C) Trigonal Planar: E-Pent-2-ene Z-Pent-2-ene Z-3-Methylpent-2-ene Z-2-Methylpent-2-ene
C) Trigonal Planar: E-Pent-2-ene Z-Pent-2-ene Z-3-Methylpent-2-ene Z-2-Methylpent-2-ene
C) Trigonal Planar: E-Pent-2-ene Z-Pent-2-ene Z-3-Methylpent-2-ene Z-2-Methylpent-2-ene
7.5 Name
a) trans-Pent-2-ene
b) cis-Pent-2-ene
c) trans-3-Methylpent-2-ene
d) cis-3-Methylpent-2-ene
7.6 Name
a) E-Pent-2-ene
b) Z-Pent-2-ene
c) E-3-Methylpent-2-ene
d) Z-3-Methylpent-2-ene
e) Z-2-Methylpent-2-ene
7.7 Name
a) CH3COOH
b) CH3CHO
c) CH3CH2OH
d) HOCH2CH2OH
e) CH3CH(OH)2
7.8
a) ClCH2CH2Cl
b) ClCH=CHCl
c) CH2=CH2
d) CH2=CHCl
7.9
a) (CH3)2CHOH
b) CH3CH2CH2OH
c) HOCH2CH2CH2OH
d) CH3CH(OH)CH2OH
7.10
a) [CH2CH(CH3)]n
b) [CH2CH2]n
c) [CH2=CH(CH3)]n
d) [CH2=CH2]n
7.12
a) CH3CCCH3
b) CH2=CHCH=CH2
c) CH3CH=CHCH3
d) CH3CH2CH2CH3
7.13
a) (CH3)2C(Br)CH3
b) (CH3)2C=CHBr
c) (CH3)2C=CH2
d) (CH3)2CHCH3
7.19
a) (CH3)3CO-, (CH3)3COH
b) CH3CH2O-, CH3CH2OH
c) NaI, acetone
d) H2, Pd
7.20
a) Pt, 500 oC
b) H2, Pt
c) H2SO4, 150 oC
d) NaI, acetone
e) NaOH
Chapter 8 Homework
8.1
a) BrCH2CH2CH3
b) BrCH2CH(Br)CH3
c) CH3CH(Br)CH3
d) CH3CH(OH)CH3
8.2
a) BrCH2CH2CH3
b) BrCH2CH(Br)CH3
c) CH3CH(Br)CH3
d) CH3CH(OH)CH3
8.3 Identify the intermediate in the reaction of an alkene with hydrogen peroxide and HBr.
a) Anion
b) Cation
c) Radical
d) Cycloalkane
8.4
a) HOCH2CH2CH3
b) CH2=CHCH3
c) HOCH2CH(OH)CH3
d) CH3CH(OH)CH3
8.6
a) HOCH2CH2CH3
b) CH3CH(OH)CH3
c) CH2=CHCH3
d) HOCH2CH(OH)CH3
8.7
a) CH3OCH2CH2CH3
b) CH3CH(OCH3)CH3
c) CH2=CHCH3
d) CH3OCH2CH(OCH3)CH3
8.8
a) HOCH2CH2CH3
b) CH3CH(OH)CH3
c) CH2=CHCH3
d) HOCH2CH(OH)CH3
8.10
a) ClCH2CH2CH3
b) CH3CH(Cl)CH3
c) CH3CH2CH3
d) ClCH2CH(Cl)CH3
8.12
a) ClCH2CH(OH)CH3
b) HOCH2CH(Cl)CH3
c) ClCH2CH(Cl)CH3
d) HOCH2CH(OH)CH3
8.13
a) CH3CH2CH2CH3
b) CH3CH2CH3
c) CH3CH3
d) HC≡CCH3
e) HC≡CCH2CH3
8.17
a) HOCH2CH2CH3
b) CH3CH(OH)CH3
c) HOCH2CH(OH)CH3
d) HOCH2CH2CH2OH
8.19
a) HOCH2CH(OH)CH3
b) H2C=O + CH3CHO
c) CO2 + CH3COOH
d) CO2 + CH3CHO
9.1
a) Hept-6-en-3-yne
b) Pent-5-en-3-yne
c) Hept-1-en-4-yne
d) Hept-3-en-5-yne
9.2
a) Pent-2-yn-4-ol
b) Pent-2-en-4-ol
c) Pent-3-en-2-ol
d) Pent-3-yn-2-ol
9.5
a) CH3CH=CH2
b) CH3CCCl
c) CH3CCCH3
d) CH3(Cl)=CHCH3
9.7
a) CH3CCCH2OH
b) CH3CH=CHCH2OH
c) CH3C(OH)=CH2
d) HOCH2C(CH3)=CH2
9.8
a) CH3C(Cl)=CHCH3
b) CH3CH(OH)CH(OH)CH3
c) CH3CH(OH)CH(Cl)CH3
d) CH3CCCH3
9.9
a) CH3CH=CHCH3 (cis)
b) CH3CH=CHCH3 (trans)
c) CH3CH2CH2CH3
d) CH3CCCH3
9.10
a) CH3CH=CHCH3 (cis)
b) CH3CH=CHCH3 (trans)
c) CH3CH2CH2CH3
d) CH3CCCH3
9.11 Describe how hydrogen is added in the reaction of an alkene with Lindlar’s catalyst.
a) Anti
b) Syn
c) Both
d) Neither
9.12
a) CH3CH=CHCH3 (cis)
b) CH3CH=CHCH3 (trans)
c) CH3CH2CH2CH3
d) CH3CCCH3
9.13
a) CH3CH2C(Br)2C(Br)2
b) CH3C(Br)2C(Br)2CH3
c) CH(Br)2CH2CH2CH(Br)2
d) CH3CH2CH(Br)2CH3
e) CH3CH(Br)CH(Br)CH3
9.14
a) CH3C(Cl)2CH3
b) CH3CH2CHCl2
c) CH3C(Cl)=CH2
d) CH3CH=CHCl (cis)
e) CH3CH=CHCl (trans)
9.15
a) CH3C(Br)2CH3
b) CH3CH2CHBr2
c) CH3C(Br)=CH2
d) CH3CH=CHBr
9.16
a) CH3C(OH)=CH2
b) (CH3)2C=O
c) CH3CH2CHO
d) CH3CH=CHOH (cis)
e) CH3CH=CHOH (trans)
9.17
a) CH3C(OH)=CH2
b) (CH3)2C=O
c) CH3CH2CHO
d) CH3CH=CHOH (cis)
e) CH3CH=CHOH (trans)
9.19 Identify the product(s) from the permanganate oxidation of but-1-yne under neutral
conditions.
a) Keto-acid
b) Diketone
c) Dialdehyde
d) Diacid
e) Aldo-acid