PBF MSDS Asphalt
PBF MSDS Asphalt
PBF MSDS Asphalt
PRODUCT
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Product Description: Asphalt / VTB (Vacuum Tower Bottoms)
Product Code: 708983-00
Intended Use: Refinery process stream, Product for Sales
COMPANY IDENTIFICATION
Manufacturer/Supplier: Chalmette Refining, L.L.C.
500 W St. Bernard Highway
Chalmette, LA 70043 USA
This material is hazardous according to regulatory guidelines (see (M)SDS Section 15).
CLASSIFICATION:
LABEL:
Pictogram: No Pictogram
Hazard Statements:
H227: Combustible liquid.
Precautionary Statements:
P210: Keep away from flames and hot surfaces. -- No smoking. P280: Wear protective gloves and eye / face
protection.P370 + P378: In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2) to
extinguish.P403 + P235: Store in a well-ventilated place. Keep cool.P501: Dispose of contents and container in
accordance with local regulations.
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200.
HEALTH HAZARDS
Exposure to high fume concentrations from heated asphalt may cause eye and respiratory tract irritation.
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
Hydrogen sulfide, a highly toxic gas, may be present. Signs and symptoms of overexposure to hydrogen
sulfide include respiratory and eye irritation, dizziness, nausea, coughing, a sensation of dryness and
pain in the nose, and loss of consciousness. Odor does not provide a reliable indicator of the presence
of hazardous levels in the atmosphere.
ENVIRONMENTAL HAZARDS
No significant hazards.
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without
expert advice. Health studies have shown that chemical exposure may cause potential human health risks which
may vary from person to person.
* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by
volume.
As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity
and exact percentage (concentration) of composition may have been withheld. Specific chemical identity and
exact percentage composition will be provided to health professionals, employees, or designated representatives
in accordance with applicable provisions of paragraph (i).
INHALATION
Immediately remove from further exposure. Get immediate medical assistance. For those providing
assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give
supplemental oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device.
SKIN CONTACT
Wash contact areas with soap and water. If burned by contact with hot material, molten material
adhering to skin should be cooled as quickly as possible with water, and see a physician for removal of
adhering material and treatment of burn.
EYE CONTACT
Flush thoroughly with water for at least 15 minutes. Get medical assistance.
INGESTION
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
First aid is normally not required. Seek medical attention if discomfort occurs.
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use dry chemical, carbon dioxide (CO2), or a dry, noncombustible
material such as, dry sand or earth, to extinguish flames.
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Firefighters should use standard protective equipment and in
enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed
surfaces and to protect personnel.
Hazardous Combustion Products: Smoke, Fume, Sulfur oxides, Aldehydes, Oxides of carbon,
Hydrogen sulfide, Incomplete combustion products
FLAMMABILITY PROPERTIES
Flash Point [Method] : >60°C (140°F) - 93°C (199°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed
the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry
creeks. The National Response Center can be reached at (800)424-8802.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for firefighting information. See the Hazard
Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for
advice on the minimum requirements for personal protective equipment. Additional protective measures
may be necessary, depending on the specific circumstances and/or the expert judgment of the
emergency responders.
For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for
organic vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used
depending on the size of spill and potential level of exposure. If the exposure cannot be completely
characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended.
Chemical goggles and face shield are recommended if contact of eyes with hot product or vapors is
possible. Small spills: normal work clothes are usually adequate. Large spills: full body suit of chemical
and thermal resistant material is recommended. Work gloves (preferably gauntlet style) that provide
adequate chemical resistance. Note: gloves made of polyvinyl acetate (PVA) are not water-resistant and
are not suitable for emergency use. If contact with hot product is possible or anticipated, heat-resistant
and thermally insulated gloves are recommended.
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
SPILL MANAGEMENT
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).
Stop leak if you can do it without risk. All equipment used when handling the product must be grounded.
Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or
confined areas. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking
tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible
material and transfer to containers. Large Spills: Water spray may reduce vapor; but may not prevent
ignition in closed spaces. If liquid is too viscous for pumping, scrape it up with shovels into a suitable
container for recycle or disposal.
Water Spill: Stop leak if you can do it without risk. Material will sink. Consult an expert. Remove
material, as much as possible, using mechanical equipment.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current
direction and speed may greatly influence the appropriate action to be taken. For this reason, local
experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Remove debris in path of spill prior to oiling and remove contaminated debris from shoreline and water
surface and dispose of according to local regulations. Large Spills: Dike far ahead of liquid spill for later
recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
HANDLING
Avoid breathing mists or vapors. When heating to normal handling temperatures, avoid local
overheating. Use only with adequate ventilation. Harmful amounts of H2S may be present. The
toxic and olfactory (sense of smell) fatigue properties of hydrogen sulfide require that air monitoring
alarms and respiratory protection be used where the concentration might be expected to reach a harmful
level, such as in an enclosed space, heated transport vessel, or in a spill or leak situation.
Prevent small spills and leakage to avoid slip hazard.
STORAGE
Non-absorbent insulation such as foam glass is recommended for tankage and piping. Keep container
closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in
a cool, well-ventilated area.
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
HYDROGEN SULFIDE TWA 1 ppm N/A ACGIH
VACUUM RESIDUUM (PETROLEUM) Inhalable TWA 0.5 mg/m3 N/A ACGIH
[benzene solubles] fraction.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure
conditions. Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as
applications, handling practices, concentration and ventilation. Information on the selection of protective
equipment for use with this material, as provided below, is based upon intended, normal usage.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure
mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are
inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be
exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use
conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times
for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be
considered for this material include:
Chemical resistant gloves are recommended. If product is hot, thermally protective, chemical
resistant gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves.
Eye Protection: If contact with material may occur, safety glasses and face shield are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published
literature or manufacturer data. The types of clothing to be considered for this material include:
Chemical / oil resistant clothing if contact with material is likely. If product is hot, thermally
protective, chemical resistant apron and long sleeves are recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing
and protective equipment to remove contaminants. Discard contaminated clothing and footwear that
cannot be cleaned. Practice good housekeeping.
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the
environment by applying appropriate control measures to prevent or limit emissions.
Note: Physical and chemical properties are provided for safety, health and environmental
considerations only and may not fully represent product specifications.
GENERAL INFORMATION
Physical State: Liquid
Form: Viscous
Color: Black
Odor: Petroleum/Solvent
Odor Threshold: N/D
OTHER INFORMATION
Freezing Point: N/A
Melting Point: N/A
CONDITIONS TO AVOID: Open flames and high energy ignition sources. Contact of hot product with water.
Overheating.
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
SECTION 11 TOXICOLOGICAL INFORMATION
OTHER INFORMATION
For the product itself:
Asphalt (bitumen): May contain low levels of polycyclic aromatic compounds (PACs), some of which are
suspected of causing cancer under conditions of poor industrial hygiene and prolonged repeated contact. These
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
PACs may also be inhaled. Inhalation studies at high concentrations of fumes resulted in bronchitis, pneumonitis,
fibrosis and cell damage. Avoid contact with the asphalt emissions.
Contains:
HYDROGEN SULFIDE: Chronic health effects due to repeated exposures to low levels of H2S have not been
established. High level (700 ppm) acute exposure can result in sudden death. High concentrations will lead to
cardiopulmonary arrest due to nervous system toxicity and pulmonary edema. Lower levels (150 ppm) may
overwhelm sense of smell, eliminating warning of exposure. Symptoms of overexposure to H2S include
headache, fatigue, insomnia, irritability, and gastrointestinal problems. Repeated exposures to approximately 25
ppm will irritate mucous membranes and the respiratory system and have been implicated in some eye damage.
EMISSIONS (generated from heated bitumen product): According to The International Agency for Research on
Cancer (IARC), certain specific occupational uses of bitumen products may result in carcinogenic hazards, as
follows: (a) Occupational exposures to oxidized bitumens and their emissions during roofing are ‘probably
carcinogenic to humans’ (Group 2A), (b) occupational exposures to hard bitumens and their emissions during
mastic asphalt work are ‘possibly carcinogenic to humans’ (Group 2B), and (c) occupational exposures to
straight-run bitumens and their emissions during road paving are ‘possibly carcinogenic to humans’ (Group 2B).
These levels of hazard identified by IARC are associated with the specified occupational uses which require
heating. Oxidized asphalts have been defined as having a Penetration Index (PI) of > 2.0.
The information given is based on data available for the material, the components of the material, and similar
materials.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
MOBILITY
Majority of components -- Low water solubility, expected to sink and migrate into the sediment. Expected
to partition to sediment and wastewater solids.
Material -- Low potential to migrate through soil.
Disposal recommendations based on material as supplied. Disposal must be in accordance with current
applicable laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
Dispose of waste at an appropriate treatment & disposal facility in accordance with applicable laws and
regulations, and product characteristics at time of disposal. Product is suitable for burning in an
enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures
to prevent formation of undesirable combustion products.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain
residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty
drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty
containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor
and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR
OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
LAND (DOT)
Proper Shipping Name: TARS, LIQUID
Hazard Class & Division: COMBUSTIBLE LIQUID
ID Number: 1999
Packing Group: III
ERG Number: 130
Label(s): 3
Transport Document Name: UN1999, TARS, LIQUID, COMBUSTIBLE LIQUID, PG III
Footnote: This material is not regulated under 49 CFR in a container of 119 gallon capacity or less when
transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or
specifically listed as a hazardous substance.
SEA (IMDG):
Proper Shipping Name: TARS, LIQUID
Hazard Class & Division: 3
ID Number: 1999
Packing Group: III
ERG Number: 130
Label(s): 3
Transport Description: UN1999; TARS, LIQUID; COMBUSTIBLE LIQUID, PG III
Marine Pollutant: No
AIR (IATA)
Proper Shipping Name: NOT STANDARD PRACTICE
Hazard Class & Division:
UN Number:
Packing Group: (N/A)
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
Label(s) / Mark(s):
Transport Document Name:
OSHA HAZARD COMMUNICATION STANDARD: This material is considered hazardous in accordance with
OSHA HazCom 2012, 29 CFR 1910.1200.
Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS,
IECSC, KECI, PICCS, TSCA
CERCLA: This material is not subject to any special reporting under the requirements of the Comprehensive
Environmental Response, Compensation and Liability Act (CERCLA). Contact local authorities to determine if
other reporting requirements apply.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier
notification requirements of the SARA 313 Toxic Release Program.
KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H220: Extremely flammable gas; Flammable Gas, Cat 1
H227: Combustible liquid; Flammable Liquid, Cat 4
H280: Contains gas under pressure; may explode if heated; Pressurized Gas
H330(2): Fatal if inhaled; Acute Tox Inh, Cat 2
H400: Very toxic to aquatic life; Acute Env Tox, Cat 1
Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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SAFETY DATA SHEET
THIS SDS COVERS THE FOLLOWING MATERIALS: CHRF: Coker Feed | CHRF: Crude 1 VTB |
CHRF: Crude 2 VTB | CHRF: VTB Storage | CHRF: Asphalt |
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Disclaimer:
This Safety Data Sheet (“SDS”) was prepared in accordance with 29 CFR 1910.1200 by PBF Holding
Company LLC (“PBF”). PBF does not assume any liability arising out of product use by others. All risks of
use of the product are assumed by the user. The information, recommendations, and suggestions
presented in this SDS are based upon test results and data believed to be reliable and is offered in good
faith. The end user of the product has the responsibility for evaluating the adequacy of the data under the
conditions of use, determining the safety, toxicity and suitability of the product under these conditions, and
obtaining additional or clarifying information where uncertainty exists. No guarantee expressed or implied is
made as to the effects of such use, the results to be obtained, or the safety and toxicity of the product in any
specific application. Furthermore, the information herein is not represented as absolutely complete, since it
is not practicable to provide all the scientific and study information in the format of this document, plus
additional information may be necessary under exceptional conditions of use, or because of applicable laws
or government regulations. WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND
NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a
recommendation for uses which infringe valid patents or as extending license under valid patents.
Appropriate warnings and safe handling procedures should be provided to handlers and users. Alteration of
this document is strictly prohibited. Except to the extent required by law, republication or retransmission of
this document, in whole or in part, is not permitted.
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Product Name: Asphalt / VTB (see Section 16 for specific products covered)
Revision Date: 08 Decemberr 2016
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