F4 Chemistry Tutorial – Mole Calculation

Part 1
1. Given 9.6 g of ammonium carbonate (NH4)2CO3, calculate
(a) the number of moles of the compound.
(b) the number of moles of ammonium ions.
(c) the number of hydrogen atoms.
9.6 96
a.) no .
of moles of ( NH4 KC03 =
14×2 +1×8+16×3
=

96
= O 't mot
i

b.) CO32
'
of
-

mole ratio NH4 : is 2 :

I

of NH4
"
i. no , of moles :
0.1×2=0.2 not

C.) no , of H atoms = 0.8×6.02×10

"

=
4.82×10231
✓
,

(3 marks)
Watts OF
2. Given 2.84 g of sodium sulphate (Na2SO4), calculate
(a) the number of moles of compound,
(b) the number of ions.
2. 84
284
a.) no ,
of moles of (Naz 4) = =
= 0.02M "
↳ ×z +321+16×4 142.1

b.) .

.
'

one formula unit of Nai 504 has 3 ions

no of moles of of 0.02 mole
'

-
. .

Tons Naz
4=3×0.02--0.06 mot
,
I ,
no .
Of Tons =
0.06×6.02×1023

3.61
1027
=
X
,

✓
(3 marks)

1
 16 14
3. (a) If 1 g of 8O contains y atoms, how many atoms does 7 g of 7N contain?
no of mule =
no of formula unit
(Express your answer in terms of y.)
,

L
(b) If 1 mole of XO2 contains the same number of atoms as 60 g of XO3, what is the
molar mass of XO2?

to
'

a.) no ,
of moles of atoms in
1g 80 =
mot
:
y
=
Is × L ( L=
toy )
'
no , of moles of atoms in
7g IN =
Y4 =
at mot

'
of atoms
7g IN
i. no in
0.5×164 841
= =
,

b.) Let m be the relative atomic mass of X .

no , of atoms in
60g XO } =
bmtioxsx LX4
NO , of atoms in 1 mot XO z = IXLX 3

.
'

I XLX 3 =
MF4E × LX4

✓
.

m 32 132+16×2 ) (4 marks)
=

-1
i.
required molar mass =
64g not

4. (a) Find the percentage by mass of sodium and oxygen respectively in sodium
sulphate-10-water, Na2SO4 ∙ 10H2O.
Formula mass of Naz I0H , 0
4
.

= 23×2+32 I +16×4 .
t 1011×2+16 )
"

g mot
=
322 I .

II
'
Percentage by mass of Na =

,
× 100% =
14.3%

Percentage by mass of 0 =
'
II × 100% = 69.5%
✓
,

(b) Find the mass of water of crystallization in 64.4 g of sodium sulphate-10-water.

of water of
mass
crystallization
II
'
644 ×
✓
=

36g
=

,,

2
4. (c) Find the total mass of metal(s) in 100 g of KMnO4.
Total of metal in of KMN 04
100g
mass

391+54.9
= 100 ×
39.454.9 HN4
✓
59.5g "
=

(d) 2.8 g of a metal M combines with 1.2 g of oxygen to form an oxide with formula
M2O3. What is the relative atomic mass of M?
4Mt 302 >
214203
Let × be the relative atomic mass of M
I moi
.

'
NO ,
of mole of M =
.
①
of mole of
I
"
no ,
Oz =
= 0.0375 not ②
①
②
= 2¥
§ 0.0375=45 56
.
'

.
X =

(8 marks)
i.
relative atomic mass of M Is 564
5. (a) What is the empirical formula for a compound having 92.3% by mass of carbon
and 7.7% by mass of hydrogen?
assume the compound is
100g .

C H
mass Ig ) 92.3 7.70

of moles
no ,
( mot )
942=7.67 t.it = 7.7 ✓
mole ratio
t¥% =
I ¥192 I
The
i.
required Formula is CH .

(b) Given the relative molecular mass of the compound is 78.0, find the molecular
formula of the compound.
Let the molecular formula be KH1N .

(12+1) n = 78
i.

n =
the
13

= 6
(4 marks)
i. molecular formula =L formula ) to
Empirical
3
Catty
✓
=

,
 Part 2
1. 20.7 g of lead metal reacts with excess oxygen gas to form lead(II) oxide on strong
heating. What is the mass of this solid product formed?
(2 marks)
2 Pb t 02 > 21%0

no .
of mole of lead = II = 0.1 mot

no .
of mole of lead all oxide =
0.1 mot

Formula mass of lead C1D oxide =

207+16=223 mot
'
g

i. mass of lead 111 ) oxide

formed
0.1×223=22
=

3g ✓.

2. 3.90 g of potassium reacts with excess water. What is the mass of the hydrogen formed?
(2 marks)
2kt 2h20 >
LK0H 4HZ
a) Il) 1Gt
lag)

no ,
of mole of Potassium =
¥ ,
= 0.1 mot
of
no , of mole
hydrogen gas = 0.1×2 =
0.05 mod .

of
i. mass
hydrogen formed
0.05×2--0.14
-_

4
 Fez 03 C
3. To reduce 7.20 g of iron(III) oxide completely, how many grams of carbon is required?
(2 marks)
211203 +3C > 4E +30oz
Formula mass of Fez 03 55 8×2+16×3=159.6 mot
"
f
=
.

no , of mole of Fez 03 = 7.27 1596=0 045 mot .

.

no . of mole of C= 0.045×3 =
0.0675 Mol .

i. mass of C =

0.0675×12=0.8141 ,
✓

4. 3.60 g of magnesium is burnt in 4.00 g of oxygen gas.

(a) Write an equation for the reaction. (1 mark)

214g + Oz >
21480 ✓

4-
16×2
(b) Show by calculation which substance is the limiting reagent. (2 marks)
of mole of If
no
oxygen gas 0.125mV
=
, =

,
of of
no ,
mole
magnesium =

Is =
0 . 148 mob
,

"

:O
148 mot
Mg requires 0.148 XI 0.125mV )
0.074 mot 0dL
'
.
.

k is in excess
Mg is limited
,

if
, .

(c) Hence calculate the mass of product formed. (2 marks)

no . of mole of My = 0148 mot
no of mole of 0.148 mot
MG0
,

mass of HG0 = 0,1481243+16 )

=

5.96g , ,

5
Given: L = 6.02 1023