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    Experimetal Values Of Liquid Phase Properties P (Kpa) X1 Y1 X2 Y2 Γ1

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    AhmAd GhAzi
    The document contains experimental and calculated values of liquid phase properties including pressure (P), mole fractions (x1, x2), activity coefficients (γ1, γ2), and excess Gibbs energy (GE) for a binary mixture. The values were measured at different pressures and compositions and were also calculated using van Laar equations. A graph is shown comparing experimental and calculated P-x1 and P-y1 values with good correlation between the two sets of values.

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    © All Rights Reserved
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    Experimetal Values Of Liquid Phase Properties P (Kpa) X1 Y1 X2 Y2 Γ1

    Uploaded by

    AhmAd GhAzi
    34 views4 pages
    The document contains experimental and calculated values of liquid phase properties including pressure (P), mole fractions (x1, x2), activity coefficients (γ1, γ2), and excess Gibbs energy (GE) for a binary mixture. The values were measured at different pressures and compositions and were also calculated using van Laar equations. A graph is shown comparing experimental and calculated P-x1 and P-y1 values with good correlation between the two sets of values.

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    Project#2 - Part (b) - 2002572

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    The document contains experimental and calculated values of liquid phase properties including pressure (P), mole fractions (x1, x2), activity coefficients (γ1, γ2), and excess Gibbs energy (GE) for a binary mixture. The values were measured at different pressures and compositions and were also calculated using van Laar equations. A graph is shown comparing experimental and calculated P-x1 and P-y1 values with good correlation between the two sets of values.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    34 views4 pages

    Experimetal Values Of Liquid Phase Properties P (Kpa) X1 Y1 X2 Y2 Γ1

    Uploaded by

    AhmAd GhAzi
    The document contains experimental and calculated values of liquid phase properties including pressure (P), mole fractions (x1, x2), activity coefficients (γ1, γ2), and excess Gibbs energy (GE) for a binary mixture. The values were measured at different pressures and compositions and were also calculated using van Laar equations. A graph is shown comparing experimental and calculated P-x1 and P-y1 values with good correlation between the two sets of values.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 4

    Experimetal Values of Liquid Phase Properti

    P (kPa) x1 y1 x2 y2 γ1
    68.728 0 0 1 1
    72.278 0.0287 0.0647 0.9713 0.9353 1.681791
    75.279 0.057 0.1295 0.943 0.8705 1.765274
    77.524 0.0858 0.1848 0.9142 0.8152 1.723433
    78.951 0.1046 0.219 0.8954 0.781 1.706136
    82.528 0.1452 0.2694 0.8548 0.7306 1.580432
    86.762 0.2173 0.3633 0.7827 0.6367 1.497196
    90.088 0.2787 0.4184 0.7213 0.5816 1.395935
    93.206 0.3579 0.4779 0.6421 0.5221 1.284584
    95.017 0.405 0.5135 0.595 0.4865 1.243455
    96.365 0.448 0.5512 0.552 0.4488 1.223754
    97.646 0.5052 0.5844 0.4948 0.4156 1.165856
    98.462 0.5432 0.6174 0.4568 0.3826 1.155098
    99.811 0.6332 0.6772 0.3668 0.3228 1.101788
    99.95 0.6605 0.6926 0.3395 0.3074 1.081772
    100.278 0.6945 0.7124 0.3055 0.2876 1.061697
    100.467 0.7327 0.7383 0.2673 0.2617 1.044897
    100.999 0.7752 0.7729 0.2248 0.2271 1.03937
    101.059 0.7922 0.7876 0.2078 0.2124 1.037025
    99.877 0.908 0.8959 0.092 0.1041 1.017144
    99.799 0.9448 0.9336 0.0552 0.0664 1.017866
    96.885 1 1 0 0 1

    x1x2RT/GE Vs. x1
    1.8
    x1x2RT/GE

    1.6

    1.4 f(x) = 0.014959978831086 x + 1.44239700151738


    R² = 0.000825511209956
    1.2

    0.8

    0.6
    0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
    x1
    Caculated Values by U
    ues of Liquid Phase Properties A'12 0.693289
    γ2 ln γ1 ln γ2 GE/RT GE/x1x2RT x1x2RT/GE x1 ln γ1
    1 0 0 0.693289
    1.012675 0.519859 0.012595 0.027154 0.974072344 1.02661779316 0.0287 0.653675
    1.011107 0.568306 0.011046 0.04281 0.796447121 1.25557613822 0.057 0.615776
    1.005832 0.544318 0.005815 0.052019 0.663177495 1.50789194051 0.0858 0.578392
    1.001977 0.534231 0.001975 0.057649 0.615523919 1.62463223501 0.1046 0.554631
    1.02632 0.457698 0.02598 0.088665 0.714367065 1.39984057083 0.1452 0.505048
    1.026917 0.403594 0.026561 0.10849 0.637876058 1.56770267139 0.2173 0.422809
    1.056919 0.333564 0.055358 0.132894 0.661078299 1.51268011984 0.2787 0.358618
    1.10271 0.250435 0.09777 0.152409 0.663203605 1.50783257601 0.3579 0.283722
    1.130403 0.217894 0.122575 0.161179 0.668861949 1.49507682539 0.405 0.243387
    1.139986 0.201923 0.131016 0.162782 0.658247986 1.51918429179 0.448 0.209293
    1.193347 0.153455 0.176762 0.164987 0.66002042 1.51510463788 0.5052 0.167966
    1.199924 0.144186 0.182258 0.161577 0.651169792 1.53569777491 0.5432 0.143045
    1.278053 0.096934 0.245338 0.151369 0.651726603 1.53438572971 0.6332 0.09206
    1.31678 0.078601 0.275189 0.145343 0.648157261 1.54283545017 0.6605 0.078822
    1.373566 0.059869 0.31741 0.138548 0.653005117 1.53138156831 0.6945 0.06378
    1.431181 0.043919 0.3585 0.128006 0.653590149 1.53001081996 0.7327 0.048789
    1.484582 0.038615 0.395133 0.11876 0.681490611 1.46737164714 0.7752 0.034477
    1.50297 0.036356 0.407443 0.113468 0.689276323 1.45079696822 0.7922 0.02945
    1.644352 0.016999 0.497346 0.061191 0.732511322 1.36516661222 0.908 0.005759
    1.746713 0.017708 0.557736 0.047518 0.911123332 1.09754625443 0.9448 0.002072
    0 1

    0.7 0.8 0.9 1


    Caculated Values by Using the van Laar Equations
    A'21 0.686153
    ln γ2 γ1 γ2 P (Kpa) y1 (P_ex - P_Cal)^(2)
    2.000284 68.728 0 0
    0.000577 1.922593 1.000577 72.13997 0.074105 0.01905113430057
    0.002273 1.851093 1.002276 75.18056 0.135973 0.009690479000353 Pxy data and
    0.005148 1.783168 1.005161 77.9784 0.190091 0.206483487171364
    0.007648 1.741298 1.007677 79.6581 0.221529 0.499987730914848 105
    0.014724 1.657065 1.014833 82.93122 0.28109 0.162584912005688 100
    0.032928 1.526243 1.033476 87.72637 0.366277 0.930000605371439
    0.054096 1.43135 1.055586 90.97822 0.424817 0.792483435925181 95

    0.089064 1.328063 1.093151 94.29182 0.488386 1.17899513979049 90


    0.113938 1.275562 1.120682 95.87929 0.522022 0.743545596088835

    P (kPa)
    85
    0.139292 1.232806 1.14946 97.11736 0.550976 0.566041646016387
    0.176922 1.182897 1.193538 98.48662 0.587881 0.706647373317358 80

    0.204378 1.153782 1.226762 99.23529 0.611891 0.5979778665534 75


    0.277197 1.096431 1.319426 100.5254 0.669119 0.510316944467556
    70
    0.301444 1.082012 1.35181 100.7827 0.68703 0.693358580997385
    0.333044 1.065858 1.395208 101.0124 0.709992 0.539281941388092 65
    0 0.1 0.2
    0.370396 1.049998 1.448308 101.1438 0.73694 0.458023197068169
    0.414248 1.035078 1.513233 101.1194 0.768793 0.014486742315669 P-x1 (Corr)
    0.432465 1.029887 1.541051 101.055 0.78221 1.579957617935E-05
    0.566782 1.005775 1.762585 99.62443 0.888132 0.063791313478828
    0.613189 1.002074 1.846311 98.73128 0.929055 1.14003361949298
    0.686153 1.986061 96.885 1 0
    RMS Deviation 0.66853971
    Pxy data and their correlation (The van Laar Equation)

    105

    100

    95

    90

    85

    80

    75

    70

    65
    0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
    x1 , y1
    P-x1 (Corr) P-x1 (Exp) P-y1 (Corr) P-y1 (Exp)

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