SAFETY DATA SHEET

VELOPEX READY TO USE FIXER

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier

Product Name VELOPEX READY TO USE FIXER
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified Uses X-Ray Fixer, Photographic Chemical.
Uses Advised Against
1.3 Details of the supplier of the safety data sheet
Supplier Medivance Instruments Ltd.
Barretts Green Road
Harlesden
London
NW10 7AP
T +44 (0) 20 8965 2913
F +44 (0) 20 8963 1270
enquiries@velopex.com
1.4 Emergency telephone number
020 8965 2913

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (EC 1272/2008)
Serious eye damage/irritation - Category 2
2.2 Label elements
Labelling

Signal Word Warning

Hazard Statements
H319 Causes serious eye irritation
Precautionary Statements
P264 Wash...thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
2.3 Other hazards
May cause respiratory tract irritation
May be harmful if swallowed

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SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Mixtures

Weight in
Ingredient EC (EINECS) No. CLP Classification
Product (% w/w)
Acetic Acid <1.0% 200-580-7 Danger
CAS No. 64-19-7 Skin Corrosive Cat.1A; H314
Sodium Borate <1.0% 215-540-4 Reproductive toxicity Cat.1B; H360FD
CAS No. 1303-96-4
Aluminium Sulphate 1-2% 233-135-0 Danger
CAS No. 10043-01-3 Serious eye damage Cat.1; H318
Ammonium Thiosulphate 10-15% 231-982-0 Not classified
CAS No. 7783-18-8
Sodium Sulphite 1-2% 231-821-4 Not classified
CAS No. 7757-83-7

Important Note: The classification descriptions given in this section relate to the components in their pure form and do not
correspond to the classification of this preparation. The classification of this product as supplied is given in Section 2.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

Inhalation
Remove fresh air and rest. If recovery is not rapid, obtain prompt medical attention,
Ingestion
Do not induce vomiting. Give plenty of water to drink. Beware of aspiration if vomiting occurs. Seek medical attention immediately.
Skin Contact
Remove contaminated clothing. Wash with soap/cleanser and rinse with plenty of water. If irritation persists, get medical attention.
Eye Contact
Irrigate with water for at least 15 minutes. If irritation persists, then consult a doctor.
4.2 Most important symptoms and effects, both acute and delayed
Inhalation
Some asthmatics or sulphite sensitive individuals may experience wheezing, chest tightness, stomach upset, hives, faintness, weak-
ness and diarrhoea. May cause irritation of the respiratory tract. May be harmful if inhaled.
Ingestion
May be harmful if swallowed. Some asthmatics or sulphite sensitive individuals may experience wheezing, chest tightness, stomach
upset, hives, faintness, weakness and diarrhoea.
Skin Contact
May cause irritation.
Eye Contact
May cause irritation
4.3 Indication of any immediate medical attention and special treatment needed
Note to physician. Treat symptomatically.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Extinguishing Media
Non-flammable material as supplied. Use fire extinguishing media appropriate for surrounding materials. Extinguish with foam,
carbon dioxide, dry powder or water fog.
5.2 Special hazards arising from the substance or mixture
Hazardous Combustion Products
Toxic fumes are produced when substance is involved in a fire.
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5.3 Advice for firefighters
Protective Measures In Fire
Use protective equipment appropriate for surrounding materials.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 personal precautions, protective equipment and emergency procedures

Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Wear rubber gloves/eye protection as necessary.
6.2 Environmental precautions
Do not allow spill to enter drains, sewers or water courses.
6.3 Methods and material for containment and cleaning up
Isolate the spillage and absorb with inert material (e.g. sand, earth, diatomaceous earth, vermiculite or absorbent granules). Scoop
up and place in a plastic container for disposal according to local/national regulations.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Avoid inhalation of vapour. Ensure adequate ventilation. Avoid skin contact. Avoid eye contact. Wear suitable protective clothing.
7.2 Conditions for safe storage, including any incompatibilities
Store in tightly closed labelled containers. Store in a cool, dry, well ventilated area. Store away from foodstuffs. Store away from
acids, strong bases, oxidising agents and halogenated compounds. Keep out of reach of children/store under lock and key.
Recommended storage temperature 5-25°C.
Contact with strong acids liberates sulphur dioxide.
Contact with strong bases liberates ammonia.
Contact with sodium hypochlorite (bleach) may form chloramine (toxic gas).
7.3 Specific end use(s)
X-Ray Fixer

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Name STD TWA - 8 Hrs STEL - 15 Min Notes

Acetic Acid WEL 10 ppm 15 ppm

WEL = Workplace Exposure Limit

8.2 Exposure controls
Protective Equipment

Hand Protection
Wear Nitrile rubber gloves.
Eye Protection
Wear approved, tight fitting safety glasses where splashing is probable.
Hygiene Measures
If skin is contaminated, wash off immediately.
Skin Protection
Wear suitable protective clothing as protection against splashing or contamination.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance Colourless liquid pH 4-5
Odour Slightly pungent Boiling Point/range >100°C
(Acetic Acid/Sulphur Dioxide)
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Melting Point/range n/a Relative Density 1.092
Flash Point n/a Solubility Completely soluble in water
Flammability Non-flammable Partition Coefficient n/a
Auto Flammability n/a Miscibility Completely miscible in water
Explosive Properties n/a Vapour Density n/a
Oxidising Properties None Evaporation Rate n/a
Vapour Pressure n/a Viscosity n/a
n/a = not applicable
9.2 Other information

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
No dangerous reaction known under normal use conditions.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazard reactions
Oxidising agents. Contact with strong acids liberates sulphur dioxide. Contact with strong bases liberates ammonia. Contact with
sodium hypochlorite (bleach) may form chloramine (toxic gas).
10.4 Conditions to avoid
High temperatures.
10.5 Incompatible materials
Materials To Avoid
Oxidising agents, strong acids, strong bases. Halogenated compounds.
10.6 Hazardous decomposition products
None when stored and handled correctly.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute Toxicity (Oral LD50) No information available
Acute Toxicity (Dermal LD50) No information available
Acute Toxicity (Inhalation LC50) No information available
Inhalation
Some asthmatics or sulphite sensitive individuals may experience wheezing, chest tightness, stomach upset, hives, faintness, weak-
ness and diarrhoea. May cause irritation of respiratory tract. May be harmful if inhaled.
Ingestion
May be harmful if swallowed. Some asthmatics or sulphite-sensitive individuals may experience wheezing, chest tightness, stomach
upset, hives, faintness, weakness and diarrhoea.
Skin Contact
May cause irritation.
Eye Contact
May cause eye irritation.
Acute Toxicity - Component Information

Chemical Name LD50 Oral LD50 Dermal LD50 Inhalation

Ammonium Thiosulphate >2000mg/kg (Rat)
Acetic Acid 3310 mg/kg (Rat) 1060 mg/kg (Rabbit) 11.4 mg/L (Rat) 4h
Sodium Sulphite 820 mg/kg (Rat) 22 mg/L (Rat) 1h
5.5 mg/L (Rat) 4h
Sodium Borate 2403 mg/kg (Rat) 2000 mg/kg (Rabbit)
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Acetic Acid Cont. Severe eye irritation.
Severe skin irritation. Acute overexposure to extremely high airborne concentrations of
respiratory irritants has been associated with development of an asthma-like reactive airways
syndrome (RADS) in susceptible individuals. Extremely high airborne concentrations are not
generated during normal conditions of use but may occur following a spill. The potential to
generate extremely high airborne concentrations in a spill situation depends upon physical
factors such as the concentration of the solution, the volume of the spill, the surface area of
the spill, the size of the room where the spill occurred and the ventilation rate in the room.
Sodium Sulphite No skin irritation.
Mild eye irritation.
Sodium Borate Based on repeated-dose ingestion studies in animals, may cause adverse reproductive and
developmental effects. However the doses administered were many times those to which
humans would normally be exposed.
Aggravated Medical Conditions
Pre-existing eye disorders, skin disorders, respiratory disorders.
Subchronic Toxicity
No data available.
Chronic Toxicity Prolonged exposure may cause chronic effects.
Sensitisation No information available.
Neurological Effects No information available.
Target Organ Effects Eyes, skin, respiratory system, teeth.
CMR Effects
Carcinogenicity Contains no ingredient listed as a carcinogen.
Reproductive Toxicity Contains a known or suspected reproductive toxin. However, based on available data the
product should not be classified for reproductive effects.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity
The environmental impact of this product has not been fully investigated.
12.1 Toxicity
Acute Aquatic Toxicity - Product Information
No information available.
Acute Aquatic Toxicity - Component Information

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia and Other
Aquatic Invertebrates
Acetic Acid LC50 = 79 mg/L (Pimephales EC50 = 47 mg/L
Promelas) 96h (Daphnia Magna) 24h
LC50 = 75 mg/L EC50 = 65mg/L
(Lepomis Macrochirus) 96h (Daphnia Magna) 48h
Sodium Sulphite LC50 = 220 - 460 mg/L LC50 = 330 mg/L
(Leuciscus Idus) 96h (Psammechinus Miliaris) 24h
Sodium Borate EC50 = 158 mg/L LC50 = 340 mg/L LC50 = 1085-1402 mg/L
(Desmodesmus subspicatus) 96h (Limanda Limanda) 96h (Daphnia Magna) 48h
EC50 = 2.6-21.8 mg/L
(Pseudokirchneriella subcapitata) 96h

12.2 Persistence and degradability

Degradability
Expected to be readily biodegradable.
12.3 Bioaccumulative potential
Bioaccumulative Potential
No information available.

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 Chemical Name log Pow
Acetic Acid -0.31
Sodium Sulphite -4

12.4 Mobility in soil

Mobility
No information available.
12.5 Results of PBT and vPvB assessment

12.6 Other adverse effects

No information available.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Do not discharge into drains or watercourses. Dispose of through an authorised contractor to a licensed landfill site. Dispose of in
accordance with Local Authority regulations.
Do not reuse empty containers. Dispose of in accordance with local regulations.

SECTION 14: TRANSPORT INFORMATION

14.1 UN number
ADR/RID Not regulated ADN Not regulated
IMDG/IMO Not regulated TDG Not regulated
ICAO/IATA Not regulated

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislations specific for the substance or mixture
EU Legislation
Labelling according to Regulation (EC) No 1272/2008 GHS label elements.
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has not been carried out.

SECTION 16: OTHER INFORMATION

Revision Comments

Issued By Chemistry Manager

Revision Date 01/06/2015
Revision GHS1
Hazard Statements In Full
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage.
H360 May damage fertility or the unborn child.

Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as
of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the
user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

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