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STOICHIOMETRY - II Page # 26

ANSWER-KEY

Exercise-I

1. B 2. C 3. D 4. B 5. B 6. B 7. D 8. A

9. C 10. C 11. A 12. B 13. C 14. A 15. B 16. D

17. B 18. C 19. B 20. B 21. A 22. C 23. C 24. D

25. A 26. A 27. A 28. B 29. A 30. B 31. C 32. D

33. B 34. A 35. C 36. D 37. A 38. D 39. C 40. A

41. B 0

Exercise-II

1. A,C 2. A,C 3. A,B,C 4. C 5. A,B,C 6. A 7. A,B 8. A,B,C

9. A,B 10. A,C,D 11. A,C,D 12. B 13. A,C 14. B,C,D 15. A,B,C

Exercise-III

1. (a) 2KMnO4 + 3H2SO4 + 5 H2O2 


K2SO4 + 2MnSO4 + 8 H2O + 5O2
2+
(b) 2Cu + 2I  2Cu+ + I2

2. (i) 2CrI3 + 27H2O2 + 10 OH–  2CrO42– + 6IO4– + 32H2O


(ii) 258KOH + K4Fe(CN)6 + 61Ce(NO3)4  61Ce(OH)3 + Fe(OH)3 + 36H2O + 6K2CO3 + 250KNO3

3. (a) 3SbCl3 + KIO3 + 6HCl  2SbCl5 + ICl + 3H2O + KCl


(b) 10FeC2O4 + 6KMnO4 + 24H2SO4  5Fe2(SO4)3 + 20CO2 + 6MnSO4 + 3K2SO4 + 24H2O
(c) 6FeCr2O4 + 12K2CO3 + 7KClO3  3Fe2O3 + 12K2CrO4 + 7KCl + 12CO2
(d) 30Pb(N3)2 + 44Co(MnO4)3 132MnO2 + 44CoO + 180NO + 10Pb3O4

4. (a) 3KClO3 + 3H2SO4  3KHSO4 + HClO4 + 2ClO2 + H2O


(b) 5Br– + BrO3– + 6H+  3Br2 + 3H2O

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page # 27 STOICHIOMETRY - II

(c) 24H2S + 8Cr2O72– + 16H+  8Cr2O3 + 3S8 + 32H2O


(d) 2MnO4– + 5C2O42– + 16H+  2Mn2+ + 10CO2 + 8H2O
(e) 3Cu2O + 14H+ + 2NO3–  6Cu2+ + 2NO + 7H2O
(f) 5[Fe(CN)6]4– + 188H+ + 61MnO4–  5Fe3+ + 30CO2 + 30NO3– + 61Mn2++ 94H2O

5. (a) 3C2H5OH + 2MnO4– + OH–  3C2H3O– + 2MnO2(s) + 5H2O


(b) Cr2O72– + 3C2H4O + 8H+  3C2H4O2 + 2Cr3++ 4H2O
(c) 4P + 3OH– + 3H2O  3H2PO4– + PH3
(d) 4S + 6OH–  2S2– + S2O32–
(e) 6Na2S2O3 + 2KMnO4 + 4H2O  3Na2S4O6 + 2MnO2 + 2KOH + 6NaOH
(f) 10FeC2O4 + 6KMnO4 + 24H2SO4  5Fe2(SO4)3 + 20CO2 + 6MnSO4 + 3K2SO4 + 24H2O
(g) C2H5OH + 4I2+ 6OH–  CHI3 + HCOO– + 5H2O + 5I–

6. KOH = 35%, Ca(OH)2 = 65% 7. V = 157.8 ml 8. 20.72 % 9. 200 mL 10. 0.424 gm; 0.21 gm

11. 23.32 gm, 22.4 gm 12. 0.06 gm; 0.0265 gm 13. +3 14. zero 15. V = 31.68 ml

16. 0.588 N 17. 337 mL 18. 41.53% 19. 6.07  6 20. 0.15 N 21. 0.174g ; 3.48 %

22. 1.406% 23. 90.1 % 24. 0.1281 g 25. V = 25 mL

Exercise-IV

1. FeO = 13.34%; Fe2O3 = 86.66% 2. 20 ml ; 40 ml; 20 ml

3. SCN– + 3I2 + 4H2O SO42– + HCN + 7H+ +6I–, 15.68 % 4. 5g 5. 15.68 % Chromite

6. VKIO 3  0.42 mL , [HCl] = 0.0168 N 7. 57.4 % CuS, 42.6% Cu2S 8. 4.67 L 9. 1.76 %

10. 95.8 % 11. pyrite : 0.06 %; S = 0.032 % 12. 40.77% 13. 59.16%

14. H2C2O4.2H2O = 14.36%, KHC2O4 . H2O = 81.71 % 15. 30.55 kg, 6 eleCtrons

Exercise-V

1. 4.48 % 2. Fe2O3 = 49.33 %, Fe3O4 = 34.8% 3. A 4. A

5. 6.57 % O3 (By weight), 1.2 × 1021 photons 6. 0.0623 M 7. 8.097 ml 8. D 9. C 10. A

11. B 12. 0.1M 13. D 14. (A) P, S ; (B) R ; (C) P, Q ; (D) P 15. B

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
www. motioniitjee.com , email-hr.motioniitjee@gmail.com

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