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SAFETY DATA SHEET

PROSOLV WCI8062
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation PROSOLV WCI8062
of the mixture
Date of first issue 22/01/2016
Version number 1.2
Revision date 17/09/2018
Supersedes date 29/04/2018
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Corrosion inhibitor
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
SUEZ Water Technologies & Solutions Middle East FZE
P.O. Box 261939
Plot S20143
Jebel Ali Free Zone South
Dubai , UAE
Tel : +971 48101700 or +971 48101742
Fax : +971 4 224 7922
e-mail : emea.productregulatory.wts@suez.com

1.4. Emergency telephone number

Multilingual emergency number (24/7)

Europe, Middle East, Africa (Europe and English language

speaking countries):
+44(0)1235 239670
Middle East & Africa (speaking Arabic):
+44(0)1235 239671

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 as amended
Health hazards
Skin corrosion/irritation Category 1B H314 - Causes severe skin burns
and eye damage.
Serious eye damage/eye irritation Category 1 H318 - Causes serious eye
damage.
Skin sensitisation Category 1A H317 - May cause an allergic skin
reaction.
Environmental hazards
Hazardous to the aquatic environment, acute Category 1 H400 - Very toxic to aquatic life.
aquatic hazard
Hazardous to the aquatic environment, Category 2 H411 - Toxic to aquatic life with
long-term aquatic hazard long lasting effects.
2.2. Label elements

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PROSOLV WCI8062
Label according to Regulation (EC) No. 1272/2008 as amended
Contains: Alkyl dimethyl benzyl ammonium chloride, Fatty acids, C18 unsat, reaction products with
diethylenetriamine, Thioglycolic acid
Hazard pictograms

Signal word Danger

Hazard statements
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE/doctor.
Storage Not available.
Disposal Not available.
Supplemental label information None.
2.3. Other hazards None known.

SECTION 3: Composition/information on ingredients

Mixtures
Chemical description Aqueous acidic solution of organic compounds
Chemical name % CAS-No. / EC REACH Registration No. INDEX No. Notes
No.

Acetic Acid < 10 64-19-7 01-2119475328-30 607-002-00-6 #

200-580-7
Classification: Flam. Liq. 3;H226, Skin Corr. 1A;H314, Eye Dam. 1;H318 B

Alkyl dimethyl benzyl ammonium 3-<5 68424-85-1 - - M=10

chloride 270-325-2
Classification: Acute Tox. 4;H302, Skin Corr. 1B;H314, Aquatic Acute 1;H400, Aquatic
Chronic 1;H410

Thioglycolic acid 1-<3 68-11-1 01-2119494933-24 607-090-00-6

200-677-4
Classification: Acute Tox. 3;H301, Acute Tox. 3;H311, Skin Corr. 1B;H314, Acute Tox. 3;H331

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UVCB substance(s)
Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes

Fatty acids, C18 unsat, reaction 2,5 - 5 1226892-43-8 01-2119487013-43 - M=10

products with diethylenetriamine 629-715-1

Classification: Skin Corr. 1C;H314, Skin Sens. 1A;H317, Aquatic Acute 1;H400, Aquatic Chronic 1;H410

The classification of the above substance(s) is given, including the hazard class, category code and hazard statements which are
assigned in accordance with their physicochemical, health and environmental hazards. Please refer to section 16 where the full text of
each relevant H-statement is listed.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Move to fresh air.
Get medical attention immediately.
Skin contact Take off immediately all contaminated clothing.
Wash off immediately with plenty of water for at least 15 minutes.
Get medical attention immediately.
Eye contact Rinse immediately with plenty of water for at least 15 minutes.
Get medical attention immediately.
Ingestion Rinse mouth.
Do not give anything to eat or drink.
Do not induce vomiting.
Call a physician or poison control centre immediately.
4.2. Most important symptoms Corrosive effects.
and effects, both acute and May cause allergic skin reaction.
delayed
4.3. Indication of any Not available.
immediate medical attention
and special treatment needed

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing Dry chemical, CO2, water spray or regular foam.
media
Unsuitable extinguishing None.
media
5.2. Special hazards arising Oxides of carbon and nitrogen evolved in fire.
from the substance or mixture
5.3. Advice for firefighters
Special protective Self contained breathing apparatus. (CEN : EN 137)
equipment for firefighters Protective clothing (CEN : EN 469)
Protective gloves (CEN : EN 659)
Helmet (CEN : EN 443)
Special fire fighting Use standard firefighting procedures and consider the hazards of other involved materials.
procedures Prevent spillage and fire-fighting water from entering in public sewers or the immediate
environment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Wear protective clothing, gloves and safety goggles.
personnel
For emergency responders Use personal protection recommended in Section 8 of the SDS.

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6.2. Environmental precautions Prevent from entering sewers or the immediate environment.
Do not empty into drains, dispose of this material and its container to hazardous or special waste
collection point.
6.3. Methods and material for Absorb onto inert material and dispose of according to Hazardous Waste Regulations.
containment and cleaning up Remove small spills with plenty of water.
6.4. Reference to other Please refer also to section no. 8 'Exposure controls' for further information.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe Avoid contact with skin and eyes.
handling Normal chemical handling.
Ensure good ventilation.
7.2. Conditions for safe Reasonable and safe chemical storage.
storage, including any Store in cool, well ventilated area.
incompatibilities Store containers closed when not in use.
7.3. Specific end use(s) Only for professional and industrial users

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits
UAE. OELs. Maximum Allowable Limits for Air Pollutants in Working Areas [Law to Protect the Air from Pollution,
Resolution of the Cabinet of Ministers No. 12 of 2006]
Components Type Value
Acetic Acid (CAS 64-19-7) STEL 37 mg/m3
15 ppm
TWA 25 mg/m3
10 ppm
Thioglycolic acid (CAS TWA 3,8 mg/m3
68-11-1)
1 ppm
US. ACGIH Threshold Limit Values
Components Type Value
Acetic Acid (CAS 64-19-7) STEL 15 ppm
TWA 10 ppm
Thioglycolic acid (CAS TWA 1 ppm
68-11-1)
EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU
Components Type Value
Acetic Acid (CAS 64-19-7) STEL 50 mg/m3
20 ppm
TWA 25 mg/m3
10 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Not available.
procedures
Derived no effect levels (DNELs)
Workers
Components Value Assessment factor Notes
Acetic Acid (CAS 64-19-7)
Long-term, Local, Inhalation 25 mg/m3 1
Short-term, Local, Inhalation 25 mg/m3 1
Thioglycolic acid (CAS 68-11-1)
Long-term, Systemic, Dermal 1,6 mg/kg 100
Long-term, Systemic, Inhalation 1,13 mg/m3 25
Short-term, Local, Inhalation 4,5 mg/m3 62

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Short-term, Systemic, Inhalation 4,5 mg/m3 62,5
UVCB substance(s) Value Assessment factor Notes
Fatty acids, C18 unsat, reaction products with diethylenetriamine (CAS 1226892-43-8)
Long-term, Systemic, Dermal 0,42 mg/kg 72
Long-term, Systemic, Inhalation 2,9 mg/m3 18
Predicted no effect concentrations (PNECs)
Components Value Assessment factor Notes
Acetic Acid (CAS 64-19-7)
Freshwater 3,058 mg/l 100
Intermittent releases 30,58 mg/l 10
Marine water 0,3058 mg/l 1000
Sediment (freshwater) 11,36 mg/kg
Sediment (marine water) 1,136 mg/kg
Soil 0,47 mg/kg
STP 85 mg/l 10
Thioglycolic acid (CAS 68-11-1)
Freshwater 0,027 mg/l 1000
Intermittent releases 0,27 mg/l 100
Marine water 0,0027 mg/l 10000
Sediment (freshwater) 0,009 mg/kg
Sediment (marine water) 0,0009 mg/kg
Soil 0,0053 mg/kg
STP 0,5 mg/l 10
UVCB substance(s) Value Assessment factor Notes
Fatty acids, C18 unsat, reaction products with diethylenetriamine (CAS 1226892-43-8)
Freshwater 25,4 µg/l 10
Intermittent releases 2,94 µg/l 100
Marine water 2,54 µg/l 100
Secondary poisoning 2 mg/kg 300
Sediment (freshwater) 99,4 mg/kg 1
Sediment (marine water) 9,94 mg/kg 1
Soil 9,44 mg/kg 100
STP 5,57 mg/l 10
Exposure guidelines
Belgium OELs: Skin designation
Thioglycolic acid (CAS 68-11-1) Can be absorbed through the skin.
8.2. Exposure controls
Appropriate engineering Adequate ventilation to maintain air contaminants below exposure limits.
controls Eye wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles.
Face shield.
CEN : EN 166
Skin protection
- Hand protection Gauntlet type neoprene gloves (Protection against unintentional short-term contact)
Gauntlet type nitrile gloves (Protection against unintentional short-term contact)
Gauntlet type butyl gloves (Protection against unintentional short-term contact)
CEN : EN 374-1/2/3/4; EN 420
- Other Chemical resistant apron.
CEN : EN ISO 13688; EN ISO 6530; EN ISO 6529; EN 14605
Respiratory protection In case of insufficient ventilation, use a breathing mask with filter type: A2-P2
CEN : EN 140; EN 14387
Thermal hazards Not available.
Environmental exposure Prevent from entering in public sewers or the immediate environment.
controls Do not empty into drains, dispose of this material and its container to hazardous or special waste
collection point.
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Colour Yellow to amber
Physical state Liquid
Odour Slight acetic
Odour threshold Not available.
pH (concentrated product) 3,5
Melting point/freezing point -4 °C
Initial boiling point and boiling 104 °C
range
Flash point > 100 °C P-M(CC)
Evaporation rate < 1 (Ether = 1)
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapour pressure 18 mm Hg
Vapor pressure temp. 21 °C
Vapour density < 1 (Air = 1)
Relative density 1,01
Relative density temperature 21 °C
Solubility
Solubility (water) 100 %
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not applicable.
Decomposition temperature Not available.
Viscosity Not applicable.
Viscosity temperature 21 °C
Explosive properties Not available.
Oxidising properties Not available.
9.2. Other information
Pour point -1 °C
VOC 2 % (Estimated)

SECTION 10: Stability and reactivity

10.1. Reactivity Not available.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous Not applicable.
reactions
10.4. Conditions to avoid No special requirement.
10.5. Incompatible materials Avoid contact with strong bases.
10.6. Hazardous Oxides of carbon and nitrogen evolved in fire.
decomposition products

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SECTION 11: Toxicological information
11.1. Information on toxicological effects
Product Test results
PROSOLV WCI8062 (Mixture) Acute Dermal LD50 Rabbit: > 5000 mg/kg (Calculated
according to GHS additivity formula)
Acute Inhalation LC50 Rat: > 20 mg/l 4 hours (Calculated
according to GHS additivity formula)
Acute Oral LD50 Rat: 2159 mg/kg (Calculated according to
GHS additivity formula)
Components Test results
Acetic Acid (64-19-7) Acute Dermal LD50 Rabbit: 1060 mg/kg
Acute Inhalation LC50 Rat: 11,4 mg/l 4 hour
Acute Oral LD50 Rat: 3310 mg/kg
Thioglycolic acid (68-11-1) Acute Dermal LD50 Rabbit: 848 mg/kg
Acute Inhalation LC50 Rat: 1,1 mg/l 4 Hours
Acute Oral LD50 Rat: 73 mg/kg
Alkyl dimethyl benzyl ammonium chloride (68424-85-1) Acute Dermal LD50 Rabbit: 3340 mg/kg
Acute Oral LD50 Rat: 344 mg/kg
Acute toxicity Not classified.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye Causes serious eye damage.
damage/irritation
Respiratory or skin May cause an allergic skin reaction.
sensitisation
Specific target organ toxicity - Not classified.
repeated exposure
Specific target organ toxicity - Not classified.
single exposure
Carcinogenicity Not classified.
Germ cell mutagenicity Not classified.
Reproductive toxicity Not classified.
Information on likely routes of exposure
Ingestion Causes digestive tract burns.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
Inhalation May cause irritation to the respiratory system.
May cause drowsiness and dizziness.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Symptoms Not available.
Aspiration hazard Not classified.
Mixture versus substance None known.
information
Other information Not available.

SECTION 12: Ecological information

12.1. Toxicity
Components Species Test results
Alkyl dimethyl benzyl ammonium chloride (CAS 68424-85-1)
EC50 Active Sludge 10 mg/l
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Components Species Test results
Daphnia magna 0,016 mg/l, 48 hour
Aquatic
Fish LC50 Rainbow trout 0,93 mg/l, 96 hour

12.2. Persistence and degradability

No data available
12.3. Bioaccumulative potential Not available.
Partition coefficient
n-octanol/water (log Kow)
Acetic Acid -0,17
Thioglycolic acid 0,09
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
12.5. Results of PBT Not a PBT or vPvB substance or mixture.
and vPvB
assessment
12.6. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Contaminated packaging According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 15 01 10

15 Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not
otherwise specified.
15 01 Packaging (including separately collected municipal packaging waste).
15 01 10 Packaging containing residues of or contaminated by dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.
Disposal methods/information According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 16 03 05

16 Wastes not otherwise specified in the list.
16 03 Off-specification batches and unused products.
16 03 05 Organic wastes containing dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.

SECTION 14: Transport information

ADR
14.1. UN number UN3265
14.2. UN proper shipping Corrosive liquid, acidic, organic, n.o.s. (Fatty acids, C18 unsat, reaction products with
name diethylenetriamine, Alkyl dimethyl benzyl ammonium chloride, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards Yes
Tunnel restriction code (E)
14.6. Special precautions Not available.
for user
RID
14.1. UN number UN3265
14.2. UN proper shipping Corrosive liquid, acidic, organic, n.o.s. (Fatty acids, C18 unsat, reaction products with
name diethylenetriamine, Alkyl dimethyl benzyl ammonium chloride, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
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14.4. Packing group II

14.5. Environmental hazards Yes
14.6. Special precautions Not available.
for user
ADN
14.1. UN number UN3265
14.2. UN proper shipping Corrosive liquid, acidic, organic, n.o.s. (Fatty acids, C18 unsat, reaction products with
name diethylenetriamine, Alkyl dimethyl benzyl ammonium chloride, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards Yes
14.6. Special precautions Not available.
for user
IATA
14.1. UN number UN3265
14.2. UN proper shipping Corrosive liquid, acidic, organic, n.o.s. (Fatty acids, C18 unsat, reaction products with
name diethylenetriamine, Alkyl dimethyl benzyl ammonium chloride, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards Yes
ERG Code Not available.
14.6. Special precautions Not available.
for user
IMDG
14.1. UN number UN3265
14.2. UN proper shipping Corrosive liquid, acidic, organic, n.o.s. (Fatty acids, C18 unsat, reaction products with
name diethylenetriamine, Alkyl dimethyl benzyl ammonium chloride, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards
Marine pollutant Yes
EmS No. F-A, S-B
14.6. Special precautions Not available.
for user
14.7. Transport in bulk This substance/mixture is not intended to be transported in bulk.
according to Annex II of
MARPOL and the IBC Code
ADN; ADR; IATA; IMDG; RID

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Marine pollutant

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 143/2011 Annex XIV Substances Subject to Authorisation
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Acetic Acid (CAS 64-19-7)
Thioglycolic acid (CAS 68-11-1)
National regulations Not available.
15.2. Chemical safety Not available.
assessment
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)

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Country(s) or region Inventory name On inventory (yes/no)*
Europe European List of Notified Chemical Substances (ELINCS) No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

SECTION 16: Other information

List of abbreviations
COD: Chemical Oxygen Demand
IATA: International Air Transport Association
CAS: Chemical Abstract Service.
EC-No: European Commission Number
CLP: Classification, Labeling and Packaging REGULATION (EC) No 1272/2008 on classification,
labeling and packaging of substances and mixtures.
CEN: European Committee for Standardization (Comité Européen de Normalisation).
TWA: Time Weighted Average.
STEL: Short-term Exposure Limit.
LD50: Lethal Dose 50%.
LC50: Lethal Concentration 50%.
EC50: Effective Concentration 50%.
NOEL: No observed effect level.
BOD: Biochemical oxygen demand.
TOC: Total Organic Carbon.
ADR: European agreement concerning the international carriage of dangerous goods by road
(Accord européen relatif transport des merchandises dangereuses par route).
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways (Accord européen relatif au transport international des marchandises dangereuses
par voies de navigation intérieures).
IMDG Code: International Maritime Dangerous Goods Code.
RID: Regulations concerning the international carriage of dangerous goods by rail (Règlement
International concernant le transport de marchandises dangereuses par chemin de fer).
References Safety data sheets of raw materials.
Information on evaluation The physical, health and environmental hazards of this mixture are assessed by applying the
method leading to the classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation
classification of mixture (EC) No 1272/2008 (CLP).
Full text of any H-statements
not written out in full under
Sections 2 to 15 H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Revision information SECTION 3: Composition/information on ingredients: Composition comments
SECTION 8: Exposure controls/personal protection: Appropriate engineering controls
Physical & Chemical Properties: Multiple Properties
SECTION 16: Other information: Further information
HazReg Data: Europe - EU
GHS: Classification
Training information Provide training on safe handling while considering the type of application and exposure scenarios.
Based on EC Directive / (EC) No 1907/2006 (REACH)
Regulations (EC) No 1272/2008
(EU) 2015/830
(EU) No 1357/2014
Further information Correction in Section: 7,8,9,16
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