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SDS Nitomortar

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Revision date: 27/02/2020 Revision: 1 Supersedes date: 22/04/2017

SAFETY DATA SHEET


NITOMORTAR S BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name NITOMORTAR S BASE

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base component of three-part epoxy mortar system.

1.3. Details of the supplier of the safety data sheet


Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number


Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317

Environmental hazards Aquatic Chronic 2 - H411

2.2. Label elements

Hazard pictograms

Signal word Warning

Hazard statements H315 Causes skin irritation.


H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P273 Avoid release to the environment.


P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with national regulations.

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NITOMORTAR S BASE

Contains reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight
≤ 700)

Supplementary precautionary P261 Avoid breathing vapour/ spray.


statements P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 60-100%


(number average molecular weight ≤ 700)
CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-
2119456619-26-XXXX

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

DIBUTYL PHTHALATE <1%


CAS number: 84-74-2 EC number: 201-557-4
M factor (Acute) = 10 M factor (Chronic) = 10
Substance of very high concern (SVHC).

Classification
Acute Tox. 3 - H331
Repr. 1B - H360
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


General information Move affected person to fresh air at once. Get medical attention if any discomfort continues.

Inhalation Move affected person to fresh air at once. Get medical attention. Move affected person to
fresh air and keep warm and at rest in a position comfortable for breathing. When breathing is
difficult, properly trained personnel may assist affected person by administering oxygen.

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NITOMORTAR S BASE

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Give plenty of
water to drink. Get medical attention immediately. Move affected person to fresh air and keep
warm and at rest in a position comfortable for breathing.

Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical
attention promptly if symptoms occur after washing.

Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation May cause coughing and difficulties in breathing.

Ingestion The product irritates mucous membranes and may cause abdominal discomfort if swallowed.

Skin contact May cause irritation to skin as well as allergic rash.

Eye contact May cause severe eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Extinguish with the following media: Dry chemicals, sand, dolomite etc.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture


Specific hazards No specific hazard known.

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon.

5.3. Advice for firefighters


Protective actions during Avoid breathing fire gases or vapours. Cool containers exposed to flames with water until well
firefighting after the fire is out. Control run-off water by containing and keeping it out of sewers and
watercourses.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with
skin and eyes.

6.2. Environmental precautions


Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses.

6.3. Methods and material for containment and cleaning up

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Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate. Absorb in vermiculite, dry sand or earth and place into
containers. Avoid the spillage or runoff entering drains, sewers or watercourses.

6.4. Reference to other sections


Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid spilling. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid inhalation
of vapours. Use approved respirator if air contamination is above an acceptable level.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters


Occupational exposure limits
DIBUTYL PHTHALATE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)

DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³


Workers - Inhalation; Long term systemic effects: 12.25 mg/m³

PNEC - Fresh water; 0.006 mg/l

PRECIPITATED SILICA (CAS: 112926-00-8)

DNEL Workers - Inhalation; Long term systemic effects: 4 mg/m³

DIBUTYL PHTHALATE (CAS: 84-74-2)

DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³


Workers - Dermal; Long term systemic effects: 0.19 mg/kg bw/day

PNEC - Fresh water; 10 µg/l


- marine water; 1 µg/l

8.2. Exposure controls

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NITOMORTAR S BASE

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.


controls

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

Hand protection Nitrile gloves are recommended.

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Promptly remove any clothing that becomes contaminated. Wash
promptly with soap and water if skin becomes contaminated. Use appropriate skin cream to
prevent drying of skin. When using do not eat, drink or smoke.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Gas filter, type A2.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Appearance Liquid.

Colour Black.

Odour Mild

Odour threshold Not determined.

Initial boiling point and range >200 ̊C

Relative density ~ 1.17 @ 20°C

Solubility(ies) Insoluble in Water

Viscosity 0.002 kcps @ 25°C

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.


of a flame

Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

9.2. Other information


Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Epoxides. Strong acids.

10.2. Chemical stability


Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

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NITOMORTAR S BASE

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid


Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials


Materials to avoid Acids. Bases Oxidising materials.

10.6. Hazardous decomposition products


Hazardous decomposition Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation May cause coughing and difficulties in breathing.

Ingestion Liquid irritates mucous membranes and may cause abdominal pain if swallowed.

Skin contact May cause Skin irritation as well allergic rashes on skin

Eye contact Severe irritation, burning and tearing.

Target organs Skin Eyes Respiratory system, lungs

Toxicological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 5,000.0


mg/kg)

Species Rat

Notes (oral LD₅₀) NOAEL 750 mg/kg, Oral, Rat

ATE oral (mg/kg) 5,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 20,000.0


mg/kg)

Species Rabbit

Notes (dermal LD₅₀) LD₅₀ >1600 mg/kg, Dermal, Rat

ATE dermal (mg/kg) 20,000.0

Skin corrosion/irritation

Animal data Rabbit Moderately irritating.

Skin sensitisation

Skin sensitisation May cause sensitisation by skin contact.

SECTION 12: Ecological information

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NITOMORTAR S BASE

Ecotoxicity The product contains substances which are toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Toxicity Ecotoxic to fish/daphnia/algae

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants

12.2. Persistence and degradability


Persistence and degradability Expected to be not readily biodegradable.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Persistence and The product is not readily biodegradable.


degradability

12.3. Bioaccumulative potential


Bioaccumulative potential No data available on bioaccumulation.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Partition coefficient log Pow: 3.242

12.4. Mobility in soil


Mobility The product is insoluble in water.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Mobility The product has poor water-solubility.

Adsorption/desorption Water - Koc: 445 @ °C


coefficient

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

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Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


General information The generation of waste should be minimised or avoided wherever possible.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name


Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
(ADR/RID) product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
DIBUTYL PHTHALATE)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
DIBUTYL PHTHALATE)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
DIBUTYL PHTHALATE)

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
DIBUTYL PHTHALATE)

14.3. Transport hazard class(es)


ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

14.4. Packing group

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NITOMORTAR S BASE

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user


EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number 90


(ADR/RID)

Tunnel restriction code (-)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40.

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTION 16: Other information

General information Only trained personnel should use this material. For professional users only.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 27/02/2020

Revision 1

Supersedes date 22/04/2017

SDS number 25356

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Hazard statements in full H315 Causes skin irritation.


H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H360 May damage fertility or the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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SAFETY DATA SHEET


NITOMORTAR S FILLER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name NITOMORTAR S FILLER

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Filler component for Epoxy based Putty

1.3. Details of the supplier of the safety data sheet


Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number


Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Not Classified

Environmental hazards Not Classified

2.2. Label elements


Hazard statements NC Not Classified

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SILICA SAND 30-60%


CAS number: 14808-60-7 EC number: 238-878-4

Classification Classification (67/548/EEC or 1999/45/EC)


Not Classified -

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NITOMORTAR S FILLER

QUARTZ (SiO2) 1-5%


CAS number: 14808-60-7 EC number: 238-878-4

Classification
Not Classified

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition comments “This product does not contain any hazardous ingredients, or ingredients with national
workplace exposure limits”.

SECTION 4: First aid measures

4.1. Description of first aid measures


General information Consult a physician for specific advice.

Inhalation Remove person to fresh air and keep comfortable for breathing.

Ingestion Rinse mouth thoroughly with water.

Skin contact Rinse cautiously with water for several minutes.

Eye contact Rinse cautiously with water for several minutes.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause discomfort.

Skin contact Prolonged skin contact may cause redness and irritation.

Eye contact Prolonged contact may cause redness and/or tearing.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture


Hazardous combustion Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or
products vapours. Oxides of carbon.

5.3. Advice for firefighters


Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Avoid inhalation of dust. Avoid contact with eyes and prolonged skin contact. Wear protective
clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

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NITOMORTAR S FILLER

Environmental precautions Avoid discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Avoid generation and spreading of dust. Collect and place in suitable waste disposal
containers and seal securely. Label the containers containing waste and contaminated
materials and remove from the area as soon as possible. Flush contaminated area with plenty
of water.

6.4. Reference to other sections


Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid inhalation of dust and contact with skin and eyes. Observe any occupational exposure
limits for the product or ingredients. Avoid inhalation of dust.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in
the original container.

Storage class Chemical storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters


Occupational exposure limits
SILICA SAND
Long-term exposure limit (8-hour TWA): TWA 0.1 mg/m³ (not whiskers) respirable dust
QUARTZ (SiO2)
Long-term exposure limit (8-hour TWA): WEL 0,1 mg/m³ Respirable crystalline silica
WEL = Workplace Exposure Limit

Ingredient comments No exposure limits known for ingredient(s).

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposure
controls limits for the product or ingredients.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.

Hand protection Gloves are recommended for prolonged use. It is recommended that gloves are made of the
following material: Polyvinyl chloride (PVC). Rubber (natural, latex).

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

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NITOMORTAR S FILLER

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any
clothing that becomes contaminated. When using do not eat, drink or smoke.

Respiratory protection Protection against nuisance dust must be used when the airborne concentration exceeds 10
mg/m3. Cartridge for organic steam with a pre-filter for particles, type AP2.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Appearance Solid

Colour Grey.

Odour Odourless.

pH Not applicable.

Melting point Not applicable.

Initial boiling point and range Not applicable.

Flash point Not applicable.

Relative density 1.07 @ 20°C

Solubility(ies) Insoluble in water.

Auto-ignition temperature Not applicable.

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.


of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information


Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability


Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions


Possibility of hazardous No potentially hazardous reactions known.
reactions

10.4. Conditions to avoid


Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials


Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

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NITOMORTAR S FILLER

Hazardous decomposition No known hazardous decomposition products.


products

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Toxicological effects Not regarded as a health or environmental hazard under current legislation.

General information No specific health hazards known.

Inhalation Dust may irritate the respiratory system. Symptoms following overexposure may include the
following: Coughing.

Ingestion May cause discomfort if swallowed.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact Dust in the eyes will cause irritation.

SECTION 12: Ecological information

Ecotoxicity The product is not expected to be hazardous to the environment.

12.1. Toxicity
Toxicity Not considered toxic to fish.

12.2. Persistence and degradability


Persistence and degradability Expected to be readily biodegradable.

12.3. Bioaccumulative potential


Bioaccumulative potential Not expected to be bioaccumulative.

12.4. Mobility in soil


Mobility The product is insoluble in water.

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


General information The generation of waste should be minimised or avoided wherever possible.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

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NITOMORTAR S FILLER

14.2. UN proper shipping name


Not applicable.

14.3. Transport hazard class(es)


No transport warning sign required.

14.4. Packing group


Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant


No.

14.6. Special precautions for user


Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40.


CHIP for everyone HSG228.
Approved Classification and Labelling Guide (Sixth edition) L131.
Safety Data Sheets for Substances and Preparations.

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTION 16: Other information

General information For professional use only. Only trained personnel should use this material.

Revision comments This is the first issue.

Revision date 28/02/2020

Revision 00

SDS number 28433

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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SAFETY DATA SHEET


NITOMORTAR S HARDENER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name NITOMORTAR S HARDENER

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hardener component for epoxy resin mortar

1.3. Details of the supplier of the safety data sheet


Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number


Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens.
1 - H317

Environmental hazards Aquatic Chronic 3 - H412

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H302+H312 Harmful if swallowed or in contact with skin.


H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.

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Precautionary statements P273 Avoid release to the environment.


P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with national regulations.

Contains ISOPHORONEDIAMINE, BENZYL ALCOHOL, SALICYLIC ACID

Supplementary precautionary P260 Do not breathe vapour/ spray.


statements P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

ISOPHORONEDIAMINE 30-60%
CAS number: 2855-13-2 EC number: 220-666-8 REACH registration number: 01-
2119514687-32-xxxx

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412

BENZYL ALCOHOL 30-60%


CAS number: 100-51-6 EC number: 202-859-9 REACH registration number: 01-
2119492630-38

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Eye Irrit. 2 - H319

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SALICYLIC ACID 1-5%


CAS number: 69-72-7 EC number: 200-712-3 REACH registration number: 01-
2119486984-17-XXXX

Classification
Acute Tox. 4 - H302
Eye Dam. 1 - H318

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


General information Consult a physician for specific advice.

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing.

Ingestion Rinse mouth thoroughly with water. Do not induce vomiting.

Skin contact Rinse immediately with plenty of water. Continue to rinse for at least 10 minutes.

Eye contact Rinse with water. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Dizziness. Difficulty in breathing.

Ingestion May cause chemical burns in mouth, oesophagus and stomach.

Skin contact May cause allergic reaction as well as serious Skin burns.

Eye contact Can cause serious Eye damage if come in contact

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture


Specific hazards Water used for fire extinguishing, which has been in contact with the product, may be
corrosive. No unusual fire or explosion hazards noted.

Hazardous combustion No known hazardous decomposition products.


products

5.3. Advice for firefighters


Protective actions during No specific firefighting precautions known.
firefighting

Special protective equipment Use protective equipment appropriate for surrounding materials.
for firefighters

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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Avoid contact with eyes and prolonged skin contact.

6.2. Environmental precautions


Environmental precautions Collect and dispose of spillage as indicated in Section 13. Do not discharge into drains or
watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Collect and dispose of
spillage as indicated in Section 13.

6.4. Reference to other sections


Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid contact with skin and eyes. Mechanical ventilation or local exhaust ventilation may be
required. Do not eat, drink or smoke when using this product.

Advice on general Wash hands and any other contaminated areas of the body with soap and water before
occupational hygiene leaving the work site.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Corrosive storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

ISOPHORONEDIAMINE (CAS: 2855-13-2)

PNEC - marine water; 0.006 mg/l


- Fresh water; 0.06 mg/l
- Soil; 1.121 mg/kg

BENZYL ALCOHOL (CAS: 100-51-6)

DNEL Workers - Inhalation; Short term systemic effects: 110 mg/m³


Workers - Inhalation; Long term systemic effects: 22 mg/m³
Workers - Dermal; Short term systemic effects: 40 mg/kg bw/day
Workers - Dermal; Long term systemic effects: 8 mg/kg bw/day

PNEC - Fresh water; 1 mg/l


- marine water; 0.1 mg/l
- STP; 39 mg/l

SALICYLIC ACID (CAS: 69-72-7)

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DNEL Workers - Inhalation; Long term systemic effects: 5 mg/m³


Workers - Dermal; Long term systemic effects: 2.3 mg/kg bw/day
Workers - Inhalation; Long term local effects: 5 mg/m³
General population - Inhalation; Long term systemic effects: 4 mg/m³

PNEC - Fresh water; 0.20 mg/l


- marine water; 0.020 mg/l
- Sediment (Freshwater); 1.42 mg/kg dw
- Soil; 0.17 mg/kg dw
- STP; 16.2 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.


controls

Personal protection Wash hands and any other contaminated areas of the body with soap and water before
leaving the work site.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield. (conform EN 166)

Hand protection Nitrile gloves are recommended.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Do not eat, drink or smoke when using this product.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Appearance Liquid.

Colour Straw.

Odour Amine.

Initial boiling point and range 220⁰ @ 1atm

Flash point 115⁰ C

Relative density ~ 1.080 g/cm3 @ 25°C

Solubility(ies) Insoluble in Water

Viscosity ~40 cP @ 25°C

Explosive under the influence Not considered to be explosive.


of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information


Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity

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Reactivity The following materials may react with the product: Acids. Alkalis.

10.2. Chemical stability


Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions


Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid


Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials


Materials to avoid Strong acids. Strong alkalis. Strong oxidising agents.

10.6. Hazardous decomposition products


Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Acute toxicity - oral
ATE oral (mg/kg) 695.27

Acute toxicity - dermal


ATE dermal (mg/kg) 1,880.34

Acute toxicity - inhalation


ATE inhalation (vapours mg/l) 28.13

Inhalation May cause coughing and difficulties in breathing.

Ingestion May be harmful if swallowed and enters airways.

Skin contact May cause allergic reaction as well as serious skin burns

Eye contact Severe irritation, burning and tearing.

Acute and chronic health Frequent inhalation of dust over a long period of time increases the risk of developing lung
hazards diseases.

Target organs Eyes, Lungs, Respiratory, Skin.

Toxicological information on ingredients.

ISOPHORONEDIAMINE

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 1,030.0


mg/kg)

Species Rat

ATE oral (mg/kg) 500.0

Acute toxicity - dermal

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Acute toxicity dermal (LD₅₀ 1,840.0


mg/kg)

Species Rabbit

ATE dermal (mg/kg) 1,100.0

BENZYL ALCOHOL

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 1,620.0


mg/kg)

Species Rat

ATE oral (mg/kg) 1,620.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 2,000.0


mg/kg)

Species Rabbit

ATE dermal (mg/kg) 2,001.0

Acute toxicity - inhalation

Acute toxicity inhalation 11.0


(LC₅₀ vapours mg/l)

Species Rat

ATE inhalation (vapours 11.0


mg/l)

Skin sensitisation

Skin sensitisation Not sensitising.

Carcinogenicity

Carcinogenicity NOAEL 200 mg/kg/day, Oral, Mouse There is no evidence that the product can
cause cancer.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure NOAEL 400 mg/kg, Oral, Rat

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause burns in mucous membranes, throat, oesophagus and stomach.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact Severe irritation, burning and tearing.

SALICYLIC ACID

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 891.0


mg/kg)

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Species Rat

ATE oral (mg/kg) 891.0

Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ >2000 mg/kg, Dermal, Rat

Acute toxicity - inhalation

Notes (inhalation LC₅₀) LC50 >0.9 mg/l, Inhalation, Rat

SECTION 12: Ecological information

Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity Expected to be ecotoxic to fish/daphnia/algae.

Ecological information on ingredients.

ISOPHORONEDIAMINE

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 110 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 23 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic IC₅₀, 72 hours: 50 mg/l, Algae


plants

12.2. Persistence and degradability


Persistence and degradability Expected to be not readily biodegradable.

Ecological information on ingredients.

ISOPHORONEDIAMINE

Persistence and The product is not readily biodegradable.


degradability

12.3. Bioaccumulative potential


Bioaccumulative potential No data available on bioaccumulation.

Ecological information on ingredients.

ISOPHORONEDIAMINE

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

Partition coefficient log Kow: 0.99

12.4. Mobility in soil


Mobility Insoluble in water.

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

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Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


General information The generation of waste should be minimised or avoided wherever possible.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 2289

UN No. (IMDG) 2289

UN No. (ICAO) 2289

UN No. (ADN) 2289

14.2. UN proper shipping name


Proper shipping name ISOPHORONEDIAMINE
(ADR/RID)

Proper shipping name (IMDG) ISOPHORONEDIAMINE

Proper shipping name (ICAO) ISOPHORONEDIAMINE

Proper shipping name (ADN) ISOPHORONEDIAMINE

14.3. Transport hazard class(es)


ADR/RID class 8

ADR/RID classification code C7

ADR/RID label 8

IMDG class 8

ICAO class/division 8

ADN class 8

Transport labels

14.4. Packing group


ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant


No.

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14.6. Special precautions for user


EmS F-A, S-B

ADR transport category 3

Emergency Action Code 2X

Hazard Identification Number 80


(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTION 16: Other information

Abbreviations and acronyms IARC: International Agency for Research on Cancer.


used in the safety data sheet IATA: International Air Transport Association.

General information For professional use only. Only trained personnel should use this material.

Revision comments It is first ıssue.

Revision date 28/02/2020

Revision 00

SDS number 28076

Hazard statements in full H302 Harmful if swallowed.


H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H412 Harmful to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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