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    (Chemical Kinetics: Chemistry Assignment - 1

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    angad bains
    The document contains 25 chemistry questions related to chemical kinetics. It asks about reaction orders, rate laws, factors affecting reaction rates, activation energy, rate constants, half-lives, and examples of zero order, first order, and pseudo-first order reactions. Specific questions calculate concentrations, rates, fractions of molecules with sufficient energy, and ages based on half-life data.

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    (Chemical Kinetics: Chemistry Assignment - 1

    Uploaded by

    angad bains
    46 views2 pages
    The document contains 25 chemistry questions related to chemical kinetics. It asks about reaction orders, rate laws, factors affecting reaction rates, activation energy, rate constants, half-lives, and examples of zero order, first order, and pseudo-first order reactions. Specific questions calculate concentrations, rates, fractions of molecules with sufficient energy, and ages based on half-life data.

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    Chemical_Kinectics_(assignment-1)

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    The document contains 25 chemistry questions related to chemical kinetics. It asks about reaction orders, rate laws, factors affecting reaction rates, activation energy, rate constants, half-lives, and examples of zero order, first order, and pseudo-first order reactions. Specific questions calculate concentrations, rates, fractions of molecules with sufficient energy, and ages based on half-life data.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    46 views2 pages

    (Chemical Kinetics: Chemistry Assignment - 1

    Uploaded by

    angad bains
    The document contains 25 chemistry questions related to chemical kinetics. It asks about reaction orders, rate laws, factors affecting reaction rates, activation energy, rate constants, half-lives, and examples of zero order, first order, and pseudo-first order reactions. Specific questions calculate concentrations, rates, fractions of molecules with sufficient energy, and ages based on half-life data.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Chemistry

    Assignment -1
    (Chemical Kinetics)
    Q1. A reaction is of second order with respect to a reactant. How will the rate of reaction
    be affected if concentration of this reaction is i) doubled ii) reduced to half.

    Q2. Define: a) Elementary step in a reaction.


    b) Rate of a reaction.

    Q3. A 1 st order reaction has a rate constant of 0.0051 min-1. If we begin with 0.10M
    concentration of the reactant. What concentration of reactant will remain in solution
    after 3 hours.

    Q4. Distinguish between order and molecularity of a reaction. When will the order and
    molecularity of a reaction be the same.

    Q5. List four factors which affect the rate of reaction.

    Q6. The decomposition of phosphine 4PH3 (g)→P4(g)+6H2(g) has rate law:


    Rate=K [PH3] . Rate constant is 6.0X10-4 s-1 at 300 K,activation energy is 3.05X105
    J mol-1. Calculate value of rate constant at 310 K. (R=8.314 J K -1 mol-1)

    Q7. Define a) Order of a reaction b) Activation energy of a reaction.


    Q8. The data given below is for the reaction:
    2 N2O5(g)→4NO2 (g) + O2 (g) at 298K
    Determine : i) order of the reaction ii) Rate constant iii) Rate law
    Q9. What is the molecularity of the reaction:
    Cl→1/2 Cl2 (g)

    Q10. As a reaction proceeds why does its rate keep on changing?

    Q11. The rate of reaction X→Y becomes 8 times when the conc. of X is doubled. Write
    rate law.

    Q12. A reaction is 50% complete in 2hours and 75% in 4hours. What is the order of the
    reaction.
    Q13. When the rate of reaction is equal to specific reaction rate.
    Q14. State the unit of “rate constant in a zero order reaction.

    Q15. Give one example of Pseudo first order reaction.

    Q16. For the reaction 3H2(g)+ N2(g)→2NH3(g), how the rate of reaction expressions
    –d[H2]/dt and d[NH3]/dt are interrelated?

    Q17. The activation energy for the reaction:


    2HI (g) →H2+I2 (g) is 209.5 KJ mol-1
    Calculate the fraction of molecules of reactants having energy equal to or greater
    than activation energy?

    Q18. The decomposition of N2O5(g) is a first order reaction with a rate of constant of
    5X10-4 sec-1 at 450C i.e.2 N2O5(g) →4 NO2(g)+ O2(g). If initial concentration of
    N2O5 is 0.25M, calculate its concentration after 2 min. Also calculate half life of
    decomposition of N2O5(g)

    Q19. A first order decomposition reaction takes 40 min for 30% decomposition.
    Calculate its t½ value.

    Q20. At elevated temperatures, HI decomposes according to the chemical equation:


    2HI (g) →H2 (g) + I2 (g) at 44.30C. The rate of reaction increases with concentration
    of HI as shown below:
    1 2 3
    -1
    HI (mol L ) → 0.005 0.01 0.02
    Rate → 7.5X10-4 3.0X10-3 1.2X10-2
    Determine i) order of reaction and ii) write the rate expression.
    Q21. A reaction is of first order in A and second order in B.
    a. Write a differential rate equation.
    b. How is the rate affected if
    i) conc. of B is tripled
    ii) conc. of both A and B are doubled.

    Q22. Calculate half life of a first order reaction from their rate constant given
    below: a) 200 s -1 b) 2 min -1 c) 4 year -1

    Q23. The half life for decay of radioactive C-14 is 5730 years. An archaeological tool
    containing wood has only 80% of C-14 activity as found in living tree.
    Calculate the age of the tool.

    Q24. Show that the time required for 99% completion is twice the time required for the
    completion of 90% reaction.

    Q25. Derive the general expression for half life of a 1st order reaction.

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