SAFETY DATA SHEET

Shell Rimula Light Duty LD4 Multi 15W-40

Version 1.3 Revision Date 01/13/2021 Print Date 01/14/2021

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name : Shell Rimula Light Duty LD4 Multi 15W-40

Product code : 001G7121

Manufacturer or supplier's details

Manufacturer/Supplier : Altipal S.A.
Cr 69B No 19A-47
Bogotá
Colombia
Telephone : +57 1 2948383
Telefax : +57 1 2948383

Emergency telephone : 018000123344

number

Recommended use of the chemical and restrictions on use

Recommended use : Engine oil.

2. HAZARDS IDENTIFICATION

Based on available data this substance / mixture does not meet the classification criteria.

Label elements

Safety data sheet available on request.

Hazard pictograms : No Hazard Symbol required

Signal word : No signal word

Hazard statements : PHYSICAL HAZARDS:

Not classified as a physical hazard according to CLP criteria.
HEALTH HAZARDS:
Not classified as a health hazard under CLP criteria.
ENVIRONMENTAL HAZARDS:
Not classified as environmental hazard according to CLP
criteria.

Precautionary statements : Prevention:

No precautionary phrases.
Response:
No precautionary phrases.
Storage:
No precautionary phrases.
Disposal:

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No precautionary phrases.

Other hazards
Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities.
Not classified as flammable but will burn.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Highly refined mineral oils and additives.

The highly refined mineral oil contains <3% (w/w) DMSO-
extract, according to IP346.
Classification based on DMSO extract content < 3%
(Regulation (EC) 1272/2008, Annex VI, Part 3, Note L).

: * contains one or more of the following CAS-numbers: 64742-

53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9, 68649-12-7, 151006-60-9, 163149-28-8.

Hazardous components
Chemical name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (REGULATION (% w/w)
Registration (EC) No
number 1272/2008)
Zinc 68784-31-6 Xi-N; R41- Eye Dam. 1; H318 < 1,25
dialkyldithiophosphate R51/53 Aquatic Chronic 2;
H411
Zinc dialkyl 84605-29-8 Xi-N; R38-R41- Skin Irrit. 2; H315 < 1,25
dithiophosphate R51/53 Eye Dam. 1; H318
Aquatic Chronic 2;
H411
Calcium alkaryl Not Assigned Xi; R43 Skin Sens. 1B; < 0,9
sulphonate ** R53 H317
Aquatic Chronic 4;
H413
Calcium alkaryl Not Assigned Xi; R43 Skin Sens. 1B; < 0,9
sulphonate** H317
Calcium sulphonate 70024-69-0 Xi; R43 Skin Sens. 1B; < 0,9
H317
Interchangeable low Not Assigned Asp. Tox. 1; H304 0 - 90
viscosity base oil
(<20,5 cSt @40°C) *
** polymer exempt.
For explanation of abbreviations see section 16.
Further information

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NFPA Rating (Health, Fire, 0, 1, 0

Reactivity)

4. FIRST-AID MEASURES

If inhaled : No treatment necessary under normal conditions of use.

If symptoms persist, obtain medical advice.

In case of skin contact : Remove contaminated clothing. Flush exposed area with
water and follow by washing with soap if available.
If persistent irritation occurs, obtain medical attention.

In case of eye contact : Flush eye with copious quantities of water.

Remove contact lenses, if present and easy to do. Continue
rinsing.
If persistent irritation occurs, obtain medical attention.

If swallowed : In general no treatment is necessary unless large quantities

are swallowed, however, get medical advice.

Most important symptoms : Oil acne/folliculitis signs and symptoms may include formation
and effects, both acute and of black pustules and spots on the skin of exposed areas.
delayed Ingestion may result in nausea, vomiting and/or diarrhoea.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Flammable properties
Flash point : 230 °C / 446 °F
Method: ASTM D92 (COC)

Ignition temperature : >

320 °C / 608 °F

Upper explosion limit : Typical 10 %(V)

Lower explosion limit : Typical 1 %(V)
Flammability (solid, gas) : Data not available

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.

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Unsuitable extinguishing : Do not use water in a jet.

media

Specific hazards during : Hazardous combustion products may include:

firefighting A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Carbon monoxide may be evolved if incomplete combustion
occurs.
Unidentified organic and inorganic compounds.

Specific extinguishing : Use extinguishing measures that are appropriate to local

methods circumstances and the surrounding environment.

Special protective equipment : Proper protective equipment including chemical resistant

for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Avoid contact with skin and eyes.

protective equipment and
emergency procedures
Environmental precautions : Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Slippery when spilt. Avoid accidents, clean up immediately.
containment and cleaning up Prevent from spreading by making a barrier with sand, earth
or other containment material.
Reclaim liquid directly or in an absorbent.
Soak up residue with an absorbent such as clay, sand or other
suitable material and dispose of properly.

Additional advice : For guidance on selection of personal protective equipment

see Section 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Section 13 of
this Safety Data Sheet.

7. HANDLING AND STORAGE

General Precautions : Use local exhaust ventilation if there is risk of inhalation of

vapours, mists or aerosols.
Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.

Advice on safe handling : Avoid prolonged or repeated contact with skin.

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Avoid inhaling vapour and/or mists.

When handling product in drums, safety footwear should be
worn and proper handling equipment should be used.
Properly dispose of any contaminated rags or cleaning
materials in order to prevent fires.

Avoidance of contact : Strong oxidising agents.

Product Transfer : Proper grounding and bonding procedures should be used

during all bulk transfer operations to avoid static accumulation.

Storage
Other data : Keep container tightly closed and in a cool, well-ventilated
place.
Use properly labeled and closable containers.

Store at ambient temperature.

Packaging material : Suitable material: For containers or container linings, use mild
steel or high density polyethylene.
Unsuitable material: PVC.

Container Advice : Polyethylene containers should not be exposed to high

temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Oil mist, mineral Not Assigned TWA 5 mg/m3 US. ACGIH
(inhalable Threshold
fraction) Limit Values
Oil mist, mineral Not Assigned TWA 5 mg/m3 Colombia
(inhalable OELs.
fraction) Resolution
No. 02400:
Norms
Concerning
Working
Conditions,
Health and
Safety in the
Workplace
Biological occupational exposure limits
No biological limit allocated.

Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general

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workplace may be required to confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and
samples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or
contact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil

Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Adequate ventilation to control airborne concentrations.

Where material is heated, sprayed or mist formed, there is

greater potential for airborne concentrations to be generated.

General Information:
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or
maintenance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.
Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard
contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

Personal protective equipment

Protective measures
Personal protective equipment (PPE) should meet recommended national standards. Check with
PPE suppliers.

Respiratory protection : No respiratory protection is ordinarily required under normal

conditions of use.
In accordance with good industrial hygiene practices,
precautions should be taken to avoid breathing of material.

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If engineering controls do not maintain airborne

concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are suitable, select an
appropriate combination of mask and filter.
Select a filter suitable for the combination of organic gases
and vapours and particles [Type A/Type P boiling point >65°C
(149°F)].

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. PVC, neoprene or nitrile rubber
gloves Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, dexterity. Always seek advice
from glove suppliers. Contaminated gloves should be
replaced. Personal hygiene is a key element of effective hand
care. Gloves must only be worn on clean hands. After using
gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.

For continuous contact we recommend gloves with

breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model.

Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.

Skin and body protection : Skin protection is not ordinarily required beyond standard
work clothes.
It is good practice to wear chemical resistant gloves.

Thermal hazards : Not applicable

Environmental exposure controls

General advice : Take appropriate measures to fulfill the requirements of
relevant environmental protection legislation. Avoid
contamination of the environment by following advice given in
Section 6. If necessary, prevent undissolved material from
being discharged to waste water. Waste water should be
treated in a municipal or industrial waste water treatment plant

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before discharge to surface water.

Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : Clear amber

Odour : Data not available
Odour Threshold : Data not available
pH : Not applicable
pour point : -36 °C / -33 °FMethod: ASTM D97

Melting / freezing point Data not available

Boiling point : Data not available
Flash point : 230 °C / 446 °F
Method: ASTM D92 (COC)

Evaporation rate : Data not available

Flammability (solid, gas) : Data not available

Upper explosion limit : Typical 10 %(V)

Lower explosion limit : Typical 1 %(V)

Vapour pressure : < 0,5 Pa (20 °C / 68 °F)

estimated value(s)
Relative vapour density : > 1estimated value(s)
Relative density : 0,881 (15,0 °C / 59,0 °F)

Density : 881 kg/m3 (15,0 °C / 59,0 °F)

Method: ASTM D4052

Solubility(ies)
Water solubility : negligible
Solubility in other solvents : Data not available

Partition coefficient: n- : log Pow: > 6(based on information on similar products)

octanol/water
Auto-ignition temperature : > 320 °C / 608 °F

Decomposition temperature : Data not available

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Viscosity
Viscosity, dynamic : Data not available
Viscosity, kinematic : 14,7 mm2/s (100 °C / 212 °F)
Method: ASTM D445

109 mm2/s (40,0 °C / 104,0 °F)

Method: ASTM D445

Explosive properties : Not classified

Oxidizing properties : Data not available

Conductivity : This material is not expected to be a static accumulator.

10. STABILITY AND REACTIVITY

Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.

Chemical stability : Stable.

Possibility of hazardous : Reacts with strong oxidising agents.

reactions
Conditions to avoid : Extremes of temperature and direct sunlight.

Incompatible materials : Strong oxidising agents.

Hazardous decomposition : No decomposition if stored and applied as directed.

products

11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on data on the components and
the toxicology of similar products.Unless indicated otherwise,
the data presented is representative of the product as a
whole, rather than for individual component(s).

Information on likely routes of : Skin and eye contact are the primary routes of exposure
exposure although exposure may occur following accidental ingestion.

Acute toxicity
Product:
Acute oral toxicity : LD50 rat: > 5.000 mg/kg
Remarks: Low toxicity:
Based on available data, the classification criteria are not met.

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Acute inhalation toxicity : Remarks: Based on available data, the classification criteria
are not met.

Acute dermal toxicity : LD50 Rabbit: > 5.000 mg/kg

Remarks: Low toxicity:
Based on available data, the classification criteria are not met.

Skin corrosion/irritation
Product:
Remarks: Slightly irritating to skin., Prolonged or repeated skin contact without proper cleaning
can clog the pores of the skin resulting in disorders such as oil acne/folliculitis., Based on
available data, the classification criteria are not met.

Serious eye damage/eye irritation

Product:
Remarks: Slightly irritating to the eye., Based on available data, the classification criteria are not
met.

Components:
Zinc dialkyldithiophosphate:
Remarks: Based on available data, the classification criteria are not met.

Zinc dialkyl dithiophosphate:

Remarks: Based on available data, the classification criteria are not met.

Respiratory or skin sensitisation

Product:
Remarks: Not a skin sensitiser.
Based on available data, the classification criteria are not met.

Components:
Calcium alkaryl sulphonate **:
Remarks: May cause an allergic skin reaction in sensitive individuals.

Calcium sulphonate:
Remarks: May cause an allergic skin reaction in sensitive individuals.

Germ cell mutagenicity

Product:
Remarks: Non mutagenic, Based on available data, the
classification criteria are not met.
Carcinogenicity
Product:

Remarks: Not a carcinogen., Based on available data, the classification criteria are not met.

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Remarks: Product contains mineral oils of types shown to be non-carcinogenic in animal skin-
painting studies., Highly refined mineral oils are not classified as carcinogenic by the
International Agency for Research on Cancer (IARC).

Material GHS/CLP Carcinogenicity Classification

Highly refined mineral oil No carcinogenicity classification.

Reproductive toxicity

Product:

Remarks: Not a developmental toxicant., Does not impair

fertility., Based on available data, the classification criteria are
not met.

STOT - single exposure

Product:
Remarks: Based on available data, the classification criteria are not met.

STOT - repeated exposure

Product:
Remarks: Based on available data, the classification criteria are not met.

Aspiration toxicity
Product:
Not an aspiration hazard.

Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumulated during use. The
concentration of such impurities will depend on use and they may present risks to health and the
environment on disposal., ALL used oil should be handled with caution and skin contact avoided
as far as possible.

Remarks: Continuous contact with used engine oils has caused skin cancer in animal tests.

Remarks: Slightly irritating to respiratory system.

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12. ECOLOGICAL INFORMATION

Basis for assessment : Ecotoxicological data have not been determined specifically
for this product.
Information given is based on a knowledge of the components
and the ecotoxicology of similar products.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).(LL/EL/IL50 expressed as the
nominal amount of product required to prepare aqueous test
extract).

Ecotoxicity
Product:
Toxicity to fish (Acute :
toxicity) Remarks: LL/EL/IL50 > 100 mg/l
Practically non toxic:
Based on available data, the classification criteria are not met.

Toxicity to crustacean (Acute :

toxicity) Remarks: LL/EL/IL50 > 100 mg/l
Practically non toxic:
Based on available data, the classification criteria are not met.

Toxicity to algae/aquatic :
plants (Acute toxicity) Remarks: LL/EL/IL50 > 100 mg/l
Practically non toxic:
Based on available data, the classification criteria are not met.

Toxicity to fish (Chronic : Remarks: Data not available

toxicity)
Toxicity to crustacean : Remarks: Data not available
(Chronic toxicity)
Toxicity to microorganisms : Remarks: Data not available
(Acute toxicity)

Persistence and degradability

Product:
Biodegradability : Remarks: Not readily biodegradable., Major constituents are
inherently biodegradable, but contains components that may
persist in the environment., Persistent per IMO criteria.,
International Oil Pollution Compensation (IOPC) Fund
definition: “A non-persistent oil is oil, which, at the time of
shipment, consists of hydrocarbon fractions, (a) at least 50%
of which, by volume, distills at a temperature of 340ºC (645ºF)
and (b) at least 95% of which, by volume, distils at a
temperature of 370ºC (700ºF) when tested by the ASTM
Method D-86/78 or any subsequent revision thereof."

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Contains components with the potential to

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bioaccumulate.

Partition coefficient: n- : log Pow: > 6Remarks: (based on information on similar

octanol/water products)
Mobility in soil
Product:
Mobility : Remarks: Liquid under most environmental conditions., If it
enters soil, it will adsorb to soil particles and will not be
mobile.
Remarks: Floats on water.
Other adverse effects
no data available
Product:
Additional ecological : Does not have ozone depletion potential, photochemical
information ozone creation potential or global warming potential., Product
is a mixture of non-volatile components, which will not be
released to air in any significant quantities under normal
conditions of use.
Poorly soluble mixture., Causes physical fouling of aquatic
organisms.
Mineral oil does not cause chronic toxicity to aquatic
organisms at concentrations less than 1 mg/l.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal
methods in compliance with applicable regulations.
Do not dispose into the environment, in drains or in water
courses

Waste product should not be allowed to contaminate soil or

ground water, or be disposed of into the environment.
Waste, spills or used product is dangerous waste.
Waste arising from a spillage or tank cleaning should be
disposed of in accordance with prevailing regulations,
preferably to a recognised collector or contractor. The
competence of the collector or contractor should be
established beforehand.
Do not dispose of tank water bottoms by allowing them to
drain into the ground. This will result in soil and groundwater
contamination.

MARPOL - see International Convention for the Prevention of

Pollution from Ships (MARPOL 73/78) which provides
technical aspects at controlling pollutions from ships.

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Contaminated packaging : Dispose in accordance with prevailing regulations, preferably

to a recognized collector or contractor. The competence of
the collector or contractor should be established beforehand.
Disposal should be in accordance with applicable regional,
national, and local laws and regulations.

Local legislation
Remarks : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.

14. TRANSPORT INFORMATION

International Regulations
ADR
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied. MARPOL Annex 1 rules apply for bulk shipments by sea.

Special precautions for user

Remarks : Special Precautions: Refer to Section 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
The regulatory information is not intended to be comprehensive. Other regulations may apply to
this material.
Other international regulations
The components of this product are reported in the following inventories:
EINECS : Not established.
TSCA : All components listed.

16. OTHER INFORMATION

Full text of R-Phrases

R38 Irritating to skin.

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R41 Risk of serious damage to eyes.

R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.

Full text of H-Statements

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.

Full text of other abbreviations

Aquatic Chronic Long-term (chronic) aquatic hazard
Asp. Tox. Aspiration hazard
Eye Dam. Serious eye damage
Skin Irrit. Skin irritation
Skin Sens. Skin sensitisation

Abbreviations and Acronyms : The standard abbreviations and acronyms used in this
document can be looked up in reference literature (e.g.
scientific dictionaries) and/or websites.

SDS Regulation : Regulation 1907/2006/EC

Further information
Training advice : Provide adequate information, instruction and training for
operators.

Other information : A vertical bar (|) in the left margin indicates an amendment
from the previous version.

Sources of key data used to : The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers’ data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).

This information is based on our current knowledge and is intended to describe the product for
the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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