Safety Data Sheet: Ardrox 9D1B, Aerosol

Safety data sheet
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Chemetall (now part of BASF Group) Safety data sheet according to Regulation (EC) No. 1907/2006 as
amended from time to time.
Date / Revised: 04.07.2018 Version: 1.0
Product: Ardrox 9D1B, Aerosol
(ID no. 30687321/SDU_GEN_GB/EN)
Date of print 07.08.2018
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Ardrox 9D1B, Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: Developer
Not recommended use: None known
1.3. Details of the supplier of the safety data sheet
Company:
Chemetall Ltd.
Denbigh Road 65
Bletchley Milton Keynes MK1 1PB
Great Britain
___________________________________________________________________________
Telephone: +44 1908 649333
E-mail address: sds.global-chemetall@basf.com
1.4. Emergency telephone number
Telephone: +49 180 2273-112
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)

Aerosols, Category 1 H222: Extremely flammable aerosol.
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H229: Pressurised container: May burst if heated.
Eye irritation, Category 2 H319: Causes serious eye irritation.
Specific target organ toxicity - single H336: May cause drowsiness or dizziness.
exposure, Category 3, Central nervous
system
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :
Signal word : Danger
Hazard statements : H222 Extremely flammable aerosol.

H229 Pressurised container: May burst if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Supplemental Hazard : EUH066 Repeated exposure may cause skin dryness or

Statements cracking.
Precautionary statements :
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P260 Do not breathe spray.
P262 Do not get in eyes, on skin, or on clothing.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/ container to an approved waste
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disposal plant.
Hazardous components which must be listed on the label:

Acetone
2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative
and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
The information required is contained in this Material Safety Data Sheet.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Chemical nature : Mixture of organic solvents.
Hazardous components
Chemical name CAS-No. Classification Concentration
EC-No. (REGULATION (EC) (% w/w)
Registration number No 1272/2008)
Acetone 67-64-1 Flam. Liq. 2; H225 >= 25 - < 50
200-662-2 Eye Irrit. 2; H319
01-2119471330-49 STOT SE 3; H336
Propane 74-98-6 Flam. Gas 1; H220 >= 10 - < 25
200-827-9 Press. Gas Liquefied
01-2119486944-21 gas; H280
Note U (Table 3.1)
Propan-2-ol 67-63-0 Flam. Liq. 2; H225 >= 3 - < 10

200-661-7 Eye Irrit. 2; H319
01-2119457558-25 STOT SE 3; H336
Isobutane 75-28-5 Flam. Gas 1; H220 >= 1 - < 2.5
01-2119485395-27 gas; H280
Note U (Table 3.1)
Note C
Ethanol, 90367-27-4 Acute Tox. 4; H302 >= 0.025 - < 0.1

2,2'-[[3-[(2-hydroxyethyl)amino]pr 291-275-8 Skin Corr. 1B; H314
opyl]imino]bis-, N-tallow alkyl 01-2119962190-43 STOT RE 1; H372
derivs. Aquatic Acute 1;
H400
Aquatic Chronic 1;
H410
M-Factor Acute
aquatic toxicity:10
M-Factor Chronic
aquatic toxicity:1
Substances with a workplace exposure limit :

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Butane 106-97-8 Flam. Gas 1; H220 >= 25 - < 50
01-2119474691-32 gas; H280
Talc 14807-96-6 Not a hazardous >= 2.5 - < 10
238-877-9 substance or mixture
according to
Regulation (EC) No.
1272/2008.
For explanation of abbreviations see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : First Aid responders should pay attention to self-protection and
use the recommended protective clothing
Move out of dangerous area.
Take off contaminated clothing and shoes immediately.
If inhaled : Move to fresh air.

If symptoms persist, call a physician.
In case of skin contact : Wash off with soap and plenty of water.
If symptoms persist, call a physician.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Consult a physician.
If swallowed : Rinse mouth with water.

Do NOT induce vomiting.
Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : May cause drowsiness or dizziness.
Risks : Causes serious eye irritation.

Repeated exposure may cause skin dryness or cracking.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
For specialist advice physicians should contact the Poisons
Information Service.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Carbon dioxide (CO2)
Dry powder
Alcohol-resistant foam
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Water spray
Unsuitable extinguishing : High volume water jet

media
5.2 Special hazards arising from the substance or mixture

Specific hazards during : Heating or fire can release toxic gas.
firefighting Carbon monoxide
Carbon dioxide (CO2)
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Further information : Use water spray to cool unopened containers.

Risk of bursting.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear personal protective equipment.
6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.
6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation.
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
6.4 Reference to other sections

For further information see Section 8 of the safety data sheet.
For disposal considerations see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Provide exhaust ventilation close to floor level.
Have eye wash bottle or eye rinse ready at the work place.
To avoid risks to man and the environment, comply with the
instructions for use.
Advice on protection against : Keep away from sources of ignition - No smoking. Take
fire and explosion precautionary measures against static discharges. Vapours
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may form explosive mixtures with air. Normal measures for
preventive fire protection.
Hygiene measures : Take off contaminated clothing and shoes immediately. Keep
away from food, drink and animal feedingstuffs. Wash hands
before breaks and immediately after handling the product.
Avoid contact with skin and eyes. Do not breathe vapours,
aerosols.
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated
areas and containers place. Store in a place accessible by authorized persons only.
To maintain product quality, do not store in heat or direct
sunlight.
Recommended storage : < 50 °C

temperature
7.3 Specific end use(s)

Specific use(s) : Developer
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure Limits

Components CAS-No. Value type (Form Control parameters Basis
of exposure)
Butane 106-97-8 TWA 600 ppm GB EH40
1,450 mg/m3
Further information Capable of causing cancer and/or heritable genetic damage. The identified
substances include those which: - are assigned the risk phrases 'R45: May
cause cancer'; 'R46: may cause heritable genetic damage'; 'R49: May cause
cancer by inhalation' or - a substance or process listed in Schedule 1 of
COSHH., Carcinogenic only applies if butane contains more than 0.1% of
buta-1,3-diene
STEL 750 ppm GB EH40
1,810 mg/m3
Further information Capable of causing cancer and/or heritable genetic damage. The identified
substances include those which: - are assigned the risk phrases 'R45: May
cause cancer'; 'R46: may cause heritable genetic damage'; 'R49: May cause
cancer by inhalation' or - a substance or process listed in Schedule 1 of
COSHH., Carcinogenic only applies if butane contains more than 0.1% of
buta-1,3-diene
Acetone 67-64-1 TWA 500 ppm 2000/39/EC
1,210 mg/m3
Further information Indicative
TWA 500 ppm GB EH40
1,210 mg/m3
STEL 1,500 ppm GB EH40
3,620 mg/m3
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Propan-2-ol 67-63-0 TWA 400 ppm GB EH40
999 mg/m3
STEL 500 ppm GB EH40
1,250 mg/m3
Talc 14807-96-6 TWA (Respirable 1 mg/m3 GB EH40
dust)
Further information For the purposes of these limits, respirable dust and inhalable dust are those
fractions of airborne dust which will be collected when sampling is undertaken
in accordance with the methods described in MDHS14/3 General methods for
sampling and gravimetric analysis of respirable and inhalable dust, Talc is
defined as the mineral talc together with other hydrous phyllosilicates including
chlorite and carbonate materials which occur with it, but excluding amphibole
asbestos and crystalline silica., The COSHH definition of a substance
hazardous to health includes dust of any kind when present at a concentration
in air equal to or greater than 10 mg.m-3 8-hour TWA of inhalable dust or 4
mg.m-3 8-hour TWA of respirable dust. This means that any dust will be subject
to COSHH if people are exposed above these levels. Some dusts have been
assigned specific WELs and exposure to these must comply with the
appropriate limit., Most industrial dusts contain particles of a wide range of
sizes. The behaviour, deposition and fate of any particular particle after entry
into the human respiratory system and the body response that it elicits, depend
on the nature and size of the particle. HSE distinguishes two size fractions for
limit-setting purposes termed 'inhalable' and 'respirable'., Inhalable dust
approximates to the fraction of airborne material that enters the nose and
mouth during breathing and is therefore available for deposition in the
respiratory tract. Respirable dust approximates to the fraction that penetrates to
the gas exchange region of the lung. Fuller definitions and explanatory material
are given in MDHS14/3., Where dusts contain components that have their own
assigned WEL, all the relevant limits should be complied with., Where no
specific short-term exposure limit is listed, a figure three times the long-term
exposure should be used
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health Value
effects
Acetone Workers Inhalation Long-term systemic 1210 mg/m3
effects
Workers Inhalation Long-term local 2420 mg/m3
effects
Workers Inhalation Acute systemic effects 1210 mg/m3
Workers Skin contact Long-term systemic 186 mg/kg
effects bw/day
Propan-2-ol Workers Inhalation Long-term systemic 500 mg/m3
effects
Workers Skin contact Long-term systemic 888 mg/kg
effects bw/day
Ethanol, Workers Inhalation Long-term systemic 0.12 mg/m3
2,2'-[[3-[(2-hydroxyethy effects
l)amino]propyl]imino]bi
s-, N-tallow alkyl
derivs.
Workers Skin contact Long-term systemic 0.017 mg/kg
effects bw/day
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Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
Acetone Fresh water 10.6 mg/l
Marine water 1.06 mg/l
Sewage treatment plant 100 mg/l
Fresh water sediment 30.04 mg/kg dry
weight (d.w.)
Marine sediment 3.04 mg/kg dry
weight (d.w.)
Soil 29.5 mg/kg dry
weight (d.w.)
Propan-2-ol Fresh water 140.9 mg/l
Sewage treatment plant 2251 mg/l
Sediment 552 mg/kg dry
weight (d.w.)
Soil 28 mg/kg dry
weight (d.w.)
Ethanol, Fresh water 0.002 mg/l
2,2'-[[3-[(2-hydroxyethyl)amino]pr
opyl]imino]bis-, N-tallow alkyl
derivs.
Intermittent use/release 0.0013 mg/l
Sewage treatment plant 1.6 mg/l
Fresh water sediment 7.5 mg/kg dry
weight (d.w.)
Marine sediment 0.75 mg/kg dry
weight (d.w.)
Soil 5 mg/kg dry
weight (d.w.)
8.2 Exposure controls
Engineering measures
Ensure adequate ventilation, especially in confined areas.
Electrical equipment should be protected to the appropriate standard.
Use only explosion-proof equipment.
Personal protective equipment
Eye protection : Eye protection (EN 166)
Tightly fitting safety goggles
Hand protection
Material : butyl-rubber
Remarks : Protective gloves complying with EN 374. Please observe the

instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the
product is used, such as the danger of cuts, abrasion, and the
contact time.
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Skin and body protection : Chemical resistant protective clothing according to DIN EN
13034 (Type 6)
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory

equipment.
Recommended Filter type:
AX-P2
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : aerosol
Colour : white
Odour : characteristic
Odour Threshold : No data available
pH : No data available
Melting point/freezing point : No data available
Boiling point/boiling range : -40 °C

Propellant
Flash point : -18 °C

Method: ASTM D 93
Active ingredient
< 0 °C
Propellant
Evaporation rate : No data available
Flammability (solid, gas) : No data available
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapour pressure : No data available
Relative vapour density : No data available
Relative density : No data available
Density : 0.88 g/cm³ (20 °C)

Active ingredient
Solubility(ies)
Water solubility : completely miscible
Solubility in other solvents : No data available

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Partition coefficient: : No data available

n-octanol/water
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, dynamic : No data available
Viscosity, kinematic : No data available
Flow time : No data available
Explosive properties : Vapours may form explosive mixture with air.
Oxidizing properties : No data available
9.2 Other information

Other physico-chemical properties: This information is not available/not determined.
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Vapours may form explosive mixture with air.
Pressurised container: May burst if heated.
10.4 Conditions to avoid

Conditions to avoid : Keep away from open flames, hot surfaces and sources of
ignition.
Strong sunlight for prolonged periods.
10.5 Incompatible materials

Materials to avoid : Strong reducing agents
Oxidizing agents
Strong bases
10.6 Hazardous decomposition products

No decomposition if stored and applied as directed.
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SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Product:
Based on available data, the classification criteria are not met.
Acute toxicity
Components:
Acetone:
Acute oral toxicity : LD50 (Rat): 5,800 mg/kg
Method: OECD Test Guideline 401
Acute inhalation toxicity : LC50 (Rat): ca. 76 mg/l

Exposure time: 4 h
Acute dermal toxicity : LD50 (Rabbit): > 158,000 mg/kg
Propan-2-ol:
Acute oral toxicity : LD50 (Rat): 5,840 mg/kg
Acute inhalation toxicity : LC50 (Rat): 30 mg/l

Exposure time: 4 h
Acute dermal toxicity : LD50 (Rabbit): 13,900 mg/kg

Ethanol, 2,2'-[[3-[(2-hydroxyethyl)amino]propyl]imino]bis-, N-tallow alkyl derivs.:

Acute oral toxicity : LD50 (Rat): > 300 - 2,000 mg/kg
Skin corrosion/irritation
Product:
Remarks: May cause skin irritation in susceptible persons.
Serious eye damage/eye irritation
Product:
Remarks: Causes serious eye irritation.
Respiratory or skin sensitisation
Product:
Remarks: No data available
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Germ cell mutagenicity
Product:
Germ cell mutagenicity
Components:
Acetone:
Genotoxicity in vitro : Test Type: Ames test
Result: negative
: Test Type: Ames test

Result: negative
Genotoxicity in vivo : Test Type: in vivo assay

Species: Mouse
Application Route: Oral
Result: negative
Carcinogenicity
Product:
Reproductive toxicity
Product:
STOT - single exposure
Product:
STOT - repeated exposure
Product:
Aspiration toxicity
Product:
Neurological effects
Product:
May cause drowsiness or dizziness.
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Further information
Product:
Remarks: Repeated exposure may cause skin dryness or cracking.
SECTION 12: Ecological information
12.1 Toxicity
Product:
Ecotoxicology studies for the product are not available.
Components:
Acetone:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 5,540 mg/l
Exposure time: 96 h
Test Type: static test
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 8,800 mg/l
aquatic invertebrates Exposure time: 48 h
NOEC (Daphnia magna (Water flea)): 2,212 mg/l

Exposure time: 28 d
Test Type: flow-through test
Toxicity to algae : NOEC (Algae): 430 mg/l

Exposure time: 96 h
NOEC (Microcystis aeruginosa (blue-green algae)): 530 mg/l

Exposure time: 8 d
Toxicity to microorganisms : (activated sludge):

Exposure time: 30 min
Test Type: Respiration inhibition
Propan-2-ol:
Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): 8,970 mg/l
Exposure time: 48 h
LC50 (Pimephales promelas (fathead minnow)): 9,640 mg/l

Exposure time: 96 h
Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 9,714 mg/l
Toxicity to algae : EC50 (Scenedesmus subspicatus): > 100 mg/l

Exposure time: 72 h
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Toxicity to microorganisms : IC50 (Bacteria): > 100 mg/l

Toxicity to fish : LC50 (Fish): > 0.1 - 1 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 0.1 - 1 mg/l
Toxicity to algae : EC10 (Pseudokirchneriella subcapitata (green algae)): > 0.001

- 0.01 mg/l
Exposure time: 72 h
M-Factor (Acute aquatic : 10

toxicity)
M-Factor (Chronic aquatic : 1

toxicity)
12.2 Persistence and degradability
Components:

Biodegradability : Result: rapidly biodegradable
12.3 Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Bioaccumulation is unlikely.
12.4 Mobility in soil
Product:
Distribution among : Remarks: No data available
environmental compartments
12.5 Results of PBT and vPvB assessment
Product:
Assessment : This substance/mixture contains no components considered to
be either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher..
12.6 Other adverse effects
Product:
Additional ecological : slightly water endangering
information Do not flush into surface water or sanitary sewer system.
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Avoid subsoil penetration.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : In accordance with local and national regulations.
Contaminated packaging : Dispose of as unused product.
Waste Code : Waste codes should be assigned by the user, preferably in

discussion with the waste disposal authorities.
SECTION 14: Transport information
14.1 UN number
ADR : UN 1950
RID : UN 1950
IMDG : UN 1950
IATA : UN 1950
14.2 UN proper shipping name
ADR : AEROSOLS
RID : AEROSOLS
IMDG : AEROSOLS
IATA : Aerosols, flammable
14.3 Transport hazard class(es)
ADR : 2
RID : 2
IMDG : 2.1
IATA : 2.1
14.4 Packing group
ADR
Packing group : Not assigned by regulation
Classification Code : 5F
Labels : 2.1
Tunnel restriction code : (D)
RID
Classification Code : 5F
Hazard Identification Number : 23
Labels : 2.1
IMDG
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Labels : 2.1
EmS Code : F-D, S-U
Remarks : "IMDG-Code segregation group not applicable"., Protected
from sources of heat., For AEROSOLS with a maximum
capacity of 1 litre: Category A. For AEROSOLS with a capacity
above 1 litre: Category B. For WASTE AEROSOLS: Category
C, Clear of living quarters., For AEROSOLS with a maximum
capacity of 1 litre: Segregation as for class 9. Stow "separated
from" class 1 except for division 1.4. For AEROSOLS with a
capacity above 1 litre: Segregation as for the appropriate
subdivision of class 2. For WASTE AEROSOLS: Segregation
as for the appropriate subdivision of class 2.
"IMDG-Code segregation group not applicable"., Protected
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IATA (Cargo)
Packing instruction (cargo : 203
aircraft)
Packing instruction (LQ) : Y203
Labels : Flammable gas
IATA (Passenger)
Packing instruction : 203
(passenger aircraft)
Packing instruction (LQ) : Y203
Labels : Flammable gas
14.5 Environmental hazards
ADR
Environmentally hazardous : no
RID
Environmentally hazardous : no
IMDG
Marine pollutant : no
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14.6 Special precautions for user
Refer to protective measures listed in sections 7 and 8.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulation (EC) No 649/2012 of the European : Not applicable
Parliament and the Council concerning the export and
import of dangerous chemicals
REACH - Candidate List of Substances of Very High : Not applicable

Concern for Authorisation (Article 59).
Regulation (EC) No 1005/2009 on substances that : Not applicable

deplete the ozone layer
Regulation (EC) No 850/2004 on persistent organic : Not applicable

pollutants
Volatile organic compounds : Directive 1999/13/EC on the limitation of emissions of volatile

organic compounds
Volatile organic compounds (VOC) content: 94.84 %
Other regulations : The product is classified and labelled in accordance with EC

directives or respective national laws.
Regional or national implementations of GHS may not
implement all hazard classes and categories.
Classification and labelling according to Directive 75/324/EEC.
15.2 Chemical safety assessment

For a mixture it is not mandatory to include an exposure scenario in the material safety data sheet.
The necessary safety - related information is stated in the first 16 sections.
SECTION 16: Other information
Full text of H-Statements

H220 : Extremely flammable gas.
H225 : Highly flammable liquid and vapour.
H280 : Contains gas under pressure; may explode if heated.
H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H319 : Causes serious eye irritation.
H336 : May cause drowsiness or dizziness.
H372 : Causes damage to organs through prolonged or repeated
exposure if swallowed.
H400 : Very toxic to aquatic life.
H410 : Very toxic to aquatic life with long lasting effects.
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Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Acute : Acute aquatic toxicity
Aquatic Chronic : Chronic aquatic toxicity
Eye Irrit. : Eye irritation
Flam. Gas : Flammable gases
Flam. Liq. : Flammable liquids
Press. Gas : Gases under pressure
Skin Corr. : Skin corrosion
STOT RE : Specific target organ toxicity - repeated exposure
STOT SE : Specific target organ toxicity - single exposure
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods
by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the
Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation;
Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration
associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good
Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air
Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG -
International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial
Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea
Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal
Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the
Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed
(Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No
Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization
for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH
- Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the
International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition
Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TRGS -
Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN
- United Nations; vPvB - Very Persistent and Very Bioaccumulative
Further information
Other information :
GB / EN
If you have any queries relating to this MSDS, it's contents or any other product safety related
questions, please write to the following e-mail address: sds.global-chemetall@basf.com
The content of this Safety Data Sheet (SDS) is based on an existing document from an acquired
company with adaptations to Section I. The data is currently under validation.
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The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.

Safety Data Sheet: Ardrox 9D1B, Aerosol

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Safety Data Sheet: Ardrox 9D1B, Aerosol

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Safety data sheet

SECTION 1: Identification of the substance/mixture and of the

Ardrox 9D1B, Aerosol

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

Telephone: +49 180 2273-112

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Eye irritation, Category 2 H319: Causes serious eye irritation.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Signal word : Danger

Hazard statements : H222 Extremely flammable aerosol.

Supplemental Hazard : EUH066 Repeated exposure may cause skin dryness or

Hazardous components which must be listed on the label:

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Propan-2-ol 67-63-0 Flam. Liq. 2; H225 >= 3 - < 10

Ethanol, 90367-27-4 Acute Tox. 4; H302 >= 0.025 - < 0.1

Substances with a workplace exposure limit :

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air.

If swallowed : Rinse mouth with water.

Risks : Causes serious eye irritation.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing : High volume water jet

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Further information : Use water spray to cool unopened containers.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

Recommended storage : < 50 °C

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Remarks : Protective gloves complying with EN 374. Please observe the

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Odour Threshold : No data available

Melting point/freezing point : No data available

Boiling point/boiling range : -40 °C

Flash point : -18 °C

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : No data available