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Adsorption and Oxidation Processes: Unit 5

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UNIT 5

ADSORPTION AND OXIDATION


PROCESSES
CHEMICAL PROCESS
CHEMICAL PROCESS
• Treatment methods in which the removal or conversion of
contaminants is brought about by the addition of
chemicals or by other chemical reactions.
• Precipitation, adsorption, and disinfection are the most
common examples used in wastewater treatment.
• Basically the treatment includes: - Coagulation -
Precipitation - Disinfection - Oxidation - Neutralization, scale
control .
COAGULATION AND FLOCCULATION
PRINCIPLE OF COAGULATION
• In coagulation, individual particles combine together.
• When a coagulant is used in water, it forms a spongy
gelatinous precipitate which absorbs fine size particles in
water and binds them together.
• The whole process results into bigger particles which are
heavier and easily settle able.
PROPERTIES OF COMMON COAGULANTS
• React quickly
• Cheap
• Easy to handle and store
• React in longer range of pH
• Electrolyte ( positively charged)
• High valance ions for high efficiency
•Not detoriate
Precipitation
• It is used for removing dissolved metals from waste water
solution containing toxic materials.
• To convert this dissolved metal into solid particles, a
precipitation reagent is added. A chemical reaction occurs
where dissolved metals form solid particles.
• Filtration can be used to remove the particles from the
mixtures. How well the process takes place depends on the
types of metal present, its concentration, and reagent used.
EXAMPLE
• In hydroxide precipitation, calcium or sodium hydroxide is
used as a reagent to create solid metal hydroxides.
• But the main difficulty being the mixture of metals in waste
water making it difficult to precipitate.
NEUTRALIZATION
• If a waste stream is found to be hazardous due to
corrosivity, neutralization is the primary treatment used.
• It is used as a pretreatment system before a variety of
biological, chemical, and physical treatment processes.
• It is the process of adjusting the pH of water through the
addition of an acid or a base, depending on the target pH
and process requirements.
• Some processes such as boiler operations and drinking
water standards need neutral water at a pH of 7.
• Water or wastewater is generally considered
adequately neutralized if: (1) its damage to metals,
concrete, or other materials is minimal; (2) it has little
effect on fish and aquatic life; (3) it has no effect on
biological matter (i.e., biological treatment systems).

PARAMETERS WHICH AFFECT NEUTRALIZATION:


• pH
• alkalinity/acidity
• Hardness
• Buffers
OXIDATION
• It is a waste water treatment which involves the use of
oxidizing agents such as ozone, hydrogen peroxide,
permanganate, chloride, chlorine, oxygen etc.
• The electrons move from the oxidant to the pollutants in
waste water. They undergo structural modification
becoming less destructive compounds.
• Alkaline chlorination uses chlorine as oxidizing agent
against cyanide. But it can lead to production of toxic
chlorinated compounds hence require further steps.
APPLICATION
• Reduce concentration of the residual organics
• Controls odors
• Remove ammonia
• Reduce microbial content
ADVANTAGES OF CHEMICAL PROCESS
• AdvantagesIt can lead to better quality effluent.
• Metals can be recovered from the solution.
• It only requires a low level of electrical current.
• Electrodes are impermanent.
• Many different faconlytors can affect results.
• Active fine-tuning is required.

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