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    Assignment 1 and 2

    Uploaded by

    Muhammad Idrees Khan
    The document contains two assignments related to materials thermodynamics and kinetics. The first assignment contains three questions about calculating vapor pressures, phase diagrams, and temperatures at which two forms of a material have the same vapor pressure using Clausius-Clapeyron relations. The second assignment contains seven questions about calculating normal boiling points, heats of vaporization, boiling points, melting points at different pressures, and phase changes using Clausius-Clapeyron relations. Students are asked to solve the problems and submit their work by October 31st, 2022 for a total of 20 marks.

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    © All Rights Reserved

    Assignment 1 and 2

    Uploaded by

    Muhammad Idrees Khan
    47 views2 pages
    The document contains two assignments related to materials thermodynamics and kinetics. The first assignment contains three questions about calculating vapor pressures, phase diagrams, and temperatures at which two forms of a material have the same vapor pressure using Clausius-Clapeyron relations. The second assignment contains seven questions about calculating normal boiling points, heats of vaporization, boiling points, melting points at different pressures, and phase changes using Clausius-Clapeyron relations. Students are asked to solve the problems and submit their work by October 31st, 2022 for a total of 20 marks.

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    The document contains two assignments related to materials thermodynamics and kinetics. The first assignment contains three questions about calculating vapor pressures, phase diagrams, and temperatures at which two forms of a material have the same vapor pressure using Clausius-Clapeyron relations. The second assignment contains seven questions about calculating normal boiling points, heats of vaporization, boiling points, melting points at different pressures, and phase changes using Clausius-Clapeyron relations. Students are asked to solve the problems and submit their work by October 31st, 2022 for a total of 20 marks.

    Copyright:

    © All Rights Reserved
    47 views2 pages

    Assignment 1 and 2

    Uploaded by

    Muhammad Idrees Khan
    The document contains two assignments related to materials thermodynamics and kinetics. The first assignment contains three questions about calculating vapor pressures, phase diagrams, and temperatures at which two forms of a material have the same vapor pressure using Clausius-Clapeyron relations. The second assignment contains seven questions about calculating normal boiling points, heats of vaporization, boiling points, melting points at different pressures, and phase changes using Clausius-Clapeyron relations. Students are asked to solve the problems and submit their work by October 31st, 2022 for a total of 20 marks.

    Copyright:

    © All Rights Reserved
    of 2

    Institute of Metallurgy and Materials Engineering

    University of Punjab, Lahore


    Assignment #1 [CLO 2]

    Subject: Materials Thermodynamics & Kinetics (MME-223)


    Total Marks: 10 (Equivalent to 4%)
    Submission Deadline: 31st October 2022

    Solve the following problems using Clapeyron or Clausius-Clapeyron


    relations as appropriate.

    Question 1: The vapor pressure p of Zn varies with temperature (T) in equilibrium with
    −15780
    Solid as ln p = − 0.755ln T + 19.25
    T
    −15250
    Liquid as ln p = − 1.255ln T + 21.79
    T
    Find Tb, Ttp, Ptp, ∆Hsub, ∆Heva at Tb and Ttp, ∆Hmelting

    Question 2: CaF2 has two solid allotropes, α (low temperature) and β (high temperature), β melts
    to form liquid at the melting point. The vapor pressure of CaF2 vapors varies with temperature as
    given below for different condensed phases.
    −54350
    CaF2 (α) : ln p = − 4.525ln T + 56.57
    T
    −53780
    CaF2 (β) : ln p = − 4.525ln T + 56.08
    T
    −50200
    CaF2 (L): ln p = − 4.525ln T + 53.96
    T
    Draw a schematic phase diagram for CaF2 showing all the transformations and label all the
    characteristic points. And find Tb, Ttp, Ptp at all the triple points, ∆Hsub(α→v), ∆Hsub(β →v), ∆Heva,
    ∆Hmelting , ∆Hα→β

    Question 3: The vapor pressure, P, (measured in mm Hg) of liquid arsenic, is given by


    −2460 −6947
    log P = + 6.69 and that of solid arsenic by log P = + 10.8
    T T
    Calculate the temperature at which the two forms of arsenic will have the same vapor pressure.
    Also find out the pressure at that temperature.
    Institute of Metallurgy and Materials Engineering
    University of Punjab, Lahore
    Assignment #2 [CLO 2]

    Subject: Materials Thermodynamics & Kinetics (MME-223)


    Total Marks: 10 (Equivalent to 4%)
    Submission Deadline: 31st October 2022

    Solve the following problems using Clapeyron or Clausius-Clapeyron


    relations as appropriate.

    Question 1: The saturated vapor pressure of liquid NdCl5 measured at 478 K and 520 K is 0.3045
    atm and 0.8310 atm. Calculate the normal boiling point of NdCl5.

    Question 2: The vapor pressures of liquid thorium tetraiodide at 1073 K and 1098 K are 62395 Pa
    and 87993 Pa, respectively. Calculate its mean heat of vaporization.

    Question 3: The heat of evaporation (∆Heva) of copper at its normal boiling point is 31172 kJ/mol.
    The vapor pressure of copper at 1773 K is 34 Pa. Calculate the boiling point of copper.

    Question 4: The densities of liquid and solid bismuth are 10.0 g/cm3 and 9.673 g/cm3,
    respectively at the normal melting point 543 K. The heat of fusion (∆Hmelting) is 2.633 12.02
    kJ/mol. Calculate the melting point of bismuth under a pressure of 100 atm, Atomic weight of
    bismuth is 209.

    Question 5: The melting point of cadmium at 1 atm is 594 K, and its heat of fusion is 57.15 kJ/kg
    [you may like to convert into J/mol]. The volume change on the melting of cadmium is +0.0064
    cm3/g [you may like to convert into cm3/mol]. Calculate the melting point of cadmium at 2 atm
    pressure.

    Question 6: Mercury melts at 234.13 K at 1 atm pressure. The densities of liquid and solid
    mercury are 13.69 g/cm3 and 14.19 cm3 respectively at the normal melting point. The heat of
    fusion of mercury is 9.75 kJ/kg). Calculate the melting point of mercury at 2 atm pressure.

    Question 7: The densities of ice and liquid water at 1 atm and 273 K are 0.917 g/ cm3 and 0.9998
    g/cm3 respectively. The heat of fusion of water is 334.72 kJ/kg. Calculate the melting point of ice
    at 0.5 atm and 107 atm pressures.

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