Model Question Paper Set- II

ekWMy ç’u&i= lsV& II

2021
Time Allowed - 3 Hours. Chemistry Full Marks- 70
Class- XIIth

General Instruction
lkekU; funsZ’k %

Group – A has 20 Multiple Choice Type Question each of 1 mark.

[k.M& v esa 20 cgqfodYih; ç’u gS] çR;sd 1 va’k dk gSA
Group – B has 07 Fill in tha blanks type Question each of 1 mark.
[k.M& c esa 07 fjDr LFkku Hkjsa çdkj ds ç’u gSa] çR;sd 1 vad dk gSA
Group – C has 07 Very Short answer type Question, each of 2 mark.
[k.M& l esa 07 vfr y?kq mÙkh; ç’u gS] çR;sd dk eku 2 vad gSA
Group – D has 05 Short answer type Question, each of 3 mark.
[k.M& n esa 05 y?kq mÙkh; ç’u gS] çR;sd dk eku 3 vad gSA
Group – E has 02 Long answer type Question, each of 7 mark.
[k.M& b esa 02 nh?kZ mÙkh; çdkj ds ç’u gS] çR;sd dk eku 7 vad
gSA
Group - A
¼[k.M & v½
v½
I- Choose and write correct answer of the following: 1x20=20
fuEufyf[kr ç’uksa ds lgh mÙkj pqu dj fy[ksa%
1. The number of atoms in a face-centered cubic unit cell of a monatomic
substance is equal to:
(a) 1 (b) 2
(c) 3 (d) 4
Qyd dsfUær ?kuh; ,dd dksf"Bdk ¼FCC½ esa mifLFkr ijek.kqvksa
dh la[;k fdruh gksrh gS\
(a) 1 (b)2
(c) 3 (d) 4
2. Number of moles of solute present in 1 liter of solution is called:
(a) Molarity (b) Molality
(c) Normality (d) Mole Fraction
,d fyCVj foy;u esa mifLFkr foys; ds eksyksa dh la[;k dks
dgrs gSa%
(a) eksyjrk (b)eksyyrk
 (c) ukeZyr (d) eksy&va’k
3. Example of strong electrolyte is:
(a) Acetic Acid (b) Formic Acid
(c) Ammonium Hydroxide (d) Hydrochloric Acid
çcy oS|qrvi?kV~; gS%
(a) ,flVhd vEy (b) QkWfeZd vEy
(c) veksfu;e gkbMªkWDlkbM (d) gkbMªksDyksfjd vEy
4. The process in which a substance gain electron is called:
(a) Oxidation (b) Reduction
(c) Hydrogenation (d) Addition
fdlh inkFkZ }kjk bysDVªkWu xzg.k djus dh çfØ;k dgykrh gS%
(a) vkDlhdj.k (b) vodj.k
(c) gkbMªkstuhdj.k (d) ladyu

5. How much charge is required for the reduction of 1 mole of Cu2+ ion to
Cu?
(a) 193000C (b) 96500C
(c) 48250C (d) 1900C
2+
1 eksy Cu vk;u dks Cu esa vod`r djus ds fy, vko’;d
vkos’k dh ek=k gS\
(a) 193000C (b) 96500C
(c) 48250C (d) 1900C
6. Order of the reaction having rate law expression, R= K [A]1 [B]1 will be:
(a) 1 (b) 2
(c) 3 (d) 0
1 1
osx fu;e lehdj.k] R= K [A] [B] okys vfHkfØ;k dh dksfV D;k
gksxh\
(a) 1 (b) 2
(c) 3 (d) 0
7. Unit of the rate constant of a Zero order reaction is:
(a) s −1 (b) mol L−1 s −1
(c) L2 mol −2 s −1 (d) L mol −1 s −1
'kwU; dksfV dh vfHkfØ;k ds osx&fLFkjkad dk ek=d gS%
(a) s −1 (b) mol L−1 s −1
(c) L2 mol −2 s −1 (d) L mol −1 s −1

8. The shape of XeF4 is :

(a) Tetrahedral (b) Square planar
(c) Octahedral (d) None of these

XeF4 dh vkd`fr gS%

(a) prq"Qydh; (b) oxZ leryh;
 (c) v"VQydh; (d) buesa ls dksbZ ugha
9. Which of the following is water soluble?
(a) Vit. D (b) Vit. E
(c) Vit. A (d) Vit. C
buesa ls ty foys; gS%
(a) foVkfeu D (b) foVkfeu E
(c) foVkfeu A (d) foVkfeu C
10. Cl
(I) NaOH, 623 K, 300 atm
A
(II) H+

‘A’ is : CH3Cl CHO OH

(a) (b) (C) (d)

Cl
(I) NaOH, 623 K, 300 atm
(II) H+

‘A’ gS: CH3Cl CHO OH

(a) (b) (C) (d)

11. Which of the following has lowest dipole moment?

(a) CH3 Cl (b) CH2 Cl2
(c) CH Cl3 (d) C Cl4

buesa ls fdldk f}/kzqo vk/kw.kZ U;wure gS\

(a) CH3 Cl (b) CH2 Cl2
(c) CH Cl3 (d) C Cl4

12. Equimolar mixture of HCl and ZnCl2 is Known as :

(a) Lucas reagent (b) Hinsberg reagent
(c) Tollen’s reagent (d) Baeyer’s reagent

HCl ,oa ZnCl2 ds leeksyj feJ.k dks dgrs gSa%

(a) Y;wdkl vfHkdeZd (b) fgUlcxZ vfHkdeZd
(c) VksysUl vfHkdeZd (d) cs;j vfHkdeZd
13. Which of the following is least soluble in water:
CH3

(a) CH3 CH2 CH2 CH2 OH (b) CH3 – CH – CH2 – OH

CH3 OH
(c) CH3 – C - OH (d) CH3 – CH2 – CH – CH3
CH3
buesa ls dkSu ty esa U;wuÙke /kqyu’khy gS\
CH3
(a) CH3 CH2 CH2 CH2 OH (b) CH3 – CH – CH2 – OH

CH3 OH
(c) CH3 – C - OH (d) CH3 – CH2 – CH – CH3
CH3

14. Which of the following is primary alcohol?

OH

(a) CH3 – CH2 – CH2 - OH (b)

OH OH

(c) (d)

CH3 NO2
buesa ls dkSu çkFkfed ,Ydksgky gS\
OH

(a) CH3 – CH2 – CH2 - OH (b)

OH OH

(c) (d)

CH3 NO2
15. Products of the reaction :
CH3 – CH2 – CH2 – O – CH3 + HI …….. are :

(a) CH3 – CH2 – CH2 - OH + CH3 I (b) CH3 – CH2 – CH2 – I +

CH3OH
(c) CH3 – CH2 – CH2 – I + CH3I (d) CH3 – CH2 – CH2 – OH +
CH3OH
fuEufyf[kr vfHkfØ;k ds mRikn D;k gS\

CH3 – CH2 – CH2 – O – CH3 + HI ……..

(a) CH3 – CH2 – CH2 - OH + CH3 I (b) CH3 – CH2 – CH2 – I +

CH3OH
(c) CH3 – CH2 – CH2 – I + CH3I (d) CH3 – CH2 – CH2 – OH +
CH3OH
O
C - Cl H2
A
16. Pd – Baso4
‘A’ is
O CHO
(a) C - CH3 (b)

CH3 Cl
(b) (d)

O
C - Cl H2
A
Pd – Baso4
‘A’ gS %

O CHO
(a) C - CH3 (b)

CH3 Cl
(b) (d)
 17. Which of the following has highest Boiling point?
(a) CH3 – CH3 – CH2 - CHO (b) CH3 – CH2 – CH2 – CH2 - OH

(c) C2H5 – O – C2H5 (d) CH3 – CH2 – CH2 – CH2 –

CH3

buesa ls fdldk DoFkukad vf/kdÙke gS\

(a) CH3 – CH3 – CH2 - CHO (b) CH3 – CH2 – CH2 – CH2 - OH

(c) C2H5 – O – C2H5 (d) CH3 – CH2 – CH2 – CH2 –

CH3

18. O + HO – NH2 A

‘A’ is :

(a) OH (b) NH2 (c) N –OH (d)

NO2

O + HO – NH2 A

‘A’ gS :

(a) OH (b) NH2 (c) N –OH (d)

NO2

19. NO2 Sn + HCl

A
‘A’ is :
NH2 Cl OH
(a) (b) (c) (d)

NO2 Sn + HCl
A
‘A’ gS:
NH2 Cl OH
(a) (b) (c) (d)
20. Which of the following is tertiary amine?
(a) C6 H5 NH2 (b) C2 H5 NH2
(c) (C2 H5)2 NH (d) (C3H5)3 N
buesa ls dkSu r`rh;d vekbu gS\
(a) C6 H5 NH2 (b) C2 H5 NH2
(c) (C2 H5)2 NH (d) (C3H5)3 N

Group - B
¼[k.M & c½ 1x7=7
(Fill in the blank Type Questions)
¼fjDr LFkkuksa dks Hkjsa½
21. dksykWbMh d.kksa ds Vs<+h&es<+h ¼Zig-Zag½ xfr dks …….
The phenomenon of Zig-Zag motion of colloidal particles is known as
……….
22. [kfutksa ls lac) v’kqf);ksa dks ……… dgrs gSaA
The impurities associated with the minerals are collectively known as ……
23. gSykstu tks ifjoÙkZu’khy vkWDlhdj.k voLFkk çnf’kZr ugha djrk
gS …………….
The hologen which doesnot show variable oxidation state is …………
24. Øksfe;e dk ckg~; bysDVªkWfud foU;kl ……….. gSA
The outer electronic configuration of chromium is ……………
25. RNA esa …………ldZjk gksrk gSA
The sugar in RNA is …………….
26. çkd`frd jcj …………… dk cgqyd gSA
Natural Rubber is a polymer of ………………
27. nnZ dks de djus okys jklk;fud inkFkZ dks ………….. dgrs gSaA
Chemical used for reducing pain are called ………………

Group - C
¼[k.M &l½
&l½ 2x7=14

(Very Short Answer Type Questions)

¼vfr y?kq mÙkjh; ç’u½
28. The resistivity of a 0.2M solution of electrotyte is 5 X 10−3 Ω cm , calculate
its molar conductivity.
,d oS|qrvi?kV~; ds foy;u dh lkaærk 0.2 M ,oa fof’k"V çfrjks/k
5 X 10−3 Ω cm gSA bldh eksyj pkydrk Kkr djsaA
29. What is roasting of ore? Give one example.
HktZu dks ifjHkkf"kr djsa ,oa ,d mnkgj.k nsaA
30. On what ground can you say that Scandium (Z=21) is a transition element
but Zinc (Z=30) is not?
 vki fdl vk/kkj ij dg ldrs gSa fd LdsfUM;e ‘Sc (Z=21) ,d
laØe.k rRo gS tcfd ftad ‘Zn’ (Z=30) ugha\
31. Calculate the Number of unpaired electrons in Mn3+ and Fe3+
Mn3+ vkSj Fe3+ vk;u esa v;qfXer bysDVªkWuksa dh x.kuk djsaA
32. Define the following:
(a) Peptide Linkage (b) Denaturation of Proteins
ifjHkkf"kr djsa %
(a) isIVkbM ca/k(b) çksVhu dk fod`rhdj.k
33. Define Homopolymer and Copolymer. Give one example of each.
lecgqyd ,oa lgcgqyd dks ifjHkkf"kr djsa ,oa ,d&,d
mnkgj.k nsaA
34. What are antibiotics. Give one example.
çfrthok.kq D;k gS\ ,d mngkj.k nsaA

Group - D
¼[k.M & n½ 3x5=15
(Short Answer Type Questions)
y?kq mÙkjh; ç’u½
35. An etement having atomic mass 60.2 has a face centred cubic unit cells.
The edgelemgth of the unit cell is 100 pm. Find out density of the element.
(NA= 6.02x1023)
,d rRo dk ijek.kq æO;eku 60-2 gS ,oa blesa fcc ,dd
dksf"Bdk,¡ gSaA bldh dksf"Bdkvksa ds dksj dh yackbZ 100pm gSA
bl rRo dk ?kuRo Kkr djsaA (NA= 6.02x1023)
36. What are emulsions? What ar their different types? Give one example of
each type.
ik;l D;k gSa\ blds fofHkUu çdkj D;k gSa\ çR;sd dk ,d
mnkgj.k nsaA
37. Nitrogen exists as diatomic molecule (N2) and phosphorus as P4 why?
ukbVªkstu f}ijekf.od v.kq (N2) gS tcfd QkWLQksjl prq"d
ijekf.od (P4) D;ksa\
38. Write the various steps involved in Manufacture of H2 SO4 by Contact
process.
lY¶;wfjd vEy H2 SO4 ds fuekZ.k ds laLi’kZ çØe ds fofHkUu
inksa dks fy[ksaA
39. Write IUPAC Names of the following compounds:
(a) [Co (NH3)6] Cl2
(b) [Ni (CO)4]
2-
(c) [Zn (OH)4]
fuEufyf[kr ds IUPAC uke fy[ksa %&
(a) [Co (NH3)6] Cl2
 (b) [Ni (CO)4]
2-
(c) [Zn (OH)4]

Group - E
¼[k.M & ;½ 7x2=14
(Long Answer Type Questions)
¼nh?kZ mÙkjh; ç’u½
40. (a) Calculate the molarity of a solution containing 40g of NaOH disolved in
2 Litre of the Solution.
40g NaOH dks ?kqykdj cuk;s x;s 2 yhVj foy;u dh eksyjrk
Kkr djsaA
(b) A First order reaction takes 40 minutes for 30% completion. Calculate
its half life period. (log7=0.845)
çFke dksfV dh ,d vfHkfØ;k 40 feuV esa 30% iw.kZ gksrh gSA
vfHkfØ;k dh v)Z vk;q vof/k Kkr djsaA (log7=0.845)
OR @ vFkok
(a) 31g of ethylene glycol (C2 H6 O2) is mixed with 500g of water.
Calculate Freezing point of the solution. [Kf = 1.86K Kg mol-1 ]
31g bFkk;fyu XykbdkWy (C2 H6 O2) dks 500g ty esa feyk;k x;k
gSA bl foy;u dk fgekad D;k gksxk\ [Kf = 1.86K Kg mol-1 ]
(b) A First order reaction has a rate constant (1.15x10-3)s-1 How long will
5g of this reactant take to reduce to 3g?
çFke dksfV dh ,d vfHkfØ;k dk osx fLFkjkad (1.15x10-3)s-1 gSA
fdrus le; esa bl vfHkfØ;k dk 5g vfHkdkjd ?kV dj 3g gks
tk,xk\

(41) (I) Write short notes on:

laf{kIr fVIi.kh fy[ksa%
(a) Aldol Condensation
(a) ,sYMksy la?kuu
(b) Hoffmam bromamide degradation reaction.
(b) gkWQeku czksekekbM fo?kVu vfHkfØ;k

(II) How you will bring about following conversions:

fuEufyf[kr ifjorZu vki dSls djsaxs\
(a) 2-Bromopropane to propene
(a) 2-czkseksçksisu ls çksihu
(b) Phenol to Benzene
(b) fQukWy ls csaftu
(c) 1-Chloropropane to 1-Iodopropane

(c) 1-Dyksjksçksisu ls 1&vk;ksMksçksisu

OR @ vFkok
Write the structure of the major organic product in each of the following
reactions:
fuEufyf[kr vfHkfØ;kvksa esa eq[; mRikn dh lajpuk fy[ksaA
(a) CH3 – CH2 – CH = CH2 + HBr Peroxide ……..

(b) CH3 - CHO + 2H LiAIH4 …….

(c) CH2 – CH3 KMnO4

KOH,
(d) CH3 – CH = CH – CH3 (I) O3
(II) H2O/Zn
(e) CH3 – CH2 – OH Conc. H2SO4
443 K
(f) CH3 – Br + C2H5 O − Na +
(g) NH2 +HCl