Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                

Safety Data Sheet: 1. Product and Company Identification

Download as pdf or txt
Download as pdf or txt
You are on page 1of 8

Safety Data Sheet

Material: 60007122 PULPSIL® 160 C


ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

1. Product and company identification


1.1 Identification of the substance or preparation:
Commercial product name: PULPSIL® 160 C
ANTIFOAM-COMPOUND
Use of substance / preparation Industrial.
defoaming agent
1.2 Company/undertaking identification:
Manufacturer/distributor: Wacker Chemie AG
Hanns-Seidel-Platz 4
81737 München
Germany
Customer information: Wacker Chemical Corporation
3301 Sutton Road
Adrian, Michigan 49221-9397
USA
InfoLine:
Tel (517) 264-8240
Hours of operation:
Monday - Friday, 8 am to 5 pm (eastern standard time)
Corporate website: www.wacker.com
Emergency telephone no. (24h): (517) 264-8500
Transportation emergency: (800) 424-9300 (CHEMTREC, USA)
(703) 527-3887 (CHEMTREC, international)
This SDS was prepared by the Regulatory Affairs and Product Safety Department (RAPS) of Wacker Chemical Corporation.

2. Hazards identification
2.1 Classification of the substance or mixture
Classification (GHS):
Not a hazardous substance or mixture.
2.2 Label elements
Labelling (GHS):
No labeling according to GHS required.
2.3 Other hazards
No data available.

3. Composition/information on ingredients
3.1 Chemical characterization (preparation)
Chemical characteristics
Polydimethylsiloxane and auxiliary
3.2 Information on ingredients:
Type CAS No. Substance Content [wt. %] Note
Lower Upper
INHA 64742-47-8 Destillates, petroleum, hydrotreated light <3.0
Type: HYD - by-product upon hydrolysis, INHA - ingredient, NEBE - by-product, MONO - residual monomer, VERU - impurity,
VUL - by-product upon vulcanization. *** Note: C1 - IARC carcinogen, C2 - NTP carcinogen, C3 - OSHA carcinogen, NH - non-
hazardous, R - reproductive toxin.

Page: 1/8
Safety Data Sheet
Material: 60007122 PULPSIL® 160 C
ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

Substances listed in the Subsections "HAPS" and "California Proposition 65 Carcinogens / Reproductive Toxins" that are not
listed in this section are only present at quantities below 0.1% for California Proposition 65 listed toxins or below 1% for non-
carcinogenic HAPS or they are inextricably bound in the product. Specific chemical identities and/or exact percentage
(concentration) of the composition may have been withheld as a trade secret.
This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57) in amounts
above ≥ 0.1%.

4. First-aid measures
4.1 General information:
Get medical attention if irritation occurs or if breathing becomes difficult. Remove contaminated clothing and shoes.
4.2 After inhalation
No special treatment required.
4.3 After contact with the skin
For skin contact, immediately wipe away excess material. Use a waterless hand cleaner to remove as much of the remaining
material as possible. Wash with soap and water.
4.4 After contact with the eyes
If contact with eyes, immediately hold eyelids apart and flush with plenty of water for at least 15 min.
4.5 After swallowing
For ingestion, if conscious, give several glasses of water but do not induce vomiting. If vomiting does occur, give additional fluids.
4.6 Advice for the physician
Treat symptomatically.

5. Fire-fighting measures
5.1 Flammable properties:
Property: Value: Method:
Flash point............................................................... : > 110 °C (> 230 °F) (The substance does not have a (ISO 3679)
flash point in the range (-20 °C to 110 °C) measured by
the ISO 3679 method. )
Sustained combustibility ..........................................: > 110 °C (> 230 °F) (ISO 9038)
Boiling point / boiling range .....................................: not applicable
Lower explosion limit (LEL) .....................................: not applicable
Upper explosion limit (UEL).....................................: not applicable
Ignition temperature ................................................: > 350 °C (> 662 °F) (DIN 51794)
5.2 Fire and explosion hazards:
This material does not present any unusual fire or explosion hazards. This material will burn with a lazy smoldering flame.
5.3 Recommended extinguishing media:
water-spray , carbon dioxide , sand , dry chemical or foam-type extinguishing media .
5.4 Unsuitable extinguishing media:
none known
5.5 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases
Hazardous decomposition products: carbon dioxide , carbon monoxide , formaldehyde , silicon dioxide and incompletely burnt
hydrocarbons .
5.6 Fire fighting procedures:
Use water spray (not stream) to fight fires. Fire fighters should wear full protective clothing including a self-contained breathing
apparatus.

Page: 2/8
Safety Data Sheet
Material: 60007122 PULPSIL® 160 C
ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

6. Accidental release measures


6.1 Precautions:
Secure the area. Wear personal protection equipment (see section 8). Keep unprotected persons away. If material is released
indicate risk of slipping. Do not walk through spilled material.
HAZWOPER PPE Level: D
6.2 Containment:
Prevent material from entering surface waters, drains or sewers and soil. Close leak if possible without risk. Contain any fluid that
runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked
containers. Inform authorities if substance leaks into surface waters, sewerage or ground.
Spills of material which could reach surface waters must be reported to the United States Coast Guard National Response
Center's toll free phone number (800) 424-8802.
6.3 Methods for cleaning up
Take up mechanically and dispose of according to local/state/federal regulations. Do not flush away with water. For small
amounts: Absorb with a neutral (non-acidic / non-basic) liquid binding material such as diatomaceous earth and dispose of
according to government regulations. For large amounts: Liquids may be recovered using suction devices or pumps. If flammable,
only air driven or properly rated electrical equipment should be used. Clean any slippery coating that remains using a detergent /
soap solution or another biodegradable cleaner. Silicone fluids are slippery; spills are a safety hazard. Apply sand or other inert
granular material to improve traction.

7. Handling and storage


7.1 General information:
Always stir well before use.
7.2 Handling
Precautions for safe handling:
Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction,
respiratory protection). Spilled substance increases risk of slipping. Observe information in section 8.
Precautions against fire and explosion:
Observe the general rules for fire prevention.
7.3 Storage
Conditions for storage rooms and vessels:
Observe local/state/federal regulations.
Advice for storage of incompatible materials:
Observe local/state/federal regulations.
Further information for storage:
Store in a dry and cool place.

8. Exposure controls and personal protection


8.1 Engineering controls
Ventilation:
Use with adequate ventilation.
Local exhaust:
Local exhaust ventilation which meets the requirements of ANSI Z9.2 is recommended to control airborne contaminants at the
point of use.
8.2 Associate substances with specific control parameters such as limit values
Maximum airborne concentrations at the workplace:
CAS No. Substance Type mg/m3 ppm Dust fract.
none known

Page: 3/8
Safety Data Sheet
Material: 60007122 PULPSIL® 160 C
ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

8.3 Personal protection equipment (PPE)


Respiratory protection:
Respiratory protection is not normally required. A NIOSH approved air purifying respirator equipped with universal multi-
contaminant multi-gas/vapor cartridges is recommended if overexposure to chemical vapors could occur.
Hand protection:
Any liquid-tight rubber or vinyl gloves.
Eye protection:
Safety glasses with side shields or chemical safety goggles.
Other protective clothing or equipment:
Additional protective clothing or equipment is not normally required. Provide eye bath and safety shower.
8.4 General hygiene and protection measures:
Avoid contact with eyes, skin and clothing. Do not eat or drink when handling. Wash thoroughly after handling.

9. Physical and chemical properties


9.1 Appearance
Physical state ..........................................................: liquid
Colour .....................................................................: colourless
Odour ......................................................................: faint
9.2 Safety parameters
Property: Value: Method:
Melting point / melting range ...................................: -45 °C (-49 °F)
Boiling point / boiling range .....................................: not applicable
Flash point............................................................... : > 110 °C (> 230 °F) (The substance does not have a (ISO 3679)
flash point in the range (-20 °C to 110 °C) measured by
the ISO 3679 method. )
Sustained combustibility ..........................................: > 110 °C (> 230 °F) (ISO 9038)
Ignition temperature ................................................: > 350 °C (> 662 °F) (DIN 51794)
Lower explosion limit (LEL) .....................................: not applicable
Upper explosion limit (UEL).....................................: not applicable
Vapour pressure......................................................: not applicable
Density ....................................................................: ca. 1 g/cm³ at 25 °C (77 °F) (DIN 12791)
Water solubility / miscibility......................................: virtually insoluble
pH-Value .................................................................: not applicable
Viscosity (dynamic) .................................................: ca. 20000 mPa.s at 25 °C (77 °F) (DIN EN ISO 3219)

10. Stability and reactivity


10.1 General information:
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
10.2 Conditions to avoid
none known
10.3 Materials to avoid
none known
10.4 Hazardous decomposition products
If stored and handled properly: none known . Measurements have shown the formation of small amounts of formaldehyde at
temperatures above about 150 °C (302 °F) through oxidation.
10.5 Further information:
Hazardous polymerization cannot occur.

Page: 4/8
Safety Data Sheet
Material: 60007122 PULPSIL® 160 C
ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

11. Toxicological information


11.1 Information on toxicological effects
11.1.1 Acute toxicity
Assessment:
For this endpoint no toxicological test data is available for the whole product.
Acute toxicity estimate (ATE):
ATEmix (Oral): > 2000 mg/kg

11.1.2 Skin corrosion/irritation


Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.3 Serious eye damage / eye irritation
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.4 Respiratory or skin sensitization
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.5 Germ cell mutagenicity
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.6 Carcinogenicity
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.7 Reproductive toxicity
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.8 Specific target organ toxicity (single exposure)
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.9 Specific target organ toxicity (repeated exposure)
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.10 Aspiration hazard
Assessment:
For this endpoint no toxicological test data is available for the whole product.
11.1.11 Further toxicological information
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP. No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Other information: According to literature aliphatic hydrocarbons are slightly irritating to the skin and mucuous membranes and
have a skin drying and narcotic effect. If the lungs are directly affected (e.g. by aspiration), inflammation of the lungs may occur.

Page: 5/8
Safety Data Sheet
Material: 60007122 PULPSIL® 160 C
ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

12. Ecological information


12.1 Toxicity
Assessment:
According to current knowledge adverse effects on water purification plants are not expected.
12.2 Persistence and degradability
Assessment:
Elimination by adsorption to activated sludge. Biologically not degradable.
12.3 Bioaccumulative potential
Assessment:
Bioaccumulation is not expected to occur.
12.4 Mobility in soil
Assessment:
Insoluble in water.
12.5 Results of PBT and vPvB assessment
No data available.
12.6 Other adverse effects
none known

13. Disposal considerations


13.1 Product disposal
Recommendation:
Material that cannot be used, reprocessed or recycled should be disposed of in accordance with Federal, State, and local
regulations at an approved facility. Depending on the regulations, waste treatment methods may include, e.g., landfill or
incineration.
13.2 Packaging disposal
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.

14. Transport information


14.1 US DOT & CANADA TDG SURFACE
Valuation ................................................ : Not regulated for transport
14.2 Transport by sea IMDG-Code
Valuation ................................................ : Not regulated for transport
14.3 Air transport ICAO-TI/IATA-DGR
Valuation ................................................ : Not regulated for transport

15. Regulatory information


15.1 U.S. Federal regulations
TSCA inventory status and TSCA information:
This material or its components are listed on or are in compliance with the requirements of the TSCA Chemical Substance
Inventory.
TSCA 12(b) Export Notification:
This material does not contain reportable amounts of any TSCA 12(b) listed chemicals.

Page: 6/8
Safety Data Sheet
Material: 60007122 PULPSIL® 160 C
ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

CERCLA Regulated Chemicals:


This material does not contain any CERCLA regulated chemicals.
SARA 302 EHS Chemicals:
This material does not contain any SARA extremely hazardous substances.
SARA 311/312 Hazard Class:
This product does not present any SARA 311/312 hazards.
SARA 313 Chemicals:
This material does not contain any SARA 313 chemicals above de minimus levels.
HAPS (Hazardous Air Pollutants):
CAS No. Chemical Upper limit wt. %
67-56-1 Methanol <=0.0950

15.2 U.S. State regulations


California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986):
This material does not contain any chemicals known to the State of California to cause cancer.
California Proposition 65 Reproductive Toxins:
67-56-1 Methanol
Massachusetts Substance List:
112945-52-5 Silica, amorphous, fumed
New Jersey Right-to-Know Hazardous Substance List:
112945-52-5 Silica, amorphous, fumed
Pennsylvania Right-to-Know Hazardous Substance List:
112945-52-5 Silica, amorphous, fumed
15.3 Details of international registration status
Relevant information about individual substance inventories, where available, is given below.
Y

Japan .......................................................... : ENCS (Handbook of Existing and New Chemical Substances):


This product is listed in, or complies with, the substance inventory. Y

New Zealand ............................................... : NZIoC (New Zealand Inventory of Chemicals):


This product is listed in, or complies with, the substance inventory. (For a correct
interpretation of the New Zealand status, additional information like GHS
classification or Group Standard is required.) Y

Australia ...................................................... : AICS (Australian Inventory of Chemical Substances):


This product is listed in, or complies with, the substance inventory. Y

China ........................................................... : IECSC (Inventory of Existing Chemical Substances in China):


This product is listed in, or complies with, the substance inventory. Y

Canada ....................................................... : DSL (Domestic Substance List):


This product is listed in, or complies with, the substance inventory. Y

Philippines ................................................... : PICCS (Philippine Inventory of Chemicals and Chemical Substances):


This product is listed in, or complies with, the substance inventory. TY

United States of America (USA) .................. : TSCA (Toxic Substance Control Act Chemical Substance Inventory):
All components of this product are listed as active or are in compliance with the
substance inventory. Y

Taiwan ........................................................ : TCSI (Taiwan Chemical Substance Inventory):


This product is listed in, or complies with, the substance inventory. General note:
The Taiwanese chemicals regulation requires a phase 1 registration for TCSI-listed
or TCSI-compliant substances if imports to Taiwan or manufacturing in Taiwan
exceed the trigger quantity of 100 kg/a (for mixtures to be calculated per each
ingredient). It is the duty of the importing/manufacturing legal entity to take care of
this obligation.

Page: 7/8
Safety Data Sheet
Material: 60007122 PULPSIL® 160 C
ANTIFOAM-COMPOUND

Version: 2.7 (US) Date of print: 04/22/2021 Date of last alteration: 11/16/2019

European Economic Area (EEA) ................. : REACH (Regulation (EC) No 1907/2006):


General note: the registration obligations for substances imported into the EEA or
manufactured within the EEA by the supplier mentioned in section 1 are fulfilled by
the said supplier. The registration obligations for substances imported into the EEA
by customers or other downstream users must be fulfilled by the latter.
South Korea (Republic of Korea) ................ : AREC (Act on Registration and Evaluation of Chemicals; “K-REACH”):
General note: in case of registration obligations for substances or polymers
imported into Korea or manufactured within Korea these are fulfilled by the supplier
mentioned in section 1. The registration obligations for substances or polymers
imported into Korea by customers or other downstream users must be fulfilled by
the latter.

16. Other information


16.1 Additional information:
This Safety Data Sheet (SDS) meets the requirements of the Federal OSHA Hazard Communication Standard (29 CFR
1910.1200).This information relates to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of
the date compiled. However, no representation, warranty or guarantee expressed or implied, is made as to its accuracy, reliability
or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his
own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing
herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license under valid
patents. This SDS provides selected regulatory information on this product, including its components. This is not intended to
include all regulations. It is the responsibility of the user to know and comply with all applicable rules, regulations and laws relating
to the product being used.
Vertical lines in the left-hand margin indicate changes compared with the previous version.
WACKER restricts the use of its products inside the human body or in contact with bodily fluids and mucosa. For further details
please review our Health Care Policy on www.wacker.com. WACKER may cancel any delivery obligation(s) if the Health Care
Policy is not observed.
16.2 Glossary of Terms:
ACGIH - American Conference of Governmental Industrial ppm - Parts per Million
Hygienists SARA - Superfund Amendments and Reauthorization Act
DOT - Department of Transportation STEL - Short Term Exposure Limit
hPa - Hectopascals TSCA - Toxic Substances Control Act
mPa*s - Milli Pascal-Seconds TWA - Time Weighted Average
OSHA - Occupational Safety and Health Administration WHMIS - Canadian Workplace Hazardous Materials
PEL - Permissible Exposure Limit Identification System
Flash point determination methods ........................................ Common name
ASTM D56................................................................................... Tagliabue (Tag) closed cup
ASTM D92, DIN 51376, ISO 2592 .............................................. Cleveland open cup
ASTM D93, DIN 51758, ISO 2719 .............................................. Pensky-Martens closed cup
ASTM D3278, DIN 55680, ISO 3679 .......................................... Setaflash or Rapid closed cup
DIN 51755 ................................................................................... Abel-Pensky closed cup
16.3 Conversion table:
Pressure: ....................: 1 hPa * 0.75 = 1 mm Hg = 1 torr; 1 bar = 1000 hPa
Viscosity: ....................: 1 mPa*s = 1 centipoise (cP)

Page: 8/8

You might also like