Chemistry Imp. Ques Sem-I

1123-SRI KRISHNA COLLEGE OF ENGINEERING, ARAKKONAM.
ENGINEERING CHEMISTRY-I
CHEMISTRY IMPORTANT QUESTIONS
PART-A
2 MARKS
UNIT-I
POLYMER CHEMISTRY
1. Define: Monomer and Polymer?

2. What is polymerization reaction?
3. What is degree of polymerization?
4. What is functionality with example?
5. What is co-polymerization with example?
6. What are plastics? Write its classification?
7. Define: Tacticity (or) Stereo specific polymer
8. What is homo polymer and hetero polymer? Give an example?
9. What are organic polymer and inorganic polymer? Give example?
10. What is natural polymer and synthetic polymer? Give an example?
11. What is glass transition temperature?
12. What is a co-catalyst? Mention its function?
13. What are the different types of molecular weight of polymers?
14. What do you understand by disproportionation of polymer chains?
15. What is poly dispersity index?
UNIT-II
CHEMICAL THERMODYAMICS
1. Explain the following

a) System b) Surroundings c) Boundary
2. What is an extensive property? Give example?
3. What is an intensive property? Give example?
4. What is an isothermal process?
5. What is an adiabatic process?
6. What is Isobaric process and Isochoric process?
7. What is a reversible process?
8. What is irreversible process?
9. Write the difference between reversible and irreversible process?
10. What is internal energy? Mention its unit?
11. What is enthalpy? How is it related with internal energy?
12. State first law of thermodynamics? Write its mathematical equation?
13. State second law of thermodynamics?
14. Define : Entropy
15. What is Gibbs free energy?
16. Write any two maxwell’s relations?
17. What are the applications of clausius?
UNIT-III
PHOTOCHEMISTRY AND SPECTROSCOPY
1. What are photochemical reactions? Give examples?

2. Define: Grothus-Draper law
3. Define: Stark-Einstein law
4. Write any two reasons for high quantum yield?
5. Write any two reasons for low quantum yield?
6. What is a photosensitiser? Give examples?
7. What is Quenching?
8. What is fluorescene? Give examples?
9. What is phosphorescence? Give examples?
10. What is an Internal conversion?
11. What is inter system crossing?
12. What is chemiluminescence ? Give examples?
13. What is bioluminescence? Give example?
14. Define: Quantum efficiency Ø (or) Quantum yield
15. State Beer’s Lambert’s law?
16. What are the various types of electronic transitions involved in an organic molecule?
17. What are Chromophores? Give example?
18. What are Auxochromes? Give example?
19. What is finger print region? Write its uses?
20. Calculate the number of modes of vibration for the following molecules
a) CH4 b) CO2 c) C2H2
21. Calculate the number of IR bands for the following molecules
a) C2H6 b) C6H6
22. Write any two applications of UV-spectroscopy?
UNIT-IV
PHASE RULE AND ALLOYS
1. State Phase rule?
2. State Condensed (or) Reduced phase rule?
3. Define: Eutectic point
4. What is eutectic temperature?
5. Calculate the degree of freedom for the following.
i) NH4Cl(s) → NH3(g) + HCl(g)
ii) Ice(s) → Water(l) → Vapour(g)
iii) CaCO3(s) → CaO(s) + CO2(g)
iv) MgCO3(s) → MgO(s) + CO2(g)
6. What is a triple point?
7. Define: Alloy and their types
8. Write any two properties of alloys?
9. What are Annealing?
10. Name any four important heat treatment process?
11. What is meant by Quenching in heat treatment of metals?
12. What is tempering?
13. Define: Normalising
14. Give the composition of Nichrome?
15. Give the composition of Brass and Bronze?
16. State the significance of increasing carbon content in steel?
UNIT-V
NANOCHEMISTRY
1. Define: Nanotechnology
2. How are nanomaterials classified?
3. What are nano particles?
4. What are nano cluters?
5. What are nano rods?
6. What are nanotube?
7. What are nano wire?
8. Name any four methods to synthesise nanomaterials?
9. Name any four properties of nanometerials?
10. What is top-down process?
11. What is bottom up process?
12. Write any two applications of nanomaterials?
13. What are carbon nano-tubes ? Mention uses of it?
14. Write the difference between bulk particles and nano particles?
***ALL THE BEST***
1123-SRI KRISHNA COLLEGE OF ENGINEERING, ARAKKONAM.
ENGINEERING CHEMISTRY-I
CHEMISTRY IMPORTANT QUESTIONS
PART-B
8 MARKS
UNIT-I
POLYMER CHEMISTRY
1. Write the differences between addition polymerization and condensation polymerization?
2. Write the differences between thermo plastics and thermo setting plastics?
3. Describe the preparation, properties and uses of Nylon-6,6?
4. Describe the preparation, properties and uses of epoxy resins (or) epoxide polymers?
5. Explain the mechanism of free radical polymerization?
6. Discuss cationic polymerization with an example?
7. Discuss anionic polymerization with an example?
8. What are various methods of molecular weight of polymers?
(Number average molecular weight, weight average molecular weight)
9. Explain are the various methods of polymerization techniques?
(Bulk polymerization, Solution polymerization, Emulsion polymerization & Suspension
polymerization)
UNIT-II
CHEMICAL THERMODYAMICS
1. State various statement of second law of thermodynamics?
2. Derive an expression for the entropy change for an ideal gas?
3. Derive an expression for entropy change in a reversible and irreversible process?
4. Discuss the criteria of spontaneity of a chemical reaction?
5. Derive Gibbs-Helmholtz equation? Write its significance? (or) Derive the relation between G & H
6. Derive any two Maxwell’s relations?
7. Derive Clausius-Clapeyron equation?
8. Derive Van’t Hoff isotherm?
9. Derive van’t Hoff equation? (or) Derive van’t Hoff reaction isochore?
UNIT-III
PHOTOCHEMISTRY AND SPECTROSCOPY
1. State and explain Stark-Einstein law?
2. Explain Grothus-Draper law?
3. Derive Beer-Lambert’s law?
4. Explain Jablonski diagram? (or) Explain mechanism of fluorescence and phosphorescence?
5. Explain the principle and working of a UV-visible spectrometer with block diagram?
6. Mention the applications of UV spectroscopy?
7. Mention the application of IR spectroscopy?
8. How will you determine the Quantum efficiency (or) Quantum yield ?
9. Explain photo-sensitization?
UNIT-IV
PHASE RULE AND ALLOYS
1. State phase rule. Explain the terms involved in it with suitable examples?
2. Draw and explain the phase diagram of water system?
( One component system)
3. Draw and explain the phase diagram of Lead-Silver system?
(two component system)
4. Draw and explain the phase diagram of zinc-magnesium system?
5. Explain pattinsos’s process? (or) Explain desilverisation of argentiferros lead?
6. Explain various methods of heat treatment of steel?
7. Explain ferrous alloys? (Nichrome and stainless steels)
8. Explain Non-ferrous alloys? (Brass and Bronze)
UNIT-V
NANOCHEMISTRY
1. What are nanomaterial? Mention its different types with examples?
2. Explain size dependent properties?
3. Explain any four methods to synthesize nanomaterials?
4. Write in details on the important properties of nanomatrials?
5. Write the applications of nanomaterials?
***ALL THE BEST***

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1123-SRI KRISHNA COLLEGE OF ENGINEERING, ARAKKONAM.

1. Define: Monomer and Polymer?

1. Explain the following

1. What are photochemical reactions? Give examples?

ALL THE BEST

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