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Answer (H.W 3) 1-Sec

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Malak El-sayed

The document contains calculations of standard enthalpy changes (ΔH°) for various chemical reactions. ΔH° values are calculated using standard heats of formation and reaction for the reactants and products. Some examples show the use of calorimetry data like heat evolved and moles of substance to determine enthalpy of solution or reaction.

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Answer (H.W 3) 1-Sec

Uploaded by

Malak El-sayed
17 views5 pages
The document contains calculations of standard enthalpy changes (ΔH°) for various chemical reactions. ΔH° values are calculated using standard heats of formation and reaction for the reactants and products. Some examples show the use of calorimetry data like heat evolved and moles of substance to determine enthalpy of solution or reaction.

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answer (H.W 3) 1-sec

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The document contains calculations of standard enthalpy changes (ΔH°) for various chemical reactions. ΔH° values are calculated using standard heats of formation and reaction for the reactants and products. Some examples show the use of calorimetry data like heat evolved and moles of substance to determine enthalpy of solution or reaction.

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© All Rights Reserved
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Download as pdf or txt
17 views5 pages

Answer (H.W 3) 1-Sec

Uploaded by

Malak El-sayed
The document contains calculations of standard enthalpy changes (ΔH°) for various chemical reactions. ΔH° values are calculated using standard heats of formation and reaction for the reactants and products. Some examples show the use of calorimetry data like heat evolved and moles of substance to determine enthalpy of solution or reaction.

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Answer (H.

W 3)
27) CH4+2O2 → CO2+2H2O
(-74.6)+(2×zero) (-393.5)+( 2x-241.8)
-74.6 - 877.1
∆H= H pr – Hr = (- 887.1 ) - (-74.6) = -802.5 kJ/mole
28) (2 × 226.75 ) + (3× 0 ) (2 × -393.5)+(2 × -241.8)
453.5 -1270.6
∆H= H pr-Hr = (-1270.6) – (453.5)= -1724.1 kj/mole
29) CH4 + 2O2 CO2 +2H2O
(-90)+(2×zero) (-406)+(2×-241.8)
-90 -889.6
∆H=Hpr –Hr = -889.6–(-90)=-799.6 kJ/mole
30) Al2Cl6 + 6Na 6NaCl
(-1390) + (6×zero) (6×-410)
-1390 -2460
∆H = Hpr – Hr = -2460 – (-1390) = -1070 K.J
31) 2Al+Fe2O3 Al2O3 + 2Fe
(2×zero)+ X (-1669.8)+(2 ×zero)
X -1669.8
∆H=Hpr – Hr
-847.6 = (-1669.8) – X
X = -1669.8+847.6 = -822.2
32) C2H2 + 5/2 O2 2CO2+H2O
X+(5/2 ×zero) (2×-396.7)+(-285.85)
X -1079.25
∆H=Hpr-Hr
-1300= -1079.25 – X
∴ X = 220.75 J

33) ∆H°C = heat of formation of products – heat of formation of reactions


= [(-393.51)+(2x-285.5)] – [(-238)+0]=-726.51KJ/mol.
34) (-84.67) + (7/2 X zero) → (2x-393.5) + (3x-286)
-84.67 → -1645
∆H= Hpr – Hr
∆H= -1645 – (-84.67) = -1560.33 KJ , the reaction is Exo.

35) qp= mC T = 1004.184(32 − 25.55)= 2698.68 J


n.(PCL3) = 1.38⁄(31 + 3 35) = 0.01 mol.
𝑞𝑝⁄ 2698.68⁄
H = 𝑛= 0.01= - 269868 J \mol.
36) qp= mC T = 10004.184(35 − 25)= 41840 J
n(NaOH) = 80⁄(23 + 16 + 1) = 2 mol.
𝑞𝑝
H = ⁄𝑛= 41840⁄2= - 2000 J\ mol.

37) qp= mC T = 10004.184(35 − 25)= 41840 J


𝑞𝑝⁄ 41840⁄ = - 2000 J\ mol.
H = 𝑛= 2
38) qp= mC T = 5004.184(15 − 25)= 20920 J
n(NaCl) = 71⁄(23 + 35.5) = 1.214 mol.
𝑞𝑝⁄ 20920⁄
H = 𝑛= 1.214= +17232.29 J \mol.
39) qp= mC T = 5004.184(35 − 25)= 20920 J
𝑞𝑝⁄ 20920 ⁄ = - 20920 J \mol.
H = 𝑛= 1
40) qp= mC T = 5004.1845= 10460J
−𝑞𝑝⁄ 10460⁄
Hc = 𝑛= 0.315 = -33206.3J\ mol.
41) qp= mC T = 3004.1844= 5020.8J
n(C3H 8) = 22⁄(123 + 18) = 0.5 mol.

Hc = 5020.8⁄0.5= - 10041.6J \mol.


42) qp = -Hc x n = -393.5 x 300\12 =-9837.5 KJ
43) qp = -Hc x n = -600 x 100\12+4 =-3750 KJ
44) qp = -Hc x n = -800 x 150\12+4 =-7500 KJ
45) HSol = H1 + H2 + H3 = 20 + 10 + (−60) = −30 KJ. , Exo.
46) HSol = H1 + H2 + H3 = 20 + 40 + (−70) = −10 KJ. , Exo.
47) HSol = H1 + H2 + H3 = 10 + 5 + (−22) = −7 KJ. , Exo.
48) HSol = H1 + H2 + H3 = 60 + 5 + (−90) = −25 KJ. , Exo.
49) HSol = H1 + H2 + H3 = 25 + 10 + (−30) = +5 KJ. , Endo.
50) Hdil. = H1 + H2 = 20+ (−40) = -20 KJ. , Exo
51) Hdil. = H1 + H2 = 60+ (−10) = +50 KJ. , Endo.

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