24 06 2021 SR Super60 All Jee Main GTM 31 Key Sol S
24 06 2021 SR Super60 All Jee Main GTM 31 Key Sol S
24 06 2021 SR Super60 All Jee Main GTM 31 Key Sol S
CHEMISTRY
31 2 32 4 33 1 34 2 35 3
36 3 37 3 38 3 39 3 40 1
41 2 42 3 43 1 44 3 45 1
46 2 47 3 48 2 49 4 50 3
51 4 52 8 53 6 54 -0.22 55 0.33
56 750 57 21.6 58 5 59 5 60 12.50
MATHEMATICS
61 3 62 4 63 2 64 4 65 1
66 1 67 2 68 3 69 2 70 1
71 3 72 2 73 3 74 4 75 1
76 2 77 1 78 1 79 1 80 2
81 2 82 13 83 4 84 0 85 1
86 3 87 0 88 0 89 1 90 2
Sri Chaitanya IIT Academy 24-06-2021_Sr.Super60 & All_Jee-Main_GTM-31_Key & Sol’s
SOLUTIONS
PHYSICS
m 21.2
1. 10.6s
b 2
E E 0e t /
0.1 e t/10.6
e t /10.6 10
t
ln10
10.6
t 10.6 2.302 24.4s
2. Given
Frequency of signal f m 20kHz
Peak voltage A m 5V
Frequency of carrier wave f c 1.2MHz
Peak voltage AC = 2.5V
V 5
Modulation index m 0.2
V0 2
Lower side band frequency f LSB f c f m
= 1200 – 20
= 1180 kHz
Upper side band frequency f USB f m f c
= 1200 – 20
= 1180 kHz
3. Object distance u u u 50.1 0.5 cm
Image distance v v v 20.1 0.2 cm
From mirror formula
1 1 1 1 1 1 1
F v u F 50.1 20.1 0.0697
F 14.34cm
F v u
and 2 2 2
F v u
2 2
F f
F u v
u v
2 2
14.3 14.3
0.5 0.2
50.1 20.1
0.04 0.10 0.14cm
Hence, f 14.3 0.1 cm
4.
1
Before K1 opened the energy stored over capacity C1 CV 2
2
1
3 106 102 150J
2
2. Now this energy will be dissipated E i 2 Rt in the two resistors in the ratio of
R 1 : R 2 as they are in series (current flowing through the resistors is same) when switch
K 2 is closed.
150J is lost at the ratio 2 : 4 = 1 : 2
1 2
In 2 rd of 150J and in 4, rd of 150J will be lost.
3 3
5. Horizontal component of velocity is decreased (or) due but vertical component remains
same.
6. Electron moves from n-side to p-side
7. ax 2 bv 2 k
bv 2 k ax 2
k a
v2 x 2
b b
Compare with v 2 A 2 2 2 x 2
2 a / b and A 2 2 k / b
A 2 2 k/b k
A 2
a/b a
8. The rate of formation of radioactive nuclei is t 2
Rate of decay of radioactive nuclei is N
dN 2
t N
dt
dN d2 N
For to be minimum; 2 0
dt dt
2
d N dN
2 2t
dt dt
2t t 2 N 0
2
2t t
N
2
Sri Chaitanya IIT Academy 24-06-2021_Sr.Super60 & All_Jee-Main_GTM-31_Key & Sol’s
2t 0 t 02
N (at t t 0 )
2
9.
After insertion of thin glass plates in path of beams from S1 and S2 as shown, path
difference at screen center becomes
a t1 1 2 1
Say after insertion of plates at point P (above O) the physical
dx
Path difference will balance the optical path difference due to plates so finally
D
effective path difference at P is zero at point P we use
dx
ap a 0
D
dx
t1 1 t 2 1
D
D
x 1 t 2 1
d
D
x 1 t1 t 2 .......1
d
In YDSE fringe width is given as
D D
d d
E
10. c
B
11. As we know for a streamline flow of a liquid velocity of each particle at a particular
cross section is constant, because Av = constant (law of continuity) between two cross
section of a tube of flow.
1main scale division
12. Least count
Number of Vernier scale divisions
1 main scale division
0.1mm
20
1 Main scale division = 2mm
13. Step-I: For diatomic gas f 5 & f rot 2;
Step-II : O 2 and N 2 both are diatomic
14.
Sri Chaitanya IIT Academy 24-06-2021_Sr.Super60 & All_Jee-Main_GTM-31_Key & Sol’s
Given Current = i
Side of square = a
Constant velocity = v
The electro motive force induced in the frame in the position
enet e1 e2 ........1
We know e1 B1va;e 2 B 2 va
e net B1va B2 va
B1 B2 va..... 2
We know magnetic field due to long wire carrying a current I is
i
B1 0
2x
0i
Due to square frame B2
2 x a
Substituting the above formulas in equation (2)
i 0i
enet 0 va
2x 2 x a
0i 1 1
va
2 x x a
0i x a x
va
2 x x a
0iva 2
2x x a
15. In the rod current density.
i
j
b a2
2
Sri Chaitanya IIT Academy 24-06-2021_Sr.Super60 & All_Jee-Main_GTM-31_Key & Sol’s
Actual field is the vector sum of two current carrying rods, having same current density
but in opposite direction. On the hole axis, only the larger rod contributes magnetic
field.
Imagine an ampere a loop of radius E and apply Ampere law.
B.dl 0i enclosed
B2 c 0 jc 2
0ic2 0ic
or B
2
2c b a 2
2 b 2 a 2
0ic
or B
2 b2 a 2
16. va s
ds
a s
dt
ds
adt
s
a2t2
2 s at s
4
Ma 2
F
2
Ma 2 a 2 t 2 1
Work done Ma 4 t 2
2 4 8
17. Here, 1 30º and 2 45º . Ratio horizontal magnetic field BH .
BH Bcos
BH 1 Bcos30º 3 / 2 3
BH 2 Bcos 45º 1 / 2 2
1
18. ne
ne
1 1
19 19
0.4m
10 1.6 10 1.6 2.56
K2 1dT
19. Heat current H
dx
r2 T2
dx
H K12 dT
r1
x T1
r
H log 2 K12 T2 T1
r1
r
H 2 lK T2 T1 log 2
r1
r
H log 2
r1
20. Energy of the photoelectron does not depend on intensity of light
V 6
21. I
R1 R 2 R 3 50 150 100
6
0.02A
300
22.
v
29. Ex 6i
x
v
Ey 8j
y
v
Ez 8zk
z
E net at origin 6 2 82 10
F qE 20N
30. x1 l 2 fl 3.14
Also, tan L
R
L Z
tan 1 tan 1
R R tan 1 3.14
Sri Chaitanya IIT Academy 24-06-2021_Sr.Super60 & All_Jee-Main_GTM-31_Key & Sol’s
72º 72 1
s
180 250
2 50
3
4 10 s k
So, 1000k = 4
CHEMISTRY
31. AB5 molecule may have either Trigonal bipyramid or square pyramidal structure.
32. The decrease in ionization energy in noble gases is very large than in alkali metals. So
the difference in 1st ionization energies of neon and sodium is very large.
33. Co3 is colourless but not oxidizing agent all 3d elements cannot liberate H 2 from 1M
HCl
Ex: Cu
34. The amount of oxygen required to decompose the organic matter in given sample of
water when kept in all incubator for 5 day is known as BOD
35. It is the definition for calcination
36.
37. Almost all compounds formed in lower +ve oxidation state contains double bonds or
triple bonds as nitrogen oxides, or cyanides which are not possible for phosphorous or
other elements. Due to bigger size the other elements in that group cannot form
bonds.
38. The kinetic energy of the ejected electron is given by the equation
1
hv hv0 mv 2
2
hc hc 1 c
mv 2 v
0 2
1 hc hc
mv 2
2 0
2hc 0
v2
m 0
2hc 0
v
m 0
39. IUPAC name of following will be
CHO
CH3
OH
4 – hydroxy 2 – methyl benzladehyde
XY5 g XY g Y g
Initial 800mm 0 0
At eqn. 800 – x x x mm
Sec: Sr.Super-60 & All Page 10
Sri Chaitanya IIT Academy 24-06-2021_Sr.Super60 & All_Jee-Main_GTM-31_Key & Sol’s
But at eqm. The pressure is = 960mm
Therefore, 800 x x x 960mm, x 160mm
amount dissociated
Degree of dissociation of XY2
Initial amount
160
0.2
800
x
47. For the adsorption of a gas on a solid kp1/n
m
This equation is known as Freundlich Adsorption isotherm.
x 1
log log k log p
m n
48. Ozonolysis of 2,3 – dimethyl – 1 – butane followed by reaction with zinc and water
gives methanol and 3 – methyl – 2 – butane
i)O3
CH3 CH C CH3
ii)Zn/H2O
CH3 C O HCHO
CH 3 CH 3 CH 3 CH 3
2,3 dimethyl - 1 - butene 3 methyl, 2 - butanone
49. Conceptual
50.
1
1.5 105 3
3.3 103
4.5 10
Sri Chaitanya IIT Academy 24-06-2021_Sr.Super60 & All_Jee-Main_GTM-31_Key & Sol’s
51. The smallest X – M – X bond angle in octahedron is 90º and largest bond angle is 180º.
Then the number of 90º angles are 12 and the number 180º angle is 3. Then the ratio is
12/3 = 4.
52. On this complex , P Me3 the phosphorous atom and the three carbon atoms of Me
groups are sp 3
53. Alkaline permanganate oxidises KI to KIO 3
54. When,
pH 14 H 1014 and OH 1M
2
K sp Cu 2 OH 1019
2 1019
Cu 2 1019
OH
The half cell reaction
Cu 2 2e Cu
0.059 1
E Eº log
2 Cu 2
0.059 1
0.34 log 19 0.22V
2 10
55. Let the mass of methane and oxygen 'm'gm
Moles of O2
Mole fraction of O 2
Moles of O2 Moles of CH 4
m / 32 m / 32 1
m / 32 m / 16 3m / 32 3
Partial pressure of O 2 total pressure mole fraction of O 2
1 1
PO2 P P
3 3
Therefore, the fraction of the total pressure exerted by oxygen is 0.33
56. For a reaction to be at equilibrium G 0
Since G H TS
So at equilibrium H TS 0
Therefore, H TS
For the reaction:
1 3
X 2 Y2 XY3 ; H 30KJ given
2 2
Calculating S for the above reaction, we get
1 3
S 50 60 40 JK 1
2 2
1
50 30 60 JK 1 40JK
At equilibrium, TS H G 0
T 40 30 1000 1KJ 1000J
HI
HI
O HO I I I
Mg
IMgCH 2CH 2CH 2CH 2 MgI
Ether
CO 2 / H3O
O
CH 2 CH 2 COOH
Adipic acid CO 2 H 2O
CH 2 CH 2 COOH
59.
60. In a ccp lattice of oxide ions, there would be two tetrahedral and one octahedral void
per oxide ion.
Out of the eight tetrahedral voids, one is occupied by A.
1
% of tetrahedral voids occupied 100 12.5%
8
1 6 – 1
y= 9 x+b
25 C
0 25
y= (x – b)
9
1 25
Required area = 2 ar OAP 2 b· b 49
2 16
49 16
b2
25
7 4 28
b .
5 5
(–2, –4) –
3
one tangent is vertical slope and other is
4
3
Equation of incident ray , y 4 x 2
4
3x + 4y + 22 = 0
| 4 | | | | | | |
67. t | | 2
| | | | | |
sin 2x sin(2 2h) sin 2h( 2)
Lim Lim Lim 2
x x h 0 h h 0 2h
68. Putting z = x + iy
|x - iy - i(x + iy)| +|x + iy - i(x - iy)| = 4
|x + y - i(x + y)| +|x - y - i(x - y)| = 4
|x + y| +|x - y| = 2 2
xy xy
2
2 2
|x|+|y| = 2
Required area = 8 sq. units.
69. z 1
x [-1, 1] (x 2 +y 2 =1)
E z 1 | z 2 – z 1|
1
E (x 1)2 y 2 z z 1
z
1
E 2 2x | z | z 1
z
E 2 1 x 2x 1
f x 2 1 x 2x – 1 in –1,1
7
f ' x 0at x
8
7 1
x 1 1
8 2
13
f (x) 3 3 3
4
13
f x |max .
4
dy
70.
1 y2 x e tan 1 y
dx 0
1
dx x e tan y
dy 1 y 2 1 y 2
dy
1 y2 1
I.F e e tan y
1 1
1
f x 1 f x
2
1 3
x x ,f x f x ....... ii
2 2
3 3
x x ,f x 3 f x ....... iii
2 2
From (ii) and (iii), f (x + 3) = f (x)
Hence, f (x) is period with period = 3
f (x – 3) = f (x)
f (x – 3) + f (x + 3) = f (x) + f (x) = 2 f (x)
h
75. In BCD, tan30 ... i
d
H
In ABD, tan60 ... ii
d
(i) divided by (ii)
A
60°
H
Tower C
h
30° 60° Pole
B D
d
h
tan 30 d
tan 60 H
d
1 h H
h
3 3 H 3
1
76. y
x
dy 1
dx x 2
Equation of normal A(t1 ) and A(t 2 )
1 1
t 2 t1
t12
t 2 t1
t13 t 2 1
1 1
px q px r 1 2 2
77. qr
dx
q r
(px q) (px r) dx
3 3
1 2
· (px q) (px r) 2
2
q r 3p
1 125
b n 1 2b n 2
3 bn
1 125
Lim b n 1 2 Lim b n
n 3 n Lim b 2n
n
1 125
b 2b 2
3 b
2b 125
b
3 3b 2
b 125
2 b3 125
3 3b
b=5
2
2
79. 21 (log 2 x ) x log2 x 30
log 2 x log 2 x 2
2· 2
x log 2 x 30
2
2·x log 2 x x log2 x 30
Now put x log2 x t
t 2 +2t - 3 = 0 (t + 3)(t - 1) = 0 t=1
log 2 x
x 1
(log 2 x)(log 2 x) = 0 t=1
2x 0
sin 1 (x 0 ) tan 1 2
cot 1 (2) tan 1 2 cot 1 2
2 (x 0 ) 2
1 0 0
80. I 0 1 0
0 0 1
3 different columns can be arranged in 3! = 6 ways
0 1 0
for ex P can be 1 0 0
0 0 1
and P 1 or – 1 in each case.
y=x
D
C
y2 = x – 2
E B
O A