SAFETY DATA SHEET

SECTION 1: IDENTIFICATION

1.1 Product Identifier

Product Name Fuel Oil, residual
Chemical name VERY LOW SULPHUR FUEL OIL
Trade Name Very low sulphur fuel oil
Product type VLSFO
CAS No. 68476-33-5

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified Use(s) Use only as a Fuel

Fuel for industrial, marine, and commercial boilers and furnaces; fuel
for other combustion equipment.

The product should not be used for purposes other than those shown above without first referring to the supplier
and obtaining written handling instructions.

1.3 Details of the supplier of the safety data sheet

Company Identification Monjasa AS
Strevelinsvej 34 7000 Fredericia
Denmark

1.4 Emergency telephone number: the details below are available 24/7

Country Emergency Contact Number Email

Angola +244 222002243 angola@monjasa.com
Cyprus +357 25 123 200 cyprus@monjasa.com
Denmark +45 70 260 230 denmark@monjasa.com
Dubai +971 4 420 8600 dubai@monjasa.com
Namibia +264 64 201 2180 namibia@monjasa.com
Panama +507 2 025 231 americas@monjasa.com
Singapore +65 3163 4000 singapore@monjasa.com
Stamford +1 203 276 6300 americas@monjasa.com
Vietnam +84 28 6287 5952 vietnam@monjasa.com

SECTION 2: HAZARD IDENTIFICATION

2.1 Classification of the substance or mixture

Regulation (EC) No. 1272/2008 (CLP)

Asp. Tox. 1: H304
Acute Tox. 4; H332
Carc. 1B; H350
Repr. 2; H361d
STOT RE 2; H373 (Thymus, Liver, blood effects)
Aquatic Acute 1; H400
Aquatic Chronic 1; H410

2.2 Label elements

Signal Word(s) Danger

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 Hazard Pictogram (s)

Hazard Statement(s) May be fatal if swallowed and enters airways.

Harmaful if inhaled.
May cause cancer.
Suspected of damaging the unborn child.
May cause damage to organs through prolonged or repeated
exposure: Thymus, Liver, blood effects
Very toxic to aquatic life with long lasting effects.

Precautionary Statement(s) Obtain special instructions before use.

Do not breathe dust/fume/gas/mist/vapours/spray.
Use personal protective equipment as required.
IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician
DO NOT induce vomitting.
Avoid release to the environment

Supplemental information Repeated exposure may cause skin dryness or cracking.

2.3 Other hazards Product may release Hydrogen Sulphide:A specific assessment of
inhalation risks from the presence of hydrogen sulphide in tank
headspaces, confied spaces, product residue, tank waste and waster
water, and unintentional releases should be made to help determine
controls appropriate to local circumstances. Remove contaminated
clothing and wash clothing before reuse. Vapour may create explosive
atmosphere. The vapour is heavier than air; beware of pits and
confined spaces.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Components CAS No. EC No. Range in
%
Fuel oil, residual 68476-33-5 270-675-6 100

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

Self-protection of the first aider The vapour is heavier than air, beware of pits and confined spaces. If
it is suspected that fumes are still present, the responder should wear
an appropriate mask or self-contained breathing apparatus. It may be
dangerous to the person providing aid to give mouth-to-mouth
resuscitation, Avoid all contact. Do not ingest. If swallowed, then seek
immediate medical assistance.

H2S Warning Hydrogen sulphide (H2S) can accumulate in the headspace of storage
tanks and reach potentially hazardous concentrations.
If there is any suspicion of inhalation: A self-contained breathing
apparatus should be worn. Remove to fresh air immediately.

Skin Contact IF ON SKIN (or hair): Remove contaminated clothing immediately and
drench affected skin with plenty of water, then wash with soap and

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 water. If irritation (redness, rash, blistering, develops) get medical
attention

Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists, get medical advice/attention.

Inhalation IF INHALED: If breathing is difficult, remove victim to fresh air and keep
at rest in a position comfortable for breathing. Maintain an open airway.
loosen tight clothing such as a collar, tie, belt or waistband. If
symptoms persist, obtain medical attention.

Ingestion IF SWALLOWED: Do not induce vomiting because of risk of aspiration

into the lungs. If vomiting occurs spontaneously, keep head below hips
to prevent aspiration into the lungs. If unconscious, place in recovery
position and get medical attention immediately. Do not give anything
by mouth to an unconscious person. Get medical attention
immediately. Do not wait for symptoms to appear.

4.2 Most important symptoms and Inhalation: Vapour may be irritant to the respiratory tract.
effects, both acute and delayed Skin Contact: Repeated and/or prolonged skin contact may cause
irritation.
Eye Contact: May cause eye irritation.
Ingestion: Aspiration hazard. Aspiration into the lungs may cause
chemical pneumonitis, which can be fatal.

4.3 Indication of any immediate medical If breathing is laboured, oxygen should be administered by qualified
attention and special treatment personnel. In case of accident or if you feel unwell, seek medical
needed advice immediately (show the label where possible).

Notes to a physician: IF INHALED: If unconscious, place in recovery position and get

medical attention immediately. Administer oxygen if available and
artificial respiration if necessary.
IF SWALLOWED: Do not induce vomiting because of risk of aspiration
into the lungs. If aspiration is suspected obtain immediate medical
attention. If vomiting occurs spontaneously, keep head below hips to
prevent aspiration into the lungs.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media Appropriate: Foam, Carbon dioxide, Water fog or dry powder
Inappropriate: Do not use water jet. Direct water jet may spread the
fire.

5.2 Special hazards arising from the Not flammable but will support combustion. The vapour is heavier than
substance or mixture air; beware of pits and confined spaces. Will float and can be reignited
on surface water. Decomposes in a fire giving off toxic fumes. A
mixture of solid and liquid particles and gases including unidentified
organic and inorganic compounds. If Sulphur compounds are present
in appreciable amounts, combustion products may include also H2S
and Sox (sulfur oxides) or sulfuric acid.

5.3 Advice for fire-fighters Fight fire with normal precautions from a reasonable distance. Fire
fighters should wear complete protective clothing including self-
contained breathing apparatus. Keep containers cool by spraying with
water if exposed to fire. Avoid release to the environment. Dike fire
control water for later disposal.

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SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions Caution – spillages may be slippery. Ensure operatives are trained to
minimize exposures. Ensure suitable personal protection during
removal of spillages. Eliminate sources of ignition. Shut off leaks if
without risk. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Avoid all contact with
substance. Ensure adequate ventilation. Do not breathe vapour. Do
not ingest if swallowed then seek immediate medical assistance. Do
not use sparking tools.

H2S Warning Product may release Hydrogen Sulphide. Exposure controls – These
controls may include: Segregation of areas, Access only to authorized
persons, Permit to work systems, Confined space working procedures,
Area H2S alarms, Personal H2S alarms, Personal escape sets, H2S
awareness training. Please see section 8 for appropriate personal
protection equipment.

Small spillages Wear flame-resistant antistatic protective clothing.

Large spillages Evacuate the area and keep personnel upwind. Drench contaminated
clothing with water before removing to avoid of sparks from static
electricity. Avoid all contact. Wear chemical protection suit and
breathing apparatus. See also Section 8.

6.2 Environmental precautions Avoid release to the environment. Do not allow to enter drains, sewers
or watercourses. Spillages or uncontrolled discharges into
watercourses must be alerted to the Environment Agency or other
appropriate regulatory body. If necessary; Dike area to contain the spill
and prevent releases to sewers, drains, or other waterways.

6.3 Methods and material for Provided it is safe to do so, isolate the source of the leak. The Vapour
containment and cleaning up is heavier than air; beware of pits and confined spaces. Ensure that
the equipment is adequately grounded. Allow small spillages to
evaporate provided there is adequate ventilation.

Spillages onto land In case of soil contamination, remove contaminated soil and treat in
accordance with local regulations. Absorb spillages onto sand, earth
or any suitable absorbent material. Transfer to a lidded container for
disposal or recovery. Dispose of this material and its container as
hazardous waste.

Small spillages: Allow small pillages to evaporate provided there is

adequate ventilation. Wear flame-resistant antistatic protective
clothing.
Large spillages: Cover spillage with foam to reduce evaporation. Do
not use water jet.

Spillages on water or at sea Collect as much as possible in clean container for reuse or disposal.
Small spillages: Contain product with floating barriers or other
equipment. Collect spilled product by absorbing with specific floating
absorbents.
Large spillages: Open waters should be contained with floating
barriers or other mechanical means and recovered, only if this is
strictly necessary and if fire/explosion risks can be adequately
prevented. Otherwise control the spreading of the spillage, and let the
substance evaporate naturally.

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6.4 Reference to other sections For guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet., Notify authorities if any exposure
to the general public or the environment occurs or is likely to occur.
For guidance on disposal of spilled material see Section 13 of this
Safety Data Sheet.
Local authorities should be advised if significant spillages cannot be
contained.
Maritime spillages should be dealt with using a Shipboard Oil Pollution
Emergency Plan (SOPEP), as required by MARPOL Annex 1
Regulation 26.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling Obtain special instructions before use. Keep away from sources of
Ignition – No smoking. Use only outdoors or in a well-ventilated area.
Prevent vapour build up by providing adequate ventilation during and
after use. Take action to prevent static discharges. Use non-sparking
tools. All parts of the plant and equipment should be electrically
bonded together and connected to earth. Electrical continuity should
be checked at regular intervals. Antistatic clothing and footwear should
be used. The vapour is heavier than air; beware of pits and confined
spaces. Avoid all contact with substance. Do not ingest. If swallowed,
then seek immediate medical assistance. Do not breathe vapour. See
Section: 8. Keep good industrial hygiene. Wash hands thoroughly after
handling. Contaminated clothing should be thoroughly cleaned.

H2S Warning Product may release Hydrogen Sulphide: A specific assessment of

inhalation risks from the presence of hydrogen sulphide in tank
headspaces, confined spaces, product residue, tank waste and waste
water, and unintentional releases should be made to help determine
controls appropriate to local circumstances. These controls may
include: Segregation of areas, Access only to authorized persons,
Permit to work systems, Confined space working procedures, Area
H2S alarms, Personal H2S alarms, Personal escape sets, H2S
awareness training.

7.2 Storage Light hydrocarbon vapours can build up in the headspace of

containers. These can cause flammability / explosion hazards. Bund
storage facilities to prevent soil and water pollution in the event of
spillage. Keep only in original packaging. Keep containers properly
sealed when not in use. Protect from sunlight. Containers of this
material may be hazardous when empty since they retain product
residue. Empty container may contain product residue which may
result in flammable or explosive vapours inside the container.

Storage temperature Stable at ambient temperatures.

Incompatible materials Keep away from oxidizing agents.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Engineering controls Provide adequate ventilation, including appropriate local extraction if
dusts, fumes or vapours are likely to be evolved. Store in a cool/low-
temperature, well-ventilated (dry) place away from heat and ignition
sources. Guarantee that the eye flushing systems and safety showers
are located close to the working place.

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8.2 Personal Protection Protective clothing should be selected specifically for the working such
place, depending on concentration and quantity of the hazardous
substances handled. The resistance of the protective clothing to
chemicals should be ascertained with the respective supplier. Fuels
are typically used, transferred and transported in closed systems. If
exposure is likely (i.e. during sampling) the following advice may be
appropriate. Keep good industrial hygiene. Always wash hands before
smoking, eating and drinking. Do not eat, drink or smoke at the
workplace.

Eye/ face protection Avoid eye contact. The wearing of chemicals safety goggles, or face
shield is recommended to protect against liquid splashes.

Skin protection Hand protection: Wear impervious gloves. Gloves should be changed
regularly to avoid permeation problems. Breakthrough time of the
glove material: refer to the information provided by the gloves’
producer. Recommended: Nitrile rubber.

Body protection: Wear anti-static clothing and shoes.

small scale: Wear suitable coveralls to prevent exposure to the skin.
large scale: Chemical protection suit.

Respiratory protection If engineering controls do not maintain airborne contaminant

concentrations at a level which is adequate to protect worker health,
an approved respirator may be appropriate. Respirator selection, use,
and maintenance must be in accordance with regulatory requirements,
if applicable.
No special requirements under ordinary conditions of use and with
adequate ventilation in closed systems.
For high airborne concentrations, use an approved supplied-air
respirator, operated in positive pressure mode. Supplied air respirators
with an escape bottle may be appropriate when oxygen levels are
inadequate, gas/vapor warning properties are poor, or if air purifying
filter capacity/rating may be exceeded.
When the product is heated /In case of inadequate ventilation wear
respiratory protection.

8.3 Environmental exposure controls Avoid release to the environment.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Basic physical and chemical properties

Melting point/freezing point < 30 °C
Initial boiling point and boiling range > 350 °C
Flash point > 60 °C
Evaporation rate Not established.
Flammability (solid, gas) Not applicable – Liquid.
Vapour pressure 0.5 kPa @ 20°C
Vapour density >1 (Air=1)
Relative density 0.80 - 0.99 g/cm³ @ 15 °C
Solubility(ies) Water: 0.4 mg/l @ 22 °C Slightly soluble.
Partition coefficient: n-octanol/water 2.7 – 6 log P
Auto-ignition temperature > 225 °C

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 Decomposition Temperature Not established.
Viscosity 7 – 20.5 mm²/s @ 40 °C (<60 mm²/s @ 100 °C)
Appearance Liquid, Viscous, May be coloured.
Odour Fuel oil-like
Explosive properties Not explosive. (Vapour may create explosive atmosphere.)
Oxidizing properties Not oxidizing.

SECTION 10: STABILITY AND REACTIVITY

10.1 Stability Stable under normal conditions. Hazardous polymerization will not
occur. Product may release Hydrogen Sulphide.

10.2 Reactivity Reacts with - Strong oxidizing agents

10.3 Possibility of hazardous reactions Vapours are heavier than air and may travel considerable distances
to a source of ignition and flashback. Product may release Hydrogen
Sulphide.

10.4 Conditions to avoid Elevated temperature: > 50 °C

Keep away from heat, sources of ignition and direct sunlight.

10.5 Incompatible materials Keep away from oxidizing agents. Strong Acids and Alkalis.
10.6 Hazardous decomposition A mixture of solid and liquid particulates and gases including
product(s) unidentified organic and inorganic compounds. Decomposes in a fire
giving off toxic fumes: COx, H2S, SOx,

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological Occupational exposure to the substance or mixture may cause
effects adverse effects.

Skin Contact Causes skin irritation. Repeated exposure may cause skin dryness or
cracking. May be absorbed through the skin.

Eye Contact Direct contact with eyes may cause temporary irritation.

Inhalation Harmful if inhaled. May cause damage to organs through prolonged or

repeated exposure by inhalation. Breathing of high concentrations
may cause dizziness, light-headedness, headache, nausea and loss
of co-ordination. Continued inhalation may result in unconsciousness.

Ingestion Ingestion may cause irritation and malaise. Droplets of the product
aspirated into the lungs through ingestion or vomiting may cause a
serious chemical pneumonia.
11.2 Toxicity Data

Acute May be fatal if swallowed and enters airways. Harmful if inhaled.

Breathing of high concentrations may cause dizziness, light-
headedness, headache, nausea and loss of co-ordination. Continued
inhalation may result in unconsciousness. May irritate and cause
stomach pain, vomiting, diarrhoea and nausea. Hydrogen sulfide, a
highly toxic gas may be present. Signs and symptoms of overexposure
to hydrogen sulfide include respiratory and eye irritation, dizziness,
nausea, coughing, a sensation of dryness and pain in the nose, and
loss of consciousness. Odor does not provide a reliable indicator of
the presence of hazardous levels of gas in the atmosphere.

Chronic Prolonged exposure may cause chronic effects.

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 Suspected of causing cancer

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity Aquatic Acute 1; Very toxic to aquatic life.

Aquatic Chronic 1; Very toxic to aquatic life with long lasting effects.
This product is expected to be resistant to biodegradation and to
persist in the environment.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste disposal Do not empty into drains, dispose of this material and its container at
Hazardous or special waste collection point. Disposal should be in
accordance with local, state or national legislation. Containers of this
material may be hazardous when empty since they retain product
residue. Containers must not be punctured or destroyed by burning,
even when empty. Contact local environmental or health authorities for
approved disposal of this material.

SECTION 14: TRANSPORT INFORMATION

14.1 UN Number UN 3082

14.2 Proper Shipping Name Fuel Oil Residual

SECTION 15: REGULATORY INFORMATION

For current health and safety information on marine fuels, contact any Sales Representative in the country where the
bunker purchase took place.

SECTION 16: OTHER INFORMATION

SOURCE OF KEY DATA:

The recommendations presented in this Safety Data Sheet were compiled from actual test data (when available),
comparison with similar products, component information from suppliers and from recognized codes of good practice.

--------------------------------------------------------------------NOTE------------------------------------------------------------------

The information and recommendations contained herein are, to the best of knowledge and belief, accurate and
reliable as of the date issued, but are offered without guarantee or warranty, express or implied. They relate to
the specific material designated and may not be valid for such material used in combination with any other
materials or in any process. Conditions of use of the material are under the control of the user; therefore, it is
the user’s responsibility to satisfy himself as to the suitability and completeness of such information for his own
particular use.

Health and safety precautions and environmental advice noted in this safety data sheet may not be accurate
for all individuals and/or situations.

It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and
regulations.

Monjasa, its affiliates and subsidiaries and their respective officers, employees or agents are, individually and
collectively, referred to in this clause as the 'Monjasa Group'. The Monjasa Group shall not be liable for any
losses, damages, injuries, or expenses caused by reliance on the information or advice in this document.

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