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MM3010 - Mindmap 2: Maxwell Boltzmann Distribution

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MM3010 - Mindmap 2

Shreya SMITHA (MM19B054) | September 14, 2021

Maxwell
Sterlings Lagrange
Boltzmann
Approximation Multiplier Method
Distribution Conservation of particles

Fixed total energ of system


Discrete nature of
atomic molecular
spectra
Classical Particle Quantum Particle
Quantum
Identical but Identical and
Mechanics
distinguishable indistinguishable Compton Modified
"Unexplained" experimental
Scattering
phenomena

Photoelectric
effect
Stefan -
Boltzmann Law
Black Body
Radiation Key features of Photoelectric effect
1. No electrons until threshold (any intensity)
Wein's 2. As frequency increase, and Kinetic Energy
displacement increases (any intensity)
Law
Rayleigh - Jean
Law

Explanations:
1. Quantised Electromagnetic
Radiation Energy
2. EMR of frequency 'v' behaves like
particels
Planc's expression
Quantum
Mechanics

de Broglie Einstein Planck Schrodinger Born Heisenberg

Heisenberg's
Davisson Germer uncertaininty principle
experiments Drude Sommerfeld
Particles which obey Fermi model
Dirac statistics - Fermions 1. Free electron model
2. Applies quantum mechanical principles on the
Particle Wave duality
Drude model
3. Applies the Pauli's exclusion principle
4. Potential is constant within the metal
5. Electrons are identical and indistinguishable
6. Behavior subject to Fermi-Dirac statistics

Probability that energy level


E is occupied
The most probable mcrostate No has
a very large probability

Maxwell Boltzmann Fermi Dirac

All the electrons can access Only the electrons close to the Fermi
Fermi Dirac empty states at energy levels energy level are able to access empty
Distribution higher than those they occupy. states at energy levels higher than
those they occupy.

Temperature change causes Same energy change causes less


more energy takeup energy takeup

Over estimation of Cp Correct estimation of Cp

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