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    Unit 11 Alcohols & Ethers

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    Deepesh kumar
    This document contains 20 questions from past years' question papers on the topic of alcohols and phenols from the Organic Chemistry unit of Class 12 CBSE. The questions cover various topics like reactions and mechanisms of alcohols and phenols, their properties and interconversions. Multiple choice and long answer questions involving reaction pathways, products, mechanisms and reasoning have been included from years 2020 to 2015.

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    © All Rights Reserved
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    Unit 11 Alcohols & Ethers

    Uploaded by

    Deepesh kumar
    167 views6 pages
    This document contains 20 questions from past years' question papers on the topic of alcohols and phenols from the Organic Chemistry unit of Class 12 CBSE. The questions cover various topics like reactions and mechanisms of alcohols and phenols, their properties and interconversions. Multiple choice and long answer questions involving reaction pathways, products, mechanisms and reasoning have been included from years 2020 to 2015.

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    UNIT 11 ALCOHOLS & ETHERS

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    This document contains 20 questions from past years' question papers on the topic of alcohols and phenols from the Organic Chemistry unit of Class 12 CBSE. The questions cover various topics like reactions and mechanisms of alcohols and phenols, their properties and interconversions. Multiple choice and long answer questions involving reaction pathways, products, mechanisms and reasoning have been included from years 2020 to 2015.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    167 views6 pages

    Unit 11 Alcohols & Ethers

    Uploaded by

    Deepesh kumar
    This document contains 20 questions from past years' question papers on the topic of alcohols and phenols from the Organic Chemistry unit of Class 12 CBSE. The questions cover various topics like reactions and mechanisms of alcohols and phenols, their properties and interconversions. Multiple choice and long answer questions involving reaction pathways, products, mechanisms and reasoning have been included from years 2020 to 2015.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    QUESTION BANK

    ORGANIC CHEMISTRY
    UNIT-11 ALCOHOLS & PHENOLS
    CLASS-12 (CBSE)

    S. No. Questions Year


    1. (a) Out of t-butyl alcohol and n-butanol, which one will undergo acid catalyzed 2020
    dehydration faster and why?
    (b) Carry out the following conversions :
    (i) Phenol to Salicylaldehyde
    (ii) t-butylchloride to t-butyl ethyl ether
    (iii) Propene to Propanol
    OR
    (a) Give the mechanism for the formation of ethanol from ethene.
    (b) Predict the reagent for carrying out the following conversions :
    (i) Phenol to benzoquinone
    (ii) Anisole to p-bromoanisole
    (iii) Phenol to 2,4,6-tribromophenol
    2. Give reasons for the following : 2020
    (a) Bond angle in alcohol is slightly less than the tetrahedral angle.
    (b) C – OH bond length in CH3OH is slightly more than the C – OH bond length in
    phenol.
    3. (a) Write the mechanism of the following reaction : 2020

    (b) Write the preparation of phenol from cumene.


    OR
    How can you convert the following :
    (i) Sodium phenoxide to o-hydroxybenzoic acid
    (ii) Acetone to propene
    (iii) Phenol to chlorobenzene
    4. Write the product(s) of the following reactions : 2020

    OR
    (a) Write the mechanism of the following SN1 reaction :

    (b) Write the equation for the preparation of 2-methyl-2-methoxypropane by


    Williamson synthesis.
    5. Give the structures of final products expected from the following reactions : 2020
    (i) Hydroboration of propene followed by oxidation with H2O2 in alkaline medium.
    (ii) Dehydration of (CH3)3C–OH by heating it with 20% H3PO4 at 358 K.
    (iii) Heating of with HI.

    OR
    QUESTION BANK
    ORGANIC CHEMISTRY
    UNIT-11 ALCOHOLS & PHENOLS
    CLASS-12 (CBSE)

    How can you convert the following?


    (i) Phenol to o-hydroxybenzaldehyde.
    (ii) Methanal to ethanol
    (iii) Phenol to phenyl ethanoate.
    6. (a) How do you convert the following : 2019
    (i) Phenol to Anisole
    (ii) Ethanol to Propan-2-ol
    (b) Write mechanism of the following reaction :

    (c) Why phenol undergoes electrophilic substitution more easily than benzene?
    OR
    (a) Account for the following :
    (i) o-nitrophenol is more steam volatile than p-nitrophenol.
    (ii) t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead
    of t-butylmethylether.
    (b) Write the reaction involved in the following :
    (i) Reimer-Tiemann reaction
    (ii) Friedal-Crafts Alkylation of Phenol
    (c) Give simple chemical test to distinguish between Ethanol and Phenol.
    7. (a) Give equations of the following reactions : 2019
    (i) Phenol is treated with conc. HNO3.
    (ii) Propene is treated with B2H6 followed by H2O2/OH–.
    (iii) Sodium t-butoxide is treated with CH3Cl.
    (b) How will you distinguish between butan-1-ol and butan-2-ol?
    (c) Arrange the following in increasing order of acidity : Phenol, ethanol, water
    OR
    (a) How can you obtain Phenol from
    (i) Cumene, (ii) Benzene sulphonic acid, (iii) Benzene diazonium chloride?
    (b) Write the structure of the major product obtained from dinitration of
    3-methylphenol.
    (c) Write the reaction involved in Kolbe’s reaction.
    8. Arrange the following in increasing order of their acidic character : 2019
    Benzoic acid, Phenol, Cresol
    9. What happens when 2019
    (a) Salicylic acid is treated with (CH3CO)2O/H+ ?
    (b) Phenol is oxidised with Na2Cr2O7/H+?
    (c) Anisole is treated with CH3Cl/anhydrous AlCl3?
    Write chemical equation in support of your answer.
    10. Arrange the following in increasing order of their boiling point : 2019
    CH3CH2OH, CH3CHO, CH3 – O – CH3
    11. Arrange the following in increasing order of their acidic character : 2019
    Ethanol, Phenol, Water
    12. Define with equation : 2019
    (a) Riemer-Tiemann Reaction
    (b) Williamson’s Synthesis
    QUESTION BANK
    ORGANIC CHEMISTRY
    UNIT-11 ALCOHOLS & PHENOLS
    CLASS-12 (CBSE)

    13. (a) How will you synthesise the following alcohol from appropriate alkene : 2019

    (b) Write the mechanism of the following reaction :

    14. Write the equations involved in the following reactions : 2019


    (a) Kolbe’s reaction
    (b) Friedel-Crafts alkylation of anisole
    15. (a) Show how you will synthesise the following alcohol prepared by the reaction of a 2019
    suitable Grignard reagent on methanal?

    (b) Write the mechanism of the following reaction :

    16. What happens when 2019


    (a) Phenol reacts with Conc. HNO3?
    (b) Ethyl chloride reacts with NaOC2H5?
    Write the chemical equations involved in the above reactions.
    17. (a) Butan-1-ol has a higher boiling point than diethyl ether. Why? 2019
    (b) Write the mechanism of the following reaction :

    18. An aromatic compound ‘A’ on treatment with CHCl3 and KOH gives two 2019
    compounds, both of which give same product ‘B’ when distilled with Zinc dust.
    Oxidation of ‘B’ gives ‘C’ with molecular formula C7H6O2. Sodium salt of ‘C’ on
    heating with soda lime gives ‘D’ which may also be obtained by distilling ‘A’ with
    Zinc dust. Identify ‘A’, ‘B’, ‘C’ and ‘D’.
    OR
    How do you convert the following :
    (a) Phenol to Toluene
    (b) Ethanol to Ethanal
    19. Give one chemical test to distinguish between the following : 2019
    (a) Phenol and 1-propanol
    (b) Ethanol and dimethyl ether
    (c) 1-propanol and 2-Methyl-2-propanol
    OR
    Write the products of the following reactions :
    QUESTION BANK
    ORGANIC CHEMISTRY
    UNIT-11 ALCOHOLS & PHENOLS
    CLASS-12 (CBSE)

    20. Write the structures of the main products in the following reactions : 2018(OD)

    21. (a) Arrange the following compounds in the increasing order of their acid strength : 2017(OD)
    p-cresol, p-nitrophenol, phenol
    (b) Write the mechanism (using curved arrow notation) of the following reaction:

    22. Write the structures of the products when Butan-2-ol reacts with the following : 2017(OD)
    (a) CrO3
    (b) SOCl2
    23. (a) Write the product(s) in the following reactions : 2017(D)

    (b) Give simple chemical tests to distinguish between the following pairs of
    compounds :
    (i) Ethanol and Phenol (ii) Propanol and 2-methylpropan-2-ol
    24. (a) Write the formula of reagents used in the following reactions : 2017(D)
    (i) Bromination of phenol to 2,4,6-tribromophenol
    (ii) Hydroboration of propene and then oxidation to propanol.
    (b) Arrange the following compound groups in the increasing order of their property
    indicated :
    (i) p-nitrophenol, ethanol, phenol (acidic character)
    (ii) Propanol, Propane, Propanal (boiling point)
    (c) Write the mechanism (using curved arrow notation) of the following reaction :
    QUESTION BANK
    ORGANIC CHEMISTRY
    UNIT-11 ALCOHOLS & PHENOLS
    CLASS-12 (CBSE)

    25. What happens when 2017(F)


    (a) (CH3)3C – OH is treated with Cu at 573 K,
    (b) Anisole is treated with CH3Cl / anhydrous AlCl3,
    (c) Phenol is treated with Zn dust?
    Write chemical equations in support of your answer.
    26. Write the major product in the following equations: 2016 (OD)

    27. Write the mechanism of the following reaction: 2016(D)


    2013(D)

    28. Write the main product (s) in each of the following reaction: 2016(D)

    29. Give reason for the following: 2015(OD)


    (i) Phenol is more acidic than methanol.
    (ii) The C-O-H bond angle in alcohols is slightly less than the tetrahedral angle
    (𝟏𝟎𝟗𝒐𝟐𝟖′)
    (iii) (𝑪𝑯𝟑)3C− 𝑶 − 𝑪𝑯𝟑 on reaction with HI gives (𝑪𝑯𝟑)𝟑𝑪 − 𝑰 𝒂𝒏𝒅 𝑪𝑯𝟑 − 𝑶𝑯 as
    the main products and not (𝑪𝑯𝟑)𝟑𝑪 − 𝑶𝑯 and 𝑪𝑯𝟑 − 𝑰.
    30. (a) How do you convert the following: 2015(D)
    (i) Phenol to anisole
    (ii) Propan-2-ol to 2-methylpropan-2-ol
    (iii) Aniline to phenol
    QUESTION BANK
    ORGANIC CHEMISTRY
    UNIT-11 ALCOHOLS & PHENOLS
    CLASS-12 (CBSE)

    31. (a) Write the mechanism of the following reaction: 2015(D)

    (b) Write the equation involved in the acetylation of Salicylic acid.


    32. (a) Write the mechanism of the following reaction. 2014(OD)
    2014(D)

    (b) Write the equation involved in Reimer-Tiemann reaction.


    33. Which of the following isomers is more volatile: o-nitrophenol or p-nitrophenol. 2014(D)
    34. Explain the mechanism of the following reaction: 2013(OD)

    35. Write the equation involved in the following reactions: 2013(OD)


    (i) Reimer - Tiemann reaction (ii) Williamson’s ether synthesis
    36. How will you convert: 2013(D)
    (i) Propene to Propan-2-ol? (ii) Phenol to 2, 4, 6 – trinitrophenol?
    37. Explain the mechanism of acid catalysed hydration of an alkene to form 2012(OD)
    corresponding alcohol.
    38. Explain the following behaviors: 2012(OD)
    (i) Alcohols are more soluble in water than the hydrocarbons of comparable molecular
    masses.
    (ii) Ortho-nitophenol is more acidic than ortho-methoxyphenol.
    39. Draw the structure and name the product formed if the following alcohols are 2012(D)
    oxidized. Assume that an excess of oxidizing agent is used.
    (i) 𝑪𝑯𝟑𝑪𝑯𝟐𝑪𝑯𝟐𝑪𝑯𝟐𝑶𝑯 (ii) 2-butenol (iii) 2-methyl-1-propanol
    40. How would you convert ethanol to ethene? 2011(OD)
    41. How would you obtain the following: 2011(OD)
    (i) Benzoquinone from phenol
    (ii) 2-Methylpropan-2-ol from methyl magnesium bromide
    (iii) Propan-2-ol from propene
    42. Name the reagents used in the following reactions: 2011(OD)
    (i) Benzyl alcohol to benzoic acid.
    (ii) Dehydration of propan-2-ol to propene.
    (iii) Butan-2-one to butan-2-ol.
    43. How would you obtain 2011(D)
    (i) Picric acid (2, 4, 6-trinitrophenol) from phenol (ii) 2-Methylpropene from 2-
    methylpropanol?

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