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Exodis-Pc540 Msds en

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SAFETY DATA SHEET

EXOdis PC540
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 -
Europe
Date of issue : 2017-10-26
Date of revision : 2017-10-26
Version : 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Product name : EXOdis PC540
Chemical name : Acrylic copolymer water solution
EC number : Polymer
CAS number : Not available.
REACH Registration number : Exempt from REACH: Polymer.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Anionic, polymeric dispersant for mineral fillers and inorganic pigments, especially titanium white. The product is dedicated as a primary
dispersant for a wide spectrum of white paints. Provides excellent stability and significantly improves the water resistance of coating
formulations.

1.3 Details of the supplier of the safety data sheet


PCC Exol SA, Sienkiewicza 4, 56-120 Brzeg Dolny, Poland
Telephone: +48 71 794 2127; Fax: +48 71 794 2550
E-mail adress: kch@pcc.eu

1.4 Emergency telephone number


National advisory body/Poison Center
Telephone number : Not available.
Supplier
Telephone number : Telephone: +48 71 794 2555, +48 71 794 2441 (available 24h/day) or +48 71 794 2690 (fax) or
the closest local Fire Brigade

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
Product definition : Polymer
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Not classified.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements


Hazard pictograms : Not applicable.
Signal word : No signal word.
Hazard statements : Not applicable.
Precautionary statements
General : Wear protective gloves/protective clothing/eye protection/face protection.
Prevention Not applicable.
Response : Not applicable.
Storage : Not applicable.

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Disposal : Not applicable.
Supplemental label elements : Not applicable.

2.3 Other hazards


Substance meets the criteria : No.
for PBT according to
Regulation (EC) No.
1907/2006, Annex XIII
Substance meets the criteria : Not available.
for vPvB according to
Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do not : None known.
result in classification

SECTION 3: Composition/information on ingredients


3.1 Substance : Polymer
Classification
Substance Identifiers % Regulation (EC) No. 1272/2008 [CLP/GHS] Type
acrylic copolimer - ~25 Not classified. [A]

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the
classification of the substance and hence require reporting in this section.
Type
[A] Constituent
[B] Impurity
[C] Stabilizing additive
Occupational exposure limits, if available, are listed in Section 8.

3.2 Mixture : Not applicable.

SECTION 4: First aid measures


4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Get medical attention if irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical
attention if symptoms occur.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get
medical attention if symptoms occur.
Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is conscious,
give small quantities of water to drink. Do not induce vomiting unless directed to do so by
medical personnel. Get medical attention if symptoms occur.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Put on
appropriate personal protective equipment (see Section 8).

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.

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Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have
been ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing : None known.


media

5.2 Special hazards arising from the substance or mixture


Hazards from the substance : In a fire or if heated, a pressure increase will occur and the container may burst.
or mixture
Hazardous combustion : No specific data.
products

5.3 Advice for firefighters


Special precautions for fire- : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a
fighters fire. No action shall be taken involving any personal risk or without suitable training.
Special protective equipment : Fire-fighters should wear appropriate protective equipment and self-contained breathing
for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-
fighters (including helmets, protective boots and gloves) conforming to European standard EN
469 will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch
or walk through spilled material. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section
8 on suitable and unsuitable materials. See also the information in "For non-emergency
personnel".

6.2 Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air).

6.3 Methods and materials for : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water
containment and cleaning up courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed
as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations. Dispose of via a licensed waste disposal contractor.

6.4 Reference to other sections : See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

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SECTION 7: Handling and storage
The information in this section contains generic advice and guidance.

7.1 Precautions for safe handling


Protective measures : Put on appropriate personal protective equipment (see Section 8).
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored
occupational hygiene and processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities


Store between the following temperatures: 10 to 40°C (50 to 104°F). Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and
food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before handling or use.

7.3 Specific end use(s)


Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection


The information in this section contains generic advice and guidance.

8.1 Control parameters


Occupational exposure limits
Not established exposure limit value.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere or
procedures biological monitoring may be required to determine the effectiveness of the ventilation or other
control measures and/or the necessity to use respiratory protective equipment. Reference should
be made to monitoring standards, such as the following: European Standard EN 689
(Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical
agents for comparison with limit values and measurement strategy) European Standard EN
14042 (Workplace atmospheres - Guide for the application and use of procedures for the
assessment of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance documents for methods for
the determination of hazardous substances will also be required.
Derived effect levels
No DELs available.

Predicted effect concentrations


No PECs available.

8.2 Exposure controls


Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical product, before eating,
smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash contaminated clothing
before reusing. Ensure that eyewash stations and safety showers are close to the workstation
location.

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Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher
degree of protection: safety glasses with side-shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at
all times when handling chemical products if a risk assessment indicates this is necessary. Wear
suitable gloves tested to EN374.It should be noted that the time to breakthrough for any glove
material may be different for different glove manufacturers.
In case of a long-term direct exposure, nitrile latex>0.2 mm thick, of minimum time of
penetration 30 min should be used.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling this
product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on
the task being performed and the risks involved and should be approved by a specialist before
handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate
standard or certification. Respirators must be used according to a respiratory protection
program to ensure proper fitting, training, and other important aspects of use.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they
controls comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Color : Yellow. Klarowna ciecz
Odor : Characteristic.
Odor threshold : Lack of data.
pH : 6 to 8 [Conc. (% w/w): 10%]
Melting point/freezing point : Lack of data.
Initial boiling point and boiling : Lack of data.
range
Flash point : Open cup: >200°C
Evaporation rate : Lack of data.
Flammability (solid, gas) : Lack of data.
Upper/lower flammability or : Lack of data.
explosive limits
Vapor pressure : Lack of data.
Vapor density : Lack of data.
Density : 1,12 g/cm³ [20°C] approx.
Relative density : Lack of data.
Solubility(ies) : Soluble in the following materials: cold water and hot water.
Solubility in water at room : Lack of data.
temperature (g/l)
Partition coefficient: n-octanol/ : Lack of data.
water
Auto-ignition temperature : Lack of data.
Decomposition temperature : Lack of data.
Viscosity : Dynamic (room temperature): 250 mPa·s
Explosive properties : Lack of data.
Oxidizing properties : No results available.
Additional information : No additional information.

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9.2 Other information
No additional information.

Note: Integers (i.e. 3 or 7) should be read as decimals (3.0 or 7.0)

SECTION 10: Stability and reactivity


10.1 Reactivity : copper and copper compounds

10.2 Chemical stability : The product is stable.

10.3 Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : copper

10.6 Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should not be
products produced.

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
acrylic copolymer LD50 Oral Rat >2000 mg/kg -

Conclusion/Summary : No known significant effects or critical hazards.


Irritation/Corrosion
Conclusion/Summary
Skin : No known significant effects or critical hazards.
Eyes : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.
Sensitizer
Conclusion/Summary
Skin : May cause an allergic skin reaction.
Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)
Not available.

Specific target organ toxicity (repeated exposure)


Not available.

Aspiration hazard
Not available.

Potential acute health effects


Inhalation : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

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Skin contact : No known significant effects or critical hazards.
Eye contact : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation : No specific data.
Ingestion : No specific data.
Skin contact : No specific data.
Eye contact : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : Not available.

Potential delayed effects : Not available.


Long term exposure
Potential immediate effects : Not available.

Potential delayed effects : Not available.

SECTION 12: Ecological information


12.1 Toxicity
Conclusion/Summary : No known significant effects or critical hazards.

12.2 Persistence and degradability


Conclusion/Summary : Not available.

12.3 Bioaccumulative potential


Not applicable.

12.4 Mobility in soil


Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment


PBT : No.
P: Not available. B: Not available. T: No.
vPvB : Not available.
vP: Not available. vB: Not available.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional or local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction.
Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as hazardous waste, as
defined by EU Directive 2008/98/EC.
European waste catalogue (EWC)

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Waste code Waste designation
16 03 06 organic wastes other than those mentioned in 16 03 05

Packaging
Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not
feasible.
Type of packaging European waste catalogue (EWC)
Barrel 15 01 02 plastic packaging
Container 15 01 02 plastic packaging
Tank 15 01 04 metallic packaging
Special precautions : This material and its container must be disposed of in a safe way. Empty containers or liners
may retain some product residues. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

SECTION 14: Transport information


International transport regulations
This product is not regulated for carriage according to ADR/RID, ADN, IMDG, ICAO/IATA.

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 2006
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) No 1907/2006
The European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)
Regulations concerning the International Carriage of Dangerous Goods by Rail (RID) constituting Appendix C to the Convention
concerning International Carriage by Rail (COTIF)
International Maritime Dangerous Goods Code (IMDG CODE)
IATA /International Air Transport Association/ Dangerous Goods Regulations (IATA DGR)
Ordinance of the Minister of Labour and Social Policy of 12 June 2018 concerning maximum permissible concentrations and intensities
of agents harmful to health in a work environment (Journal of Laws 2018 item 1286).
Act on Waste of 14 December 2012 (Dz. U. /Journal of Laws/ of 2013, No. 0, item 21)
Act on Packaging and Packaging Waste Management of 13 June 2013 (Dz. U. /Journal of Laws/ of 2013, No. 0, item 888)
Act on Chemical Substances and Their Mixtures of 25 February 2011 (Dz. U. /Journal of Laws/ No. 63, item 322)
Regulation of the Minister of Labour and Social Policy on the general occupational health and safety regulations of 26 September 1997
(Dz. U. /Journal of Laws/ of 2003, No. 169, item 1650 as amended)
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on : Not applicable.
the manufacture, placing on
the market and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
Europe inventory : Not determined.

Priority List Chemicals : Not determined


Seveso Directive
This product is not controlled under the Seveso Directive.

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15.2 Chemical Safety : Not applicable.
Assessment

SECTION 16: Other information

Changes to the Safety Data : Not applicable.


Sheet
Training advice : Ensure operatives are trained to minimise exposures.
Abbreviations and acronyms : ADN = European Provisions concerning the International Carriage of Dangerous Goods by
Inland Waterway
ADR = The European Agreement concerning the International Carriage of Dangerous Goods
by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS = Chemical Abstracts Service
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
CMR = Carcinogen, Mutagen or Reproductive toxicant
CSA = Chemical Safety Assessment
CSR = Chemical Safety Report
DNEL = Derived No Effect Level
EC number = EINECS or ELINCS number
EC50 = Half maximal effective concentration
ES = Exposure Scenario
EUH statement = CLP-specific Hazard statement
EWC = European Waste Catalogue
GHS = Globally Harmonized System of Classification and Labelling of Chemicals H statement
= CLP/GHS Hazard statement
IATA = International Air Transport Association
IC50 = Half maximal inhibitory concentration
IMDG = International Maritime Dangerous Goods
LC50 = Median lethal concentration
LD50 = Median lethal dose
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978. ("Marpol" = marine pollution)
OECD = Organisation for Economic Co-operation and Development
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
[Regulation (EC) No. 1907/2006]
RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail
RRN = REACH Registration Number
STOT = Specific Target Organ Toxicity
SVHC = Substances of Very High Concern
VOC = Volatile Organic Compound
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Not classified.

Full text of abbreviated H : Not applicable.


statements
Full text of classifications : Not applicable.
[CLP/GHS]
Notice to reader

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The information contained herein is accurate to the latest knowledge and describes the product from the point of view of help
and environmental protection as well as safe handling. The information presented in this SDS refers to the technical product
only and will not apply to any processed product. Final determination of the suitability of any materials for the chosen
application(s) is the sole responsibility of the user"

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