Soil PH
Soil PH
Soil PH
Soil pH is a master variable in soils because it controls many chemical and biochemical
processes operating within the soil. It is a measure of the acidity or alkalinity of a soil. The
study of soil pH is very important in agriculture due to the fact that soil pH regulates plant
nutrient availability by controlling the chemical forms of the different nutrients and also
influences their chemical reactions. As a result, soil and crop productivities are linked to soil
pH value. Though soil pH generally ranges from 1 to 14, the optimum range for most
agricultural crops is between 5.5 and 7.5. However, some crops have adapted to thrive at soil
pH values outside this optimum range. The United States Department of Agricultural
National Resources Conservation Service groups soil pH values as follows: ultra acidic
(<3.5), extremely acidic (3.5–4.4), very strongly acid (4.5–5.0), strongly acidic (5.1–5.5),
moderately acidic (5.6–6.0), slightly acidic (6.1–6.5), neutral (6.6–7.3), slightly alkaline (7.4–
7.8), moderately alkaline (7.9–8.4), strongly alkaline (8.5–9.0) and very strongly alkaline
(>9.0) [1].
Soil pH is affected by the mineral composition of the soil parent material and the weathering
reactions undergone by that parent material. For instance, in humid environments, soil
acidification occurs for a long time as the products of weathering leached by water moving
laterally or downwards through the soil, while in the dry environments, soil weathering and
leaching are less intense, and soil pH is often neutral or alkaline
Definition of Soil
Soil can be simply defined as a mixture of small rock particles/debris and organic materials/
humus which develop on Earth surface and help to grow plants
In India, soil had been classified from the ancient period itself even though it was not as detail
as the modern classifications.In the ancient period, the classification was based on only two
things; whether the soil is fertile or sterile. Thus the classification were:
A-Sandy Soil: it contain mainly sand ( having large particles with large spaces).Due to large
space between the particles the water holding capacity is poor and it contain little amounts of
humus so it is also less fertile and also contain air in it .it easily get dried up .
B-clayey Soil: It contains mainly clay .the water holding capacity is very good due to very
small and tightly packed particles.this lead to water logging of soil and damage of crop
plants.Due to small pore size,it is not able to trap enough Air.It is mainly highly rich in
minerals.it is mainly used for making pots and toys.
C-Loamy Soil: It is good mixture of sand clay silt and humus in right proportions.it has the
right water holding capacity for growth of plant's.the Excess water is drained out easily.it
contain sufficient amounts of air and humus needed for plants root's.it is most fertile soil.
Alluvial soil:
1-Mostly available soil in India (about 43%) which covers an area of 143 sq.km.
6-They are depositional soil – transported and deposited by rivers, streams etc.
10-Colour: Light Grey to Ash Grey .11-Texture: Sandy to silty loam or clay.
14-Wheat, rice, maize, sugarcane, pulses, oilseed etc are cultivated mainly.
Red soil:
4-Colour: Red because of Ferric oxide. The lower layer is reddish yellow or yellow.
5-Texture: Sandy to clay and loamy.Wheat, cotton, pulses, tobacco, oilseeds, potato etc are
cultivated.
1-Regur means cotton – best soil for cotton cultivation.Most of the Deccan is occupied by
Black soiland it is Mature soil.
2-High water retaining capacity.Swells and will become sticky when wet and shrink when
dried.
3-Self-ploughing is a characteristic of the black soil as it develops wide cracks when dried.
Laterite soil:
1-Name from Latin word ‘Later’ which means Brick.Become so soft when wet and so hard
when dried.In the areas of high temperature and high rainfall.
2-Formed as a result of high leaching.Lime and silica will be leached away from the soil.
Organic matters of the soil will be removed fast by the bacteria as it is high temperature and
humus will be taken quickly by the trees and other plants. Thus, humus content is low.
4-Rich in: Iron and AluminumDeficient in: Nitrogen, Potash, Potassium, Lime, Humus
5-Colour: Red colour due to iron oxide.Rice, Ragi, Sugarcane and Cashew nuts are cultivated
mainly.
3-Kankar or Impure Calcium carbonate content is high which restricts the infiltration of
water.
5-Colour: Red to Brown.Peaty / marshy soil:Areas of heavy rainfall and high humidity.
7-A large quantity of dead organic matter/humus which makes the soil alkaline.
Forest soil:
1-Regions of high rainfall.Humus content is less and thus the soil is acidic.
3-Immature soil with low humus and acidic.hich develop on the earth surface and support
growth of plant.
Properties Of Soil:
A-percolation rate -Percolation is the movement of water through soil, and the percolation
rate is the speed at which that movement occur.
B-moisture in Soil: 1-soil absorbs water and also holds water in it ,which is known as
moisture.
3-Simmering of air : On a hot summer day ,the air above the land seems to simmer .it
happen because the vapour coming out of the soil reflect the sunlight and the air seem to
simmer.
horizon as litter zone :- It is called as organic horizon It is formed in the upper part the
mineral soil. : -
A horizon (top soil) :- Horizon of organic matter accumulation adgicent to surface and
B-horizon (Sub soil) :- Horizon in which the deminant features are accumulation of
day, iron, alluminium or in combination strenger of red colour than ourlying or under
lying horizons.
C- horizon 4D horizon (weathing rock) :- It is the horizon below the solum (A+B),
relatiuly less offected by soil forming process. It is out side the zone majer biological
R-horizon (bed rock) :- underlying on solidated rock and it may or may not be like the
Texture of soil indicates the relative content of particles of vorious sizes, such as sand sitt and
Textur influences the case with which soil can be worked the amount of water and air it helds,
and the rate at which water can enter and move soil.
To find the texture of soil sample, first, separate the find earth. all particles less than 2 mm,
from larger particles such gravel and stenes, fine earth is a mixture of sand, sitt and clay,
You musts be sure to use only fine earth to perform the following field tests.
Soil texture (such as loam, sandy loam or clay) refers to the proportion of sand, silt and clay
sized particles that make up the mineral fraction of the soil.
For example, light soil refers to a soil high in sand relative to clay, while heavy soils are made
up largely of clay.
For example, sand is well aerated but does not hold much water and is low in nutrients. Clay
soils generally hold more water, and are better at supplying nutrients.
Texture often changes with depth so roots have to cope with different conditions as they
penetrate the soil. A soil can be classified according to the way the texture changes with
1. Take about 2 tablespoons of soil in one hand and add water, drop by drop, while
2. Squeeze the wetted soil between thumb and forefinger to form a flat ribbon.
3. Determine the texture based on the length of the ribbon that can be formed without
Importance :-
Soil texture plays crucial role for nutrient supplies, acration, reet duvelopment,
moisture content.
Soil structure
Soil structure refers to the way soil particles group together to form aggregates (or peds).
These aggregates vary in size and shape from small crumbs through to large blocks.
Some soils resemble a large, solid, featureless mass—referred to as massive—and have little
or no structure. For example, very sandy soils have no structure because sand grains do not
cling together.
Good soils fit in between the two extremes. A well-structured soil breaks up easily into peds
Good structure is important, as it allows water to soak into the soil and excess water to drain
away. It also allows air movement through the soil. Soil, air and water are vital for healthy
Soil peds
Peds are made up of mineral particles (clay, silt, sand) and organic matter. Peds are held
together by the electrical charges on the surfaces of the minerals and organic matter.
Although clay particles are small, they have large surface areas. For example the surface on
the clay in a teaspoon of black cracking clay soil is equal to the surface area of a tennis court.
Such clays and soils with a lot of organic matter are more likely to form strong peds. Sandy
soils or soils with little organic matter often have little or no ped development.
Peds are described by their shape—for example: blocky, columnar, massive, single grain or
platy.
Types of Aggregates
Granular :- small spherical, no, perouss (0.5 mm), formed in horizons, reet growth
Plaly - thin, flat plates that in heerizontally, usually found in complacted soil
Colummar - vertical columns of soil houzing salt caps at the top, found in soils of
arid climates.
Mostly this is just the topsoil but it does not reflect the entire soil. The topsoil is usually
darker than lower layers (or horizons) because this is where organic matter accumulates.
White—from silicates and salt.
Colour can be a useful indicator of some of the general properties of a soil, as well as some of
Soils can be naturally acid or alkaline, and this can be measured by testing their pH value.
Having the correct pH is important for healthy plant growth. Being aware of the long-term
effects of different soil management practices on soil pH is also important. Research has
What is pH?
concentration varies over a wide range, a logarithmic scale (pH) is used: for a pH decrease of
It is a ‘reverse’ scale in that a very acid soil has a low pH and a high hydrogen ion
concentration. Therefore, at high (alkaline) pH values, the hydrogen ion concentration is low.
Most soils have pH values between 3.5 and 10. In higher rainfall areas the natural pH of soils
6.5 to 7.5—neutral
over 7.5—alkaline
less than 6.5—acidic, and soils with pH less than 5.5 are considered strongly acidic.
Acid sulfate soils can have extremely acidic pH values (pH less than 4).
Origins
Natural soil pH depends on the rock from which the soil was formed (parent material) and the
weathering processes that acted on it—for example climate, vegetation, topography and time.
Effects
Soil pH affects the amount of nutrients and chemicals that are soluble in soil water, and
therefore the amount of nutrients available to plants. Some nutrients are more available under
acid conditions while others are more available under alkaline conditions.
However, most mineral nutrients are readily available to plants when soil pH is near neutral.
The development of strongly acidic soils (less than 5.5 pH) can result in poor plant growth as
aluminium toxicity
manganese toxicity
calcium deficiency
magnesium deficiency
Alkaline soils may have problems with deficiencies of nutrients such as zinc, copper, boron
and manganese. Soils with an extremely alkaline pH (greater than 9) are likely to have high
levels of sodium.
The correct balance is where the soil pH is between 5.5 and 7.5, so every effort should be
taken to check soil pH levels regularly. Early identification of soil pH problems is important
Changing soil pH
Some fertilisers can change soil pH and increase or reduce the amount of nutrients available
to plants.
Fertilisers such as crushed sulfur and some ammonium-based nitrogen fertilisers lower pH
and make soil more acid. They are, therefore, useful for soils with problems caused by high
pH.
When soils are too acidic for a particular crop, lime or dolomite can be used to increase the
pH to the desired level. The amount of lime or dolomite required to correct an acidic pH will
Soils with high organic matter and clay content will be more resistant to changes in pH and
will require larger application rates. Therefore soil pH, while indicating the need for lime, is
Trials
Field trials, in which good quality lime was cultivated into the soil surface to a depth of 0.1m,
Across all soils, for every tonne of lime added per hectare, soil pH increased from 0.1 to 0.8
pH units.
The most common change was an increase of 0.2 to 0.3 pH units. The larger pH increases
Commercial applications
Typical commercial application rates of around 2 tonnes of lime per hectare are therefore
However, these small pH increases are often enough to result in an increased yield.
Liming tropical and subtropical acidic soils usually results in an increase in their capacity to
Measurement
Inexpensive and easy-to-use field kits are available to measure soil pH—these provide only
Most Queensland laboratories use a 1:5 (soil:water) suspension method to determine pH.
However, some laboratories may use different testing methods, so professional advice should
2. Porosity :- Porosity is the space between soil particles in given volume. The pores
space are necessary for holding water, an the free gaseous exchange of oxygen and
4. Soil temperature :- soil temperature is influenced by soil colour, texture and water
Soil temperature
Soil temperature is affected by climate, water content of a soil, soil color, soil cover (e.g.
presence or absence of mulch), depth in the soil profile, and air and water flow within a soil.
Minnesota soils are generally slow to warm in spring due to climate, but the following
Dark colored soils warm more quickly and attain higher temperatures than light colored
soils
Organic matter imparts a darker color to soil, leading to increased warming, but also
Soils with high porosity and well connected pores will warm faster and cool quicker
Soils on south facing slopes are subject to greater thermal inputs compared to north facing
soils
Soil temperatures are an important consideration in vegetated systems. Human activities that
Adding organic matter and mulch will slow warming but also increase heat retention
Activities that improve soil structure, reduce compaction, and increase pore connectivity
Light colored soil coverings reflect solar radiation and decrease heating
SOIL CARBON
Soils can store, cycle and emit as gases different forms of carbon as part of the carbon cycle
process. These forms may be very stable and stay in the soil for thousands of years or may be
broken down in just a few hours. Soil stores more carbon than the atmosphere and plants
combined.
Organic carbon includes decaying plant matter, soil organisms and microbes, and carbon
compounds such as sugars, starches, proteins, carbohydrates, lignins, waxes, resins and
organic acids.
Inorganic carbon is mineral-based with the most common form being calcium carbonate.
Soil organic matter influences soil functions and properties and is a vital indicator of soil
health as it:
provides energy for soil microorganisms, nutrient storage and supply (especially
improves soil structure as well as the soil's ability to hold water and resist
acidification.
The amount of organic matter in soil is difficult to measure directly. Laboratory tests actually
measure soil organic carbon, which makes up about 58% of total soil organic matter.
Soil organic matter is made up of several ‘pools’ which last for different lengths of time in
soil and affect different soil functions. Organic matter and residue deposited in, or on the soil,
Humus, made up of decayed organic residues from plants, soil organisms and microbes, is
more resistant to breaking down than particulate or active organic matter and is a more stable
slow pool. Charcoal is very stable, but is not biologically active, and therefore is an inert or
passive pool.
Soil organic carbon is an important global carbon pool, about 3 times larger than the amount
of carbon stored in vegetation and twice the amount stored in the atmosphere. In general,
organic carbon stocks in Australian soils are much lower than the global average.
Soil cultivation and soil degradation result in loss of organic carbon through release as carbon
Land clearing and over-grazing disturb the soil and can contribute to organic carbon loss by
Improved soil management methods such as retaining crop stubble on the soil surface and
reducing grazing pressure have the potential to increase the store of soil organic carbon
However, by burning fuels and interacting with soil and vegetation, human activities affect
the distribution of carbon between the terrestrial, marine and atmospheric pools of the global
carbon cycle.
Benefits of soil organic matter
Soil organic matter and soil carbon are indicators of soil health. Soil organic matter influences
supporting soil structure by binding particles together into aggregates, which keeps
compaction
preventing leaching losses of plant nutrients like calcium, magnesium and potassium
Ways to improve soil carbon levels will vary according to land-use, soil type and climate. As
Queensland is a large state, there is large variation in the range of soil conditions.
Grazing lands
Around 85% of Queensland is used for grazing of pasture land. This area includes woodlands,
forests, natural grasslands and areas planted to exotic pasture species. General practices for
rate of plant growth—thus increasing or maintaining the level of carbon in the soil.
Cropping lands
Queensland farmers have been very selective in the land they choose to grow crops on as only
Healthy crops efficiently convert carbon dioxide into plant growth. Practices that may help
maintaining a healthy soil that makes optimal use of rainfall and irrigation, has
adequate levels of plant nutrients, is well aerated, has a close to neutral pH and high
farming (CTF)
using green and brown manure crops (green manure crops sprayed with herbicide)
However, adopting a perennial pasture phase is the most promising practice to increase soil
More information
Environment)
The make up of macropores, micropores, soil mineral, water and organic matter
Water supply through soils is vital for both plants and soil organisms—they need water to
survive.
Soil water contains nutrients that move into the plant roots when plants take in water.
Water enters the soil through large pores (macropores) and is stored in many small pores
(micropores). Porous soils have a balance between macro and micro pores.
In Queensland
Queensland has highly variable rainfall and agricultural lands can experience extremes of wet
and dry.
When conditions are predominantly dry, there can be insufficient moisture in the soil to grow
crops or maintain pastures.
Specific terms
To understand how much water is held in soil, the following terms are important:
field capacity—the amount of water held in the soil after it has been fully wetted and
free drainage has stopped. Water applied above this limit will make the soil saturated
but water will drain quickly or be lost as runoff.
permanent wilting point—the soil moisture condition at which the plant could not
obtain water and has wilted and died. The crop cannot be revived by an irrigation or
rainfall event.
plant available water capacity (PAWC)—the amount of water between field capacity
and permanent wilting point that is available to a plant. This requires careful
management and depends on soil texture, structure and organic matter in the soil.
When soil is at field capacity, further rainfall cannot be stored in the soil profile so most of
the water runs off and can cause erosion.
When a soil profile is full, one option is to plant a crop to use the water. This opportunity
cropping reduces the stored water and makes room for more from further rainfall.
Waterlogging
When the soil is at or near field capacity, micropores in the soil are full of water and the
macropores allow for the movement of oxygen.
When a soil is above field capacity, the macropores fill with water and the soil is depleted of
oxygen. When this happens, plant roots cannot get oxygen from the soil and microbial
activity slows. Over a prolonged period, plants eventually die.
Also, without oxygen in the soil, nitrogen breaks down and is lost as gas in a process
called denitrification. This can cause a decline in soil fertility.
Soil limitations to water entry
Water infiltration into the soil will be limited by the least permeable layer, so restrictions near
the surface may be more important than restrictions deep in the profile.
If water is unable to enter the soil profile due to surface sealing or hardsetting for example,
the ability of the soil to store water is reduced.
Surface seal
A surface seal or crust is a thin layer (1−10mm) formed on the soil surface by water drop
impact. It can have a porosity 90% lower than that of an unsealed soil. Permeability declines
during rain or irrigation when the surface aggregates break down and are compacted under
drop impact.
Surface sealing is largely responsible for restricted initial infiltration under rainfall or
irrigation. Water that is unable to move into the soil profile will run off.
Sealing and crusting may be natural, or induced when soil cover is removed. It is sometimes
associated with sodicity.
Hardsetting layer
Hardsetting is an inherent feature of some soils (for example some texture-contrast soils and
weakly structured cracking clays).
Soil aggregates break down during wetting, then set to a hard, structureless mass during
drying. This can be exacerbated by over-cultivation and reduction in organic matter, which
reduces aggregate stability.
Soil compaction
Surface compaction is induced by tillage tool smearing, tractor wheels and farm animals.
This occurs when the soil is sheared or compressed at the critical moisture content known as
the plastic limit.
Compaction results in high soil strength and reduced porosity, preventing water from
accessing the root zone. In tilled soils, a plough pan can be created directly under the tilled
layer by the smearing action of tines.
Compaction below the tilled layer (subsurface compaction) is created by high axle loads
under moist soil conditions. Water is unable to move freely through the soil profile. In dry
conditions, subsurface compaction will prevent roots accessing deep stored moisture.
Impermeable subsoils
Impermeable subsoils are an inherent feature of some soils and may be associated with
a sodic subsoil or shallow soil profile on rock.
Water entry is limited and under high rainfall, waterlogging may occur on top of the
impermeable layer.
A layer that restricts water infiltration in the soil may have the following characteristics:
Management practices that can help overcome restrictive soil layers include:
maintaining stubble cover
gypsum application
cultivation
pasture phase
minimising traffic
controlled traffic farming practices
rotation with deep-rooting crops.
Each of these management practices will improve infiltration in only one or two of the
restrictive layers.
Since the most restrictive layer will control water movement, simply removing one may not
improve the overall physical condition of the soil profile. A combination of practices may be
required to achieve real benefits.
CHEMICAL PROPERTIES OF SOIL
Abstract
Materils required -
Soil Sample
Polythene bags
PH papper
PH colour charg
Test tube
Beaker 250 ml
Funnel
Wistilled water
Filter paper
Experimentation
Obsevation
Experimentation
Take a beaker 250 ml of distilled water and a table spoon full of soil in it.
Stir it well and leave undisturbed for about 20 minute to settle down the soil particles.
Now its time to check the PH tells us how acidic or alkaline a substance is.
The content of this paper highlights the role of soil pH as a master soil variable that has a
bidirectional relationship with soil biogeochemical processes. Although not all
biogeochemical processes were discussed in this paper, those discussed have substantial
influences on soil health, nutrient availability, pollution, and potential hazards of pollutants as
well as their fate in the food chain. The mobility of unwholesome substances through the
hydrological cycle cannot be overlooked here because of the intimate relationship between
soil and water. Thus, an understanding of this can form a basis and a guide to decisions and
choices of soil management, remediation, rehabilitation, and the maintenance of soil quality.
The observed soil pH-biogeochemistry relationships provide insight for future applications
for increased yields for specific crops through nutrient recycling and availability, which
enhances crop growth. The transient rhizosphere soil pH could also be used to enhance the
availability of certain nutrients in certain soil conditions [80]. More importantly, soil pH
could be useful for soil pollution control through the distribution and removal of harmful
substances from systems. For instance, the mineralization and degradation processes such as
those of C and N mineralisation and the degradation of pesticide occur between pH 6.5 and 8,
while the maximum degradation of petroleum and PAHs occur between pH 7 and 9. These, as
well as pH maxima for various microbial enzymes, could be utilized in many soil remediation
strategies, particularly in bioremediation. Ultimately, soil pH can broadly be applied in two
broad areas, i.e., nutrient cycling and plant nutrition and soil remediation (bioremediation and
physicochemical remediation).
REFERENCES
2. FAO, Revised World Soil Charter, Food and Agriculture Organization, Rome, Italy, 2015.
3. FAO and ITPS, Status of the World’s Soil Resources (SWSR)—Main Report, Food and
Agriculture Organization of the United Nations and Intergovernmental Technical Panel on
Soils, Rome, Italy, 2015.
6. N. C. Brady and R. R. Weil, The Nature and Property of Soils, Prentice Hall, Upper Saddle
Hall, NJ, USA, 1999.