Safety Data Sheet

Revision Number: 004.1 Issue date: 04/26/2018

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE FREKOTE FREWAX known IDH number: 548972
as FREKOTE® FREWAX®
RELEASING INT
Product type: Mold Release Item number: 38411
Restriction of Use: None identified Region: Canada
Company address: Contact information:
Henkel Canada Corporation Telephone: +1 (905) 814-6511
Meadowpine Boulevard 2515
Mississauga, Ontario L5N 6C3

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: FLAMMABLE LIQUID AND VAPOR.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.

HAZARD CLASS HAZARD CATEGORY

FLAMMABLE LIQUID 3
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
ASPIRATION HAZARD 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container tightly
closed. No release into water. Use explosion-proof equipment. Use non-sparking tools. Take
action to prevent static discharges. Avoid breathing vapors, mist, or spray. Wash affected area
thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective
gloves, eye protection, and face protection.
Response: IF SWALLOWED: Immediately call a physician or poison control center. If on skin (or hair):
Take off immediately all contaminated clothing. IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you
feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Do NOT induce vomiting. If skin irritation
occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off
contaminated clothing. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Keep cool. Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.
IDH number: 548972 Product name: LOCTITE FREKOTE FREWAX known as FREKOTE® FREWAX® RELEASING INT

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Classification complies with Canadian Hazardous Products Regulations (WHMIS 2015) and is consistent with the provision of the United
Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Weight %*
Naphtha (petroleum), hydrotreated heavy
64742-48-9 70 - 80
(<0.1% benzene)
Hydrocarbons, C9-C10, n-alkanes,
1174921-73-3 10 - 20
isoalkanes, cyclics, <2% aromatics
Reaction product of tris(n-
methylamino)methylsilane (TMAS) and
1432471-92-5 1-5
silanol terminated polydimethylsiloxane
(PDMS)
Octane 111-65-9 1-5
Talc 14807-96-6 0.1 - 1

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Remove contaminated clothing and footwear. Immediately flush skin with
plenty of water (using soap, if available). If symptoms develop and persist, get
medical attention. Wash clothing before reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get immediate medical attention.

Ingestion: Keep individual calm. Do not induce vomiting: contains petroleum distillates
and/or aromatic solvents. If vomiting occurs, prevent aspiration by keeping the
patient's head below the knees. Never give anything by mouth to an
unconscious person. Get immediate medical attention.

Symptoms: See Section 11.

Notes to physician: This material is an aspiration hazard. Potential danger from aspiration must
be weighed against possible oral toxicity when deciding whether to induce
vomiting.

5. FIRE FIGHTING MEASURES

Extinguishing media: Carbon dioxide. Dry powder. Alcohol-resistant foam. Do not use high volume
water jet.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear. Water may be unsuitable as an extinguishing media, but may be
helpful in keeping adjacent containers cool. Keep personnel upwind of fire.

Unusual fire or explosion hazards: Hydrocarbon solvents are basically non-conductors of electricity and can
become electrostatically charged during mixing, filtering or pumping at high
flow rates. If this charge reaches a significantly high level, sparks can form
that may ignite vapors of flammable liquids. Do not handle or store near an
open flame, heat or other sources of ignition. Vapors may form explosive
mixtures with air.

IDH number: 548972 Product name: LOCTITE FREKOTE FREWAX known as FREKOTE® FREWAX® RELEASING INT
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 Hazardous combustion products: Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways. Advise authorities if product
has entered or may enter sewers, water sources or extensive land areas.
Prevent further leakage or spillage if safe to do so. This product is insoluble in
water and will float on surface.

Clean-up methods: Remove all sources of ignition. Ventilate area. Wear suitable protective
clothing, gloves and eye/face protection. Soak up with inert absorbent material
(e.g. sand, silica gel, acid binder, universal binder, sawdust). Spilled liquid is
combustible and can be ignited by heat, flames, sparks, or other sources of
ignition. Avoid inhalation of vapor, fumes, dust and/or mist from the spilled
material. Keep upwind of the spilled material and isolate exposure. Store in a
closed metal container until ready for disposal.

7. HANDLING AND STORAGE

Handling: During use and until all vapors are gone: Keep area ventilated - do not
smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical
tools and appliances, and any other sources of ignition. Prevent contact with
eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly
after handling. Make sure containers are properly grounded before use or
transfer of material. For operations where eye or face contact could occur,
provide safety shower and eyewash fountain. Refer to Section 8.

Storage: For safe storage, store at or below 48.8 °C (119.8 °F)

Store away from heat, sparks, flames, or other sources of ignition. Keep
container closed.

Shelf Life Statement: Not available.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

Naphtha (petroleum), hydrotreated heavy (<0.1% 100 ppm (400
None None 196 ppm TWA
benzene) mg/m3) PEL
Hydrocarbons, C9-C10, n-alkanes, isoalkanes,
None None None None
cyclics, <2% aromatics
Reaction product of tris(n-
methylamino)methylsilane (TMAS) and silanol None None None None
terminated polydimethylsiloxane (PDMS)
500 ppm (2,350
Octane 300 ppm TWA None None
mg/m3) PEL
0.1 mg/m3 TWA
Respirable.
2 mg/m3 TWA
Talc 2.4 MPPCF TWA None 50 ppm
Respirable fraction.
Respirable.
20 MPPCF TWA

Engineering controls: Use explosion-proof mechanical ventilation and local exhaust to control
contaminants to within their occupational exposure limits during the use of this
product.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed
established exposure limits exists.

IDH number: 548972 Product name: LOCTITE FREKOTE FREWAX known as FREKOTE® FREWAX® RELEASING INT
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 Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color: Colorless
Odor: Mild, Solvent
Odor threshold: Not available.
pH: Not applicable
Vapor pressure: 21 mbar
Boiling point/range: 141 °C (285.8 °F)1,013 hPa
Melting point/ range: Not determined
Specific gravity: 0.754
Vapor density: Heavier than air.
Flash point: 28 °C (82.4 °F) Tagliabue closed cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Slower than ether.
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available.
VOC content: 754 g/l of coating
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Risk of ignition.Stable under normal conditions of storage and use.

Hazardous reactions: Will not occur.

Hazardous decomposition Hydrocarbons. Oxides of carbon. Traces of Ammonia. Amines.

products:

Incompatible materials: Strong oxidizing agents. Strong acids. Strong alkalis. Humid air. Water.

Reactivity: Not available.

Conditions to avoid: Exposure to air or moisture over prolonged periods. Avoid static discharge. Keep away from
open flames, hot surfaces and sources of ignition. Vapors may form explosive mixtures with
air. Spray mist may be flammable at temperatures below the flash point. Fire or intense heat
may cause violent rupture of packages. Protect from direct sunlight.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

IDH number: 548972 Product name: LOCTITE FREKOTE FREWAX known as FREKOTE® FREWAX® RELEASING INT
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 Potential Health Effects/Symptoms

Inhalation: Vapors and mists will irritate nose and throat and possibly eyes.
Skin contact: Causes skin irritation. Solvent action can dry and defat the skin, causing the skin to crack,
leading to dermatitis.
Eye contact: Causes serious eye irritation.
Ingestion: This product may be fatal if it is swallowed. Aspiration may occur during swallowing or vomiting,
resulting in lung damage. Central nervous system depression, including dizziness, drowsiness,
fatigue, nausea, headache, unconsciousness.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Naphtha (petroleum), hydrotreated heavy
None Irritant
(<0.1% benzene)
Hydrocarbons, C9-C10, n-alkanes,
None No Data
isoalkanes, cyclics, <2% aromatics
Reaction product of tris(n-
methylamino)methylsilane (TMAS) and
None No Data
silanol terminated polydimethylsiloxane
(PDMS)
Octane Inhalation LC50 (Rat, 4 h) = 118 mg/l Central nervous system, Irritant, Lung
Irritant, Lung, Some evidence of
Talc None
carcinogenicity

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Naphtha (petroleum), hydrotreated heavy
No No No
(<0.1% benzene)
Hydrocarbons, C9-C10, n-alkanes,
No No No
isoalkanes, cyclics, <2% aromatics
Reaction product of tris(n-
methylamino)methylsilane (TMAS) and
No No No
silanol terminated polydimethylsiloxane
(PDMS)
Octane No No No
Talc No Group 2B No

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

Canada Transportation of Dangerous Goods - Ground

Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
Identification number: UN 1866
Packing group: III

IDH number: 548972 Product name: LOCTITE FREKOTE FREWAX known as FREKOTE® FREWAX® RELEASING INT
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 International Air Transportation (ICAO/IATA)
Proper shipping name: Resin solution
Hazard class or division: 3
Identification number: UN 1866
Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: RESIN SOLUTION
Hazard class or division: 3
Identification number: UN 1866
Packing group: III

15. REGULATORY INFORMATION

Canada Regulatory Information

CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the
Domestic Substances List or the Non-Domestic Substances List.

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components of this product are listed on the U.S. Toxic Substances Control Act (TSCA)
inventory or are exempt from listing because a Low Volume Exemption (LVE) has been
granted in accordance with 40 CFR 723.50.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: 3

Prepared by: Product Safety and Regulatory Affairs

Issue date: 04/26/2018

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 548972 Product name: LOCTITE FREKOTE FREWAX known as FREKOTE® FREWAX® RELEASING INT
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