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Report Sheet: Color: Cyan Color: White Color: Colorless Color: Colorless

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CHEMICAL ACTIVITY AND CORROSION OF METALS

Report sheet

A. Activity of Metals

1. Write the color change observed on the metal and the solution after the addition of the
solution to the metal.

Copper(II) Magnesium Zinc chloride Iron(II) sulfate


sulfate sulfate
Color: Cyan Color: White Color: Colorless Color: Colorless

Copper
NO NO NO
Color:
REACTION REACTION REACTION
Bronze

Reaction: Reaction:
Magnesiu
M: Dark Blue NO M: Blackish
m
S: Cyan REACTION S: Colorless
Color:
Silverish

Zinc Reaction: Reaction:


Color: M: Blackish NO M: Greyish
Blueish S: Light Cyan REACTION S: Colorless
Gray

Iron Reaction:
Color: M: Brown NO NO
Silvery- S: Cyan REACTION REACTION
Gray

2. Arrange the metals according to decreasing activity.

Most reactive Least reactive


Magnesium (Mg), Zinc (Zn), Iron (Fe), Copper (Cu)
3. Write the chemical equations for the reactions that occurred between the metal and
solution. What type of chemical reaction is taking place?

Magnesium in Copper Sulfate: Oxidation Reduction Reaction Single displacement

Oxidation: Mg(s) → Mg2+(aq) + 2e-


Reduction: Cu2+(aq) + 2e- → Cu(s)
Full Reaction: Mg (s) + Cu2+ (aq) → Cu (s) + Mg2+ (aq)

Magnesium in Iron Sulfate: Oxidation Reduction Reaction Single displacement

Oxidation: Mg(s) → Mg2+(aq) + 2e–


Reduction: Fe3+(aq) + 3e– → Fe(s)

Full Reaction: Mg(s) + Fe2+ (aq) → Fe(s) + Mg2+(aq)

Zinc in Copper Sulfate: Oxidation Reduction Reaction Single displacement

Oxidation: Zn(s) → Zn2+(aq) + 2e-


Reduction: Cu2+(aq) + 2e- → Cu(s)
Full Reaction: Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)

Zinc in Iron Sulfate: Oxidation Reduction Reaction Single displacement

Oxidation: Zn(s) → Zn2+(aq) + 2e-


Reduction: Fe3+(aq) + 3e– → Fe(s)
Final Reaction: Zn(s) + Fe2- (aq) → Zn2- (aq) + Fe (s)

Iron in Copper Sulfate: Oxidation Reduction Reaction Single displacement

Oxidation: Fe(s) → Fe2+(aq) + 2 e-


Reduction: Cu2+(aq) + 2e- → Cu(s)
Final Reaction: Fe(s) + Cu2+(aq) = Fe2+(aq) + Cu (s)

B. Preparation of Agar

1. Give the function of each of the following materials in the preparation of the agar media.
a. Sodium chloride- maintains salt concentration in the medium so that it will turn into
saltwater that is an enhanced conductor than regular water.

a. Agar- used for the cultivation of microbes supporting growth of a wide range of non-
fastidious organisms.

b. Phenolphthalein solution- acid base indicator that will change color when exposed to
normal alkaline conditions in the agar.

b. Potassium ferricyanide solution- reacts with ferrous iron in acidic solutions to


produce the insoluble blue pigment.

c. Agar- used for the cultivation of microbes supporting growth of a wide range of non-
fastidious organisms.

E. Types of Corrosion

1. What does the color patches signify? Represent with balance equations, the reactions
that produced the different colors.

Blue Patches – Presence of iron ions due to corrosion


Pink – Indicates OH- ion due to corrosion
Redox reaction:
Oxidation: Fe(s) → Fe2+(aq) + 2 e-
Reduction: 2H2O + 1/2O2 + 2e- →2OH-
Final Reaction: Fe + H2O → FeO + H2
Fe2+ (aq) + 2OH– (aq) → Fe (OH)2(s)

2. On the circle provided, draw the observed color developed on the different iron nails.
Indicate the position of the color patches observed. Label the type of nails properly.

Scenario A. Straight nail and bent a.What kind of corrosion exhibited the bent
nail nail?
-Stress Corrosion

Nail with
copper wire Straight Nail
b. What happens to the structure of the nail
when it is bent? How is this related to
corrosion

When the nail is bent it will cause a stress in


the bent area that allows faster oxidation of
Iron ions.

Bent Nail
Blue Coloration: Head, the Tip of
the nail, and the bent area.
Pink Coloration: In between the
ends of the nail and the bent area.
Scenario B. Nail hammered at the c. What type of corrosion is demonstrated here?
middle and nail heated until red hot -Stress Corrosion and High Temperature
then cooled Corrosion

Heated Nail

d. What happens to structure of metals when


they are heated and how is this related to
corrosion?

When a metal is heated, its size will expand.


The corrosion will accelerate because the
Hammered Nail electrochemical process will accelerate at
higher temperature.
Blue Coloration: Head and the tip
of the nail.
Pink Coloration: In between the
ends of the nail. The hammered nail
has more pink coloration than heated
nail

Scenario C. Nail wrapped with Cu, e. What type of corrosion was shown in this
Al and Sn experiment?
-Galvanic Corossion
f. Which of the following metals can act as an
example of cathodic protection? Explain
your answer.
Aluminum Metals like Copper and Tin have high
Tin covered
covered Nail
Nail chance of being use as cathodes because they
are less reactive than the Iron nail.

Blue Coloration: NONE


Pink Coloration: All area of the
nails except to the covered area.

g. Which of the following metals can act as an


example of anodic protection? Explain your
answer.
Aluminum would be the best fit to be
used since it is more reactive than the
iron and it can act as sacrificial anode to
protect the cathode metal.

Scenario D. Nail wrapped with Mg h. Which of the following scenario is an


ribbon and nail beside Mg ribbon example of a sacrificial anode?

Iron Nail Nail + Magnesium


and Ribbon Nail wrapped with a Magnesium Ribbon

Magnesium Ribbon
i. How can a sacrificial anode prevent
corrosion?

A sacrificial anode prevents


corrosion by flowing a current to the
corrosion of the cathode and moves the
corrosion toward the anode.

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