Engineering Physics Lecture Notes Module 1
Engineering Physics Lecture Notes Module 1
Lecture Notes
Module 1
QUANTUM MECHANICS, PHYSICS OF
VIBRATIONS AND ELASTICITY
Module 1
SYLLABUS
ENGINEERING PHYSICS
Lecture-1
Introduction to Quantum Mechanics, Blackbody radiation
Introduction
The discovery of microscopic sub atomic particles (electron, proton, neutron etc...) and their
experimental observations could not be explained by Newtonian mechanics (classical
mechanics). The attempts made to explain the experimental results like black body radiation
spectrum, specific heat of solids at low temperatures, photoelectric effect, Compton effect,
atomic spectra etc., led to the development of quantum mechanics. The interaction of light
with matter gave birth to quantum theory of light. Quantum theory of light was first
introduced by Max Planck in the year 1900. In 1924 de Broglie extended wave particle
duality to matter particles (microscopic particles), which says that particles in motion
possess wave nature along with particle nature. In 1926, Erwin Schrodinger developed an
equation for the waves associated with these elementary particles which would describe
the behaviour of particles. The Schrodinger equation plays the same role in quantum
mechanics as that played by Newton’s laws and conservation laws in classical mechanics.
Black body
The body which completely absorbs radiation of all wavelengths incident on it is known
as Black body. Black body is an idealised concept. No perfect black body exists in uni-
verse. But lamp black is considered as nearly blackbody.
1. The black body radiates energy when it get heated to a temperature ‘T’.
2. The emitted radiation is independent of the nature of the body and depend only on
the temperature of the black body. The radiating energy and its relation to the
temperature is formulated by Stefan in the year 1989. Later, Boltzmann has derived
the Stefan formula.
The black body is a one, which completely absorb radiation of all the wavelengths in-
cident on it and emits all wavelengths when it heated to a temperature.
The distribution of energy in the radiation spectrum of black body is of the form of the
curves as shown in figure.
The different curves correspond to different temperatures of the black body.
The following are the conclusions obtained
from the above graph.
1. The distribution of energy is not uniform.
2. For a particular temperature, the intensity of radia-
tion increases upto a particular wavelength and then it is
found to decrease with increase in wavelength.
3. As the temperature increases, the peak energy shifts
towards shorter wavelength.
4. As the temperature increases, the area under each curve increases. It shows that, the
rate of emission increases very rapidly as the temperature rises.
Lecture-2
i.e E = nhν
Where ‘h’ is the Planck's constant h= 6.626×10−34 Js, ν is the frequency of radiation and n is a
number which can take values 0,1,2,3…etc
2. The energy of a single photon of frequency ν is given by
E = hν
3. A vibrating particle can emit energy only when it moves from one quantized state to another
quantized state .
4. A oscillating particle can emit or absorb energy only in discrete amounts of hν.
i.e The exchange of energy between radiation and matter is not continuous . But , it is in small
packets of quanta of definite energy. These small packets of energy are called as photons.
Based on the above assumptions, Planck derived a radiation law governing the entire spectrum of
the black body.
Let ‘N’ be the total number of Planck’s oscillators and ‘E’ be their total energy.
̅ ----------- (1)
Let No, N1, N2, -----------Nr be the number of oscillators having energies
0, hϑ, 2hϑ,3hϑ ----- rhϑ respectively.
Nr is the number density of molecules in nth state (i.e., the number of molecules per unit volume). T
is the temperature, and kB is Boltzmann’s constant.1.38 × 10-23 m2 kg s-2 K-1.
Substituting the values of N1, N2, N3…………by substituting n = 1,2,3........ from equation (4) in equation
(2) We get
Similarly in equation (3) substituting the values of N1, N2, ........... we get
Substituting the values of N and E in equation (1) we get the average energy of the oscillator.
̅ = hv exp(- )/(1-exp(- )
̅= ----------- (6)
( )
The no. of oscillators per unit volume in the frequency range of v and v+dv are given by
N= ----------(7)
The energy density of radiation (Ev) in the frequency range v and v+dv of oscillator is given by
Ev dv =
( )
Ev dv = ---------(8)
( )
Eλ dλ = ---------(9) ( , | | )
( )
i) Wien's Law : When λ is very small, then ( ) So neglected 1 in the denominator from
Eλ dλ = ---------(10)
( )
ii) Rayleigh-Jeans Law: When λ is very large, then ( ) . From Planck's formula (9)
we have
Eλ dλ =
( )
Lecture-3
De-Broglie Hypothesis, Heisenberg’s uncertainty principle
As like light, matter exhibits both particle and wave nature . The waves associated with moving ma-
terial particles (like electrons, protons, and neutrons) are called matter waves or de-Broglie waves.
The wave length of matter waves is derived based on radiation.
Equation of matter waves:
According to Planck’s theory of radiation, the energy of a photon is given by
….. (1)
…… (3),
where P = momentum of photon
This is known as de-Broglie general wave equation. It can be applicable to material particles as
well as light waves.
If m is mass of the material particle and v is the velocity, then the momentum associated with mov-
ing particle is p= mv.
From equation (3), we get
-------- (4)
E= mv2 ---------------(5)
E= mv2 *
2Em=m2v2
mv √
p =√
λ ---------------(6)
√
2eV = mv2
Multiply by ‘m’ on both sides we get
2 2
2meV=
mv =√
From de-Broglie general equation
λ
√
λ or λ √
√
Ex. If the voltage applied to accelerate the electron is V = 100 volts then
λ = 1.227
√
1. Lesser the mass of the particle, greater is the wavelength associated with it.
2. Smaller the velocity of the particle, longer is the wav-length associated with the particle.
3. When V = 0, = ∞ & = ∞, = 0.
4. Matter waves produced when the particles in motion are charged or uncharged.
5. Matter wave are not electro-magnetic waves.
6. Matter waves travel faster than the velocity of light.
E = h and E= mc2
h = mc2
As particle velocity (v) cannot exceed velocity of light (c) , is greater than velocity of light.
If ∆x and are the uncertainties in the measurement of position and momentum of the particle
then the uncertainty can be written as
--------------- (1)
The product of uncertainties determination of the position and momentum of the particle is
equal to or greater than h/4π.
Statement 2: It is impossible to measure simultaneously both the energy and time of a particle
accurately.
The product of uncertainties in energy and time is always greater than or equal to .
--------------- (2)
The product of uncertainties in angular position and angular momentum is always greater
than or equal to .
-------------------(3)
Applications: -
Lecture-4
Schrodinger describes the wave nature of a particle in mathematical form and is known as Schrodinger
wave equation.
Schrödinger equation is a mathematical differential equation for the matter waves associated with
moving material particles.
Let a particle of mass 'm' moving with velocity 'v' along X-axis. Then according to de-Broglie's
hypothesis a particle can have a wave nature.
+ k2= 0
+( ) = 0 ---------(2) (since k = )
Thus, we obtain, + =0
+ = 0 -------------- (3)
The total energy E of the particle is the sum of its kinetic energy K.E and potential energy (V)
Total energy (E) = K.E + P.E
E= v2 + V
v2 = ( E-V )
mv2 = 2( E-V )
+ [E-V] = 0 ------------(5)
+ [E -V]= 0 ------------(6)
This is known as one -dimensional Schrodinger's time independent wave equation.
For a three -dimensional space, the equation becomes
+ + + (E -V) = 0 ------------(7)
𝛙 𝛙
This is known as three dimensional Schrodinger wave equation.
( + + )
Lecture-5
+ = 0 ------------------- (3)
------------ (4)
Where A and B are arbitrary constants, and the value of these constant can be obtained by
applying the boundary conditions.
B=0
Equation (4) becomes
As A 0,
π
…………………. (5)
....................... (6)
This equation gives the allowed energy values for the particle in the potential box.
For n =1,
For n =2, ,
The allowed energy values are quantized and these are known as energy Eigen values.
The allowed wave function of the particle is
……… (7)
Calculation of A:
According to normalization condition, the total probability that the particle is somewhere in the
box must be unity.
∫ ∫ | | dx=1
∫ * +
* +
The second term of the integrand expression becomes zero at both the limits.
Fig. Energy level diagram corresponding to the normalized wave functions of the particle
Problems
1. An electron is moving under a potential field of 15kV. Calculate the wavelength of the electron
waves.
λ
√
2. Electrons are accelerated by 344 volts and are reflected from a crystal. The first reflection
maximum occurs when the glancing angle is 60o. Determine the spacing of the crystal.
λ
√
λ
According to Bragg's law
2dsin =
For first reflection maximum n=1
sin60o = 0.866
Inter atomic spacing of the crystal
Lecture-6
FREE OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-6
ENGINEERING PHYSICS
The particle or body executing simple harmonic motion is called a simple oscillator.
Ex: Motion of a pendulum
Motion of mass attached to a suspended spring.
Differential equation of Simple harmonic motion(SHM)
Let us consider a particle of mass ‘m’ be executing S.H.M along a straight line. Let x
be the displacement of the particle from mean position at any time t.
Then, the restoring force will be
F α –x
F = −kx ------(1)
Where ‘k’ is proportionality constant and is also known as force constant. It is defined
as the force per unit displacement, –ve sign indicates force F is opposite to the
displacement.
According to Newton second law of motion
F= m -----------------(2)
=𝐶 𝛼 -------- (2)
FREE OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-6
ENGINEERING PHYSICS
= 𝐶𝛼 𝛼
α
α --------- (3)
C𝛼2 𝛼 + 2
𝐶 𝛼 =0
𝐶 𝛼(𝛼2 + 2
)=0
(𝛼2 + 2
)=0
𝛼2 = - 2
= 𝐶1 + t+ 𝐶2 − t
= sin( + 𝜙 ) ------------------(4)
FREE OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-6
ENGINEERING PHYSICS
Lecture-7
Consider a particle of mass 'm' is executing damped harmonic oscillations. Let x be the
displacement of the body from its mean position at an instant of time t.
The total forces are acting on the oscillating body is
1) Restoring force (Fr): According to Hook's law, the restoring force acting on the oscillator is
directly proportional to its displacement but in opposite direction.
i.e
𝐹 = − x ---------(1) where k is the constant of proportionality.
2) The damping (frictional) force: The damping force acting on the oscillator is proportional to
its velocity but in opposite direction
i.e 𝐹d
𝐹d ------------(2)
---------------(3)
But according to Newton’s second law of motion, the total force acting on the
oscillator is
DAMPED OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-7
ENGINEERING PHYSICS
𝐹=
F= -----------------(4)
------------(5)
𝛼 and 𝛼 --------(7)
𝛼 𝛼 𝛼
𝛼 α
As 𝛼 α
This gives 𝛼 √
The general solution of eq. (1) is given by
[ √ ] [ √ ]
------------(3)
DAMPED OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-7
ENGINEERING PHYSICS
2 2
When = , This is the condition for critically damped case. Here the body comes back to the
initial state more rapidly than the over damped condition. Here b is optimum where the body
does not oscillate but comes to mean position quickly (curve 2).
Thus in the case of critical damping, the motion just becomes a periodic or non oscillatory.
Ex: This type of motion is exhibited by many pointer instruments such as Ammeter,
voltmeter, etc, in which the pointer moves to the correct position and comes to rest
much rapidly without any oscillations.
Let us write √ = i√ = iβ
where 𝛽 = √(w2 − b2) and = √
(− + 𝛽) (− − 𝛽)
Now eq.(3) becomes = 1 + 2
DAMPED OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-7
ENGINEERING PHYSICS
x= − ( 1 𝛽 + 2 − 𝛽)
−
= (( 1 cos 𝛽 + sin 𝛽 ) + 2(cos 𝛽 − sin 𝛽 ))
−
= (( 1 + 2) cos 𝛽 + ( 1 − 2) 𝛽)
−
= ( sin ∅ cos 𝛽 + ∅ sin 𝛽 )
−
= sin(𝛽 + ∅)
−
= sin(√ ) + ∅)
The above expression is the equation of motion of damped harmonic oscillator. The amplitude
−
of the motion continuously decreasing owing to the factor which is calleddamping factor.
DAMPED OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-7
ENGINEERING PHYSICS
Lecture-8
The total forces acting on the oscillator can be divided into three parts.
i) Restoring force( :
ii) Damping (Frictional) force (Fd): Frictional force is proportional to velocity but oppositely
directed, givenby
𝐹 𝛼
𝐹 ------------(2)
FORCED OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-8
ENGINEERING PHYSICS
Total force F = Fr + Fd + Fe
From (1), (2) and (3)
𝐹 𝐹 .................(4)
But according to Newton second law of motion, the total force acting on the oscillator is
F= ma
𝐹 -------------(5)
.....................(6)
In this case, when the steady state is setup, the particle vibrates with the frequency of applied force
and not with its own natural frequency.
The solution of differential equation (6) must be of the type
= sin( − )..............(7)
Where A is the steady amplitude of vibration and θ is the angle by which the displacement x lags
behind the applied force 𝐹 sin . A and θ are arbitrary constants.
Differentiating equation (6) we get
θ ...................(8) and
FORCED OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-8
ENGINEERING PHYSICS
θ ................(9)
2
− sin( − ) + 2b cos( − ) + 2 sin( − ) = f sin
sin( − ) ( 2 − 2) + 2 cos( − ) = sin( − + )
2 2
sin( − )( − )+2 cos( − ) = sin{( − )+ }
2 2
sin( − )( − )+2 cos( − ) = sin( − ) cos + cos( − ) sin
---------------(12)
√
FORCED OSCILLATIONS-DIFFERENTIAL EQUATION OF SIMPLE HARMONIC MOTION AND SOLUTION MODULE-1 L-8
ENGINEERING PHYSICS
Lecture-9
Elastic Properties of Materials
Introduction
Elasticity is an elegant and fascinating subject that deals with determination of the stress, strain and
displacement distribution in an elastic solid under the influences of external forces.
Elasticity:
It is a property of material bodies by virtue of which they regain their original shape and size after
the deforming forces are removed.
Stress :
When a force acts on a body producing deformation, the internal reactional force which tries to
restore the original condition is called stress.
It is measured in terms of force per unit area. Its unit is Nm-2.
Types of stress
(i) longitudinal : force acting along one direction such as length.
Strain: When a deforming force acts on a body, the dimensions of the body such as length, shape or
volume undergoes a change. The ratio of change in dimension to its original dimension is called
strain. It has no unit and is a dimensionless quantity.
Types of strain
1. Longitudinal strain:
If a force acting on the body results in change of length, then the strain is longitudinal. The
longitudinal strain is the ratio of change in length to the original length.
2. Shearing strain:
If a tangential force is applied on a body, there is a shearing strain. The body is sheared
through an angle . This shearing angle is called shearing strain.
3. Volume strain :
If a normal force (force acting perpendicular to the surface of the body) is applied on the
body which changes its volume, then the ratio of change in volume to the original volume is
called volume strain.
Hooke’s Law: For sufficiently small stresses, strain is proportional to stress; the constant of
proportionality known as modulus of elasticity depends on the material being deformed and
on the nature of the deformation. Within the elastic limit, the stress is directly proportional
to strain.
Stress α strain
Stress = E Strain
Modulus of Elasticity (E) depends on the nature of the material and its unit is Nm-2.
Moduli of elasticity
According to Hook's law , within the elastic limit, the stress is directly proportional to strain
i.e stress α strain
stress =E x strain
where E is known as the modulus of elasticity
Young’s modulus (Y): It is defined as the ratio of normal stress applied to the corresponding
longitudinal strain produced within the elastic limits.
Consider a metal wire of length (l) , radius 'r' and having uniform area of cross-section 'A'.
Let it be suspended from a rigid support. Let a normal force 'F' be applied at its other
end and its length increases by
Longitudinal strain
Normal stress
Y=
where F is the force or the load applied to a wire, A is its area of cross section, Δl is the change in
length and l is the original length of a wire.
The SI units are N/m2 (or) Pascal(Pa)
Rigidity modulus: The ratio of tangential stress applied to the corresponding shearing strain
produced in the body, within the elastic limit.
Let its lower face CDHG be fixed and a tangential force is applied on
the top face ABEF and an equal and opposite force 'F' will be set up
on the lower face and a couple is formed by these forces.
Thus , the body will not change its volume but suffers a change in its
shape. Due to this , the vertical planes ADEH and BCGF be shifted laterally to positions A'E'DH and
B'F'CG through an angle .
------------(2)
-------------(3)
------------(4)
Bulk modulus (k): It is the ratio of normal stress applied to the corresponding volumetric strain
produced in the body, within the elastic limit.
Let us consider a spherical solid body, having volume 'V' and surface area 'A' . Let a force 'F' be
applied normally on the surface of the body in order to compress it and its volume 'V' decreases by
Volume strain =
Normal stress =
For a perfectly rigid body ' Young's modulus and bulk modulus of elasticity are infinity.
Consider a wire stretched by applying load (weight). As the stress is increased, the strain (extension
of length) also increases linearly obeying Hooke’s law. This is indicated by the straight line OA. The
point A indicates the elastic limit i.e. within this limit of stress the wire will regain its original length
if the load is removed.
It is observed that even within the elastic limit, the material takes some time to regain its original
dimension after the load is removed. This delay is called elastic after effect. In the design of
structures, care should be taken to see that material is well within the breaking stress. The fraction
of the breaking stress to be maintained is called working stress.
The ratio of the ultimate strength to working stress is called the factor of safety. For most of the
materials this factor is between 5 and 10.
The ratio of lateral strain to the longitudinal strain within the elastic limits is called Poisson's ratio of
the material.
When a force acts on a wire along its length, then its length increases by but its diameter (or)
radius decreases by By this single applied force, two types of strains are produced in the wire.
The negative sign shows that, if the length increases, the radius of wire will decrease.
The Poisson's ratio is a dimensionless and unit less quantity.
Poisson's ratio for all substances lies in between -1 and +0.5. It is a measure of Poisson's effect in
which a material tends to expand in a direction perpendicular to the direction of compression.
Limits of (σ)