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PROBEM 2

a) α values
Temp alpha vs t
time 826°C 900°C 1020°C 0.300
1 0.035 0.05 0.1 0.250
2 0.076 0.15 0.18
0.200
3 0.106 0.14 0.22
4 0.13 0.17 0.24 0.150
5 0.148 0.192 0.255 0.100
6 0.16 0.21 0.262
0.050
7 0.178 0.23 0.27
0.000
0 1 2 3 4 5 6 7 8

b) Plot g(α) v/s t


g(α) values =1-(2/3*α)-((1-α)^(2/3))
Temp
time 826°C 900°C 1020°C
0 0 0 0
1 0.000138273 0.000284 0.001164
2 0.000664468 0.002683 0.003922
3 0.001311175 0.002326 0.005983
4 0.001995286 0.003481 0.007197
5 0.002609215 0.00449 0.008191
6 0.003067874 0.005423 0.00868
7 0.003831811 0.006574 0.009259
c) Plot ln k v/s 1/T
From the plot of g(α) v/s t we get slope i.e. k rate constant as shown in table below. Then we plotted ln k v/s 1/T
which is known as Arrhenius Plot.
Slope of ln k v/s 1/T will give value of activation energy.

Temp
826°C 900°C 1020°C
k 0.0005 0.0009 0.0015
lnk -7.60090246 -7.01312 -6.50229
1/T 0.000909918 0.000853 0.000773

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