required Half-Face Full-Face Powered
Minimum Respirator Respirator Air
Protection
up to 5 x ES AK-AUS / - AK-PAPR-
Respirator
Factor Class 1 AUS / Class
up to 25 x ES Air-line* AK-2 AK-PAPR-2
1
up to 50 x ES - AK-3 -
50+ x ES - Air-line** -

^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas
or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E =
Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 5
 Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg =
Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling
point organic compounds(below 65 degC)

Section 9 Physical and Chemical Properties

Appearance Thick orange liquid.

Odour Not available
Odour Threshold Not available
pH Not available
Boiling Point 154.440C
Melting Point Not available
Freezing Point Not available
Flash Point >610C
Flammability Combustible
Upper and Lower Not available
Exposure Limits
Volatile Component Not available
Vapour Pressure 200C <0.13 kPa
Relative Density (water 0.96-1.02
=1)
Solubilities Partly Miscible
Partition Coefficient: Not available
Auto-ignition Not available
Temperature
Decomposition Not available
Temperature
Kinematic Viscosity Not available
Particle Characteristics Not available
VOC g/L 871.03 g/L

Section 10. Stability and Reactivity

Stability of Substance This product is stable under normal conditions.

Conditions to Avoid Sources of ignition, smoking or naked lights.
Incompatible Materials Oxidisers
Hazardous Decomposition Carbon Dioxide and nitrogen Oxides. Other pyrolysis products
Products typical of burning organic material. WARNING: Long standing in
contact with air and light may result in the formation of
potentially explosive peroxides. May emit poisonous fumes.

Section 11 Toxicological Information

Acute Effects:

Swallowed May be harmful if swallowed. Accidental ingestion of the material may

be damaging to the health of the individual.
Considered an unlikely route of entry in commercial/industrial
environments. The liquid may produce considerable gastrointestinal
discomfort and may be harmful or toxic if swallowed. Ingestion may
result in nausea, pain and vomiting. Vomit entering the lungs by
aspiration may cause potentially lethal chemical pneumonitis.
Dermal Not applicable.
Inhalation Not applicable.
Eye Causes severe eye irritation. Evidence exists, or practical experience
predicts, that the material may cause eye irritation in a substantial
number of individuals and/or may produce significant ocular lesions
which are present twenty-four hours or more after instillation into the
eye(s) of experimental animals. Repeated or prolonged eye contact
may cause inflammation characterised by a temporary redness (similar
Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 6
 to windburn) of the conjunctiva (conjunctivitis); temporary impairment
of vision and/or other transient eye damage/ulceration may occur.
Skin Causes mild skin irritation. May cause an allergic skin reaction.
Evidence exists, or practical experience predicts, that the material
either produces inflammation of the skin in a substantial number of
individuals following direct contact, and/or produces significant
inflammation when applied to the healthy intact skin of animals, for up
to four hours, such inflammation being present twenty-four hours or
more after the end of the exposure period. Skin irritation may also be
present after prolonged or repeated exposure; this may result in a
form of contact dermatitis (nonallergic). The dermatitis is often
characterised by skin redness (erythema) and swelling (oedema) which
may progress to blistering (vesiculation), scaling and thickening of the
epidermis. At the microscopic level there may be intercellular oedema
of the spongy layer of the skin (spongiosis) and intracellular oedema of
the epidermis.
The material may accentuate any pre-existing dermatitis condition
Open cuts, abraded or irritated skin should not be exposed to this
material
Entry into the blood-stream through, for example, cuts, abrasions,
puncture wounds or lesions, may produce systemic injury with harmful
effects. Examine the skin prior to the use of the material and ensure
that any external damage is suitably protected.

Chronic Effects:

Carcinogenicity Not applicable.

Reproductive May damage fertility or the unborn child.
Toxicity
Germ Cell Not applicable.
Mutagenicity
Aspiration Not applicable.
STOT/SE Not applicable.
STOT/RE Not applicable.
Other Chronic solvent inhalation exposures may result in nervous system
impairment and liver and blood changes. [PATTYS]

Individual component information:

Acute Toxicity:
Chemical Name Oral – LD50 Dermal – LD50 Inhalation – LC50
N-Methyl-2-pyrrolidone 3500mg/kg - -
(872-50-4) (rabbit)
d-Limonene (5989-27-5) 4400mg/kg (rat) - -

Section 12. Ecotoxicological Information

New Zealand:
HSNO Classes: 9.1A = Very toxic to aquatic life
9.2B = Toxic to the soil environment.

Persistence and degradability No data available

Bioaccumulation No data available
Mobility in Soil No data available
Other adverse effects No data available

Individual component information (Please refer to www.epa.govt.co.nz for full details):

d-Limonene (5989-27-5):
Route Species Duration Value LC50/EC50
Aquatic, fish Pimephales promelas Fathead minnow 96 hr 0.702 mg/L
Aquatic, Crustacean Daphnia magna 48 hr 0.421mg/L
Algae Algae or other aquatic plants 72 Ca 8mg/L
Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 7
Algae Algae or other aquatic plants 72 NOEC 2.62mg/L
Bioaccumulative Yes
Rapidly Degradable Yes

N-Methyl-2-pyrrolidone (872-50-4):
Route Species Duration Value LC50/EC50
Aquatic, fish Fish 96 hr 464 mg/L
Aquatic, Crustacean Crustacea 48 hr Ca 4897 mg/L
Crustacea 504 12.5mg/L
Algae Algae or other aquatic plants 72 >500mg/L
Algae Algae or other aquatic plants 72 >500mg/L
Bioaccumulative Yes
Rapidly Degradable Yes

Section 13. Disposal Considerations

Disposal Method: Place recovered product into an appropriate waste container for disposal
through appropriate waste company or specialized landfill in accordance
with local regulations. Ensure container is sealed and isolated away from
ignition sources and marked “Combustible”.

Precautions: If triple rinsing container, add rinsate to waste container for disposal.

Disposal methods to avoid: Do not release product into the environment prior to curing.

Section 14 Transport Information

This product is classified as Dangerous Goods according to the Australian Code for the
Transport of Dangerous Goods by Road and Rail (ADG Code) (7th edition).

This product is classified as a Dangerous Good for transport in NZ ; NZS 5433:2012

Road and Rail Transport

UN No: 3082
Class-primary 9
Packing Group III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS LIQUID, N.O.S

Air Transport
UN No: 3082
Class-primary 9
Packing Group III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS LIQUID, N.O.S

Marine Transport
UN No: 3082
Class-primary 9
Packing Group III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS LIQUID, N.O.S
Marine Pollutant Yes

Limited Quantities Statement:

If the product’s individual container is below 5L, it can be transported as a non-DG as long as
the product packaging is still labelled as per DG requirements and the driver is given safety
information in accordance with Chapter 3.4 of the UNRTDG.

Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 8
Section 15 Regulatory Information

Australia:
Classified as Hazardous according to the Globally Harmonised System of Classification and
labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia.

Classified as a Schedule 6 Poison according to the Standard for the Uniform Scheduling of
Medicines and Poisons (SUSMP).

New Zealand
This substance is classified hazardous according to the EPA Hazardous Substances
(Classification) Notice 2017

EPA Approval Code: Cleaning Products (Combustible) – HSR002525

HSNO Classification: 3.1D, 6.1E(oral), 6.3A, 6.4A, 6.5B, 6.8A, 9.1A, 9.2B

HSW (HS) Regulations 2017 and EPA Notices Trigger Quantity

Certified Handler Not required
Location Certificate Not required
Tracking Trigger Quantities Not required
Signage Trigger Quantities 100L (9.1A)
Emergency Response Plan 100L (9.1A)
Secondary Containment 100L (9.1A)
Restriction of Use Only use for the intended purpose.

Section 16 Other Information

Glossary
EC50 Median effective concentration.
EEL Environmental Exposure Limit.
EPA Environmental Protection Authority
HSNO Hazardous Substances and New Organisms.
HSW Health and Safety at Work.
LC50 Lethal concentration that will kill 50% of the test organisms
inhaling or ingesting it.
LD50 Lethal dose to kill 50% of test animals/organisms.
LEL Lower explosive level.
OSHA American Occupational Safety and Health Administration.
TEL Tolerable Exposure Limit.
TLV Threshold Limit Value-an exposure limit set by responsible
authority.
UEL Upper Explosive Level
WES Workplace Exposure Limit

References:
Australia:
1. Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice.
2. National Industrial Chemicals Notification and Assessment Scheme (NICNAS).
3. Standard for the Uniform Scheduling of Medicines and Poisons.
4. Australian Code for the Transport of Dangerous Goods by Road & Rail.
5. Model Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens,
restricted carcinogens and restricted hazardous chemicals.
6. Workplace exposure standards for airborne contaminants, Safe work Australia.
7. American Conference of Industrial Hygienists (ACGIH).
8. Globally Harmonised System of Classification and Labelling of chemicals.

New Zealand:
1. EPA Hazardous Substances (Safety Data Sheets) Notice 2017
2. Workplace Exposure Standards and Biological Exposure Indices Nov 2017 edition.
3. Assigning a hazardous substance to a HSNO Approval (Aug 2013).
4. Transport of Dangerous goods on land NZS 5433:2012
Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 9
 5. HSW (Hazardous Substances) Regulations 2017

Disclaimer
This document has been prepared by TCC (NZ) Ltd and serves as the suppliers Safety Data
Sheet ('SDS'). It is based on information concerning the product which has been provided to
TCC (NZ) Ltd or obtained from third party sources and is believed to represent the current state
of knowledge as to the appropriate safety and handling precautions for the product at the time
of issue. Further clarification regarding any aspect of the product should be obtained directly
from the manufacturer. While TCC (NZ) have taken all due care to include accurate and up-to-
date information in this SDS, it does not provide any warranty as to accuracy or completeness.
As far as lawfully possible, TCC (NZ) Ltd accept no liability for any loss, injury or damage
(including consequential loss) which may be suffered or incurred by any person as a
consequence of their reliance on the information contained in this SDS
The information herein is given in good faith, but no warranty, express or implied is made.
Please contact the Australian Manufacturer or New Zealand distributor, if further information is
required.
Issue Date: 10 December 2018 Review Date: 10 December 2023

Product Name: Orange Peel Prepared by: Technical Compliance Consultants (NZ) Ltd
Date of SDS: 10 December 2018 Tel: 64 9 475 5240 www.techcomp.co.nz
Page 10