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Reversible Reaction

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10 The diagram shows crystals of copper(II) sulphate, CuSO4. 5H2O, being heated.

crystals

steam

heat

The crystals change colour.

Which two terms describe this change?

A endothermic and dehydration


B endothermic and hydration
C exothermic and dehydration
D exothermic and hydration

11 When hydrated copper(II) sulphate is heated in the apparatus shown, solid X and liquid Y are
produced.

hydrated copper(II)
sulphate

heat

cold water

liquid Y

Which changes are noticed when liquid Y is added to cold solid X?

colour change heat change


A blue to white heat given out
B blue to white heat taken in
C white to blue heat given out
D white to blue heat taken in
12 Two reactions involving water are shown.
X FeSO4 + water → hydrated iron(II) sulphate
Y Fe + O2 + water → rust

Which of these reactions are reversible by heating?

X Y
✓ ✓
A
✓ ✗
B ✗ ✓
C ✗ ✗

13 When pink cobalt(II) sulfate crystals are heated, they form steam and a blue solid.

When water is added to the blue solid, it turns pink and becomes hot. Which terms

describe the pink cobalt(II) sulfate crystals and the reactions?

pink cobalt sulfate reactions

A aqueous irreversible
B aqueous reversible
C hydrated irreversible
D hydrated reversible
15 Chlorine can be manufactured by using the reversible reaction between hydrogen chloride and
oxygen.

4HCl(g) + O2(g) 2H2O(g) + 2Cl2(g) ∆H is negative


o
A mixture in dynamic equilibrium is present at 450 C.

Which change to the mixture will increase the amount of chlorine at equilibrium?

A adding a catalyst
B adding more HCl(g)
C decreasing the pressure
D increasing the temperature

16 In the Contact process for making sulphuric acid, one step involves the oxidation of sulphur dioxide
as shown below.
2SO2(g) + O2(g) 2SO3(g)

The forward reaction is exothermic.

Which change would increase the amount of sulphur trioxide produced at equilibrium?

A increasing the temperature


B decreasing the temperature
C decreasing the pressure
D adding a catalyst

17 The equation shows the reaction for the formation of sulphur trioxide.

2SO2(g) + O2(g) 2SO3(g) ∆H = –197 kJ

Which change in reaction conditions would produce more sulphur trioxide?

A adding more catalyst

B decreasing the pressure

C increasing the temperature


D removing some sulphur trioxide
18 At 400 °C the reaction between hydrogen and iodine reaches an equilibrium.

H2(g) + I2(g) 2HI(g) ∆H = –13 kJ

Which change in conditions would increase the percentage of hydrogen iodide in the equilibrium
mixture?

A a decrease in pressure
B a decrease in temperature
C an increase in pressure
D an increase in temperature

19 The equation shows a reversible reaction.

N2O4(g) 2NO2(g)

The forward reaction is endothermic.

Which of these changes will increase the yield of NO2?

pressure temperature

A decreased decreased
B decreased increased
C increased decreased
D increased increased

20 Which statement about catalysts is correct for a typical equilibrium reaction?

A A catalyst can be either an inorganic or an organic species.


B A catalyst does not take part in the reaction.
C A catalyst only speeds up the forward reaction.
D A catalyst provides the energy required to start a reaction.
21 When a solution containing silver ions is added to a solution containing iron(II) ions, an
equilibrium is set up.
+ 2+ 3+
Ag (aq) + Fe (aq) Ag(s) + Fe (aq)

The addition of which substance would not affect the amount of silver precipitated?
+ 2+ 3+
A Ag (aq) B Fe (aq) C Fe (aq) D H2O(l)

22 Which statement about catalysts is correct for a typical equilibrium reaction?

A A catalyst can be either an inorganic or an organic species.


B A catalyst does not take part in the reaction.
C A catalyst only speeds up the forward reaction.
D A catalyst provides the energy required to start a reaction.

23 Nitrogen reacts with oxygen.

N2(g) + O2(g) 2NO(g) ∆H = +170 kJ / mol

At equilibrium, which statement is true?

A The concentration of nitrogen present will change with time.

B The forward and backward reaction are taking place at the same rate.
C The forward reaction releases heat energy.
D There are more molecules on the left hand side of the equation than on the right.

24 The equation shows a reaction in the Contact process.

2SO2(g) + O2(g) 2SO3(g) ∆H = –98 kJ / mol

Which change would move the position of equilibrium to the left?

A adding more O2

B increasing the pressure


C increasing the temperature
D removing SO3 from the reacting mixture

25 Ammonia is made by a reversible reaction between nitrogen and hydrogen.

The equation for the reaction is shown.

N2(g) + 3H2 (g) 2NH3(g) ∆H is negative


What is the effect of increasing the pressure in this process?

A Less ammonia is formed.


B Less heat is produced.
C More ammonia is formed.
D The reaction slows down.

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