First developer

SAFETY DATA SHEET

[In accordance with the criteria of Regulation No 1907/2006 (REACH) as amended

Date of update: 29.04.2020 Version: 2.0/EN

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

First developer
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: photographic developer.
Uses advised against: not determined.
1.3 Details of the supplier of the safety data sheet
Manufacturer: Adox Fotowerke GmbH
Address: Pieskower Str. 30A, 15526 Bad Saarow, Germany
Telephone/fax: 033631/645927
E-mail address for a competent person responsible for SDS: info@adox.de
1.4 Emergency telephone number
112

Section 2: Hazards identification

2.1 Classification of the substance or mixture

Skin Sens. 1 H317, Eye Dam. 1 H318, Muta. 2 H341, Carc. 2 H351, Aquatic Chronic 3 H412
May cause an allergic skin reaction. Causes serious eye damage. Suspected of causing genetic defects. Suspected
of causing cancer. Harmful to aquatic life with long lasting effects.
2.2 Label elements
Hazard pictograms and signal words

DANGER

Names of substances mentioned on the label

Contains sodium metabisulphite; hydroquinone.
Hazard statements
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P501 Dispose of contents/container in accordance with local regulations.

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SAFETY DATA SHEET

[In accordance with the criteria of Regulation No 1907/2006 (REACH) as amended

Date of update: 29.04.2020 Version: 2.0/EN

2.3 Other hazards

The components of this mixture do not meet the criteria for PBT or vPvB in accordance with Annex XIII
of REACH.

Section 3: Composition/information on ingredients

3.1 Substances
Not applicable.
3.2 Mixtures
CAS: 7681-57-4 sodium metabisulphite
EC: 231-673-0 Acute Tox. 4 H302, Eye Dam. 1 H318, EUH031*
Index number: 016-063-00-2 2-3 %
REACH number:
01-2119531326-45-XXXX
CAS: 584-08-7 potassium carbonate
EC: 209-529-3 Skin Irrit. 2 H315, Eye Irrit. 2 H319, STOT SE 3 H335
2-3 %
Index number: -
REACH number: -
CAS: 123-31-9 hydroquinone
EC: 204-617-8 Acute Tox. 4 302, Eye Dam. 1 H318, Skin Sens. 1 H317, Muta. 2 H341, Carc
Index number: 604-005-00-4 2 H351, Aquatic Acute 1 H400 (M=10), Aquatic Chronic 1 H410 (M=1) 1-<2,5 %
REACH number:
01-2119524016-51-XXXX
CAS: 1310-73-2 sodium hydroxide
EC: 215-185-5 Met. Corr. 1 H290, Skin Corr. 1A H314, Eye Dam. 1 H318
Index number: 011-002-00-6 Specific concentration limits:
REACH number: Eye Irrit. 2 H319: 0,5 % ≤ C < 2 % < 0,5 %
01-2119457892-27-XXXX Skin Corr. 1A H314: C ≥ 5 %
Skin Corr. 1B H314: 2 % ≤ C < 5 %
Skin Irrit. 2 H315: 0,5 % ≤ C < 2 %
*Additional code specifying the type of threat.

Full text of each relevant H phrase is given in section 16 of SDS.

Section 4: First aid measures

4.1 Description of first aid measures

Skin contact: consult a doctor if disturbing symptoms appear. Take off contaminated clothing. Wash the
contaminated skin thoroughly with plenty of water with soap.
Eye contact: consult a doctor immediately. Protect the non-irritated eye, remove contact lenses. Wash the
contaminated eyes with plenty of water for 10-15 minutes. Avoid powerful water stream – risk of cornea
damage. Put on sterile dressing.
Ingestion: consult a doctor if disturbing symptoms appear. Rinse mouth with water, give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Inhalation: consult a doctor if disturbing symptoms appear. Move the victim to fresh air. Keep victim warm and
calm.
4.2 Most import ant symptoms and effects, both acute and delayed
Skin contact: prolonged contact may cause redness, skin dryness, itch, rash or other allergic reactions.
Eye contact: possible redness, tearing, burning sensation pain, irritation, risk of eye damage.
Ingestion: possible stomach pain, nausea, vomiting.
Inhalation: high concentration of vapours and mists may cause respiratory tract irritation.
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[In accordance with the criteria of Regulation No 1907/2006 (REACH) as amended

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Other effects of exposure: suspected of causing genetic defects. Suspected of causing cancer.

4.3 Indication of any immediate medical attention and special treatment needed
Physician makes a decision regarding further medical treatment after thoroughly examination of the injured.

Section 5: F i r e f i gh t i n g m e a s u r e s

5.1 Extinguishing media

Suitable extinguishing media: adapt the extinguishing media to surrounding materials.
Unsuitable extinguishing media: water jet – risk of the propagation of the flame.
5.2 Special hazards arising from the substance or mixture
During the fire, the product may produce toxic fumes of carbon oxides or other unidentified thermal
decomposition products. Do not inhale combustion products, they can be dangerous for human health.
5.3 Advice for firefighters
Personal protection typical in case of fire. Do not stay in the fire zone without self-contained breathing
apparatus and protective clothing resistant to chemicals. Cool the endangered containers with water spray from
a safe distance. Collect used extinguishing media.

Section 6: A c c i d e n t a l r e l e a se m e a s u r e s

6.1 Personal precautions, protective equipment and emergency procedures

Limit the access for the outsiders into the breakdown area, until the suitable cleaning operations are completed.
Ensure that only the trained personnel removes the effects of the accident. In case of large spills, isolate the
exposed area. Use personal protective measures. Avoid skin and eyes contamination. Ensure adequate
ventilation.
6.2 Environmental precautions
In case of release of large amounts of the product, it is necessary to take appropriate steps to prevent it from
spreading into the environment. Notify relevant emergency services.
6.3 Methods and material for containment and cleaning up
Large leakage: isolate places where liquid accumulates; pump the collected liquid out of contaminated area.
Small leakage: collect with liquid absorbing materials (e.g. soil, sand, silica, universal binding agent, vermiculite,
etc.) and place it in labeled containers. Treat the collected material as waste. Clean the contaminated place and
ventilate it.
6.4 Reference to other sections
Personal protective equipment – see section 8. Appropriate conduct with waste product – see section 13.

Section 7: Handling and storage

7.1 Precautions for safe handling

Handle in accordance with good occupational hygiene and safety practices. Avoid contact with skin and eyes.
Before break and after work wash hands. Use only in accordance with the identified purpose. Ensure adequate
ventilation of area, where the product is used. Use personal protective equipment.
7.2 Conditions for safe storage, including any incompatibilities
Keep only in tightly closed, original containers in a dry, cool and well-ventilated area. Keep away from food,
beverages or animal feed. Avoid direct exposure to sunlight. Do not store with incompatible materials
(see subsection 10.5).

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SAFETY DATA SHEET

[In accordance with the criteria of Regulation No 1907/2006 (REACH) as amended

Date of update: 29.04.2020 Version: 2.0/EN

7.3 Specific end use(s)

No information about other uses than those mentioned in subsection 1.2.

Section 8: Exposure controls/personal protection

8.1 Control parameters

No occupational exposure limit values were established for the components of the mixture.
Legal basis: Commission Directive 2006/15/EC, 2000/39/EC, 2009/161/EC, 2017/164/EU, 2019/1831/EU.
Please check any national occupational exposure limit values in your country.
DNEL for sodium metabisulphite [CAS 7681-57-4]
Workers, Long-term - systemic effects, inhalation: 225 mg/m3
Population, Long-term - systemic effects, inhalation: 66 mg/m3
Population, Long-term - systemic effects, oral: 8,6 mg/kg bw/day
DNEL for potassium carbonate [CAS 584-08-7]
Workers, Long-term - local effects, inhalation: 10 mg/m3
PNEC for sodium metabisulphite [CAS 7681-57-4]
Fresh water: 1 mg/l
Marine water: 0,1 mg/l
Sewage treatment plant: 75,4 mg/l
8.2 Exposure controls
Use the product in accordance with good occupational hygiene and safety practices. Ensure adequate
ventilation of the area where the product is used and stored. Before break and after work wash hands carefully.
Do not eat, drink or smoke when using the product. Take off contaminated clothing and wash it before next use.
Provide eye fountain.
Hand and body protection
Use protective gloves resistant to the product. Material for gloves choose individually at the worplace. In case
of a short contact, use protective gloves with effectiveness level ≥ 2 (breakthrough time > 30 min.). In case of
a prolonged contact, use protective gloves with effectiveness level = 6 (breakthrough time > 480 min.). Wear
protective clothing.
When using protective gloves during work with chemical products, it should be noted that the efficacy levels and
corresponding breakthrough times do not indicate actual times of protection at a particular workplace, because the protection
can be affected by many factors, e.g. temperature, other substances etc. If there are any signs of degradation, damage or
change in appearance (colour, flexibility, shape), it is recommended to replace the gloves with a new pair. Please follow the
manufacturer's instructions, not only in terms of gloves' usage, but also in terms of their cleaning, maintenance and storage. It
is also important to know how to take off the gloves in order to avoid hands contamination.
Eyes protection
Use safety glasses.
Respiratory protection
Use respiratory protection in case of insufficient ventilation.
Applied personal protective equipment must comply with the requirements of the Regulation (EU) 2016/425. The choice of
personal protective equipment should be made taking into account the concentration and form of the substance in the
workplace, the routes of exposure, the time of exposure and activities performed by the employee. The employer is obliged to
provide protective equipment relevant to performed activities and in accordance with all quality requirements, including its
maintenance and cleaning.
Environmental exposure controls
Do not allow large quantities of the product to contaminate ground water, drains, sewages or soil. Possible
emissions from the ventilation systems and processing equipment should be controlled in order to determinate
their compatibility with environmental protection regulations.

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SAFETY DATA SHEET

[In accordance with the criteria of Regulation No 1907/2006 (REACH) as amended

Date of update: 29.04.2020 Version: 2.0/EN

Section 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

physical state: liquid
colour: colourless
odour: odourless
odour threshold: not determined
pH (25,8 °C): 9,96
melting point/freezing point: not determined
initial boiling point and boiling range: not determined
flash point: not determined
evaporation rate: not determined
flammability (solid, gas): not applicable
upper/lower flammability or explosive limits: not determined
vapour pressure: not determined
vapour density: not determined
density (26,3 °C): 1,076 g/cm3
solubility(ies): solutable in water
partition coefficient: n-octanol/water: not determined
auto-ignition temperature: not determined
decomposition temperature: not determined
explosive properties: not display
oxidising properties: not display
viscosity: not determined
9.2 Other information
There are no additional test results.

Section 10: Stability and reactivity

10.1 Reactivity
Product is reactive. Product does not undergo a dangerous polymerization. See also subsections 10.3-10.5.
10.2 Chemical stability
The product is stable under normal conditions of use and storage.
10.3 Possibility of hazardous reactions
Hazardous reactions are not known.
10.4 Conditions to avoid
Avoid heat sources and direct exposure to sunlight.
10.5 Incompatible materials
Strong oxidizing agents, acids, bases.
10.6 Hazardous decomposition products
Not known.

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Section 11: Toxicological information

11.1 Information on toxicological effects

Toxicity of components
potassium carbonate [CAS 584-08-7]
LD50 (oral, rat) > 2000 mg/kg
LD50 (dermal, rabbit) > 2000 mg/kg
sodium metabisulphite [CAS 7681-57-4]
LD50 (oral, rat) 1540 mg/kg
LD50 (dermal, rat) > 2000 mg/kg
Toxicity of mixture
Acute toxicity
ATEmix (oral) > 2000 mg/kg
The acute toxicity estimate (ATEmix) for the classification of a substance in a mixture was determined using the
appropriate conversion value from Table 3.1.2 in Annex I to CLP as amended.
Based on available data, the classification criteria are not met.
Skin corrosion/irritation
Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation
May cause an allergic skin reaction.
Germ cell mutagenicity
Suspected of causing genetic defects.
Carcinogenicity
Suspected of causing cancer.
Reproductive toxicity
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.

Section 12: Ecological information

12.1 Toxicity
Toxicity of components
potassium carbonate [CAS 584-08-7]
Toxicity for invertebrates EC50 200 mg/l/48 h (Daphnia magna)
sodium metabisulphite [CAS 7681-57-4]
Toxicity for fish: LC50 > 150 mg/l (Oncorhynchus mykiss)
Toxicity for daphnia: EC50: 89 mg/l/48h
Toxicity for algae: EC50 48 mg/l (Scenedesmus subspicatus)

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SAFETY DATA SHEET

[In accordance with the criteria of Regulation No 1907/2006 (REACH) as amended

Date of update: 29.04.2020 Version: 2.0/EN

Toxicity of mixture
Harmful to aquatic life with long lasting effects..
12.2 Persistence and degradability
No data.
12.3 Bioaccumulative potential
No data.
12.4 Mobility in soil
Mobility of components of the mixture in soil depends on the hydrophilic and hydrophobic properties and biotic
and abiotic conditions of soil, including its structure, climatic conditions, seasons and soil organisms.
12.5 Results of PBT and vPvB assessment
Components of the mixture do not meet the PBT or vPvP criteria.
12.6 Other adverse effects
The mixture is not classified as hazardous to the ozone layer. Consider other harmful effects of individual
components of the mixture on the environment (e.g., endocrine disrupting potential, global warming potential).

Section 13: Disposal considerations

13.1 Waste treatment methods

Disposal methods for the product: disposal in accordance with the local legislation. Store residues in original
containers. Recycle, if possible. Waste code should be given in the place of waste formation.
Disposal methods for used packing: reuse/recycle/liquidate empty containers in accordance with the legislation
in force. Only containers completely empty can be recycled.
Legal basis: Directive 2008/98/EC as amended, 94/62/EC as amended.

Section 14: Transport information

14.1 UN number
Not applicable. Product is not classified as dangerous during transport (by land, by sea or by air).
14.2 UN proper shipping name
Not applicable.
14.3 Transport hazard class(es)
Not applicable.
14.4 Packing group

Not applicable.
14.5 Environmental hazards
Not applicable.
14.6 Special precautions for user
Not applicable.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable.

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SAFETY DATA SHEET

[In accordance with the criteria of Regulation No 1907/2006 (REACH) as amended

Date of update: 29.04.2020 Version: 2.0/EN

Section 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning
the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency,
amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)
No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC
and 2000/21/EC as amended.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC,
and amending Regulation (EC) No 1907/2006 as amended.
Commission Regulation (EU) No 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European
Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain
Directives as amended.
European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste as
amended.
Commission Directive 2000/39/EC of 8 June 2000 establishing a first list of indicative occupational exposure limit values
in implementation of Council Directive 98/24/EC on the protection of the health and safety of workers from the risks related
to chemical agents at work.
Commission Directive 2006/15/EC of 7 February 2006 establishing a second list of indicative occupational exposure limit
values in implementation of Council Directive 98/24/EC and amending Directives 91/322/EEC and 2000/39/EC.
Commission Directive 2009/161/EU of 17 December 2009 establishing a third list of indicative occupational exposure limit
values in implementation of Council Directive 98/24/EC and amending Commission Directive 2000/39/EC.
Commission Directive 2017/164/EU of 31 January 2017 establishing a fourth list of indicative occupational exposure limit
values pursuant to Council Directive 98/24/EC, and amending Commission Directives 91/322/EEC, 2000/39/EC
and 2009/161/EU.
Commission Directive 2019/1831/EU of 24 October 2019 establishing a fifth list of indicative occupational exposure limit
values pursuant to Council Directive 98/24/EC and amending Commission Directive 2000/39/EC.
Regulation (EU) No 2016/425 of the European Parliament and of the Council of 9 March 2016 on personal protective
equipment and repealing Council Directive 89/686/EEC.
15.2 Chemical safety assessment
A Chemical Safety Assessment is not required for mixtures.

Section 16: Other information

Full text of indicated H phrases mentioned in section 3

H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H341 Suspected of causing genetic defects
H351 Suspected of causing cancer.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects
EUH031 Contact with acids liberates toxic gas.
Clarification of aberrations and acronyms
PBT Persistent, Bioaccumulative and Toxic substance
vPvB very Persistent, very Bioaccumulative substance.
Acute Tox. 4 Acute toxicity, category 4
Skin Corr. 1A,1B Skin corrosion cat. 1A,1B

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Eye Irrit. 2 Eye irritation category 2

Skin Irrit. 2 Skin irritation category 2
Skin Sens. 1 Skin sensitization act. 1, 1B
Met. Corr. 1 Substance or mixture corrosive to metals cat. 1
Eye Dam. 1 Serious eye damage category 1
Muta. 2 Germ cell mutagenicity cat. 2
Carc. 2 Carcinogenicity category 2
Aquatic Chronic 1 Hazardous to the aquatic environment (chronic) category 1,2
Aquatic Acute 1 Hazardous to the aquatic environment (acute) category 1
STOT SE 3 Specific target organ toxicity — single exposure category 3
Trainings
Before commencing working with the product, the user should learn the Health & Safety regulations, regarding
handling chemicals, and in particular, undergo a proper workplace training.
Key literature references and sources of data
This SDS was prepared on the basis of sheets of the individual components, literature data, online databases
(eg. ECHA, TOXNET, COSING) as well as our knowledge and experience, taking into account current legislation.
Procedures used to classify the mixture according to Regulation EC 1272/2008
Classification was based on test results and data on the content of hazardous substances and prepared using
calculation method under the guidance of Regulation 1272/2008/EC (CLP) as amended.
Other data
Safety Data Sheet made by: „THETA” Doradztwo Techniczne
Changes: section: 1-16
This SDS annuls and replaces all previous versions
The information above is based on a current available data concerning the product, but also on the experience and
knowledge in this field of the producer. They are neither a quality description of the product nor a guarantee of particular
features. They are to be treated as aid to safety in transport, storage and usage of the product. That does not free the user
from the responsibility of improper usage of the information above and also of improper compliance with the law norms
in the field.

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