Condensate Sweet MSDS

Material Safety Data Sheet

1. Product and Company Identification

Product Name: Condensate, Sweet

Synonym: Condensate
Product use: Refinery feedstock
Manufacturer: Keyera
Address: Suite 600, Sunlife Plaza West
144 – 4th Avenue SW
Calgary, AB, T2P 3N4
Emergency Contact: 1-866-377-7110

2. Hazards Identification

EMERGENCY OVERVIEW
This product is highly flammable! Contains benzene, a proven human carcinogen.
Vapors are heavier than air and may travel considerable distances to a source of ignition
and flash back. Vapors may spread along the ground and may enter sewers,
basements, and other confined spaces. Refer to North American Emergency Response
Guide (NAERG) 128.
POTENTIAL HEALTH EFFECTS/ROUTES OF EXPOSURE
Eye: This product is a moderate eye irritant and chronic exposure may
cause reddening of the eye.
Skin: This product is a moderate skin irritant and repeated or prolonged
contact may defat the skin.
Ingestion: If ingested, abdominal cramping, vomiting, and diarrhea may
occur. Aspiration of liquid into the lungs may cause chemical
pneumonia, severe lung damage and respiratory failure.
Inhalation: Potential effects target the Central Nervous System (CNS), liver,
and kidneys. The benzene component is a known human
carcinogen that may result in aplastic anemia and leukemia
(cancer of the bone marrow).

3. Composition/Information on Ingredients
Ingredient Name % CAS No.
Natural gas condensates 100 68919-39-1
Butane(s) 1-5 75-28-5
iso-Pentane 15-30 78-78-4
n-Pentane 15-30 109-66-0
Cyclopentane 1-5 287-92-3
Methylcyclopentane 1-6 96-37-7
n-Hexane 8-20 110-54-3
Cyclohexane 2-5 110-82-7
Methylcyclohexane 1-6 108-87-2
Heptane 5-20 142-82-5
Octane 1-15 111-65-9

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 Condensate Sweet MSDS
Benzene 1-3 71-43-2
Toluene 1-3 108-88-3
Ethylbenzene 0.1-1.5 100-41-4
Xylene 0-3 1330-20-7
1, 2, 4 Trimethylbenzene 0-4 25551-13-7
Condensate is a liquid hydrocarbon product associated with Natural Gas and is used as
refinery feedstock for petroleum products. This product is a commingled stream from
multiple petroleum facilities and is a complex mixture consistent with the definition within
WHMIS regulation CPR section 2. The listed components are provided as guidance
based on the available knowledge of the commingled stream.

4. First Aid Measures

Eyes: In case of contact with eyes, immediately flush with clean, low-
pressure water for at least 20 minutes. Hold eyelids open to
ensure adequate flushing. Seek medical attention.
Skin: Remove contaminated clothing. Wash contaminated areas
thoroughly with soap and water (waterless hand cleanser may be
used if water is not readily available). Obtain medical attention if
irritation or redness develops.
Ingestion: Do not induce vomiting because of the danger of aspiration the
fluid into the lungs. Obtain immediate medical attention.
Inhalation: Ensure your own safety and use the appropriate respiratory
protection to immediately remove the victim to an uncontaminated
area. Give CPR or artificial respiration as needed and give oxygen
if breathing is difficult. Keep victim at rest and get immediate
medical attention.

5. Fire Fighting Measures

FLAMMABLE PROPERTIES
Flammable Liquid
HAZARDOUS COMBUSTION PRODUCTS
During combustion carbon monoxide and/or carbon dioxide may be produced.
FIRE AND EXPLOSION HAZARDS
Product vapors are heavier than air and may travel considerable distances to sources of
ignition and flash back. Vapors may spread along the ground and may enter sewers,
basements, and other confined spaces. Vapors can be easily ignited by heat, sparks, or
flames.
EXTINGUISHING MEDIA
Small Fires: Dry chemical, CO2, water spray or regular foam.
Large Fires: Water spray, fog or regular foam. Use water spray or fog; do not use
straight streams. Move containers from fire area if possible without risk.
FIRE FIGHTING INSTRUCTIONS:
Water may be ineffective for fighting the fire, but may be used to cool fire-exposed
containers. Consider initial downwind evacuation for at least 800 meters (1/2 mile). Cool
containers with large quantities of water until well after the fire has been put out. Do not

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 Condensate Sweet MSDS
direct the water stream at the source of the leak. Withdraw immediately in case of rising
sound from venting safety devices or discoloration of tank. ALWAYS stay away from
tanks engulfed in fire. Fight fires from maximum distance and for massive fires, use
unmanned hose holders or monitor nozzles. If this is not possible, withdraw from the
area and let the fire burn. Approved self-contained breathing apparatus (SCBA) with full-
face piece and full protective firefighting clothing should be worn.
If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all
directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
UNUSUAL FIRE & EXPLOSION HAZARDS
Product floats on water and is capable of creating a fire hazard along path of runoff.

6. Accidental Release Measures

ACTIVATE SITE SPECIFIC EMERGENCY RESPONSE PLAN, IF AVAILABLE.
Small Spills: Ensure your own safety and use the appropriate respiratory protection.
An approved self-contained breathing apparatus (SCBA) with full-face piece may be
required. Remove all ignition sources. Ventilate the area and attempt to stop the leak if
possible without risk. Do not attempt to extinguish a fire unless the leak can be stopped.
Large Spills: Ensure your own safety and use the appropriate respiratory protection.
An approved self-contained breathing apparatus (SCBA) with full-face piece may be
required. Isolate spill or leak area immediately for at least 300 meters (1000 feet) in all
directions. Keep unauthorized personnel away and stay upwind. Keep out of low areas;
many vapors are heavier than air and will spread along ground and collect in low or
confined areas (sewers, basements, tanks). Do not discharge solid water stream pattern
into the liquid resulting in splashing. Do not flush down sewer or drainage systems; if
possible protect bodies of water by dyking. For large spills, recover liquid and remove
contaminated earth, place suitable absorbent materials into closed containers for
approved disposal.
Evacuation: Fire: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800
meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2
mile) in all directions.
Caution: Ensure your own safety and use the appropriate respiratory protection. An
approved self-contained breathing apparatus (SCBA) with full-face piece may be
required. Consideration should be given to environmental clean-up and waste material
generation when deciding if the use of large volumes of water is appropriate for non-fire
emergency situations. Clean-up crews must be properly trained and must utilize proper
protective equipment.

7. Handling and Storage

HANDLING PRECAUTIONS
Ensure your own safety and use the appropriate respiratory protection. An approved
self-contained breathing apparatus (SCBA) with full-face piece may be required. Handle
as a flammable liquid. Keep away from all sources of heat, sparks, open flame or any
sources of ignition, as well as flammable materials or oxidizers. Do not pressurize, cut,
heat, weld or expose such containers to sources of ignition. Use only with adequate

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 Condensate Sweet MSDS
ventilation and avoid breathing vapors. Ground and bond all lines and equipment.
Electrical equipment must be approved for classified areas. DO NOT siphon by mouth.
STORAGE PRECAUTIONS
Store in a cool, dry, ventilated area, out of sunlight and away from all sources of heat
and ignition sources. Avoid storage in low, confined locations or near incompatible
materials such as other flammable materials, oxidizers or materials that support
combustion. Reference the applicable standards for safe storage practices of petroleum
products.
WORK/HYGIENIC PRACTICES
An emergency eye wash station should be available in the vicinity of any potential splash
exposure. Use good personal hygiene practices. Avoid skin exposure and wash hands
before eating, drinking, smoking, or using toilet facilities. Do not eat, drink or smoke in
areas of use or storage. Promptly remove contaminated clothing and launder before
reuse. Use care when laundering to prevent the formation of flammable vapors which
could ignite via washer or dryer.

8. Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Ensure your own safety and use the appropriate respiratory protection. An approved
self-contained breathing apparatus (SCBA) with full-face piece may be required. Ensure
adequate ventilation to keep vapor and gas concentrations of this product below
occupational exposure and flammability limits, particularly in confined spaces. Electrical
equipment including ventilation systems should be approved for classified areas.
Showers and/or eyewash fountains should be provided within the immediate work area
for emergency use when there is any possibility of exposure to liquids.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: Wear chemical goggles or a full-face shield when handling this
product.
Skin Protection: Avoid contact with skin. Wear appropriate fire retardant and chemical
resistant gloves when handling this product.
Respiratory Protection: Ensure your own safety and use the appropriate respiratory
protection. An approved organic vapour respirator with face-piece appropriate for
concentrations the concentration exceeds the OEL (Occupational Exposure Limit).
When assessing the proper type of respiratory protection consider the occupational
exposure limits applicable to individual ingredients. Refer to CSA Standard “Selection,
Use and Care of Respirators” (Z94.4-02) and NIOSH Respirator Decision Logic for
additional guidance on respiratory protection.

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Exposure Limits
Ingredient Name CAS No. Occupational Exposure Limits
Natural gas condensates 68919-39-1 Not applicable
n-Butane 75-28-5 ACGIH TLV-TWA =1000ppm
iso-Pentane 78-78-4 ACGIH TLV-TWA =600ppm
n-Pentane 109-66-0 ACGIH TLV-TWA =600ppm
Cyclopentane 287-92-3 ACGIH TLV-TWA =600ppm
Methylcyclopentane 96-37-7 Not applicable
n-Hexane 110-54-3 ACGIH TLV-TWA =50ppm (skin)
Cyclohexane 110-82-7 ACGIH TLV-TWA =100ppm
Methylcyclohexane 108-87-2 ACGIH TLV-TWA =400ppm
Heptane 142-82-5 ACGIH TLV-TWA =400ppm
ACGIH TLV-STEL =500ppm
Octane 111-65-9 ACGIH TLV-TWA =300ppm
Benzene 71-43-2 ACGIH TLV-TWA =0.5ppm (skin)
ACGIH TLV-STEL =2.5ppm
Toluene 108-88-3 ACGIH TLV-TWA =600ppm
Ethylbenzene 100-41-4 ACGIH TLV-TWA =100ppm
ACGIH TLV-STEL =125ppm
Xylene 1330-20-7 ACGIH TLV-TWA =600ppm
1, 2, 4 Trimethylbenzene 25551-13-7 ACGIH TLV-TWA =25ppm
ACGIH – American Conference of Governmental Industrial Hygienists
TLV – Threshold Limit Value
TWA – Time Weighted Average
STEL – Short Term Exposure Limits

9. Physical and Chemical Properties

Appearance and state: Pale yellow to brown liquid
Odour: Hydrocarbon
Odour Threshold: Not available
Flash Point: <-35oC (Closed Cup)
Auto Ignition: 260oC (n-Pentane)
Lower Explosive Limit (%): 1.5 (n-Pentane)
Upper Explosive Limit (%): 7.8 (n-Pentane)
Boiling Point: >28oC
Melting Point: Not available
Vapor Pressure: 103 kPA @ 37.8oC
Vapor Density (Air = 1): >1
Viscosity: Not available
Specific Gravity: 0.65-0.67
Solubility (H2o): Slight
Percent Volatiles: 100%
Evaporation Rate: Not available

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10. Stability and Reactivity

STABILITY
Stable
CONDITIONS TO AVOID (STABILITY)
Material is stable under normal conditions but can rapidly become volatile. Avoid high
temperatures, open flames, sparks, welding, smoking, and other ignitions sources.
INCOMPATIBLE MATERIALS
Keep away from strong oxidizers, ignition sources, and heat.
HAZARDOUS DECOMPOSITION PRODUCTS
Irritating or toxic substances may be emitted upon thermal decomposition.
Decomposition products include carbon dioxide and carbon monoxide.
HAZARDOUS POLYMERIZATION
Will not occur

11. Toxicological Information

Chemical Name CAS No. LD50 LC50

Butane(s) 75-28-5 Not available Rat:658 mg/l/4Hrs
iso-Pentane 78-78-4 Not available Mouse: 14000 ppm
n-Pentane 109-66-0 Mouse (ivn): 446 Rat: 364 gm/m3 (4Hr)
mg/kg
Cyclopentane 287-92-3 Not available Not available
Methylcyclopentane 96-37-7 Not available Not available
n-Hexane 110-54-3 Rat (oral): 43.5 Mouse inhalation
mg/kg BW 48000 ppm/4 hr
Cyclohexane 110-82-7 Rat oral 8.0 Not available
mL/kg
Methylcyclohexane 108-87-2 Not available Not available
Heptane 142-82-5 Mouse, iv Not available
222 mg/kg
Octane 111-65-9 Not available Rat inhalation
118 g/cu m/4 hr
Benzene 71-43-2 Rat (oral): Rat ihl: 10,000 ppm
3306mg.kg 7hr
Toluene 108-88-3 Rat oral 5000 rats 8000 ppm for 4 hr.
mg/kg
Ethylbenzene 100-41-4 Rat oral 3500 Not available
mg/kg
Xylene 1330-20-7 LD50 Rat oral 4.3 Not available
g/kg
1, 2, 4 Trimethylbenzene 25551-13-7 Rat, oral 8970 Not available
mg/kg

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 Condensate Sweet MSDS
POTENTIAL HEALTH EFFECTS
Acute effects: Low concentrations may irritate eyes, skin, respiratory system, Central
Nervous System (CNS), and peripheral nervous system. May cause CNS depression,
cardiac sensitization, drowsiness, narcosis, and asphyxia.
Chronic effects: Potential chronic effects to this product include peripheral neuropathy
and blurred vision. Chronic exposure has resulted in aplastic anemia, acute myoblastic
leukemia, bone marrow depression, corneal vacuolization erythroleukemia, and even
death.
Sensitization: Butane is linked with cardiac sensitization.
Mutagenicity: Benzene is a weak mutagen.
Reproductive effects: Spontaneous abortion is possible for women exposed to
Toluene during pregnancy. Benzene exposure has been linked to menstrual changes,
spontaneous abortion and stillbirth. Xylene is embryotoxic.
Carcinogenicity: Benzene carcinogenic listings are as follows: Known Carcinogen
NTP, Known Human Carcinogen IARC Group 1 proven and Confirmed Human
Carcinogen ACGIH A1. Ethylbenzene is classified as a Possible Carcinogen IARC 2B.
Target organs: Central nervous system (CNS), heart, blood forming systems, liver and
kidneys, gastrointestinal tract and respiratory system.

12. Ecological Information

If released into soil, this product will absorb and may biodegrade in anaerobic conditions.
In water, it may become volatile. Photo-oxidation products include phenol, nitrophenols,
nitrobenzene, formic acid and peroxyacetyl nitrate.

13. Disposal Considerations

Maximize product recovery for reuse or recycling. Contaminated materials may be
classified as a hazardous waste due to the low flash point and benzene. Empty
containers can have residues that are subject to hazardous waste disposal
requirements. Dispose of waste in accordance with all applicable federal, provincial,
and/or local regulations.

14. Transport Information

PROPER SHIPPING NAME: Petroleum distillate, N.O.S.
TDG CLASS: 3
TDG IDENTIFICATION NUMBER: UN1268
TDG SHIPPING LABEL: Flammable liquid
PACKING GROUP: II
NAERG: Guide 128

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 Condensate Sweet MSDS

15. Regulatory Information

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)
Workplace Hazardous Materials Information Systems (WHMIS): This product has been
classified in accordance with the hazard criteria of the CPR (Controlled Product
Regulations), and the MSDS contains all of the information required by the CPR.

Class B3 – Flammable Liquid

Class D2A – Materials Causing Serious and Other Toxic Effects
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA)
All components of this product are listed on the Canadian DSL Inventory.

16. Other Information

Prepared for: Keyera Health and Safety
Issue Date: June 19, 2009
More Information: (403) 843-7162
Technical Preparation by: Deerfoot Consulting Inc.
Disclaimer of Expressed and Implied Warranties

The information presented in the Material Safety Data Sheet is based on data believed to be accurate as of
the date this Material Safety Data Sheet was prepared. However, neither Keyera, Deerfoot Consulting Inc
nor any of their subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. No responsibility is assumed for any damage or injury resulting from abnormal
use or from any failure to adhere to recommended practices. The information provided above, and the
product, are furnished on the condition that the person receiving them shall make their own determination as
to the suitability of the product for their particular purpose and on the condition that they assume the risk of
their use.

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