Sample CEP PP
Sample CEP PP
Sample CEP PP
Contents
Abstract ........................................................................................................................................... 3
1. Introduction ............................................................................................................................. 3
2. Standards of Emissions ........................................................................................................... 5
2.1. Global Emission Standards .............................................................................................. 5
2.1.1. United States of America .......................................................................................... 5
2.1.2. Europian Union ......................................................................................................... 6
2.1.3. Japan ......................................................................................................................... 7
2.2. National Emission Standards ........................................................................................... 7
2.3. Provincial Emission Standards ......................................................................................... 8
3. Clean Coal Technologies ........................................................................................................ 8
3.1. Review of Clean Coal Technologies ................................................................................ 8
3.1.1. Carbon Capture and Storage ..................................................................................... 8
3.1.1.1. Absorption ............................................................................................................. 9
3.1.1.2. Adsorption ............................................................................................................. 9
3.1.1.3. Membrane Gas Separation .................................................................................... 9
3.1.2. High Efficiency Low Emission Technology............................................................. 9
3.1.2.1. Subcritical Boiler Technology .............................................................................. 9
3.1.2.2. Supercritical Boiler Technology ........................................................................... 9
3.1.2.3. Ultra Supercritical Boiler Technology .................................................................. 9
3.1.2.4. Advanced Ultra Supercritical Boiler Technology ............................................... 10
3.1.3. Mineral Washing ..................................................................................................... 10
3.1.4. Wet Scrubbers/Flu Gas desulfurization .................................................................. 10
3.1.5. Low NOx Burners ................................................................................................... 10
3.1.6. Electrostatic Precipitators ....................................................................................... 10
3.1.7. Integrated Gassification Combined Cycle .............................................................. 10
3.1.8. Flu Gas Separation .................................................................................................. 10
3.2. Technologies Best-Suited for Pakitani Coal .................................................................. 10
4. Technical Evaluation of Using Pakistani Coal in Place of Imported Coal ........................... 12
4.1. Selection of Techology - Underground Coal Gasification combined with Integrated Coal
Gasification Combined Cycle (UCG-IGCC) ............................................................................ 12
4.2. Extraction of Coal Gas without Mining ......................................................................... 12
Abstract
Pakistan is a country rich in coal resources with around 185 million tonnes reserves. But most of
the coal is of lignite quality and therefore not suitable for the coal power plants economically and
technically. The coal-based power plants in Pakistan work on imported coal despite the vast
reserves of local coal present. In this work, a brief review of the global, national and provincial
standards that define the emission limits of the coal power plants and the various clean coal
techniques are presented. A comprehensive study is conducted to determine the potential
utilization of local in place of imported coal. The underground coal gasification with integrated
coal gasification combine cycle (UCG-IGCC) is found to be a suitable alternate for the utilization
of local coal. The technology is able to use the local low-quality coal efficiently and in an
environmentally friendly way. The technology can be combined with carbon capture technology
to decrease the CO2 emissions to negligible amount. The technology is also able to keep the
emission under the national and provincial standards of Pakistan and possess economic benefits.
It eradicates the need of conventional mining procedures and enhances the safety of the process.
1. Introduction
Due to the increasing demand of energy, earth is being depleted of its natural resources. According
to the Energy Information Administration (US), the total energy demand increases by 56%
between 2010 to 2040. Fossil fuels will continue to fulfill almost 80% of the World’s energy
demand through 2040 [1] but contribute to greenhouse gas emissions. Greenhouse gases absorb
incident solar energy and re-radiate it in the atmosphere leading to global warming [2]. At the
earlier time, man used to get heat by burning wood and stones but since most the burning was done
on small extent in open air, so the impact was small. With increase in population the extent of
burning fuels to get energy increased. The first episodes of smog were observed in Donora, USA
in 1948. The city got trapped under a thick layer of grey smog trapping the pollutants in it. The
14000 residents suffered from severe cardiovascular and respiratory syndromes and the death rate
rose to 40. The onset of smog was a clear indication of the rapid industrialization in the country.
The second most adverse effect was observed in London, UK. The industrial revolution of UL was
based on the utilization of coal in the 18th and 19th century. The greater London smog of 1952 was
observed by the whole world as an alarm to the health conditions, causing 4000 deaths [3].
Following the two incidents, the “Clean Air Act” of 1956 and 1968 was passed by the
governmental bodies to regulate the industrial pollution. It focused on the construction of higher
chimneys to disperse the pollutants in the upper atmosphere for their easy dispersal. In the second
world war, the extensive use of dispersion techniques relying on gaseous chemicals such as
Phosgene gas also elevated the environmental pollution. In 1980’s, the rapid expansion of
automotive industry became the prevalent cause of degradation of air quality. In 1995, “National
Air Quality Strategy” was released in UK targeting the local bodies to reduce the emissions by
2005 [3]. In general, the prevailing two standards are the “U.S. National Ambient Air Quality
Standards” and the “E.U. Air Quality Directive” that set the standards to control air pollution.
The thermal power plants work by converting the heat energy obtained from the
combustion of fuel to thermal energy. The major fuels used in such power plants are fossil fuels
comprising of coal, natural gas and petroleum. These fuels are hydrocarbons based and upon
reaction with oxygen, they give off carbon dioxide, carbon monoxide, nitrogen oxides, Sulphur
oxides and unburnt hydrocarbons depending upon the combustion environment and completion.
These gases are harmful, and they can further form more pollutants by reacting with each other
spontaneously or under the influence of sunlight. These pollutants then cause smog with different
mechanisms for winter and summer.
When there is absence of degradation through water and mud and the oxidization of the
remains of the dead plants occur then there is the formation of fossil fuels called coal. Coal is
formed in the absence of oxygen and moisture for a considerable amount of time under higher
temperatures and pressure. The more intense environment means the more maturity of the coal on
a physical, chemical and biochemical level. On the basis of maturity levels of coals, there are
different types of coals are present such as peat, lignite, bituminous, sub-bituminous, anthracite
and graphite [4].
Approximately 40% of world electricity is being produced by coal. In the above-mentioned
types, peat is a kind of soft and highly compressible type of coal that is used in countries as fuel
for food cooking and heating mode for household works. Lignite is the lowest-ranked coal and
used only in steam power generation mode fuel. Bituminous is a lump of dense coal that is
consumed for heat generation, steam power generation and power applications. Anthracite is the
black and the second last in the order of hardness and is used for space heating purposes for
residential and commercial both. In the end, the graphite is the hardest coal among all and that is
why it is gnarly to burn as well as not so commonly consumed as fuel [5].
The moisture content in the coal i.e. less mature coal has a higher level of moisture level
and the temperature at which the coal is being ignited. So at temperatures higher than 300°C, the
alkyl and ether linkages are taken out first and almost immediately the functional groups are taken
out in the form of gases such as CO2 , H2 O, NO2 , SO2 and CH4 . The temperatures lower than 300°C,
cause the volatilization of organic compounds and with the steam generated with the help of
wastewater converts the liquids organic compounds to the vapors and take them out this is also
called the steam stripping effect [6]. Coal-based power generation plants are the primary producers
of the pollutants like CO2 , NOx and SO2 . The SO2 is basically produced from the coals that have
higher Sulphur contents in the composition but NOx can be produced in two ways. It is generated
either from the nitrogen content trapped in the coal composition or from the thermal oxidation of
the diatomic nitrogen N2 present in the atmosphere to NOx . The CO2 is released as the carbon
content is burnt in the presence of excess air and it is considered as the greenhouse gas.
2. Standards of Emissions
In order to combat the pollution, several standards are set on different levels. Some of the major
global standards include Japanese, United States and European Union standards. While some
national standards and provincial standards also exist depending upon the countries and the
different regulatory bodies within the states.
2.1. Global Emission Standards
The most common global emission regulations that are followed by many countries of other
regions also; include the United States of America, European Union and Japanese standards and
are discussed below briefly.
2.1.1. United States of America
The very initial environmental act “The Clean Air Act (CAA)” was an American policy that
restricted the excessive emission in the clean air. The clean air act enforces the Environmental
Protection Agency (ETA) to define the National Ambient Air Quality Standards (NAAQS) for
setting the safe amount of emissions from the various sources of pollution. The first rules on
defining the safe levels of Particulate Matter were established by Clean Air Act in 1971. The
primary annual level of PM2.5 (Particulate Matter of diameter less than 2.5 μm) was reduced from
15 μm/m3 to 12 μm/m3 in 2012. Particulate matter includes all the pollutants of a specific size
range. The current restrictions on SOx and NOx defined by the National Ambient Air Quality
Standards (NAAQS) are presented in table 1. These restrictions are being applied more strictly to
the newly based coal-based power plants, as well as to the previously operational power plants.
Table 1 Environmental Protection Agency Current National Ambient Air Quality Standards for SO2 and NOx [7]
Final Rule Primary/Secondary Averaging Time Level Form
Primary 1 hour 100 ppb 98th percentile of 1-hour daily
maximum concentrations,
NOx averaged over 3 years
Primary and Annual 53 ppb Annual Mean
Secondary
Primary 1 hour 75 ppb 99th percentile of 1-hour daily
maximum concentrations
SOx averaged over 3 years
Secondary 3 hours 0.5 Not to be exceeded more than
ppm once per year
The New Source Performance Standards are presented in table below and are determined at 0℃,
101.325 KPa, and a time of average 24 hours.
Table 2 New Source Performance Standards for Coal Fired Power Plants [8]
Plant Age NOx SO2 Particulate Matter (PM)
1971-1978 300 ng/J Heat Input 520 ng/J Heat Input 43 ng/J Heat Input
Sep 1978-1997 Subbituminous: 520 ng/J Heat Input 13 ng/J Heat Input
210 ng/J heat input; 90% Reduction
Other (or 70% reduction
1978-Mar 2005 New Plant: where < 260 ng/J);
200 ng/J Gross Output; 180 ng/J Gross Output;
Reconstructed: 65 ng/J Heat Input
65 ng/J Heat Input
Commenced 130 ng/J Gross output; 180 ng/J Gross Output 18 ng/J Gross Output
Construction 95% Reduction 6.4 ng/J Heat Input
March 2005 - Or;
May 2011 13 ng/J Input
Commenced 130 ng/J Gross Output; 180 ng/J Gross Output 99.9% Reduction
Re-Construction 47 ng/J Heat Input; 65 ng/J Heat Input
March 2005 - 95% Reduction
May 2011
Modified 180 ng/J Gross Output; 180 ng/J Gross Output 18 ng/J Gross Output
March 2005 - 65 ng/J Heat Input; 65 ng/J Heat Input 6.4 ng/J Heat Input
May 2011 90 % Reduction Or;
13 ng/J Input
99.8% Reduction
Construction or 88 ng/J Gross Output; 130 ng/J Gross Output 11 ng/J Gross Input;
Reconstruction 95 ng/J Net Output 140 ng/J Net Input 12 ng/J Net Input
after 3 May, 2011 97% Reduction
Modified 140 ng/J Gross Output 180 ng/J Gross Output; 18 ng/J Gross Output
after 3 May 2011 90% Reduction 6.4 ng/J Heat Input
Or 13 ng/J Input
99.8% Reduction
Table 4 Emission Limit Values from Industrial Emissions Directive for NOx, SO2 and Dust from New and Retrofitted Coal and
Lignite Combustion Plants [9]
Total Rated Thermal Emission Limit Values (mg/m3)
Power (MW) NOx SO2 Dust
50-100 300 400 20
100-300 200 200 20
>300 150 150 10
The minimum rate of desulphurization from Industrial Emissions Directive for combustion plants
as defined by the European commission is given as:
3.1.1.1. Absorption
In absorption, the atoms, ions and molecules get inside the bulk volume of absorbing material
fully. Such absorption is useful to capture the required atoms/molecules in a medium then
separating them with physical separation techniques.
3.1.1.2. Adsorption
Adsorption is the name for phenomenon in which the atoms/ions/molecules get attached to the
surface of the adsorbent. It is clearly a surface phenomenon and results because of the surface
energy resulting from the forces of the surface molecules of the adsorbent.
3.1.1.3. Membrane Gas Separation
CO2 separation is also possible by synthetic membranes. Such membranes make it possible to
extract and separate the CO2 from the flu gases. Membranes can only separate the desired
compounds when the permeability matches to the desired results such that membrane permits the
passage of the compound to be separated from it while restricting the rest of the mass flow.
Membrane technology although has a good potential but it is till now an expensive technique for
carbon capture.
3.1.2. High Efficiency Low Emission Technology
High Efficiency Low Emission (HELE) technologies are used to increase the efficiency of the
system by decreasing the fuel consumption and the emissions associated. The HELE Technologies
can increase the efficiency from 33 to 40% and can reduce the emissions of CO2 by 2 Giga Tons
annually [13]. These technologies are further divided into the following types:
3.1.2.1. Subcritical Boiler Technology
This technology is the most commonly applied one due to its easier and less costly features. It has
efficiency up to 30% but no restriction no restriction on the emissions of CO2.
3.1.2.2. Supercritical Boiler Technology
This technology comprises of 22% of the total coal fired power plants. It has thermal efficiency of
around 40% and operates at high temperature and pressure. It has relatively higher capital cost but
emits 20% less CO2 than the subcritical technology [13].
3.1.2.3. Ultra Supercritical Boiler Technology
These plants have thermal efficiency of around 45% and operate at higher temperatures and
pressures as compared to supercritical plants. This technology comprises of 3% of the total coal
fired power plants. This technology is able to reduce the emissions of CO2 by a third as compared
to the subcritical counter parts. But it has a high capital cost, higher than the supercritical plants
and operates only on the high quality, low ash coal only. They can operate at steam temperatures
of 620 ℃ and pressure ranges of 25-29 MPa [13].
Since the greatest amount of coal lies in Sindh, so the detailed resources are presented in table
below for completeness.
Clearly the larger amount of Pakistani coal lies in the Lignite and Sub-Bituminous range but the
Thar coal is found to be present in greater proportion of lignite form [16] with higher levels of
water, followed by sulphur; so, the techniques applied for the lignite coal will be considered here.
The indigenous coal of found to be inadequate for Sahiwal Coal Power Plant and coal imported
from South Africa and Indonesia is used as fuel [17]. The composition of the coal found from Thar
field of Sindh is presented in table below:
safety risks are absent in UCG-IGCC. The coal which is too deep or is not of good quality so not
economically feasible to mine can be utilized also by this technology [19].
4.3. Transportation
With UCG-IGCC, the heavy transportation of coal is also not required. If the plant is at the coal
seam site, then no transport is required but if the plant cannot be build on the site and is further
apart then, the gas can easily be transported through gas pipelines which is relatively easier than
the vehicular transmission of coal from seam to the plant site. The transport of gas through
pipelines needs a setup requiring capital cost only and very little maintenance cost. Considering
the pressure constrains enough to ensure the transmission of gas through pipelines, gas could also
be transferred through tanks and carriages.
4.4. Utilization
In the UCH-IGCC system, the synthesis gas is used to burn in a gas turbine producing the primary
power through gas turbine. The flu gases are hot enough and a large amount of energy is wasted if
their heat energy is not recovered. The heat energy from the gas turbine flu gases are used to
provide heat to run the combined steam turbine. This makes combined gas and steam turbines
cycle with thermal efficiencies in range of 42 - 44%. The synthesis gas is then cleaned particularly
with the acid gas removal to remove the H2S and COS products formed from Sulphur. During the
cleaning, the desulphurization and the dehydration is specifically important. Both the composition
of this syngas before and after cleaning is given in tables below:
CO2 20-25%
CH4 1-2%
4.5. CO2 emissions
The CO2 emissions can be reduced by either pre-combustion techniques or post combustion carbon
capture and storage techniques. In the pre-combustion techniques CO2 is removed in the syngas
purification plant and re injected into the empty cavity of coal seam. The CO2 that evolves after
the combustion can again be injected into the empty coal cavity. The empty coal cavity serves as
a potential feature of carbon storage in UCG-IGCC technologies.
4.6. Pollution
During gasification the sulphur present is converted to Hydrogen sulphide (H2S) and carbonyl
sulphide (COS) and these products can be easily removed by commercially available systems such
as the acid gas removal system. SOx are removed by installed Flue Gas Desulphurization systems
which prove to be much economical in UCG-IGCC systems. It has been reported that flu gas
desulphurization takes about 3% of the auxiliary power from the system in case of solid coal
combustion but the value is practically negligible in case of UCG-IGCC [18]. NOx is not formed
in considerable amount due to the fact that combustion of gas takes place at lower temperatures as
compared to combustion of coal which takes place at higher temperatures [19]. The particulate
matter can be removed by the water scrubbing techniques.
4.7. Waste Removal
Practically, all the solid waste including the particulate metal like Mercury, Arsenic and ash
remains underground so the waste problem and the associated waste burning problems are
eradicated and there are no cost expenditures associated.
5. Cost Analysis
UCG requires 75% less capital cost as compared to surface integrated coal gasification [16]. A
detailed cost analysis is provided by [20]. In the cost analysis presented 3 coal samples were
considered for the Underground Coal Gasification technology. The properties of the samples are
provided below:
Table 17 Composition of the Samples Analyzed [20]
Sample A Sample B Sample C
(Lignite) (Lignite) (Sub-Bituminous Coal)
Moisture 5.01 13.42 9.53
Volatile Matter 27.39 45.51 20.23
Fixed carbon 51.25 23.15 6617
Ash 16.01 17.89 4.05
C 64.72 50.84 75.47
H 3.72 5.38 1.89
N 1.10 0.33 0.02
O 8.47 18.33 6.80
S - 0.83 -
Gross Calorific value (MJ/kg) 19.22 16.57 20.96
The summary of the capital and operating costs of 100 MW operating UCG plant is presented in
table below:
Table 19 Summary of the capital and Operational Cost of 100 MW UCG Coal Power Plant [20]
Sample A Sample B Sample C
Capital Cost ($)
(Lignite) (Lignite) (Sub-Bituminous Coal)
Drilling 869000 5670000 10.962000
Air Compressor 12163646 10355703 13462448
Dust removal 7400654 6300658 8190876
Gas Cooling 6680012 5687129 7393286
Gas Cleaning 7915800 739236 8761028
Sour Water stripper 8385906 7139468 9281331
Acid Gas Removal and Sulphur Recovery 30402076 25883267 33648331
Gas Turbine and HRSG 100340115 100340115 100340115
Offsite and Auxiliaries 41051248 34949600 45434594
Buildings 8200116 6981292 9075703
Total 231233572 210046468 246549713
Operating Cost ($)
Drilling per year 8694000 5670000 10962000
10 %UCG Cost 869400 567000 1096200
4.6% of total plant 10636744 9662138 11341287
Total 20200144 15899138 23399487
Unit Cost of Production
Syngas ($/GJ) 1.34 0.9 1.73
Electricity ($/MWh) 21.27 19.1 28.11
As compared to the Sahiwal Coal Project, where the cost o the coal is as follows:
Table 20 Coal Cost for Sahiwal Col Power Plant [17]
Year Average cost of Coal Coal Purchase Cost Total Cost of Coal (including transport)
(USD/ton) (Million USD) (million USD)
2017 87.69 403 521
2018 95.53 439 582
2019 71.23 332 502
It is inferred that the coal technology UCG-IGCC will be more beneficial for the country as it can
utilize the country’s vast coal resources while remaining clean and efficient. The addition of
combined cycle further decreases the unit cost of electricity and makes the process even more
efficient. The addition of Carbon Capture and Storage will add a bit to the capital cost, but it will
greatly reduce the CO2 emissions and will make the process environmentally friendly.
8. Conclusion
Pakistan has vast reserves of around 185 million tonnes of coal in Thar field, but the absence of
appropriate economical and efficient technology hinders its utilization and the country in turn
relies on the imported coal which is way more expensive. UCG-IGCC is an environmentally
friendly technique that minimizes the pollution and can be combined with carbon capture and
storage to reduce the CO2 emissions as well. It does not require the conventional mining practices
and is safer than other technologies, uses less land area and less surface disturbances. The
utilization of local coal can prove beneficial for the country as it can provide a sustainable solution
to the coal demand and power sector.
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