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Chemistry Sk025 SESSION 2019/2020 Topic: Thermochemistry

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SET 1

CHEMISTRY SK025
SESSION 2019/2020
TOPIC : THERMOCHEMISTRY

Name : _______________________________________ Class : ______________

Answer all the questions.

PART A (5 marks)

1. What will be observed when solid A (50ºC) is placed in contact with solid B (80ºC)?
A. Heat energy flows from A to B, thus the average kinetic energy of the particles in
A decreases.
B. Heat energy flows from A to B, thus the average kinetic energy of the particles in
A increase.
C. Heat energy flows from B to A, thus the average kinetic energy of the particles in
B decreases.
D. Heat energy flows from B to A, thus the average kinetic energy of the particles in
B increases.

2. Of the following, ∆ H of is not zero for __________.

A O2(g) D
B. N2(g) C. F2 (s) Cl2(g)
. .

3. For which one of the following equations gives ∆ H orxn equal to ∆ H of for the product?
A. Xe (g) + 2F2 (g) XeF4 (g)
B. CH4 (g) +2Cl2 (g) CH2Cl2 (l) + 2HCl (g)
C. N2 (g) + O3 (g) N2O3 (g)
D. 2CO (g) +O2 (g) 2CO2 (g)

1
SET 1

4. The value of ∆ H o❑ for the reaction below is -126 kJ. Thus __________ kJ are released
when 2.00 mol of NaOH is formed in the reaction?
2Na2O2 (s) + 2H2O (l) 4NaOH (s) + O2 (g)

A -126 B. 252 C. 63 D. 31.5


.

5. Given below are the thermochemical equation for areaction and data of ∆ H of of each
substance involved.

SO2Cl2 (g) +2H2O (l) H2SO4 (l) + 2HCl (g) ∆ H orxn = -62 kJ

Substance ∆ H of (kJ /mol)


SO2 (g) -297
SO3 (g) -396
SO2Cl2 (g) -364
H2SO4 (l) -814
H2O (l) -286

Find ∆ H of of HCl (g) in kJ mol-1.

A -184 B. 60 C. -92 D. 30
.

PART B (15 marks)

1. A 45.5 g sample of copper at 99.8 oC is dropped into a beaker containing 152 g of water at
18.5 oC. What will be the final temperature of copper-water mixture?
(Specific heat capacity : copper is 0.385 J g-1 oC-1 and water 4.18 J g-1 oC-1)
[2 marks]

2. A 100 mL of 0.200 M CsOH is added to 50.00 mL of 0.400 M HCl in a coffee-cup


calorimeter. The following reaction occurs.

2
SET 1

CsOH (aq) + HCl (aq) CsCl (aq) + H2O (l)

The temperature of both solutions before mixing was 22.50 oC, and it rose to 24.28 oC when
the reaction take placed.
a. What is the enthalpy of the reaction per mole of CsOH?
(Assume the densities of the solutions are all 1.00 g mL-1 and the specific heat capacities
of the solutions are 4.21 J g-1 oC-1)
b. Write the balanced thermochemical equation.
c. Sketch the energy profile diagram of the reaction.
[9 marks]

3. The standard enthalpy of formation of solid barium oxide, BaO, is -553.5 kJ mol-1 and the
enthalpy of formation of barium peroxide, BaO2, is -634.3 kJ mol-1. Sketch an energy cycle
diagram and calculate the standard enthalpy change for the following reaction.

1
BaO (s) + O2 (g) BaO2 (s) [4 marks]
2

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