Time: 65 min. No.

of Questions: 45
Only Periodic Table is allowed.

Question 1: Which of these below statements is correct:

a. Silver isn’t conducted in solid crystal state.
b. Silver has higher density in solid state than in liquid state.
c. Materials which have solid state cannot be conducted.
d. Pure water is strong conductive substance.
Question 2: Choose the wrong statement. Cl – O bonding in ClO -, ClO2-, ClO3-, ClO4- are 1.7,
1.64, 1.57 and 1.42 A0 respectively. The ions series is:
a) Increasing of stability.
b) Increasing of bonding energy.
c) Increasing of oxidation property in acidic solution.
d) Increased of bond order.
Question 3: Arrange following compounds VCl2, VCl3, VCl4 and VCl5 (V: Vanadium) in the
decreasing order of covalent bonding:
a) VCl3 < VCl4 < VCl2 < VCl5 b) VCl5 < VCl4 < VCl3 < VCl2
c) VCl2 < VCl3 < VCl4 < VCl5 d) VCl4 < VCl2 < VCl3 < VCl5
Question 4: Choose the wrong answer:
a) Solid I2 is easy to dissolve into water because it has high polarity.
b) BaCl2 has high melting point because it is ionic compound.
c) Diamond is hard to melt because of its covalent crystal.
d) Copper (Cu) has good conductivity because of it is metal.
Question 5: Among below gases, the easiest to be liquid at the same conditions is
a) H2O b) CO2 c) H2Se d) SO2
Question 6: Choose the correct answer:
Consider compounds HnX of elements in period 2, with X are: N, O, F, respectively.
a) They have decreasing of melting temperature because of decreasing of molecular weight.
b) They have increasing of melting temperature because of decreasing of molecular weight.
c) They have the same melting point because they have hydrogen bonding.
d) All are wrong.
Question 7: Please calculate the equilibrium constant of below reaction:
NH4Cl(aq) + Na2S(aq) + H2O NH4OH(aq) + NaHS(aq) + NaCl(aq)

a) 1.10-4,76 b) 1.10-11,98 c) 1.1011,98 d) 1.104,76

Knew that Ka1, Ka2 of H2S are 1.10-7,2 and 1.10-14, Kb of NH4OH is 1.10-4,76 , and Kw of water
is 10-14.
Question 8: Which oxide of Manganese can be reacted easier to hydrocloric acid as acid-
base reaction?
a) MnO b) Mn2O3 c) MnO2 d) Mn2O7
Question 9: Choose the correct answers (with solvent is water)
1. CH3NH2, CO32-, CH3COO-, Cl- are bases according to Bronsted-Lawry’s theory.
2. The strength of acids BF3, BCl3, BBr3 will be decreased.
3. HCN, H3O+, Na+, C6H5OH, N2H5+ are acid according to Bronsted-Lawry’s theory.
4. The base strength is increased in series: anilin<3,5 dinitroanilin<2,6 dinitroanilin
5. Higher value pKa of an acid leads to weaker of its conjugated base.
a) 1,2,3,5 b) 1,5 c) 2,3,4 d) 3,5
Question 10: There are cations: (1) NH4 , (2) CH3NH3 , (3) (CH3)2NH2 , (4) CH3COOH2+.
+ + +

Please arrange in series of increasing the strength of acid:

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 a) (4) < (3) < (1) < (2) b) (3) < (4) < (1) < (2)
c) (4) < (3) < (2) < (1) d) No result above is correct
Question 11: There is the reaction: NH2-(k) + HBr(k) = NH3(k) + Br-(k)
Q ( KJ/ mol) 1689 1354
Choose the wrong statements:
1. Br- has stronger basic than that of NH2- because of lower of Q value.
2. NH2- has stronger basic than that of Br- because of higher of Q value
3. When NH2- react with H+ will has ∆H higher than that of Br-
4. Conjugated acid of NH2- has weaker acidic than that of Br-
a) 1,3 b) 2,3 c) 2,3,4 d) 2,4
Question 12: Choose the right statement:
1. Bronsted - Lawry’s theory can be used in gas as well liquid phases.
2. In Usanovic’s theory, every reactions can be considered as acid-base reaction,
including redox reactions.
3. Strength of acid- base according to Lewis’s theory just can be compared by using the
general standard the same to Bronsted-Lawry’s theory.
a) 1, 2 b) 2, 3 c) 1, 3 d) 1, 2, 3
Question 13: Choose the right statement: What substances impulse the hydrolysis reaction of
NaCN in water?
a. NaOH, Ba(OH)2 b. HCl, H2SO4
c. NH4NO3, CH3COONa c. There is no.
Question 14: What are amphoteric substances base on Bronsted-Lawry’s theory:
a. HS- ,Ag+aq ,Fe2+aq , H2O, HCl, NH3
b. HS-, H2O, HCl, SO42-
c. F- , S2-, HS-, H2O, HCl, NH3
d. HS-, H2O, HCl, HCO3-
Question 15: There is difference from crystal and amorphous state in term of:
a) Structure b) Shape c) Isotropic d) a and c
Question 16: What are molecule lattice structures among below substances (in solid state):
COCl2, NO, Al2S3, BaO, SO2
a) COCl2, NO, SO2 b) COCl2, NO, Al2S3
c) COCl2 , BaO, SO2 d) NO, As2S3
Question 17: What are ion lattice structures among below substances (in solid state):
K3[Fe(CN)6], Fe(CO)5 , As2O3, BaO, Na2S
a) K3[Fe(CN)6], Fe(CO)5 b) As2O3, BaO
c) As2O3, BaO, K3[Fe(CN)6] d) BaO, K3[Fe(CN)6], Na2S.
Question 18: Which is strongest acid among these acids below?
a) HClO b) HBrO c) HMnO4 d) HClO4
Question 19: Which is strongest base among below substances?
a) Ba(OH)2 b) Al(OH)3 c) Mg(OH)2 d) Fe(OH)3
Question 20: Which substance has highest valence bonding among below substances?
a) Co(OH)3 b) FeCl3 c) C10H22 d) NiSO4
Question 21: Choose the right statement:
a.In Pauling’s rule for acids HaXOn(OH)m , value of n decides strenght of acid.
b. Base on Kartletch’s rule, the rate of q/r of center ion higher leads to stronger acidic
of a substance.
c. Cations that have pKtp lower then their acidic also stronger.
d. Alls are correct.
Question 22: Choose the incorrect statement.
1) The conjugate base of a strong acid is weak base.

2
 2) In conjugated acid-base pair NH4+ / NH3 (with water is solvent) we have:
KNH4+ xKNH3 =10-14 , exactly at all temperature.
3) HCl is strong acid.
a) 1 b) 2,3 c) 3 d) Alls are correct.
Question 23: Plase calculate the pH value of solution on H2SO4 10-9 M:
a) 5 b) 9 c) 7 d) 14
Question 24: In octahedral complex compounds, if numbers of electrons are lower than 3 or
higher than 8, then:
a) If ∆ > P is low spin complex. b) If ∆ > P is high spin complex.
c) If ∆ < P is high spin complex. d) All are wrong
Question 25: Base on Latimer series of Chlorine in acid solution below:
1,201 1,181 1,701 1,630
ClO4- ClO3- HClO2 HClO Cl2 1,358 Cl-
Standard Redox Potential of ClO / Cl2 is:
3-

a) 1,83475 b) 1,4678 c) 1,5395 d) None of them

Question 26: What electron configurations below can have both low and high spin structures:
1) d5 2) d7 3) d2 4) d8 5) d6
a) 1, 2, 5 b) 2, 3 c) 1, 2, 3 d) 1, 2, 3, 4
Question 27: In below reactions:
TiO2+ + 2H+ + e =Ti + H2O, 0 = 0.1V; ZrO2+ + 2H+ + 4e = Zr +H2O, 0 = -1.5V
HfO2+ + 2H+ + 4e = Hf + H2O, 0 = -1.7V
Plsease choose correct answer for unstable series of Ti(+4);Zr(+4); Hf(+4):
a) Ti <Hf < Zr b) Ti < Zr < Hf c) Zr < Ti < Hf d) Hf < Zr < Ti

Use below Latimer’s diagrams of S for questions from 28 to 32:

(3)

(1) 0.500

(4)
Question 28: Please calculate the values of Redox Potentials at positions (1), (2), (3), (4) in
these Latimer’s diagram.
a. (1): 0.158 V, (2): 0.400 V, (3)0.386 V, (4) -0.2806 V
b. (1): 0.411 V, (2): -0.400 V, (3)0.006 V, (4)0.2806 V
c. (1): 0.158 V, (2):-0.218 V, (3) 0.176 V, (4)-0.2608 V
d. There is no correct answer.
Question 29: Base on Latimer’s diagram of S, please determine what are compound of S that
can be disproportionated in corresponding solution:
a. Acid: , Base:
b. Acid: , Base:
SO 2− , S
c. Acid: , Base: 3

d. Acid: , Base: there is no compound can be disproportionated.

Question 30: From Latimer’s diagram, through Frost’s diagram please determine the
compounds that can be comproportionated:

3
 a. Acid: , Base:
b. Acid: , Base:
c. Acid: , Base:
d. There is no compound can be comproportionated.
Question 31: Base on Latimer’s diagram of S, please determine the values of redox potential
at 1,2,3,4 positions below in solution with pH = 6:

a. (1): -0.467 V, (2): -0.157 V, (3) -0.166 V, (4) 0.333 V

b. (1): -0.389 V, (2): -0.088V, (3) -0.0171V, (4) 0.31V
c. (1): 0.467 V, (2): 0.157 V, (3) 0.0171 V, (4) -0.31V
d. No correct answer.
Question 32: From Latimer’s diagram of S, please determine the compounds that can be
disproportionate and comproportionated at pOH=6:
a. Disproportionated: ; comproportionated:
b. Disproportionated: ; comproportionated:
c. Disproportionated: ; comproportionated:
d. There are no disproportionated and comproportionated compounds.
Question 33: Please determine magnetic property and lattice stable energy of complex ions
(1) hexachloromaganate (II) and (2) tetrachloromaganate (II).
a) (1) Diamagnetic, 304,2 kJ/mol. b) (1) Paramagnetic, 0 kJ/mol.
(2) Diamagnetic, 101 kJ/mol (2) Paramagnetic, 0 kJ/mol.
c) (1) Paramagnetic, 304,2 kJ/mol. c) (1) Diamagnetic, 0 kJ/mol.
(2) Paramagnetic, 101 kJ/mol (2) Diamagnetic, 0 kJ/mol.
Question 34: Please compare lattice stable energy of 2 complex ion: [MnCl6]2+ (E1) and
[FeCl6]2+ (E2)
a. Can not compare because we don’t know ∆, P b. E1=E2
c. E1>E2 d. E2>E1
Question 35: Calculate lattice stable energy of complex ion [HgI 4]2- (Hg has Z=80) and what
is its color:
a) E = 0, diamagnetic b) E = -2∆T, diamagnetic
c) E = 0, paramagnetic d) E = -2∆T, paramagnetic.
Question 36: Please calculate the lattice stable energy of [Ni(SCN)6]4-
a. E=6 × ( ) (
−2
∆ +2 × ∆ o
5 o
3
5 )
( ) (
2
5
3
b. E=6 × ∆ o +2 × ∆ o +3 E P
5 )
c. E=4 × ( ) (
−3
5
∆o +4 × ∆o
2
5 )
d. E=6 × ( ) (
−2
5
3
)
∆ o +2 × ∆ o +3 E P
5
Question 37: In acid environment, please arrange in series of stability of these compounds:
HClO4, HBrO4, HIO4, HAtO4
a) HClO4 > HBrO4 > HAtO4 b) HIO4 > HAtO4 > HClO4
c) HAtO4 < HBrO4 < HClO4 d) HClO4 > HAtO4 > HBrO4
Question 38: The Latimer’s diagram of Cl at pH=1

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What compound(s) of Cl can not be stable in solution at pH = 1?
a)HClO b) ClO2- c) Cl- d) ClO4- & Cl2.
Question 39: Choose the wrong statement:
a) In tetrahedral complex compounds orbital dxy, dyz, dxz have higher energy than that
of dx2-y2 and dz2.
b) Complex compounds that have no π bonding if they have higher Δ lead to high
spin complex compound and more stable.
c) In octahedral complex compounds orbital dx2-y2 & dz2 have higher energy than that
of dxy, dyz, dxz..
d) Crystal Field Theory can explain why complex compounds of d and f elements
have many case of color.
Question 40: Knew standard reduction potential of the semi-reaction Fe3+(aq) + e− → Fe2+
(aq) is +0,77V. Please determine changing of its potential when CN- is added into solution,
where stable constant of Fe(CN)63- is 1031 and Fe(CN)64- is 1024.
a. Increase b. No change c. Decrease d. Can’t determine.
Question 41: The complex ion hexacyanoferate(III) (Fe: 3d 4s , and CN- is strong field
6 2

ligand) has:
a) Octahedral structure, paramagnetic, low spin
b) Formula is [Fe(CN)6]3-
c) Lattice stable energy is E= -2+2P
d) Alls are correct.
Question 42: Knew:
Au3+ + 3e  Au φ = 1,50 V
Where overall unstable constant of [AuCl4 ] is Kus = 2.10-21,3
-

Please calculate the standard reduction potential at 250C of below semi-reaction :

AuCl4- + 3e  Au + 4Cl-
a) 0.98 V b) 1.08 V c) 1.2 V d) 1.15 V
Question 43: What are stable oxidation numbers of Cl among below values:
1) -1 2) +2 3) +5 4) +7
a) 3 b) 3 & 4 c) 1 , 3 d) 2 & 3
Question 44: Sulfurous gas will has reduction property in what below reaction(s)?
1) SO2 + H2O  2) SO2 + H2S + H2O 
3) SO2 + H2O2 + H2O  4) SO2 + Cl2 + H2O 
a) 3 & 4 b) 2 , 3 & 4 c) 1 & 3 d) 2 & 4
Question 45: Choose the correct answers:
1) Specific property of acid sulfurous is oxidation.
2) Hydro sulfide gas is stable in atmospheric.
3) Acid sulfuric 2M solution is strong oxidizer.
4) Dioxide Sulfur gas (Sulfur (IV) oxide) can be dissolved strong into water.
a) 4 b) 2 c) 3 d) Alls are wrong.