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Stoichiometry-Sheet: 2 (Balancing of Reactions) : Level - 1 1. 1. 2. 3. 4. 5. 6. 7

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CPP-SANKALP_ST-02-PH-I

CPP
STOICHIOMETRY- SHEET : 2
(Balancing of Reactions)
LEVEL - 1
1. Balance the following equation using desired medium –
1. H2O2 + KMnO4 → MnO2 + KOH + O2 + H2O
2. HNO2 + KMnO4 + H2SO4 → HNO3 + MnSO4 + K2SO4 + H2O
3. K2Cr2O7 + HCl → KCl + CrCl3 + H2O + Cl2
4. MnO4– + C2O42– + H+ → CO2 + Mn2+ + H2O
5. Cr2O72– + C2O42– + H+ → Cr3+ + CO2 + H2O
6. KMnO4 + H2S + H2SO4 → KHSO4 + MnSO4 + S + H2O
7. Ag + KCN + H2O + O2 → KAg(CN)2 + KOH

2. What may be the values of x , y ,z in the reaction:


xBr2 → yBr- + zBrO3- ?

3. Calculate the number of electrons lost or gained during the changes:


a) 3Fe + 4H2O → Fe3O4 + 4H2
b) AlCl3 + 3K → Al + 3KCl
c) H2S + NO3– → S + NO
d) Mn(OH)2 + H2O2 → MnO2

4. Six mole of Cl2 undergo a loss and gain of 10 mole of electrons to form two oxidation states of Cl.
Write down the two half reactions and find out the oxidation number of each Cl atom involved.
LEVEL - 2
5. Ι2 + KΙ → KΙ3 in the above reaction –
(A) Only oxidation takes place (B) Only reduction takes place
(C) Both the above (D) None of the above
6. In the reaction 4P + 3KOH + 3H2O → 3KH2PO 2 + PH3
(A) P undergoes reduction only
(B) P undergoes oxidation only
(C) P undergoes both oxidation and reduction
(D) neither undergoes oxidation nor reduction
7. Which of the following reactions involves oxidation and reduction-
(A) NaBr + HCl → NaCl + HBr (B) HBr + AgNO 3 → AgBr +HNO 3
(C) H2 + Br2 → 2HBr (D) Na2O + H2SO 4 → Na2SO 4 + H2O

8. Which of the following reactions does not involve either oxidation or reduction ?
2+ + +2 –2 –2
(A) VO → V2O 3 (B) Na → Na (C) Zn → Zn (D) CrO 4 → Cr2O 7

9. In the half reaction 2ClO 3 → Cl 2
(A) 5 electrons are gained (B) 5 electrons are liberated
(C) 10 electrons are gained (D) 10 electrons are liberated
CPP-SANKALP_ST-02-PH-I

10. Which of the following represent redox reactions :


(A) Cr2O72– + 2OH– 2CrO42– + H2O
2– +
(B) 2CrO4 + 2H Cr2O72– + H2O
(C) 2MnO4– + 3Mn2+ + 4OH 5 MnO2 + 2H2O
(D) 2Cu+ Cu + Cu2+
11. When (NH4)2 Cr2O7 is heated :
(A) there is oxidation of N (B) there is reduction of Cr
(C) net reaction is disproportionations (D) net reaction is neutralisation
12. Which of the following are disproportionation reaction ?

(A) 2RCHO Al ( OEt )
 3 → RCOOCH2R (B) 4H3PO3 → 3H3 PO4 + PH3
∆ ∆
(C) NH4NO3 → N2O + 2H2O (D) PCl5 → PCl3 + Cl2

13. Which of the following are not redox reactions ?


(A) Mg + N2 → Mg3N2
(B) K4[Fe(CN)6] + H2SO4 + H2O → K2SO4 + CO + FeSO4 + (NH4)2SO4
(C) I2 + 3Cl2 → ICl3
(D) CuSO4 + NH3 → [Cu(NH3)4]SO4

14. Which of the following are redox reactions ?


(A) NaIO3 + NaHSO3 → NaHSO4 + Na2SO4 + I2 + H2O
(B) FeCl3 + K4[Fe(CN)6] → KCl + Fe4[Fe(CN)6]3
(C) AgCl + Na2S2O3 → Na3[Ag(S2O3)2] + NaCl
(D) NaBiO3 + MnSO4 + HNO3 → HMnO4 + Bi(NO3)3 + NaNO3 + Na2SO4 + H2O

ANSWER KEY
1. 1. 3H2O2 + 2KMnO4 → 2MnO2 + 2KOH +3O2 + 2H2O
2. 5HNO2 + 2KMnO4 + 3H2SO4 → 5HNO3 + 2MnSO4 + K2SO4 + 3H2O
3. K2Cr2O7 + 14HCl → 2KCl + 2CrCl3 + 7H2O + 3Cl2
4. 2MnO4– + 5C2O42– + 16H+ → 10CO2 + 2Mn2+ + 8H2O
5. Cr2O72– + 3C2O42– + 14H+ → 2Cr3+ + 6CO2 + 7H2O
6. 2KMnO4 + 5H2S + 4H2SO4 → 2KHSO4 + 2MnSO4 + 5S + 8H2O
7. 4Ag + 8KCN + 2H2O + O2 → 4KAg(CN)2 + 4KOH
2. x=6, y=10, z=2
3. a) 8
b) 3
c) 6
d) 2
4. +5; 6Cl2 → 2Cl5+ + 10Cl–
5. C 6. C 7. C 8. D 9. C 10. AB 11. AB
12. AB 13. BD 14. AD

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