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JEE Mains 2023 Part Test # 1

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JEE Mains 2023 Part Test # 1

Duration : 3 Hours Total Marks : 300

Please read the instructions carefully.

This booklet is your question paper. Attempt all the questions.


Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers and electronic gadgets are not allowed.

Question Paper Format

The question paper consists of 3 part(s):


Physics , Chemistry , Mathematics .

Physics

No. of question: 25
Total Marks: 100
Questions 1 to 20 are of type Single Correct MCQ. Each question has multiple choices out of which only one is correct.
For each question from 1 to 20, you will be awarded 4.00 mark(s) for correct answer and zero mark for unattempted questions. In all other
cases, (–1.00) mark will be awarded.
Questions 21 to 25 are of type Numerical Answer. The answer to each question is numeric.
For each question from 21 to 25, you will be awarded 4.00 mark(s) for correct answer and zero mark for unattempted questions. No negative
marks will be awarded for incorrect answers in this section.

Chemistry

No. of question: 25
Total Marks: 100
Questions 26 to 45 are of type Single Correct MCQ. Each question has multiple choices out of which only one is correct.
For each question from 26 to 45, you will be awarded 4.00 mark(s) for correct answer and zero mark for unattempted questions. In all other
cases, (–1.00) mark will be awarded.
Questions 46 to 50 are of type Numerical Answer. The answer to each question is numeric.
For each question from 46 to 50, you will be awarded 4.00 mark(s) for correct answer and zero mark for unattempted questions. No negative
marks will be awarded for incorrect answers in this section.

Mathematics

No. of question: 25
Total Marks: 100
Questions 51 to 70 are of type Single Correct MCQ. Each question has multiple choices out of which only one is correct.
For each question from 51 to 70, you will be awarded 4.00 mark(s) for correct answer and zero mark for unattempted questions. In all other
cases, (–1.00) mark will be awarded.
Questions 71 to 75 are of type Single Correct MCQ. Each question has multiple choices out of which only one is correct.
For each question from 71 to 75, you will be awarded 4.00 mark(s) for correct answer and zero mark for unattempted questions. No negative
marks will be awarded for incorrect answers in this section.

1/10
Physics cubes placed with one edge along positive x-axis.

Questions 1 to 20 are of type Single Correct MCQ. Each


question has multiple choices out of which only one is
correct.
For each question from 1 to 20, you will be awarded 4.00
mark(s) for correct answer and zero mark for unattempted
questions. In all other cases, (–1.00) mark will be awarded.

1 Two identical charged spheres are suspended by strings of equal


length. The strings make an angle of 30 with each other. When

List-I List-II
suspended in a liquid of density 0.8g/cc, the angle remains the same.
The dielectric constant of the liquid is : A. Cube of 1m edge with one corner at
P. Positive
[density of the material of sphere is 1.6g/cc] origin

A. 2 B. Cube of 1m edge which lies between x


Q. Negative
=3 to x = 4
B. 4 C. Cube of 2m edge placed between the
R. Zero
coordinate x = 4 to x = 6
C. 2.5
D. Cube of 6m edge placed between the S. Magnitude of charge
D. 3.5 coordinate x = 0 to x = 6 is 2ε units
0

2 Assertion A. A→PQ; B→PS; C→QS; D→PR


A capacitor can be given only a limited quantity of charge
B. A→RS; B→PQ; C→QR; D→QS
Reason
A capacitor is an arrangement which can store sufficient quantity of C. A→QS; B→PQ; C→PS; D→PS
charge
A. Both Assertion and Reason are correct and Reason is the D. A→QS; B→R; C→R; D→P

correct explanation for Assertion 6 Electric field outside a long wire carrying charge q is proportional to :
1
A.
B. Both Assertion and Reason are correct but Reason is not the r
1
B.
correct explanation for Assertion r
2

1
C. Assertion is correct but Reason is incorrect C. 1

3/5
r
D. Assertion is incorrect but Reason is correct 1
D. 1

3 Two charges of equal magnitude ' q' are placed in air at a distance ′
2a

r
3/2

apart and third charge −2q is placed at midpoint. The potential


7
energy of the system is (ϵ = permittivity of free space) :
0
Charge Q taken from the battery of 12V in the circuit is :
2
q
A. −
8πϵ0 a
2
3q
B. −
8πϵ0 a
2
5q
C. −
8πϵ0 a
2
7q
D. −
8πϵ0 a

4 The electric potential V at any point (x, y, z), all in meters in space is
given by V = 4x volt. The electric field at the point (1, 0, 2) in
2

volt/meter is :
A. 8 along positive X-axis
A. 72μC
B. 16 along negative X-axis
B. 36μC
C. 16 along positive X-axis
C. 156μC
D. 8 along negative X-axis
D. 20μC
5 Graph between electric potential and the x-coordinate is given and the
electric field is along the x-axis.Then find total charge in various 8 Two small spheres each of radius 1 mm are kept 10 cm apart.
Assuming each proton has a charge +e and each electron has a charge
0.1% less than +e then find the force between the two spheres.
Density of copper is 8.9 gcm and atomic mass number is 63.5.
−3

A. 1.17 × 10 1
2N

2/10
B. 2.34 × 10 −12
N A. 8q 1

C. 1.17 × 10 −12
N B. 6q 1

D. 2.34 × 10 12
N C. 8q 2

9 Identical charges -q each are placed at 8 corners of a cube of each D. 6q 2

side b. Electrostatic potential energy of a charge +q which is placed at


the centre of cube will be : 14 Three electric charges +q each are placed at the three corners of a
2
−4√2q
A. square of side d. The intensity of electric field at the fourth corner is :
πϵ0 b
2
−8√3q 1 q 1
B. A. (2 + )
πϵ0 b 4πϵ0 d2 √2
2
−4q 1 q 1
C. B. (√2 + )
√3πϵ0 b 4πϵ0 d2 2

2 1 2Q
−8√2q
D. C.
2
4πϵ0 d
πϵ0 b
1 √2q
10 An electron and a proton are sent into an electric field. The ratio of D. 2
magnitudes of force experienced by them is : 4πϵ0 d

A. 1 : 1 15 A number of capacitors, each of equal capacitance C, are arranged as


shown in the figure. The equivalent capacitance between A and B is :
B. 1 : 1840

C. 1840 : 1

D. 1 : 9.11

11 Two condensers C and C in a circuit are joined as shown in figure.


1 2

The potential of point A is V and that of B is V . The potential of


1 2

point D will be-

1
A. (V1 + V2 )
2
C2 V1 + C1 V2
B.
C1 + C2

C1 V1 + C2 V2
C.
C1 + C2

C2 V1 − C1 V2
D.
C1 + C2
A. n 2
C
12 Two condensers each of capacitance 2μF are connected in parallel
and this combination is connected in series with a 12μF capacitor. B. (2n + 1)C
The resultant capacity of the system will be: (n − 1)n
C. C
A. 16μf 2

(n + 1)n
B. 13μf D. C
2

C. 6μf 16 The equivalent capacitance between A and B in the circuit given


below is:
D. 3μf

13 Two charges q and q are placed 30 cm apart, as shown in the


1 2

figure. A third charge q is moved along the arc of a circle of radius


3

40 cm from C to D. The change in the potential energy of the system


q3
is 4πϵ 0
k , where k is

A. 4.9μF

B. 3.6μF

C. 5.4μF

D. 2.4μF

17 The equivalent capacitance C AB of the circuit shown in the figure is :

3/10
dielectric constant K is given by :

5
A. C
4
4 1 1 1 1
B. C A. = + +
5 K K1 K2 2K 3
3
C. C
B.
1
=
1
+
1

5
K K1 + K2 2K 3
5
D. C 1 K 1K 2
3 C. = + 2K 3
K K1 + K2
18 What is the equivalent capacitance of the system of capacitors
between A & B? D. K = K 1 + K 2 + 2K 3

Questions 21 to 25 are of type Numerical Answer. The


answer to each question is numeric.
For each question from 21 to 25, you will be awarded 4.00
mark(s) for correct answer and zero mark for unattempted
questions. No negative marks will be awarded for incorrect
answers in this section.

21 There are 27 drops of a conducting fluid. Each drop has radius r, and
each of them is charged to the same potential V .They are then
1

combined to form a bigger drop.The potential of the bigger drop is V 2

.Find the ratio V /V . Ignore the change in density of the fluid on


2 1

combining the drops.

7
A. C
6

B. 1.6C 22 Two identical small equally charged conducting balls are suspended
from long threads secured at one point. The charges and masses of
C. C the balls are such that they are in equilibrium when the distance
between them is a (the length of the thread L >> a). One of the balls
D. None
is then discharged. Again for the certain value of distance b (b << l)
19 Two parallel plate capacitors of capacitances C and 2C are connected between the balls, the equilibrium is restored, the value of
in parallel and charged to a potential difference V. The battery is then
3 3
(a /b ) =?

disconnected, and the region between the plates of C is filled


completely with a material of dielectric constant K. The common
potential difference across the combination becomes :
2V 23 A thin nonconducting ring of radius R has linear charge density
A.
K + 2 λ = λ cosθ , where λ is a constant, θ is azimuthal angle. The
0 0

V λ0
B. electric field at the centre of the ring is . Find x :
K + 2 xε 0 R
3V
C.
K + 3

3V
D.
K + 2 24 A solid sphere of radius R has a charge Q distributed in its volume
20 A parallel plate capacitor of plate area A, plate separation d and with a charge density rho = kr\^a , where k and a are constants and
capacitance C is filled with three different dielectric materials having r is the distance from its centre. If the electric field at r = R/2 is 1/8
dielectric constants K , K and K . If a single dielectric material is to
1 2 3
times that at r = R, find the value of a.
be used to having the same capacitance C in this capacitor then its

25 Three point charges q, 2q and 8q are to be placed on a 9 cm long


straight line. If potential energy of system is minimum possible, then
find the distance between 2q and q.

4/10
Chemistry C. tertiary alkyl halide

D. none of these
Questions 26 to 45 are of type Single Correct MCQ. Each 30 The product formed in the following reaction is:
question has multiple choices out of which only one is C H3 C H C H3 C H = C H2 + H Br → product
correct.
For each question from 26 to 45, you will be awarded 4.00 A. (C H 3 ) 2 C H C H BrC H3

mark(s) for correct answer and zero mark for unattempted B. (C H 3 ) 2 C H C H2 C H2 Br


questions. In all other cases, (–1.00) mark will be awarded.
C. (C H 3 ) 2 C BrC H2 C H3

26 Match the column (I) and (II). D. C H 3 C H C H3 C H BrC H2 C H2

Column (I) Column (Il) 31 The largest value of Henry's law constant for the liquid solvent H O 2

Reaction Type of Reaction will be obtained with ............. gas as the solute and a temperature of
.............. C.
o

A. C 2 H4 , 45
(a) (p) SN1
B. Ar, 11

C. HC l, 49

D. C O 2, 32
(b) (q) SN2
32 The concentration of CO in a soft drink bottled with a partial
2

pressure of CO of 4.0 atm over the liquid at 25 C is 1.2 × 10 M.


2
o −1

The Henry's law constant for C O at this temperature is .................. .


2

A. 3.0 × 10 −2
mol/L − atm
(c) (r) E1
B. 4.5 × 10 −3
mol/L − atm

C. 5.6 × 10 −3
mol/L − atm

D. 2.3 × 10 −2
mol/L − atm
(d) (s) E2
E. More information is needed to solve the problem.

33 hv

A. (a - q), (b - s), (c - p), (d - r) C H3 − C H − C H3 + C l 2 −


→P (Major product)
| (on monochlorination)
B. (a - p), (b -q), (c - r), (d -s) C H3

C. (a - s), (b - p), (c - p), (d - r) The product P is:


Cl

|
D. (a -r), (b - s), (c - q), (d - r) A. C H 3 − C − C H3
|

27 Acetyl bromide reacts with excessof C H M gI followed by


3
CH
3

treatment with a saturated solutionof N H C I gives:


4
Cl

A. Acetone B. C H 3 − C − C H2 − C H3
|

B. Acetamide H

C. H 3C − C H − C H2 − C l
C. 2-Methyl- 2-propanone
|
D. Acetyl iodide
C H3
28 Which one of the following statements is wrong?
D. Cl
A. All carbonyl compounds of the general structure C H 3 C OR

|
give a positive iodoform test
C H2 − C H − C H2
B. All secondary alcohols give iodoform reaction
| |
C. Alcohols of the structure C H 3 C H(OH)R give iodoform
Cl Cl
reaction
34 Assertion
D. The only aldehyde giving iodoform reaction is acetaldehyde
S 1 reaction is carried out in the presence of a polar protic solvent.
N

29 An alkyl halide in which halogen atom is attached to that C atom Reason


which is attached to only one C in molecule is called as: A polar protic solvent increases the stability of carbocation due to
solvation.
A. primary alkyl halide

B. secondary alkyl halide

5/10
A. Both Assertion and Reason are correct and Reason is the C. ii, i, iv

correct explanation for Assertion D. all are correct

B. Both Assertion and Reason are correct but Reason is not the 40 50g of saturated aqueous solution of potassium chloride at 30 C is
o

evaporated to dryness. When 13.2g of dry KC l was obtained. The


correct explanation for Assertion solubility of KC l in water at 30 C is: o

C. Assertion is correct but Reason is incorrect A. 35.87 g

D. Assertion is incorrect but Reason are correct B. 25.62 g

35 The cryoscopic constant for acetic acid is 3.6 K kg/mol. A solution C. 28.97 g
of 1 g of a hydrocarbon in 100 g of acetic acid freezes at 16.14 C

instead of the usual 16.60 C . The hydrocarbon contains 92.3%


∘ D. 27.81 g
carbon. If the molecular formula is CxHy . Find the value of x and 41 The order of reactivity of following alcohols with halogen acids is:
y (A) C H C H − C H − OH
3 2 2

(B) C H − C H − C H − OH
3 2
A. x = 2, y = 4 |

CH3

B. x = 3, y = 5 CH3

C. x = 4, y = 4
(C) C H3 − C H2 − C − OH
|

CH
3

D. x = 6, y = 6
A. (A) > (B) > (C )

36
B. (C ) > (B) > (A)

C. (B) > (A) > (C )

D. (A) > (C ) > (B)

42 acetone

R − C l + N aI −−−−→ R − I + N aC l

This given reaction is:


A. Wurtz reaction

B. Fittig reaction
A. a -→q ; b→p ; c→r ; d→q
C. Finkelstein reaction
B. a→q,r : b→p,s ; c→r ; d→q
D. Frankland reaction
C. a→q ; b→p ; c→p ; d→r
43 Alkyl halides are very reactive organic compounds in which alkyl
D. a →p ; b→q ; c→r ; d→q fluorides are generally not used in chemical reactions because of its:
37 Electrophile that participates in nitration of benzene is: A. Nucleophillic character.
A. N O +

B. High reactivity.
B. N O +

2 C. Less reactivity.
C. N O D. None of these
D. N O −

3 44 In the below reaction, Z is :


38 Which will react faster with NBS?
A. C 6 H6

B. C H 4

C. Toluene
A. toulene
D. Cyclopropane
B. biphenyl
39 The reactions that occur during the preparation of C HC l from
3

C H OH and bleaching powder is:


2 5 C. 4-chlorotoulene
i) oxidation
ii) disproportionation D. ethyl benzene
iii) hydrolysis
iv) chlorination 45 Heating chloroethane with _________ yields a product containing
isocyanide group.

A. i, iii, iv A. AgCN

B. iii, iv only B. KCN

6/10
C. HCN Mathematics
D. HN O 3

Questions 51 to 70 are of type Single Correct MCQ. Each


question has multiple choices out of which only one is
Questions 46 to 50 are of type Numerical Answer. The correct.
answer to each question is numeric. For each question from 51 to 70, you will be awarded 4.00
For each question from 46 to 50, you will be awarded 4.00 mark(s) for correct answer and zero mark for unattempted
mark(s) for correct answer and zero mark for unattempted questions. In all other cases, (–1.00) mark will be awarded.
questions. No negative marks will be awarded for incorrect
answers in this section.
51 1 1 1
⎡ ⎤
Find A , if A =
−1
⎢1 ω ω
2
, where ω is the cube root of unity

46 32 g of hydratedmagnesium sulphateMgSO 4.x H 2O , when ⎣ 2 ⎦
1 ω ω
dissolved in 84 g of water, the solution freezes at 1 1 1

4.836 ºC . If K f = 1.86 K kg mol -1 and MgSO 4 is a strong 1 ⎡ ⎤


A. ⎢1 ω
2
ω ⎥
electrolyte, what is the value of x ? 3 ⎣
2 ⎦
1 ω ω
2
1 ω ω
1 ⎡ ⎤
B. ⎢1 1 1 ⎥
3 ⎣ ⎦
2
1 ω ω
47 10 g of N H C l (mol. weight = 53.5) when dissolved in 100 g of
4 2
1 ω ω
water lowered the freezing point by 0.637 C .

1 ⎡ ⎤
C. ⎢1 ω
2
ω ⎥
If the degree of hydrolysis of the salt is 109 × 10 , then what is the
−x
3 ⎣ ⎦
value of x? 1 1 1

(Degree of dissociation = 0.75, t he molal depression constant of D. none of these


water is 1.86 kg mol K )
−1

52 If x, y are rational numbers such that


(x + 2y) + (x − 3y) √6 = (x − y − 2) √5 + (2x + y − 2) , then
A. x + y = 6
48 A decimolar solution of potassium ferrocyanide is 50% dissociated at
300 K. Calculate the osmotic pressure of the solution. B. x + y = 5

C. x + y = 4

D. x + y = 3
49 M X_2 dissociates in M 2+) and X ions in an aqueous solution
( −

,with a degree of dissociation (alpha) of 0.5.The ratio of the 53 Which of the following graph represents the function
observed depression of freezing point of the aqueous solution to the f (x) = tan
−1
(x + 1)

value of the depression of freezing point in the absence of ionic


dissociation is

50 Calculate the relative lowering in vapour pressure if 100 g of a


nonvolatile solute (mol.wt.100) is dissolved in 432 g water.(If your A.
answer is x, then write x × 100).

B.

7/10
B. λ 3

C. λ 3
+ 1

D. λ 3
− 1

C. 59 ⎧ 1 4 −1 ⎫
⎪ ⎪

The rank of the matrix A = ⎨2 3 0 ⎬ is



⎪ ⎭

0 1 2

A. 3

B. 2
D. None of these
C. 1
54 0 1
If A = [ ] and (aI 2 + bA)
2
= A , then D. 0
−1 0

60 Unary operation is one in which yields another number when


A. a = b = √2
performed on
B. a = b = 1/√2 A. two numbers
C. a = b = √3 B. a single number
D. a = b = 1/√3 C. three numbers
55 Statement I : The equation (sin −1
x)
3
+ (cos
−1
x)
3
− aπ
3
= 0 D. four numbers
has a solution for all a ⩾ . 1

32
61 If the system of equations
Statement II : For any xϵR, sin −1
x + cos
−1
x =
π
and
2 x + αy + αz = 0
2

0 ≤ (sin
−1
x −
π
)
2
≤ . bx + y + bz = 0
4 16

cx + cy + z = 0
A. Both statements I and II are true.
where α, b, c are non-zero non-unity,has a non-trivial solution,then
B. Both statements I and II are true but I is not an explanation α b c
the value of + + is
1 − α 1 − b 1 − c
of II
A. 0
C. Statement I is true and statement II is false
B. 1
D. Statement I is false and statement II is true.
C. -1
56 ⎛
1 2 2
⎞ αbc
D.
If A = ⎜ 2 1 2⎟
α2 + b2 + c2
⎝ ⎠
2 2 1
62 Which of the following is the new row that results when you add
rows 1 and 3?
If A − 4A = pI where I and O are the unit matrix and the null
2

3 4 2 11
matrix of order 3 respectively. Find the value of p ⎡ ⎤
9 1 0 0
⎢ ⎥
A. p = 2

⎢0 1 0

2 ⎥
⎣ ⎦
0 0 6 1
B. p = 3

A. 6, 8, 4, 22
C. p = 4

B. 3, 5, 2, 13
D. p = 5

C. 3, 4, 2, 11
57 Which of the following is the solution set of equation
sin
−1
x = cos x + sin
−1
(3x − 1) ?
−1
D. 3, 4, 8, 12
1
A. [0, ] E. 4, 5, 3, 12
3

B. [
1
,
2
]
63 If a 1, a 2, a 3. . . , a n . are in G.P, then the determinant
3 3 ∣ log a n log a n+1 log a n+2 ∣
∣ ∣
C. [0,
2
]
Δ = log a n+3 log a n+4 log a n+5 is equal to
∣ ∣
3
∣ log a n+6 log a n+7 log a n+8 ∣

D. none of these A. 0
58 If α and β are non-real numbers satisfying x 3
− 1 = 0 , then the B. 1
∣λ + 1 α β ∣

value of ∣

α λ + β 1

is? C. 2

∣ β 1 λ + α∣
D. 4
A. 0
64 The domain of the function f (x) = √log
2
x is
16

8/10
A. x = 0
D. [−1,
1
]
√2
B. |x| ≥ 4

C. |x| ≥ 1

Questions 71 to 75 are of type Single Correct MCQ. Each


D. |x| ≥ 2 question has multiple choices out of which only one is
correct.
65 1
What is the range of the function defined as g(x) = + 3 For each question from 71 to 75, you will be awarded 4.00
x
mark(s) for correct answer and zero mark for unattempted
A. all real numbers questions. No negative marks will be awarded for incorrect
answers in this section.
B. all real numbers except 0

C. all real numbers > 3


71 1 4 7
⎡ ⎤
D. all real numbers except 3 If A = ⎢2 6 5⎥ and B = diag (1 2 5), then
⎣ ⎦
3 −1 2
E. all real numbers > 1
trace of matrix AB is 2

66 ∣ 1 n n ∣ n A. 74
∣ ∣
If D k = ∣ 2k n
2
+ n+ 2 n
2
+ n ∣ , ∑D k = 48 , then

∣ 2k − 1
2 2

k =1 B. 75
n n + n+ 2 ∣

n equals C. 529
A. 4
D. 23
B. 6
72 ∣ a2 + 1 ab ac ∣
∣ ∣
C. 8 ∣ ab b
2
+ 1 bc ∣ = f (a, b, c) , f is
∣ ∣
2
∣ ac bc c + 1∣
D. none of these
A. Non-Homogeneous of degree 2
67 If f x
and f for n =
0 (x) = n + 1 = f0 ∘ fn (x) 0, 1, 2, ⋯
(x + 1) B. Homogeneous of degree 4
then f n (x) is
x C. Homogeneous of degree 6
A.
(n + 1)x + 1
D. Non-Homogeneous of degree 6
B. f 0 (x)
73 Solve the system of the equations:
nx
C. ax + by + cz = d,
2 2
a x + b y + c z = d ,
2 2 3 3 3
a x + b y + c z = d
nx + 1
d(d + b)(c − d) d(a − d)(d − c) d(b

D.
x
A. x = , y = , z =
a(a − b)(c − a) b(a − b)(b − c) d(b
nx + 1
d(d − b)(c − d) d(a + d)(d − c) d(b
68 ∣ 1 a a
2
∣ B. x = , y = , z =
∣ ∣ a(a − b)(c − a) b(a − b)(b − c) d(b
∣ cos(n − 1)x cosnx cos(n + 1)x ∣ = k sin x then k =
∣ ∣ d(d − b)(c − d) d(a − d)(d − c) d(b
∣ sin(n − 1)x sin nx sin(n + 1)x ∣ C. x = , y = , z =
a(a − b)(c − a) b(a − b)(b − c) d(b

A. 1 + a 2
− 2a
D. None of these.
B. 1 − a 2
− 2a
74 ∣ a1 b1 c1 ∣
∣ ∣
C. 1 + a 2
+ 2acosx If Δ = ∣
a2 b2 c2

and A 2, B2 , C2 are respectively cofactors of
∣ a3 b3 c3 ∣
D. 1 + a 2
− 2acosx
a 2 , b2 , c2 then a is equal to
1 A2 + b1 B2 + c1 C2

69 ⎡
1 −2 3

A. −Δ
If A = ⎢ 4 0 −1 ⎥ , then (adj. A) is equal to
B. 0
23
⎣ ⎦
−3 1 5

A. 13 C. Δ

B. −13 D. none of these

C. 5 75 If a, b, c are positive and are the pth, q th and rth terms, respectively,
∣ log a p 1∣

D. −5 of a G.P., then Δ =

log b q 1

is
∣ ∣
∣ log c 1∣
70 If cos −1
x > sin
−1
, then x belongs to the interval
x
r

A. [−∞, 0] A. 0

B. [−1, 0] B. log (abc)

1
C. −(p + q + r)
C. [0, ]
√2

9/10
D. none of these

10/10

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