GTM 5 Key

Sec: SR.
IIT_COSC GTM-5 Date: 10-02-21

Time: 3 Hrs Max.Marks: 300
KEY SHEET
PHYSICS
1 A 2 A 3 B 4 C 5 A
6 C 7 C 8 A 9 B 10 D
11 D 12 A 13 B 14 C 15 C
16 D 17 B 18 D 19 A 20 B
21 6 22 3970 23 12 24 1.5 25 500
26 50 27 1.25 28 8 29 25 30 18
CHEMISTRY
31 C 32 A 33 C 34 B 35 C
36 A 37 C 38 A 39 C 40 B
41 C 42 B 43 A 44 B 45 C
46 A 47 D 47 A 49 C 50 D
51 24 52 3 53 5 54 8 55 11
56 4 57 10 58 3 59 6 60 7
MATHEMATICS
61 B 62 B 63 C 64 D 65 B
66 D 67 C 68 C 69 C 70 C
71 C 72 B 73 D 74 B 75 A
76 B 77 C 78 B 79 A 80 D
81 0.4 82 1 83 3.5 84 1 85 5.5
86 1.8 87 4 88 0 89 1 90 0.35
https://t.me/education_for_all_123
Narayana IIT Academy 10-02-21_Sr.IIT CO SC_ JEE-MAIN_GTM-5_Key & Sol
SOLUTIONS
PHYSICS
1. Let us consider the motion of the ball with respect to disk
Net force along groove = n r sin 

2
x
 m 2 r
r
 m 2 x
 ma  m 2 x
dv
 v  2x
dx
v R /2
  vdv    2 xdx
0 0
v  R
2 2 2
   
2 2 2
R
v
 2  
v Ball,Ground  v Ball,Disk  v Disk,Ground

 v Ball,Ground
1/2
  R  
2
 R  0 3
  R      2  R    R
2
 cos120 
  2   2   2
SR.IIT_N-SC Page. No. 2
Believe you can and you’re halfway there.
2.
  P  E  PE sin  ........ i 
 PE sin   I
[ I is the moment of inertia and  the angular acceleration].
Since displacement is small sin  
PE
The angular frequency of oscillation is given by  
l
The potential energy is lowest when the dipole moment is aligned with the
filed and highest when the two are antialigned.
3. Consider a coaxial cylindrical shell of radius r and thickness dr a shown in diagram. The radial rate
of flow of heat through this shell in steady state will be
dQ d
H   KA
dt dr
[Negative sign is used as with increase in r , decrease ]. Now as for cylindrical shell A  2 rL,
d b dr 2 LK 2
H  2 rLK
dr
or  a r

H 1
d
Which on integration and simplification gives :
dQ 2 KL 1   2 
H  ……….(i)
dt log e  b / a 
I 2 R  5  4
2
Here H    24 cal/s, L = 2m = 200cm

4.2 4.2
r1   0.64 / 2  mm = 0.032cm and r2  r1  d  0.032+0.006 = 0.038 cm
24  log e  38 / 32 
So, 1   2  
2  3.14  200  0.16  102
551.57 1.50 0
24  2.3026 log10 38  log10 32 1  2  2 C
 or 2
3.14  0.64
4. For 0  x  1,U  E0
 Kinetic energy, K1  Total energy – U
 2E0  E0  E0
h
1  …(i)
2mE0
For x  1,U  0
 Kinetic energy K 2  total energy – U
 2E0
h
 2  .... ii 
2m  2 E0 
From Eqs. (i) and ( ii), we have
1
 2
2
5. Angular Momentum about Hinge
LH  I H .
 m1l 2 
 H
I  
 3 
L M 1L2
LH  M 2v  
2 3
3M 2v
 ...........1
2 M 1L
L
For e  1, vcm  v  ... 2 
2
2v 3M 2v
 
L 2 M 1L
M 3
 1  = 0.75
M2 4
6. Since diode D1 is reverse biased, therefore it will act as an open circuit.
The effective resistance of the circuit is R  4  2  6
Current in the circuit is I  E / R  12 / 6  2 A
Given, pT  constant
2
7.
 nRT  2
  T  constant
 v 
3 1
or T V  constant
Differentiating the equation, we get
3T 2 T3 T
.dT  2 .dV  0 or 3.dT  .dV
v V V
From the equation, dV  V dT
dV
  Coefficient of volume expansion of gas =
V .dT
dV 3
  
V .dT T
8 Let the quantity be Q, then,
Q  f  v, F , T 
Assuming that the function is the product of power functions of v, F and T ,
Q  Kv x F yT z ... i 
Where K is a dimensionless constant of proportionality. The above equation dimensionally becomes
Q    LT 1   MLT 2  T 
x y z
i.e., Q    M   L T
y x x y  x2 y  z
 ……..(ii)
Now
Q  mass i.e., Q    M 
So Equation (ii) becomes
 M    M y Lx yT  x2 y  z 
Its dimensional correctness require
y  1, x  y  0 and  x  2 y  z  0
Which on solving yields
x  1, y  1 and z  1
Substituting it in equations (i), we get
Q  Kv 1FT
9. Lens will from image of two sources at 70 cm from lens ( i.e., screen)
v hi
From magnification of lens m  
u h0
70 0.7 / 2

30 d / 2
On solving, d = 0.3 cm
D
Now, fringes width  
d
 d 0.0195  102  0.3  10 2 0
So,     5850 A
D 1
m1 x1  m2 x2  ......  mn xn
10. X cm 
m1  m2  m3  ......  mn
mL   2m  2 L    3m  3L   ......   nm  nL 
X cm 
m  2m  3m  ......  nm
L  1  2  32  .....  n 2 
2
X cm 
1  2  3  ......  n
  r2 
11.   BA cos t   B   cos t 
 2 
d d  1 
Induced emf e     B r 2 cos t  
dt dt  2 
e 2
B r
2 2 4 2
Power P   sin 2 t 
R 4R
1
But  sin t 
2
2
 B r  
2 2
 P 
8R
12. From first law of thermodynamics
dQ  dv  dw
dQ  dU dW  0 dQ  0 
 dU  0
So, temperature will decrease
1 1 1
13.  
K s K1 K 2
m
t1  2
K1
m
t2  2
K2
m
T  2
Ks
14. For TI R i  ic
i  450
sin i  sin c
1 1
  sin c 
sin c 
1
sin 450 

  1.414
 red  1.414 but green  1.414 and  violet  1.414
15. Ace to conservation of angular momentum
mL2
mv0 x  mv1 x   1
3
 x  v1 1
e    2
v0 2
Impulse at hinge J = 0
L
m  mv1  mv0  0   3
2
Solve (1),(2) & (3)
16. N 2  1 1016 cm 3
N a  1.1 1017 cm 3
ni  1012 cm 3
N  Na  N  Na 
2
Then electron density n0  2   2   ni2

2  2 
17. Velocity  LT 1
Density  ML3
Wave length y  L
Surface tension  MT 2
Verify options.
2
 sin  
18. I  I0  
  


2

d sin    2n  1
2
2
  d sin  

   2n  1 
 
  2n  1
2 2
2
  2n  1  
 sin  2   
 I  I0    
   
 
2 n 1
  2  
I0
I 2
 2n  1  
 2   
  
4I0 4I0
I 0 : I1 : I 2  I 0 : :
9 2 25 2

19. l    2l  3
2
Equation of stationary wave
y   2 A sin Kx  cos t 
If y  A  amplitud  2 A
A  2 A sin Kx
1 2
sin Kx  ; K 
2 
1 5
sin Kx1  and Kx2 
6 6
5 1
Then, x2  x1    1m
4 4
dU
20. For U max  0
dx
d  x2 x2 
  0
dx  4 2 
 x  0 or x =  1
d 2U
At x  0   1
dx 2
d 2U
x  1  2  2
dx
Hence U  min at x  
1
U min   J
4
K max  U min  E  2
1 2 1 3
mvmax   2  Vmax  m/s
2 4 2
1
  z  1
2
21.

1  z2  1
2
 
2  z1  12
1  Z2  1 
 
4  11  1 
Solving this, we get Z 2  6
V V 2
22. i    1 103 A  1mA
Reff 1970  30 2000
This current provides full scale deflection (i.e, 20 division)in order to limit the deflection 10
divisions,
The resistance needed to connect can be obtained as
miAB  i
  1 1
k  2 i2
1 :  2  2
 i1 : i2  2 :1
ii 1 103
 i2    5  104 mA
2 2
v V
i   Rs   Reff
Reff  Rs i
2
  2000
5  104
2
  104  2000
5
 4  103  2000  2000 
 The resistance of 1970  is to be replaced by 1970  2000  3970 
23. Current in tangent galvanometer

2rBH
I tan  ..... i 
0 N
From Eq.(i), we get

r tan  0 I
  same for both
N 2 BH
r tan  A rB tan  B 8 1 16 3
A   
NA NB  2 3 N B
 N B  12 times
In an adiabatic process, T   constant  P
  1
24.
or T
 /  1
  constant  P
Given T 3   constant  P

  3  3  3  
 1
Cp
or 2  3    3 / 2   1.5
Cv
25. Force on SR and PQ are equal but opposite so their net will be zero.
Force between two parallel conductors carrying currents I1 and I 2
0 I1I 2l
F
2 r
Where r  distance between two parallel conductors
107  2  20  20  15  102
FPS 
2  102
 6  104 N
107  2  20  20  15  102
FQR  2
 1 104 N
2  10
Fnet  FPS  FQR
 6  104  1 104  5  104 N  500 N
26. T '  50ms
I
T  2
MBH
ml 2
I  m  massof magnet 
l2
2
l ml  I
I '  2    3 
l  3  3 9
L
M '  M  3  M
3
I' T 150
T '  2 T '   50 ms
M ' BH 3 3
r3
27. T  2
GM
R
r  Rh R
4
GM  gR 2
 R
2  R   R  R
2  R  h  Rh  4 4
T ; T
R g R g
dN
28.   N   N 0e  t  N  N 0e  t 
dt
 dN 
log e    log e  N 0e  t   log e   N 0   t
 dt 
1 1
From graph    05
2 year
N  N 0e  t  N 0e 0.54.16  N 0e 2.08
N
On solving N  0
8
H 50
29. Rmax    25cm
2 2
30.
Al St
L L1 L2
 1 2
1`
L  L T  L total  L1  L2

 L1  L2   19  106  T  L1  23  106  T  L2 12  106  T
 L1  L2   19  23L1  12 L2
 L1   L2  L1 L2
19    23   12 Let  x  1 x
 L1  L2   L1  L2  L1  L2 L1  L2
7 p
19  x  23  1  x 12  x    p  q  18
11 q
CHEMISTRY
31. EK  hv  E0
Where E0 = work function
y  mx  c
Comparison shown that the Plank’s constant will be the slope of the line.
i  t  E 5  193  8
32. w 
F 96500
 At NTP, volume of 32g o2  22400mL
22400  0.08
Volume of 0.08 g O2   56mL
32
33. Work done = Area bounded by the triangle ABC
1
  2V1  5P1  5PV
1 1
2
34. I 2  2 NaOH  NaOI  NaI  H 2O
PhCH 2CH  OH  CH 3 
NaOI
 PhCH 2  CO  CH 2 
NaOI
 PhCH 2  CO  CI 3

NaOH
 CHI 3  PhCH 2COONa


H 3O
 PhCH 2COOH
4
35. The reaction of CFSE for tetrahedral and octahedral complex is given as  t   0 . So  t for
9
4
CoCl4 
2
  18000cm 1  8000cm 1
9
Pd  BaSO4
36. CH 3  COCl  H 2   CH 3CHO  HCl
acetyl chloride acetaldehyde
This reaction is called Rosenmund’s reaction.
37. The reactions are as follows
38. C12 H 22O11  H 2O  C6 H12O6  C6 H12O6
Glucose Fructose
H 2O in excess, a rate of reaction depends only on sucrose so inversion of cane sugar is an example
of pseudo-first order reaction.
38. Here compound A is calcium hydroxide and the milky solution is of calcium carbobnate.
40. Here only in option B is incorrect while rest other are correct. In borax  Na2 B4O7 .10 H 2O  ,
among 10 water molecules 2 molecules are part of structure, i.e., exists
Na2  B4O5  OH 4  .8 H 2O .
Na2  B4O5  OH 4  .8 H 2O  2 HCl  2 NaCl  4 H 3 BO3  5 H 2O

Methyl orange (pH=3.7) is used to detect end point. Aqueous solution of borax acts as buffer, as borx
is salt of strong base NaOH and weal acid H 3 BO3 .
H   1  s 
41. InK    
R T  R
At high temperature of shifted backward, it is exothermic reaction.
H reac
o
is –ve
Slope is +ve
42. NaCl gives following reaction as follows
1
1 1 1 1 1   R 2
43.  R 2  2   R 2  2   n  
  n1 n2  1 n    R  1 
44. The heating of oxime of acetone in presence of conc. H 2 SO4 to form N-mithyl ethanamde is called
Beckmann rearrangement. In Beckmann rearrangement, R-migrates from carbon to nitrogen of an
oxime to form N-substituted amide.
Loss of H 2O occurs with simultaneous migration of the trans-R’.
45. NO2 is an odd electron molecule so NO2 is paramagnetic
The dimer, N 2O4 , has no unpaired electron so it is diamagnetic.
46. This is an example of oxymercutation –demercuration and gives alcohol corresponding to

Markovnikov’s addition of water to carbon-carbon double bond.
47. Due to inert pair effect, Tl prefers its +1 oxidation state while bonding with iodine and TlI form.
Although thallium (Tl) from TlI3, but the O.S. of thallium is +1 in this compound, because iodine is
 
present as tri-iodide ion I 3 .
48. In case of AgBr, the ionic product will exceed the solubility product before AgCl , Ag 2CO3 and
Ag 3 AsO4 . Thus, AgBr will start precipitation before other salts.
49. T  i  K f  m
 273  269.28  i  1.86  1  3.72  i  1.86
i 1 2 1
 1 n2
n 1 n 1
Thus, the complex should give two ions in the solution, i.e., the complex will be
 Pd  H 2O 3 Cl3  Cl. 3H 2O
2
50. Number of O ions = n
Number of tetrahedral voids = 2n
Number of octahedral voids = n
n
Number of Y ions =
2
n
Number of X ions =
4
n n n
Occupied octahedral voids   
4 4 2
1
So fraction of occupied octahedral voids 
2
51. 12 H 2O  8 Al  4 Al2O3  24 H  24e 

24 H   3Fe3O4  24e   9 Fe  12 H 2O
24 electrons are transferred from reductant to oxidant.
52.
2-Buranone will show tautomerism
Total enol products = 1 + 2 = 3

 In  
53. Indicator equations is pH  pK ln  log
 H ln 
Colour change takes place when  In    H ln 

i.e., when pH  pK ln  5
54.
So x+y = 6+2 = 8
55. OC C C O
sp sp sp
There are eight covalent bonds in C3O2 , so x = 8 and y = 3 as c-atoms are sp-hybridised. So x+y =
8+3 = 11
56. Bithional has 4 Cl-atoms
0.693
57. t for first order reaction
k
2.303  a 
k log  
time ax
0.693 2.303  100  6.903
 log    time  t1/2  10t1/2
t1/2 time  100  99.9  0.93
58.
59. The oxidation number of Mn in the product of alkaline oxidative fusion of MnO2 is +6 as follows.
2  x  8
4 KOH  2 MnO2  O2  2 K 2 MnO4  2 H 2O
Potassium maganate
 2  x  8  0  x  6
60. Glucose, HF , R  OH , R  COOH , R2 NH have intermolecular H-bonding while CCl3CHO
and o-nitro phenol has intramolecular H-bonding.
MATHEMATICS
61. s  t  s  t
  p    p  q    p    p  q 
  p   p  q
  p  p   q
tqt
Also, p   p  q    p   p  q   t

62. Given line is parallel to iˆ  2 ˆj  6kˆ  b  let 

Let a  2iˆ  3 ˆj  4kˆ

  a.b 2  6  24 32
Projection of a on b is   
b 41 41
 
f  x   lim cos 2  x 2    x 
n
63.
n
 x  cos 2  x 2    0,1


1   x  cos  x   1
2 2
 x  x 2  I

1   x  x  I
2
For x = 1
f  1  1   0, f 1   1   1, f 1  1  1  2
 f 1   f 1 
 f  x  is discontinuous at x = 1
For x = 0
f  0    0   1, f  0    0   0, f  0   1   0  1
 f  0   f  0   f  x  is discontinuous at x = 0
64.  3 4

Coefficient of x in 1  5 x  9 x  13 x  17 x  ...... 1  11x  C2 x  ......
4 2 2 11 4

Coefficient of x in  C2  9  11  17  1
4 11
11  10
  99  17  55  99  17  171
2
65. S  1  4 x  7 x 2  10 x 3  .........
xS  x  4 x 2  7 x 3  10 x 4  .........
On subtracting , we get
S  x  1  1  3 x  3 x 2  3 x 3  .........
 1 
 1  3x  , x  1
1 x 
1  x  3x 1  2 x
1  x  S  
1 x 1 x
1  2 x 35
S 
  16

2
1 x
16  32 x  35  35 x 2  70 x   5 x  1   7 x  19   0
1 19
x ,
5 7
1
But, x  1  x 
5
Let the equation of the circle be  x  r    y  r   r and x  y  2rx  2ry  r  0
2 2 2 2 2 2
66.
If they are orthogonal 2   r1   r2   2   r2   r2   r1  r2
2 2
 r12  4r1r2  r22  0

r r
 1  2 2 32 3  4
r2 r1
Let f  x   cot x  x  4   cos 1 x 2  4 x  1

1
67.
For f  x  to be defined, we have x  4 x  0 and 0  x  4 x  1  1
2 2
Which is only possible if x  4 x  0  x  0, 4

2
Also these values satisfies the equation.

Number of solutions = 2
68. If the plane contains the given line then it must pass through (3,b,3) and should be parallel to
2iˆ  4 ˆj  3kˆ
Also, the plane passes through the points  a,1,2  2,1,4  2,3,5 
Equation of the plane is
x  2 y 1 z  4
0 2 1  0   x  2  2    y  1 2    z  4  4   0
2 4 3
 x  2  y  1  2z  8  0  x  y  2z  5  0
Points (3,b,3) (a,1,2) satisfy the equation of the plane, if
3  b  6  5  0  b  2
a  1  4  5  0  a  2
69. As,  x  y   3
 x  y   3, 2 
Hence, the required area is

2

1 2
3  22   sq.units
5
2
70. dashes (5) Dots (8) Arrangements
7
5 2 C2
7
4 3 C3
7
3 4 C4
7
2 5 C5
7
1 6 C6
7
0 7 C7
Required number of ways C2  C3  C4  C5  C6  C7  2  7  1  120
7 7 7 7 7 7 7
 2 3 4 5 
2

Required expression =  cos cos
71. cos cos cos 
 11 11 11 11 11 
 2 8 4 5 
2

=  cos cos cos cos cos 
 11 11 11 11 11 
16   10 
2 2
    
 sin 11 5   2sin 11 cos 11   sin 11  1 1
  cos        2
 11   32sin  
 16sin   32  sin  32 1024
 11   11   11 
72. Applying  a  b  x  and adding we get,
x   x
  dx
2I   dx  2 I     2I  
0 1  tan x
6 0 1  tan 6 x

 1 1  
dx
0 1  tan x 1  tan   x 
2
 6
 6 dx  2 I  2 0 1  tan 6 x
2
 

cos6 x
 2  2
dx
0cos6 x  sin 6 x
Again, applying  a  b  x  and adding we get,
 
sin 6 x  cos 6 x   2
2I    2
dx  2 I    1dx      I 
2
0 sin 6 x  cos 6 x 0
2 4
Let the chord of contact is PQ which touches x  4 y  4 at R
2 2
73.
Now, assume R   2cos ,2sin  
Equation of the chord of contact PQ is hx  2 yk  6..... i 
x cos y sin 
Again, the equation of the tangent PQ us   1.... ii 
2 2
h2 2k h k
From (i) and (ii), we get   6  cos  ,sin  
cos sin  3 3
 x  y 9
2 2
Hence, the perimeter of the circle is 6 units

Let, z1 and z2 are roots of the equation 3 z  3 z    0
2
74.

 z1  z2  1 and  z1 z2 
3
If 0, z1 and z2 form an equilateral triangle, then

z12  z22  z1 z2   z1  z2   3z1 z2   1  3      1
2 2
3
1
 z1 z2   3 z1  1 unit
3
   2
75. a  2b  5  a  2b  25
2 2 
 a  4 b  4a.b  25
 1  4  4cos   25  cos   5
    0,  
76.  
As f   x   3 x  1  3  x  1 x  1
2
Local maximum = -1+3-1=1 and local minimum = -3

The positive difference = 4
77. x  y  z  10
10
Number of solutions is equal to the coefficient of x in the expansion of
3
 1  x6 
x  x 2
 x  .......  x
3

6 3
x 
3

 1 x 
The coefficient of x in the expansion of 1  x
7
  1  x 
6 3 3
 1  3x 6  1  x 
3
 7 31C7  3  131 C1 
 9C7  3  3 C1   36  9  27
Let the slope of the tangent be k. then the equation of the tangent to x  12 y is
2
78.
kx  y   3 k 2 .
Le the slope of the normal be m, then the equation of the normal to y  4 x is y  mx  2m  m .
2 3
 k  m and 2m  m3  3k 2
 m  m 2  3m  2   0  m  1, 2
M = 0 is rejected
  1   2
79. We have, tan tan   1  tan tan 
2 2 3 2 2 3
   
tan  tan tan tan
    2 2  2 2
Now, tan  
 2  1  tan  tan  2
2 2 3
    3   3  1 
 tan     tan  tan   tan   3tan 
 2  2 2 2 2 2 2 2
3  1  
 tan  cot  cot
2 2 2 2 2
     1     
 tan    cot   1  tan   .tan  0
 2  2 tan   2  2
2
     
       
 2  2 2
Let, x  t  2 xdx  dt
2
80.
1 t 1 t
 
2
I  e sin t  cos t dt  e .sin t  c
2
{As, e  f  x   f   x   dx  e . f  x   c }
x x
1  cos 4 x 1  cos x  1  cos3 x  cos 2 x  cos x 

lim  lim
  x 0 5  sin 2 x cos x 
81.
x 0 5 sin 2 x cos x
2sin 2
x
2
1  cos x  cos 2 x  cos3 x  1 1  cos x  cos x  cos x  2
2 3
lim  lim 
x 0  x x x 0 2
 x
2
5
 2sin cos  5cos x  cos  5cos x
 2 2  2
Let, f  x   ax   a  2  x  2
2
82.
 f  0   2 and f  1  0
Since, the quadratic expression is negative for exactly two integral values
 f 1  0 and f  2   0
 a  a  2  2  0 and 4a  2a  4  2  0
 a  2 and a  1
 a  1,2 
Hence, the integral value of a  1
Total cases  C5  C1 (there are 5ways to choose a chairperson)
9 5
83.
4
Favourable cases = 3 men can be chosen is C2 ways and there are 3 ways to choose the
chairperson.
Total number of favourable ways  C3  C2  3
5 4
5
C3  4C2  3 10  6  3 2
Required probability =   
9
C5  5 126  5 7
84.
The equation of the family is  x  a   y  a , which has only one arbitrary constant
2 2 2
 the order will be 1.

Hence, the maximum value of y  kcosx  cos x is ‘1’.
85.
 1 1 
Let A   t ,  and B   , t  { both curves are symmetric about line y = x}
 t t 
2 2
 1 1 
Then,  AB    t      t   14
2
 t t 
 1 1
 2  t 2  2   14  4  t 2  2  9
 t  t
1
Now,  OA   t  2  9  r  9  t  3
2 2 2
t
14
 OF   9   5.5
2
4
 1
86. Case I : x  2 y  3  0 and  x  y  2  0 are parallel      0.5
1 2
 1
Case II: 3 x  y  1  0 and  x  y  2  0 are parallel     3
3 1
Case III: x  2 y  3  0 , 3 x  y  1  0 and  x  y  2  0 are concurrent
 1 2
 1 2 3  0  5  8  14  0    1.2
3 1 1
Hence, the product of all the values of    0.5  3  1.2  1.8
  
Let tan x  t  t   1,1 x    ,
 4 4 
87.
 f  t   t 3  3t 2  1
 f   t   3t 2  6t  3t  t  2 
 f  1  1  3  1  3
f 1  1  3  1  1
f  0  1
Least value = -3
Local maximum value = 1
 The positive difference = 4
 a11 a12 a13   a12 a13 
 a11 k2 
88.

Let, A  a21 a22 a23  then 
k

  B   ka21 a22
a23 
 a31 a32 a33   k 
k 2a a33 
 31 ka32
 
a12 a13
a11
k k2
a23
B  ka21 a22
k
k 2 a31 ka32 a33
k 2 a11 ka12 a13 a11 a12 a13
1
B  3 k 2 a21 ka22 a23  a21 a22 a23  A   A  B  0
k 2
k a31 ka32 a33 a31 a32 a33
On comparison,     0
Consider 1  x   C0  C1 x  C2 x  ......  Cn x
n 2 n
89.
x2 x3 x n1
  1  x  dx  C0 x  C1  C2  ......  Cn
x n
0 2 3 n 1
1  x   1  C x  C x 2  C x3  ....  C x n1
n 1

n 1 n 1
0 1 2 n
2 3
Also,  1  x   C0 x  C1 x  C2 x  ....  Cn
n n n 1 n2
n 1 C02 C12 C22 Cn2

Multiply and compare x    .....   Coefficient of x n1 in
1 2 3 n 1
 1  x n1  1   x  12 n1   x  1n
 x  1  
n
n  1  n 1
 
2 n 1
Cn1  2n  1!
Required coefficient =    1
n 1   n  1!
2
90.
Let AB = 40 and CD = 25 be the two poles.

l
AC = is the length of the wire.
CE is the horizontal through C and ACE  
AE
 sin 
l
15 30 2 3 1
l    sin  
sin  3 1  
2 2
Hence, 2 sin   0.35

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Sec: SR.

IIT_COSC GTM-5 Date: 10-02-21

Net force along groove = n r sin 

SR.IIT_N-SC Page. No. 2

Believe you can and you’re halfway there.

Here H    24 cal/s, L = 2m = 200cm

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SR.IIT_N-SC Page. No. 4

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SR.IIT_N-SC Page. No. 5

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SR.IIT_N-SC Page. No. 6

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Then electron density n0  2   2   ni2

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SR.IIT_N-SC Page. No. 8

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23. Current in tangent galvanometer

From Eq.(i), we get

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L  L T  L total  L1  L2

SR.IIT_N-SC Page. No. 11

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37. The reactions are as follows

SR.IIT_N-SC Page. No. 12

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Na2  B4O5  OH 4  .8 H 2O  2 HCl  2 NaCl  4 H 3 BO3  5 H 2O

42. NaCl gives following reaction as follows

SR.IIT_N-SC Page. No. 13

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Loss of H 2O occurs with simultaneous migration of the trans-R’.

45. NO2 is an odd electron molecule so NO2 is paramagnetic

The dimer, N 2O4 , has no unpaired electron so it is diamagnetic.

46. This is an example of oxymercutation –demercuration and gives alcohol corresponding to

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2-Buranone will show tautomerism

Total enol products = 1 + 2 = 3

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56. Bithional has 4 Cl-atoms

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 r12  4r1r2  r22  0

Let f  x   cot x  x  4   cos 1 x 2  4 x  1

Which is only possible if x  4 x  0  x  0, 4

Also these values satisfies the equation.

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Hence, the required area is

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Hence, the perimeter of the circle is 6 units

Local maximum = -1+3-1=1 and local minimum = -3

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1  cos 4 x 1  cos x  1  cos3 x  cos 2 x  cos x 

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 the order will be 1.

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