Vidyamandir Classes

Solutions to JEE Advanced – 3 |JEE 2023 | Paper-1

PHYSICS
1.(C) Time depends on velocity component  to river which is same for all
All the four boats A, B, C and D take same time.

2GM
2.(B) u  kVe  k
R
ΔU  ΔK  0
 GM   GM  1 2
m  m    0  mu  0
 r   R  2
 GM  1 2  2GM  mGM
 m   mk  
 R  2  R  r
GMm GMm R
 (1  k 2 )   r
R r 1  k2
R R k2
 h  r R  2
R 
1 k 1 k2

3.(C) As the curve is smooth, there is no gain in angular motion.

 Mgh  1 / 2Mu 2  u  2 gh
i.e. velocity with which it gets on to the plank.
N   MA [For plank]
N  Mg ; Mg   MA
 A  g [Towards right]
[For cylinder]
a  g [Towards left]
 cm  I cm
2g 
N  R  1 / 2MR2   (clockwise)
R
Let V and v be linear velocity of plank and center of cylinder when pure rolling begins
V  g t
v  u  g t
2g 
 t
R
When pure rolling begins
v  R  V   u  g t   2 g t  g t
u
 t
4g
3u u
 v and V 
4 4
ar  2 g  ; ur  u
2
3u u u u 2 3u 2
Vr        u  2  2 g    l 
4 4 2 2 16 g 

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1 2 1
4.(C) Work  KE  mv  m  2a  2r   2mra
2 2
5.(A) Let velocity of water at the two cross-sections be v1 and v2
 Av1  av2  V
Applying Bernoulli’s Theorem between two points below the two arms of
the U-tube at the centre of the pipe : [Let air pressure in U-tube = P0]
1 2 1
P1  v1  P2  v22
2 2
1
P1  P2   (v22  v12 )
2
V V
Using P1  P0 gh1 , P2  P0 gh2 , v1  , v2 
A a
1 V 2 V 2  V2  1 1 
g (h1  h2 )    2  h1  h2    2
2  a 2 A  2g  a 2
A 

6.(C) From constraint equation ar  2a

 Acceleration of block

 a 2  (2a )2  2(a)(2a ) (cos (   ))

 a 5  4cos 

7.(BC) As air is pumped out, pressure above surface of water decreases because of which pressure at all points of water decreases
( P  Psurface   gh) .
So, force on bottom decreases.
Since water is assumed to be incompressible, density and volume remain unchanged.

8.(BD) During collision, no impulsive friction force acts on A or B.

 JCM  0  ΔLCM  0
So, there is no change in angular velocity and just after collision ω A  ω & ω B  0 .
Their linear velocities get exchanged (same mass elastic head on collision).

After both start pure rolling :

2 2
For A : mR 2ω  mR 2 ω1  mV1R
5 5
2 2 V  2
 mR 2 ω = mR 2  1   mV1R  V1  ωR
5 5 R 7
2
For B : mVR  mR 2 ω2  mV 2 R
5
2 V  5
 m(ωR ) R  mR 2  2   mV 2 R  V2  ωR
5  R 7

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 Vidyamandir Classes

9.(BD) B cannot move in vertical line relative to A as horizontal component of their velocities cannot be equal.

vBA is constant  Straight line motion

Particle collide if v BA is along BA
 y-component of vBA  0  u 1 sin   u 2 sin 
 Time of flight is equal
If t is the time of collision and T is the time of flight, for collision : t  T
u1 cos  t  u2 cos  t  d
u1 cos  T  u2 cos  T  R1  R2
 T  t  R1  R2  d

G  4M  m GMm
10.(ACD) At x  2R, F 2
 0
4R 16 R2
 Velocity is decreasing at x  2 R
For minimum velocity put F  x   0

G  4M  GM
  2
 0  x  4R
x  6R  x2
So, minimum velocity occurs at x  4 R , and once this point is reached, the particle reaches surface of B.
Applying energy conservation : K f  Ki  U i  U f

1  G  4 M  m G  M  m   G  4 M  m GMm 
0  mv 2         
2  2R 4R   4R 2R 

3GM
 v
2R

11.(BCD)
When stationary
gh  P
When accelerating upwards
  g  a  h1  P
 h1  h
When accelerating downwards
 g  ah2  P  h2  h
When moving with constant velocity
gh 3  P  h3  h

12.(ABD) After time t, mass of plank with sand will be m0   t and let its velocity be v. In next small time interval dt, let
dm mass of sand falls with sped u and sticks to it.
Change in momentum of dm:

d p  dm vi  dm u j  dm vi  u j
     

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 Vidyamandir Classes

d p dm  ˆ
Force on dm   vi  uj   vi  u j
 
dt dt
 Force on plank    vi   u j  F horizontal  v and Fvertical  u
 u  2 gh  Fvertical  h
Horizontal component of this force causes deceleration of plank.
dv
  m0   t    v
dt
V t
 dv  dt v0 m  t
     n  ln 0
V0
v m
0 0
 t v m0
v0 m0   t m0v0
   v
v m0 m0  t
Let time taken to cross be T.
 T
dx m0 v0 dt

dt m0  t
  dx  m0 v0  m0  t
0 0

mv m  T
   0 0 n 0  m0  T  m0e m0v0
 m0
 Velocity after crossing
 
m0 v0 m0 v0
v   v0 e m0v0
m0  T m e 
0
m0 v0
2
dv  m0 v0     m0 v0   2
a  2
    v
dt  m0   t  m0 v0  m0   t  m0v0

d 2 3  (0.04)2
1.(60) Minimum friction on plug F  hg   5  1000  10   60 N
4 4
2.(130) Ejection speed of water  2 gh
d 2
Volume flow rate  2 gh
4
d 2 3  (0.04)2
Water flows in time t is  2 gh  t  2  10  5  3  3600  130 m3 (approx.)
4 4
3.(2) Time after which block will move
F cos    s N
F cos    s  mg  F sin  
 s mg
F
 cos   us sin  
 s mg
t
 cos    s sin   
 s mg
tmin   2sec
 1   2s

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When   37

4.(28) For   37 , after t  2sec

9t
N  10 
5
Block leaves contact when N  0
 9t / 5  10
50
t s
9
Impulse    mv
50/9 50/9
 12t N   10 
 v  
 5
  dt 
3   3t   dt  28 m / s
 3
2 2
5.(1)
Taking x and y as shown, for motion of ball :
ux  u cos   5, u y  u sin 
a x   g sin 37   6
a y   g cos37   8
At the centre at hoop, Sy  4 and Vy  0

 V y2  u y2  2a y s y  0  (u sin  ) 2  2( 8) (4)

 u sin   8
u sin  8
Also Vy  u y  a y t  0  u sin   (8)t  t  1
8 8

6.(10) s  s x2  s 2y
2 2
 s x  s  s y  80  16  8 m
1
(u cos   5)(1)  (6)(1)  8  u cos   6
2
(u sin )2  (u cos ) 2  82  62  100
 u  10 m / s

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CHEMISTRY
1.(B) Nitrogen has half-filled configuration.

2.(A) Bond angle of NH3  Bond angle of NF3

3.(B) K P  PNH3  PH2S

0.36  PNH3  PH 2S
PNH3  PH2S  0.6 atm
PNH3  PH2S  0.6  0.6  1.2atm
1 1 1  3
4.(A)  RH  2  2   RH  
 1 2  4
5.(D) Moles of HCl  M  V  5  3.26  16.3
16.3
Moles of MgCO3   8.15
2
Mass of MgCO3  8.15  84  684.6g

 Z2 
6.(A) I.E4 of Be   2  13.6  1.6  10 19  J  16 13.6 1.6 10 19  348.16 10 19  Y 1019 J
n 
 
 Y  348.16
7.(C) Al(CH3 )3 is electron deficient, therefore it exist as dimer.

8.(CD) As temperature decreases or molar mass increases

H increases
L decreases
W decreases
9.(ABD) O 2 contains unpaired electron in  -antibonding M.O and N2 in 2p orbital N 22  contains unpaired electron in
 -antibonding M.O.

10.(CD) Weak acid and weak base gives less heat in neutralisation hence smaller temperature rise than in case of strong acids and
bases if all other conditions are same.

11.(ACD) By definition.

12.(AC) (A) IE (I) of N is more than O due to stable half filled electronic configuration of valence shell in N.
(B) Electron gain enthalpy of O (–141 kJmol–1) is less than S, Se, Te and Po due to its small atomic size.
(C) Electronegativity on Mulliken scale is 2.8 times the electronegativity on Pauling scale.
(D) The ionic radius decreases as more electrons are ionized off.

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10  4 
9  4 
8  4
1.(6)  Total 6 spectral lines
7  4
6  4

5  4
2.(8)

3.(525)
NH 4 HS  s   NH3  g   H 2S  g 
Initial partial pressure P mm 0
Equilibrium partial pressure  P  x  mm  x  mm
From question, P  x  625 and  P  x   x  725
 x  100 and P  525

4.(250) PNH 3  PH 2S  K P  250 mm of Hg

5.(576) w   nRΔT  1  8  72  576 J

6.(1.56)  ΔU  q  w
 1.6  0.576  1.024 kJ
ΔH 1.6
   1.56
ΔU 1.024

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MATHEMATICS
1.(B) All the possible number are 9 C5 (none containing the digit 0 )
 126 .
Total numbers starting with
1  8C 4  70

(using 2,3, 4,5, 6, 7,8,9 ) Total numbers starting with 23  6 C3  20

(using 4,5,6,7,8,9 ) Total numbers starting with 245  4 C2  6

(using 6,7,8,9 )

97th number =

2.(D) Let roots of x3 – ax 2  bx – c  0 be , , 

 a     , b      , c  
Now,    1 ,    1 ,    1 are the roots of x3  px 2  qx – 9  0

    1   1   1  9               1  9  a  b  c  8

n n n

3.(C)
 r0nCr sin 2rx   r 0nCnr sin 2  n  r  x   r 0nCr sin 2rx  sin 2  n  r  x 
n n n
 r 0nCr cos 2rx  r 0nCnr cos 2  n  r  x  r 0nCr cos 2rx  cos 2  n  r  x 
n
 nCr 2sin nx cos(2r  n) x
r 0
 n
 tan nx .
n
 Cr 2 cos nx cos(2r  n) x
r 0

4.(D) tr 1  rS r  r t r  S r 1   r 2 S r 1  r 2  r  1 S r 2

 t r 1  r  r ! t1  S1  t1 
 Sr   r ! t1
tr 1  Sr   r  1 Sr 1   r  1 tr 1

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5.(D) z  z  straight line AB

while z  arg z  arg z   Arc AB
 z  z  z  arg z  arg z 

6.(A) We have sin x cos y  a 2 ……(1)

and cos x sin y  a ……(2)
Adding the equations (1) and (2), we get sin x cos y  cos x sin y  a 2  a
sin  x  y   a 2  a  1  sin  x  y   1  1  a 2  a  1
a 2  a  1  0 and a 2  a  1  0
 5 1 5  1
a 2  a  1  0 is true for all values of a  R and a 2  a  1  0  a    ,  ……(3)
 2 2 
And subtracting equations (1) and (2)
sin x cos y  cos x sin y  a 2  a ; sin  x  y   a 2  a ; 1  a 2  a  1
1  5 1  5 
a  ,  ……(4)
 2 2 
Taking common solution of equation (3) and (4).
1  5 5  1
a , .
 2 2 
kz kz
7.(BC) represent any point lying on the line joining origin and z. So, should lie outside the
k 1 k 1
circle z  2i  2
So, z should lie in the shaded region

   arg  z   0.
4

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8.(ABC)

sin 2 x  a sin x  b  0 has only one solution in  0,  

 sin x  1 gives one solution and sin x   gives other solution such that   1 or   0
  sin x  1 sin x    is the same equation as sin 2 x  a sin x  b  0
 1    a and   b
 1  b  a and b  1 or b  0
 b  (,0]  [1, ) and a  (,1]  [2, ).

9.(AD)

10.(AB)
x cannot be odd integer for if x is odd, x 2 is odd but 2 px  2q is even;

so x 2  2 px  2q  0

x cannot be even integer for if x is even, x 2  2 px is a multiple of 4 but 2q is not.

So x 2  2 px  2q  0
2
Also  x  p   p 2  2q
2
 If x is fraction then  x  p  is also a fraction but p 2  2q is an integer. So, roots cannot be integer or
rational numbers.

11.(ABC)

12.(BD)
The three possible discriminants are
c 2  4ab, b 2  4ac, a 2  4bc
For a  b  c  0 they are perfect square.
n
n
1.(5) For the expansion 1  x    nCr xr , we have
r 0
n
C0  C1  C2  ........  Cn  2n
n n n
…(i)

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1   n  n
C0  n C1  n C22  n C3  n C4  nC52  n C6  ......., ….(2)
n
1  2   n C0  n C12  n C2  n C3  nC42  n C5  n C6  ...... ….(3)

Add (1), (2) and (3), we get

n
2 n  2   n
    3  n C0  n C3  n C6  ........
 

 3  1 and1    2  0 
1
 n
3 
n

C0  n C3  n C6  ....   2n   1 n   n 
   2   
1 n 2n   2 2 
  2n   1 .2cos    cos 3  i sin 3 
3 3 
1 n  n  
 2 n   1 .2cos  n   
3  3 
1 n n n  1  n 
  2n  2  1  1 cos    2n  2 cos     2;   3
3 3  3 3

2.(0) Let n  2 m where m is positive integer then k  3m.

We have

1  x 6 m  1  6 mC1 x  6m C2 x 2  6m C3 x3 6 m C4 x4 ...... 6 m C6m x6 m

Put x  3i, we get
6m 6m
1  3i   1  6mC1 3i 6 m C2 3. 6 m C3 3 3i 6 m C4 9  ....  6 m C6 m  3i 
6m
  
 26 m cos  i sin 
 3 3
 
 1  6 mC2 .3  6 m C4 .32  .........  3i  6m C1 6m C3 3  ....
Equating imaginary parts we get
3m
3  6m

C1 6 m C2 .3  6m C2 .32  ......  26m sin 2m  0    3 
r 1
r 1 6 m
C2 r 1  0

r 1
3.(9) Vr 
2 2

 2  r    r  1 2r  1   2r 3  r 2  r 
n n
1 n 2 1 n
  Vk   k 3  k  2 k
2 k 1
k 1 k 1 k 1
1 2 2 1 1
 n  n  1  n  n  1 2n  1  n  n  1
4 12 4
1
 n  n  1 3n  n  1   2n  1  3
12

VMC |JEE-2023 | Paper – 1 11 Solutions |JEE Advanced-3

 Vidyamandir Classes

1

12
 
n  n  1 3n 2  n  2  a  12, b  3, c  2

Tr  Vr 1  Vr  2
3 1 2 1
  r  1  r 3    r  1  r 2    r  1  r   2
  2  2
1 1

 3r 2  3r  1   2
 2r  1   2
2
 3r 2  2 r  1   3r  1 r  1  d  3, e  1
 a  b  c  d  e  12  3  2  3  1  9

1 1 1 1
4.(6) Wr    
Tr 4  r  1  3r  1 r  1 4  r  1
3
  p  3, q  3  p  q  0
4  3r  1

 2

Qr  Tr 1  Tr  3  r  1  r 2  2  r  1  r  3  2r  1  2  5  6 r

 Q1, Q2 ,..... forms an A.P. with common difference 6.

 6

5.(18) Let B1, B2 , B3 ,.............., Bk black balls are placed in a row.

2
Printed number on B1 is 1  1 i.e. 2
2
Printed number on B2 is 2  2 i.e. 6


Printed number on Bk is k 2  k .

  2
Similarly the number of white balls between last two black balls  k  k   k  1   k  1   2k
2
 
 Total number of white balls  4  6  8  ....  2k

 k2  k  2 …(i)
Since, number of white balls  340
  i   k 2  k  2  340  k  18

VMC |JEE-2023 | Paper – 1 12 Solutions |JEE Advanced-3

 Vidyamandir Classes

6.(9) Number of white balls available  140

Number of black balls available  12
2
If k  12; then k  k  2  154  140

If k  11; then k 2  k  2  130

Hence,   140  130  10 and   12  11  1
   9

VMC |JEE-2023 | Paper – 1 13 Solutions |JEE Advanced-3