Synthesis and Properties of Fe3O4 Nanoparticles by
Synthesis and Properties of Fe3O4 Nanoparticles by
Synthesis and Properties of Fe3O4 Nanoparticles by
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Intensity
60
relevant chemical reaction can be expressed as follows eq.1: 50
40
Fe2+ + 2Fe3+ + 8OH-→Fe3O4 + 4H2O (1) 30
20
C. Characterizations of Materials. 10
The crystal structure of the products was characterized by 0
X-ray Diffraction (XRD) Shimadzu XD-610. The patterns 0 10 20 30 40 50 60 70 80 90
with the Cu Kα radiation (λ = 1,54051 Å) were recorded in 2 θ (degree)
the region of 2θ range 10 to 800. The morphology of the Fig. 1. XRD pattern for Fe3O4
Fe3O4 materials were examined by Scanning Electron
Microscope-Energy Dispersive X Ray Spectrometry In order to investigate the morphology of obtained
(SEM-EDS) JEOL-JSM-6510 LV. Transmission Electron materials by SEM and TEM images. Fig. 2. shown SEM
Microscope (TEM) JEOL JEM 1400 was used for image of Fe3O4, in the picture appears that Fe3O4 particles
characterizing the size of nanoparticles. The magnetic composed of small particle. Fig. 3. shown the TEM image of
properties of the Fe3O4 materials measurement by Vibrating Fe3O4, from which we can know that the diameter size 5-20
Sample Magnetometers (VSM) Lakeshore 74004 at room nm. Fe3O4 synthesized by co-precipitation with different
temperature. Uv-Vis Spectrometry by Shimadzu 2550 used reagen (FeCl3.6H2O, FeCl2.4H2O, propylene glycol and
to measurement procion dye concentration. ammonium hydroxide) indicated the mean size of particles
was 8 nm [18]. The control of the monodisperse size is very
D. Adsorption Experiment. important because the properties of nano crystal strongly
The studies of procion dye adsorption were performed by depend upon the dimension of nanoparticles [16].
batch adsorption method. The adsorption experiments were
conducted by varying initial concentration of procion dye
from 25 to 150 mg L-1, pH solution was adjusted over the
range pH 5-9 using HCl and NaOH 1 M, dosage of Fe3O4
from 0,5; 0,6; 0,7; 0,8; 0,9 and 1 g L-1 and contact time at 15,
30, 45, 60 and 75 minutes. Adsorption experiments were
carried out with a thermostatic shaker at 120 rpm.
Adsorption data analysis. The concentration retained in
color removal color (η,%) and adsorption capacity for Fe3O4,
qe (mg g-1), was determined by analyzing procion dye before
and after the treatment and calculated by using the eq.2. and
eq.3
(3)
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International Journal of Environmental Science and Development, Vol. 4, No. 3, June 2013
100
Momen Magnet (emu/gr)
80 30
-100
pH solution
Fig. 7. Effect pH solution procion dye
Field (tesla)
Fig. 5. Saturation Magnetization of Fe3O4 Fig. 8 shows effect of dosage Fe3O4 and contact time to
adsorb procion dye. The corresponding result showed that an
Fig. 5 shows the magnetization curve of Fe3O4 obtained by increased in adsorbent dosage could increase adsorption
VSM at 250C. The saturation magnetization of Fe3O4 capacity. With increasing adsorbent dosage, more surface
nanoparticles was 89.46 emu g-1. The magnetization of Fe3O4 area was available for adsorption due to the increase in active
is not far from the actual magnetization of the Fe3O4 is 92 site on the surface Fe3O4 and thus making easier penetration
emu g-1 [19]. The excellent magnetic responsivity was of adsorbate to adsorption. The dosage Fe3O4 to adsorb
necessary for magnetic separation from dye-containing procion dye at a fixed of 0.8 g L-1.
effluents in the future.
B. Optimum Condition Adsorption 30
Color removal (%)
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International Journal of Environmental Science and Development, Vol. 4, No. 3, June 2013
REFERENCE
Poedji Loekitowati Hariani was born in Madiun,
[1] U. Hafeli, W. Schutt, J. Teller, and M. Zborowski, Scientific and Indonesia, on August 27, 1968. In 1992 graduated with
Clinical Applications of Magnetic Microspheres, Plenum, New York, a scholar science in Chemistry Department, Gadjah
pp. 324-326, 1997. Mada University, Indonesia. In 1997 graduated from
[2] V. S. Zaitsev, D. S. Filimonov, I. A. Presnyakov, R. J. Gambino, and B. master of scince, field of environmental chemistry at
Chu, “Physical and Chemical Properties of Magnetite and Magnetite the Institute of Technology Bandung, Indonesia. At this
Polymer Nanoparticles and Their Colloidal Dispersions,” Journal time, she is study doctoral in the field of environmental
Colloid Interface Sci., vol. 212, pp. 49-57, 1999 scince at Sriwijaya University, Indonesia. She works
[3] B. A. Bolto, “Magnetic Particle Technology for Wastewater has a lecturer in the Chemistry Department, Faculty of
Treatment,” Waste Management, vol. 10, pp. 11-21, 1990 Mathematics and Science, Sriwijaya University, Palembang, Indonesia.
[4] A. B. Fuertes and P. Tartaj, “A Facile Route for the Preparation of Research carried out for this focus wastewater treatment.
Superparamagnetic Porous Carbon,” Chem. Mater, vol. 18, pp.
1675-1679, 2008.
[5] T. Yang, S. H. Zhu, D. Zhang, and S. H. Xu, “Synthesis and properties Muhammad Faizal was born in Palembang Indonesia
of magnetic Fe3O4-Activated Carbon Nanocomposite Particles for Dye on May 14, 1958. Currently he is working as a lecturer
Removal,” Mater. Lett., vol. 62, pp. 645-647, 2008. in the Department of Chemical Engineering, Faculty of
[6] M. Senthil and C. Ramesh, “Biogenic Syhthesis of Fe3O4 Engineering and at Graduate School Program (master
Nanoparticles using Tridax Procumbens leaf Extract and Its and doctor program) University of Sriwijaya. He has
Antibacterial Activity on Pseudomonas Aeruginosa,” Journal of completed formal education engineering degree in the
Nanomaterials and Biostructures, vol. 7, no. 3, pp. 1655-1660, 2012. Department of Chemical Engineering Faculty of
[7] S. Liong, “A Multifunctional Approach to Development, Fabrications Engineering, Sriwijaya University in 1983. She has
and Characterizations of Fe3O4 Composite,” Georgia Institut of completed a master's program in ENSCT-INPT
Technology, North Ave, Atlanta, Georgia, pp. 213-217, 2005. Toulouse France in 1988, and a doctoral program in the same university in
[8] S. E. Kentish and G. W. Stevens, “Innovation in Separations 1991. He is currently also active in the field of environment and energy
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Chem. Eng., vol. 84, pp. 149-159, 2001.
339
International Journal of Environmental Science and Development, Vol. 4, No. 3, June 2013
Ridwan was born in Prabumulih City, Indonesia, on 28 Dedi Setiabudidaya was born in Bandung, West Java
Juny 1959. Doctor of Science on Solid State Physics in 1960. His bachelor degree in Physics was from
from Kyoto University. At this time, Ridwan is a Bandung Institute of Technology, Indonesia in 1984.
professor in the field physics material and work at He obtained his M.Sc degree in Exploration
National Nuclear Energy Agency, Tangerang Selatan Geophysics from Department of Earth Sciences, the
15314, Indonesia. Currently, Prof. Dr. Ridwan is a University of Leeds, UK in 1987 and his PhD from
member of Indo-Asean Magnetic Material. Department of Earth Sciences (now Department of
Earth, Ocean and Ecological Sciences, School of
Environmental Sciences), the University of Liverpool,
UK in 1992. He has worked as a lecturer at Sriwijaya University, Indonesia
Marsi was born at Petanggan, East OKU, South since 1986.
Sumatra, Indonesia on July 14th, 1960. He was
graduated from Bogor Agricultural University,
Indonesia for his Bachelor Degree in field of Soil
Science in 1983. He got his Master Degree in 1989
and Ph.D Degree in 1992 both from University of
Kentucky, USA, in field of soil chemistry. He has
worked as a lecturer at Soil Science Department,
Faculty of Agriculture, Sriwijaya University since 1985. He is interested in
soil chemistry of swampy land for his focus research since one-third of South
Sumatera area was covered by swampy land. Currently, Dr. Marsi is a
member of Indonesian Soil Science Society.
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