FIITJEE

ALL INDIA TEST SERIES

JEE (Advanced)-2023
OPEN TEST – I
PAPER –1
TEST DATE: 05-02-2023

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

Section – A

1. B, D
2k P
Sol. E
r
V r  
r  r
 0

dV   Edr
r0
R
 +
 V  2k(nr  nr0 ) O x = +a
x = a
V  2kn(r)  C
r 
VP  V  V  2kn(r )  2kn(r )  2kn   
 r 

r  (x  a)iˆ  yjˆ

r  (x  a)iˆ  yjˆ
(x  a)2  y 2
VP  2kn
(x  a)2  y 2

for vP  ln2
40
(n  a)2  y 2
 2
(x  a)2  y2
(x  a)2  y 2  2(x  a)2  2y 2
(x  3a)2  y 2  8a2
 Equipotential surface is cylinder with radius 2 2a

2. A, C
Sol. For oscillation to occur it must be in the stable equilibrium i.e. centre of mass of the system must
be below the centre of hemisphere.

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 2

3. A, C, D
320
Sol. 1000   1 = 8 cm
41
3  320
1000   2 = 24 cm
4 2
dh dh a
A
dv
 2 2gh   
h A 
2g dt 
4. B, D
Sol. Charge flown through S1 is Q + 3Q = 12 mC (Q+q) (Q+q) (+3Qq)
(Q  q) (3Q  q)2d
0 d 0 d 2d
0 A 0 A
By solving q = 15 mC

1 2 3

q
=1V

5. A, C, D
Sol. Conserve angular momentum about O. 2mv 02 = I  /2
O
40m 2
Where I 
3 r 
3v C
  0
10
2
2  
r    
4  2
5
r 
2
5 3v 3
v c  rc   0  v0
2 10 2 10
1 3
K.E. = I2  mv 20
2 5

6. A, B, C, D
Sol. Torque along vertical axis is zero

7. B
 3H 
Sol. (I) PN  P0  g  
 2 
H
PN  P0  3g
2

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 3 AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

(II) V  2g(2H)  2 gH

H 1
P0  gH  PN  g  (4gH)
2 2

gH gH
PN  P0  gH   2gH  
2 2

2
1 2H
(III) PN  P0  gh    
2 2

1 2 2
PN  P0  gH   H
8

2H  2g

5
 PN  P0  gH
4

(IV) PN  P0  (gcos60)2H

PN  P0  gH

8. B
4
Sol. (I) vI  3  4
3
vr  4  3  1 m/s
2
dv  v  du
(II)   
dt  u  dt
 vI  1 m/s and vr  10 m/s
(III) vI,m  4
 vI, g = 7  vr = 8 m/s
(IV) final image is at the position of object hence magnification is 1
 vI = v0 = 1m/s
 vr = 0

9. C
Sol. (I)

Q  Tds = Area between T-s diagram = 700 J
3 5
(II) Q = n R  Tf  Ti   n R(Tf  Ti )
2 2
3 5
 (nRTf  nRTi )  (nRTf  nRTi )
2 2
3 5
 (500  100)  (1000  500)  1850 J
2 2

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 4

T
(III) Process is T = 100 V   constant i.e. pressure = constant
V
5
 Q = nCPT = 2 R(300  100)  1000R
2
(IV) A  B is V = constant and B  C, P = constant
3 5 5
Q = n R(TB  TA )  n R(TC  TB )  (1000  500)  (500  1000)
2 2 3

10. D
R 2  3g 
Sol. (I) mg   mR2       
2 3  4R 
4R
T  2
3g
2R
(II) maR = mg
 R
2g ma 2R/
a
 mg

4R2
mgeff R2  sin   2mR2 
2
4
geff  a2  g2  g 1 
2
 g  4  2R
     1  2     T  2
 2R     4 
g 1  2 
  
(III) P  IP  O
d
mgdsin = IP 
3R 13 N mg
d , IP  mR2
8 20
P fS
 mgd 
   
 IP 
IP 26R
T  2  T  2
mgd 15g
gsin 
(IV) a 
I r 
1 C 2 R
mR
5g 5g x g 
a   x
7 7 r R 7R
7R
T  2
g

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 5 AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

Section – B

11. 0.68
MR2 I0
Sol. I1   MR2 …(i)
4 I2
2
 4R 
I2  Icm  M  R   …(ii)
 3 
cm O
2
 4R  R
I0  Icm  M 
 3 
MR4 Icm
I0 
4
Solving the equations
I2  I1
 0.68
I1

12. 0.01
h
Sol. Fn

and F = mg
hc
 Power P = n

P
 mg 
c
P = mgc
dm 2
Also, P  c
dt
dm mg
   0.01 kg/s
dt c

13. 19.11
Sol. mv0 cos   2mv C
v 0 cos 
 vC 
2
Conservation of angular momentum
  m 2 m  2 m 2 
mv0 cos      
4  16 12 16 
6v cos 
 0
5
 3v 2 sin2
 = t and N=  0
2 10g

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 6

14. 3.14
Sol. f S = ma
N = mg
0 = 0 N
Nx  fS   0 fS
x fS x
mgx
fs 

g mg N
a x


Time =    sec
g

15. 1.19
Sol. 2  4k   2  1 k p cos 60  2  17k 0 cos 
2  1 k P sin60  2  17  k 0 sin 
Solving k0 = 0.71 MeV
 Q = (k  kP  k0) = 1.19 MeV

16. 0.80
Range ( 0.79 to 0.82)
Sol. For rotation equilibrium net torque is zero
 NIAB + 4g  5  102 + (100x)  2.5  102 = 0
x = 0.8 m

17. 0.75
Sol. Minimum speed of sphere w.r.t. block at highest point is v min=5m/s.
Conservation of momentum
1v 0 = (1+4)v = 5v1 + 5(v15)
Conservation of energy
1 1 1
 5v 2  5g(2  2.5)  5v12  5(v1  5)2
2 2 2

18. 0.75
Sol. Velocity of pendulum before collision
v 0  2g cos30  6 m/s
Ft = mv0
Ft cos 30 = mv Ft
v
3 v 3 30
 mv0  mv  v  0
2 2 Ft
3
v
2 3
e 
v0 4

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 7 AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

Chemistry PART – II

Section – A

19. A, D
Sol. H3C H3C H3C
CH3 CH3 CH3


H
 
H
HO O

H3C H
H3C H3C
CH3 CH3 CH3

CH3 CH3
CH3

CH3 CH3 CH2 CH3



CH3 CH3 H3C

CH3
CH3 CH3

CH3 CH3

CH3 H


CH3  Option A 

CH3 CH3
H
H3C
CH3
CH3 CH3

CH3  CH3  Option D 

CH3 CH3
H
H3C
CH3

20. A, B, C, D
Sol. The driving force behind these reactions (A and B) is the formation of LiCl or LiBr (very large
lattice energy and insoluble in organic solvents in which the reaction is performed)
 Benzene is more acidic than C2H6 , so the reaction (C) can occur.
 Li3 N converts into amides and hydrides by reaction with hydrogen.

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 8

21. B, D
Sol. BeO  Ba  OH 2  Ba Be  OH4 
 Amphoteric oxide  Baryta water 
 basic 

22. A, B, C
Sol.   keto acids, gem-dioic acids and ,   unsaturated acids decarboxylates on simple heating.
(D) is however a   keto acid but in transition state, there will be a double bond at bridge head
position which is not stable. So, (D) will not decarboxylate on heating.

23. B, D
Sol. (A) Second nearest neighbours of Cs are 6 and not 8 (in CsCl crystal).
(B)

There are 6 triangular voids around a sphere in two dimensional hcp layer.
(C) r 0.3
  0.75 which indicates that cations are present in cubic void of a simple cubic unit
r 0.4
cell, so its coordination number is 8 and not 6.

(D) Definition of Frenkel defect.

24. B, C
Sol. C Cl has less priority than ester, so, (A) is wrong but (B) is correct.
O
Double bond has more priority than ‘Br’.

25. B
Sol. (I) Ph Ph
4
Ph  C  C  Ph  
Pd BaSO C C
H 2
H H
D  10 
Ph H
Na

liq. NH3
 C C
H Ph

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 9 AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

(II) OH
Pd BaSO 4
H2

CH CH2

OH ONa
 Na
  H2
C C H n hexane
C CNa
D  3 

OH
 AgNH3  
 2


C C Ag

 White precipitate 
(III)
Pd BaSO
4

H
 C C CH2 CH3
2

H H
C C CH2 CH3

D  6  Ph H
Na

liq. NH3
 C C
H Et
(IV) CH3OH

H3C

CH3OH
Pd BaSO
4

H

2

H2C O
H3C

HC C H3C CH3ONa
O
Na
D  6  
n hexane
 
O
NaC C

26. D
3 2
Sol. AlCl3  H2 O   Al H2 O 6    Al H2 O 5  OH   H
BCl3  3H2 O  H3 BO3  3HCl
B 2H6  H2 O  H3 BO3  H2
 Acid
Alums contains Al3  or Cr 3  or Fe3  ions whose aqueous solution is strongly acidic.
Also, in B2H6 , there is 3c-2e bond formation in which vacant 2p-orbital of ‘B’ is also involved in
sp3-hybridisation.

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 10

27. C
   
Sol. Pt  s  / H2  g |  H3 PO4  Na3 PO 4   CH3 COOH | H2  g / Pt  s  
1 bar   100 mL, 0.2 M 100 mL, 0.1 M   100 mL, 0.1 M 1 bar  
   
From Nernst Equation
H 
 a
Ecell  0.06  log
H 
 c
or Ecell   pHa   pHc   0.06 … (1)

H3 PO4  PO34  H2 PO4  HPO42

(I)
20 10 0 0
10 0 10 10
Again,
H3 PO4  HPO42  2H2PO 4
10 10 10
0 0 30
pK a1  pK a2
48
  pHa   6
2 2
Also, at cathode
CH3 COOH  CH3 COO  H
Ka 105
   102 , H   103
 c
C 0.1
  pHc  3
Ecell  0.06 6  3   0.18 V
(II) If 100 mL, 0.1 M NaOH is added in anode compartments
H3 PO4 , PO34 , NaOH
20 m.mol 10 m.mol 10 m.mol
H3 PO4  OH  H2PO 4  H2 O
20 10 0
10 0 10
Also,
H3 PO4  PO34  H2 PO4  HPO42
10 10 10 0
0 0 20 10
So, it is a buffer.
HPO24  10
 
 pHa  pK a2  log
2
 8  log
H2PO 4  20
 
  pHa  7.7
Ecell  0.06 7.7  3  0.282 V

(III) 50 mL, 0.1 M NaOH is added in cathode compartment

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 11 AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

CH3 COOH  OH  CH3 COO   H2 O

10 5 0
5 0 5

 P it is also a buffer.
5
 pHc  5  log  5
5
 Ecell  0.06 6  5   0.06 V

(IV) 100 mL, 0.1 M HCl is added in anode compartment

PO34  H  HPO24
10 10 0
0 0 10
H3 PO4  HPO24  2H2PO 4
20 10 0
10 0 20
  pHa  4  log 2  4.3
Ecell  0.06 4.3  3  0.06  1.3  0.078 V

28. D
Sol. (I) Br

2 5C H ONa




E  2 
(II)

ONa  CH3 I 
S 2
 O CH3  NaI
N

(III) O Br
KOH alc.
O



  KBr  H2 O
E1cb 
(IV)
N(CH3)3
KOH alc.



  NMe3  H2 O
E2 
Section – B

29. 3.50
Sol. Except statements (i) and (iv), all other statements are correct.
(i) SF6 molecule has a maximum of 9 planes of symmetry (and not 5).
(iv) About 75% (and not 60%) of the solar energy reaching the earth is absorbed by earth
surface which increases its temperature.

30. 8.97
[Range :8.96 – 8.98]
Sol. PV = nRT

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 12

W 
PV   He   R  T
 4 
20.14 110  100.5  WHe
   0.082   273  30.2 
760 1000 4
WHe  8.97  10 4 g  x  10 4 g
 x  8.97

31. 19.82
[Range : 19.81 – 19.83]
Sol. W  P2  V2  V1 
 nRT nRT 
 P2   
 P2 P1 
 P 
 nRT 1  2 
 P1 
 5
 2  8.314  298  1  
 1
W  19820.576 J
Now, W  mgh
W
h
mg
19820.576
h  19.82 'm '
100  10

32. 0.24
[Range : 0.23 – 0.25]
Sol. meq. of iodine in 200 mL solution = meq. of Ce 4  15  0.05
= 0.75
0.75
 Normality of iodine 
200
127
Eq. weight of I 
2
0.75 127
Iodide ion concentration   = 0.238 g/L
200 2

33. 1.50
Sol. Total number of isomers of B.H.C. = 9
Total number of isomers of K Co NH3 2 F  2  Cl 2  = 6

34. 2.20
Sol. X  H3 PO4 , Y  H2 S, Z  PSCl3
x  8  3  11
y5
x 11
  2.20 P4 S10  16H2 O  4H3 PO4  10H2 S
y 5  X  Y
P4 S10  6PCl5  10PSCl3
 Z

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 13 AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

35. 9.33
[Range : 9.33 – 9.34]
Sol. Pd  46  : 1s2 2s 2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s0
    
4 4 8 4 8
So, x = 28
y=3

36. 1.33
[1.33 – 1.34]
Sol. Number of triangular faces in truncated cube = 8
Number of octagonal faces in truncated cube = 6
Each corner of the cube will become a triangular face and each square face will become an
octahedral face in a truncated solid cube.

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 14

Mathematics PART – III

Section – A

37. A, B, D
Sol. Apply AM  GM
d – ax – by – cz > 0
ax, by, cz, d – ax – by – cz
Apply AM  GM

38. A, B, C
Sol. Sn2  Sn21  1  Sn  n

39. B, C
10 10 10
Cr 1 10
Sol.  30
 30  10  r
Cr  20  r
C10 = coefficient of x is (1 – x)–22
r 0 C10  r C20  20 C10 r 0

40. A, B, C
  sin x 2 ; x  1

 ln 4  sin1 ; x  1
 2

Sol. f x  ln 3  x 2 
   ; 1  x  1
 ln 4  sin1
 ; x 1
 2

  sin  x 
2
; x 1

41. A, B, D
Sol. F(x) – f(x) = k(x – 1)2(x – 2)2(x – 3)2

42. A, C, D
     
Sol. The plane  r  n1  a     r  n2  b   0 is identical with r  n3  c

43. A
Sol. Domain of g(x) is [0, ) and range of g(x) is [–1, )

44. D
Sol. (I) The point of intersection is (2, –1, 2)
x  2 2y  3 3z  4
(II) Line drawn from P intersects the line   measured parallel to the plane
3 4 5
 5 
4x + 12y – 3z + 1 = 0 at  4, , 2 
 2 
AR 4
(III) 
RQ 9
   5 
(IV) f   x   sin  x    sin x  0  x  or at x  local maxima exists
 3 3 6 3

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 15 AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

45. B
d  g  x   g  x  1 ex
Sol.          g x   e
dx  g x  g x e

46. C
Sol. (I) Expand the square

1 g1

(II)  g  x  dx    g
1
 x  dx  1 g 1  0  g  0 
0 g0
1 e 2

  e  x  1 dx 
x
 g1  x  dx   e  2   1  0  2
0 2

e2 1
x2  1   1 3
 g1  x  dx   e  2   e x   x =  e  2    e   1  e0  = e  2  e  =
2 2 0   2   2 2
(III) g(x) = ax + b
2 2
1  x   1
(IV) Area bounded =  44  2   dx    
2 2  2x  1   2
3

Section – B

47. 0.00
Sol. P(a) = b, P(b) = c and P(c) = a
bc c a ab
  I1 ,  I2 and  I3
ab bc c a

48. 2.00
Sol. AC·BC = CS2

49. 2.00
Sol. Circle touches each other externally

50. 33.00
 3 2 3  36 9 1 9 1 36  10 13
Sol. P ,      =   
 5 5 2 50 50 4 10 4 40 20

51. 1.00
cos   isin  cosk  isink
Sol. Let z  ; zk 
cos  cosk 
cosn  isinn
n 1
n 1
1  z cosn  sinn cosn   cos n
 zk   =  i
k 0 1 z
1
cos   isin  sin  cosn 1  sin  cosn 1 
cos 

sinn
 n 1 k  sinn 6
So, Re   z   n 1
 n 1
 k  0  sin  cos   
sin  cos 
6 6

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AITS-OT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 16

52. 5.00
1
Sol. P 1  Q 1  P  Q    P1  Q 1  P  Q   I  I  P 1Q  Q 1P  I  I
Let P 1Q  A , then A  A 1  I  0  A 2  A  I  0
3
A = I  |A| = 1
1
P1Q  1  P1 Q  1   Q  1  |Q| = 5
P

53. 0.50
Sol. The person B will score more if
Case-I: In first 9 chances A and B have same score and B is successful in 10th chance
Case-IIL In first 9 chances B has more score.

54. 2.00
Sol. Multiply and divide by sin 2 sin 4 sin 6 ..... sin 88

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