Safety Data Sheet

Aquagum P/030

Safety Data Sheet dated 18/5/2020, version 6

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Mixture identification:
Trade name : Aquagum P/030
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
Spray adhesive.
Uses advised against:
Any use other than recommended.
1.3. Details of the supplier of the safety data sheet
Producer:
FRABO ADESIVI spa - via Garibaldi 76/78 - 20061 Carugate - Milan - ITALY
Tel. +39 02 9253631 - Fax +39 02 9252357
Company with certified Quality Sistem UNI EN ISO 9001/2008
Competent person responsible for the safety data sheet:
Dr. Marco Marinelli (marinelli.laboratorio@frabo.it)
1.4. Emergency telephone number
FRABO ADESIVI spa - Tel.(+39) 02 9253631 ( 8h00 - 12h00 // 13h30 - 17h00 )

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
EC regulation criteria 1272/2008 (CLP)
The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP).
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP).
Hazard pictograms:
None
Hazard statements:
None
Precautionary statements:
None
Special Provisions:
EUH210 Safety data sheet available on request.
Contains
reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1): May produce an allergic
reaction.
Special provisions according to Annex XVII of REACH and subsequent amendments:
Industrial use only
None

2.3. Other hazards

vPvB Substances: None - PBT Substances: None
Other Hazards:
No other adverse effect at the time known.

SECTION 3: Composition/information on ingredients

3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of the CLP regulation and related classification:

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Qty Name Ident. Number Classification

>= 0.001%reaction mass of 5- Index 613-167-00-5 3.1/2/Inhal Acute Tox. 2 H330

- < 0.01% chloro-2-methyl-2H- number: 3.1/2/Dermal Acute Tox. 2 H310
isothiazol-3-one and 2- CAS: 55965-84-9 3.1/3/Oral Acute Tox. 3 H301
methyl-2H-isothiazol-3- 3.2/1C Skin Corr. 1C H314
one (3:1) 3.3/1 Eye Dam. 1 H318
3.4.2/1A Skin Sens. 1A H317
4.1/A1 Aquatic Acute 1 H400
M=100.
4.1/C1 Aquatic Chronic 1 H410
M=100.
EUH071
Specific Concentration Limits:
C >= 0,6%: Skin Corr. 1C H314
0,06% <= C < 0.6%: Skin Irrit. 2
H315
C >= 0,6%: Eye Dam. 1 H318
0,06% <= C < 0.6%: Eye Irrit. 2
H319
C >= 0,0015%: Skin Sens. 1A H317

SECTION 4: First aid measures

4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
D.P.I for those for first aid: Refer to Section 8.2
4.2. Most important symptoms and effects, both acute and delayed
No known symptoms to date.
Refer to the individual substances, see item 11.1 (Information on toxicological effects).
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale combustion gases. Possible Carbon Oxides (COx) formation.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
D.P.I for those for first aid: Refer to Section 8.2
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
See also section 8 for recommended protective equipment.
General recommendations on occupational hygiene:
Do not eat or drink while working.
Provide electrical equipment comply with the current legislation on electrical safety for places with fire hazard.
7.2. Conditions for safe storage, including any incompatibilities
To shelter from the cold, avoid the storage at temperature lower to 10°C and upper to 30°C
Keep away from food, drink and feed.
Store in closed and labeled containers. Containers should also be protected from damage, accidental shocks and falls.
Store only in the original container.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
Spray adhesive.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No occupational exposure limit available
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.

8.2. Exposure controls

Keep in mind that, as a first intervention, collective technical solutions for the control of exposure should always be
preferred.
Below is information for individual exposure control.
Not needed for normal use.
Eye protection:
Use close fitting safety goggles and/or visor conforming to EN166.
Protection for skin:
Not necessary for occasional, non-continuous use; for prolonged use wear work clothes with long sleeves and safety
footwear for professional use and category II (see Regulation (EU) 2016/425 and EN 344 standard). Wash with soap
and water after removing protective clothing.
Protection for hands:
Not required for not prolonged, non-continuous use. For prolonged use suitable protective gloves (eg Butyl Rubber IIR,>
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0.5 mm, time of occurrence of> = 480 min, or nitrile rubber or neoprene) (Dir.89/686/CEE and standard EN 374)
Respiratory protection:
Not required for workers exposure levels below those indicated in Section 8.
In the absence of aspiration system to ensure concentrations of vapors below the exposure limit values (TLV-TWA,
TLV STEEL), respiratory protection is required, such as a mask with cartridge filter (combination A2-P2) (ref. standard
EN 141). the respiratory protection filter class must be absolutely adapted to the maximum concentration of toxic
substance (gas / vapor / aerosol / particles) that can be generated in the treatment with the product (EN ISO 14387). In
extreme cases, use suitable breathing apparatus (ref. standard EN 137 or EN 138)

Thermal Hazards:
Wear resistant gloves in case of thermal hazards
Environmental exposure controls:
Expect to applicable regulations
Appropriate engineering controls:
None

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Method: Notes

Appearance and colour: Liquid white -- --

Odour: Characteristic -- --

Odour threshold: Not defined/ -- --

Not available

pH: 7,5 internal --

method
MLF004

Melting point / freezing about 0 ° C -- --

point:

Boiling point: about 100 ° C -- --

Flash point: Not Relevant -- --

Evaporation rate: Not defined/ -- --

Not available

Solid/gas flammability: Not Relevant -- --

Lower/Upper flammability Not Relevant -- --

or explosive limits:

Vapour pressure: Not defined/ -- --

Not available

Vapour density: > 1,0 (rif. air -- --

= 1,0) Kg/m³

Relative density: 1,08 ±0,05 kg/ internal --

dm³ method
MLF003

Solubility in water: Yes -- --

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Solubility in oil: Not defined/ -- --

Not available

Partition coefficient (n- Not defined/ -- --

octanol/water): Not available

Auto-ignition temperature: Not Relevant -- --

Decomposition Not defined/ -- --

temperature: Not available

Viscosity: 4000 ± 800 internal --

method
MLF001

Explosive properties: Not Relevant -- --

Oxidizing properties: Not Relevant -- --

9.2. Other information

Properties Value Method: Notes

Miscibility: Not defined/ -- --

Not available

Fat Solubility: Not defined/ -- --

Not available

Conductivity: Not defined/ -- --

Not available

V.O.C. contained : <1 % -- --

Substance Groups Not defined/ -- --

relevant properties Not available

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Stable under normal conditions
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Toxicological information of the product:
Aquagum P/030
a) acute toxicity
Not classified
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Based on available data, the classification criteria are not met
b) skin corrosion/irritation
Not classified
Based on available data, the classification criteria are not met
c) serious eye damage/irritation
Not classified
Based on available data, the classification criteria are not met
d) respiratory or skin sensitisation
Not classified
Based on available data, the classification criteria are not met
e) germ cell mutagenicity
Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity
Not classified
Based on available data, the classification criteria are not met
g) reproductive toxicity
Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure
Not classified
Based on available data, the classification criteria are not met
i) STOT-repeated exposure
Not classified
Based on available data, the classification criteria are not met
j) aspiration hazard
Not classified
Based on available data, the classification criteria are not met
Toxicological information of the main substances found in the product:
N.A.

SECTION 12: Ecological information

12.1. Toxicity
Adopt sound working practices, so that the product is not released into the environment. Refer to point 6.2.
Aquagum P/030
Not classified for environmental hazards
Based on available data, the classification criteria are not met
12.2. Persistence and degradability
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
No other known effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Recover if possible.
The preparation to be disposed-of and its container,if polluted,has to be considered as SPECIAL WASTE.Consign to
authorized draining plants by authorized carriers.The waste code in accordance with European waste catalogue
cannotbe specified as it depend on utilizer.
Comply with the local and national regulations currently in force.
Council Directive : 2008/98/CE and subsequent amendments

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SECTION 14: Transport information

Not classified as dangerous in the meaning of transport regulations.

14.1. UN number
ADR-UN number:
IATA-Un number:
IMDG-Un number:
14.2. UN proper shipping name
N.A.
14.3. Transport hazard class(es)
N.A.
14.4. Packing group
N.A.
14.5. Environmental hazards
N.A.
14.6. Special precautions for user
N.A.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) 2015/830
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Regulation (EU) n. 2015/1221 (ATP 7 CLP)
Regulation (EU) n. 2016/918 (ATP 8 CLP)
Regulation (EU) n. 2016/1179 (ATP 9 CLP)
Regulation (EU) n. 2017/776 (ATP 10 CLP)
Regulation (EU) n. 2018/669 (ATP 11 CLP)
Regulation (EU) n. 2018/1480 (ATP 13 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH)
and subsequent modifications:
Restrictions related to the product:

Restrictions related to the substances contained:

No restriction.
When applicable refers to the following regulations.
Directive 2012/18/EU (Seveso III)
Regulation (EC) nr 648/2004 (detergents).
Dir. 2004/42/EC (VOC directive)

Provisions related to directive EU 2012/18 (Seveso III):

Seveso III category according to Annex 1, part 1
None

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for the mixture.

SECTION 16: Other information

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Full text of phrases referred to in Section 3:
H330 Fatal if inhaled.
H310 Fatal in contact with skin.
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
EUH071 Corrosive to the respiratory tract.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

Hazard class and Code Description

hazard category

Acute Tox. 2 3.1/2/Dermal Acute toxicity (dermal), Category 2

Acute Tox. 2 3.1/2/Inhal Acute toxicity (inhalation), Category 2

Acute Tox. 3 3.1/3/Oral Acute toxicity (oral), Category 3

Skin Corr. 1C 3.2/1C Skin corrosion, Category 1C

Skin Irrit. 2 3.2/2 Skin irritation, Category 2

Eye Dam. 1 3.3/1 Serious eye damage, Category 1

Eye Irrit. 2 3.3/2 Eye irritation, Category 2

Skin Sens. 1A 3.4.2/1A Skin Sensitisation, Category 1A

Aquatic Acute 1 4.1/A1 Acute aquatic hazard, category 1

Aquatic Chronic 1 4.1/C1 Chronic (long term) aquatic hazard, category 1

Paragraphs modified from the previous revision:

SECTION 2: Hazards identification

SECTION 3: Composition/information on ingredients
SECTION 9: Physical and chemical properties
SECTION 15: Regulatory information
SECTION 16: Other information

This document was prepared by a competent person who has received appropriate training.

Main bibliographic sources:

NIOSH - Registry of toxic effects of chemical substances (1983)
I.N.R.S. - Fiche Toxicologique
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the
product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use
intended.
This document was prepared by a competent person who has received appropriate training.
This safety data sheet has been completely updated in compliance to Regulation 2015/830.
This MSDS cancels and replaces any preceding release.

ADR: European Agreement concerning the International Carriage of

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Dangerous Goods by Road.
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
CAS: Chemical Abstracts Service (division of the American Chemical
Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"
(ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWA: Time-weighted average
WGK: German Water Hazard Class.

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