1 Introduction 1-1

1 Introduction

The development of equations of state for the description of the properties of fluids and fluid mixtures began
with the 1873 doctoral thesis of J.D. van der Waals. Since that time new experiments have revealed that the
phase behaviour of fluid mixtures is of much greater complexity than was then thought, and has proved to be
very difficult to predict. While great advances have been made in the development of thermodynamic
equations of state, in statistical mechanical models, and in machine simulation techniques, it is still far from
easy to accurately predict the full phase behavior of many binary mixtures.
Among the thermodynamic properties of fluid mixtures, heats of mixing are particularly important for
understanding molecular interactions because they are related to the structure and the energy of interaction
of the molecules. Heats of mixing are also important to the design of industrial process equipment, such as
refrigerators, distillation apparatus, supercritical fluid technology, heaters and heat exchangers.
The volumes in this series deal with the change of energy which accompanies the formation of a multi-
component gas, liquid, or supercritical fluid system, usually from its pure components. The process of
formation is called mixing, solution or dilution. The difference between a mixing process and a solution or
dilution process is that in the former case all components involved in the process are treated equivalently,
while in the latter, a distinction is made between a group of components, named solutes, and another group
of components, named solvents. The solvent may be a pure component (pure solvent) or a mixture (mixed
solvent).
An important function of the measurements collected in these volumes is that they provide a database of
carefully selected experimental heats of mixing and solution data which can be used for the testing and
development of new theoretical models and correlations, and process design software.
The first volume in this series, Vol. IV/10A (04GRO1), dealt with the mixing of two pure liquid
components to form a binary homogeneous (single-phase) liquid system or a heterogeneous (two-phase)
liquid-liquid system.
The present, second volume in this series, Vol. IV/10B, deals with:
a) the mixing of two pure gases, near-critical liquids, or supercritical fluids to form a binary
homogeneous (single-phase) or a heterogeneous (two-phase) liquid-liquid or fluid-fluid system
b) the solution of a pure gas in a pure liquid solvent to form a binary homogeneous (single-phase)
liquid system (solution).
All the components are well-defined pure substances (nonelectrolytes). Only heats of mixing and solution
data obtained by direct calorimetric measurements are considered.
The aim of the introduction to this volume is to give sufficient information to show how heats of mixing
and solution can be measured, how the data can be correlated, how it can be analyzed, and how the
measurements at high pressures, particularly in the near-critical region, can be understood. Only a brief
description of some of the methods and models which can be used to analyze the experimental data is given,
a more extensive account is contained in the IUPAC publication Experimental Thermodynamics, vol. V,
Equations of State for Fluids and Fluid Mixtures (00SEN1).
This introduction is divided into six main parts.
1.1 Fundamental principles and basic relations, which establish the notion of the heat of mixing as a
thermodynamic function;
1.2 Calorimetric measurement of the enthalpy of solution of gases in liquids;
1.3 Principles of heat of mixing calorimetry and types of calorimeter;
1.4 Analysis of excess enthalpies of gas mixtures at low pressures;
1.5 Analysis of enthalpies of mixing of fluids at high pressures;
1.6 Correlation of experimental data.

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1.1 Fundamental principles and basic relations

1.1.1 Basic thermodynamic equations

Each component involved in a mixing or solution process is assumed to be a molecular substance

(nonelectrolyte), organic (i.e. containing carbon) or inorganic material. Each substance has a well-defined
relative molar mass Mr, corresponding to the natural isotopic abundances of the constitutive elements.
A mixture may be (1) of two components in the same phase, gas, liquid, or supercritical fluid, or (2) of
components in different phases, gas + liquid, or supercritical fluid + liquid. For a gas or supercritical fluid +
liquid system the liquid phase can be called the solvent, the gas can be called the solute, and the process of
dissolution of the gas or supercritical fluid into the liquid can be referred to as a solution process rather than
a mixing process.
The composition of a mixture is expressed in terms of the mole fractions xi (i = 1 or 2) of the component i:
xi = ni / Σ ni (1.1)
where ni is the amount (number of moles) of substance i and Σ ni the total amount (number of moles) of
substance in the mixture.
The composition of a solution is expressed in terms of the mole fraction x1 of the solute (component 1).
Extensive thermodynamic quantities are always expressed as molar quantities, i.e. the extensive quantity
divided by the total amount (number of moles) of substance: molar volume V, molar internal energy U,
molar enthalpy H, molar entropy S, molar Gibbs energy G, molar Helmholtz energy A, etc.
These molar quantities are inter-related by basic thermodynamic equations, the most important being
those which define H, A, and G:
H = U + PV (1.2)
A = U – TS (1.3)
G = H – TS (1.4)
where P is the pressure and T is the temperature. Of particular importance are the temperature and pressure
derivatives of G and H:
S = − (∂ G / ∂T )p (1.5)

V = (∂ G / ∂P )T (1.6)

Cp = (∂ H / ∂T )p (1.7)

φ = (∂ H / ∂P )T (1.8)

Here Cp is the isobaric heat capacity and φ is the isothermal enthalpy-pressure coefficient, often called the
isothermal Joule-Thomson coefficient. This quantity is related to the molar volume V through the equation:
(∂ H / ∂P )T = V − T (∂ V / ∂T )p (1.9)

Another important relationship is that between H and G which is given by the Gibbs-Helmholtz equation.
This equation can be written in two forms
H = G − T (∂ G / ∂ T ) p and H = −T 2 [∂(G / T ) / ∂ T ]p (1.10)

Equations (1.2) to (1.10) hold for both pure substances and mixtures. In the case of mixtures the total molar
quantities can be expressed in terms of partial molar quantities (00SEN1). In particular the molar Gibbs
energy G of a mixture is the sum of the partial molar Gibbs energies (chemical potentials) µi of the
components i multiplied by their respective mole fractions xi:

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G= ∑x µi
i i (1.11)

Similarly the enthalpy H of a mixture is the sum of the partial molar enthalpies Hi of the components i
multiplied by their respective mole fractions xi:

H= ∑x Hi
i i (1.12)

1.1.2 Residual functions

Residual functions χR, residual molar volume VR, molar enthalpy HR, molar entropy SR, molar Gibbs energy GR,
and molar Helmholtz energy AR, are defined as the property of the real fluid χ minus the corresponding property
of the ideal gas χid under the same conditions of temperature, pressure or volume. They can be used for the gas,
liquid and supercritical regions over the whole range of pressures and temperatures. They are best defined in
terms of the residual Helmholtz energy:
A R (V , T ) = −kT ln(QN / V N ) (1.13)

where QN is the configurational partition function of the system containing N molecules. Residual functions χR
are defined (82ROW1) by the general equation:
∞
⎧⎪⎛ ∂ χ ⎞ ⎛ ∂ χ id ⎞ ⎫⎪
χ R (V , T ) = − ∫ ⎨⎜⎜ ⎟⎟ − ⎜⎜ ⎟⎟ ⎬ dV (1.14)
V ⎪⎩⎝ ∂ V ⎠ T ⎝ ∂ V ⎠ T ⎪⎭
which follows from Eq. (1.13) by factorizing the total partition function. In the case of the Helmholtz energy Eq.
(1.14) yields:
∞ ∞
AR (V , T ) = ∫ ( P − Pid ) dV = ∫ ( P − RT / V ) dV (1.15)
V V

The route to the residual enthalpy now follows via the residual internal energy, since:
U R = A R − T (∂ A R / ∂ T )V (1.16)

hence:
∞
⎧⎪ ⎛ RT ⎞ ⎛∂P⎞ ⎛ RT ⎞⎫⎪
∞
⎧⎪ ⎛ ∂ P ⎞ ⎫⎪
U R (T , V ) = ∫ ⎨ P − ⎜ ⎟ − T ⎜⎜ ⎟⎟ + ⎜ ⎟⎬ dV = ∫ ⎨ P − T ⎜⎜ ⎟⎟ ⎬ dV (1.17)
V ⎪⎩ ⎝ V ⎠ ⎝ ∂ T ⎠V ⎝ V ⎠⎭⎪ V ⎪⎩ ⎝ ∂ T ⎠ V ⎪⎭

It follows from Eq. (1.2) that:

∞
⎧⎪⎛ ∂ U ⎞ ⎛ ∂ P ⎞ ⎫⎪ ∞
⎧ ⎛ ∂ P ⎞⎫
H R (T , V ) = − ∫ ⎨⎜⎜ ⎟⎟ + P + V ⎜⎜ ⎟⎟ ⎬ dV = ∫ ⎨ P − T ⎜⎜ ⎟⎟⎬ dV + PV − RT (1.18)
V ⎪ ⎩⎝ ∂ V ⎠ ⎝ ∂ V ⎠ T ⎭⎪ V ⎩ ⎝ ∂ T ⎠⎭
Calculation of HR is now possible provided that an equation of state is available in the form P = f(V, T), as is
often the case. It is sometimes more useful to express HR as a function of P and T rather than V and T. This can
be done using:

⎛∂ H ⎞ ⎛∂ G ⎞ ⎛ ∂ 2G ⎞ ⎛∂ V ⎞
⎜⎜ ⎟⎟ = ⎜⎜ ⎟⎟ − T ⎜⎜ ⎟⎟ = V − T ⎜⎜ ⎟⎟ (1.19)
⎝∂ P ⎠T ⎝ ∂ P ⎠T ⎝ ∂ T ∂ P ⎠ ⎝∂ T ⎠p

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which leads to:

P
⎧⎪ ⎛ ∂V ⎞ ⎫⎪
H R (T , P) = ∫ ⎨V − T ⎜⎜ ⎟⎟ ⎬ dP (1.20)
0⎪ ⎩ ⎝ ∂T ⎠ P ⎪⎭
For pure substances V is the molar volume of the pure fluid, and for a mixture of specified composition V is the
molar volume of the mixture at mole fraction x1. An enthalpy-pressure diagram for hexane is shown in Fig. 6 of
reference (85WOR1). The length of the vertical lines in the figure corresponds to the enthalpy of vaporization,
and these lines are at the saturated vapor pressure. A residual enthalpy-pressure diagram can be constructed by
subtracting the ideal gas enthalpy from the measurements at each temperature, so that at all temperatures the
residual enthalpies are zero at zero pressure, and at finite pressures the residual enthalpies are negative
quantities.

1.1.3 Excess functions

An excess property of a fluid mixture is defined as the difference between the property of the real mixture and
the same property of an ideal hypothetical mixture of the same composition. For an ideal mixture the chemical
potential µi of component i is given by the relation (82ROW1):

µ i = µ i$ + RT ln xi (1.21)

where µ i$ is the chemical potential of component i in a defined reference state, usually its pure state at the
temperature and pressure of the mixture. The molar Gibbs energy of the ideal mixture G id is then given by

G id = ∑x µ
i
$
i i + RT ∑ x ln x
i
i i (1.22)

The molar enthalpy of the ideal mixture H id can be obtained using Eq. (1.10). The RT term in Eq. (1.22)
disappears and H id is:

H id = ∑x Hi
i
$
i (1.23)

where H i$ is the molar enthalpy of pure component i.

To describe the non-ideal behaviour of the mixture the mole fraction xi can formally be replaced by the
activity ai defined by:
ai = xiγ i (1.24)

where γi is the activity coefficient of component i. For a non-ideal mixture the chemical potential µi of
component i can be written:

µ i = µ i$ + RT ln xi + RT ln γ i (1.25)

Excess functions are defined as the difference between the particular function of the real mixture and the
corresponding function of the ideal mixture. The excess chemical potential µ iE and the molar excess Gibbs
energy GE are given by

µiE = RT ln γ i (1.26)

GE = ∑x µ
i
i i
E
(1.27)

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The molar excess enthalpy HE is given by

[( ) ]
H E = −T 2 ∂ G E / T / ∂ T p (1.28)

Equations similar to Eqs. (1.2) – (1.8) can be written for other thermodynamic properties. They are of exactly the
same form as those which relate the pure substance thermodynamic functions. The most important are the
equations:

GE = H E −T S E (1.29)

S E = − (∂ G E / ∂ T ) p (1.30)

V E = (∂ G E / ∂ P ) T (1.31)

C pE = (∂ H E / ∂ T ) p (1.32)

φ E = (∂ H E / ∂ P)T (1.33)

Here C pE is the excess molar isobaric heat capacity and φ E is the excess molar isothermal enthalpy-pressure
coefficient, (isothermal Joule-Thomson coefficient), which is an important quantity for analyzing the heat of
mixing of gases. This quantity is related to the excess molar volume VE through the useful equation:

(∂ H E / ∂ P ) T = V E − T ( ∂ V E / ∂ T ) p (1.34)

1.1.4 Experimentally accessible thermodynamic quantities

Thermodyamic properties of fluids and fluid mixtures are mostly obtained by measuring volumetric properties,
thermal properties or phase equilibrium properties.
For pure substances volumetric properties include measurement of the molar volume V or the density ȡ as a
function of the pressure P and the temperature T, or of the compressibility, or of the expansivity. In the gaseous
phase measurements of the second and third virial coefficients B and C are also important. For phase equilibria,
measurement of the vapor pressure as a function of temperature is of fundamental importance. Thermal
properties include calorimetric measurements of the molar enthalpy H or the molar energy U, or the
corresponding temperature derivatives, the isobaric heat capacity Cp and the isochoric heat capacity Cv. The
enthalpy of vaporization ǻvapH is often measured using a suitable calorimeter in conjunction with measurements
of the vapor pressure. In the gaseous phase calorimetric measurements of the isothermal Joule-Thomson
coefficient φ are important, particularly for polar gases which can adsorb onto the walls of a (P,V,T) apparatus
and introduce an error in the compressibility measurements.
For mixtures it is essential to determine the phase diagram, and in particular the vapor pressure as a function
of the temperature and composition. At high temperatures the vapor pressure curves terminate at the critical
temperature Tc and critical pressure Pc. Between the critical points is a critical locus which may be concave or
convex, or even discontinuous. At temperatures below the critical, vapor and liquid are in equilibrium, and the
coexisting phases are of different composition. Vapor–liquid equilibrium (VLE) measurements yield information
about the excess molar Gibbs energy GE of the mixture, and this important quantity is related through Eq. (1.28)
to the excess molar enthalpy, HE which can be measured in a suitable calorimeter. The related quantity, the
excess molar volume VE, can be obtained from density measurements or can be determined directly using a
specially designed mixing vessel. VE is related to HE by Eq. (1.34).
For solutions gas solubility measurements yield information about the molar enthalpy of solution, Hsol which
can be measured in a suitable calorimeter.

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1.1.5 Calorimetric measurements of the heat of mixing

It is often possible to measure the excess enthalpy under isothermal (constant temperature)-isobaric (constant
pressure) conditions, either in a batch calorimeter or in a flow-mixing calorimeter. For an endothermic mixing
process the temperature can be held constant by supplying energy ǻQ via an electrical heater, sufficient to
balance the change of energy ǻU which occurs on mixing. For an exothermic mixing process energy ǻQ can be
removed from the calorimeter by means of a Peltier device or a controlled heat leak. Under isobaric conditions
the mixing process is accompanied by a change of volume ǻV, and the amount of work done against the pressure
P is:
ǻW = – PǻV (1.35)
From the First Law of Thermodynamics the amount of energy ǻQ which compensates the change of molar
energy ǻU on mixing is given by the equation:
∆Q = ∆U – ∆W (1.36)
When one mole of mixture is formed at constant pressure from the pure components ǻQ can be identified with
the change of molar enthalpy ǻH
ǻQ = ǻH (1.37)
and Eq. (1.36) can be written:
∆H = ∆U + p∆V (1.38)

ǻH is the difference between the sum of the molar enthalpies H i$ of the pure components i, and that of the
mixture H, and is given by:

∆H = H − ∑x H
i
i
$
i (1.39)

ǻH is in fact the excess molar enthalpy HE. The excess enthalpy can also be written in terms of residual
enthalpies HR, so that for a binary mixture.

H E (T , P, x) = H R (T , P, x) − x1H1R (T , P) − x2 H 2R (T , P ) (1.40)

where HR without a subscript is the residual enthalpy of the mixture. In a flow mixing calorimeter HE is given by
the equation :
HE = (Q* – W*)/F* (1.41)
where Q* is the rate of heat leak, W* is the rate of electrical energy supplied to the heater or removed by a
calibrated Peltier device, and F* is the molar flow rate. In a well designed mixing calorimeter the rate of heat
leak is small compared with the energy supplied to the heater. A good test of a flow mixing calorimeter is to
measure the heat of mixing as a function of the flow rate. If it is found to be substantially independent of the
flow rate it can be identified with the excess enthalpy. If there is a variation with flow rate, then the excess
enthalpy can be obtained by extrapolation to infinite flow rate.

1.1.6 Enthalpies of solution of gases in liquids

The molar enthalpy of solution Hsol(T,P,x1) is defined as the change of enthalpy divided by the amount n1
(number of moles) of the solute (component 1). Generally Hsol(T,P,x1) reaches a constant value for x1 → 0, the
∞
molar enthalpy of solution at infinite dilution, H sol (T , P ) . This experimentally measured quantity is usually
$
transformed to the standard molar enthalpy of solution H sol (T , P ) using the virial coefficients of the gaseous
solute.

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For many years, in the absence of calorimeters designed specifically to directly measure heats of solution of
gases in pure liquids (component 2), the only reliable source of information on enthalpies of solution and on the
corresponding heat capacity changes C P$ , sol = dH sol
$
/ dT were precision measurements of Henry coefficients
H1,2 of solute 1. In general Henry coefficients H1,2(T, Ps,2) at different temperatures T refer to different saturation
pressures Ps,2(T). Precision measurements of solubilities of gases in liquids are exemplified by the work of
Benson and Krause (76BEN1; 79BEN1) and Rettich et al. (81RET1; 00RET1). The correct thermodynamic
treatment of the data has been summarized by Wilhelm (85WIL1). From a large number of experimental Henry
coefficients for a gas-liquid system covering an extended temperature range, the temperature dependence of
H1,2(T, Ps,2) can be conveniently represented by a Taylor expansion of the form:

ln H1, 2 (T , Ps , 2 ) = Ao + A1T −1 + A2 ln T + A3T + A4T 2 (1.42)

Even more simply, the temperature dependence of H1,2(T, Ps,2) can be well fitted by a power series in T–1. Using
either of these equations Henry coefficients H1,2(T, Ps,2) can be obtained at different temperatures at the
saturation pressure Ps,2(T), and the variation of saturation pressure with temperature can be calculated using the
Clapeyron relation

dPs , 2 / dT = ( Ps , 2 / RT 2 ) (∆ vap H 2 / ∆ Z s ,2 ) (1.43)

where ∆vapH2 is the enthalpy of vaporization of pure solvent and ∆Z s ,2 = Z sV, 2 − Z sL,2 is the difference of the
compressibility factors of pure coexisting solvent vapor and liquid.
From precision measurements made over sufficiently large temperature ranges it is possible to calculate the
$
standard enthalpy of solution H sol of sparingly soluble gases at temperature T and the saturation pressure of the
solvent:
$
H sol (T , Ps ,2 ) / RT = ( H1∞ L − H1V ) / RT

= −T [d ln H1, 2 (T , Ps ,2 ) / dT ] + (V1∞ L / R) (dPs , 2 / dT ) (1.44)

where H 1∞L is the partial molar enthalpy of the gaseous solute at infinite dilution in the liquid solvent and H1
V

is the molar enthalpy of pure solute in the perfect gas reference state. The partial molar volume at infinite
dilution V1∞L is obtained by correlation methods.
Similarly the heat capacity change upon solution C P$ , sol can be calculated from the equation:

C P$ , sol (T , Ps ,2 ) / R = (C P∞,1L − C VP,1 ) / R

$
= (1/ R)[dH sol (T , Ps, 2 ) / dT ] − (1/ R)[V1∞ L − T (dV1∞ L / dT )(dPs ,2 / dT )] (1.45)

where C P∞,L1 is the partial molar heat capacity of the solute at infinite dilution in the liquid solvent and CVP,1 is the
molar heat capacity at constant pressure of the pure solute in the perfect gas reference state.
With the advent of more recent calorimeters specially designed to precisely measure the enthalpy of solution,
such as injection calorimeters (Chap. 1.2.4), direct comparison is now possible. Agreement between enthalpies
of solution measured by calorimetric methods and those calculated from solubility measurements is remarkably
good, and is often to within the combined experimental errors (see e.g. 84OLO1; 85WIL1; 86WIL1).

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1.2 Calorimetric measurement of the enthalpy of solution of gases in

liquids

Heats of solution of sparingly soluble gases in liquids have been measured using several types of batch
mixing calorimeter, isothermal displacement calorimeters, flow-mixing calorimeters, or injection
calorimeters. These heats of solution are very small, and to measure them requires specially designed
sensitive calorimeters.

1.2.1 Batch solution calorimeters

One of the first measurements of the enthalpy of solution of rare gases in liquid water was the pioneering
work of Alexander (59ALE1) using a twin calorimeter batch mixing technique. Each calorimetric unit
comprised a spherical top bulb and cylindrical bottom bulb of equal volume, the bulbs being connected by
capillary tubing and a tap. The top bulb of one of the calorimetric units (the measuring unit) was filled with
gas-free water, the bottom bulb was filled with gas, saturated with water vapor. Upon opening the tap, the
liquid displaced the gas and the solution occurred to the extent of about one third saturation as water flowed
from the capillary. Assuming that no solution occurred in the reference calorimeter, the difference in
temperature between the bottom bulbs allowed the determination of the heat change associated with the
solution of the gas. The precision of the measured heats of solution was only 10 % (ca. 1·103J mol–1).
Another batch mixing technique described by Jadot (73JAD1), used a Tian-Calvet calorimetric cell to
estimate the heat of solution of gaseous hydrocarbons in different solvents. The data were less accurate, the
measured energy change including relatively large corrections resulting from the enthalpy of vaporization of
the solvent.
Cone et al. (79CON1; 79CON2) reported a batch calorimeter for the study of the solution of gaseous
hydrocarbons or carbon dioxide in non-polar liquids (see e.g. File Numbers LB0297 and LB0295). The
calorimetric vessel was completely filled with solvent and the solute gas was added by injection using a gas-
tight syringe. The heat was measured by the compensation principle using a heater and Peltier cooler.
Because of several correction terms which had to be made the accuracy was usually not better than ca.
0.5·103J mol–1. This calorimeter prefigured the injection type calorimeters described in Chap. 1.2.4.

1.2.2 Isothermal displacement calorimeters

A high precision displacement calorimeter was reported by Battino and Marsh (80BAT1) who measured the
enthalpy of solution of several gases in nonelectrolytes such as methane in cyclohexane, (File Number
LB0408, p. 2-14). The calorimeter was a modification of that designed by Ewing et al. (70EWI1) and further
modified by Costigan et al. (80COS1). The calorimetric vessel was filled with degassed liquid so that gas
added from a burette dissolved rapidly. Temperature changes were compensated by a heater or Peltier cooler.
The estimated precision on enthalpies of solution was within a few percent, e.g. for carbon dioxide +
benzene the estimated precision was ca. 0.20·103J mol–1 (File Number LB0415), while the standard molar
enthalpy of solution at (298.15 to 318.15) K ranged from about - (8 to 9)·103J mol–1.

1.2.3 Flow mixing calorimeters

The design of industrial gas removal processes (gas purification, capture of acidic gases) needs two
important thermodynamic quantities, the solubility and the enthalpy of solution (absorption) of the gas in a
solvent. This need prompted several research groups to measure these quantities by an original use of flow-

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mixing calorimetry. Although most of the measurements concerned the absorption of gases in mixed aqueous
solvents, they are worth reporting here as examples of a special use of such calorimetric techniques.
At Brigham Young University systematic measurements were made by Christensen et al. (86CHR1),
Merkley et al. (87MER1) and Oscarson et al. (89OSC1; 89OSC2) to cite a few. Basically, these
measurements were made with flow-mixing calorimeters of the type developed by Christensen et al.
(76CHR1) (Chap. 1.2.4). More recently Mathonat et al. (97MAT1; 98MAT1) used the flow mixing
calorimeter (94MAT1) described in Chap. 1.2.4. The measurements were made in titration mode with the
liquid solvent continuously circulated at constant flow rate through the calorimeter. When a stable base-line
had been obtained, gas from a high precision pump was merged with the solvent at a tee junction in the
coiled tube mixing cell. The absorption process produced a heat effect recorded as a “plateau” signal. The
gas flow was stopped, the calorimetric signal returned to its initial base-line and another addition of gas took
place. Thus successive “plateaus” gave successive heats of solution of the gas in the solvent.

1.2.4 Injection calorimeters

In this type of calorimeter gas is injected into a continuously flowing liquid stream. Gill and Wadsö
(82GIL1) recognized the importance of direct measurements of the enthalpies of solution of slightly soluble
gases in water for the understanding of hydrophobic effects, and set the standard for these new types of
calorimeter. The main problem in constructing such calorimeters was achieving the dissolution of an
accurately known amount of gas in a time interval compatible with the stability of the calorimeter. To
achieve this, the liquid solvent was forced to flow around a gas bubble injected through a hypodermic needle
into a sophisticated mixing chamber of concentric glass or stainless steel tubes. Calibration was achieved by
means of small heaters placed close to the dissolution zone. The apparatus was tested by measuring the
enthalpies of solution of rare gases and hydrocarbons in water. The calorimetric measurements were checked
by comparison with enthalpies of solution derived from accurate gas solubilities (Chap 1.1.6). For example
∞
the molar enthalpy of solution at infinite dilution of oxygen in water was found to be H sol = – (12.06 ±
3 –1
0.02)·10 J mol at 298.15 K (File Number LB0290).
Dec and Gill (84DEC1) have developed a flow calorimeter of the heat conduction type, operated in
steady-state mode, capable of measuring heats of solution of slightly soluble gases in water. The dissolution
occurred in a heat conduction calorimeter where the power generated by the continuously dissolving gas was
detected by a semiconductor thermopile whose voltage output was proportional to the power. The major
improvement to the previous calorimeter of Gill and Wadsö (82GIL1) was the design which permitted the
water to flow radially in a thin layer beneath the gas bubble in such a way that the rate of dissolution of the
gas was roughly proportional to the thickness of the water layer. The optimal condition for a particular water
layer thickness was obtained by computer controlled feed-back of the gas flow-rate. Measurements of the
enthalpy of solution of oxygen in water used as test of the technique showed the reproducibility of
successive measurements to be within 1%. The calorimeter was used for an extensive study of the heats of
solution of several hydrocarbons in water, e.g. methane (86NAG1) (File Number LB0347), ethane
(86NAG1) (File Number LB0345) and propane (87NAG1) (File Number LB0346) in the temperature range
from (273 to 323) K, allowing the accurate determination of the heat capacity change for the dissolution
process.
Among other calorimeters specially designed to measure the heat of solution of slightly soluble gases, the
calorimeter of Hallen and Wadsö (89HAL1) has several interesting features. In batch mode it works
differentially and uses vessels which were primarily designed for microcalorimetric titrations and for
perfusion experiments. Further improvements (89HAL2) resulted in a modular system of microcalorimeter
vessels essential for measurements of slow processes like the dissolution of slightly soluble compounds. The
calorimetric system was calibrated by dissolution of oxygen in water and was tested by measuring the
enthalpies of solution of helium (File Number LB0322) and propane (File Number LB0323) in the same
solvent.

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1-10 1 Introduction

1.3 Principles of heat of mixing calorimetry and types of calorimeter

Three main types of mixing calorimeter have been used to measure excess enthalpies of binary liquid
mixtures: batch calorimeters which allow one measurement at a time, isothermal displacement calorimeters
which allow a succession of measurements, and flow mixing calorimeters which allow measurements to be
scanned over the whole composition range.
An advantage of batch and isothermal displacement calorimeters is that relatively small amounts of
material is required. A disadvantage is that they are not well suited to making measurements at high
pressures and temperatures. Flow mixing calorimeters are well suited to making measurements both at
ambient conditions and at high temperatures and pressures, and in recent years some well designed
instruments have been developed.
The design of batch and isothermal dilution calorimeters has been fully described in (94STO1) and
briefly in the previous volume in this series (04GRO1), so no further description will be given here. Recent
advances in flow mixing calorimetry have allowed measurements to be made on both liquid and gaseous
mixtures at pressures from ambient up to the critical and supercritical regions.

1.3.1 Low pressure gas mixing flow calorimetry

The first flow mixing calorimeter for the measurement of the heat of mixing of gases at pressures close to
atmospheric pressure was reported in 1969 by Wormald (69WOR1), and an improved design was reported in
1977 (77WOR1). Both calorimeters were differential, consisting of two identical calorimeters connected in
series. This arrangement ensured that Joule-Thomson and kinetic effects were cancelled out at source, and it
permitted the measurement of exothermic mixing processes. Endothermic mixing processes were measured
by adjusting the energy supplied to a heater fixed in the first mixing calorimeter until isothermal conditions
were obtained. Exothermic mixing process were measured by adjusting the energy supplied to the heater in
the second calorimeter until the temperature rise was the same as that observed in the first calorimeter.

1.3.2 High pressure gas mixing flow calorimetry

The construction of a high pressure gas phase mixing calorimeter was discussed in 1962 by Beenakker and
Coremans (62BEE1; 65BEE1). Details of the calorimeter were given by Knoester et al. (67KNO1). They
used a cylindrical flow mixing calorimeter with internal baffles and a heater wound round the outside. The
calorimeter was connected to two gas cylinders, each containing a different gas, and both gases were at the
same pressure. The two gases were allowed to flow continuously from the cylinders, and the composition of
the gas mixture was determined by the ratio of the cylinder volumes. As the pressure fell continuously a true
steady state was never achieved; the calorimeter was allowed to drift through an approximation to isothermal
conditions, and a single measurement was made at each pressure. The accuracy of the measurements was
around 5 %. Much improved flow mixing calorimeters for use on gases at high pressures were described by
Hejmadi et al. (70HEJ1; 71HEJ1), Klein et al. (69KLE1; 71KLE1) and Ba et al. (77BAL1).

1.3.3 Calorimeters for mixing fluids in the two-phase and supercritical regions

Wormald (77WOR2) described a low temperature high pressure flow mixing calorimeter which was used to
make measurements on condensed gases in the liquid, two-phase, and supercritical regions. A high
temperature version of this calorimeter was then reported (83WOR1) and used to make extensive
measurements on mixtures containing steam at pressures up to 26·106Pa and temperatures up to 698.2 K.

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 1 Introduction 1-11

Both of these calorimeters were of the reverse-flow labyrinth design which was developed (76ELL1) for
precision measurements on binary liquid mixtures. An important feature of this design is that measurements
of the heat of mixing are substantially independent of the flow rate. This is achieved by mixing the fluids
over a central electrical heater surrounded by concentric cylinders which reverse the flow, promote mixing
and smooth out temperature gradients.

1.3.4 Coiled tube high pressure flow calorimetry

Many designs of flow mixing calorimeter consist of a tee junction followed by a length of tube in which
mixing is accomplished. In the Picker isothermal flow calorimeter (69PIC1) the tube is short (15 cm) and
straight. In the calorimeter of Christensen et al. (76CHR1) the tube was wound into a flat spiral and attached
to a brass disk. A calibration heater was mounted at the centre of the disk, and a Peltier cooling device was
attached to the underside. This calorimeter was used to make measurements up to 40·106Pa and 423 K.
Christensen et al. (84CHR1) constructed a flow mixing calorimeter in which the tube was wound onto
the upper half of a metal cylinder, and a calibration heater was wound between the turns of the tube. A
second heater was wound onto the lower half of the cylinder which was in contact with a metal plate
maintained at a temperature approximately 1 K cooler than the calorimeter enclosure. This second heater
was used to back off the heat flow from the cylinder to the plate. This arrangement permitted the
measurement of either exothermic or endothermic processes. The calorimeter was used up to 40.5·106Pa and
673 K.
Busey et al. (84BUS1) constructed a coiled tube flow mixing calorimeter designed to be inserted into a
high temperature Calvet calorimeter. This was operated up to 700 K and 50·106Pa.
A somewhat similar design was developed by Mathonat et al. (94MAT1) based on a differential heat
flow calorimeter, SETARAM C-80. The mixing cell was a cylindrical coil of stainless-steel capillary tubing
which tightly fitted in the thermopile well of the calorimeter. The fluids were delivered by high pressure
pumps at controlled flow rates from (100 to 1500)·10–6L min–1. A special arrangement using a counter
current heat exchanger and a preheater permitted active control of the temperature of the incoming liquids
when they were in thermal contact with the mixture leaving the calorimeter. Test measurements on the gas-
liquid system carbon dioxide + toluene (File Number LB0396, p. 2-73) showed that enthalpies of mixing
could be measured with this calorimeter at temperatures up to 500 K and at pressures up to 20·10 6Pa within 2
% uncertainty. This instrument was also employed under more severe conditions for the measurement of the
heat of solution of gases in liquids (Chap.1.2.3).
A flow mixing calorimeter developed by Hynek et al. (99HYN1) featured a “calo-densimeter” operated
in dynamic flow mode in which the liquid mixture leaving the calorimeter flowed through a vibrating tube
densimeter operating at the same temperature and pressure. When the required experimental temperature had
been obtained the experiment was started by pumping one of the pure fluids through the calorimeter, and
readings from the calorimeter and the densimeter were recorded. The mixing process was started by
switching on the other pump, and at the same time decreasing the flow rate of the first pump so that the
required composition was obtained but the overall flow rate was unchanged. The energy corresponding to the
mixing effect for different concentrations was first estimated from the change of control heater input without
activating the compensation heater. In endothermic experiments at least 80% of the energy needed was
supplied by the compensation heater which was switched on after starting the mixing process; the control
heater automatically offset the remaining effect. The opposite situation occurred in exothermic experiments.
The performance of the apparatus was checked by making measurements on the mixtures water + ethanol
and water + methanol and on water + benzene which exhibits partial miscibility.

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1-12 1 Introduction

1.4 Analysis of excess enthalpies of gas mixtures at low pressures

Thermodynamic properties of gases at low densities can be represented, with adequate accuracy, by the virial
equation of state truncated at the fourth virial coefficient, written either as a density series:
⎛ RT ⎞ ⎛ B C D⎞
P=⎜ ⎟ ⎜1 + + 2 + 3 ⎟ (1.46)
⎝ V ⎠⎝ V V V ⎠
or as a pressure series:

P = V −1 (1 + B′P + C ′P 2 + D′P 3 ) (1.47)

The coefficients of these two series are related through the equations:
B′ = B (1.48)

C ′ = (C − B 2 ) /( RT ) (1.49)

D ′ = ( D − 3 BC + 2 B 3 ) /( RT ) 2 (1.50)

Full details of the virial equation of state are given in the book by Mason and Spurling (69MAS1).
Using the pressure series Eq. (1.47) together with Eqs. (1.15) and (1.16) it has been shown (77WOR1) that
the excess molar enthalpy HE is given by the equation:

H E = y1 y 2 P ( 2φ12 − φ11 − φ22 ) − ( P 2 / RT )( Bφ − y1 B11φ11 − y 2 B22φ22 )

+ ( P 2 / RT )(ψ − y1ψ 111 − y 2ψ 222 ) (1.51)

where y1 and y2 are the gas phase mole fractions of components 1 and 2, φ and ψ are defined by the equations:
φ = B – T (dB / dT) (1.52)
and:
ψ = C − (T / 2)(dC / dT ) (1.53)

The quantities B, φ and ψ in Eq. (1.51) which have no subscript are for the mixture, and are given by:

B = y12 B11 + 2 y1 y 2 B12 + y 22 B22 ; φ = y12φ11 + 2 y1 y 2φ12 + y 22φ 22 (1.54)

ψ = y13ψ 111 + 3 y12 y 2ψ 112 + 3 y1 y 22ψ 122 + y 23ψ 222 (1.55)

Eq. (1.51) contains terms which are functions of the second and third virial coefficients B and C and is adequate
up to pressures of (0.1 or 0.2)·106Pa. At higher pressures the neglect of the D' and E' coefficients, which include
B and C terms as well as the virial coefficients D and E, may become significant. At higher pressures it is better
to use the density series, Eq. (1.46), which yields more compact equations.
It was shown previously (88LAN1) that putting Eq. (1.46) into Eq. (1.13) gives the following equation for
the residual molar enthalpy HR of a pure fluid:

⎛HR ⎞ 1⎛
⎜ ⎟ = ⎜ B − T dB ⎞⎟ + 1 ⎛⎜ C − T dC ⎞⎟ + 1 ⎛⎜ D − T dD ⎞⎟ (1.56)
⎜ RT ⎟ V⎝ dT ⎠ V 2 ⎝ dT ⎠ V 3 ⎝ dT ⎠
⎝ ⎠
Substitution into Eq. (1.27) yields the excess molar enthalpy

⎛HE ⎞ ⎛φ ψ λ ⎞ ⎛ φ11 ψ 111 λ1111 ⎞ ⎛ φ22 ψ 222 λ2222 ⎞

⎜ ⎟=⎜ + ⎜ ⎟ ⎜ ⎟
⎜ RT ⎟ ⎝ V V 2 + V 3 ⎟⎠ − y1 ⎜ V + V 2 + V 3 ⎟ − y2 ⎜ V + V 2 + V 3 ⎟ (1.57)
⎝ ⎠ ⎝ 1 1 1 ⎠ ⎝ 2 2 2 ⎠

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 1 Introduction 1-13

where λ is defined by:

λ = D − (T / 3)(dD / dT ) (1.58)

the value of λ in the first term in parentheses which refers to properties of the mixture is given by:

λ = y14 λ1111 + 4 y13 y 2 λ1112 + 6 y12 y 22 λ1122 + 4 y1 y 23λ2221 + y 24 λ2222 (1.59)

To calculate HE at a chosen pressure from Eq. (1.57) it is first necessary to compute the molar volume V of the
mixture and the volumes V1 and V2 of the pure components. This can be done iteratively by adjusting V in Eq.
(1.46) until the required value of the pressure is obtained.

1.4.1 Weakly polar gas mixtures

Low pressure gas phase mixing calorimeters were developed in response to the need for a technique which gives
accurate information about the excess properties of mixtures which contain polar components such as water,
alcohol, sulfur dioxide or hydrogen chloride. The conventional method for obtaining information about pairwise
interactions between unlike molecules is the measurement of the second virial coefficient B using a (P,V,T)
apparatus. It is of course necessary to measure B11 and B22 for both pure components, and the second cross virial
coefficient B12 for the mixture. For mixtures of polar substances a significant source of error which often spoils
the measurements, particularly at low temperatures, is adsorption of the gas on the walls of the apparatus.
Adsorption errors result in measurements of B being too negative. An alternative to the measurement of B for the
mixture using a (P,V,T) apparatus, is the direct measurement of either the pressure change on forming a mixture
using the method of Knobler, Beenakker and Knaap (59KNO1) or the volume change on mixing using the
method of Edwards and Roseveare (42EDW1). These experiments yield the excess molar volume VE where:

V E = y1 y 2 (2 B12 − B11 − B22 ) (1.60)

If B11 and B22 are known to good accuracy, reliable values of B12 can be obtained. However for polar fluids
adsorption errors are still a problem. Flow calorimetric techniques, such as measurement of the pressure
derivative of the heat capacity, or of the isothermal Joule-Thomson coefficient, or the excess enthalpy, are not
spoiled by adsorption effects. Adsorption does occur, and there is an accompanying heat change, but once a
steady state adsorbed layer is formed, there is no further heat flux, and the calorimetric measurements are not
spoiled. The calorimeter is then sensitive only to the change in thermodynamic property (heat capacity or
enthalpy) of the fluid which passes through it. Isothermal throttling calorimeters yield the isothermal Joule-
Thomson coefficient φ, where:
φ = (∂H / ∂P)T = V – T(∂V / ∂T)P (1.61)
Measurement of φ for a binary mixture, and of φ1 and φ2 for the two pure components, yield the cross term φ12
which contains exactly the same information about the unlike pair potential as does a measurement of B12. The
measurement of the isothermal Joule-Thomson coefficient of gases at low pressures is very difficult due to
kinetic energy effects in the high velocity gas stream, and consequent heat leaks. In flow mixing calorimeters the
kinetic energy effects are very small, and can be cancelled out completely if a differential mixing calorimeter is
constructed. A flow mixing calorimeter should be designed to ensure that during the residence time in the
calorimeter the extent of mixing is better that 99%, that the calorimeter heater is located at the centre of the
mixing zone so that heat leaks are minimized, and that the pressure drop across the calorimeter is as low as
possible so that the Joule-Thomson effect is small.

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1-14 1 Introduction

1.4.2 Second virial coefficients from excess enthalpies

If third virial coefficients are neglected the excess molar enthalpy HE is given by:

H E = y1 y 2 P(2φ12 − φ11 − φ 22 ) − ( P 2 / RT )( Bφ − y1 B11φ11 − y 2 B22φ 22 ) (1.62)

Assuming that accurate values of B11 and B22 are available it is possible to obtain B12 and φ12 from HE
measurements by a purely thermodynamic analysis which assumes no pair potentials, corresponding states
correlations, or combining rules. What is assumed is that B12 and φ12 can be adequately fitted by the simple
equations:
B12 = a + b{exp(c / T )} (1.63)

or:
φ12 = a + b{1 + (c / T )} exp(c /T ) (1.64)

The analysis is done (03WOR1) at mole fraction y1 = 0.5 by first setting the P2 term in Eq. (1.62) to zero. The
first term of the equation at once yields values of φ12 at all the experimental temperatures of the HE
measurements. These are fitted by the method of least squares to Eq. (1.64), and when the coefficients are
inserted into Eq. (1.63) values of B12 are obtained. The P2 term in Eq. (1.62) is then calculated and new values of
φ12 and hence B12 are obtained from the first term of this equation. This iterative cycle is repeated until the
values of φ12 and hence B12 become constant.
Another way of obtaining B12 from Eq. (1.62) is to fit the values of B(T) for the pure components to a suitable
pair potential, such as that of Kihara (58KIH1) or Stockmayer (41STO1) or the combined Kihara-Stockmayer
potential suggested by Storvick and Spurling (68STO1). Values of B12 and φ12 are then computed from suitable
combining rules, and usually the cross term potential energy ε12 is adjusted until the calculated excess enthalpy
agrees with that obtained experimentally. This adjustment is made by changing the quantity (1 – k12) in the
equation:

ε12 = (1 − k12 )(ε11ε 22 )1 / 2 (1.65)

An analysis of excess enthalpies and cross term second virial coefficients of a large number of non polar gaseous
mixtures (79WOR1) showed that values of (1 – k12) are well fitted by the combining rule:
−3
(1 − k12 ) = 2(σ 11σ 22 ) (σ 12
3 3 1/ 2
)( I1 I 2 )1/ 2 ( I1 + I 2 ) −1 (1.66)

Here σ12 is the cross term collision diameter, which is the arithmetic mean of the values for the pure gases, and I1
and I2 are the ionization energies.
For mixtures of a small molecule such as argon with a polar molecule such as hydrogen chloride, it is
possible to obtain values of pure component second virial coefficients for the polar substance from excess
enthalpy measurements (97WOR2) (File Number LB 0392, p. 2-121). For this mixture φ22 for the polar molecule
is about 5 times bigger than the cross term φ12, and the coefficient φ11 for argon is smaller than φ12. The HE
measurements were analyzed using the Stockmayer potential by setting up a grid of possible values of ε22 and
σ22 and for each pair of values computing the standard deviation of the calculated values of HE from those
determined experimentally. Cross coefficients B12 and φ12 were calculated using Eq. (1.66) in the combining rule
for the cross term potential energy. The best fit potential parameters values were then used to calculate B22 for
hydrogen chloride. Fig. 4 of reference (97WOR2) shows the virial coefficients B11 for argon, B22 for hydrogen
chloride, and the cross term B12.

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 1 Introduction 1-15

1.4.3 Associated gas mixtures at low pressures

Where there is a strong interaction between the unlike molecules, such as the hydrogen bond formation between
diethyl ether + trichloromethane (81DOY1), it is impossible to find a value of (1 – k12) in Eq. (1.65) which
causes the right hand side of Eq. (1.62) to fit the HE measurements. Under these circumstances it is appropriate
to use the association treatment of Lambert (49LAM1) and Woolley (53WOO1) who suggested that hydrogen
bond formation should be regarded as a quasi-chemical equilibrium for which there is an equilibrium constant
K12 and an enthalpy of association ∆H12. The observed cross term second virial coefficient B12(obs) and
isothermal Joule-Thomson coefficient φ12(obs) can be written:
B12 (obs) = B12 − 1 2 K12 RT (1.67)

φ12 (obs) = φ12 + 1 2 K12∆H12 (1.68)

The excess enthalpy can now be written:

H E = y1 y2 P{2(φ12 + 1 2 K12 ∆H12 ) − φ11 − φ22 }

− ( P 2 / RT ){( B − y1 y2 K12 RT )(φ + y1 y 2 K12 ∆H12 ) − y1B11φ11 − y2 B22φ22 } (1.69)

The quantities B12, φ12, and B and φ for the mixture at y1 = 0.5 are calculated from the pure component
potentials. The P2 term in Eq. (1.69) is set to zero, and the quantity K12∆H12 is calculated at each experimental
temperature. The ratio of this quantity at lowest and highest temperatures T1 and T2 yields a value of ∆H12:

ln[( K12 ∆H 12 (T2 )) /( K12 ∆H 12 (T1 ))] = − ( ∆H 12 / R )(1 / T2 − 1 / T1 ) −1 (1.70)

The values of K12 and ∆H12 are inserted into the P2 term in Eq. (1.69), the P2 term is subtracted from HE, and
new values of K12 and ∆H12 are calculated. This iterative process is repeated until constant values of K12 and
∆H12 are obtained. These equations have been used to fit several sets of HE measurements on associating
mixtures, e.g. of diethyl ether + trichloromethane (81DOY1) (File Number LB0187, p. 2-52). Fig. 3 of this paper
shows the isothermal Joule-Thomson coefficients φ11 of ether and φ22 of trichloromethane, which are not very
different, and the cross term φ12 which, because of association, is about twice as negative as the mean of the pure
component values. The curve through the φ12 values corresponds to an enthalpy of association of -23·103J mol–1.
The broken curve in the figure, which was calculated by adjusting (1 – k12) in Eq. (1.65), cannot be made to fit
the φ12 values. For gas mixtures such as water + hydrocarbon, in which one component is self-associated, the
corresponding equations are:
B11 (obs) = B11 − K11RT (1.71)

and:
φ11 (obs) = φ11 + K11∆H11 (1.72)

These equations have been used to fit several sets of measurements on mixtures containing water or alcohol at
low pressures.
Even at atmospheric pressure alcohol gas mixtures contain not only dimer but significant amounts of higher
associates (trimer, tetramer, etc.) as well. The pressure dependence of the enthalpy and the excess enthalpy of
these mixtures is much greater than for non-associated fluids. To describe these mixtures Ginell (55GIN1) has
extended the association model to include these additional hydrogen bonded complexes. The relevant virial
coefficients are given by the equations:
B = b1 − K 2 RT (1.73)

C = b12 + (b2 − 3b1 ) K 2 RT + (4 K 22 − 2 K 3 )( RT ) 2 (1.74)

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New Series IV/10B
1-16 1 Introduction

D = b13 + (2b1b2 − 5b12 ) K 2 RT + [(14b1 − 5b2 ) + (b3 − 5b1 ) K 3 ]( RT ) 2

(1.75)
+ (18K 2 K 3 − 20K 23 − 3K 4 )( RT )3

Differentiation of Eq. (1.73) with respect to temperature yields:

φ = φ1 + ∆H2K2. (1.76)
Here φ1 is the Joule-Thomson coefficient of the monomer, K2, K3 and K4 are the equilibrium constants for the
formation of dimer, trimer and tetramer respectively, and b1, b2, and b3 are the excluded volumes of the
monomer, dimer, and trimer. By assuming a linear packing of monomers in the formation of polymers, Ginell
expressed the higher excluded volume terms, bn, in terms of b1, by:
bn = b1 (11n + 5) / 16 (1.77)

where n is the number of monomers making up the polymer. The pressure dependence of the enthalpy of gaseous
alcohol is much greater than for a non-associated fluid. Similarly the pressure dependence of measurements of
the excess molar enthalpy of the binary equimolar mixtures nitrogen + methanol (92MAS1) (File Number
LB0080, p. 2-151) and nitrogen + ethanol (92MAS2) (File Number LB0081, p. 2-151) at low temperatures is
large. As the enthalpies of trimer and tetramer formation are approximately 3 and 4 times greater than that of the
dimer, the corresponding equilibrium constants diminish rapidly with temperature, and at high temperatures only
the dimerization equilibrium is important. The measurements on the above two alcohol mixtures were made in
order to obtain second virial coefficients for methanol and ethanol which were not spoiled by adsorption errors.
The quantity b1 was equated to the second virial coefficient of CH3F, which has almost the same dipole moment
as methanol. Excellent values of B11 for methanol and ethanol were obtained from the analysis.

1.5 Analysis of enthalpies of mixing of fluids at high pressures

The use of the virial equation of state is usually restricted to gases at low pressures, but at high temperatures
where fourth and higher virial coefficients are negligible, and at pressures up to about half the critical pressure,
the virial equation can be used with success. To fit measurements at pressures up to, and beyond the critical, a
two-fluid corresponding states model can be used. While this model is very successful at high pressures it is not
as good as the virial equation at low pressures. Cubic equations of state can be used to fit gas phase properties in
the supercritical region quite well, but their principle advantage is that they can also fit measurements in the two
phase region, and give an approximate fit to liquid phase measurements.

1.5.1 The virial equation of state at high pressures

If second virial coefficients are known, and third virial coefficients can be estimated, Eq. (1.57) can be used to
calculate the excess enthalpy of binary mixtures up to quite high pressures and temperatures. In many industrial
processes mixtures containing steam are important, and to provide a database for the calculation of mixture
properties Wormald et al. (84WOR1, 85WOR2, 87LAN1, 89ALB1, 90WOR1, 95WOR1, 97WOR3, 00WOR1)
have measured the excess molar enthalpy of 19 binary mixtures containing water at temperatures which are
mostly up to 698.2 K and pressures in the range (10 to 26)·106Pa. For the mixtures in which there is no
association between water and the other component of the mixture, the measurements in the vapor phase region
can be well described by the virial equation of state. The best example of this is the set of measurements made
by Lancaster and Wormald (88LAN1) on water + pentane (File Number LB0169, p. 2-95), and full details of the
data analysis are given in this paper. Virial coefficients B, C, and D for water which are consistent with the
NBS/NRC (84HAA1) steam tables have been calculated by Gallagher. These coefficients permit the calculation
of φ11 for water in Eq. (1.57). The values of φ22 for pentane were calculated from parameters of the Kihara

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 1 Introduction 1-17

potential which had been fitted to the experimental B(T) data. Third virial coefficients and temperatures
derivatives ψ were calculated from the corresponding states correlation of Orbey and Vera (83ORB1). The
approximate values of the fourth virial coefficient of water calculated by Gallagher yielded λ1111, and as there is
no way of calculating other fourth virial derivatives these were set to zero. Fortunately these terms are small and
neglecting them is not serious. The three coefficients in the first term of equation (1.57) are all for the mixture.
In calculating the second and third virial cross coefficients it is important to recognize that there is no
hydrogen bonding between water and pentane, and in this interaction the parameters of the Stockmayer potential
fitted to values of B11 for pure water are inappropriate. Water, in its interaction with pentane, behaves like the
homomorph CH3F, which has the same dipole moment (1.85 D) as water. The Stockmayer potential parameters
for water which are appropriate to the interaction of a nonpolar substance with water are ε/k = 233 K, σ =
0.312·10–9m and t* = 1.238. Combining these with the potential parameters for pentane gives good values for B12
and φ12. Third virial cross terms and their temperature derivatives were calculated from the corresponding states
correlation of Orbey and Vera (83ORB1) using the parameters for CH3F in place of those for water. When the
calculation of HE is done very good agreement with experiment up to pressures of 12·106Pa is found, as shown in
Fig. 1 of reference (88LAN1) (File Number LB0169, p.2-95).

1.5.2 A two-fluid model for high pressure calculations

The virial equation of state is limited to the gas phase and to the moderate pressures at which the coefficients B
and C are sufficient. A method which is very useful at high pressures beyond the range of the virial expansion is
the two-fluid model of Rowlinson and Watson (69ROW1). In this model the real fluid mixture consisting of
components i and j is considered to be an ideal mixture of two hypothetical components. The residual molar
Helmholtz energy AR of the mixture is given by

A R (V , T , x) = ∑x A
i
R
i i (V , T ) (1.78)

where AiR (V ,T ) is the residual Helmholtz energy of the i'th hypothetical component. To utilize the Principle of
Corresponding States the residual Helmholtz energy of each hypothetical component is expressed in terms of the
properties of a real reference fluid ri so that:

AiR (V , T ) = f i ArRi ( V / hi , T / f i ) (1.79)

where hi and fi are scaling parameters. For the van der Waals two-fluid model the scaling parameters are given
by:

hi = ∑x h
j
j ij and f i = ∑xj
j f ij hij (1.80)

The cross-term scaling parameters hij and fij are obtained using Lorentz-Berthelot combining rules:

hij = ηij [0.5(hii1 / 3 + h1jj/ 3 )]3 and f ij = ξ ij ( f ii f jj )1/ 2 (1.81)

The binary interaction parameters ηij and ξij are adjustable. All that is needed are equations of state which
describe the Helmholtz energy of the two real fluids. A good example of the application of this two fluid model
is the fit to measurements of the excess molar enthalpy of equimolar of water + carbon dioxide (94WOR1;
95WOR1) (File Number LB0163, p. 2-108) and (97WOR3) (File Number LB0043, p. 2-108). The equation of
state of Saul and Wagner (89SAU1) was used for water, and the equation of Angus et al. (76ANG1) was used
for carbon dioxide. Fig. 1 of reference (97WOR3) shows the excellent fit to HE measurements at pressures up to
26·106Pa.

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1.5.3 Cubic equations of state

As shown above, the residual enthalpy of a fluid can be calculated from Eq. (1.18) or (1.20). The simplest cubic
equation is that of van der Waals, and for this equation the shapes of heats of mixing and volumes of mixing
curves in the critical region have been explored (86WOR1) The equation generates curves of similar shape to
most of the experimentally determined curves, though the fit to experiment is not good. Cubic and generalized
equations of state are reviewed by Anderko (00AND1) One of the modern equations of state currently in use is
the cubic equation suggested by Peng and Robinson (76PEN1). The equation gives an approximate fit to the
properties of a pure fluid, and, when suitable combining rules are assumed, an approximate fit to mixture
properties. Nevertheless it gives a useful description of the phase behavior of a fluid mixture, and generates
thermodynamic surfaces of nearly the correct shape. The equation is of the form:
P = RT /(V − b) − a (T ) /[V (V + b) + b(V − b)] (1.82)

where the parameters a(T) and b are functions of Tc, Pc and Ȧ.

The residual molar enthalpy HR is given by:

H R = RT ( Z − 1) + {[T ( da / dT ) − a ] /( 2 2b )} ln[( Z + 2.414 B ) /( Z − 2.414 B )] (1.83)

where B = bP/RT. For mixtures the combining rules are:

am = ∑∑ x x a
i j
i j ij , aij = (1 − kij )(aii a jj ) 0.5 and bm = ∑xb
i
i i (1.84)

The quantity (1 – kij) is adjustable. The excess molar enthalpy HE is given by Eq. (1.40). At the cost of increased
complexity a better fit to both HE and VE measurements can be obtained with more recent cubic equations
(00SEN1) of which the equation developed by Patel and Teja (82PAT1) is notable.

1.5.4 Heats of mixing in the liquid and supercritical regions

For weakly polar fluid mixtures in which dispersion forces are dominant, is usually found that HE(x) and VE
measurements at a single temperature can be fitted reasonably well using the Peng-Robinson or Patel-Teja
equations of state by adjusting (1 – kij). Because these cubic equations do not perfectly fit the residual enthalpies
of the pure components, a different value of (1 – kij) must be chosen at each temperature. Furthermore the value
of (1 – kij) which best fits the HE measurements often gives a poor fit to VE measurements, and these must be
fitted separately.
For strongly polar fluid mixtures, in which dipole-dipole forces or hydrogen bonding is dominant, the fit to
HE(x) measurements may be less good, and the use of a model such as that of Heidemann and Prausnitz
(76HEI1) which includes an association term is more appropriate. Müller and Gubbins (00MUE1) review
models that can be used to fit measurements on associated fluid mixtures.
At elevated temperatures the kinetic energy of molecular motion is high, and much of the structure due to
specific forces in liquid mixtures at low temperatures is wiped out. Consequently cubic equations are a better fit
to the thermodynamic properties of polar supercritical fluid mixtures than they are to the properties of liquid
mixtures at near-ambient temperatures.
For some mixtures the excess enthalpy measurements extend over a wide range of composition, temperature
and pressure, and it is possible to construct HE(x, P, T) surfaces up to the critical region and beyond. To
understand why these surfaces have the shape they do, it is necessary refer to the phase diagrams in the critical
region, and to examine the residual enthalpies of both pure components, and that of the mixture. At subcritical
temperatures the HE(x) curves may show a linear region which corresponds to a range of partial miscibility.

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 1 Introduction 1-19

1.5.5 Heats of mixing across a two-phase region

On a (T,x) phase diagram at subcritical temperatures the two-phase regions are indicated by either liquid-liquid
or liquid-vapor coexistence curves. For a liquid-vapor equilibrium these two-phase loops terminate at the critical
locus, and a line drawn at constant pressure across the loop represents the transition from a gaseous state to a
liquid state. A good example are measurements of HE(x) at P = 16.4·106Pa for water + benzene (96WOR1) (File
Number LB0375, p. 2-103). This mixture exhibits partial miscibility in the liquid phase at temperatures up to
575 K, and at temperatures above 585 K there is a two phase liquid-vapor equilibrium loop.
Two points on an isotherm for a binary mixture are the bubble pressure Pb and the dew point pressure Pd.
Since Maxwell’s equal area rule cannot be used within the two phase loop, enthalpies can be calculated in the
homogeneous gas region up to the dew point pressure, and in the homogenous liquid phase region up to the
bubble point pressure. The enthalpy of the mixture within the two phase loop can then be calculated on the
following basis. A mixture consists of amounts α of liquid of composition xl and β of gas of composition xg. If
the actual composition of the mixture is given by xm then the following simultaneous equations must hold:
xl α + xg β = xm (1.85)
(1 – xl ) α + (1 – xg ) β = (1 – xm ) (1.86)
When these equations are solved for α and β the residual enthalpy of the mixture H is given by:
R

H R = α [ H R ( xl )] + β [ H R ( x g )] (1.87)

where H R (xl ) is the residual enthalpy of the liquid mixture of composition xl and H R (xg ) is the residual enthalpy
of the gaseous mixture of composition xg. The functional form of Eq. (1.87) is such that the residual enthalpy of
the mixture varies linearly from the bubble point pressure to the dew point pressure. This is what is observed
experimentally, e.g. for ethane + chloromethane (93GRU1) (File Number LB0172, p. 2-20) and carbon dioxide +
ethane (97WOR1) (File Number LB0387, p. 2-56).

1.5.6 Binary mixtures for which the critical temperatures are almost equal

In this chapter, and in Chap. 1.5.7, we point out that the shape of HE(x) curves, and the shape of HE(x,P,T)
surfaces is determined firstly by the location of the critical points on the (P,T) phase diagram, and secondly by
the curvature of the critical locus. Furthermore the magnitude of the heats of mixing is approximately
proportional to the separation of the critical points. This can be illustrated by inspection of measurements on
mixtures for which the pure components have similar critical temperatures, or for which they have similar
critical pressures.
Two mixtures for which the critical temperatures are almost the same are carbon dioxide + ethane (88WOR1)
(File Number LB0063, p. 2-58) and acetone + hexane (88ALB1) (File Number LB0285, p. 2-49), (88WOR2)
(File Number LB0090, p. 2-48). For carbon dioxide Tc = 304.2 K, Pc = 7.38·106Pa and for ethane Tc = 305.3K,
Pc = 4.87·106Pa. The critical temperature of the mixture at x = 0.5 is 14 K below the mean of the pure component
values. For acetone Tc = 508.1 K, Pc = 4.70·106Pa, for hexane Tc = 507.4 K, Pc = 2.97·106Pa. The critical
temperature of the mixture at x = 0.5 is again 14 K below the mean of the pure component values. For both
mixtures the heat of mixing has been measured over a range of pressure in the supercritical region. Values of HE
(x = 0.5) measured at a fixed temperature and plotted against pressure P show two consecutive maxima which
are biggest close to the critical point, and which diminish as the temperature is increased (File Number LB0063,
p. 2-58 ; LB0090, p. 2-48 ; LB0285, p. 2-49). The curves for carbon dioxide + ethane are shown in Fig 2 of
reference (88WOR1). Similar curves for acetone + hexane are shown in Fig 3 of reference (88ALB1). This
figure shows how the two consecutive maxima change with composition. The broken curves shown in Fig 2 of
reference (88WOR1) were calculated from the Patel-Teja equation of state.
The origin of the double maximum in the HE (x = 0.5) curve for carbon dioxide + ethane can be seen from
inspection of the supercritical residual enthalpy curves shown in Fig. 7 of reference (88WOR1). The figure
shows the residual enthalpy of pure carbon dioxide (upper solid curve), and of pure ethane (lower solid curve).

Landolt-Börnstein
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1-20 1 Introduction

The short dashed curve is the mean of the residual molar enthalpies of the two pure components, and the long
dashed curve is the residual enthalpy of the mixture. The excess molar enthalpy HE (x = 0.5) is the difference
between the curve for the mixture and the curve for the mean of the two pure components.

1.5.7 Binary mixtures for which the critical pressures are almost equal

Two mixtures for which the critical pressures are almost the same are propane + dichlorodifluoromethane
(85CHR1) (File Numbers LB0258 and LB0259, p. 2-25) and acetone + benzene (92LLO1) (File Number
LB0196, p. 2-51). For propane Tc = 369.8 K, Pc = 4.24·106Pa, and for dichlorodifluoromethane Tc = 385 K, Pc =
4.12·106Pa. For acetone Tc = 508.1 K, Pc = 4.70·106Pa, and for benzene Tc = 561.7 K, Pc = 4.87·106Pa. The
critical pressure at x = 0.5 of the first mixture is estimated to be about 0.2·106Pa greater than the mean of the pure
component values, and for the second mixture it is estimated to be about 0.3·106Pa greater. For both mixtures H E
has been measured at a fixed pressure which is greater than the critical pressure of the mixture. At these
pressures, 4.45·106Pa and 5.68·106Pa respectively, measurements have been made at three compositions and at
temperatures which range from below the critical to above the critical. Fig 3 of reference (92LLO1) shows H E
curves for acetone + benzene at x = 0.25, 0.50 and 0.75 measured at 5.68·106Pa over the temperature range 495
K to 577 K. Fig. 2 of reference (85CHR1) shows H E curves for propane + dichlorodifluoromethane at x = 0.2,
0.5 and 0.8 measured at 4.45·106Pa over the temperature range (355 to 398) K. These two figures again show
that for mixtures of quite different substances, if the critical region phase diagrams are similar, the shape of the
H E (x,T) diagrams are also very much alike. Some other mixtures which have similar critical pressures are
cyclohexane + toluene, butane + sulfur hexafluoride (03WOR2) (File Number LB0132, p. 2-133), and ethane +
chlorodifluoromethane (84CHR2) (File Numbers LB0254 and LB0256, p. 2-27).

1.6 Correlation of experimental data

E
Several equations have been proposed for correlating the experimental molar excess enthalpies H exp of binary
liquid mixtures as a function of mole fraction x1 of component 1.
The expression:
n
E
H calc = x1 (1 − x1 ) ∑ A( j) z
j =1
j −1
(1.88)

where:
z = 2 x1 – 1 (1.89)
first suggested by Guggenheim (37GUG1) and known as the Redlich-Kister equation (48RED1), is most
E
commonly used for representing H calc ( x1 ) curves at constant temperature T and low pressure P which are
approximately symmetrical about the equimolar composition, x1 = 0.5.
Other functional forms of z in Eq. (1.88) have been also used in order to obtain the best fit reducing the
number of coefficients A(j):
z = x1 (1.90)
z = 1 – x1 (1.91)
z = 1/ x1 (1.92)
1/2
z = x1 (1.93)

Landolt-Börnstein
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 1 Introduction 1-21

The coefficients A(j) are determined by least squares procedures with proper weighting of the variables x1 and
E
H exp . Usually equal weights are assigned to both variables but alternate assignments may be considered
depending on the experimental conditions.
The standard deviation of the fit ı(HE) is defined as
N
σ (H E ) = [ ∑ (H
i =1
E
exp, i − H calc
E
, i ) /( N − n)]
2 1/ 2
(1.94)

where N is the number of experimental points and n the number of coefficients A(j).
E
For n = 1 the H calc curve is perfectly symmetrical. The least squares fitting is carried out for increasing
values of n, the selected value being the one which minimizes ı(HE). Obviously, n < N. It is recommended to use
the smallest value of n possible which still accurately represent the data. A smoothed curve that wiggles through
the data indicates that the order of n is too high.
In fitting results for mixtures having skewed HE 's the equation
n
E
H calc = {x1 (1 − x1 ) /[1 + k (2 x1 − 1)]} ∑ A( j) z
j =1
j −1
(1.95)

with the term [1 + k(2x1 – 1)] in the denominator, has been shown to be useful (63MYE1). In order to have no
pole in the denominator in the range x1 = 0 to x1 = 1, the value of the skewing factor k must be – 1 < k < 1. For
k = 0 Eq.(1.95) reduces to Eq. (1.88).
Usually the value of k is not evaluated by least squares. A trial value for k is first used and then calculations
are repeated until a satisfactory representation is obtained. An approximate value of k is given by
k = 2(2x1,max – 1)/[1 + (2x1,max – 1)] (1.96)
E
where x1,max is the mole fraction of component 1 corresponding to the maximum (or minimum) of H . Eq.(1.95)
is not superior to Eq.(1.88) in case of HE’s presenting several extremums such as S-shaped curves.
Other equations have been suggested for strongly asymmetrical or S-shaped curves. The equation:
m n
E
H calc = {x1 (1 − x1 ) /[1 + ∑
k =1
∑ A( j)(2 x
B(k )(2 x1 − 1) k ]}
j =1
1 − 1) j (1.97)

with m > 1 coefficients B(k), provides a good fit but is more difficult to apply because of possible discontinuities
resulting from the polynomial expression in the denominator.
Ott et al. (86OTT1) and Gruszkiewicz et al. (93GRU1) have proposed another equation:
m n
E
Hcalc = x1(1 − x1)[S ∑i =1
A(i)(2x1 − 1)i + (1 − S ) ∑ B( j)(2x −1) ]
j =1
1
j
(1.98)

where S is a switching function serving to change the coefficients from a set which fits the data at low x1 to a set
which fits the data at higher x1. For systems where the switch occurs at low x1:

S = e α x1 (1.99)
For systems where the switch occurs at higher x1:
S = 0.5 tanh{a (x1 – b) – 1} (1.100)
where a determines the sharpness of the switch and b sets the value of x1 where the switch occurs.
In a region where phase separation occurs, HE changes linearly with x1:
E
H calc = B (1) + B ( 2) x1 (1.101)

This is due the fact that the equilibrium compositions of the two phases do not change with x1 in this region. The
coefficients B(1) and B(2) can be obtained by linear regression of the HE(x1) data. Calculating the intersection

Landolt-Börnstein
New Series IV/10B
1-22 1 Introduction

E
points of the H calc curve in the single-phase region with the straight line in the two-phase region permits the
determination of the compositions of the phases in equilibrium curve at any given temperature and pressure.
The equations listed above work usually well when both the pure components and the binary mixture are in
the same state of aggregation, i.e. liquid (Property Types HMSD1111, HMSD1121, and HMSD1131) or (gas or
supercritical fluid) (Property Types HMSD1221 and HMSD1222) and not too close to the critical line. Heat of
mixing vs. composition curves, HM(x1), of (gas or supercritical fluid) + liquid mixtures (Property Type
HMSD1311) or the HE(x1) curve of two liquids forming a single or two-phase fluid-fluid mixture (Property Type
HMSD1161) are often impossible to correlate with any simple empirical equation.
The HE(P) curves representing the pressure dependence of the molar excess enthalpy at constant temperature
T and composition x1 (Property Types HMSD1141, HMSD1231, and HMSD1232) can be often, if they are not
too close to the critical locus, expressed as a polynomial equation:
n
E
H calc = ∑ A( j) z
j =1
j −1
(1.102)

where
z=P (1.103)
z = 1/ P (1.104)
z = P – P° (1.105)
or
z = (P – P°)/P = 1 – P°/P (1.106)
In Eqs. (1.105) and (1.106) P° is a reference pressure, e.g. P° = 0.1·106Pa (1 bar).
The coefficients A(j) are determined by least squares procedures with proper weighting of the variables P and
E
H exp . Usually equal weights are assigned to both variables but alternate assignments may be considered
depending on the experimental conditions.
The standard deviation of the fit ı(HE) is defined as
N
σ (H E ) = [ ∑ (H
i =1
E
exp, i − H calc
E 2
,i ) / N ]
1/ 2
(1.107)

where N is the number of experimental points. Similar equations can be used for correlating HM(P) curves
(Property Type HMSD1351).
The HE(T) curves representing the temperature dependence of the molar excess enthalpy at constant pressure
P and composition x1 (Property Types HMSD1241 and HMSD1242) can be fitted to Eq. (1.102) where:
z=T (1.108)
z = 1/ T (1.109)
z = T – T° (1.110)
or
z = (T – T°)/T = 1 – T°/T (1.111)
In Eqs. (1.110) and (1.111) T° is a reference temperature, usually T° = 0.29815·103K (25°C).
The Hsol(x1) curves representing the composition dependence of the molar enthalpy of solution at constant
pressure P and temperature T (Property Type HMSD1331) can be fitted to Eq. (1.102) with z = x1, the mole
fraction of the solute. Generally Hsol(x1) reaches a constant value for x1 → 0, the molar enthalpy of solution at
∞
infinite dilution, H sol , which is given by the coefficient A(1).
A quite unusual strong composition dependence of Hsol(x1) at very low x1 was observed by Becker et al.
(81BEC1) for some gaseous halomethane solutes in aromatic hydrocarbons (e.g. File Numbers LB0212 and
LB0215, p. 2-19). They suggested a special correlation function for this case.

Landolt-Börnstein
New Series IV/10B
 1 Introduction 1-23

∞ $
The H sol (T ) and H sol (T ) curves representing the temperature dependence of, respectively, the molar
enthalpy of solution at infinite dilution at constant pressure P (Property Type HMSD1332) and the standard
molar enthalpy of solution (Property Type HMSD1333), can be fitted to Eq. (1.102) with z = T – T°:
$
A(1) = H sol (T $ ) (1.112)

and

A(2) = C P$ ,sol (T $ ) (1.113)

$
where H sol (T $ ) is the standard molar enthalpy of solution and C P$ ,sol is the standard molar heat capacity of
solution, both at the reference temperature T°.

Landolt-Börnstein
New Series IV/10B
 5 General References 5-1

5 General References

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Landolt-Börnstein
New Series IV/10B
5-2 5 General References

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 5 General References 5-3

80BAT1 Battino, R.; Marsh, K.N.: An isothermal displacement calorimeter for the measurement of the
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82GIL1 Gill, S.J.; Wadsoe, I.: Flow-microcalorimetric techniques for solution of slightly soluble gases.
Enthalpy of solution of oxygen in water at 298.15 K. J. Chem. Thermodyn. 14 (1982) 905-919.
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83ORB1 Orbey, H.; Vera, J.H.: Correlation for the third virial coefficient. AIChE J. 29 (1983) 107-113.
83WOR1 Wormald, C.J.; Colling, C.N.: Excess enthalpies for (water + nitrogen)(g) up to 698.2 K and 12.6
MPa. J. Chem. Thermodyn. 15 (1983) 725-737.
84BUS1 Busey, R.J.; Holmes, H.F.; Mesmer, R.E.: The enthalpy of dilution of aqueous sodium chloride
to 673 K using a new heat-flow microcalorimeter. Excess thermodynamic properties and their
pressure coefficients. The enthalpy of dilution of aqueous sodium chloride to 673 K using a new
heat-flow microcalorimeter. J. Chem. Thermodyn. 16 (1984) 343-372.
84CHR1 Christensen, J.J.; Izatt, R.M.: An isothermal flow calorimeter designed for high temperature, high
pressure operation. Thermochim. Acta 73 (1984) 117-129.
84CHR2 Christensen, J.J.; Zebolsky, D.M.; Schofield, R.S.; Cordray, D.R.; Izatt, R.M.: The excess
enthalpies of (ethane + chlorodifluoromethane) from 293.15 to 383.15 K at 5.15 MPa. J. Chem.
Thermodyn. 16 (1984) 905-916.
84DEC1 Dec, S.F.; Gill, S.J.: Steady-state gas dissolution flow microcalorimeter for determination of
heats of solution of slightly soluble gases in water. Rev. Sci. Instrum. 55 (1984) 765-772.
84HAA1 Haar, L.; Gallagher, J.S.; Kell, G.S.: NBS/NRC Steam Tables. Hemisphere Publ. Corp., New
York, USA, 1984.
84OLO1 Olofsson, G.; Oshodj, A.A.; Qvarnstroem, E.; Wadsoe, I.: Calorimetric measurements on slightly
soluble gases in water. Enthalpies of solution of helium, neon, argon, krypton, xenon, methane,
ethane, propane, n-butane, and oxygen at 288.15, 298.15, and 308.15 K. J. Chem. Thermodyn. 16
(1984) 1041-1052.
84WOR1 Wormald, C.J.; Colling, C.N.: Excess enthalpies for (water + methane) vapor up to 698.2 K and
12.6 MPa. AIChE J. 30 (1984) 386-393.
85CHR1 Christensen, J.J.; Cordray, D.R.; Zebolsky, D.M.; Izatt, R.M.: The excess enthalpies of (propane
+ dichlorodifluoromethane) from 353.15 to 398.15 K at 4.45 MPa. J. Chem. Thermodyn. 17
(1985) 335-348.

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5-4 5 General References

85WIL1 Wilhelm, E.: Precision methods for the determination of the solubility of gases in liquids. CRC
Crit. Rev. Anal. Chem. 16 (1985) 129-175.
85WOR1 Wormald, C.J.; Yerlett, T.K.: A new enthalpy-increment calorimeter. Enthalpy increments for n-
hexane. J. Chem. Thermodyn. 17 (1985) 1171-1186.
85WOR2 Wormald, C.J.; Colling, C.N.: Excess enthalpies of (water + hydrogen)(g) up to 698.2 K and
11.13 MPa. J. Chem. Thermodyn. 17 (1985) 437-445.
86CHR1 Christensen, J.J.; Brown, P.R.; Izatt, R.M.: An isothermal flow calorimeter for high temperature
aqueous solutions. Thermochim. Acta 99 (1986) 159-168.
86NAG1 Naghibi, H.; Dec, S.F.; Gill, S.J.: Heat of solution of methane in water from 0 to 50 °C. J. Phys.
Chem. 90 (1986) 4621-4623.
86OTT1 Ott, J.B.; Stouffer, C.E.; Cornett, G.V.; Woodfield, B.F.; Wirthlin, R.C.; Christensen, J.J.;
Deiters, U.K.: Excess enthalpies for (ethanol + water) at 298.15 K and pressures of 0.4, 5, 10,
and 15 MPa. J. Chem. Thermodyn. 18 (1986) 1-12.
86WIL1 Wilhelm, E.: Dilute solutions of gases in liquids. Fluid Phase Equilib. 27 (1986) 233-261.
86WOR1 Wormald, C.J.: Heats and volumes of mixing in the critical region. An exploration using the van
der Waals equation. Fluid Phase Equilib. 28 (1986) 137-153.
87LAN1 Lancaster, N.M.; Wormald, C.J.: The excess molar enthalpies of (0.5H2O + 0.5C3H8)(g) and
(0.5H2O + 0.5C4H10)(g) at high temperatures and pressures. J. Chem. Thermodyn. 19 (1987)
1001-1006.
87MER1 Merkley, K.E.; Christensen, J.J.; Izatt, R.M.: Enthalpies of absorption of carbon dioxide in
aqueous methyldiethanolamine solutions. Thermochim. Acta 121 (1987) 437-446.
87NAG1 Naghibi, H.; Dec, S.F.; Gill, S.J.: Heats of solution of ethane and propane in water from 0 to
50°C. J. Phys. Chem. 91 (1987) 245-248.
88ALB1 Al-Bizreh, N.; Wormald, C.J.; Yerlett, T.K.: Enthalpies of {x(CH3)2CO + (1-x)C6H14} for x =
0.25, 0.50, and 0.75 at 510.2 K up to 9.11 MPa. J. Chem. Thermodyn. 20 (1988) 797-804.
88LAN1 Lancaster, N.M.; Wormald, C.J.: Excess molar enthalpies of {xH2O + (1-x)C5H12}(g) up to 698.2
K and 14.0 MPa. J. Chem. Soc., Faraday Trans. 1, 84 (1988) 3159-3168.
88WOR1 Wormald, C.J.; Eyears, J.M.: Excess enthalpies and excess volumes of (0.5CO2 + 0.5C2H6) in
the supercritical region. J. Chem. Soc., Faraday Trans. 1 84 (1988) 1437-1445.
88WOR2 Wormald, C.J.; Al-Bizreh, N.; Yerlett, T.K.: Excess enthalpies of {x (CH3)2CO + (1-x) C6H14}
in the supercritical region. J. Chem. Soc., Faraday Trans. 1, 84 (1988) 3587-3596.
89ALB1 Al-Bizreh, N.; Colling, C.N.; Lancaster, N.M.; Wormald, C.J.: Excess molar enthalpies of steam-
n-hexane and steam-n-heptane up to 698.2 K and 12.6 MPa. J. Chem. Soc., Faraday Trans. 1, 85
(1989 ) 1303-1313.
89HAL1 Hallen, D.; Wadsoe, I.: A new microcalorimetric vessel for dissolution of slightly soluble gases.
Enthalpies of solution in water of carbon tetrafluoride and sulphur hexafluoride at 288.15,
298.15, and 308.15 K. J. Chem. Thermodyn. 21 (1989) 519-527.
89HAL2 Hallen, D.; Nilsson, S.-O.; Wadsoe, I.: A new flow-calorimetric vessel for dissolution of small
quantities of easily or slightly soluble liquids. J. Chem. Thermodyn. 21 (1989) 529-537.
89OSC1 Oscarson, J.L.; Van Dam, R.H.; Christensen, J.J.; Izatt, R.M.: Enthalpies of absorption of carbon
dioxide in aqueous diethanolamine solutions. Thermochim. Acta 146 (1989) 107-114.
89OSC2 Oscarson, J.L.; Van Dam, R.H.; Christensen, J.J.; Izatt, R.M.: Enthalpies of absorption of
hydrogen sulfide in aqueous diethanolamine solutions. Thermochim. Acta 154 (1989) 89-95.
89SAU1 Saul, A.; Wagner, W.: J. Phys. Chem. Ref. Data 18 (1989) 1537-1564.

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 5 General References 5-5

90WOR1 Wormald, C.J.; Al-Bizreh, N.: Excess molar enthalpy of steam - n-octane up to 648.2 K and 10.0
MPa. J. Chem. Soc., Faraday Trans. 86 (1990) 69-73.
92LLO1 Lloyd, M.J.; Wormald, C.J.: Excess molar enthalpies of {x(CH3)2CO + (1-x)C6H6} at
temperatures from 494.5 to 577.4 K and at the pressure 5.68 MPa. J. Chem. Thermodyn. 24
(1992) 67-73.
92MAS1 Massucci, M.; Du'Gay, A.P.; Diaz-Laviada, A.M.; Wormald, C.J.: Second virial coefficient of
methanol from measurements of the excess molar enthalpy of methanol - nitrogen. J. Chem. Soc.,
Faraday Trans. 88 (1992) 427-432.
92MAS2 Massucci, M.; Von Kralik, M.M.; Wormald, C.J.: Second virial coefficient of ethanol from
measurements of the excess molar enthalpy of ethanol - nitrogen. J. Chem. Soc., Faraday Trans.
88 (1992) 985-989.
93GRU1 Gruszkiewicz, M.S.; Ott, J.B.; Sipowska, J.T.: Excess enthalpies for (ethane + chloromethane) at
the temperatures (298.15, 323.15, 348.15, and 363.15) K and pressures from 5 MPa to 16 MPa. J.
Chem. Thermodyn. 25 (1993) 1017-1029.
94MAT1 Mathonat, C.; Hynek, V.; Majer, V.; Grolier, J.-P.E.: Measurements of excess enthalpies at high
temperature and pressure using a new type of mixing unit J. Solution Chem. 23 (1994) 1161-
1182.
94STO1 Stokes, R.H.: in Solution Calorimetry. Experimental Thermodynamics, Volume IV (K.N. Marsh
and P.A.G. O’Hare, eds.), Blackwell Scientific Publications, London, UK, 1994.
94WOR1 Wormald, C.J.; Lloyd, M.J.: Excess molar enthalpies for (0.5H2O + 0.5CO2) at temperatures
from 598.2 K to 698.2 K and pressures up to 20 MPa J. Chem. Thermodyn., 26 (1994) 101-110.
95WOR1 Wormald, C.J.: Selected experimental high temperature-high pressure excess enthalpy data for 16
binary systems containing steam. ELDATA Int. Electron. J. Phys.-Chem. Data 1 (1995 ) 95-112.
96WOR1 Wormald, C.J.; Slater, J.: Excess enthalpies for (water + benzene) in the liquid and supercritical
regions at T = 503 K to T = 592 K and p = 16.4 Pa. J. Chem. Thermodyn., 28 (1996) 627-636.
97MAT1 Mathonat, C.; Majer, V.; Mather, A.E.; Grolier, J.-P.E.: Enthalpies of absorption and solubility of
CO2 in aqueous solutions of methyldiethanolamine. Fluid Phase Equilib. 140 (1997) 171-182.
97WOR1 Wormald, C.J.; Hodgetts, R.W.: Excess enthalpies and volumes for (carbon dioxide + ethane) at
T = 291.6 K, close to the minimum in the critical locus. J. Chem. Thermodyn., 29 (1997) 75-85.
97WOR2 Wormald, C.J.; Massucci, M.: The excess enthalpy of {yAr + (1 - y)HCl}(g) and the second
virial coefficient of HCl from T = 210 K to T = 370 K. J. Chem. Thermodyn. 29 (1997) 3-14.
97WOR3 Wormald, C.J.; Lloyd, M.J.; Fenghour, A.: The excess molar enthalpy of (steam + carbon
dioxide) in the supercritical region up to T = 698.2 K and p = 25.5 MPa. J. Chem. Thermodyn. 29
(1997) 1253-1260.
98MAT1 Mathonat, C.; Majer, V.; Mather, A.E.; Grolier, J.-P.E.: Use of flow calorimetry for determining
enthalpies of absorption and the solubility of CO2 in aqueous monoethanolamine solutions. Ind.
Eng. Chem. Res. 37 (1998) 4136-4141.
99HYN1 Hynek, V.; Degrange, S.; Polednicek, M.; Majer, V.; Quint, R; Grolier, J.-P.E.: Combined flow-
mixing power-compensation calorimeter and vibrating tube densimeter for measurements at
superambient conditions. J. Solution Chem. 28 (1999) 631-666.
00AND1 Anderko, A.: Cubic and generalized van der Waals equations. In: Equations of State for Fluids
and Fluid Mixtures (Sengers, J.V.; Kayser, R.F.; Peters, C.J.; White, Jr. H.J. eds.). IUPAC,
Physical Chemistry Division, Commission on Thermodynamics, Vol. 5, Part I, Elsevier,
Amsterdam, The Netherlands ( 2000) 75-126.

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5-6 5 General References

00MUE1 Mueller, E.A.; Gubbins, K.E.: Associating fluids and fluid mixtures. In: Equations of State for
Fluids and Fluid Mixtures (Sengers, J.V.; Kayser, R.F.; Peters, C.J.; White, Jr. H.J. eds.).
IUPAC, Physical Chemistry Division, Commission on Thermodynamics, Vol. 5, Part II, Elsevier,
Amsterdam, The Netherlands ( 2000) 435-477.
00RET1 Rettich, T. R.; Battino, R.; Wilhelm, E.: Solubility of gases in liquids. 22. High-precision
determination of Henry's law constants of oxygen in liquid water from T = 274 K to T = 328 K.
J. Chem. Thermodyn., 32 (2000) 1145-1156.
00SEN1 Sengers, J.V.; Kayser, R.F.; Peters, C.J.; White, Jr. H.J.(eds.): Equations of State for Fluids and
Fluid Mixtures. IUPAC, Physical Chemistry Division, Commission on Thermodynamics, Vol. 5,
Part I, Elsevier, Amsterdam, The Netherlands, 2000.
00WOR1 Wormald, C.J.; Lloyd, M.J.; Fenghour, A.: The excess enthalpy of steam + ethane) in the
supercritical region up to T = 699.4 K and p = 25.3 MPa. Int. J. Thermophys. 21 (2000) 85-93.
03WOR1 Wormald, C.J.: (Water + hydrogen sulphide) association. Second virial cross coefficients for
(water + hydrogen sulphide) from gas phase excess enthalpy measurements. J. Chem.
Thermodyn. 35 (2003) 1019-1030.
03WOR2 Wormald, C.J.; Du'Gay, A.P.: Measurements of HmE and VmE for (n-butane + sulphur
hexafluoride) in the supercritical region at the pressure 6.00 MPa. J. Chem. Thermodyn., 35
(2003) 393-403.
04GRO1 Grolier, J.-P.E.; Wormald, C.J.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H.V.:
Heats of Mixing and Solution. In: Landolt-Boernstein Numerical Data and Functional
Relationships in Science and Technology, New Serie, Vol. IV/10A, (Martienssen, W., ed.),
Springer-Verlag Berlin, Germany , 2004.
04LID1 Lide, D.R.: CRC Handbook of Chemistry and Physics, 85th Ed., CRC Press, Boca Raton, Florida,
USA, 2004

Landolt-Börnstein
New Series IV/10B
 4 Indexes 4-1

4 Indexes

The computer program ELBT of the CD version of this book permits the retrieval of data tables using any single
or combined search criterion based on chemical system (a single component or the binary mixture), the enthalpy
of mixing property type, and/or the reference (authors, original source of data, and/or year range) (Chap. 3).
All the mixture components considered in this book are substances with a well-defined molecular formula
consisting of one or several of the following elements:
C, H, Ar, Br, Cl, F, He, Kr, N, Ne, O, S, Xe
The elements are written in the formula in alphabetical order except for C and H which, if present, precede the
other elements, as shown above.
The purpose of the printed Indexes is to give an overview of the substances and mixtures for which data
tables are provided.
4.1 Formula Index of Substances
The substances are ordered by molecular formula in a modified Hill order, in which all substances not containing
C (carbon) (inorganic substances) are listed alphabetically before those that do contain C (organic substances).
The relative molar mass (molecular weight) Mr, and the primary names of all the isomers (substances having the
same molecular formula) are also given (pp. 4-2 to 4-3).
4.2 Name Index of Substances
The substances are ordered in the alphabetical order of both their primary and their alternate names (synonyms
and acronyms). The molecular formula and the CAS Registry Number (CAS RN) are also given (pp. 4-4 to 4-8).
4.3 Class Index of Organic Substances
The chemical classes of organic substances are listed in subgroups according to the constitutive elements of their
molecular formula arranged in the following order:
C, H, F, Cl, Br, O, S, N
Within each subgroup of elements the classes are roughly listed in the order of increasing complexity (structure
and molecular interactions) of their characteristic functional groups (p. 4-9).
4.4 Class Index of Organic Systems
The mixtures are listed in subgroups according to the classes of the two constitutive organic substances (pp. 4-10
to 4-14).
4.5 Class Index of Carbon Dioxide - Organic Systems
The mixtures are listed in subgroups according to the classes of the constitutive organic substances (pp. 4-15 to
4-16).
4.6 Class Index of Aqueous-Organic Systems
The mixtures are listed in subgroups according to the classes of the constitutive organic substances (pp. 4-17 to
4-18).
4.7 Index of Systems Containing Inorganic Substances
The mixtures containing at least one inorganic substance are listed in subgroups according to the molecular
formula of the inorganic substance (pp. 4-19 to 4-21).
4.8 Formula Index of Systems
The mixtures are ordered by molecular formula in the modified Hill order (Chap. 4.1) of the substances,
Component 1 being the substance that precedes in the Hill order the substances identified as Component 2 (pp.
4-19 to 4-21).
In each of the five Indexes of Mixtures the column HMSD represents the Property Type Identifier (Chap.
2.1.1). The letter a after the Property Type Identifier indicates a two-phase fluid-fluid system. The number in
column LB represents the File Number of the numerical data extractable from the CD as a table in PDF format
and as a fully documented ASCII file (SELF or ELDATA format, Chap. 3). If a number appears in column Page,
then it represents the page in Chap. 2 where the numerical data table is printed.

Landolt-Börnstein
New Series IV/10B
4-2 4.1 Formula Index of Substances

Ar C6H14O
Formula Mr Name
Ar 39.948000000 Argon
ClH 36.460940000 Hydrogen chloride
F6S 146.055419200 Sulfur hexafluoride
H2 2.015880000 Dihydrogen
H2O 18.015280000 Water
H2S 34.080880000 Dihydrogen sulfide
H3N 17.030520000 Ammonia
He 4.002602000 Helium
Kr 83.798000000 Krypton
N2 28.013400000 Dinitrogen
N2O 44.012800000 Dinitrogen oxide
Ne 20.179700000 Neon
O2 31.998800000 Dioxygen
O2S 64.063800000 Sulfur dioxide
Xe 131.290000000 Xenon
CBrF3 148.909909600 Bromotrifluoromethane
CClF3 104.458909600 Chlorotrifluoromethane
CCl2F2 120.913506400 Dichlorodifluoromethane
CCl4 153.822700000 Tetrachloromethane
CF4 88.004312800 Tetrafluoromethane
CHClF2 86.468446400 Chlorodifluoromethane
CHCl3 119.377640000 Trichloromethane
CHF3 70.013849600 Trifluoromethane
CH2Cl2 84.932580000 Dichloromethane
CH3Cl 50.487520000 Chloromethane
CH4 16.042460000 Methane
CH4O 32.041860000 Methanol
CO 28.010100000 Carbon oxide
CO2 44.009500000 Carbon dioxide
C2H2 26.037280000 Ethyne
C2H3N 41.051920000 Ethanenitrile
C2H4 28.053160000 Ethene
C2H5Cl 64.514100000 Chloroethane
C2H6 30.069040000 Ethane
C2H6O 46.068440000 Dimethyl ether
Ethanol
C3H6 42.079740000 Cyclopropane
Propene
C3H6O 58.079140000 Propan-2-one
C3H8 44.095620000 Propane
C3H8O 60.095020000 Propan-1-ol
Propan-2-ol
C4H5NO2 99.088000000 Methyl cyanoethanoate
C4H6O3 102.088640000 (+,-)-Methyl-1,3-dioxolan-2-one
C4H8 56.106320000 But-1-ene
C4H8O 72.105720000 Oxolane
C4H8O2 88.105120000 1,4-Dioxane
C4H9NO 87.120360000 N,N-Dimethylethanamide
C4H10 58.122200000 Butane
2-Methylpropane
C4H10O 74.121600000 Butan-1-ol
Butan-2-ol
Diethyl ether
C4H10O2 90.121000000 2,5-Dioxahexane
C5H5N 79.099900000 Pyridine
C5H9NO 99.131060000 1-Methylpyrrolidin-2-one
C5H9NO2 115.130460000 N-Formylmorpholine
C5H10O 86.132300000 Pentan-3-one
C5H12 72.148780000 2,2-Dimethylpropane
Pentane
C5H12O 88.148180000 Pentan-1-ol
C6F6 186.054619200 Hexafluorobenzene
C6H6 78.111840000 Benzene
C6H11NO 113.157640000 N-Formylpiperidine
C6H12 84.159480000 Cyclohexane
C6H14 86.175360000 2,3-Dimethylbutane
Hexane
C6H14O 102.174760000 Hexan-1-ol

Landolt-Börnstein
New Series IV/10B
 4.1 Formula Index of Substances 4-3

C6H14O3 C10H22O
Formula Mr Name
C6H14O3 134.173560000 2,5,8-Trioxanonane
C7H8 92.138420000 Toluene
C7H13NO 127.184220000 1-Methylhexahydroazepin-2-one
C7H16 100.201940000 Heptane
C8H10 106.165000000 1,4-Dimethylbenzene
C8H18 114.228520000 Octane
C8H18O 130.227920000 Octan-1-ol
C9H12 120.191580000 1,3,5-Trimethylbenzene
C9H20 128.255100000 Nonane
C10H22 142.281680000 Decane
C10H22O 158.281080000 Decan-1-ol

Landolt-Börnstein
New Series IV/10B
4-4 4.2 Name Index of Substances

Formula CASRN Name

C3H6O 67-64-1 Acetone see Propan-2-one
C2H3N 75-05-8 Acetonitrile see Ethanenitrile
C2H2 74-86-2 Acetylene see Ethyne
H3N 7664-41-7 Ammonia
syn. Azane R 717 R-717
C5H12O 71-41-0 Amyl alcohol see Pentan-1-ol
C2H3N 75-05-8 AN see Ethanenitrile
C2H3N 75-05-8 ANT see Ethanenitrile
Ar 7440-37-1 Argon
H3N 7664-41-7 Azane see Ammonia
C5H5N 110-86-1 Azine see Pyridine
C6H6 71-43-2 Benzene
C6H14O3 111-96-6 Bis(2-methoxyethyl) ether see 2,5,8-Trioxanonane
CBrF3 75-63-8 Bromotrifluoromethane
syn. Freon 13B1 R 13b1 R-13b1
C4H10 106-97-8 Butane
syn. R 600 R-600
C4H10O 71-36-3 Butan-1-ol
syn. Butyl alcohol 1-Butanol
C4H10O 71-36-3 1-Butanol see Butan-1-ol
C4H10O 78-92-2 Butan-2-ol
syn. sec-Butanol sec-Butyl alcohol 2-Butanol
C4H10O 78-92-2 2-Butanol see Butan-2-ol
C4H10O 78-92-2 sec-Butanol see Butan-2-ol
C4H8 106-98-9 But-1-ene
C4H10O 71-36-3 Butyl alcohol see Butan-1-ol
C4H10O 78-92-2 sec-Butyl alcohol see Butan-2-ol
C8H18O 111-87-5 Capryl alcohol see Octan-1-ol
CH4 74-82-8 Carbane see Methane
CO2 124-38-9 Carbon dioxide
CO 630-08-0 Carbon monoxide see Carbon oxide
CO 630-08-0 Carbon oxide
syn. Carbon monoxide
CCl4 56-23-5 Carbon tetrachloride see Tetrachloromethane
CF4 75-73-0 Carbon tetrafluoride see Tetrafluoromethane
CCl2F2 75-71-8 CFC 12 see Dichlorodifluoromethane
CCl2F2 75-71-8 CFC-12 see Dichlorodifluoromethane
ClH 7647-01-0 Chlorane see Hydrogen chloride
CHClF2 75-45-6 Chlorodifluoromethane
syn. Freon 22 HCFC 22 HCFC-22 R 22 R-22
C2H5Cl 75-00-3 Chloroethane
syn. Ethyl chloride R 160 R-160
CHCl3 67-66-3 Chloroform see Trichloromethane
CH3Cl 74-87-3 Chloromethane
syn. HCC 40 HCC-40 Methyl chloride R 40 R-40
CClF3 75-72-9 Chlorotrifluoromethane
syn. Freon 13 R 13 R-13
C4H5NO2 105-34-0 Cyanoacetic acid methyl ester see Methyl cyanoethanoate
C4H5NO2 105-34-0 Cyanoethanoic acid methyl ester see Methyl cyanoethanoate
C2H3N 75-05-8 Cyanomethane see Ethanenitrile
C6H12 110-82-7 Cyclohexane
C3H6 75-19-4 Cyclopropane
C10H22 124-18-5 Decane
C10H22O 112-30-1 Decan-1-ol
syn. Decyl alcohol 1-Decanol
C10H22O 112-30-1 1-Decanol see Decan-1-ol
C10H22O 112-30-1 Decyl alcohol see Decan-1-ol
CCl2F2 75-71-8 Dichlorodifluoromethane
syn. R 12 CFC 12 CFC-12 Freon 12 R-12
CH2Cl2 75-09-2 Dichloromethane
syn. Methylene chloride R 30 R-30
C6H14O3 111-96-6 Di(ethylene glycol) dimethyl ether see 2,5,8-Trioxanonane
C4H10O 60-29-7 Diethyl ether
syn. Ethoxyethane Ethyl ether Ether
C5H10O 96-22-0 Diethyl ketone see Pentan-3-one
C6H14O3 111-96-6 Diglyme see 2,5,8-Trioxanonane
H2 1333-74-0 Dihydrogen
syn. Hydrogen
H2S 7783-06-4 Dihydrogen sulfide
syn. Hydrogen sulfide Sulfane

Landolt-Börnstein
New Series IV/10B
 4.2 Name Index of Substances 4-5

Formula CASRN Name

C6H14 79-29-8 Diisopropyl see 2,3-Dimethylbutane
C4H10O2 110-71-4 1,2-Dimethoxyethane see 2,5-Dioxahexane
C4H9NO 127-19-5 N,N-Dimethylacetamide see N,N-Dimethylethanamide
C8H10 106-42-3 1,4-Dimethylbenzene
syn. 1,4-Xylene
C6H14 79-29-8 2,3-Dimethylbutane
syn. Diisopropyl
C4H9NO 127-19-5 N,N-Dimethylethanamide
syn. N,N-Dimethylacetamide DMA DMAC
C2H6O 115-10-6 Dimethyl ether
syn. Methyl ether RE 170 RE-170
C3H6O 67-64-1 Dimethyl ketone see Propan-2-one
C5H12 463-82-1 2,2-Dimethylpropane
syn. Neopentane
N2 7727-37-9 Dinitrogen
syn. Nitrogen
N2O 10024-97-2 Dinitrogen oxide
syn. Nitrous oxide
C4H10O2 110-71-4 2,5-Dioxahexane
syn. 1,2-Dimethoxyethane Ethane-1,2-diol dimethyl ether Ethylene glycol dimethyl ether
Glyme
C4H8O2 123-91-1 1,4-Dioxane
O2 7782-44-7 Dioxygen
syn. Oxygen
C4H9NO 127-19-5 DMA see N,N-Dimethylethanamide
C4H9NO 127-19-5 DMAC see N,N-Dimethylethanamide
C2H6 74-84-0 Ethane
syn. R 170 R-170
C4H10O2 110-71-4 Ethane-1,2-diol dimethyl ether see 2,5-Dioxahexane
C2H3N 75-05-8 Ethanenitrile
syn. Acetonitrile Cyanomethane Ethanonitrile Methanecarbonitrile Methyl cyanide AN
ANT
C2H6O 64-17-5 Ethanol
syn. Ethyl alcohol
C2H3N 75-05-8 Ethanonitrile see Ethanenitrile
C2H4 74-85-1 Ethene
syn. Ethylene R 1150 R-1150
C4H10O 60-29-7 Ether see Diethyl ether
C4H10O 60-29-7 Ethoxyethane see Diethyl ether
C2H6O 64-17-5 Ethyl alcohol see Ethanol
C2H5Cl 75-00-3 Ethyl chloride see Chloroethane
C2H4 74-85-1 Ethylene see Ethene
C4H10O2 110-71-4 Ethylene glycol dimethyl ether see 2,5-Dioxahexane
C4H10O 60-29-7 Ethyl ether see Diethyl ether
C2H2 74-86-2 Ethyne
syn. Acetylene
CHF3 75-46-7 F 23 see Trifluoromethane
CHF3 75-46-7 F-23 see Trifluoromethane
CHF3 75-46-7 Fluoroform see Trifluoromethane
C5H9NO2 4394-85-8 N-Formylmorpholine
syn. 4-Morpholinecarboxaldehyde
C6H11NO 2591-86-8 1-Formylpiperidine see N-Formylpiperidine
C6H11NO 2591-86-8 N-Formylpiperidine
syn. 1-Formylpiperidine
CCl2F2 75-71-8 Freon 12 see Dichlorodifluoromethane
CClF3 75-72-9 Freon 13 see Chlorotrifluoromethane
CBrF3 75-63-8 Freon 13B1 see Bromotrifluoromethane
CF4 75-73-0 Freon 14 see Tetrafluoromethane
CHClF2 75-45-6 Freon 22 see Chlorodifluoromethane
CHF3 75-46-7 Freon 23 see Trifluoromethane
C4H10O2 110-71-4 Glyme see 2,5-Dioxahexane
C3H8 74-98-6 HC 290 see Propane
C3H8 74-98-6 HC-290 see Propane
CH3Cl 74-87-3 HCC 40 see Chloromethane
CH3Cl 74-87-3 HCC-40 see Chloromethane
CHClF2 75-45-6 HCFC 22 see Chlorodifluoromethane
CHClF2 75-45-6 HCFC-22 see Chlorodifluoromethane
He 7440-59-7 Helium
C7H16 142-82-5 Heptane

Landolt-Börnstein
New Series IV/10B
4-6 4.2 Name Index of Substances

Formula CASRN Name

C6F6 392-56-3 Hexafluorobenzene
syn. Perfluorobenzene
C7H13NO 2556-73-2 Hexahydro-1-methyl-2H-azepin-2-one see 1-Methylhexahydroazepin-2-one
C6H14 110-54-3 Hexane
C6H14O 111-27-3 Hexan-1-ol
syn. Hexyl alcohol 1-Hexanol
C6H14O 111-27-3 1-Hexanol see Hexan-1-ol
C6H14O 111-27-3 Hexyl alcohol see Hexan-1-ol
CHF3 75-46-7 HFC 23 see Trifluoromethane
CHF3 75-46-7 HFC-23 see Trifluoromethane
ClH 7647-01-0 Hydrochloric acid see Hydrogen chloride
H2 1333-74-0 Hydrogen see Dihydrogen
ClH 7647-01-0 Hydrogen chloride
syn. Chlorane Hydrochloric acid
H2S 7783-06-4 Hydrogen sulfide see Dihydrogen sulfide
C3H8O 67-63-0 IPA see Propan-2-ol
C4H10 75-28-5 Isobutane see 2-Methylpropane
C3H8O 67-63-0 Isopropanol see Propan-2-ol
C3H8O 67-63-0 Isopropyl alcohol see Propan-2-ol
Kr 7439-90-9 Krypton
C9H12 108-67-8 Mesitylene see 1,3,5-Trimethylbenzene
CH4 74-82-8 Methane
syn. Carbane R 50 R-50
C2H3N 75-05-8 Methanecarbonitrile see Ethanenitrile
CH4O 67-56-1 Methanol
syn. Methyl alcohol
C6H14O3 111-96-6 2-Methoxyethyl ether see 2,5,8-Trioxanonane
CH4O 67-56-1 Methyl alcohol see Methanol
C7H8 108-88-3 Methylbenzene see Toluene
C5H9NO 872-50-4 1-Methylbutano-4-lactam see 1-Methylpyrrolidin-2-one
C7H13NO 2556-73-2 N-Methyl-.epsilon.-caprolactam see 1-Methylhexahydroazepin-2-one
C7H13NO 2556-73-2 1-Methyl-6-caprolactam see 1-Methylhexahydroazepin-2-one
C7H13NO 2556-73-2 N-Methylcaprolactam see 1-Methylhexahydroazepin-2-one
CH3Cl 74-87-3 Methyl chloride see Chloromethane
C2H3N 75-05-8 Methyl cyanide see Ethanenitrile
C4H5NO2 105-34-0 Methyl cyanoacetate see Methyl cyanoethanoate
C4H5NO2 105-34-0 Methyl cyanoethanoate
syn. Methyl cyanoacetate Cyanoacetic acid methyl ester Cyanoethanoic acid methyl ester
C4H6O3 108-32-7 (+,-)-Methyl-1,3-dioxolan-2-one
syn. (+,-)-Propylene carbonate
CH2Cl2 75-09-2 Methylene chloride see Dichloromethane
C2H6O 115-10-6 Methyl ether see Dimethyl ether
C7H13NO 2556-73-2 1-Methylhexahydroazepin-2-one
syn. 1-Methyl-6-caprolactam 1-Methylhexahydro-2-azepinone 1-Methylhexano-6-lactam
Hexahydro-1-methyl-2H-azepin-2-one N-Methyl-.epsilon.-caprolactam
N-Methylcaprolactam
C7H13NO 2556-73-2 1-Methylhexahydro-2-azepinone see 1-Methylhexahydroazepin-2-one
C7H13NO 2556-73-2 1-Methylhexano-6-lactam see 1-Methylhexahydroazepin-2-one
C4H10 75-28-5 2-Methylpropane
syn. Isobutane R 600a R-600a
C5H9NO 872-50-4 1-Methylpyrrolidin-2-one
syn. 1-Methyl-2-pyrrolidone 1-Methylbutano-4-lactam N-Methylpyrrolidin-2-one
N-Methylpyrrolidone NMP
C5H9NO 872-50-4 N-Methylpyrrolidin-2-one see 1-Methylpyrrolidin-2-one
C5H9NO 872-50-4 1-Methyl-2-pyrrolidone see 1-Methylpyrrolidin-2-one
C5H9NO 872-50-4 N-Methylpyrrolidone see 1-Methylpyrrolidin-2-one
C5H9NO2 4394-85-8 4-Morpholinecarboxaldehyde see N-Formylmorpholine
Ne 7440-01-9 Neon
C5H12 463-82-1 Neopentane see 2,2-Dimethylpropane
N2 7727-37-9 Nitrogen see Dinitrogen
N2O 10024-97-2 Nitrous oxide see Dinitrogen oxide
C5H9NO 872-50-4 NMP see 1-Methylpyrrolidin-2-one
C9H20 111-84-2 Nonane
C8H18 111-65-9 Octane
C8H18O 111-87-5 Octan-1-ol
syn. Octyl alcohol Capryl alcohol 1-Octanol
C8H18O 111-87-5 1-Octanol see Octan-1-ol
C8H18O 111-87-5 Octyl alcohol see Octan-1-ol
C6H14O3 111-96-6 3-Oxapentane-1,5-diol dimethyl ether see 2,5,8-Trioxanonane
H2O 7732-18-5 Oxidane see Water

Landolt-Börnstein
New Series IV/10B
 4.2 Name Index of Substances 4-7

Formula CASRN Name

C4H8O 109-99-9 Oxolane
syn. Tetrahydrofuran THF
O2 7782-44-7 Oxygen see Dioxygen
C5H12 109-66-0 Pentane
C5H12O 71-41-0 Pentan-1-ol
syn. Amyl alcohol Pentyl alcohol 1-Pentanol
C5H12O 71-41-0 1-Pentanol see Pentan-1-ol
C5H10O 96-22-0 Pentan-3-one
syn. Diethyl ketone
C5H12O 71-41-0 Pentyl alcohol see Pentan-1-ol
C6F6 392-56-3 Perfluorobenzene see Hexafluorobenzene
CF4 75-73-0 Perfluoromethane see Tetrafluoromethane
C7H8 108-88-3 Phenylmethane see Toluene
C3H8 74-98-6 Propane
syn. HC 290 HC-290 R 290 R-290
C3H8O 71-23-8 Propan-1-ol
syn. Propyl alcohol 1-Propanol
C3H8O 71-23-8 1-Propanol see Propan-1-ol
C3H8O 67-63-0 Propan-2-ol
syn. Isopropanol Isopropyl alcohol IPA 2-Propanol
C3H8O 67-63-0 2-Propanol see Propan-2-ol
C3H6O 67-64-1 Propan-2-one
syn. Acetone Dimethyl ketone
C3H6 115-07-1 Propene
syn. Propylene R 1270 R-1270
C3H8O 71-23-8 Propyl alcohol see Propan-1-ol
C3H6 115-07-1 Propylene see Propene
C4H6O3 108-32-7 (+,-)-Propylene carbonate see (+,-)-Methyl-1,3-dioxolan-2-one
C5H5N 110-86-1 Pyridine
syn. Azine
CCl4 56-23-5 R 10 see Tetrachloromethane
C2H4 74-85-1 R 1150 see Ethene
CCl2F2 75-71-8 R 12 see Dichlorodifluoromethane
C3H6 115-07-1 R 1270 see Propene
CClF3 75-72-9 R 13 see Chlorotrifluoromethane
CBrF3 75-63-8 R 13b1 see Bromotrifluoromethane
CF4 75-73-0 R 14 see Tetrafluoromethane
C2H5Cl 75-00-3 R 160 see Chloroethane
C2H6 74-84-0 R 170 see Ethane
CHCl3 67-66-3 R 20 see Trichloromethane
CHClF2 75-45-6 R 22 see Chlorodifluoromethane
CHF3 75-46-7 R 23 see Trifluoromethane
C3H8 74-98-6 R 290 see Propane
CH2Cl2 75-09-2 R 30 see Dichloromethane
CH3Cl 74-87-3 R 40 see Chloromethane
CH4 74-82-8 R 50 see Methane
C4H10 106-97-8 R 600 see Butane
C4H10 75-28-5 R 600a see 2-Methylpropane
H3N 7664-41-7 R 717 see Ammonia
H2O 7732-18-5 R 718 see Water
CCl4 56-23-5 R-10 see Tetrachloromethane
C2H4 74-85-1 R-1150 see Ethene
CCl2F2 75-71-8 R-12 see Dichlorodifluoromethane
C3H6 115-07-1 R-1270 see Propene
CClF3 75-72-9 R-13 see Chlorotrifluoromethane
CBrF3 75-63-8 R-13b1 see Bromotrifluoromethane
CF4 75-73-0 R-14 see Tetrafluoromethane
C2H5Cl 75-00-3 R-160 see Chloroethane
C2H6 74-84-0 R-170 see Ethane
CHCl3 67-66-3 R-20 see Trichloromethane
CHClF2 75-45-6 R-22 see Chlorodifluoromethane
CHF3 75-46-7 R-23 see Trifluoromethane
C3H8 74-98-6 R-290 see Propane
CH2Cl2 75-09-2 R-30 see Dichloromethane
CH3Cl 74-87-3 R-40 see Chloromethane
CH4 74-82-8 R-50 see Methane
C4H10 106-97-8 R-600 see Butane
C4H10 75-28-5 R-600a see 2-Methylpropane
H3N 7664-41-7 R-717 see Ammonia
H2O 7732-18-5 R-718 see Water

Landolt-Börnstein
New Series IV/10B
4-8 4.2 Name Index of Substances

Formula CASRN Name

C2H6O 115-10-6 RE 170 see Dimethyl ether
C2H6O 115-10-6 RE-170 see Dimethyl ether
H2S 7783-06-4 Sulfane see Dihydrogen sulfide
O2S 7446-09-5 Sulfur dioxide
syn. Sulfur(IV) oxide
F6S 2551-62-4 Sulfur(VI) fluoride see Sulfur hexafluoride
F6S 2551-62-4 Sulfur hexafluoride
syn. Sulfur(VI) fluoride
O2S 7446-09-5 Sulfur(IV) oxide see Sulfur dioxide
CCl4 56-23-5 Tetrachloromethane
syn. Carbon tetrachloride R 10 R-10
CF4 75-73-0 Tetrafluoromethane
syn. Carbon tetrafluoride Freon 14 Perfluoromethane R 14 R-14
C4H8O 109-99-9 Tetrahydrofuran see Oxolane
C4H8O 109-99-9 THF see Oxolane
C7H8 108-88-3 Toluene
syn. Methylbenzene Phenylmethane
CHCl3 67-66-3 Trichloromethane
syn. Chloroform R 20 R-20
CHF3 75-46-7 Trifluoromethane
syn. F 23 F-23 Fluoroform Freon 23 HFC 23 HFC-23 R 23 R-23
C9H12 108-67-8 1,3,5-Trimethylbenzene
syn. Mesitylene
C6H14O3 111-96-6 2,5,8-Trioxanonane
syn. 2-Methoxyethyl ether 3-Oxapentane-1,5-diol dimethyl ether Bis(2-methoxyethyl) ether
Di(ethylene glycol) dimethyl ether Diglyme
H2O 7732-18-5 Water
syn. Oxidane R 718 R-718
Xe 7440-63-3 Xenon
C8H10 106-42-3 1,4-Xylene see 1,4-Dimethylbenzene

Landolt-Börnstein
New Series IV/10B
 4.3 Class Index of Organic Substances 4-9

C-H C-N-O-H
Elements Name
C-H Hydrocarbons
Alkanes (Saturated hydrocarbons, paraffins)
Linear alkanes
Branched alkanes
Cycloalkanes (Naphthenes)
Alkenes (Olefins)
Linear alkenes
Alkynes (Acetylenes)
Arenes (Monocyclic and polyciclic aromatic hydrocarbons)
Benzene
Alkylbenzenes
C-F Perfluorohydrocarbons
Perfluoroalkanes
Hexafluorobenzene (Perfluorobenzene)
C-F-H Fluorohydrocarbons (Partially fluorinated hydrocarbons)
Fluoroalkanes
C-Cl Perchlorohydrocarbons
Tetrachloromethane (Carbon tetrachloride)
C-Cl-H Chlorohydrocarbons (Partially chlorinated hydrocarbons)
Chloroalkanes (Partially chlorinated alkanes)
C-Cl-F Per(chlorofluoro)hydrocarbons
Per(chlorofluoro)alkanes
C-Cl-F-H Chlorofluorohydrocarbons (Partially chlorinated/fluorinated hydrocarbons)
Chlorodifluoromethane
C-Br-F Per (bromofluoro)hydrocarbons (Totally brominated/fluorinated hydrocarbons)
Per(bromofluoro)alkanes
C-O Carbon oxides
Carbon oxide
Carbon dioxide
C-O-H Ethers
Di(linear-alkyl) ethers
Linear polyethers (Linear polyoxaalkanes)
Cyclic monoethers (Monooxacycloalkanes)
Cyclic polyethers (Polyoxacycloalkanes)
Alcohols
Primary linear-alkyl monoalcohols (Alkan-1-ols)
Secondary monoalcohols (Alkan-2-ols)
Ketones
Di(linear-alkyl) ketones (Linear alkanones)
Carbonates (Esters of carbonic acid)
Cyclic carbonates
Pyridine derivatives
Pyridine
Nitriles (Cyanides)
Alkanenitriles (Linear-alkyl cyanides, 1-Cyanoalkanes)
C-N-O-H Cyanoesters
Amides (Carboxamides)
N,N-Dialkylalkanamides
Cyclic N-Alkylamides
Cyclic N-Acylamines
Cyclic N-Acylaminoethers

Landolt-Börnstein
New Series IV/10B
4-10 4.4 Class Index of Organic Systems

C-H + C-H a - Two-phase fluid-fluid C-H + C-H

HMSD LB Page
Linear alkanes + Linear alkanes
CH4 Methane
+ C2H6 Ethane ........................................................... 1221 0022 2-6
+ C3H8 Propane .......................................................... 1221 0023 2-6
+ C4H10 Butane ........................................................... 1221 0024 2-7
+ C5H12 Pentane ........................................................... 1221 0025 2-7
+ C6H14 Hexane ........................................................... 1221 0026 2-8
+ C7H16 Heptane .......................................................... 1221 0027 2-8
+ C8H18 Octane ........................................................... 1221 0028 2-9
C2H6 Ethane
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0050 2-9
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0051 2-10
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0052 2-10
C3H8 Propane
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0053 2-11
+ C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0054 2-11
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0055 2-12
C4H10 Butane
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0056
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0057 2-12
C5H12 Pentane
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0058
+ C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0059
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0060 2-13
C6H14 Hexane
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0061 2-13
C7H16 Heptane
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0062
Cycloalkanes + Linear alkanes
C6H12 Cyclohexane
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0286 2-14
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0408 2-14
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0409
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0411
Linear alkenes + Linear alkanes
C2H4 Ethene
+ C2H6 Ethane ........................................................... 1121 0078 2-15
+ C2H6 Ethane ........................................................... 1221 0199 2-15
+ C2H6 Ethane ........................................................... 1311 0200 2-16
+ C3H8 Propane .......................................................... 1121 0034 2-16
+ C3H8 Propane .......................................................... 1221 0035 2-17
+ C3H8 Propane .......................................................... 1311 0036 2-17
Linear alkenes + Cycloalkanes
C2H4 Ethene
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0410
Benzene + Linear alkanes
C6H6 Benzene
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0268
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0416
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0293
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0418
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0296
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0412
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0297
Benzene + Cycloalkanes
C6H6 Benzene
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0287

Landolt-Börnstein
New Series IV/10B
 4.4 Class Index of Organic Systems 4-11

C-H + C-H a - Two-phase fluid-fluid C-Cl-H + C-Cl-H

HMSD LB Page
Benzene + Alkenes
C6H6 Benzene
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0417
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0298
Alkylbenzenes + Linear alkanes
C7H8 Toluene
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0273 2-18
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0274 2-18
Fluoroalkanes + Arenes
CHF3 Trifluoromethane
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0212 2-19
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0213
+ C8H10 1,4-Dimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0214
+ C9H12 1,3,5-Trimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0215 2-19
Tetrachloromethane + Linear alkanes
CCl4 Tetrachloromethane
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0422
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0304
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0424
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0307
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0425
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0308
Tetrachloromethane + Cycloalkanes
CCl4 Tetrachloromethane
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0068
Tetrachloromethane + Alkenes
CCl4 Tetrachloromethane
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0423
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0306
Tetrachloromethane + Benzene
CCl4 Tetrachloromethane
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0067
Chloroalkanes + Linear alkanes
CH3Cl Chloromethane
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0173 2-20
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0172 2-20
Chloroalkanes + Cycloalkanes
CH3Cl Chloromethane
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0070 2-21
CH2Cl2 Dichloromethane
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0015 2-21
CHCl3 Trichloromethane
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0120
Chloroalkanes + Benzene
CH3Cl Chloromethane
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0069 2-22
CH2Cl2 Dichloromethane
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0014 2-22
CHCl3 Trichloromethane
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0119
Chloroalkanes + Chloroalkanes
CH3Cl Chloromethane
+ C2H5Cl Chloroethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0115

Landolt-Börnstein
New Series IV/10B
4-12 4.4 Class Index of Organic Systems

C-Cl-F + C-H a - Two-phase fluid-fluid C-O-H + CH

HMSD LB Page
Per(chlorofluoro)alkanes + Linear alkanes
CClF3 Chlorotrifluoromethane
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0197 2-23
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0079 2-23
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0198 2-24
CCl2F2 Dichlorodifluoromethane
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0257 2-24
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0259 2-25
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0258 2-25
Per(chlorofluoro)alkanes + Arenes
CClF3 Chlorotrifluoromethane
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0210 2-26
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0211
+ C8H10 1,4-Dimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0217
+ C9H12 1,3,5-Trimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0216 2-26
Chlorofluoroalkanes + Alkanes
CHClF2 Chlorodifluoromethane
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0254 2-27
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0256 2-27
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0255 2-28
+ C6H14 2,3-Dimethylbutane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0264 2-28
Di(linear-alkyl) ethers + Hydrocarbons
C4H10O Diethyl ether
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0064 2-29
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0065 2-29
Cyclic monoethers + Hydrocarbons
C4H8O Oxolane
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0299
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0301
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0302
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0303
Cyclic polyethers + Hydrocarbons
C4H8O2 1,4-Dioxane
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0112 2-30
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0012 2-30
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0011
Primary linear-alkyl monoalcohols + Linear alkanes
CH4O Methanol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0137 2-31
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0096 2-31
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0202 2-32
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0182 2-32
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0262 2-33
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0208 2-33
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0209 2-34
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0097 2-34
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0283 2-35
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0098 2-35
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0284 2-36
C2H6O Ethanol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0138 2-36
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0373 2-37
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0374 2-37
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0084 2-38
C3H8O Propan-1-ol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0371 2-38
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0139 2-39
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0372 2-39
C4H10O Butan-1-ol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0095 2-40

Landolt-Börnstein
New Series IV/10B
 4.4 Class Index of Organic Systems 4-13

C-O-H + C-H a - Two-phase fluid-fluid C-O-H + C-Cl-H

HMSD LB Page
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0144 2-40
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0201 2-41
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0181 2-41
C5H12O Pentan-1-ol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0140 2-42
C6H14O Hexan-1-ol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0143 2-42
C8H18O Octan-1-ol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0141 2-43
C10H22O Decan-1-ol
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0142 2-43
Primary linear-alkyl monoalcohols + Cycloalkanes
CH4O Methanol
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0242 2-44
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0104 2-44
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0244 2-45
C2H6O Ethanol
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0083 2-45
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0017
Primary linear-alkyl monoalcohols + Arenes
CH4O Methanol
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0241 2-46
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0103 2-46
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0243 2-47
C2H6O Ethanol
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0082 2-47
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0016
Di(linear-alkyl) ketones + Linear alkanes
C3H6O Propan-2-one
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1141 0289 2-48
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0090 2-48
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0285 2-49
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0288 2-49
Di(linear-alkyl) ketones + Cycloalkanes
C3H6O Propan-2-one
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0122 2-50
C5H10O Pentan-3-one
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0072 2-50
Di(linear-alkyl) ketones + Benzene
C3H6O Propan-2-one
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0099
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0195 2-51
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0121
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0196 2-51
C5H10O Pentan-3-one
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0071
Di(linear-alkyl) ethers + Chloroalkanes
C2H6O Dimethyl ether
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0447
C4H10O Diethyl ether
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0021 2-52
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0187 2-52
Di(line3r-alkyl) ketones + Chloroalkanes
C3H6O Propan-2-one
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0020 2-53
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0190 2-53

Landolt-Börnstein
New Series IV/10B
4-14 4.4 Class Index of Organic Systems

C-N-H + C-H a - Two-phase fluid-fluid C-N-O-H + C-Cl-F-H

HMSD LB Page
Alkanenitriles + Linear alkanes
C2H3N Ethanenitrile
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0426 2-54
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0427 2-54
N,N-Dialkylalkanamides + Chlorofluoroalkanes
C4H9NO N,N-Dimethylethanamide
+ CHClF2 Chlorodifluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0263

Landolt-Börnstein
New Series IV/10B
 4.5 Class Index of Carbon Dioxide - Organic Systems 4-15

C-H a - Two-phase fluid-fluid C-Cl

HMSD LB Page
Carbon dioxide + Linear alkanes
CO2 Carbon dioxide
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0049
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1222 0437 2-55
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0239 2-55
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1161a 0387 2-56
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0394 2-56
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0093 2-57
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0145 2-57
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0063 2-58
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0240 2-58
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0395
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0238 2-59
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0087 2-59
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0146 2-60
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0237 2-60
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0260 2-61
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0088 2-61
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0171 2-62
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0261 2-62
+ C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0089 2-63
+ C9H20 Nonane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0279 2-63
+ C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0147 2-64
+ C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0266 2-64
+ C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0204 2-65
+ C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0267 2-65
Carbon dioxide + Cycloalkanes
CO2 Carbon dioxide
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0219 2-66
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0185 2-66
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0085 2-67
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0184 2-67
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0188 2-68
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0276 2-68
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0407
Carbon dioxide + Linear alkenes
CO2 Carbon dioxide
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0178 2-69
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0248 2-69
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0250 2-70
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0448 2-70
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0249 2-71
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0251 2-71
Carbon dioxide + Arenes
CO2 Carbon dioxide
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0218 2-72
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0086 2-72
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0415
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0295
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0396 2-73
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0094 2-73
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0136 2-74
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0179 2-74
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0183 2-75
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0278 2-75
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0275
Carbon dioxide + Tetrachloromethane
CO2 Carbon dioxide
+ CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0305
+ CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0421

Landolt-Börnstein
New Series IV/10B
4-16 4.5 Class Index of Carbon Dioxide - Organic Systems

C-O-H a - Two-phase fluid-fluid C-N-O-H

HMSD LB Page
Carbon dioxide + Linear polyethers
CO2 Carbon dioxide
+ C4H10O2 2,5-Dioxahexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0377 2-76
+ C4H10O2 2,5-Dioxahexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0380 2-76
+ C6H14O3 2,5,8-Trioxanonane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0378 2-77
+ C6H14O3 2,5,8-Trioxanonane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0379 2-77
Carbon dioxide + Cyclic ethers
CO2 Carbon dioxide
+ C4H8O Oxolane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0294
+ C4H8O2 1,4-Dioxane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0111
Carbon dioxide + Primary linear-alkyl monoalcohols
CO2 Carbon dioxide
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0431 2-78
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0446 2-78
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0005
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0272 2-79
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0227 2-79
+ C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0432 2-80
+ C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0436 2-80
+ C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0277 2-81
+ C3H8O Propan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0269 2-81
+ C4H10O Butan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0270 2-82
+ C8H18O Octan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0271 2-82
Carbon dioxide + Secondary monoalcohols
CO2 Carbon dioxide
+ C3H8O Propan-2-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0002 2-83
+ C4H10O Butan-2-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0001 2-83
Carbon dioxide + Cyclic carbonates
CO2 Carbon dioxide
+ C4H6O3 (+,-)-Methyl-1,3-dioxolan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0399 2-84
+ C4H6O3 (+,-)-Methyl-1,3-dioxolan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0402 2-84
Carbon dioxide + Pyridine derivatives
CO2 Carbon dioxide
+ C5H5N Pyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0186 2-85
+ C5H5N Pyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0265 2-85
Carbon dioxide + Cyanoesters
CO2 Carbon dioxide
+ C4H5NO2 Methyl cyanoethanoate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0433
Carbon dioxide + Cyclic N-alkylamides
CO2 Carbon dioxide
+ C5H9NO 1-Methylpyrrolidin-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0434 2-86
+ C7H13NO 1-Methylhexahydroazepin-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0400 2-86
+ C7H13NO 1-Methylhexahydroazepin-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0403
Carbon dioxide + Cyclic N-acylamines
CO2 Carbon dioxide
+ C6H11NO N-Formylpiperidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0401 2-87
+ C6H11NO N-Formylpiperidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0404 2-87
Carbon dioxide + Cyclic N-acylaminoethers
CO2 Carbon dioxide
+ C5H9NO2 N-Formylmorpholine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0435

Landolt-Börnstein
New Series IV/10B
 4.6 Class Index of Aqueous-Organic Systems 4-17

C-H a - Two-phase fluid-fluid C-H

HMSD LB Page
Water + Linear alkanes
H2O Water
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0225 2-88
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0154 2-88
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0164 2-89
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0439 2-89
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0325
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0347
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0351
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0311
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0040 2-90
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0124 2-90
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0166 2-91
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0352
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0326
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0345 2-91
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0312
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0037 2-92
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0167 2-92
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0353
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0346
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0313
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0323
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0327
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0354
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0291
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0314
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0038 2-93
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0168 2-93
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0328
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0220 2-94
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0155 2-94
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0169 2-95
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0221 2-95
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0156 2-96
+ C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0170 2-96
+ C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0157 2-97
+ C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0222 2-97
+ C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0193 2-98
+ C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0206 2-98
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0223 2-99
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0158 2-99
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0192 2-100
+ C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0207 2-100
Water + Branched alkanes
H2O Water
+ C4H10 2-Methylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0361
+ C4H10 2-Methylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0292
+ C4H10 2-Methylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0335
+ C5H12 2,2-Dimethylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0355
+ C5H12 2,2-Dimethylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0329
Water + Cycloalkanes
H2O Water
+ C3H6 Cyclopropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0332
+ C3H6 Cyclopropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0358
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0118
+ C8H18 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0233 2-101
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0194 2-101
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0205
Water + Linear alkenes
H2O Water
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0041 2-102
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0165 2-102
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0331

Landolt-Börnstein
New Series IV/10B
4-18 4.6 Class Index of Aqueous-Organic Systems

C-H a - Two-phase fluid-fluid C-O-H

HMSD LB Page
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0357
+ C3H6 Propene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0039
+ C3H6 Propene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0359
+ C3H6 Propene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0333
+ C4H8 But-1-ene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0360
+ C4H8 But-1-ene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0334
Water + Alkynes
H2O Water
+ C2H2 Ethyne . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0330
+ C2H2 Ethyne . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0356
Water + Benzene
H2O Water
+ C6H6 Benzene .......................................................... 1121a 0375 2-103
+ C6H6 Benzene .......................................................... 1221 0232 2-103
+ C6H6 Benzene .......................................................... 1221 0117
+ C6H6 Benzene .......................................................... 1231 0203 2-104
+ C6H6 Benzene .......................................................... 1311 0376 2-104
+ C6H6 Benzene .......................................................... 1351 0042
Water + Perfluorohydrocarbons
H2O Water
+ CF4 Tetrafluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0320
+ CF4 Tetrafluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0341
+ C6F6 Hexafluorobenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0123
Water + Chloroalkanes
H2O Water
+ CH3Cl Chloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0234 2-105
+ C2H5Cl Chloroethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0235 2-105
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0236
Water + Per(chlorofluoro)alkanes
H2O Water
+ CClF3 Chlorotrifluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0342
+ CCl2F2 Dichlorodifluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0343
Water + Per(bromofluoro)alkanes
H2O Water
+ CBrF3 Bromotrifluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0344
Water + Carbon oxides
H2O Water
+ CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0230 2-106
+ CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0162 2-106
+ CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0440 2-107
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0231
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0153 2-107
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0163 2-108
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0043 2-108
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0441 2-109
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0226 2-109
Water + Primary linear-alkyl monoalcohols
H2O Water
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1222 0444 2-110
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0382 2-110
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0381 2-111
+ C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0398 2-111
+ C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0383 2-112
+ C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0384 2-112
Water + Di(linear-alkyl) ketones
H2O Water
+ C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0106

Landolt-Börnstein
New Series IV/10B
 4.7 Index of Systems Containing Inorganic Substances 4-19

H a - Two-phase fluid-fluid Cl
HMSD LB Page
Hydrogen
H2 Dihydrogen
+ Ar Argon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0006 2-113
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0003 2-113
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0224 2-114
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0160 2-114
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0442 2-115
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0397 2-115
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0033 2-116
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0008 2-116
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0282 2-117
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0030 2-117
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0101 2-118
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0074 2-118
Helium
He Helium
+ Ar Argon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0044 2-119
+ Ar Argon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0077 2-119
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0315
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0322 2-120
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0337
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0075 2-120
Neon
Ne Neon
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0317
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0339
Argon
Ar Argon
+ ClH Hydrogen chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0392 2-121
+ ClH Hydrogen chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0393 2-121
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0229 2-122
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0159 2-122
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0300
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0336
+ H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0046
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0385 2-123
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0032 2-123
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0007 2-124
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0386 2-124
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0100 2-125
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0029 2-125
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0073 2-126
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0281 2-126
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0405
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0413
+ CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0419
Krypton
Kr Krypton
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0316
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0338
Xenon
Xe Xenon
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0319
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0340
Hydrogen chloride
ClH Hydrogen chloride
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0129

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4-20 4.7 Index of Systems Containing Inorganic Substances

O a - Two-phase fluid-fluid N
HMSD LB Page
Oxygen
O2 Dioxygen
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0290
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0324
+ H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0318
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0018
Water
H2O Water
+ F6S Sulfur hexafluoride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0321
+ H2S Dihydrogen sulfide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0127 2-127
+ H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0105
+ H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0348
+ H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0349
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0228 2-127
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0152 2-128
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0161 2-128
+ N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0443 2-129
+ O2S Sulfur dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0110 2-129
Hydrogen sulfide
H2S Dihydrogen sulfide
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0366 2-130
Sulfur hexafluoride
F6S Sulfur hexafluoride
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0180 2-130
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0174 2-131
+ C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0246 2-131
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0252 2-132
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0176 2-132
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0253 2-133
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0132 2-133
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0134 2-134
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0130 2-134
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0128 2-135
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0135 2-135
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0133 2-136
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0175 2-136
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0177 2-137
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0189 2-137
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0247 2-138
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0245 2-138
Sulfur dioxide
O2S Sulfur dioxide
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0125 2-139
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0126 2-139
Nitrogen
N2 Dinitrogen
+ H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0048 2-140
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0031 2-140
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0102 2-141
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0076 2-141
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0430 2-142
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0280 2-142
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0367 2-143
+ C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0368 2-143
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0370 2-144
+ C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0369 2-144
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0391 2-145
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0150 2-145
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0149 2-146
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0406
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0019 2-146

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 4.7 Index of Systems Containing Inorganic Substances 4-21

N a - Two-phase fluid-fluid N
HMSD LB Page
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0390 2-147
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0151 2-147
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0148 2-148
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0414
+ CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0004 2-148
+ CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0420
+ CH3Cl Chloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0113 2-149
+ C2H5Cl Chloroethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0114 2-149
+ CH2Cl2 Dichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0013
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0388 2-150
+ CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0116 2-150
+ C4H8O2 1,4-Dioxane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0010
+ CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0080 2-151
+ C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0081 2-151
+ CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1131 0445 2-152
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0350 2-152
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0365 2-153
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1222 0438 2-153
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1232 0362 2-154
+ C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0389 2-154
+ C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0009 2-155
+ C5H10O Pentan-3-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0066 2-155
Ammonia
H3N Ammonia
+ CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0047 2-156
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0109 2-156
+ C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0045 2-157
+ C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0108 2-157
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0107
Dinitrogen oxide
N2O Dinitrogen oxide
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0363 2-158
+ C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0364 2-158
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0428 2-159
+ C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0429 2-159
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0309 2-160
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0191 2-160
+ C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0310 2-161
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0091 2-161
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0092 2-162
+ CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0131 2-162

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New Series IV/10B
4-22 4.8 Formula Index of Systems

Ar a - Two-phase fluid-fluid H2O

Formula
Comp. 1 Comp. 2 Name HMSD LB Page
Ar Argon
ClH Hydrogen chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0392 2-121
ClH Hydrogen chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0393 2-121
H2 Dihydrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0006 2-113
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0229 2-122
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0159 2-122
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0300
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0336
H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0046
He Helium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0044 2-119
He Helium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0077 2-119
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0385 2-123
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0032 2-123
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0007 2-124
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0386 2-124
CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0419
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0100 2-125
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0029 2-125
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0073 2-126
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0281 2-126
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0413
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0405
ClH Hydrogen chloride
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0129
F6S Sulfur hexafluoride
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0321
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0175 2-136
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0177 2-137
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0189 2-137
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0247 2-138
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0245 2-138
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0180 2-130
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0174 2-131
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0246 2-131
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0252 2-132
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0176 2-132
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0253 2-133
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0132 2-133
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0134 2-134
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0130 2-134
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0128 2-135
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0135 2-135
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0133 2-136
H2 Dihydrogen
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0003 2-113
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0224 2-114
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0160 2-114
H2O Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0442 2-115
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0397 2-115
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0033 2-116
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0008 2-116
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0282 2-117
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0030 2-117
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0101 2-118
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0074 2-118
H2O Water
H2S Dihydrogen sulfide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0127 2-127
H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0105
H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0348
H3N Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0349
He Helium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0315 2-120
He Helium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0322
He Helium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0337
Kr Krypton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0316
Kr Krypton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0338
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0228 2-128
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0152 2-128

Landolt-Börnstein
New Series IV/10B
 4.8 Formula Index of Systems 4-23

H2O a - Two-phase fluid-fluid H2O

Formula
Comp. 1 Comp. 2 Name HMSD LB Page
H2O Water (cont.)
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0161 2-129
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0443 2-129
Ne Neon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0317
Ne Neon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0339
O2 Dioxygen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0290
O2 Dioxygen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0324
O2 Dioxygen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0318
O2S Sulfur dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0110 2-127
Xe Xenon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0319
Xe Xenon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0340
CBrF3 Bromotrifluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0344
CClF3 Chlorotrifluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0342
CCl2F2 Dichlorodifluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0343
CF4 Tetrafluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0320
CF4 Tetrafluoromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0341
CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0236
CH3Cl Chloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0234 2-105
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0225 2-88
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0154 2-88
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0164 2-89
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0439 2-89
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0325
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0347
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0351
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0311
CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1222 0444 2-110
CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0382 2-110
CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0381 2-111
CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0230 2-106
CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0162 2-106
CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0440 2-109
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0231
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0153 2-107
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0163 2-107
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0043 2-108
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0441 2-108
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0226 2-109
C2H2 Ethyne . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0330
C2H2 Ethyne . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0356
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0041 2-102
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0165 2-102
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0331
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0357
C2H5Cl Chloroethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0235 2-105
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0040 2-90
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0124 2-90
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0166 2-91
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0352
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0326
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0345 2-91
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0312
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0398 2-111
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0383 2-112
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0384 2-112
C3H6 Cyclopropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0332
C3H6 Cyclopropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0358
C3H6 Propene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0039
C3H6 Propene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0359
C3H6 Propene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0333
C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0106
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0037 2-92
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0167 2-92
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0353
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0346
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0313
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1332 0323

Landolt-Börnstein
New Series IV/10B
4-24 4.8 Formula Index of Systems

H2O a - Two-phase fluid-fluid N2

Formula
Comp. 1 Comp. 2 Name HMSD LB Page
H2O Water (cont.)
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0327
C4H8 But-1-ene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0360
C4H8 But-1-ene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0334
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0354
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0291
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0314
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0038 2-93
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0168 2-93
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0328
C4H10 2-Methylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0361
C4H10 2-Methylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0292
C4H10 2-Methylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0335
C5H12 2,2-Dimethylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0355
C5H12 2,2-Dimethylpropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0329
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0220 2-94
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0155 2-94
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0169 2-95
C6F6 Hexafluorobenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0123
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0375 2-103
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0232 2-103
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0117
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0203 2-104
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0376 2-104
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0042
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0118
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0194 2-101
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0205
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0221 2-95
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0156 2-96
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0170 2-96
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0157 2-97
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0222 2-97
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0193 2-98
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0206 2-98
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0223 2-99
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0158 2-99
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0192 2-100
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0207 2-100
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0223 2-101
H2S Dihydrogen sulfide
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0366 2-130
H3N Ammonia
N2 Dinitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0048 2-140
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0047 2-155
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0107
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0045 2-156
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0108 2-156
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0109 2-155
He Helium
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0075 2-120
N2 Dinitrogen
O2 Dioxygen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0018
CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0004 2-148
CCl4 Tetrachloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0420
CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0388 2-150
CHCl3 Trichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0116 2-150
CH2Cl2 Dichloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0013
CH3Cl Chloromethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0113 2-149
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0031 2-140
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0102 2-141
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0076 2-141
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0430 2-142
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0280 2-142
CH4O Methanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0080 2-151
CO Carbon oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1131 0445
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0350 2-152

Landolt-Börnstein
New Series IV/10B
 4.8 Formula Index of Systems 4-25

N2 a - Two-phase fluid-fluid CHClF2

Formula
Comp. 1 Comp. 2 Name HMSD LB Page
N2 Dinitrogen (cont.)
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0365 2-152
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1222 0438 2-153
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1232 0362 2-153
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0019 2-146
C2H5Cl Chloroethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0114 2-149
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0081 2-151
C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0389 2-154
C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0009 2-154
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0367 2-143
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0368 2-143
C4H8O2 1,4-Dioxane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0010
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0370 2-144
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0369 2-144
C5H10O Pentan-3-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0066
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0390 2-147
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0151 2-147
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0148 2-148
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0414
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0391 2-145
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0150 2-145
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0149 2-146
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0406
N2O Dinitrogen oxide
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0091 2-160
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0092 2-161
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0131 2-161
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0363 2-157
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0364 2-157
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0428 2-158
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0429 2-158
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0309 2-159
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0191 2-159
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0310 2-160
O2S Sulfur dioxide
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0126 2-139
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0125 2-139
CClF3 Chlorotrifluoromethane
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0197 2-23
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0079 2-23
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0198 2-24
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0210 2-26
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0211
C8H10 1,4-Dimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0217
C9H12 1,3,5-Trimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0216 2-26
CCl2F2 Dichlorodifluoromethane
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0257 2-24
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0259 2-25
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0258 2-25
CCl4 Tetrachloromethane
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0422
CH4 Methane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0304
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0305
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0421
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0423
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0306
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0424
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0307
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0425
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0308
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0067
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0068
CHClF2 Chlorodifluoromethane
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0254 2-27
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0256 2-27
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0255 2-28
C4H9NO N,N-Dimethylethanamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0263

Landolt-Börnstein
New Series IV/10B
4-26 4.8 Formula Index of Systems

CHClF2 a - Two-phase fluid-fluid CO2

Formula
Comp. 1 Comp. 2 Name HMSD LB Page
CHClF2 Chlorodifluoromethane (cont.)
C6H14 2,3-Dimethylbutane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0264 2-28
CHCl3 Trichloromethane
C2H6O Dimethyl ether . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0447
C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0020 2-53
C3H6O Propan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0190 2-53
C4H10O Diethyl ether . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0021 2-52
C4H10O Diethyl ether . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1242 0187 2-52
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0119
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0120
CHF3 Trifluoromethane
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0212 2-19
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0213
C8H10 1,4-Dimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0214
C9H12 1,3,5-Trimethylbenzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1331 0215 2-19
CH2Cl2 Dichloromethane
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0014 2-22
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0015 2-21
CH3Cl Chloromethane
C2H5Cl Chloroethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0115
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0173 2-20
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0172 2-20
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0069 2-22
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0070 2-21
CH4 Methane
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0049
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1222 0437 2-57
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0022 2-6
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0023 2-6
C4H8O Oxolane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0299
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0024 2-7
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0025 2-7
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0268
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0416
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0293
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0286 2-14
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0408 2-14
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0026 2-8
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0027 2-8
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0028 2-9
CH4O Methanol
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0431 2-78
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0446 2-78
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0005
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0272 2-79
CO2 Carbon dioxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0227 2-79
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0137 2-31
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0096 2-31
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0202 2-32
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0182 2-33
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0262 2-33
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0208 2-34
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0209 2-34
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0097 2-35
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0283 2-35
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0241 2-46
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0103 2-46
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0243 2-47
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0242 2-44
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0104 2-44
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0244 2-45
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0098 2-36
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0284 2-36
CO2 Carbon dioxide
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0178 2-69
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0248 2-69
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0250 2-70

Landolt-Börnstein
New Series IV/10B
 4.8 Formula Index of Systems 4-27

CO2 a - Two-phase fluid-fluid CO2

Formula
Comp. 1 Comp. 2 Name HMSD LB Page
CO2 Carbon dioxide (cont.)
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1251 0448 2-70
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0249 2-71
C2H4 Ethene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0251 2-71
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0239 2-55
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1161a 0387 2-55
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0394 2-56
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0093 2-56
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0145 2-57
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0063 2-58
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0240 2-58
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0395
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0432 2-80
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0436 2-80
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0277 2-81
C3H8O Propan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0269 2-81
C3H8O Propan-2-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0002 2-83
C4H5NO2 Methyl cyanoethanoate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0433
C4H6O3 (+,-)-Methyl-1,3-dioxolan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0399 2-84
C4H6O3 (+,-)-Methyl-1,3-dioxolan-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0402 2-84
C4H8O Oxolane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0294
C4H8O2 1,4-Dioxane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0111
C4H10O Butan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0270 2-82
C4H10O Butan-2-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0001 2-83
C4H10O2 2,5-Dioxahexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0377 2-76
C4H10O2 2,5-Dioxahexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0380 2-76
C5H5N Pyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0186 2-85
C5H5N Pyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0265 2-85
C5H9NO 1-Methylpyrrolidin-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0434 2-86
C5H9NO2 N-Formylmorpholine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0435
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0238 2-59
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0087 2-59
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0146 2-60
C5H12 Pentane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0237 2-60
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0218 2-72
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0086 2-72
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0415
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0295
C6H11NO N-Formylpiperidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0401 2-87
C6H11NO N-Formylpiperidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0404 2-87
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0219 2-66
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0185 2-66
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0085 2-67
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0184 2-67
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0188 2-68
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0276 2-68
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0407
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0260 2-61
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0088 2-61
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0171 2-62
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0261 2-62
C6H14O3 2,5,8-Trioxanonane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0378 2-77
C6H14O3 2,5,8-Trioxanonane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0379 2-77
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0396 2-73
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0094 2-73
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0136 2-74
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0179 2-74
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0183 2-75
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0278 2-75
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0275
C7H13NO 1-Methylhexahydroazepin-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0400 2-86
C7H13NO 1-Methylhexahydroazepin-2-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0403
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0089 2-63
C8H18O Octan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0271 2-82
C9H20 Nonane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0279 2-63
C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0147 2-64
C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0266 2-64

Landolt-Börnstein
New Series IV/10B
4-28 4.8 Formula Index of Systems

CO2 a - Two-phase fluid-fluid C4H10

Formula
Comp. 1 Comp. 2 Name HMSD LB Page
CO2 Carbon dioxide (cont.)
C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0204 2-65
C10H22 Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0267 2-65
C2H3N Ethanenitrile
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121a 0426 2-54
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0427 2-54
C2H4 Ethene
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0078 2-15
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0199 2-15
C2H6 Ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0200 2-16
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0034 2-16
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0035 2-17
C3H8 Propane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0036 2-17
C4H8O Oxolane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0303
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0417
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0298
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0410
C2H6 Ethane
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0138 2-37
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0373 2-37
C2H6O Ethanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0374 2-38
C3H8O Propan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0371 2-39
C3H8O Propan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0139 2-39
C3H8O Propan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311a 0372 2-40
C4H8O Oxolane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0301
C4H10 Butane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0050 2-9
C4H10O Butan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0201 2-32
C4H10O Butan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0095 2-40
C4H10O Butan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0144 2-41
C5H12O Pentan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0140 2-42
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0418
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0296
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0409
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0051 2-10
C6H14O Hexan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0143 2-42
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0052 2-10
C8H18O Octan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0141 2-43
C10H22O Decan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0142 2-43
C2H6O Ethanol
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0082 2-47
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0016
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0083 2-45
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0017
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0084 2-38
C3H6O Propan-2-one
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0099
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0195 2-51
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0121
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0196 2-51
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0122 2-50
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1141 0289 2-48
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0090 2-48
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1231 0285 2-49
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1351 0288 2-49
C3H8 Propane
C4H8O Oxolane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0302
C4H8O2 1,4-Dioxane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0112 2-30
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0412
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0297
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1333 0411
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0053 2-11
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0054 2-11
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0055 2-12
C4H8O2 1,4-Dioxane
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0011
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0012 2-30

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 4.8 Formula Index of Systems 4-29

C4H10 C7H16
Formula
Comp. 1 Comp. 2 Name HMSD LB Page
C4H10 Butane
C4H10O Butan-1-ol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0181 2-41
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0056
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0057 2-12
C4H10O Diethyl ether
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0065 2-29
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0064 2-29
C5H10O Pentan-3-one
C6H6 Benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0071
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0072 2-50
C5H12 Pentane
C6H14 Hexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0058
C7H16 Heptane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0059
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0060 2-13
C6H6 Benzene
C6H12 Cyclohexane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1241 0287
C6H14 Hexane
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1121 0273 2-18
C7H8 Toluene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1311 0274 2-18
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0061 2-13
C7H16 Heptane
C8H18 Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1221 0062

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 3 Instructions on using the computer program ELBT 3-1

3 Instructions on using the computer program ELBT

Electronic supplementary material is available at http://dx.doi.org/10.1007/11005155_3

and accessible for authorized users.

3.1 Introduction

The ELBT Program on the CD accompanying the printed volume permits to search, retrieve, display and
export the 448 numerical data sets in the five formats: PDF, SELF, ELDATA, and the XML versions of
SELF and ELDATA described in Chap. 2.1, 3.5.2, and 3.5.3. The SI units of pressure, temperature and
molar energy in the ELDATA numerical and graphical displays may be converted into several practical
units. The Program permits in some cases the correlation of the experimental data by means of a few
equations (Chap. 3.5.5) and save the results of the calculation in a separate file (Chap. 3.5.6).
The ELBT Program can be used both in conjunction with, or independently from, the book. This Chapter
describes requirements and procedures for installing, starting and using the Program with the book. This assumes
the mixture is either one selected from the Class Indexes Chap. 4.4, 4.5, 4.6, or 4.7 or one printed as a PDF table
in Chap. 2.2, 2.3, or 2.4. In both cases, the File Number: LBnnnn is specified either in column 4 of the Index,
or on the top of the PDF table.
The ELBT Program on the CD includes a large, but not exhaustive, bibliographical database, HMSD’2005,
giving 3444 references to experimental (calorimetric) heat of mixing and solution measurements for 10867 two-
to six-component systems. These components are organic or inorganic electrolytes and nonelectrolytes, ionic
liquids, alloys, fused salts, polymers and other materials.
Instructions on Using the Computer Program ELBT independently from the book are given in detail in the
ELBT_Guide.pdf file supplied on the CD. Moreover, the Windows Help offers a full Manual-on-Line. The
Program allows the retrieval of bibliographical and numerical data using any single or combined search criterion
based on the enthalpy of mixing property type, chemical system (a single component or the multicomponent
system), and/or the reference (authors, original source of data, and/or year range of publication) .

3.2 System requirements

The ELBT software works on IBM®-compatible PC under Microsoft Windows®98 or later. It requires a CD-
ROM drive, a minimum of 16 MB RAM, 20 MB available hard disk space, and Adobe®Acrobat® Reader version
4.0 or later. Microsoft® Office Excel 2002 or later is requested to display SpreadsheetML documents (Chap. 3.6).

3.3 Installing the program

Insert the CD-ROM into the drive. From Windows Explorer open the readme.txt file in the root directory of the
CD-ROM. This file contains important information regarding the installation of Adobe®Acrobat® Reader and the
ELBT Program. After reading this information, click on ELBT_program. To proceed with the installation, run
the setup.exe application and follow the screen instructions in the setup procedure. The program will be installed
in the specified drive and directory (default C:\ ELBT10B).

Landolt-Börnstein
New Series IV/10B
3-2 3 Instructions on using the computer program ELBT

3.4 To start

When the installation is complete click the OK button on the Opening screen (Fig. 3.1) displaying the dialog box
(Fig. 3.2). Check out the Data File Name (direct access) option and click OK.

Fig. 3.1 Opening screen

Fig. 3.2 Select the primary search option

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-3

Enter the file number in the box and press the Select button (Fig. 3.3)

Fig. 3.3 Input of the file number

This displays the following (Fig. 3.4):

Fig. 3.4. Descriptors and menu entries for a numerical data file

This allows viewing of reference, chemical system, and property type descriptors of the selected file.

Landolt-Börnstein
New Series IV/10B
3-4 3 Instructions on using the computer program ELBT

3.5 Visualization of numerical data

In order to visualize the numerical data, choose the menu entry Data command (Fig. 3.4) and select from the
following dialog box (Fig. 3.5) the display format:

Fig. 3.5 Select the display format of numerical data

3.5.1 PDF display

The PDF display looks similar to the tables printed in Chap. 2. In addition, the property type descriptor
(Chap. 2.1.1) appears on the top of the table.

3.5.2 SELF (Standard ELectronic File) display

The concept of a Standard ELectronic File (SELF) format has been developed in 1998-2002 by the Task Group
on Standard Physico-Chemical Data Formats (IUCOSPED) of the International Union of Pure and Applied
Chemistry (IUPAC) and the Committee on Data for Science and Technology (CODATA) in cooperation with
the International Council of Scientific and Technical Information (ICSTI). A data portal, called DataExplorer,
implemented SELFs for a variety of physico-chemical properties. The structure of the ELBT SELFs follows the
general format of IUCOSPED SELFs.

3.5.2.1 SELF structure. Identifiers

Each SELF consists of two sections:

HEADER - contains four Digital Object Identifiers (DOIs) for: SELF name, original source of data, property
type, and chemical system
BODY - contains the numerical data and eventually some auxiliary identifiers

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-5

Example:

10.1007/b97686/2005.LB0034
S0021-9614(1996)28;905;921;0
HMSD1121
74-85-1
74-98-6
[NL] 2
10.1007/b97686/2005.LB0035
10.1007/b97686/2005.LB0036
[NP] 6
[P1] .500000E+07[EP1C].10E+06[EP1A].10E+06
[P2] .273150E+03[EP2C].20E-01[EP2A].20E-01
[NX1] 25
[X1] .000000E+00[EX1].00E+00[Y1] .000000E+00[EY1].00E+00
[X1] .211000E-01[EX1].10E-03[Y1]-.300000E+01[EY1].26E+00
[X1] .634000E-01[EX1].10E-03[Y1]-.210000E+02[EY1].62E+00
...
[X1] .897300E+00[EX1].10E-03[Y1]-.151000E+03[EY1].32E+01
[X1] .946800E+00[EX1].10E-03[Y1]-.800000E+02[EY1].18E+01
[X1] .100000E+01[EX1].00E+00[Y1] .000000E+00[EY1].00E+00
[P1] .600000E+07[EP1C].10E+06[EP1A].10E+06
[P2] .273150E+03[EP2C].20E-01[EP2A].20E-01
[NX1] 27
[X1] .000000E+00[EX1].00E+00[Y1] .000000E+00[EY1].00E+00
[X1] .281000E-01[EX1].10E-03[Y1]-.200000E+01[EY1].24E+00
[X1] .677000E-01[EX1].10E-03[Y1]-.600000E+01[EY1].32E+00
...
[X1] .941000E+00[EX1].10E-03[Y1]-.820000E+02[EY1].18E+01
[X1] .970100E+00[EX1].10E-03[Y1]-.360000E+02[EY1].92E+00
[X1] .100000E+01[EX1].00E+00[Y1] .000000E+00[EY1].00E+00
[P1] .750000E+07[EP1C].10E+06[EP1A].10E+06
[P2] .273150E+03[EP2C].20E-01[EP2A].20E-01
[NX1] 25
[X1] .000000E+00[EX1].00E+00[Y1] .000000E+00[EY1].00E+00
[X1] .307000E-01[EX1].10E-03[Y1]-.700000E+00[EY1].21E+00
[X1] .615000E-01[EX1].10E-03[Y1]-.270000E+01[EY1].23E+00
...

Fig. 3.6 Structure of a SELF (single-phase binary system)

where:

10.1007/b97686/2005.LB0034
is the File Identifier (SELF Name), incorporating the identifier of the publisher (10.1007), of the publication
(b97686), and the year of publication (2005). LB0034 is the File Number.

S0021-9614(1996)28;905;921;0
is the Original Reference Identifier, incorporating the SELF identifier of the original source of data (S0021-
9614), the year of publication (1996), the volume (28), the first and last page numbers, and a serial number
(usually 0), to distinguish papers having the same first page number (905;921;0).

HMSD1121
is the Property Type Identifier, incorporating the Property Group Identifier (HMSD).

Landolt-Börnstein
New Series IV/10B
3-6 3 Instructions on using the computer program ELBT

The descriptors of the 18 property types (Chap. 2.1.1) included in the numerical database are stored in the
ELBT10BPropTypes.txt file (Fig. 3.7) on the same drive as the program.

Example:

Property Code: [HMSD1311] HEAT OF MIXING AND SOLUTION

State : Two-component system, single-phase fluid or two-phase
fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: [P1] P/Pa Pressure
[P2] T/K Temperature
Variables: [X1] x1/- Mole fraction of component 1
[Y1] HM/J mol-1 Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and
constant P and T
#
etc. etc.

Fig. 3.7 Structure of the ELBT10BPropTypes.txt file

10.1007/b97686/2005.LB0035
10.1007/b97686/2005.LB0036
are the file names of two Linked Files (see Chap. 3.5.2.8).

74-85-1
74-98-6
are the Substance Identifiers, here the CAS registry numbers of the two components, 1 and 2.

The descriptors of the 79 substances included in the numerical database are stored in the
ELBT10BSubstances.txt file (Fig. 3.8) on the same drive as the program.

72-28-5
C4 H10
2-Methylpropane
Isobutane
R 600a
R-600a
#
75-45-6
C H Cl F2
Chlorodifluoromethane
Freon 22
HCFC 22
HCFC-22
R 22
R-22
#
etc. etc.

Fig. 3.8 Structure of the ELBT10BSubstances.txt file

The first line is the substance identifier (CAS RN), the following lines are the molecular formula, primary name,
and alternate names (if any).

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-7

The descriptors of the 163 References included in the numerical database are stored in the
ELBT10BReferences.txt file (Fig. 3.9) on the same drive as the program.

S0021-9614(1986)18;545;550;0
Lancaster, N. M.; Wormald, C. J.
The molar enthalpies for {xH2O + (1-x)C3H6}(g), {xH2O + (1-x)C3H8}(g),
and {xH2O + (1-x)C4H10}(g)
J. Chem. Thermodyn. 1986, 18, 545-550.
#
S0021-9614(1970)2;881;895;0
Lee, J. I.; Mather, A. E.
The excess enthalpy of gaseous mixtures of nitrogen and carbon dioxide
J. Chem. Thermodyn. 1970, 2, 881-895.
see also
T0001-0014(1970);1;121;0
Lee, J. I.
The excess enthalpy of gaseous mixtures
M. Sc. Thesis (Univ. Alberta, Edmonton, Canada) 1970, , 1-121.
etc. etc.

Fig. 3.9 Structure of the ELBT10BReferences.txt file

The first line is the original reference identifier.

3.5.2.2 Physical quantities and physico-chemical properties

This volume refers to eight physical quantities: HM - molar enthalpy of mixing, HE - molar excess enthalpy,
∞ $
Hsol - molar enthalpy of solution, H sol - molar enthalpy of solution at infinite dilution, H sol - standard molar
enthalpy of solution, P - pressure, T - temperature, and x1 mole fraction of component 1. They are all
intensive quantities, i.e. their magnitudes are independent of the extent of the chemical system.
The physico-chemical properties are functional relationships between these quantities, e.g. HE (x1) at
constant P and T, or HM (P) at constant x1 and T, etc.

3.5.2.3 Independent variables and dependent variables

Generally, each property type is characterized by a group of 'independent variables' and a group of 'dependent
variables'. There must be at least one independent variable and one dependent variable.
∞ $
In the 18 property types of this volume HM, HE, Hsol , H sol , or H sol is the dependent variable. In the property
types HMSD1111, HMSD1121, HMSD1131, HMSD1161, HMSD1221, HMSD1222, HMSD1311, and
HMSD1331 the independent variable is x1. In the property types HMSD1141, HMSD1231, HMSD1232, and
HMSD1351, the independent variable is P. In the property types HMSD1241, HMSD1242, HMSD1332, and
HMSD1333 the independent variable is T. In the property types HMSD1151 and HMSD1251 P, T, and x1 are
independent variables.

3.5.2.4 Parameters

Generally, in the case of physico-chemical properties consisting of three or more physical quantities, all the
physical quantities remaining after selecting the independent and the dependent variables are considered as
'parameters', if they take one or several discrete constant values. E.g. in the property types HMSD1121 and
HMSD1141 the parameters are, respectively, P, T and T, x1. In the property type HMSD1111 the data are taken
at a low P that does not affect HE. Accordingly the value of P is not specified. In the property type. HMSD1131

Landolt-Börnstein
New Series IV/10B
3-8 3 Instructions on using the computer program ELBT

the data are taken at the saturation P and one or several discrete constant values of T. Accordingly, T is a
parameter and P is a dependent variable. However, the value of P, a vapor-liquid equilibrium property, is not
specified in a HMSD type table, often it is not even known. In the property types HMSD1332 the parameter is P.
The property type HMSD1333 refers to the standard enthalpy of solution at infinite dilution of an ideal gas in a
liquid, T is the variable and there is no parameter.

3.5.2.5 Symbols, units and scales of physical quantities

In PDF files the symbols used for molar enthalpy, pressure, temperature, and mole fraction are those
recommended by IUPAC.
The symbols [X1], [X2], etc. used for independent variables, [Y1], [Y2], etc. used for dependent variables,
and [P1], [P2], etc. used for parameters in SELF and ELDATA files, are functional symbols having nothing in
common with the physical symbols.
All the physical quantities are reported in SI units (product or quotient of SI base units), without multiple or
submultiple prefixes. So there is no need to specify the unit in the SELFs.
Whenever necessary, values taken from the literature have been converted into SI units using the appropriate
conversion factors. Temperatures are based on the International Temperature Scale of 1990 (ITS-90). The molar
quantities are based on the 1999 table of the IUPAC Commission on Atomic Weights and Isotopic Abundances.
The standard atomic weights apply to elements as they exist naturally on Earth (natural abundance of the stable
nuclides) (04LID1).

Symbol Physical Quantity SI Unit

M
H Molar enthalpy of mixing joule per mole (J mol–1 = kg m2s–2mol–1)
HE Molar excess enthalpy joule per mole (J mol–1 = kg m2s–2mol–1)
Hsol Molar enthalpy of solution joule per mole (J mol–1 = kg m2s–2mol–1)
∞
H sol Molar enthalpy of solution at infinite dilution joule per mole (J mol–1 = kg m2s–2mol–1)

$
H sol Standard molar enthalpy of solution joule per mole (J mol–1 = kg m2s–2mol–1)

P Pressure pascal (Pa = N m–2 = kg m–1s–2)

T Temperature kelvin (K)
x Mole fraction (dimensionless)

The year of publication of a SELF appears in the SELF name. If it differs from the year of publication of the
original source of data, then temperatures and molar quantities should be converted to the above-mentioned
scales. The corrections being within the limits of uncertainties of the measured quantities they were not
applied to the data reported in this volume.

3.5.2.6 Numerical data and estimated uncertainties

In the body of the SELF or ELDATA file of a property type including parameters, [NP] represents the number
of parameter sets (not the number of parameters) and [NX1] the number of data points in each set (block) of
parameters. The numerical values are expressed in engineering style, starting with either a space, in case of
positive values, or the – (minus) sign in the case of negative values, followed by a decimal point, then usually by
six digits, the letter E for exponent (base 10), a + (plus) or – (minus) sign, and two digits which indicate the
power of 10.
In the data files each measured physical quantity is accompanied by its absolute uncertainty. The symbols:
[EX1], [EX2], etc. and [EY1], [EY2], etc. are used, respectively, for the independent and the dependent

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-9

variables. The uncertainties are expressed by a decimal point, followed by two digits, the letter E for exponential
(base 10), a + (plus) or – (minus) sign, and two digits which indicate the power of 10 (see example, Fig. 3.6).
Two uncertainties assigned to parameters: [EPC1], [EPC2], etc. express the reproducibility of the
'constant' values of the parameters. [EPA1], [EPA2], etc. express the absolute experimental uncertainty of
the parameters. In the example on p. 3-10, Fig. 3.10, [P2].323150E+03[EP2C].10E-02[EP2A].20E-
01 means the measurements are isothermal to within [EP2C].10E-02 (0.001 K), but the ITS-90
temperature itself, [P2] .323150E+03 (323.15 K), is known with an accuracy of only [EP2A].20E-01
(0.02 K).
The uncertainties of the different quantities, if reported by the authors, are given in the SELFs and identically
in the corresponding ELDATA files. In many cases additions and corrections were necessary. In view of the
difficulty of assigning the uncertainties for this type of measurements, the reported values should be regarded as
rough estimates and used with care.
In the footnote of the PDF tables, only estimates of the overall uncertainties of the main physical quantities,
usually of x1 and the enthalpy, e.g., HE, are given in terms of ı(x1 ), the average uncertainty of x1 , and of ırel(HE),
the average relative uncertainty of HE , or more generally of ı(HE) /J mol–1 = a + b | HE/J mol–1|, the average
absolute uncertainty of HE (where b may be equal to zero).

3.5.2.7 Two-phase fluid-fluid systems

In the case of two-phase fluid-fluid systems the HE or HM data are presented in the body of a SELF or ELDATA
file in five distinct blocks. This is marked by [NB] 5.
In the example Fig. 3.10, for the parameter values [P1] .500000E+07 (5.0·106Pa) and [P2]
.323150E+03 (T = 323.15 K):
the first block contains [NX1] 9 HM data points in the homogeneous region at mole fractions of component
1 from [X1] .000000E+00 (x1 = 0.0000) to [X1] .319400E+00 (x1 = 0.3194);
the fifth block contains [NX1] 3 HM data points in the homogeneous region at mole fractions of
component 1 from [X1] .988200E+00 (x1 = 0.9882) to [X1] .100000E+01 (x1 = 1.0000);
the third block contains [NX1] 14 HM data points in the heterogeneous region at mole fractions of
component 1 from [X1] .365500E+00 (x1 = 0.3655) to [X1] .985900E+00 (x1 = 0.9859). In this
region HM is a linear function of x1 (Chap. 1.2);
the second and fourth blocks contain [NX1] 1 data point each, which are the HM values on the two-phase
fluid-fluid equilibrium phase boundary curve at mole fractions of component 1 [X1] .352000E+00 (x1 =
0.3520) and [X1] .987800E+00 (x1 = 0.9878). These values are usually obtained by analytical or graphical
determination of the intersection points of the HM(x1) curve in the homogeneous regions with the HM(x1) line in
the heterogeneous region.
In case of absence of data in a block, [NX1] 0.

3.5.2.8 Linked data files

Linked data files contain data for a given system in different regions of the phase diagram, therefore
corresponding to different property types, which were obtained in the same apparatus and are reported in the
same publication. E. g. the file in Fig. 3.10, file number LB0374, property type HMSD1311, contains HM data
for a mixture of pure component 1 in the gas or supercritical fluid state, and pure component 2 in the liquid state.
This file is linked to another numerical data file, file number LB0373, containing HE data for the same mixture in
which both components are in the liquid state, property type HMSD1121. The source of data is the same.

Landolt-Börnstein
New Series IV/10B
3-10 3 Instructions on using the computer program ELBT

10.1007/b97686/2005.LB0374
S0021-9614(1990)22;683;694;0
HMSD1311
74-84-0
64-17-5
[NL] 1
10.1007/b97686/2005.LB0373
[NP] 6
[P1] .500000E+07[EP1C].10E+05[EP1A].10E+05
[P2] .323150E+03[EP2C].10E-02[EP2A].20E-01
[NB] 5
[NX1] 9
[X1] .000000E+00[EX1].00E+00[Y1] .000000E+00[EY1].00E+00
[X1] .357000E-01[EX1].50E-03[Y1]-.224900E+03[EY1].11E+02
[X1] .725000E-01[EX1].50E-03[Y1]-.440100E+03[EY1].12E+02
...
[X1] .231900E+00[EX1].50E-03[Y1]-.134120E+04[EY1].17E+02
[X1] .274900E+00[EX1].50E-03[Y1]-.151560E+04[EY1].18E+02
[X1] .319400E+00[EX1].50E-03[Y1]-.171550E+04[EY1].19E+02
[NX1] 1
[X1] .352000E+00[EX1].50E-03[Y1]-.182200E+04[EY1].10E+03
[NX1] 14
[X1] .365500E+00[EX1].50E-03[Y1]-.176130E+04[EY1].19E+02
[X1] .413100E+00[EX1].50E-03[Y1]-.161770E+04[EY1].18E+02
[X1] .462500E+00[EX1].50E-03[Y1]-.145550E+04[EY1].17E+02
...
[X1] .953300E+00[EX1].50E-03[Y1] .210900E+03[EY1].11E+02
[X1] .976500E+00[EX1].50E-03[Y1] .283100E+03[EY1].11E+02
[X1] .985900E+00[EX1].50E-03[Y1] .317400E+03[EY1].12E+02
[NX1] 1
[X1] .987800E+00[EX1].50E-03[Y1] .327000E+03[EY1].20E+03
[NX1] 3
[X1] .988200E+00[EX1].50E-03[Y1] .327200E+03[EY1].12E+02
[X1] .991100E+00[EX1].50E-03[Y1] .259400E+03[EY1].11E+02
[X1] .100000E+01[EX1].00E+00[Y1] .000000E+00[EY1].00E+00
...

Fig. 3.10 Structure of a SELF (two-phase fluid-fluid system)

3.5.3 ELDATA display

The ELDATA (ELectronic DATA) display is an ASCII file containing all the numerical data in a format similar
to, but more explicit, than SELF (Chap. 3.5.2). Like in SELF, all the data points are displayed with their
uncertainties. Additionally, the descriptors of the DOIs of property type, chemical system and reference appear
in the file. In the case of two-phase systems, the data blocks are clearly shown.
In PDF and SELF the physical quantities are displayed in SI units and no change of units is possible. The
ELDATA display permits the conversion of the SI scale and units of temperature, and of the units of pressure
and of molar energy into several practical units (Chap. 3.5.3.1).

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-11

3.5.3.1 Selection of units

Using the dialog box shown in Fig. 3.5 click on the Units Selection option. The following will be displayed
(Fig. 3.11):

Fig. 3.11 Select the unit of pressure

Select the physical quantity and the practical unit, click first on the Change Unit button and then on the
Close button. To cancel all the unit conversions click on the Restore SI button.

3.5.4 Graphical display

For the property types HMSD1111, HMSD1121, HMSD1131, HMSD1161, HMSD1221, HMSD1222, and
HMSD1311 the graph displays the HE or HM data points as a function of x1, from x1 = 0 to x1 = 1, individually for
each set of parameters, T or P, T. For HMSD1331 Hsol is plotted as a function of x1 at constant value(s) of P and
T. For HMSD1141, HMSD1231, HMSD1232, and HMSD1351 HE or HM are plotted as a function of P at
constant value(s) of T and x1. For HMSD1241 and HMSD1242 HE is plotted as a function of T at constant
∞ $
value(s) of P and x1. For HMSD1332 and HMSD1333 H sol or H sol are plotted as a function of T. There is no
graph in the case of HMSD1151 and HMSD1251. The graphical display serves as dialog box for correlating the
experimental data (Fig. 3.12).

3.5.5 Correlating experimental data

The experimental HE (x1) or HM (x1) data in the homogeneous region can be correlated by means of Eqs. (1.88)
or (1.95) the function z being one of the following:

Function z Identifier
x RKX
1–x RK1MINX
2x – 1 RK2XMIN1
x½ RKSQRTX
1/x RKINVX

Landolt-Börnstein
New Series IV/10B
3-12 3 Instructions on using the computer program ELBT

Fig. 3.12 Graphical display and controls for correlating experimental HE (x1) or HM (x1) data, Eqs. (1.88) or (1.95)

Using the appropriate controls shown in Fig. 3.12, check out the type of function z, select the number n of
coefficients A(j), enter the value of the skewing factor k, and press the Do calculations button. The default
values are z = 2x – 1 (RK2XMIN1), n = 3, and k = 0. The number N of data points should be N > 2, i. e. the data
set should contain at least one data point for 0 < x1 < 1, and n < N (Chap. 1.2).
When using Eqs. (1.98) and (1.100), Identifier SWXAB, enter the values of the sharpness factor a (default
value 10) and of the switching position b (default value 0.5) and select the numbers n, of coefficients A(i), and m,
of coefficients B(j) (default values 3) (Fig. 3.13).

Fig. 3.13 Graphical display and controls for correlating experimental HE (x1) or HM (x1) data, Eqs. (1.98) and (1.100)

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-13

Fig. 3.14. Graphical display of correlated experimental data for a two-phase fluid-fluid system

In the presence of a two-phase region for the selected values of the parameters, with at least two data points
including the data points on the fluid-fluid equilibrium phase boundary curve, the coefficients B(1) and B(2), Eq.
(1.101), are calculated and displayed automatically. The procedure of correlating the data in the homogeneous
regions is the same as described above (Fig. 3.14).
∞ $
The experimental HE (P), HM(P), HE (T), H sol (T), or H sol (T) data can be sometimes correlated by means of
Eq. (1.102) the function z being one of the following:

Function z Identifier
P or T POLYX
1/P or 1/T POLYINVX
P – P° or T – T° POLYXMINX0
(P – P°)/ P or (T – T°)/ T POLYX0INVX

where P° is a reference pressure (default value P° = 0.1·106Pa ) and T° is a reference temperature (default value
T° = 0.29815·103K).

Landolt-Börnstein
New Series IV/10B
3-14 3 Instructions on using the computer program ELBT

Fig. 3.15 Graphical display and controls for correlated experimental HE (T) data, Eq. (1.102)

Using the appropriate controls shown in Fig. 3.15, check out the type of function z, select the number n of
coefficients A(j), enter the value of the reference pressure or temperature X0, and press the Do calculations
button. The default values are z = X (POLYX), n = 3, and X0 = .100000E+06 Pa or X0 = .298150E+03 K The
number N of data points should be N > 1, i. e. the data set should contain at least two data points (Chap. 1.6).

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-15

3.5.6 Output of correlated experimental data

Selecting Show / Results from the main menu, (Figs. 3.14 or 3.15), displays the calculated values in an
ELDATA style ASCII file (Fig. 3.16 a, b, and c).

Publisher : Springer Berlin Heidelberg New York

-------------------------------------------------------------------------
Property Code : [HMSD1315]
Property Group: HEAT OF MIXING AND SOLUTION
State : Two-component system, single-phase fluid or two-phase
fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters : [P1] P/Pa Pressure
[P2] T/K Temperature
Variables : [X1] x1/- Mole fraction of component 1
[Y1] HM/J mol-1 Molar enthalpy of mixing
Method : Smoothed HM values obtained from direct calorimetric
Measurements
-------------------------------------------------------------------------
ORIGINAL SOURCE OF EXPERIMENTAL DATA
-------------------------------------------------------------------------
SELF Name : [10.1007/ b97686/2005.LB0374]
Reference : Ott, J. B.; Sipowska, J. T.; Owen, R. L.; Izatt, R. M. J.
Chem. Thermodyn. 1990, 22, 683.
-------------------------------------------------------------------------
Component (1) : [F1]C2 H6
[N1]Ethane
[CASRN1] 74-84-0
[M1] 30.069040000
Component (2) : [F2]C2 H6 O
[N2]Ethanol
[CASRN2] 64-17-5
[M2] 46.068440000
-------------------------------------------------------------------------
PARAMETERS
-------------------------------------------------------------------------
[P1] .500000E+07
[P2] .323150E+03

Fig. 3.16 a. ELDATA display of correlated experimental data.

Landolt-Börnstein
New Series IV/10B
3-16 3 Instructions on using the computer program ELBT

SINGLE-PHASE REGION
-------------------------------------------------------------------------
COEFFICIENTS [A(I)], ERRORS [EA(I)] AND SKEWING FACTOR [SF]
-------------------------------------------------------------------------
[A(1)]-.699165E+04[EA(1)].17E+03
[A(2)] .777021E+04[EA(2)].53E+03
[A(3)] .183912E+05[EA(3)].33E+03
[A(4)] .104686E+05[EA(4)].65E+03
[SF] .000000E+00
-------------------------------------------------------------------------
STANDARD DEVIATION [SD] AND MAXIMUM DEVIATION [MAXD]
-------------------------------------------------------------------------
[SD].12E+02[MAXD].23E+02
-------------------------------------------------------------------------
CALCULATED [Y1] DATA FOR EXPERIMENTAL [X1] VALUES AND DEVIATIONS
[DY1]=[Y1](CALC)-[Y1](EXP)
-------------------------------------------------------------------------
[X1] .000000E+00[Y1] .000000E+00[DY1] .00E+00
[X1] .357000E-01[Y1]-.231716E+03[DY1]-.68E+01
[X1] .725000E-01[Y1]-.452816E+03[DY1]-.13E+02
[X1] .110500E+00[Y1]-.671610E+03[DY1] .10E+02
[X1] .149700E+00[Y1]-.892088E+03[DY1] .48E+01
[X1] .190100E+00[Y1]-.111394E+04[DY1] .49E+01
[X1] .231900E+00[Y1]-.133311E+04[DY1] .81E+01
[X1] .274900E+00[Y1]-.153833E+04[DY1]-.23E+02
[X1] .319400E+00[Y1]-.171563E+04[DY1]-.13E+00
[X1] .352000E+00[Y1]-.181377E+04[DY1] .82E+01
[X1] .987800E+00[Y1] .335197E+03[DY1] .82E+01
[X1] .988200E+00[Y1] .325024E+03[DY1]-.22E+01
[X1] .991100E+00[Y1] .249646E+03[DY1]-.98E+01
[X1] .100000E+01[Y1] .000000E+00[DY1] .00E+00

Fig. 3.16 b. ELDATA display of correlated experimental data (homogeneous region)

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-17

TWO-PHASE REGION
-------------------------------------------------------------------------
PHASE BOUNDARY POINTS
-------------------------------------------------------------------------
[X1] .352000E+00[EX1].50E-03[Y1]-.182200E+04[EY1].10E+03
[X1] .987800E+00[EX1].50E-03[Y1] .327000E+03[EY1].20E+03
-------------------------------------------------------------------------
CORRELATING EQUATION
-------------------------------------------------------------------------
Identifier : LINE
-------------------------------------------------------------------------
COEFFICIENTS [B(I)], ERRORS [EB(I)]
-------------------------------------------------------------------------
[B(1)]-.301121E+04[EB(1)].75E+01
[B(2)] .337948E+04[EB(2)].10E+02
-------------------------------------------------------------------------
STANDARD DEVIATION [SD] AND MAXIMUM DEVIATION [MAXD]
-------------------------------------------------------------------------
[SD].87E+01[MAXD].17E+02
-------------------------------------------------------------------------
CALCULATED [Y1] DATA FOR EXPERIMENTAL [X1] VALUES AND DEVIATIONS
[DY1]=[Y1](CALC)-[Y1](EXP)
-------------------------------------------------------------------------
[X1] .352000E+00[Y1]-.182163E+04[DY1] .37E+00
[X1] .365500E+00[Y1]-.177601E+04[DY1]-.15E+02
[X1] .413100E+00[Y1]-.161514E+04[DY1] .26E+01
[X1] .462500E+00[Y1]-.144820E+04[DY1] .73E+01
[X1] .513600E+00[Y1]-.127550E+04[DY1] .17E+02
[X1] .566600E+00[Y1]-.109639E+04[DY1]-.87E+01
[X1] .621600E+00[Y1]-.910520E+03[DY1]-.91E+01
[X1] .678700E+00[Y1]-.717552E+03[DY1] .91E+01
[X1] .737900E+00[Y1]-.517486E+03[DY1] .12E+02
[X1] .799600E+00[Y1]-.308972E+03[DY1]-.10E+02
[X1] .863700E+00[Y1]-.923474E+02[DY1]-.91E+01
[X1] .930400E+00[Y1] .133064E+03[DY1]-.53E+01
[X1] .953300E+00[Y1] .210454E+03[DY1]-.45E+00
[X1] .976500E+00[Y1] .288858E+03[DY1] .58E+01
[X1] .985900E+00[Y1] .320626E+03[DY1] .32E+01
[X1] .987800E+00[Y1] .327047E+03[DY1] .47E-01

Fig. 3.16 c. ELDATA display of correlated experimental data (two-phase region)

Landolt-Börnstein
New Series IV/10B
3-18 3 Instructions on using the computer program ELBT

Selecting Show / History from the main menu (Fig. 3.17), displays the standard deviations ı (Std. Dev.) and the
maximum deviations į (Max. Dev.) obtained using a sequence of (up to ten) different types of correlating
functions with a number n (and m) of coefficients and a selected value (if any) of the skewing factor k (Fig.
3.18).
The initial position of the cursor marks the choice with the smallest standard deviation. Positioning the cursor
on any of the listed choices and pressing the Select button displays the corresponding graph with correlated data.

Fig. 3.17. Select Show / History in order to visualize the results of a sequence of data correlations

The initial position of the cursor marks the choice with the smallest standard deviation ı.

Fig. 3.18. Select the best correlating equation from a sequence of calculations

Positioning the cursor on any of the listed choices and pressing the Select button displays the corresponding
graph with correlated data.

Landolt-Börnstein
New Series IV/10B
 3 Instructions on using the computer program ELBT 3-19

3.6 Creating SpreadsheetML documents

The ELBT.EXE program allows importing the information of SELF and ELDATA files, as well as of the files
containing the results of correlations into SpreadsheetML documents.
After selecting the numerical data file LBnnnn, choose the menu entry File command (Fig. 3.4) and select
from the dialog box (Fig. 3.19) the XML File display format, ELDATA or SELF.

Fig. 3.19 Select the XML display format of numerical data file (ELDATA or SELF)

Alternatively, after selecting the set of correlated data, choose the menu entry File command (Fig. 3.14) and
press the XML File button (Fig. 3.20):

Fig. 3.20 Save the XML format of correlated numerical data

The files can be saved in a user-defined directory. The default names are LBnnnn_S.XML for SELF,
LBnnnn_E.XML for ELDATA, and LBnnnn_C.XML for calculated data files.
The XML files can be viewed by means of Microsoft® Office Excel 2002 or later (Fig. 3.21).

Landolt-Börnstein
New Series IV/10B
3-20 3 Instructions on using the computer program ELBT

Fig. 3.21 ELDATA file displayed in SpreadsheetML format

Landolt-Börnstein
New Series IV/10B
 2 Tables on heats of mixing and solution 2-1

2 Tables on heats of mixing and solution

2.1 Introduction

The present Landolt-Börnstein volume provides numerical data for the molar enthalpy of mixing HM, or the
excess molar enthalpy HE,, or the molar enthalpy of solution Hsol , for 448 binary systems of nonelectrolytes as a
function of temperature T, pressure P, and mole fraction composition x1. Eighteen Property Types are
distinguished depending on the state of aggregation of the pure components and on whether none, one, or several
among the physical quantities P, T or x1 is kept constant in the particular data file: isobaric (constant P),
isothermal (constant T), isoplethal (constant x1) (Chap. 2.1.1).
All these data files can be displayed from the CD-ROM version of the volume, by means of the ELBT
Program in five formats: PDF, SELF, ELDATA, and the XML versions of SELF and ELDATA (Chap. 3).
The PDF (Portable Document Format) display presents the numerical data in a more traditional tabular and
graphical form. The property type, including the physical quantities with their SI units, the state of the chemical
system, and the method used to obtain the data, the molecular formulas, primary names and CAS Registry
Numbers of the components are given. Alternate names (synonyms) are listed in the Name Index of Substances
(Chap. 4.2). The full reference to the original source of data is given with the author(s) and the title of the
publication.
The state (of aggregation) is the same for all the chemical systems of this volume: each pure component is
either a liquid or a gas or supercritical fluid, the binary is a single-phase fluid or two-phase fluid-fluid system.
Two-phase regions are clearly marked on the PDF tables and the SELF and ELDATA files.
The original units of the physical quantities have all been converted into SI units. When the number of direct
experimental data points reported in the original source is very large (usually more than 50) then part of the data
do not appear in the numerical PDF table. More data may appear in graphical form. In any case, this is marked in
the footnote of the tables as “See SELF for the totality of data”.
The footnote gives merely an overall estimate of the uncertainties of the main physical quantities, usually of
x1 and HM, HE, or Hsol (Chap. 3.5.2.6).
On the graph, the dotted line joining the experimental points is not a calculated best-fit, but a ‘hand-drawn’
curve.
In this Chapter a selection of 314 representative data sets are printed. The data tables are grouped in four
subchapters:
2.2 Organic Systems
2.3 Carbon Dioxide - Organic Systems
2.4 Aqueous-Organic Systems
2.5 Systems Containing Inorganic Substances
Chap. 2.2 contains 98 data tables for binary systems of two ‘organic’ (C-containing) substances. Chap. 2.3
contains 66 data tables for binary systems of carbon dioxide + an organic substance. Chap 2.4 contains 50
data tables for binary systems of water + an organic substance. Chap 2.5 contains 100 data tables for binary
systems of at least one ‘inorganic’ (no C-containing) substance. These systems are listed in the Indexes,
Chap. 4.4, 4.5, 4.6 and 4.7, with page numbers given in the Page column.
In order to conserve space in the data tables printed in the book only the property type identifier is displayed.
The corresponding descriptors are shown in Chap. 2.1.1.

Landolt-Börnstein
New Series IV/10B
2-2 2 Tables on heats of mixing and solution

2.1.1 Property Types

HMSD1111 Example: Vol. IV/10A LB0151, p.2-117

Property Type [HMSD1111] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters T/K Temperature
Variables x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Direct low-pressure calorimetric measurement of HE at variable x1 and constant T

HMSD1121 Example: Vol. IV/10B LB0432, p.2-80

Property Type [HMSD1121] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters P/Pa Pressure
T/K Temperature
Variables x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable x1 and constant P and T

HMSD1131 Example: Vol. IV/10B LB0445, p.2-152

Property Type [HMSD1131] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters T/K Temperature
Variables x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at saturation pressure, variable x1, and constant T

HMSD1141 Example: Vol. IV/10B LB0289, p.2-48

Property Type [HMSD1141] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters T/K Temperature
x1/- Mole fraction of component 1
Variables P/Pa Pressure
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable P and constant T and x1

HMSD1151 Example: Vol. IV/10A LB0100, p.2-75

Property Type [HMSD1151] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Variables P/Pa Pressure
T/K Temperature
x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable P, T, and x1

Landolt-Börnstein
New Series IV/10B
 2 Tables on heats of mixing and solution 2-3

HMSD1161 Example: Vol. IV/10B LB0387, p.2-56

Property Type [HMSD1161] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid - fluid
Pure component 1, liquid
Pure component 2, liquid
Parameters P/Pa Pressure
T/K Temperature
Variables x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable x1 and constant P and T

HMSD1221 Example: Vol. IV/10B LB0145, p.2-57

Property Type [HMSD1221] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters P/Pa Pressure
T/K Temperature
Variables x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable x1 and constant P and T

HMSD1222 Example: Vol. IV/10B LB0444, p.2-110

Property Type [HMSD1222] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters P/Pa Pressure
T/K Temperature
Variables x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Smoothed HE data at variable x1 and constant P and T, obtained from direct calorimetric
measurements of HE at variable P, T and x1

HMSD1231 Example: Vol. IV/10B LB0043, p.2-108

Property Type [HMSD1231] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters T/K Temperature
x1/- Mole fraction of component 1
Variables P/Pa Pressure
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable P and constant T and x1

HMSD1232 Example: Vol. IV/10B LB0362, p.2-154

Property Type [HMSD1232] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters T/K Temperature
x1/- Mole fraction of component 1
Variables P/Pa Pressure
HE/J mol-1 Molar excess enthalpy
Method Smoothed HE data at variable P and constant T and x1, obtained from direct calorimetric
measurements of HE at variable P, T and x1

Landolt-Börnstein
New Series IV/10B
2-4 2 Tables on heats of mixing and solution

HMSD1241 Example: Vol. IV/10B LB0127, p.2-127

Property Type [HMSD1241] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters P/Pa Pressure
x1/- Mole fraction of component 1
Variables T/K Temperature
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable T and constant P and x1

HMSD1242 Example: Vol. IV/10B LB0150, p.2-145

Property Type [HMSD1242] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters P/Pa Pressure
x1/- Mole fraction of component 1
Variables T/K Temperature
HE/J mol-1 Molar excess enthalpy
Method Smoothed HE data at variable T and constant P and x1 , obtained from direct calorimetric
measurements of HE at variable P, T and x1

HMSD1251 Example: Vol. IV/10B LB0440, p.2-107

Property Type [HMSD1251] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables P/Pa Pressure
T/K Temperature
x1/- Mole fraction of component 1
HE/J mol-1 Molar excess enthalpy
Method Direct calorimetric measurement of HE at variable P, T, and x1

HMSD1311 Example: Vol. IV/10B LB0172, p.2-20

Property Type [HMSD1311] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters P/Pa Pressure
T/K Temperature
Variables x1/- Mole fraction of component 1
HM/J mol-1 Molar enthalpy of mixing
Method Direct calorimetric measurement of HM at variable x1 and constant P and T

HMSD1331 Example: Vol. IV/10B LB0212, p.2-19

Property Type [HMSD1331] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters P/Pa Pressure
T/K Temperature
Variables x1/- Mole fraction of component 1
Hsol/J mol-1 Molar enthalpy of solution of component 1
Method Direct calorimetric measurement of Hsol at variable x1 and constant P and T

Landolt-Börnstein
New Series IV/10B
 2 Tables on heats of mixing and solution 2-5

HMSD1332 Example: Vol. IV/10B LB0322, p.2-120

Property Type [HMSD1332] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters P/Pa Pressure
Variables T/K Temperature
∞
H sol /J mol-1 Molar enthalpy of solution at infinite dilution of component 1
∞
Method H sol calculated by extrapolation to infinite dilution of direct calorimetric measurements
of the molar enthalpy of solution at constant P and variable T

HMSD1333 Example: Vol. IV/10B LB0345, p.2-91

Property Type [HMSD1333] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables T/K Temperature
$
H sol /J mol-1
Standard molar enthalpy of solution of component 1
$
Method H sol obtained by correcting for gas phase nonideality calorimetric measurements
of the molar enthalpy of solution at infinite dilution at constant P and variable T

HMSD1351 Example: Vol. IV/10B LB0381, p.2-111

Property Type [HMSD1351] HEAT OF MIXING AND SOLUTION
State Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters T/K Temperature
x1/- Mole fraction of component 1
Variables P/Pa Pressure
HM/J mol-1 Molar enthalpy of mixing
Method Direct calorimetric measurement of HM at variable P and constant T and x1

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0022

Components: 1. CH4, Methane [74-82-8]
2. C2H6, Ethane [74-84-0]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 241.1 T/K = 298.2 HE/J mol-1
8.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 241.1
0.196000 3.56 0.168000 1.75
0.224000 4.45 0.245000 2.29 P/103Pa = 101.325; T/K = 298.2
0.278000 4.05 0.359000 2.76
0.305000 4.95 0.434000 2.99
0.369000 5.74 0.593000 3.23 6.
0.450000 5.94 0.642000 3.07
0.493000 6.33 0.716000 2.71
0.521000 5.44 0.732000 2.42
0.613000 6.04 0.824000 1.54
0.690000 5.25 4.

2.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σ (HE)/J mol-1
= 1.0 See SELF for the totality of data
Hutchings, D. J.; Lewis, E. J.; Wormald, C. J. Excess enthalpies of mixtures of methane + each of the n-alkanes from ethane to
n-octane J. Chem. Thermodyn. 1978, 10, 559-566

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0023

Components: 1. CH4, Methane [74-82-8]
2. C3H8, Propane [74-98-6]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 245.2 T/K = 290.7 HE/J mol-1
32.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 245.2
0.205000 16.40 0.155000 8.30
0.302000 21.20 0.201000 9.70 P/103Pa = 101.325; T/K = 290.7
0.406000 24.60 0.344000 13.40
0.466000 25.10 0.352000 13.80
0.522000 25.50 0.419000 14.70 24.
0.584000 24.70 0.500000 15.20
0.632000 23.70 0.619000 14.10
0.689000 21.90 0.693000 12.50
0.806000 14.80 0.708000 11.40
0.750000 10.70 16.
0.753000 10.00
0.792000 9.10
0.892000 5.10

8.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σ (HE)/J mol-1
= 1.0 See SELF for the totality of data
Hutchings, D. J.; Lewis, E. J.; Wormald, C. J. Excess enthalpies of mixtures of methane + each of the n-alkanes from ethane to
n-octane J. Chem. Thermodyn. 1978, 10, 559-566

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0024

Components: 1. CH4, Methane [74-82-8]
2. C4H10, Butane [106-97-8]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 277.0 T/K = 328.7 HE/J mol-1
64.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 277.0
0.209000 32.50 0.357000 28.60
0.273000 36.90 0.422000 30.40 P/103Pa = 101.325; T/K = 328.7
0.333000 43.00 0.475000 30.60
0.427000 49.90 0.498000 30.00
0.476000 51.20 0.557000 30.40 48.
0.569000 49.20 0.578000 29.20
0.610000 47.10 0.580000 30.00
0.674000 41.80 0.617000 28.30
0.730000 36.70 0.620000 28.50
0.653000 28.10 32.
0.659000 26.30
0.676000 27.40
0.709000 26.20
0.743000 22.20
0.799000 19.70
16.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Hutchings, D. J.; Lewis, E. J.; Wormald, C. J. Excess enthalpies of mixtures of methane + each of the n-alkanes from ethane to
n-octane J. Chem. Thermodyn. 1978, 10, 559-566

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0025

Components: 1. CH4, Methane [74-82-8]
2. C5H12, Pentane [109-66-0]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 318.5 T/K = 383.4 HE/J mol-1
84.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 318.5
0.303000 59.10 0.278000 28.90
0.352000 61.60 0.339000 33.80 P/103Pa = 101.325; T/K = 383.4
0.413000 66.60 0.382000 36.30
0.447000 66.10 0.470000 37.80
0.465000 67.90 0.510000 37.60 63.
0.504000 67.00 0.526000 36.30
0.525000 67.60 0.624000 35.60
0.588000 64.60 0.658000 32.30
0.630000 62.80 0.708000 30.80
0.688000 56.70 42.

21.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Hutchings, D. J.; Lewis, E. J.; Wormald, C. J. Excess enthalpies of mixtures of methane + each of the n-alkanes from ethane to
n-octane J. Chem. Thermodyn. 1978, 10, 559-566

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0026

Components: 1. CH4, Methane [74-82-8]
2. C6H14, Hexane [110-54-3]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 343.2 T/K = 389.2 HE/J mol-1
128.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 343.2
0.304000 83.70 0.348000 52.10
0.355000 91.40 0.351000 60.60 P/103Pa = 101.325; T/K = 389.2
0.421000 94.20 0.423000 67.30
0.456000 99.30 0.428000 64.20
0.478000 96.80 0.465000 67.90 96.
0.533000 98.20 0.470000 65.50
0.595000 94.30 0.517000 66.10
0.684000 82.40 0.522000 64.30
0.750000 72.30 0.580000 63.20
0.822000 56.30 0.613000 59.20 64.
0.625000 60.20
0.676000 58.60
0.729000 52.50
0.783000 45.00

32.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Hutchings, D. J.; Lewis, E. J.; Wormald, C. J. Excess enthalpies of mixtures of methane + each of the n-alkanes from ethane to
n-octane J. Chem. Thermodyn. 1978, 10, 559-566

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0027

Components: 1. CH4, Methane [74-82-8]
2. C7H16, Heptane [142-82-5]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 389.2 T/K = 413.3 HE/J mol-1
140.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 389.2
0.369000 98.70 0.330000 79.10
0.524000 105.10 0.381000 81.40 P/103Pa = 101.325; T/K = 413.3
0.587000 101.90 0.414000 81.30
0.661000 92.40 0.465000 84.60
0.792000 68.90 0.489000 86.60 105.
0.542000 86.80
0.571000 82.50
0.606000 84.80
0.658000 74.50
0.810000 55.60 70.

35.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Hutchings, D. J.; Lewis, E. J.; Wormald, C. J. Excess enthalpies of mixtures of methane + each of the n-alkanes from ethane to
n-octane J. Chem. Thermodyn. 1978, 10, 559-566

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0028

Components: 1. CH4, Methane [74-82-8]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 410.2 T/K = 418.3 HE/J mol-1
180.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 410.2
0.395000 131.40 0.380000 118.10
0.480000 140.40 0.432000 126.10 P/103Pa = 101.325; T/K = 418.3
0.520000 140.70 0.457000 128.30
0.596000 136.30 0.483000 126.80
0.601000 132.20 0.541000 126.60 135.
0.602000 136.40 0.590000 122.80
0.678000 120.50 0.624000 122.00
0.745000 99.90 0.630000 118.10
0.796000 84.00 0.707000 103.80
0.715000 104.70 90.

45.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02
Hutchings, D. J.; Lewis, E. J.; Wormald, C. J. Excess enthalpies of mixtures of methane + each of the n-alkanes from ethane to
n-octane J. Chem. Thermodyn. 1978, 10, 559-566

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0050

Components: 1. C2H6, Ethane [74-84-0]
2. C4H10, Butane [106-97-8]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 304.500 T/K = 363.200 HE/J mol-1
24.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 304.5
0.398000 17.70 0.377000 8.90 P/103Pa = 101.325; T/K = 333.2
0.434000 18.80 0.383000 11.00 P/103Pa = 101.325; T/K = 363.2
0.466000 18.70 0.411000 9.20
0.522000 18.50 0.441000 10.10
0.524000 19.00 0.447000 10.70 18.
0.562000 19.00 0.449000 9.40
0.595000 18.20 0.468000 9.80
0.623000 18.00 0.506000 9.90
0.661000 17.20 0.536000 10.60
0.596000 9.90 12.

6.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σ (HE)/J mol-1
= 1.0 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0051

Components: 1. C2H6, Ethane [74-84-0]
2. C6H14, Hexane [110-54-3]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 372.200 T/K = 403.200 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 372.2
0.448000 51.30 0.434000 38.60
0.480000 51.70 0.455000 39.20 P/103Pa = 101.325; T/K = 383.2
0.502000 51.20 0.468000 39.30 P/103Pa = 101.325; T/K = 403.2
0.563000 51.00 0.491000 39.80
0.588000 49.30 0.522000 39.30 60.
0.594000 49.00 0.544000 39.30
0.631000 51.20 0.595000 37.30
0.644000 47.90 0.651000 36.20
0.666000 47.30
0.692000 44.00 40.
0.720000 41.20
0.748000 38.30

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0052

Components: 1. C2H6, Ethane [74-84-0]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 413.200 HE/J mol-1
160.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.394000 116.60 0.434000 110.90
0.458000 122.40 0.459000 109.30 P/103Pa = 101.325; T/K = 413.2
0.473000 118.60 0.480000 108.30
0.512000 119.60 0.489000 110.50
0.557000 119.70 0.510000 110.00 120.
0.585000 116.00 0.550000 106.90
0.595000 114.20 0.595000 104.70
0.630000 109.10 0.650000 100.60
0.695000 100.50 0.701000 91.10
0.740000 88.50 0.792000 69.40 80.

40.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0053

Components: 1. C3H8, Propane [74-98-6]
2. C6H14, Hexane [110-54-3]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 344.200 T/K = 396.900 HE/J mol-1
64.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 344.2
0.521000 47.10 0.471000 27.30
0.588000 45.60 0.494000 27.10 P/103Pa = 101.325; T/K = 363.2
0.632000 42.40 0.538000 26.90 P/103Pa = 101.325; T/K = 396.9
0.646000 42.40 0.596000 26.30
0.674000 40.80 0.638000 25.20 48.
0.686000 40.80 0.697000 22.60
0.745000 34.60 0.760000 19.20
0.748000 34.90 0.810000 16.30
0.788000 31.30
0.815000 27.50 32.

16.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0054

Components: 1. C3H8, Propane [74-98-6]
2. C7H16, Heptane [142-82-5]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 383.200 T/K = 413.200 HE/J mol-1
84.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 383.2
0.535000 63.70 0.366000 43.70
0.564000 62.00 0.420000 48.20 P/103Pa = 101.325; T/K = 403.2
0.586000 61.00 0.455500 48.60 P/103Pa = 101.325; T/K = 413.2
0.643000 55.70 0.486000 46.50
0.648000 56.90 0.520000 48.00 63.
0.670000 54.90 0.561000 48.80
0.689000 53.20 0.575000 45.40
0.705000 52.70 0.606000 44.40
0.749000 46.60 0.675000 42.10
0.833000 35.20 0.794000 29.40 42.
0.849000 32.20
0.897000 23.80

21.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0055

Components: 1. C3H8, Propane [74-98-6]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 413.300 HE/J mol-1
128.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.455000 96.20 0.363000 78.70
0.473000 95.70 0.404000 84.30 P/103Pa = 101.325; T/K = 410.2
0.484000 93.50 0.437000 86.80 P/103Pa = 101.325; T/K = 413.3
0.515000 92.40 0.463000 86.70
0.534000 94.90 0.490000 84.70 96.
0.581000 93.90 0.531000 87.60
0.625000 86.70 0.620000 83.30
0.686000 81.00 0.634000 77.90
0.742000 71.20 0.655000 77.70
0.703000 70.70 64.

32.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0056

Components: 1. C4H10, Butane [106-97-8]
2. C6H14, Hexane [110-54-3]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.200 T/K = 393.200 HE/J mol-1
24.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.331000 16.80 0.383000 11.80
0.370000 19.60 0.452000 14.70 P/103Pa = 101.325; T/K = 393.2
0.425000 19.70 0.474000 12.70
0.453000 18.40 0.497000 15.60
0.482000 18.90 0.521000 11.90 18.
0.522000 19.90 0.580000 14.10
0.566000 20.30 0.596000 12.40
0.595000 17.30 0.622000 14.70
0.625000 19.70 0.670000 13.30
0.670000 16.80 0.781000 9.60 12.

6.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σ (HE)/J mol-1
= 1.0 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0057

Components: 1. C4H10, Butane [106-97-8]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 413.200 HE/J mol-1
100.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.400000 69.10 0.441000 60.10
0.449000 70.30 0.459000 61.30 P/103Pa = 101.325; T/K = 410.5
0.475000 68.80 0.484000 65.50 P/103Pa = 101.325; T/K = 413.2
0.520000 69.00 0.499000 63.50
0.544000 71.60 0.535000 60.10 75.
0.583000 69.30 0.558000 61.70
0.618000 66.10 0.586000 60.00
0.629000 64.20 0.648000 56.40
0.705000 57.80 0.706000 51.90
0.710000 56.30 0.755000 44.40 50.

25.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0058

Components: 1. C5H12, Pentane [109-66-0]
2. C6H14, Hexane [110-54-3]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 343.200 T/K = 383.200 HE/J mol-1
12.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 343.2
0.417000 5.60 0.397000 4.40
0.430000 5.90 0.438000 3.10 P/103Pa = 101.325; T/K = 383.2
0.472000 9.00 0.485000 6.30
0.485000 6.00 0.494000 3.50
0.510000 7.50 0.520000 3.00 9.
0.550000 5.30 0.554000 4.70
0.556000 6.20 0.597000 2.70
0.562000 8.00

6.

3.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σ (HE)/J mol-1
= 1.0 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0059

Components: 1. C5H12, Pentane [109-66-0]
2. C7H16, Heptane [142-82-5]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 393.200 T/K = 413.200 HE/J mol-1
28.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 393.2
0.347000 18.40 0.328000 14.20
0.383000 19.00 0.347000 13.50 P/103Pa = 101.325; T/K = 403.2
0.430000 18.60 0.405000 12.50 P/103Pa = 101.325; T/K = 413.2
0.439000 16.90 0.432000 16.00
0.474000 17.80 0.472000 15.10 21.
0.495000 20.60 0.511000 14.50
0.522000 17.90 0.534000 17.30
0.552000 16.90 0.583000 13.20
0.622000 18.80 0.596000 13.70
0.628000 17.10 0.615000 13.50 14.

7.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σ (HE)/J mol-1
= 1.0 See SELF for the totality of data
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0060

Components: 1. C5H12, Pentane [109-66-0]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 413.200 HE/J mol-1
52.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.394000 43.60 0.421000 39.80
0.437000 44.40 0.440000 37.60 P/103Pa = 101.325; T/K = 413.2
0.445000 42.30 0.453000 38.40
0.475000 42.10 0.462000 38.70
0.484000 43.70 0.481000 39.90 39.
0.511000 44.10 0.499000 41.00
0.546000 44.50 0.525000 40.20
0.592000 40.00 0.553000 38.50
0.633000 40.90 0.574000 37.50
0.704000 34.30 0.638000 35.50 26.

13.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0061

Components: 1. C6H14, Hexane [110-54-3]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 413.200 HE/J mol-1
28.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.248000 16.70 0.280000 14.20
0.304000 19.80 0.376000 19.20 P/103Pa = 101.325; T/K = 413.2
0.376000 20.70 0.424000 19.10
0.425000 21.00 0.450000 17.80
0.477000 20.50 0.487000 18.20 21.
0.530000 20.70 0.523000 19.90
0.550000 22.20 0.540000 20.40
0.598000 21.10 0.581000 17.50
0.676000 18.10 0.625000 16.90
0.753000 15.80 0.749000 15.00 14.

7.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σ (HE)/J mol-1
= 1.0
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0062

Components: 1. C7H16, Heptane [142-82-5]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 413.200 HE/J mol-1
10.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.326000 6.50 0.370000 3.40
0.374000 6.00 0.395000 4.50 P/103Pa = 101.325; T/K = 413.2
0.385000 5.20 0.430000 6.40
0.450000 4.80 0.481000 5.30
0.481000 6.70 0.495000 4.50 8.
0.505000 5.00 0.553000 6.30
0.510000 7.20 0.580000 4.80
0.526000 6.60 0.610000 3.80
0.598000 7.10 0.675000 4.40
0.623000 4.60 0.744000 3.00 5.

3.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σ (HE)/J mol-1
= 1.0
Wormald, C. J.; Lewis, E. J.; Hutchings, D. J. Excess enthalpies of gaseous mixtures of n-alkanes J. Chem. Thermodyn. 1979,
11, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0286

Components: 1. CH4, Methane [74-82-8]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.150 T/K = 413.150 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.15
0.313000 59.90 0.331000 42.00 P/103Pa = 101.325; T/K = 393.15
0.364000 64.10 0.370000 45.40
0.410000 66.10 0.442000 47.90
0.476000 67.90 0.474000 47.80
0.562000 67.50 0.540000 46.90 60.
0.580000 65.70 0.555000 46.30
0.620000 64.30 0.650000 43.60
0.664000 60.20 0.717000 37.90
0.733000 53.20 0.766000 34.00
0.779000 45.90 0.839000 24.90 40.

20.

P/103Pa = 101.325; T/K = 413.15

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J. A differential-flow mixing calorimeter. The excess enthalpy of methane + benzene, methane + cyclohexane, and
benzene + cyclohexane J. Chem. Thermodyn. 1977, 9, 901-910

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0408

Components: 1. CH4, Methane [74-82-8]
2. C6H12, Cyclohexane [110-82-7]
T/K H°sol/103J mol-1
298.15 –3.000 H°sol/103J mol-1
318.15 –2.450 –2.3

–2.5

–2.7

–2.9

–3.1
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.08
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0409

Components: 1. C2H6, Ethane [74-84-0]
2. C6H12, Cyclohexane [110-82-7]
T/K H°sol/103J mol-1
298.15 –11.140 H°sol/103J mol-1
318.15 –10.290 –10.0

–10.5

–11.0

–11.5

–12.0
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10 – 0.20
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0411

Components: 1. C3H8, Propane [74-98-6]
2. C6H12, Cyclohexane [110-82-7]
T/K H°sol/103J mol-1
298.15 –16.660 H°sol/103J mol-1
318.15 –15.980 –15.20

–15.65

–16.10

–16.55

–17.00
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.17–0.36
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0078

Components: 1. C2H4, Ethene [74-85-1]
2. C2H6, Ethane [74-84-0]
P/106Pa = 5.0 P/106Pa = 15.0
T/K = 273.15 T/K = 273.15 HE/J mol-1
160.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 273.15
0.020500 1.20 0.033400 14.60
0.061600 9.10 0.066800 29.10 P/106Pa = 7.5; T/K = 273.15
0.103700 15.30 0.100100 41.00 P/106Pa = 5.0; T/K = 273.15
0.144900 23.20 0.150200 59.10
0.193200 27.80 0.233600 82.30 120.
0.276700 37.30 0.267000 87.00
0.305000 40.60 0.300300 93.40
0.352100 42.90 0.350400 101.00
0.387000 42.60 0.383700 104.70
0.425300 42.40 0.433700 111.20 80.
0.467500 40.80 0.467100 113.10
0.510500 39.60 0.500400 113.60
0.594000 36.60 0.550400 112.70
0.655400 31.90 0.583700 110.30
0.689000 27.50 0.633700 104.50
0.724800 25.30 0.667000 100.60 40.
0.763000 20.00 0.700300 94.90
0.803800 15.90 0.750200 85.20
0.847500 11.10 0.783600 76.20
0.894600 6.20 0.866800 50.80
0.945200 2.40 0.900100 37.60
0.950100 18.80 0.
0.983400 5.60 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 0.50 + 0.02 |HE/J mol-1| See SELF for the totality of data
Gruszkiewicz, M. S.; Sipowska, J. T.; Ott, J. B.; Brown, P. R.; Moore, J. D. Excess enthalpies for (ethane + ethene) at the
temperatures (273.15, 298.15, 323.15, 348.15, and 363.15) K and the pressures (5, 7.5, 10, 12.5, and 15) MPa J. Chem.
Thermodyn. 1995, 27, 507-524

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0199

Components: 1. C2H4, Ethene [74-85-1]
2. C2H6, Ethane [74-84-0]
P/106Pa = 7.5 P/106Pa = 15.0
T/K = 323.15 T/K = 363.15 HE/J mol-1
800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.500; T/K = 323.150
0.014300 26.60 0.033400 13.80 P/106Pa = 10.000; T/K = 348.150
0.057500 101.70 0.036700 14.20 P/106Pa = 15.000; T/K = 363.150
0.101300 182.10 0.100100 37.80
0.122000 231.80 0.150200 52.30
0.145800 278.90 0.150200 53.10 600.
0.191000 358.20 0.183500 62.80
0.267800 488.70 0.300300 89.90
0.314900 557.80 0.350300 97.40
0.346700 578.70 0.383700 104.30
0.395000 615.00 0.433700 109.30 400.
0.460500 632.10 0.517000 112.10
0.510600 629.10 0.567000 111.10
0.544400 611.20 0.608700 107.70
0.595900 592.60 0.633700 104.40
0.630600 557.50 0.750300 84.50
0.665700 521.30 0.783600 76.60 200.
0.726400 460.70 0.866800 52.00
0.755300 420.60 0.900100 40.10
0.791800 366.60 0.933400 27.50
0.828700 307.70 0.943400 22.00
0.866000 242.90 0.950100 19.80
0.945800 104.20 0.966700 15.30 0.
0.980500 35.70 0.971700 12.50 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 0.5 + 0.02 |HE/J mol-1| See SELF for the totality of data
Gruszkiewicz, M. S.; Sipowska, J. T.; Ott, J. B.; Brown, P. R.; Moore, J. D. Excess enthalpies for (ethane + ethene) at the
temperatures (273.15, 298.15, 323.15, 348.15, and 363.15) K and the pressures (5, 7.5, 10, 12.5, and 15) MPa J. Chem.
Thermodyn. 1995, 27, 507-524

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0200

Components: 1. C2H4, Ethene [74-85-1]
2. C2H6, Ethane [74-84-0]
P/106Pa = 5.0 P/106Pa = 15.0
T/K = 298.15 T/K = 298.15 HM/J mol-1
3000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 5.0; T/K = 298.15
0.015200 –52.80 0.066800 22.50 P/106Pa = 7.5; T/K = 298.15
0.020500 –67.20 0.100100 32.40
0.037200 –91.00 0.150200 47.50
0.055300 –114.10 0.183500 55.40
0.061600 –124.50 0.233600 67.10 2000.
0.081800 –151.40 0.266900 73.40
0.103700 –178.60 0.300300 79.50
0.127600 –187.10 0.350300 85.80
0.144900 –242.50 0.383700 89.30
0.153900 –305.60 0.433700 93.50 1000.
0.163300 –344.10 0.467000 94.40
0.571400 1915.50 0.500400 95.10
0.577000 1897.00 0.583700 91.80
0.594000 1854.90 0.633700 88.80
0.623800 1781.50 0.667000 84.30
0.636200 1725.60 0.700300 80.40 0.
0.655400 1608.10 0.723600 75.00
0.689000 1459.50 0.750300 70.90
0.724800 1356.50 0.783600 64.40
0.763000 1167.20 0.833500 53.00 P/106Pa = 15.0; T/K = 298.15
0.803800 976.30 0.866800 43.00
0.847600 759.70 0.900100 34.60 –1000.
0.894600 550.20 0.933400 24.20 0.50
0.945300 308.80 0.966700 12.40
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 0.50 + 0.02 |HM/J mol-1| See SELF for the totality of data
Gruszkiewicz, M. S.; Sipowska, J. T.; Ott, J. B.; Brown, P. R.; Moore, J. D. Excess enthalpies for (ethane + ethene) at the
temperatures (273.15, 298.15, 323.15, 348.15, and 363.15) K and the pressures (5, 7.5, 10, 12.5, and 15) MPa J. Chem.
Thermodyn. 1995, 27, 507-524

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0034

Components: 1. C2H4, Ethene [74-85-1]
2. C3H8, Propane [74-98-6]
P/106Pa = 5.0 P/106Pa = 15.0
T/K = 273.15 T/K = 273.15 HE/J mol-1
100.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 273.15
0.021100 –3.00 0.038200 10.80
0.063400 –21.00 0.076000 19.20
0.106500 –35.00 0.113500 24.80
0.148600 –44.00 0.150600 31.30
0.187300 –58.00 0.187300 37.10 0.
0.187300 –57.00 0.223600 41.50
0.231600 –69.00 0.277500 47.50
0.269200 –87.00 0.312900 50.50
0.311300 –101.00 0.348100 51.80
0.342300 –110.00 0.382800 53.90 –100.
0.394100 –128.00 0.434400 55.40
0.432600 –141.00 0.468400 54.80
0.474800 –148.00 0.502000 53.80
0.521400 –168.00 0.551900 51.40
0.546600 –174.00 0.584700 49.20
0.601100 –192.00 0.633400 44.70 –200.
0.630700 –197.00 0.665500 42.10
0.730600 –219.00 0.713100 35.90 P/106Pa = 10.0; T/K = 273.15
0.768300 –216.00 0.744500 31.80
0.808400 –209.00 0.791000 26.00 P/106Pa = 7.5; T/K = 273.15
0.851300 –188.00 0.821700 22.80 P/106Pa = 5.0; T/K = 273.15
0.897300 –151.00 0.867200 18.10 –300.
0.946800 –80.00 0.912000 12.40 0.50
0.941600 7.70
x1
Uncertainties: σ (x1) = 0.00010; σ (HE)/J mol-1
= 0.20 + 0.015 |HE/J mol-1| See SELF for the totality of data
Brown, P. R.; Ott, J. B.; Lemon, L. R.; Moore, J. D. Excess molar enthalpies for (propane + ethene) over the temperature range
from 273.15 K to 373.15 K and the pressure range from 5 MPa to 15 MPa J. Chem. Thermodyn. 1996, 28, 905-921

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0035

Components: 1. C2H4, Ethene [74-85-1]
2. C3H8, Propane [74-98-6]
P/106Pa = 6.0 P/106Pa = 12.5
T/K = 373.15 T/K = 373.15 HE/J mol-1
3600.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.0; T/K = 373.15
0.028100 51.00 0.037000 –31.30
0.067700 206.00 0.073800 –60.60
0.109900 437.00 0.110300 –89.80
0.143400 792.00 0.146500 –106.60
0.190700 1462.00 0.182400 –128.70 2400.
0.228400 1961.00 0.235800 –147.30
0.268200 2472.00 0.235800 –147.60
0.310300 2728.00 0.271000 –155.40
0.354800 2884.00 0.306000 –156.00
0.385900 2927.00 0.392400 –134.10 1200.
0.435000 2938.00 0.426500 –120.20
0.469400 2842.00 0.460300 –90.50
0.505200 2790.00 0.510600 –56.70
0.542700 2586.00 0.543900 –20.60
0.581700 2478.00 0.593300 32.70
0.622600 2310.00 0.625900 69.70 0.
0.665300 2076.00 0.674400 125.50
0.710100 1754.00 0.754100 173.50 P/106Pa = 7.5; T/K = 373.15
0.757000 1516.00 0.785600 191.50
0.781400 1402.00 0.832500 192.30 P/106Pa = 10.0; T/K = 373.15
0.831900 1132.00 0.863400 176.90 P/106Pa = 12.5; T/K = 373.15
0.885000 714.00 0.909400 137.50 –1200.
0.912600 596.00 0.954900 76.20 0.50
0.941000 397.00 0.985000 23.50
x1
Uncertainties: σ (x1) = 0.00010; σ (HE)/J mol-1
= 0.20 + 0.030 |HE/J mol-1| See SELF for the totality of data
Brown, P. R.; Ott, J. B.; Lemon, L. R.; Moore, J. D. Excess molar enthalpies for (propane + ethene) over the temperature range
from 273.15 K to 373.15 K and the pressure range from 5 MPa to 15 MPa J. Chem. Thermodyn. 1996, 28, 905-921

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0036

Components: 1. C2H4, Ethene [74-85-1]
2. C3H8, Propane [74-98-6]
P/106Pa = 6.0 P/106Pa = 6.0
T/K = 298.15 T/K = 363.15 HM/J mol-1
4000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 6.0; T/K = 363.15
0.026900 –126.00 0.026900 –33.00 P/106Pa = 6.0; T/K = 348.15
0.064800 –259.00 0.064800 –48.00
0.105300 –375.00 0.105300 –12.00
0.137700 –491.00 0.148800 96.00
0.220200 –879.00 0.183500 228.00 2000.
0.259100 –1035.00 0.220200 444.00
0.300300 –1130.00 0.272500 1083.00
0.344100 –1322.00 0.300300 1570.00
0.374800 –1411.00 0.344100 2242.00
0.423400 –1494.00 0.390600 2596.00 0.
0.457600 –1637.00 0.423400 2761.00
0.493400 –1767.00 0.475300 2823.00
0.530900 –1851.00 0.512000 2748.00
0.571400 –1968.00 0.550300 2644.00
0.611400 –2052.00 0.590600 2550.00
0.654700 –2154.00 0.632800 2366.00 –2000.
0.700300 –2292.00 0.677200 2142.00
0.748300 –2327.00 0.700300 1990.00
0.773200 –2361.00 0.748300 1736.00 P/106Pa = 6.0; T/K = 323.15
0.825200 –2440.00 0.798800 1501.00 P/106Pa = 6.0; T/K = 298.15
0.880100 –2116.00 0.825200 1255.00
0.908800 –1627.00 0.880100 878.00 –4000.
0.938300 –1095.00 0.908800 726.00 0.50
0.968700 –194.00 0.968700 308.00
x1
Uncertainties: σ (x1) = 0.00010; σ (HM)/J mol-1
= 2.00 + 0.030 |HM/J mol-1| See SELF for the totality of data
Brown, P. R.; Ott, J. B.; Lemon, L. R.; Moore, J. D. Excess molar enthalpies for (propane + ethene) over the temperature range
from 273.15 K to 373.15 K and the pressure range from 5 MPa to 15 MPa J. Chem. Thermodyn. 1996, 28, 905-921

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0410

Components: 1. C2H4, Ethene [74-85-1]
2. C6H12, Cyclohexane [110-82-7]
T/K H°sol/103J mol-1
298.15 –9.030 H°sol/103J mol-1
318.15 –8.240 –8.0

–8.3

–8.6

–8.9

–9.2
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.06 – 0.17
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0268

Components: 1. CH4, Methane [74-82-8]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.150 T/K = 413.150 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.15
0.369000 58.80 0.309000 37.20 P/103Pa = 101.325; T/K = 393.15
0.413000 62.00 0.368000 40.30 P/103Pa = 101.325; T/K = 413.15
0.468000 62.60 0.389000 40.30
0.570000 62.30 0.432000 42.60
0.604000 60.70 0.470000 43.40 60.
0.626000 58.60 0.529000 43.00
0.692000 53.10 0.610000 40.90
0.733000 48.30 0.645000 38.80
0.781000 42.90 0.825000 24.80
0.844000 32.50 0.871000 19.00 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J. A differential-flow mixing calorimeter. The excess enthalpy of methane + benzene, methane + cyclohexane, and
benzene + cyclohexane J. Chem. Thermodyn. 1977, 9, 901-910

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0416

Components: 1. CH4, Methane [74-82-8]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
298.15 –1.720 H°sol/103J mol-1
318.15 –1.170 –1.0

–1.2

–1.4

–1.6

–1.8
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.12 – 0.21
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0293

Components: 1. CH4, Methane [74-82-8]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
288.15 –3.540 H°sol/103J mol-1

–3.0

–3.5

–4.0

–4.5
283. 288. 293.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.50
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0418

Components: 1. C2H6, Ethane [74-84-0]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
298.15 –9.600 H°sol/103J mol-1
318.15 –9.080 –9.0

–9.2

–9.4

–9.6

–9.8
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.15 – 0.25
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0296

Components: 1. C2H6, Ethane [74-84-0]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
288.15 –15.090 H°sol/103J mol-1
298.15 –11.620

–11.5

–13.0

–14.5

–16.0
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.60–1.15
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0412

Components: 1. C3H8, Propane [74-98-6]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
298.15 –14.710 H°sol/103J mol-1
318.15 –14.140 –14.0

–14.2

–14.4

–14.6

–14.8
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.20
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0297

Components: 1. C3H8, Propane [74-98-6]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
288.15 –20.350 H°sol/103J mol-1
298.15 –16.560 –14.

–16.

–18.

–20.

–22.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.50
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0287

Components: 1. C6H6, Benzene [71-43-2]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
0.5
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.15 0.44
373.15 0.40
383.15 0.28
393.15 0.26
403.15 0.16 0.4
413.15 0.22

0.3

0.2

0.1
375. 390. 405.
T/K
Uncertainties: σ (T)/K = 0.01; σ (HE)/J mol-1
= 0.20
Wormald, C. J. A differential-flow mixing calorimeter. The excess enthalpy of methane + benzene, methane + cyclohexane, and
benzene + cyclohexane J. Chem. Thermodyn. 1977, 9, 901-910

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0417

Components: 1. C2H4, Ethene [74-85-1]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
298.15 –9.460 H°sol/103J mol-1
318.15 –8.200 –8.0

–8.5

–9.0

–9.5

–10.0
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.15 – 0.24
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0298

Components: 1. C2H4, Ethene [74-85-1]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
288.15 –15.390 H°sol/103J mol-1
298.15 –10.940

–11.5

–13.0

–14.5

–16.0
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.30–0.80
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0273

Components: 1. C6H14, Hexane [110-54-3]
2. C7H8, Toluene [108-88-3]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 358.150 T/K = 308.150 HE/J mol-1
640.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 308.15
0.049600 106.00 0.016500 37.00
0.083200 146.00 0.049700 112.00 P/106Pa = 12.5; T/K = 470.15
0.117400 228.00 0.083500 178.00
0.152100 259.00 0.117800 240.00
0.187300 321.00 0.152500 303.00 480.
0.223100 347.00 0.187800 350.00
0.259400 382.00 0.223600 401.00
0.296300 422.00 0.260000 436.00
0.333700 448.00 0.296900 471.00
0.371800 467.00 0.334500 497.00 320.
0.410400 481.00 0.372500 516.00
0.449700 475.00 0.411200 531.00
0.489600 482.00 0.450500 533.00
0.530200 479.00 0.490400 533.00
0.571400 465.00 0.531000 531.00
0.613400 457.00 0.572200 515.00 160.
0.656000 429.00 0.614100 493.00
0.699300 405.00 0.656700 462.00
0.743400 356.00 0.700000 425.00
0.788300 303.00 0.744000 382.00
0.833900 255.00 0.788800 325.00
0.880300 199.00 0.834300 263.00 0.
0.927600 112.00 0.880700 184.00 0.50
0.975600 35.00 0.927800 109.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 10.00 + 0.008 |HE/J mol-1| See SELF for the totality of data
Faux, P. W.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of (n-hexane + toluene) at 308.15, 358.15, 413.15, 470.15,
and 573.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1987, 19, 1087-1094

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0274

Components: 1. C6H14, Hexane [110-54-3]
2. C7H8, Toluene [108-88-3]
P/106Pa = 10.500 P/106Pa = 10.500
T/K = 573.15 T/K = 573.15 HM/J mol-1
600.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 573.15
0.016400 22.00 0.656400 376.00
0.049700 81.00 0.699700 352.00 P/106Pa = 12.5; T/K = 573.15
0.083400 124.00 0.743800 325.00
0.117600 174.00 0.743800 324.00
0.152400 216.00 0.788600 266.00 450.
0.187600 258.00 0.834200 219.00
0.187600 258.00 0.880500 185.00
0.223400 308.00 0.880500 165.00
0.223400 290.00 0.927700 94.00
0.259800 315.00 0.975700 31.00 300.
0.296700 352.00
0.296700 341.00
0.334200 378.00
0.372200 402.00
0.410900 428.00
0.410900 407.00 150.
0.450200 428.00
0.450200 407.00
0.490100 438.00
0.490100 415.00
0.530700 424.00
0.571900 410.00 0.
0.613800 397.00 0.50
0.656400 376.00
x1
Uncertainties: σ (x1) = 0.00050; σ (HM)/J mol-1
= 10.00 + 0.008 |HM/J mol-1| See SELF for the totality of data
Faux, P. W.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of (n-hexane + toluene) at 308.15, 358.15, 413.15, 470.15,
and 573.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1987, 19, 1087-1094

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0212

Components: 1. CHF3, Trifluoromethane [75-46-7]
2. C6H6, Benzene [71-43-2]
P/103Pa = 100.0
T/K = 298.150 Hsol/103J mol-1
0.0
x1/10-3 Hsol/103J mol-1
P/103Pa = 100.0; T/K = 298.15
0.036000 –18.08
0.042000 –17.85
0.072000 –16.84
0.082000 –16.90
0.144000 –15.46 –5.0
0.196000 –12.70
0.204000 –12.86
0.244000 –12.07
0.343000 –9.70
0.509000 –8.30 –10.0
0.564000 –8.05
0.632000 –7.70
0.771000 –7.05
1.020000 –6.64
1.192000 –6.27
1.283000 –6.27 –15.0
1.427000 –6.06
1.503000 –5.70
1.583000 –5.63
1.711000 –5.52
1.803000 –5.33
–20.0
0.00 0.05 0.10 0.15 0.20
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0213

Components: 1. CHF3, Trifluoromethane [75-46-7]
2. C7H8, Toluene [108-88-3]
P/103Pa = 100.000
T/K = 298.150 Hsol/103J mol-1
x1/10-3 Hsol/103J mol-1
P/103Pa = 100.; T/K = 298.15
0.057000 –16.59
0.062000 –15.28
0.098000 –14.40
0.187000 –13.40
0.220000 –13.10 –11.0
0.282000 –12.53
0.286000 –12.95
0.541000 –11.92
0.556000 –12.07
0.660000 –11.45 –14.0
0.775000 –11.32
0.818000 –11.00
0.975000 –10.72
1.154000 –10.39
1.222000 –10.62
1.260000 –10.29 –17.0
1.469000 –10.30
1.646000 –10.05
2.060000 –9.85

–20.0
0.6 1.2 1.8
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0214

Components: 1. CHF3, Trifluoromethane [75-46-7]
2. C8H10, 1,4-Dimethylbenzene [106-42-3]
P/103Pa = 100.000
T/K = 298.150 Hsol/103J mol-1
x1/10-3 Hsol/103J mol-1
P/103Pa = 100.; T/K = 298.15
0.050000 –18.86
0.060000 –16.98
0.075000 –15.91
0.170000 –13.84
0.235000 –12.98 –12.5
0.295000 –12.44
0.405000 –12.10
0.633000 –11.80
0.761000 –11.70
0.861000 –11.62 –15.0
1.102000 –11.61
1.334000 –11.64
1.526000 –11.63
1.799000 –11.53
2.306000 –11.61
–17.5

–20.0
0.6 1.2 1.8
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0215

Components: 1. CHF3, Trifluoromethane [75-46-7]
2. C9H12, 1,3,5-Trimethylbenzene [108-67-8]
P/103Pa = 100.000
T/K = 298.150 Hsol/103J mol-1
x1/10-3 Hsol/103J mol-1
P/103Pa = 100.; T/K = 298.15
0.061000 –16.99
0.095000 –15.76
0.138000 –14.35
0.188000 –13.37
0.357000 –12.20 –12.0
0.414000 –11.78
0.500000 –11.67
0.642000 –11.62
0.890000 –11.63
1.315000 –11.67 –14.0
1.674000 –11.56
1.843000 –11.58

–16.0

–18.0
0.5 1.0 1.5
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0422

Components: 1. CH4, Methane [74-82-8]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
298.15 –3.190 H°sol/103J mol-1
318.15 –2.430 –2.2

–2.5

–2.8

–3.1

–3.4
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.05
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0304

Components: 1. CH4, Methane [74-82-8]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
288.15 –6.440 H°sol/103J mol-1
–4.

–5.

–6.

–7.

–8.
283. 288. 293.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 1.3
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0424

Components: 1. C2H6, Ethane [74-84-0]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
298.15 –10.690 H°sol/103J mol-1
318.15 –10.060 –10.0

–10.2

–10.4

–10.6

–10.8
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.05
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0307

Components: 1. C2H6, Ethane [74-84-0]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
288.15 –16.180 H°sol/103J mol-1
298.15 –11.540 –10.

–12.

–14.

–16.

–18.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.30–0.90
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0425

Components: 1. C3H8, Propane [74-98-6]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
298.15 –16.040 H°sol/103J mol-1
318.15 –14.990 –14.

–15.

–16.

–17.

–18.
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.20
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0308

Components: 1. C3H8, Propane [74-98-6]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
288.15 –22.590 H°sol/103J mol-1
298.15 –17.500 –16.

–18.

–20.

–22.

–24.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.30–0.40
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0068

Components: 1. CCl4, Tetrachloromethane [56-23-5]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
0.4
T/K HE/J mol-1
353.20 –0.10
363.20 0.00
373.20 0.30
383.20 –0.10
403.20 –0.40 0.0
423.20 –0.60

–0.4

–0.8
P/103Pa = 101.325; x1 = 0.500

–1.2
365. 390. 415.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Parker, A. P.; Rieger, F.; Johnson, P. W.; Wormald, C. J. The excess molar enthalpy of (benzene, or cyclohexane +
tetrachloromethane)(g), and (benzene, or cyclohexane + chloromethane)(g) from the temperatures 353.2 to 423.2 K J. Chem.
Thermodyn. 1998, 30, 999-1010

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0423

Components: 1. C2H4, Ethene [74-85-1]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
298.15 –10.170 H°sol/103J mol-1
318.15 –9.140 –9.0

–9.3

–9.6

–9.9

–10.2
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.08 – 0.38
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0306

Components: 1. C2H4, Ethene [74-85-1]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
288.15 –15.100 H°sol/103J mol-1
298.15 –10.510

–11.0

–12.5

–14.0

–15.5
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.20–0.60
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0067

Components: 1. CCl4, Tetrachloromethane [56-23-5]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
1.4
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 1.30
363.20 0.70
373.20 0.40
383.20 0.80
403.20 0.60 1.0
423.20 0.10

0.7

0.3

0.0
365. 390. 415.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Parker, A. P.; Rieger, F.; Johnson, P. W.; Wormald, C. J. The excess molar enthalpy of (benzene, or cyclohexane +
tetrachloromethane)(g), and (benzene, or cyclohexane + chloromethane)(g) from the temperatures 353.2 to 423.2 K J. Chem.
Thermodyn. 1998, 30, 999-1010

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0173

Components: 1. CH3Cl, Chloromethane [74-87-3]
2. C2H6, Ethane [74-84-0]
P/106Pa = 5.0 P/106Pa = 5.0
T/K = 298.15 T/K = 298.15 HE/J mol-1
1000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 298.15
0.050300 46.60 0.860100 168.80
0.074900 68.30 0.909000 113.80 P/106Pa = 10.0; T/K = 298.15
0.122600 118.10 0.944200 76.80 P/106Pa = 7.5; T/K = 298.15
0.145900 141.00 0.978100 29.40
0.191300 184.80 750. P/106Pa = 5.0; T/K = 298.15
0.191300 177.10
0.213400 202.80
0.235200 232.80
0.277600 244.70
0.298400 261.90 500.
0.358600 291.90
0.397200 313.50
0.434600 333.80
0.470900 338.20
0.506200 341.80
0.557100 338.30 250.
0.589900 334.60
0.621700 318.90
0.667800 314.00
0.712100 288.10
0.740600 274.70
0.782000 237.60 0.
0.821800 204.60 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 0.5 + 0.02|HE/J mol-1| See SELF for the totality of data
Gruszkiewicz, M. S.; Ott, J. B.; Sipowska, J. T. Excess enthalpies for (ethane + chloromethane) at the temperatures (298.15,
323.15, 348.15, and 363.15) K and pressures from 5 MPa to 16 MPa J. Chem. Thermodyn. 1993, 25, 1017-1029

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0172

Components: 1. C2H6, Ethane [74-84-0]
2. CH3Cl, Chloromethane [74-87-3]
P/106Pa = 5.000 P/106Pa = 5.000
T/K = 323.15 T/K = 323.15 HM/J mol-1
8400.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 5.0; T/K = 363.15
0.021900 –75.60 0.701600 a –2496.00 P/106Pa = 5.0; T/K = 348.15
0.055800 –220.90 0.705800 a –2501.00 P/106Pa = 5.0; T/K = 323.15
0.091000 –356.90 0.705800 a –2501.00
0.115100 –462.20 0.709900 a –2299.00
0.139900 –555.90 0.722400 a –1728.00 5600.
0.152500 –616.10 0.743400 a –787.40
0.165200 –650.10 0.756200 a –409.10
0.178200 –714.80 0.782200 a 336.90
0.218000 –860.00 0.786600 a 706.20
0.259400 –1017.00 0.799800 a 1138.00 2800.
0.287900 –1154.00 0.804300 a 1331.00
0.332200 –1338.00 0.808700 1525.00
0.378300 –1508.00 0.817700 1544.00
0.410100 –1656.00 0.831200 1526.00
0.459600 –1847.00 0.854100 1415.00
0.493800 –2033.00 0.877400 1250.00 0.
0.529100 –2116.00 0.901100 1044.00
0.565400 –2265.00 0.920300 857.70
0.602800 –2381.00 0.925100 773.90
0.641400 –2485.00 0.949700 556.60
0.681200 –2568.00 0.974600 289.40
0.697500 –2574.00 –2800.
0.50
x1
Uncertainties: σ (x1) = 0.0005;σ (HM)/J mol-1
= 0.5 + 0.02|HM/J mol-1| a Two-phase region; See SELF for the totality of data
Gruszkiewicz, M. S.; Ott, J. B.; Sipowska, J. T. Excess enthalpies for (ethane + chloromethane) at the temperatures (298.15,
323.15, 348.15, and 363.15) K and pressures from 5 MPa to 16 MPa J. Chem. Thermodyn. 1993, 25, 1017-1029

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0070

Components: 1. CH3Cl, Chloromethane [74-87-3]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
60.0
T/K HE/J mol-1
353.20 55.90
358.20 51.20
363.20 50.50
368.20 47.70
373.20 46.00 50.0
378.20 43.40
383.20 41.00
393.20 38.20
403.20 35.20
413.20 32.90 40.0
423.20 30.30

30.0

P/103Pa = 101.325; x1 = 0.500

20.0
368. 393. 418.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Parker, A. P.; Rieger, F.; Johnson, P. W.; Wormald, C. J. The excess molar enthalpy of (benzene, or cyclohexane +
tetrachloromethane)(g), and (benzene, or cyclohexane + chloromethane)(g) from the temperatures 353.2 to 423.2 K J. Chem.
Thermodyn. 1998, 30, 999-1010

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0015

Components: 1. CH2Cl2, Dichloromethane [75-09-2]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
50.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 35.50
363.20 29.40
373.20 26.40
383.20 24.60
393.20 22.00 40.
403.20 19.00
413.20 17.70
423.20 16.90
433.20 15.90
443.20 13.00 30.
453.20 12.60

20.

10.
350. 400. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.0–2.0
Wormald, C. J.; Johnson, P. W. Benzene-dichloromethane association. The excess molar enthalpy of (cyclohexane +
dichloromethane)(g) and (benzene + dichloromethane)(g) from the temperature 353.2 K to 453.2 K J. Chem. Thermodyn. 1998,
30, 1243-1251

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0120

Components: 1. CHCl3, Trichloromethane [67-66-3]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
20.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 17.50
363.20 14.60
373.20 13.20
383.20 13.20
393.20 10.80 16.
403.20 8.60
413.20 9.00
423.20 7.10

12.

8.

4.
370. 390. 410.
T/K
Uncertainties: σ (T)/K = 0.1; σrel
(HE)= 0.02
Wormald, C. J.; Johnson, P. W. Benzene-chloroform association. Excess molar enthalpy of (cyclohexane + chloroform)(g) and
(benzene + chloroform)(g) at temperatures from 353.2 to 423.2 K J. Chem. Soc., Faraday Trans. 1998, 94, 1267-1270

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0069

Components: 1. CH3Cl, Chloromethane [74-87-3]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
40.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 32.70
358.20 29.90
363.20 28.10
368.20 26.50
373.20 24.80 32.5
378.20 24.10
383.20 21.00
393.20 20.70
403.20 18.00
413.20 15.80 25.0
423.20 15.40

17.5

10.0
365. 390. 415.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Parker, A. P.; Rieger, F.; Johnson, P. W.; Wormald, C. J. The excess molar enthalpy of (benzene, or cyclohexane +
tetrachloromethane)(g), and (benzene, or cyclohexane + chloromethane)(g) from the temperatures 353.2 to 423.2 K J. Chem.
Thermodyn. 1998, 30, 999-1010

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0014

Components: 1. CH2Cl2, Dichloromethane [75-09-2]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
0.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 –16.10
363.20 –12.90
373.20 –13.00
383.20 –10.80
393.20 –10.10 –5.
403.20 –7.70
413.20 –6.90
423.20 –8.10
433.20 –6.70
443.20 –6.60 –10.
453.20 –4.90

–15.

–20.
350. 400. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.0–2.0
Wormald, C. J.; Johnson, P. W. Benzene-dichloromethane association. The excess molar enthalpy of (cyclohexane +
dichloromethane)(g) and (benzene + dichloromethane)(g) from the temperature 353.2 K to 453.2 K J. Chem. Thermodyn. 1998,
30, 1243-1251

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0119

Components: 1. CHCl3, Trichloromethane [67-66-3]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
–12.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 –40.90
363.20 –32.70
373.20 –28.90
383.20 –24.20
393.20 –19.90 –20.
403.20 –18.50
413.20 –16.40

–28.

–36.

–44.
370. 390. 410.
T/K
Uncertainties: σ (T)/K = 0.1; σrel
(HE)= 0.02
Wormald, C. J.; Johnson, P. W. Benzene-chloroform association. Excess molar enthalpy of (cyclohexane + chloroform)(g) and
(benzene + chloroform)(g) at temperatures from 353.2 to 423.2 K J. Chem. Soc., Faraday Trans. 1998, 94, 1267-1270

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0115

Components: 1. CH3Cl, Chloromethane [74-87-3]
2. C2H5Cl, Chloroethane [75-00-3]
P/103Pa = 101.3
x1 = 0.500 HE/J mol-1
8.0
T/K HE/J mol-1
P/103Pa = 101.3; x1 = 0.500
290.20 7.60
300.20 6.10
310.20 5.10
330.20 3.70
350.20 2.90 6.4
370.20 2.30
390.20 1.80

4.8

3.2

1.6
280. 310. 340. 370. 400.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 0.2
Massucci, M.; Wormald, C. J. Second virial coefficients of chloromethane and chloroethane from measurements of the excess
enthalpy of (0.5N2 + 0.5CH3Cl)(g), and (0.5N2 + C2H5Cl)(g). The excess enthalpy of (0.5CH3Cl + 0.5C2H5Cl)(g) J. Chem.
Thermodyn. 1998, 30, 919-927

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0197

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. C3H8, Propane [74-98-6]
P/106Pa = 4.45 P/106Pa = 4.45
T/K = 293.15 T/K = 293.15 HE/J mol-1
480.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 4.45; T/K = 293.15
0.013700 4.00 0.443400 398.00 P/106Pa = 4.45; T/K = 300.95
0.041500 24.00 0.463400 422.00
0.070100 90.00 0.483800 415.00
0.099500 129.00 0.504400 417.00
0.114500 142.00 0.525400 411.00 360.
0.129600 163.00 0.546800 400.00
0.160600 196.00 0.568500 401.00
0.192500 253.00 0.590500 398.00
0.208800 260.00 0.612900 388.00
0.225300 281.00 0.658900 368.00 240.
0.225300 285.00 0.706400 335.00
0.259000 310.00 0.755600 306.00
0.259000 329.00 0.755600 311.00
0.276300 328.00 0.806500 256.00
0.293700 342.00 0.859300 199.00
0.311500 363.00 0.859300 200.00 120.
0.329500 364.00 0.914000 131.00
0.329500 375.00 0.970800 43.00
0.366300 374.00
0.385100 417.00
0.404300 391.00
0.423700 388.00 0.
0.443400 409.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE)= 0.02 See SELF for the totality of data
Cordray, D. R.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of (propane + chlorotrifluoromethane) from 293.15 to
383.15 K at 4.45 MPa J. Chem. Thermodyn. 1986, 18, 581-590

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0079

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. C3H8, Propane [74-98-6]
P/106Pa = 4.450 P/106Pa = 4.450
T/K = 373.15 T/K = 373.15 HE/J mol-1
3200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.45; T/K = 373.15
0.013700 971.00 0.612900 1690.00 P/106Pa = 4.45; T/K = 383.15
0.027500 1410.00 0.755600 1190.00
0.041500 1850.00 0.806500 963.00
0.070100 2210.00 0.806500 951.00
0.099500 2480.00 0.859300 658.00 2400.
0.129600 2610.00 0.859300 618.00
0.160600 2740.00 0.914000 382.00
0.192500 2820.00 0.970800 158.00
0.192500 2790.00
0.225300 2840.00 1600.
0.259000 2780.00
0.293700 2720.00
0.329500 2630.00
0.329500 2620.00
0.366300 2510.00
0.366300 2440.00 800.
0.404300 2360.00
0.443400 2300.00
0.463400 2130.00
0.463400 2220.00
0.525400 1970.00
0.525400 2030.00 0.
0.612900 1690.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE)= 0.02 See SELF for the totality of data
Cordray, D. R.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of (propane + chlorotrifluoromethane) from 293.15 to
383.15 K at 4.45 MPa J. Chem. Thermodyn. 1986, 18, 581-590

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0198

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. C3H8, Propane [74-98-6]
P/106Pa = 4.45 P/106Pa = 4.45
T/K = 323.15 T/K = 323.15 HM/J mol-1
3200.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 4.45; T/K = 333.15
0.013700 3.00 0.483800 –1480.00 P/106Pa = 4.45; T/K = 323.15
0.027500 –36.00 0.504400 –1430.00
0.027500 –18.00 0.504400 –1480.00
0.041500 –96.00 0.525400 –1480.00
0.070100 –187.00 0.546800 –1440.00 1600.
0.099500 –295.00 0.568500 –1310.00
0.129600 –387.00 0.568500 –1340.00
0.160600 –488.00 0.590500 –991.00
0.192500 –646.00 0.612900 –735.00
0.208800 –670.00 0.624300 –279.00 0.
0.242000 –792.00 0.635700 –45.00
0.259000 –830.00 0.658900 498.00
0.276300 –882.00 0.682400 910.00
0.293700 –983.00 0.694400 1220.00
0.311500 –1050.00 0.706400 1390.00
0.329500 –1100.00 0.755600 1460.00 –1600.
0.366300 –1160.00 0.780800 1430.00
0.385100 –1230.00 0.806500 1340.00
0.394700 –1270.00 0.859300 1100.00
0.404300 –1290.00 0.886400 879.00 P/106Pa = 4.45; T/K = 313.15
0.423700 –1330.00 0.914000 738.00 P/106Pa = 4.45; T/K = 308.15
0.423700 –1340.00 0.942100 504.00 –3200.
0.443400 –1400.00 0.970800 245.00 0.50
0.483800 –1480.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 See SELF for the totality of data
Cordray, D. R.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of (propane + chlorotrifluoromethane) from 293.15 to
383.15 K at 4.45 MPa J. Chem. Thermodyn. 1986, 18, 581-590

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0257

Components: 1. CCl2F2, Dichlorodifluoromethane [75-71-8]
2. C3H8, Propane [74-98-6]
P/106Pa = 4.450 P/106Pa = 4.450
T/K = 353.150 T/K = 363.150 HE/J mol-1
400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.45; T/K = 353.15
0.019100 19.00 0.009600 18.00
0.057500 61.00 0.019100 31.00 P/106Pa = 4.45; T/K = 369.95
0.076700 82.00 0.057500 85.00
0.096000 111.00 0.096000 129.00
0.134700 147.00 0.134700 170.00 300.
0.173400 177.00 0.173400 197.00
0.212400 203.00 0.212400 227.00
0.271000 241.00 0.291600 266.00
0.330000 266.00 0.330000 281.00
0.369400 283.00 0.389200 305.00 200.
0.409100 288.00 0.409100 299.00
0.448800 294.00 0.448800 310.00
0.488700 291.00 0.488700 308.00
0.528800 288.00 0.508700 307.00
0.569000 286.00 0.569000 295.00
0.609300 270.00 0.589100 290.00 100.
0.670100 261.00 0.649800 282.00
0.690400 250.00 0.670100 260.00
0.710800 232.00 0.731200 226.00
0.772200 193.00 0.772200 190.00
0.813200 163.00 0.854500 135.00
0.895900 107.00 0.895900 102.00 0.
0.937400 53.00 0.937400 61.00 0.50
0.979100 18.00 0.979100 16.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE)
= 0.02 See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Zebolsky, D. M.; Izatt, R. M. The excess enthalpies of (propane +
dichlorodifluoromethane) from 353.15 to 398.15 K at 4.45 MPa J. Chem. Thermodyn. 1985, 17, 335-348

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0259

Components: 1. CCl2F2, Dichlorodifluoromethane [75-71-8]
2. C3H8, Propane [74-98-6]
P/106Pa = 4.450 P/106Pa = 4.450
T/K = 385.650 T/K = 393.150 HE/J mol-1
4000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.45; T/K = 386.65
0.019100 149.00 0.019100 38.00
0.096000 578.00 0.057500 100.00 P/106Pa = 4.45; T/K = 393.15
0.134700 807.00 0.096000 129.00 P/106Pa = 4.45; T/K = 398.15
0.212400 1190.00 0.134700 220.00
0.290600 1620.00 0.173400 271.00 3000.
0.330000 1810.00 0.212400 332.00
0.369400 2030.00 0.251400 374.00
0.409100 2200.00 0.290600 436.00
0.448800 2360.00 0.330000 484.00
0.488700 2450.00 0.369400 518.00 2000.
0.528800 2580.00 0.409100 557.00
0.569000 2740.00 0.448800 586.00
0.609300 2780.00 0.488700 608.00
0.629500 2800.00 0.528800 632.00
0.649800 2860.00 0.569000 630.00
0.690400 2910.00 0.609300 658.00 1000.
0.710800 2860.00 0.649800 653.00
0.731200 2750.00 0.690400 634.00
0.772200 2580.00 0.731200 627.00
0.813200 1830.00 0.813200 541.00
0.854500 1020.00 0.854500 469.00
0.895900 390.00 0.895900 370.00 0.
0.937400 88.00 0.937400 274.00 0.50
0.979100 16.00 0.979100 96.60
x1
Uncertainties: σ (x1) = 0.00050; σrel
(HE)= 0.02 See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Zebolsky, D. M.; Izatt, R. M. The excess enthalpies of (propane +
dichlorodifluoromethane) from 353.15 to 398.15 K at 4.45 MPa J. Chem. Thermodyn. 1985, 17, 335-348

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0258

Components: 1. C3H8, Propane [74-98-6]
2. CCl2F2, Dichlorodifluoromethane [75-71-8]
P/106Pa = 4.450 P/106Pa = 4.450
T/K = 373.15 T/K = 373.15 HM/J mol-1
6000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 4.450; T/K = 384.65
0.020900 –42.00 0.650300 –1500.00
0.062600 –165.00 0.670100 –1600.00 P/106Pa = 4.450; T/K = 381.65
0.104100 –286.00 0.689700 –1590.00 P/106Pa = 4.450; T/K = 373.15
0.124800 –293.00 0.709400 –1600.00
0.145500 –413.00 0.709400 –1600.00 4000.
0.186800 –540.00 0.729000 –1620.00
0.207300 –522.00 0.748600 –1690.00
0.227800 –658.00 0.768100 –1680.00
0.268800 –686.00 0.787600 –1740.00
0.309600 –785.00 0.807100 –1660.00 2000.
0.329900 –794.00 0.826600 –1630.00
0.350200 –920.00 0.846000 –1450.00
0.370500 –891.00 0.865300 –1230.00
0.390700 –976.00 0.884700 –999.00
0.431000 –1140.00 0.894300 –775.00
0.451100 –1160.00 0.904000 –576.00 0.
0.471200 –1130.00 0.923300 –279.00
0.491300 –1250.00 0.942500 –179.00
0.511300 –1280.00 0.980900 –68.00
0.551300 –1304.00
0.571100 –1330.00
0.590900 –1430.00 –2000.
0.630600 –1464.00 0.50
0.650300 –1500.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM)= 0.02 See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Zebolsky, D. M.; Izatt, R. M. The excess enthalpies of (propane +
dichlorodifluoromethane) from 353.15 to 398.15 K at 4.45 MPa J. Chem. Thermodyn. 1985, 17, 335-348

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0210

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. C6H6, Benzene [71-43-2]
P/103Pa = 100.000
T/K = 298.150 Hsol/103J mol-1
0.0
x1/10-3 Hsol/103J mol-1
0.056000 –12.99
0.083000 –12.10
0.143000 –10.22
0.145000 –9.77
0.151000 –9.84 –4.0
0.212000 –8.00
0.267000 –6.90
0.279000 –6.11
0.296000 –5.92
0.384000 –4.72 –8.0
0.401000 –4.08
0.431000 –4.51
0.482000 –3.92
0.593000 –3.10
0.700000 –2.64
0.808000 –1.98 –12.0
0.984000 –1.55
1.306000 –0.82
1.542000 –0.90
1.786000 –0.41 P/103Pa = 100.; T/K = 298.15
–16.0
0.5 1.0 1.5
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0211

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. C7H8, Toluene [108-88-3]
P/103Pa = 100.000
T/K = 298.150 Hsol/103J mol-1
–4.0
x1/10-3 Hsol/103J mol-1
P/103Pa = 100.; T/K = 298.150
0.064000 –11.09
0.086000 –10.59
0.130000 –9.63
0.167000 –9.62
0.251000 –9.26 –6.0
0.343000 –8.62
0.355000 –8.72
0.409000 –8.59
0.546000 –8.03
0.800000 –7.34 –8.0
0.908000 –7.28
1.090000 –7.07
1.380000 –6.78
1.477000 –6.74
1.619000 –6.50
1.780000 –6.50 –10.0
1.903000 –6.29

–12.0
0.5 1.0 1.5
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0217

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. C8H10, 1,4-Dimethylbenzene [106-42-3]
P/103Pa = 100.000
T/K = 298.150 Hsol/103J mol-1
x1/10-3 Hsol/103J mol-1
P/103Pa = 100.; T/K = 298.15
0.049000 –12.95
0.068000 –11.96
0.116000 –10.83
0.262000 –9.79
0.352000 –9.47 –9.5
0.469000 –9.11
0.774000 –8.68
0.810000 –8.64
0.959000 –8.61
1.179000 –8.57 –11.0
1.335000 –8.61
1.581000 –8.62
2.014000 –8.64

–12.5

–14.0
0.6 1.2 1.8
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1331] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
Hsol/J mol-1, Molar enthalpy of solution of component 1
Method: Direct calorimetric measurement of Hsol at variable x1 and constant P and T

File Number: LB0216

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. C9H12, 1,3,5-Trimethylbenzene [108-67-8]
P/103Pa = 100.000
T/K = 298.150 Hsol/103J mol-1
x1/10-3 Hsol/103J mol-1
P/103Pa = 100.; T/K = 298.15
0.054000 –12.63
0.077000 –11.89
0.188000 –10.13
0.228000 –9.75
0.344000 –9.25 –9.0
0.477000 –8.99
0.723000 –8.73
1.026000 –8.73
1.318000 –8.66
1.614000 –8.62 –11.0
1.679000 –8.61

–13.0

–15.0
0.5 1.0 1.5
x1/10-3
Uncertainties: σ (x1)/10-3 = 0.002; σ (Hsol)/103J mol-1 = 0.020 + 0.008 |Hsol/103J mol-1|
Becker, F.; Braun, G.; Steiger, A. Microcalorimetric determination of the enthalpies of solution at 298.15 K of trifluoromethane
and of chlorotrifluoromethane in aromatic hydrocarbons J. Chem. Thermodyn. 1981, 13, 833-842

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0254

Components: 1. CHClF2, Chlorodifluoromethane [75-45-6]
2. C2H6, Ethane [74-84-0]
P/106Pa = 5.150 P/106Pa = 5.150
T/K = 293.150 T/K = 303.150 HE/J mol-1
880.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 5.15; T/K = 293.15
0.024700 70.00 0.024700 46.00
0.073300 235.00 0.073300 135.00 P/106Pa = 5.15; T/K = 303.15
0.121000 358.00 0.121000 229.00
0.167800 465.00 0.167800 326.00
0.213800 540.00 0.213800 372.00 660.
0.258900 609.00 0.258900 425.00
0.303200 650.00 0.303200 464.00
0.346800 692.00 0.346800 492.00
0.389500 711.00 0.368300 510.00
0.431600 726.00 0.389500 529.00 440.
0.431600 733.00 0.410600 530.00
0.472800 714.00 0.431600 531.00
0.513400 714.00 0.452300 540.00
0.553300 713.00 0.472800 540.00
0.592500 687.00 0.513400 534.00
0.631100 649.00 0.553300 528.00 220.
0.669000 628.00 0.592500 512.00
0.706300 585.00 0.669000 469.00
0.742900 546.00 0.706300 436.00
0.779000 463.00 0.779000 369.00
0.814500 403.00 0.814500 312.00
0.883800 266.00 0.883800 236.00 0.
0.917700 193.00 0.917700 170.00 0.50
0.983800 33.00 0.983800 18.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE) = 0.02 See SELF for the totality of data
Christensen, J. J.; Zebolsky, D. M.; Schofield, R. S.; Cordray, D. R.; Izatt, R. M. The excess enthalpies of (ethane +
chlorodifluoromethane) from 293.15 to 383.15 K at 5.15 MPa J. Chem. Thermodyn. 1984, 16, 905-916

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0256

Components: 1. CHClF2, Chlorodifluoromethane [75-45-6]
2. C2H6, Ethane [74-84-0]
P/106Pa = 5.150 P/106Pa = 5.150
T/K = 373.150 T/K = 383.150 HE/J mol-1
2400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 5.15; T/K = 373.15
0.024700 139.00 0.024700 85.00
0.073300 315.00 0.073300 152.00 P/106Pa = 5.15; T/K = 383.15
0.121000 489.00 0.121000 256.00
0.167800 621.00 0.167800 388.00
0.213800 778.00 0.213800 500.00 1800.
0.258900 950.00 0.258900 532.00
0.303200 1050.00 0.303200 569.00
0.346800 1230.00 0.325100 679.00
0.389500 1330.00 0.346800 684.00
0.431600 1400.00 0.346800 689.00 1200.
0.472800 1540.00 0.389500 723.00
0.513400 1580.00 0.431600 809.00
0.553300 1580.00 0.472800 837.00
0.592500 1740.00 0.472800 814.00
0.631100 1730.00 0.513400 838.00
0.669000 1830.00 0.553300 886.00 600.
0.706300 1800.00 0.592500 880.00
0.742900 1790.00 0.631100 873.00
0.779000 1760.00 0.742900 745.00
0.814500 1670.00 0.814500 650.00
0.849500 1410.00 0.849500 560.00
0.883800 1240.00 0.883800 494.00 0.
0.951000 519.00 0.917700 380.00 0.50
0.983800 230.00 0.983800 91.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE) = 0.02 See SELF for the totality of data
Christensen, J. J.; Zebolsky, D. M.; Schofield, R. S.; Cordray, D. R.; Izatt, R. M. The excess enthalpies of (ethane +
chlorodifluoromethane) from 293.15 to 383.15 K at 5.15 MPa J. Chem. Thermodyn. 1984, 16, 905-916

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0255

Components: 1. C2H6, Ethane [74-84-0]
2. CHClF2, Chlorodifluoromethane [75-45-6]
P/106Pa = 5.150 P/106Pa = 5.150
T/K = 363.15 T/K = 363.15 HM/J mol-1
8400.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 5.150; T/K = 313.15
0.016200 119.00 0.388100 5610.00
0.049000 373.00 0.446700 5310.00 P/106Pa = 5.150; T/K = 333.15
0.049000 363.00 0.486600 5000.00 P/106Pa = 5.150; T/K = 363.15
0.082300 a 996.00 0.527200 4760.00
0.082300 a 986.00 0.527200 4810.00 5600.
0.099200 a 2405.00 0.568400 4350.00
0.116200 a 3884.00 0.653200 3740.00
0.133300 a 4440.00 0.696800 3310.00
0.133300 a 4570.00 0.696800 3240.00
0.150500 a 5650.00 0.741100 2910.00 2800.
0.150500 a 5480.00 0.786200 2390.00
0.150500 a 5470.00 0.832200 1930.00
0.185500 5950.00 0.879000 1320.00
0.221000 6060.00 0.926700 826.00
0.221000 5930.00 0.975300 323.00
0.257100 5930.00 0.975300 328.00 0.
0.257100 6040.00
0.293700 5820.00
0.293700 5920.00
0.331000 5720.00
0.331000 5840.00
0.368900 5630.00 –2800.
0.368900 5730.00 0.50
0.388100 5610.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Zebolsky, D. M.; Schofield, R. S.; Cordray, D. R.; Izatt, R. M. The excess enthalpies of (ethane +
chlorodifluoromethane) from 293.15 to 383.15 K at 5.15 MPa J. Chem. Thermodyn. 1984, 16, 905-916

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0264

Components: 1. CHClF2, Chlorodifluoromethane [75-45-6]
2. C6H14, 2,3-Dimethylbutane [79-29-8]
P/106Pa = 5.500 P/106Pa = 5.500
T/K = 363.150 T/K = 423.150 HE/J mol-1
1500.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 5.50; T/K = 363.15
0.036000 18.30 0.036000 –156.00 P/106Pa = 5.50; T/K = 383.15
0.104500 99.10 0.104500 –477.00 P/106Pa = 5.50; T/K = 423.15
0.137100 148.00 0.229300 –1062.00
0.199500 223.00 0.286300 –1330.00
0.229300 253.00 0.340100 –1507.00 0.
0.286300 287.00 0.391000 –1756.00
0.340100 302.00 0.439200 –1895.00
0.391000 319.00 0.484900 –2007.00
0.439200 332.00 0.528300 –2017.00
0.484900 322.00 0.569600 –1922.00 –1500.
0.528300 309.00 0.608900 –1653.00
0.569600 294.00 0.646300 –857.00
0.608900 272.00 0.682100 –68.40
0.646300 247.00 0.716200 758.00
0.682100 213.00 0.748900 1220.00
0.716200 183.00 0.780100 1399.00 –3000.
0.748900 147.00 0.810000 1451.00
0.780100 117.00 0.838800 1381.00
0.810000 89.40 0.866300 1231.00
0.838800 54.80 0.892800 1064.00
0.892800 6.70 0.918200 838.00
0.942700 –22.80 0.942700 607.00 –4500.
0.966300 –27.20 0.966300 375.00 0.50
0.989000 –8.20 0.989000 82.10
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 10.0 + 0.008 |HE/J mol-1| See SELF for the totality of data
Izatt, R. M.; Schofield, R. S.; Faux, P. W.; Harding, P. R.; Christensen, S. P.; Christensen, J. J. The excess enthalpies of
liquid Freon-22 + 2,3-dimethylbutane mixtures from 363 to 423 K at 5.5 MPa Thermochim. Acta 1983, 68, 223-232

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0064

Components: 1. C4H10O, Diethyl ether [60-29-7]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
20.0
T/K HE/J mol-1
353.20 18.90
358.20 16.30
363.20 13.90
368.20 15.50
373.20 13.30 16.0
383.20 12.50
393.20 11.80
403.20 9.40
413.20 8.70
423.20 8.40 12.0

8.0

P/103Pa = 101.325; x1 = 0.500

4.0
365. 390. 415.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Bowles, J.; Lacey, M.; Mathonat, C.; Sowden, C. J.; Wormald, C. J. Benzene-diethyl ether association. The excess molar
enthalpy of (cyclohexane + diethyl ether)(g) and (benzene + diethyl ether)(g) from the temperatures 353.2 K to 423.2 K J. Chem.
Thermodyn. 1998, 30, 939-949

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0065

Components: 1. C4H10O, Diethyl ether [60-29-7]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
8.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 5.40
358.20 4.30
363.20 3.80
368.20 3.70
373.20 3.70 6.0
383.20 2.40
393.20 2.70
403.20 2.10
413.20 1.10
423.20 1.00 4.0

2.0

0.0
365. 390. 415.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Bowles, J.; Lacey, M.; Mathonat, C.; Sowden, C. J.; Wormald, C. J. Benzene-diethyl ether association. The excess molar
enthalpy of (cyclohexane + diethyl ether)(g) and (benzene + diethyl ether)(g) from the temperatures 353.2 K to 423.2 K J. Chem.
Thermodyn. 1998, 30, 939-949

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0299

Components: 1. CH4, Methane [74-82-8]
2. C4H8O, Oxolane [109-99-9]
T/K H°sol/103J mol-1
288.15 –10.070 H°sol/103J mol-1
298.15 –5.150 –4.

–6.

–8.

–10.

–12.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.20–0.70
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0301

Components: 1. C2H6, Ethane [74-84-0]
2. C4H8O, Oxolane [109-99-9]
T/K H°sol/103J mol-1
288.15 –17.200 H°sol/103J mol-1
298.15 –11.230 –10.

–12.

–14.

–16.

–18.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.40–0.80
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0302

Components: 1. C3H8, Propane [74-98-6]
2. C4H8O, Oxolane [109-99-9]
T/K H°sol/103J mol-1
288.15 –20.740 H°sol/103J mol-1
298.15 –16.690 –14.

–16.

–18.

–20.

–22.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.50–0.60
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0303

Components: 1. C2H4, Ethene [74-85-1]
2. C4H8O, Oxolane [109-99-9]
T/K H°sol/103J mol-1
288.15 –16.680 H°sol/103J mol-1
298.15 –12.530 –10.

–12.

–14.

–16.

–18.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.80
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0112

Components: 1. C3H8, Propane [74-98-6]
2. C4H8O2, 1,4-Dioxane [123-91-1]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
64.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 59.60
383.20 52.90
393.20 48.90
403.20 46.20
413.20 42.20 56.
423.20 39.20
433.20 36.90

48.

40.

32.
385. 405. 425.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Johnson, P. W. Quadrupole coupling in (carbon dioxide + dioxane)(g). The excess molar enthalpy and second
cross-coefficient of (dioxane + carbon dioxide or propane) (g) J. Chem. Thermodyn. 1999, 31, 1085-1091

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0012

Components: 1. C4H8O2, 1,4-Dioxane [123-91-1]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
60.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 54.20
378.20 51.50
383.20 48.10
388.20 46.30
393.20 44.20 52.5
403.20 41.30
413.20 39.20
423.20 34.50

45.0

37.5

30.0
350. 375. 400. 425. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Parker, A. P.; Rieger, F. Benzene-dioxane association. The excess molar enthalpy of (cyclohexane +
dioxane)(g) and (benzene + dioxane)(g) from the temperature (373.2 to 433.2) K J. Chem. Thermodyn. 1998, 30, 1227-1234

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0011

Components: 1. C4H8O2, 1,4-Dioxane [123-91-1]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
25.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 22.60
378.20 22.10
383.20 22.50
388.20 20.00
393.20 18.00 22.5
403.20 18.20
413.20 16.50
423.20 16.20

20.0

17.5

15.0
350. 375. 400. 425. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Parker, A. P.; Rieger, F. Benzene-dioxane association. The excess molar enthalpy of (cyclohexane +
dioxane)(g) and (benzene + dioxane)(g) from the temperature (373.2 to 433.2) K J. Chem. Thermodyn. 1998, 30, 1227-1234

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0137

Components: 1. CH4O, Methanol [67-56-1]
2. C2H6, Ethane [74-84-0]
P/106Pa = 6.9 P/106Pa = 6.9
T/K = 298.15 T/K = 298.15 HE/J mol-1
150.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.15
0.020200 131.89 0.768700 16.14
0.039900 136.17 0.812300 19.89
0.059200 134.39 0.852900 23.40
0.078200 127.45 0.890700 22.14
0.096800 117.56 0.926000 18.76 100.
0.115000 111.35 0.959000 12.29
0.150400 93.98 0.990100 4.17
0.167600 88.70
0.201100 80.10
0.233300 71.22 50.
0.249000 67.33
0.294300 56.08
0.337400 43.43
0.378200 35.90
0.417100 25.44
0.454100 14.21 0.
0.489400 4.87
0.523000 –1.85
0.555200 –5.18
0.585900 –6.97
0.615400 –4.65
0.670700 1.01 –50.
0.721600 7.03 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0096

Components: 1. CH4O, Methanol [67-56-1]
2. C2H6, Ethane [74-84-0]
P/106Pa = 7.5 P/106Pa = 7.5
T/K = 298.15 T/K = 298.15 HE/J mol-1
240.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 298.15
0.025500 134.70 0.744000 23.45 P/106Pa = 7.5; T/K = 298.15
0.026900 137.16 0.782500 26.68
0.031800 138.37 0.818800 28.46
0.062600 138.46 0.853200 29.23
0.092500 129.39 0.885700 26.72 180.
0.121600 117.61 0.916500 21.58
0.149700 101.32 0.945800 16.52
0.177100 a 96.78 0.973500 8.76
0.219300 a 85.40
0.254800 a 79.14 120.
0.293600 a 65.62
0.326300 a 59.17
0.362200 a 48.33
0.392400 a 44.59
0.425600 a 32.96
0.453600 a 27.55 60.
0.484500 a 20.32
0.510500 a 14.63
0.539300 a 9.21
0.580500 6.57
0.613100 8.50
0.659500 13.70 0.
0.703000 19.30 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE)= 0.02 a Two-phase region; See SELF for the totality of data
Sipowska, J. T.; Graham, R. C.; Neely, B. J.; Ott, J. B.; Izatt, R. M. Excess enthalpies for (ethane + methanol) at 298.15 and
348.15 K and 7.5 and 15 MPa, and at 323.15 K at 7.5, 10, and 15 MPa J. Chem. Thermodyn. 1989, 21, 1085-1093

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0202

Components: 1. C2H6, Ethane [74-84-0]
2. CH4O, Methanol [67-56-1]
P/106Pa = 7.500 P/106Pa = 7.500
T/K = 348.15 T/K = 348.15 HM/J mol-1
1000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 348.15
0.008700 –20.00 0.937400 a 858.20
0.017500 –44.70 0.943500 a 866.50 P/106Pa = 7.5; T/K = 323.15
0.026500 –69.00 0.949600 a 885.50
0.054200 –152.80 0.955800 a 901.10
0.083500 –235.40 0.962000 831.10 500.
0.114300 –325.10 0.968200 753.10
0.146800 –422.80
0.181200 –530.70
0.217500 –635.30
0.230100 a –650.40 0.
0.256000 a –597.10
0.296900 a –508.80
0.340400 a –417.20
0.386900 a –316.20
0.436400 a –209.10
0.489500 a –96.30 –500.
0.607600 a 155.40
0.673700 a 301.70
0.745200 a 443.40
0.780700 a 514.50
0.822900 a 620.10
0.861400 a 688.90 –1000.
0.907500 a 791.60 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Sipowska, J. T.; Graham, R. C.; Neely, B. J.; Ott, J. B.; Izatt, R. M. Excess enthalpies for (ethane + methanol) at 298.15 and
348.15 K and 7.5 and 15 MPa, and at 323.15 K at 7.5, 10, and 15 MPa J. Chem. Thermodyn. 1989, 21, 1085-1093

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0182

Components: 1. CH4O, Methanol [67-56-1]
2. C3H8, Propane [74-98-6]
P/106Pa = 5.0 P/106Pa = 15.0
T/K = 298.15 T/K = 363.15 HE/J mol-1
1680.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 363.15
0.026600 192.50 0.034200 651.10 P/106Pa = 15.0; T/K = 348.15
0.035300 211.80 0.047500 791.70 P/106Pa = 15.0; T/K = 323.15
0.069400 258.00 0.067200 928.30
0.102200 292.10 0.129900 1139.70
P/106Pa = 15.0; T/K = 298.15
0.133800 312.30 0.159600 1191.50 1260.
0.193700 341.70 0.188400 1221.30
0.276400 367.90 0.216300 1245.30
0.350800 376.20 0.243300 1249.50
0.418800 379.60 0.269400 1252.60
0.480900 377.60 0.319300 1238.60 840.
0.537900 372.00 0.431800 1159.70
0.590400 362.10 0.472400 1112.30
0.638800 346.80 0.510900 1066.60
0.683700 329.90 0.547500 1023.20
0.725400 316.80 0.582100 967.20
0.764300 287.20 0.630900 884.80 420.
0.800600 263.50 0.661600 838.20
0.834600 233.70 0.704800 754.70
0.866400 202.70 0.829800 489.80
0.896300 165.30 0.862400 405.40
0.924500 128.90 0.909300 297.70
0.951100 87.70 0.940600 198.80 0.
0.976200 46.40 0.983800 56.20 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE) = 0.02 See SELF for the totality of data
Sipowska, J. T.; Ott, J. B.; Neely, B. J.; Izatt, R. M. Excess enthalpies for (propane + methanol) at the temperatures (298.15,
323.15, 348.15, and 373.15) K and pressures (5, 10, and 15) MPa, and at 363.15 K and (5 and 15) MPa J. Chem. Thermodyn.
1991, 23, 551-559

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0262

Components: 1. C3H8, Propane [74-98-6]
2. CH4O, Methanol [67-56-1]
P/106Pa = 5.000 P/106Pa = 5.000
T/K = 373.15 T/K = 373.15 HM/J mol-1
2000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 15.0; T/K = 373.15
0.049200 92.70 0.898400 1391.60
0.075900 142.20 0.898400 1391.60 P/106Pa = 5.0; T/K = 373.15
0.104200 181.70 0.911300 1375.90
0.134300 237.50 0.931000 1294.80
0.177400 298.20 0.951200 1132.30 1500.
0.212300 340.60
0.249500 392.40
0.289400 443.40
0.332200 494.50
0.378400 555.70 1000.
0.411100 600.70
0.445700 636.50
0.482100 694.40
0.520600 756.00
0.561400 809.80
0.604600 884.10 500.
0.650600 960.20
0.735600 1063.30
0.735600 1130.20
0.779000 1236.30
0.807300 1293.70
0.836600 1353.00 0.
0.867000 1394.20 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 See SELF for the totality of data
Sipowska, J. T.; Ott, J. B.; Neely, B. J.; Izatt, R. M. Excess enthalpies for (propane + methanol) at the temperatures (298.15,
323.15, 348.15, and 373.15) K and pressures (5, 10, and 15) MPa, and at 363.15 K and (5 and 15) MPa J. Chem. Thermodyn.
1991, 23, 551-559

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0208

Components: 1. CH4O, Methanol [67-56-1]
2. C5H12, Pentane [109-66-0]
P/106Pa = 0.400 P/106Pa = 0.400
T/K = 283.15 T/K = 283.15 HE/J mol-1
1800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.000; T/K = 363.15
0.034700 171.30 0.752400 418.80
0.046000 189.60 0.788000 397.10 P/106Pa = 15.000; T/K = 298.15
0.089300 250.00 0.820600 370.70
0.130200 295.70 0.869000 316.20
0.168800 324.70 0.903300 257.30 1350.
0.205400 351.80 0.941600 177.90
0.240100 368.80 0.981800 58.80
0.273000 a 378.30
0.304300 a 384.70
0.334100 a 385.40 900.
0.362500 a 395.10
0.389600 a 390.10
0.415500 a 401.10
0.440200 a 406.00
0.463900 a 409.40
0.486600 a 411.50 450.
0.508300 a 415.30
0.549200 a 414.00
0.587000 a 425.70
0.622100 a 428.30 P/106Pa = 0.400; T/K = 283.15
0.670100 a 433.70
0.713300 435.50 0.
0.739800 425.90 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.010 |HE/J mol-1|
a Two-phase region; See SELF for the totality of data
Ott, J. B.; Sipowska, J. T.; Marchant, B. G. Excess enthalpies for (pentane + methanol) at the temperatures (283.15, 298.15,
and 363.15) K and the pressures (0.4, 5, and 15) MPa J. Chem. Thermodyn. 1994, 26, 717-725

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0209

Components: 1. C5H12, Pentane [109-66-0]
2. CH4O, Methanol [67-56-1]
P/106Pa = 0.40 P/106Pa = 0.40
T/K = 363.15 T/K = 363.15 HM/J mol-1
19500.
x1 HM/J mol-1 x1 HM/J mol-1
0.012000 –187.00 0.374600 a 15900.00
0.018200 –292.00 0.395100 a 16800.00
0.024500 –407.00 0.416600 a 17900.00
0.037600 –550.00 0.450800 18700.00
0.039800 –499.00 0.487400 17700.00 13000.
0.044400 –494.00 0.513400 16900.00
0.048500 –405.00 0.555000 15900.00
0.051300 a –236.00 0.584500 14900.00
0.054200 a –119.00 0.632000 13700.00
0.058400 a 72.00 0.665900 12800.00 6500.
0.061300 a 120.00 0.683600 12200.00
0.065700 a 277.00 0.701800 11500.00
0.073200 a 508.00 0.759900 8510.00
0.080800 a 1120.00 0.801800 7030.00
0.096700 a 1690.00 0.823700 6310.00
0.131000 a 3600.00 0.869800 4650.00 0.
0.159200 a 5410.00 0.910700 3290.00
0.189900 a 6500.00 0.932100 2520.00
0.223500 a 8160.00 0.945200 2130.00 P/106Pa = 0.40; T/K = 363.15
0.260200 a 10100.00
0.300600 a 11900.00
0.318000 a 13000.00 –6500.
0.345400 a 14400.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 1.00 + 0.03 |HM/J mol-1|
a Two-phase region;
Ott, J. B.; Sipowska, J. T.; Marchant, B. G. Excess enthalpies for (pentane + methanol) at the temperatures (283.15, 298.15,
and 363.15) K and the pressures (0.4, 5, and 15) MPa J. Chem. Thermodyn. 1994, 26, 717-725

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0097

Components: 1. CH4O, Methanol [67-56-1]
2. C5H12, Pentane [109-66-0]
T/K = 482.700 T/K = 492.700
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
8000
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 472.5; x1 = 0.500
0.340 129.000 0.370 134.000 T/K = 492.7; x1 = 0.500
0.520 202.000 0.520 163.000 T/K = 522.7; x1 = 0.500
0.690 254.000 0.690 232.000
1.030 395.000 1.040 367.000
1.390 563.000 1.390 507.000 6000
1.730 764.200 1.720 666.000
2.010 927.000 1.990 810.000
2.520 1383.000 2.500 1129.000
3.000 1987.000 3.000 1555.000
3.510 2837.000 3.510 2140.000 4000
3.710 3515.000 4.000 3032.000
3.890 4527.000 4.500 4502.000
4.110 5598.000 5.000 5217.000
4.200 5775.000 5.180 5351.000
4.300 5933.000 5.520 5468.000
4.520 6193.000 5.640 5654.000 2000
4.660 6272.000
4.680 6164.000
4.780 6078.000
4.790 6167.000
4.820 6415.000
0.0 1.6 3.2 4.8 6.4
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - n-pentane and methanol - n-hexane from 454.4 to 522.7 K
and up to 6 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 1345-1349

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0283

Components: 1. CH4O, Methanol [67-56-1]
2. C5H12, Pentane [109-66-0]
T/K = 452.400 T/K = 462.400
x1 = 0.5000 x1 = 0.5000 HM/J mol-1
9000
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
T/K = 452.40; x1 = 0.500
2.59 7212.00 2.96 7908.00
3.02 8004.00 T/K = 462.40; x1 = 0.500
3.09 7945.00
3.21 7361.00
8500

8000

7500

7000
2.4 2.7 2.9 3.2 3.4
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HM) = 0.05
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - n-pentane and methanol - n-hexane from 454.4 to 522.7 K
and up to 6 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 1345-1349

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0098

Components: 1. CH4O, Methanol [67-56-1]
2. C6H14, Hexane [110-54-3]
T/K = 502.200 T/K = 522.500
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
6000
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 472.5; x1 = 0.500
0.390 187.000 0.410 152.000 T/K = 502.2; x1 = 0.500
0.640 293.000 0.560 202.000 T/K = 522.5; x1 = 0.500
0.680 306.000 0.690 259.000
0.710 328.000 0.850 316.000
0.770 361.000 1.060 414.000 4500
0.960 447.000 1.130 419.000
1.020 471.000 1.240 487.000
1.120 544.000 1.390 561.000
1.230 593.000 1.730 786.000
1.450 731.000 1.910 908.000 3000
1.520 771.000 1.980 1026.000
1.580 803.000 2.500 1429.000
1.710 919.000 2.730 1674.000
1.880 1106.000 3.000 2206.000
1.890 1142.000 3.120 2555.000
1.980 1152.000 3.400 3171.000 1500
2.110 1336.000 3.490 3812.000
2.260 1621.000 3.520 4203.000
2.480 1990.000 3.860 5347.000
2.500 2180.000 4.070 5701.000
2.610 2588.000 4.230 5462.000
2.740 2898.000 4.490 5360.000 0
4.740 5651.000 0.0 1.6 3.2 4.8 6.4
6.010 5615.000
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - n-pentane and methanol - n-hexane from 454.4 to 522.7 K
and up to 6 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 1345-1349

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0284

Components: 1. CH4O, Methanol [67-56-1]
2. C6H14, Hexane [110-54-3]
T/K = 492.300 T/K = 502.200
x1 = 0.5000 x1 = 0.5000 HM/J mol-1
8000
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
T/K = 492.30; x1 = 0.500
2.41 7497.00 2.80 6563.00
4.04 7644.00 2.80 7082.00 T/K = 502.20; x1 = 0.500
4.49 7456.00 2.80 7076.00
4.85 7091.00 3.01 7271.00
3.20 7254.00 7500
3.42 7214.00
3.50 7297.00
4.00 6930.00
4.02 7133.00
4.96 6841.00 7000

6500

6000
2.0 3.0 4.0 5.0 6.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HM) = 0.05
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - n-pentane and methanol - n-hexane from 454.4 to 522.7 K
and up to 6 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 1345-1349

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0138

Components: 1. C2H6, Ethane [74-84-0]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 6.9 P/106Pa = 6.9
T/K = 298.15 T/K = 298.15 HE/J mol-1
180.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.150
0.014200 –4.42 0.864300 31.11
0.057900 –24.34 0.877300 44.06
0.103300 –44.58 0.889050 50.16
0.150300 –66.22 0.903800 62.37
0.199100 –86.87 0.917200 76.92 90.
0.249800 –109.22 0.930700 88.75
0.302400 –132.58 0.944400 97.24
0.329600 –137.11 0.958100 109.69
0.357200 –144.06 0.972000 113.97
0.385500 –151.74 0.985900 109.97 0.
0.414300 –157.96
0.443700 –159.53
0.473800 –159.89
0.535800 –148.91
0.557000 –147.74
0.600500 –134.83 –90.
0.622700 –127.49
0.668100 –105.41
0.703100 –90.84
0.738900 –66.49
0.775500 –43.38
0.812900 –14.64 –180.
0.851300 13.45 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0373

Components: 1. C2H6, Ethane [74-84-0]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 5.000 P/106Pa = 5.000
T/K = 298.15 T/K = 298.15 HE/J mol-1
400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 5; T/K = 298.15
0.011800 –8.10 0.820700 –220.80
0.047900 –34.50 0.842000 –197.70 P/106Pa = 10; T/K = 298.15
0.080100 –62.30 0.863700 –163.80 P/106Pa = 15; T/K = 298.15
0.110500 –92.50 0.885600 –136.80
0.136500 –111.00 0.907900 –99.20 200.
0.176500 –152.60 0.930400 –59.70
0.217700 –188.10 0.939600 –37.60
0.246000 –209.10 0.953300 –7.40
0.289600 –241.40 0.964400 11.40
0.334600 –275.30 0.976500 41.90 0.
0.365500 –298.90 0.981700 45.80
0.413200 –322.00
0.445900 –340.20
0.496400 –350.40
0.531100 –352.10
0.566600 –352.10 –200.
0.603100 –348.60
0.659400 –334.10
0.693200 –318.20
0.738000 –293.20
0.758200 –272.30
0.778800 –259.30 –400.
0.799600 –236.60 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 10.00 + 0.008 |HE/J mol-1| See SELF for the totality of data
Ott, J. B.; Sipowska, J. T.; Owen, R. L.; Izatt, R. M. Excess enthalpies for (ethane + ethanol) at (298.15, 323.15, and 348.15) K
and at (5, 10, and 15) MPa J. Chem. Thermodyn. 1990, 22, 683-694

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0374

Components: 1. C2H6, Ethane [74-84-0]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 5.000 P/106Pa = 5.000
T/K = 348.15 T/K = 348.15 HM/J mol-1
1200.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 5; T/K = 348.15
0.023700 –134.90 0.930400 a 822.00
0.047900 –255.90 0.953300 860.80 P/106Pa = 10; T/K = 348.15
0.097700 –513.70 0.976500 753.10 P/106Pa = 15; T/K = 348.15
0.136500 –694.50 0.982600 601.00
0.176500 –899.70 600.
0.217700 –1072.90
0.260400 a –999.50
0.289600 a –906.90
0.334600 a –805.80
0.365500 a –702.80 0.
0.413200 a –596.10
0.445900 a –500.30
0.496400 a –365.80
0.531100 a –280.20
0.566600 a –178.70
0.603100 a –85.50 –600.
0.659400 a 81.70
0.698200 a 180.40
0.738000 a 306.40
0.778800 a 395.00
0.799600 a 470.70
0.863700 a 619.50 –1200.
0.907900 a 731.80 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 10.00 + 0.02 |HM/J mol-1|a Two-phase region; See SELF for the totality of data
Ott, J. B.; Sipowska, J. T.; Owen, R. L.; Izatt, R. M. Excess enthalpies for (ethane + ethanol) at (298.15, 323.15, and 348.15) K
and at (5, 10, and 15) MPa J. Chem. Thermodyn. 1990, 22, 683-694

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0084

Components: 1. C2H6O, Ethanol [64-17-5]
2. C6H14, Hexane [110-54-3]
T/K = 483.20 T/K = 522.90
x1 = 0.500 x1 = 0.500 HE/J mol-1
7200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 462.9; x1 = 0.500
0.410 156.000 0.420 130.000 T/K = 483.2; x1 = 0.500
0.700 277.000 0.690 204.000 T/K = 512.8; x1 = 0.500
0.950 452.000 0.970 298.000
1.240 648.000 1.250 397.000
T/K = 522.9; x1 = 0.500
1.530 961.000 1.520 518.000 5400.
1.790 1365.000 1.810 654.000
2.050 776.000
2.290 964.000
2.600 1191.000
3.000 1741.000 3600.
3.520 3010.000
4.000 4881.000
4.240 5113.000
4.510 5054.000

1800.

0.
0.4 1.5 2.6 3.7 4.8
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Massucci, M.; Wormald, C. J.; Lu, Y. Excess molar enthalpies of ethanol - hexane, ethanol - cyclohexane and ethanol - benzene
from 453.5 to 522.9 K and up to 4.5 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 4193-4197

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0371

Components: 1. C2H6, Ethane [74-84-0]
2. C3H8O, Propan-1-ol [71-23-8]
P/106Pa = 5.000 P/106Pa = 5.000
T/K = 298.15 T/K = 298.15 HE/J mol-1
220.
x1 HE/J mol-1 x1 HE/J mol-1
0.044700 –53.70 0.888900 –230.30
0.089900 –109.10 0.925600 –156.90
0.135600 –157.10 0.944100 –107.20
0.181800 –204.80 0.962700 –49.00
0.213000 –239.10 0.981300 12.70 0.
0.244300 –268.20 0.986000 23.60
0.275900 –299.20 0.988800 32.50
0.307700 –330.50
0.339800 –356.10
0.372100 –375.50 –220.
0.404700 –399.10
0.437500 –414.20
0.470600 –434.30
0.504000 –438.30
0.537600 –446.70
0.571500 –448.20 –440.
0.605600 –448.00
0.657400 –446.80 P/106Pa = 15; T/K = 298.15
0.692200 –428.50
0.727300 –412.60 P/106Pa = 10; T/K = 298.15
0.762700 –380.50 P/106Pa = 5; T/K = 298.15
0.816400 –332.60 –660.
0.852500 –289.10 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 10 + 0.008 |HE/J mol-1| See SELF for the totality of data
Ott, J. B.; Lemon, L. R.; Sipowska, J. T.; Brown, P. R. Excess enthalpies and excess volumes for (ethane + propan-1-ol) at the
temperatures (298.15, 323.15, and 348.15) K and at the pressures (5, 10, 12.5, and 15) MPa J. Chem. Thermodyn. 1995, 27
, 1033-1045

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0139

Components: 1. C2H6, Ethane [74-84-0]
2. C3H8O, Propan-1-ol [71-23-8]
P/106Pa = 6.9 P/106Pa = 6.9
T/K = 298.15 T/K = 298.15 HE/J mol-1
100.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.150
0.018200 –15.39 0.934200 28.13
0.073000 –57.04 0.945100 43.98
0.128500 –96.91 0.956000 58.48
0.184600 –137.32 0.967000 73.39
0.241400 –171.08 0.978000 84.97 0.
0.298900 –204.25 0.989000 86.11
0.357000 –228.87
0.415800 –240.33
0.475300 –249.67
0.505300 –246.26 –100.
0.535500 –248.97
0.565900 –241.51
0.596400 –235.20
0.627200 –224.27
0.658100 –212.87
0.689200 –194.66 –200.
0.720500 –175.50
0.752000 –152.57
0.783700 –132.93
0.815600 –100.67
0.847700 –74.47
0.879900 –37.36 –300.
0.912400 –3.94 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0372

Components: 1. C2H6, Ethane [74-84-0]
2. C3H8O, Propan-1-ol [71-23-8]
P/106Pa = 5.000 P/106Pa = 5.000
T/K = 348.15 T/K = 348.15 HM/J mol-1
800.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 5; T/K = 323.15
0.029700 –162.00 0.888900 a 290.50 P/106Pa = 10; T/K = 323.15
0.059700 –309.60 0.907200 a 339.80 P/106Pa = 15; T/K = 323.15
0.089900 –453.40 0.907200 a 339.80
0.135600 –698.90 0.925600 a 402.60
0.166400 –885.50 0.962700 a 509.80 0.
0.213000 –1092.60 0.981300 a 552.00
0.244300 –1266.30 0.986000 568.10
0.291800 a –1371.80 0.988800 409.80
0.339800 a –1270.10 0.990600 320.70
0.372100 a –1167.90 0.992000 293.30 –800.
0.404700 a –1022.80
0.454100 a –919.00
0.487300 a –831.60
0.537600 a –688.40
0.571500 a –600.00
0.605600 a –500.70 –1600.
0.657400 a –353.30
0.692200 a –257.00
0.727300 a –151.10
0.762700 a –60.80
0.816400 a 91.30
0.852500 a 211.30 –2400.
0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 10.00 + 0.02 |HM/J mol-1|a Two-phase region; See SELF for the totality of data
Ott, J. B.; Lemon, L. R.; Sipowska, J. T.; Brown, P. R. Excess enthalpies and excess volumes for (ethane + propan-1-ol) at the
temperatures (298.15, 323.15, and 348.15) K and at the pressures (5, 10, 12.5, and 15) MPa J. Chem. Thermodyn. 1995, 27
, 1033-1045

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0095

Components: 1. C2H6, Ethane [74-84-0]
2. C4H10O, Butan-1-ol [71-36-3]
P/106Pa = 5.0 P/106Pa = 15.0
T/K = 298.15 T/K = 298.15 HE/J mol-1
200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 298.15
0.036200 –52.60 0.041300 –11.90
0.054200 –76.40 0.082000 –26.80 P/106Pa = 10.0; T/K = 298.15
0.090000 –124.20 0.122000 –34.90
0.213800 –267.60 0.275600 –63.60
0.283500 –340.70 0.312500 –67.70 0.
0.335200 –395.40 0.348900 –66.10
0.369400 –426.50 0.384600 –67.30
0.403500 –456.40 0.419900 –61.40
0.537700 –527.00 0.454600 –58.00
0.570800 –531.20 0.488700 –48.70 –200.
0.603700 –539.50 0.539100 –33.90
0.652700 –533.40 0.572000 –20.10
0.685100 –528.90 0.698900 36.00
0.733500 –510.30 0.729600 49.90
0.765500 –493.10 0.774700 70.20
0.907300 –310.70 0.818800 88.60 –400.
0.922900 –268.50 0.847800 98.40
0.938400 –222.80 0.890400 114.30
0.953900 –160.70 0.918400 120.60
0.975400 –70.40 0.932200 124.20
0.984700 –20.70 0.946000 126.30 P/106Pa = 5.0; T/K = 298.15
0.990800 4.80 0.973200 123.10 –600.
0.992300 9.30 0.986600 112.40 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 2.0 + 0.02 |HE/J mol-1| See SELF for the totality of data
Sipowska, J. T.; Ott, J. B.; Wooley, A. T.; Izatt, R. M. Excess enthalpies for (ethane + butan-1-ol) at (298.15, 323.15, and
348.15) K and at (5, 10, and 15) MPa J. Chem. Thermodyn. 1991, 23, 1013-1021

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0144

Components: 1. C2H6, Ethane [74-84-0]
2. C4H10O, Butan-1-ol [71-36-3]
P/106Pa = 6.9 P/106Pa = 6.9
T/K = 298.15 T/K = 298.15 HE/J mol-1
110.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.150
0.022100 –13.00 0.927300 –57.38
0.087900 –83.74 0.954700 –6.47
0.152900 –135.42 0.981900 47.47
0.217000 –173.35 0.991000 57.67
0.280300 –217.05 0.
0.342800 –250.93
0.404600 –275.31
0.465500 –293.14
0.495700 –297.48
0.525800 –299.82 –110.
0.555600 –299.38
0.585200 –296.57
0.614700 –291.81
0.644000 –285.32
0.673100 –273.52
0.702000 –261.72 –220.
0.730800 –247.44
0.759300 –233.98
0.787800 –213.03
0.816000 –194.25
0.844100 –161.99
0.872000 –136.60 –330.
0.899700 –100.52 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0201

Components: 1. C2H6, Ethane [74-84-0]
2. C4H10O, Butan-1-ol [71-36-3]
P/106Pa = 5.0 P/106Pa = 5.0
T/K = 323.15 T/K = 323.15 HM/J mol-1
900.
x1 HM/J mol-1 x1 HM/J mol-1 P/106Pa = 15.0; T/K = 348.15
0.036200 –285.60 0.570800 a –1996.70 P/106Pa = 15.0; T/K = 323.15
0.052400 –402.10 0.570800 a –1996.70 P/106Pa = 5.0; T/K = 348.15
0.072100 –527.20 0.603700 a –1841.30 P/106Pa = 5.0; T/K = 323.15
0.110800 –760.30 0.652700 a –1598.20
0.143400 –927.70 0.685100 a –1442.70 0.
0.161100 –1025.40 0.733500 a –1203.10
0.178700 –1152.90 0.765500 a –1043.50
0.213800 –1338.51 0.813200 a –820.70
0.248800 –1545.60 0.844700 a –666.00
0.283500 –1758.00 0.891800 a –433.20 –900.
0.300800 –1836.50 0.938400 a –198.10
0.307700 –1891.90 0.969300 a –46.10
0.318000 –1976.90 0.984700 a 29.10
0.335200 –2050.20 0.988500 a 49.60
0.352300 –2136.70 0.990800 a 61.30
0.369400 –2237.60 0.992300 70.00 –1800.
0.386500 –2354.50
0.403500 –2432.20
0.420400 –2512.60
0.437300 –2577.80
0.454200 a –2510.60
0.487700 a –2384.30 –2700.
0.537700 a –2146.90 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Sipowska, J. T.; Ott, J. B.; Wooley, A. T.; Izatt, R. M. Excess enthalpies for (ethane + butan-1-ol) at (298.15, 323.15, and
348.15) K and at (5, 10, and 15) MPa J. Chem. Thermodyn. 1991, 23, 1013-1021

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0181

Components: 1. C4H10, Butane [106-97-8]
2. C4H10O, Butan-1-ol [71-36-3]
P/106Pa = 5.000 P/106Pa = 5.000
T/K = 298.15 T/K = 298.15 HE/J mol-1
1400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 348.15
0.015300 8.80 0.786100 417.60 P/106Pa = 15.0; T/K = 323.15
0.030700 17.00 0.803700 410.80 P/106Pa = 15.0; T/K = 298.15
0.046100 27.70 0.856600 384.00
0.061600 36.00 0.892100 354.20
0.077100 44.70 0.927900 314.80 1050.
0.092600 56.40 0.963800 252.50
0.139500 88.30 0.966100 242.20
0.171000 109.10 0.981900 192.30
0.218600 141.50
0.250500 161.80 700.
0.298700 199.40
0.331000 219.90
0.379900 257.40
0.412700 281.00
0.445700 303.20
0.495500 337.70 350.
0.529000 358.40
0.579600 387.50
0.613500 404.80
0.647600 416.40
0.699200 428.50
0.733800 427.30 0.
0.768600 424.80 0.50
x1
Uncertainties: σ (x1) = 0.00050; σrel
(HE) = 0.02 See SELF for the totality of data
Sipowska, J. T.; Lemon, L. R.; Ott, J. B.; Brown, P. R.; Marchant, B. G. Excess enthalpies and excess volumes for (butane +
butan-1-ol) at the temperatures (298.15, 323.15, and 348.15) K and pressures (5, 10, and 15) MPa J. Chem. Thermodyn. 1994, 26
, 1275-1286

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0140

Components: 1. C2H6, Ethane [74-84-0]
2. C5H12O, Pentan-1-ol [71-41-0]
P/106Pa = 6.9 P/106Pa = 6.9
T/K = 298.15 T/K = 298.15 HE/J mol-1
120.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.150
0.026000 –21.29 0.864800 –209.99
0.064500 –57.38 0.889500 –177.69
0.102300 –89.12 0.913800 –136.85
0.139300 –127.96 0.937800 –87.39
0.175800 –149.90 0.961400 –26.43 0.
0.246700 –201.99 0.976900 16.82
0.281200 –229.25 0.984700 33.75
0.315200 –256.31 0.992300 48.84
0.348600 –271.52
0.381400 –289.18 –120.
0.445300 –310.58
0.507200 –332.68
0.537400 –340.97
0.567100 –346.20
0.596300 –345.91
0.625100 –344.31 –240.
0.653400 –341.88
0.681300 –332.29
0.708700 –327.69
0.735700 –312.92
0.762300 –301.73
0.788500 –283.53 –360.
0.839700 –240.15 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0143

Components: 1. C2H6, Ethane [74-84-0]
2. C6H14O, Hexan-1-ol [111-27-3]
P/106Pa = 6.9 P/106Pa = 6.9
T/K = 298.15 T/K = 298.15 HE/J mol-1
130.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.150
0.029900 –25.78 0.979900 –7.14
0.059200 –50.97 0.986700 16.48
0.116100 –103.20 0.993400 34.22
0.170800 –145.10
0.223400 –186.37 0.
0.274100 –222.64
0.346700 –270.73
0.415400 –309.21
0.480700 –340.01
0.542700 –361.11 –130.
0.601600 –376.45
0.657800 –378.19
0.711300 –373.86
0.762400 –360.34
0.811300 –327.98
0.858000 –285.90 –260.
0.880600 –250.52
0.902700 –211.40
0.917200 –187.67
0.931500 –151.56
0.945600 –118.32
0.959400 –75.68 –390.
0.973100 –30.96 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0141

Components: 1. C2H6, Ethane [74-84-0]
2. C8H18O, Octan-1-ol [111-87-5]
P/106Pa = 6.9 P/106Pa = 6.9
T/K = 298.15 T/K = 298.15 HE/J mol-1
150.
x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.150
0.018900 –12.62 0.989400 –16.12
0.037500 –20.54 0.994700 20.39
0.091300 –61.42
0.142400 –96.59
0.190900 –132.72 0.
0.237100 –165.62
0.323100 –228.04
0.401500 –284.34
0.473300 –331.29
0.539200 –367.17 –150.
0.600000 –397.67
0.656900 –424.28
0.708400 –435.04
0.757000 –435.86
0.802300 –420.48
0.844600 –383.93 –300.
0.864700 –356.95
0.884200 –330.28
0.903100 –291.67
0.921400 –245.90
0.939200 –200.89
0.956400 –145.43 –450.
0.973200 –73.30 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0142

Components: 1. C2H6, Ethane [74-84-0]
2. C10H22O, Decan-1-ol [112-30-1]
P/106Pa = 6.9
T/K = 298.15 HE/J mol-1
170.
x1 HE/J mol-1
P/106Pa = 6.9; T/K = 298.150
0.022800 –8.28
0.045000 –20.28
0.128500 –64.00
0.204200 –107.13
0.273200 –145.12 0.
0.366000 –207.98
0.447900 –271.24
0.520800 –326.15
0.586000 –375.82
0.644700 –415.79 –170.
0.697800 –450.13
0.746100 –474.07
0.790300 –475.37
0.830700 –447.50
0.868000 –371.24
0.902300 –296.24 –340.
0.918500 –252.07
0.934200 –214.79
0.963700 –144.97
0.977700 –93.43
0.991200 –30.18
0.995600 1.17 –510.
0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 0.50 + 0.020 |HE/J mol-1|
McFall, T. A.; Post, M. E.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15
K J. Chem. Thermodyn. 1981, 13, 441-446

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0242

Components: 1. CH4O, Methanol [67-56-1]
2. C6H12, Cyclohexane [110-82-7]
T/K = 462.7 T/K = 512.8
x1 = 0.500 x1 = 0.500 HE/J mol-1
1800.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 452.80; x1 = 0.500
0.560 318.000 0.550 209.000
0.690 407.000 0.690 261.000 T/K = 472.90; x1 = 0.500
0.830 521.000 0.830 316.000 T/K = 492.60; x1 = 0.500
0.900 566.000 0.970 378.000
0.960 662.800 1.100 450.000 1400. T/K = 522.80; x1 = 0.500
1.010 683.000 1.240 519.000
1.020 691.000 1.380 596.000
1.520 680.000
1.650 784.000
1.790 896.000 1000.
1.930 1021.000
2.000 1068.000
2.020 1104.000
2.200 1375.000
2.300 1549.000
600.

200.
0.2 0.8 1.4 2.0 2.6
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.020 See SELF for the totality of data
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - cyclohexane and methanol - benzene from 454.2 to 523.0
K and up to 4 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 3375-3380

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0104

Components: 1. CH4O, Methanol [67-56-1]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
160.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.20 146.00
368.20 133.00
373.20 118.00
378.20 107.00
383.20 102.00 125.0
393.20 88.00
403.20 77.00
413.20 70.00
423.20 63.00
433.20 57.00 90.0
473.20 44.00
483.20 41.00
493.20 38.00
503.20 36.00
513.20 34.00
523.20 32.00 55.0

20.0
400. 450. 500.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Sowden, C. D. Benzene-methanol association. The excess molar enthalpy and second virial cross coefficients of
(benzene + methanol)(g) and (cyclohexane + methanol)(g) Int. J. Thermophys. 1997, 18, 1465-1481

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0244

Components: 1. CH4O, Methanol [67-56-1]
2. C6H12, Cyclohexane [110-82-7]
T/K = 472.9 T/K = 522.8
x1 = 0.500 x1 = 0.500 HM/J mol-1
13000.
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
T/K = 462.7; x1 = 0.500
1.39 11477.00 2.71 9073.00 T/K = 483.0; x1 = 0.500
1.51 11536.00 2.72 9266.00 T/K = 503.0; x1 = 0.500
1.60 11400.00 2.78 9536.00
1.90 11175.00 2.91 9664.00
T/K = 522.8; x1 = 0.500
2.00 11144.00 3.00 9842.00 12000.
2.21 11029.00 3.20 9691.00
2.32 11039.00 3.30 9709.00
2.40 11106.00 3.50 9777.00
2.50 11086.00
2.90 10795.00 11000.
3.10 10629.00

10000.

9000.
1.2 1.9 2.5 3.2 3.8
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HM) = 0.050 See SELF for the totality of data
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - cyclohexane and methanol - benzene from 454.2 to 523.0
K and up to 4 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 3375-3380

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0083

Components: 1. C2H6O, Ethanol [64-17-5]
2. C6H12, Cyclohexane [110-82-7]
T/K = 483.15 T/K = 522.89
x1 = 0.500 x1 = 0.500 HE/J mol-1
1600.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 462.85; x1 = 0.500
0.410 160.000 0.400 107.000
0.690 293.000 0.680 194.000 T/K = 483.15; x1 = 0.500
0.960 428.000 0.970 291.000 T/K = 512.72; x1 = 0.500
1.250 618.000 1.240 407.000
1.430 755.000 1.520 530.000 1200. T/K = 522.89; x1 = 0.500
1.780 638.000
2.050 815.000
2.320 1067.000
2.640 1309.000
800.

400.

0.
0.4 1.0 1.6 2.2 2.8
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Massucci, M.; Wormald, C. J.; Lu, Y. Excess molar enthalpies of ethanol - hexane, ethanol - cyclohexane and ethanol - benzene
from 453.5 to 522.9 K and up to 4.5 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 4193-4197

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0017

Components: 1. C2H6O, Ethanol [64-17-5]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
200.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.20 182.00
368.20 158.00
373.20 133.00
378.20 118.00
383.20 104.00 160.0
393.20 89.00
403.20 76.00
413.20 65.00
423.20 59.00
433.20 54.00 120.0

80.0

40.0
350. 375. 400. 425. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Sowden, C. J. Benzene-ethanol association. The excess molar enthalpy and second virial cross-coefficients for
(benzene + ethanol)(g) and (cyclohexane + ethanol)(g) J. Chem. Thermodyn. 1997, 29, 1223-1236

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0241

Components: 1. CH4O, Methanol [67-56-1]
2. C6H6, Benzene [71-43-2]
T/K = 473.6 T/K = 512.6
x1 = 0.500 x1 = 0.500 HE/J mol-1
620.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 454.2; x1 = 0.500
0.410 141.000 0.410 121.000
0.570 196.000 0.550 155.000 T/K = 473.6; x1 = 0.500
0.690 243.000 0.690 208.000 T/K = 492.9; x1 = 0.500
0.830 302.000 0.830 260.000
0.970 366.000 0.970 309.000 490. T/K = 523.0; x1 = 0.500
1.100 442.000 1.100 386.000
1.240 526.000
1.390 575.000

360.

230.

100.
0.2 0.5 0.8 1.1 1.4
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.020 See SELF for the totality of data
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - cyclohexane and methanol - benzene from 454.2 to 523.0
K and up to 4 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 3375-3380

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0103

Components: 1. CH4O, Methanol [67-56-1]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
130.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.20 119.00
368.20 104.00
373.20 92.00
378.20 82.00
383.20 76.00 100.
393.20 66.00
403.20 57.00
413.20 51.00
423.20 46.00
433.20 40.00 70.
473.20 31.00
483.20 29.00
493.20 26.00
503.20 25.00
513.20 24.00
523.20 23.00 40.

10.
400. 450. 500.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Sowden, C. D. Benzene-methanol association. The excess molar enthalpy and second virial cross coefficients of
(benzene + methanol)(g) and (cyclohexane + methanol)(g) Int. J. Thermophys. 1997, 18, 1465-1481

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0243

Components: 1. CH4O, Methanol [67-56-1]
2. C6H6, Benzene [71-43-2]
T/K = 463.0 T/K = 503.4
x1 = 0.500 x1 = 0.500 HM/J mol-1
13000.
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
T/K = 454.20; x1 = 0.500
1.22 10204.00 2.30 10552.00 T/K = 473.60; x1 = 0.500
1.24 12131.00 2.60 10392.00 T/K = 492.90; x1 = 0.500
1.38 12101.00 2.90 10382.00
1.52 12135.00 3.20 10392.00
T/K = 523.00; x1 = 0.500
1.72 12074.00 12000.
2.00 11741.00
2.29 11480.00
2.51 11432.00
2.61 11381.00
11000.

10000.

9000.
1.0 1.7 2.3 3.0 3.7
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HM) = 0.050 See SELF for the totality of data
Massucci, M.; Wormald, C. J. Excess molar enthalpies of methanol - cyclohexane and methanol - benzene from 454.2 to 523.0
K and up to 4 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 3375-3380

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0082

Components: 1. C2H6O, Ethanol [64-17-5]
2. C6H6, Benzene [71-43-2]
T/K = 483.15 T/K = 522.89
x1 = 0.500 x1 = 0.500 HE/J mol-1
1200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 462.85; x1 = 0.500
0.410 89.000 0.410 66.000
0.680 166.000 0.700 121.000 T/K = 483.15; x1 = 0.500
0.980 270.000 0.960 173.000 T/K = 512.75; x1 = 0.500
1.230 362.000 1.240 239.000
1.430 473.000 1.510 306.000 900. T/K = 522.89; x1 = 0.500
1.560 532.000 1.800 377.000
2.010 463.000
2.280 581.000
2.600 794.000
2.760 911.000 600.

300.

0.0
0.4 1.0 1.6 2.2 2.8
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Massucci, M.; Wormald, C. J.; Lu, Y. Excess molar enthalpies of ethanol - hexane, ethanol - cyclohexane and ethanol - benzene
from 453.5 to 522.9 K and up to 4.5 MPa J. Chem. Soc., Faraday Trans. 1993, 89, 4193-4197

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0016

Components: 1. C2H6O, Ethanol [64-17-5]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
180.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.20 155.00
368.20 118.00
373.20 101.00
378.20 95.00
383.20 76.00 140.0
393.20 61.00
403.20 49.00
413.20 44.00
423.20 37.00
433.20 34.00 100.0

60.0

20.0
350. 375. 400. 425. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Sowden, C. J. Benzene-ethanol association. The excess molar enthalpy and second virial cross-coefficients for
(benzene + ethanol)(g) and (cyclohexane + ethanol)(g) J. Chem. Thermodyn. 1997, 29, 1223-1236

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1141] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0289

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H14, Hexane [110-54-3]
T/K = 493.2
x1 = 0.500 HE/J mol-1
8000.0
P/106Pa HE/J mol-1
T/K = 493.2; x1 = 0.500
3.81 7204.00
3.83 5855.00
3.86 5171.00
3.95 3932.00
4.13 3183.00 6000.0
4.48 2742.00
4.86 2555.00
5.31 2442.00
5.91 2137.00
4000.0

2000.0

0.0
3.0 4.0 5.0 6.0 7.0
P/106Pa
Uncertainties: σrel(P) = 0.0025; σrel(HE) = 0.020
Wormald, C. J.; Al-Bizreh, N.; Yerlett, T. K. Excess enthalpies of {x(CH3)2CO + (1-x)C6H14} in the supercritical region J.
Chem. Soc., Faraday Trans. 1 1988, 84, 3587-3596

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0090

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H14, Hexane [110-54-3]
T/K = 523.20 T/K = 548.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
6000.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 523.20; x1 = 0.500
2.49 630.00 2.71 822.00
2.91 899.00 3.30 1201.00 T/K = 548.20; x1 = 0.500
3.32 1340.00 4.29 1755.00
3.80 2522.00 4.57 2013.00
4.07 3667.00 5.00 2540.00 4500.
4.11 3864.00 5.74 2708.00
4.25 3973.00 6.00 2702.00
4.53 3789.00 6.38 2614.00
4.90 3488.00 7.25 2486.00
5.22 3195.00 7.91 2350.00 3000.
5.49 3010.00
5.90 3176.00
6.26 3334.00
6.52 3387.00
6.95 3120.00
7.31 2853.00 1500.
7.94 2520.00

0.0
0.0 2.0 4.0 6.0 8.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.020 See SELF for the totality of data
Wormald, C. J.; Al-Bizreh, N.; Yerlett, T. K. Excess enthalpies of {x(CH3)2CO + (1-x)C6H14} in the supercritical region J.
Chem. Soc., Faraday Trans. 1 1988, 84, 3587-3596

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0285

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H14, Hexane [110-54-3]
T/K = 510.200 T/K = 510.200
x1 = 0.2500 x1 = 0.7500 HE/J mol-1
6000.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 510.2; x1 = 0.500
2.000 632.000 2.270 641.000
2.500 1065.000 2.890 1329.000
2.800 1594.000 3.050 1832.000
2.890 1840.000 3.240 3043.000
2.960 2316.000 3.380 3129.000 4500.
3.050 3120.000 3.570 3149.000
3.100 4495.000 3.710 3113.000
3.170 6533.000 4.080 3001.000
3.250 6842.000 4.250 2919.000
3.310 6831.000 4.420 2880.000 3000.
3.380 6661.000 4.520 2872.000
3.580 6149.000 4.580 2880.000
3.810 4998.000 4.670 2977.000
3.940 4025.000 4.760 3534.000
4.070 2522.000 4.840 4891.000
4.240 1293.000 4.890 5285.000 1500.
4.410 460.000 4.960 5276.000
4.720 162.000 5.050 4677.000
4.830 880.000 5.210 3668.000
4.940 1480.000 5.360 3252.000
5.140 1478.000 5.500 2952.000
5.340 1153.000 5.710 2654.000 0.0
5.580 1037.000 6.010 2196.000 1. 3. 5. 7. 9.
5.860 896.000 6.360 1709.000
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.020 See SELF for the totality of data
Al-Bizreh, N.; Wormald, C. J.; Yerlett, T. K. Enthalpies of {x(CH3)2CO + (1-x)C6H14} for x = 0.25, 0.50, and 0.75 at 510.2
K up to 9.11 MPa J. Chem. Thermodyn. 1988, 20, 797-804

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0288

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H14, Hexane [110-54-3]
T/K = 493.20
x1 = 0.500 HM/J mol-1
8000.0
P/106Pa HM/J mol-1
T/K = 493.20; x1 = 0.500
2.38 6364.00
2.48 7130.00
2.54 7008.00
2.62 7062.00
2.79 6887.00 7000.0
2.91 6740.00
3.11 6431.00
3.21 6323.00
3.38 5953.00
3.47 5580.00 6000.0
3.69 5243.00
3.72 5142.00
3.73 4916.00

5000.0

4000.0
2.0 2.5 3.0 3.5 4.0
P/106Pa
Uncertainties: σrel(P) = 0.0025; σrel(HM) = 0.020
Wormald, C. J.; Al-Bizreh, N.; Yerlett, T. K. Excess enthalpies of {x(CH3)2CO + (1-x)C6H14} in the supercritical region J.
Chem. Soc., Faraday Trans. 1 1988, 84, 3587-3596

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0122

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
120.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 113.10
363.20 98.40
373.20 86.50
383.20 77.10
393.20 68.00 105.
403.20 61.60

90.

75.

60.
365. 380. 395.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Mayr, J. C. Benzene-dimethyl ketone association. Excess molar enthalpy of (cyclohexane + dimethyl
ketone)(g) and (benzene + dimethyl ketone)(g) from temperatures of 353.2 to 403.2 K J. Chem. Soc., Faraday Trans. 1998, 94
, 207-212

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0072

Components: 1. C5H10O, Pentan-3-one [96-22-0]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
100.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 94.40
378.20 87.50
383.20 79.70
388.20 73.50
393.20 69.10 85.0
403.20 60.30
413.20 51.70
423.20 44.60

70.0

55.0

40.0
350. 375. 400. 425. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Mathonat, C. Benzene-diethyl ketone association. The excess molar enthalpy of (cyclohexane + diethyl
ketone)(g) and (benzene + diethyl ketone)(g) from temperatures 373.2 K to 423.2 K J. Chem. Thermodyn. 1998, 30, 959-969

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0099

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H6, Benzene [71-43-2]
P/106Pa = 5.68
T/K = 494.50 HE/J mol-1
360.
x1 HE/J mol-1
P/106Pa = 5.68; T/K = 494.5
0.103000 56.00
0.347000 194.00
0.473000 205.00
0.565000 218.00
0.684000 116.00 270.
0.814000 56.00

180.

90.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HE)/J mol-1
= 10
Lloyd, M. J.; Wormald, C. J. Excess molar enthalpies of {x(CH3)2CO + (1-x)C6H6} at temperatures from 494.5 to 577.4 K
and at the pressure 5.68 MPa J. Chem. Thermodyn. 1992, 24, 67-73

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0195

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H6, Benzene [71-43-2]
P/106Pa = 5.68
T/K = 577.40 HE/J mol-1
2400.
x1 HE/J mol-1
P/106Pa = 5.68; T/K = 577.4
0.225000 1695.00
0.240000 1613.00
0.291000 1862.00
0.407000 1876.00
0.481000 1744.00 1800.
0.490000 1697.00
0.491000 1642.00
0.507000 1680.00
0.580000 1526.00
0.693000 1212.00 1200.
0.733000 1046.00
0.757000 973.00

600.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HE)/J mol-1
= 100
Lloyd, M. J.; Wormald, C. J. Excess molar enthalpies of {x(CH3)2CO + (1-x)C6H6} at temperatures from 494.5 to 577.4 K
and at the pressure 5.68 MPa J. Chem. Thermodyn. 1992, 24, 67-73

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0121

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
64.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
353.20 58.90
363.20 51.80
373.20 45.20
383.20 42.00
393.20 37.30 56.
403.20 34.50

48.

40.

32.
365. 380. 395.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Mayr, J. C. Benzene-dimethyl ketone association. Excess molar enthalpy of (cyclohexane + dimethyl
ketone)(g) and (benzene + dimethyl ketone)(g) from temperatures of 353.2 to 403.2 K J. Chem. Soc., Faraday Trans. 1998, 94
, 207-212

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0196

Components: 1. C3H6O, Propan-2-one [67-64-1]
2. C6H6, Benzene [71-43-2]
P/106Pa = 5.68 P/106Pa = 5.68
T/K = 519.0 T/K = 559.2 HM/J mol-1
6000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 5.680; T/K = 559.2
0.149000 –169.00 0.146000 1614.00
0.232000 –235.00 0.179000 3698.00
0.344000 –373.00 0.259000 5217.00
0.492000 –634.00 0.351000 5181.00
0.570000 –724.00 0.352000 5296.00 4000.
0.700000 –1003.00 0.412000 5091.00
0.793000 –792.00 0.484000 4795.00
0.487000 4751.00
0.494000 4745.00
0.509000 4455.00 2000.
0.742000 2737.00

0.

P/106Pa = 5.680; T/K = 519.0

–2000. P/106Pa = 5.680; T/K = 535.7
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HM)/J mol-1
= 200 See SELF for the totality of data
Lloyd, M. J.; Wormald, C. J. Excess molar enthalpies of {x(CH3)2CO + (1-x)C6H6} at temperatures from 494.5 to 577.4 K
and at the pressure 5.68 MPa J. Chem. Thermodyn. 1992, 24, 67-73

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0071

Components: 1. C5H10O, Pentan-3-one [96-22-0]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
60.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 55.40
378.20 53.10
383.20 48.30
388.20 44.30
393.20 41.70 50.0
403.20 36.10
413.20 31.70
423.20 28.50

40.0

30.0

20.0
350. 375. 400. 425. 450.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Mathonat, C. Benzene-diethyl ketone association. The excess molar enthalpy of (cyclohexane + diethyl
ketone)(g) and (benzene + diethyl ketone)(g) from temperatures 373.2 K to 423.2 K J. Chem. Thermodyn. 1998, 30, 959-969

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0447

Components: 1. CHCl3, Trichloromethane [67-66-3]
2. C2H6O, Dimethyl ether [115-10-6]
P/103Pa T/K x1 HE/J mol-1
78.700 333.20 0.6510 –80.2
78.700 333.20 0.5510 –84.9
78.700 333.20 0.5310 –86.5
77.500 343.20 0.5980 –60.3
77.500 343.20 0.4930 –61.8
77.500 343.20 0.4360 –61.3
78.900 353.20 0.6050 –51.2
78.900 353.20 0.5040 –52.0
78.900 353.20 0.4950 –49.2
77.200 363.20 0.5510 –40.8
77.200 363.20 0.4980 –39.6
77.200 363.20 0.4760 –41.1
77.900 373.20 0.5520 –30.4
77.900 373.20 0.5170 –32.3
77.900 373.20 0.4400 –30.9
77.100 393.20 0.6090 –21.5
77.100 393.20 0.5610 –22.5
77.100 393.20 0.5420 –23.2

Uncertainties: σ (P)/103Pa = 0.1; σ (T)/K = 0.1; σ (x1) = 0.001; σrel(HE) = 0.020

Lancaster, N. M.; Wormald, C. J. The enthalpy of mixing of (dimethyl ether + trichloromethane) vapour Z. Phys. Chem.
(Frankfurt/Main) 1981, 128, 51-56

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0187

Components: 1. CHCl3, Trichloromethane [67-66-3]
2. C4H10O, Diethyl ether [60-29-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
0.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
323.30 –227.90
333.20 –177.00
338.30 –158.00
353.20 –110.90
363.20 –85.10 –60.0
378.20 –62.50
393.30 –51.50

–120.0

–180.0

–240.0
340. 360. 380.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.5 – 2.5
Doyle, J. A.; Mayr, J. C.; Wormald, C. J. The enthalpy of mixing of (diethyl ether + trichloromethane) vapour Z. Phys. Chem.
(Frankfurt/Main) 1981, 124, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0021

Components: 1. CHCl3, Trichloromethane [67-66-3]
2. C4H10O, Diethyl ether [60-29-7]
P/103Pa T/K x1 HE/J mol-1 P/103Pa T/K x1 HE/J mol-1
61.000 323.20 0.6090 –129.5 85.200 353.20 0.5360 –95.3
61.100 323.20 0.5870 –130.7 85.600 353.20 0.5230 –92.1
61.500 323.20 0.5580 –132.9 85.400 353.20 0.4790 –91.5
61.300 323.20 0.4830 –133.2 85.300 353.20 0.4420 –90.3
61.900 323.20 0.4260 –132.9 85.900 353.20 0.4030 –90.0
62.000 323.20 0.4080 –131.8 86.000 353.20 0.3780 –88.2
61.000 323.20 0.3880 –127.8 86.600 363.20 0.5990 –67.4
62.900 323.20 0.3270 –122.2 88.500 363.20 0.5350 –74.0
80.100 333.20 0.5950 –133.4 88.900 363.20 0.5000 –75.2
79.600 333.20 0.5870 –135.2 86.600 363.20 0.4960 –69.9
79.400 333.20 0.5370 –133.9 87.800 363.20 0.4220 –75.6
79.300 333.20 0.5120 –138.4 88.900 363.20 0.4130 –70.4
79.200 333.20 0.4920 –139.6 85.700 363.20 0.3680 –67.4
79.300 333.20 0.4770 –136.8 88.200 363.20 0.3540 –68.2
79.400 333.20 0.4490 –136.2 82.800 378.20 0.5220 –53.7
80.100 333.20 0.3540 –125.3 82.800 378.20 0.5080 –53.6
85.800 338.30 0.6610 –118.9 82.700 378.20 0.4990 –52.9
85.800 338.30 0.6580 –118.5 82.700 378.20 0.4600 –53.3
85.800 338.30 0.6530 –119.6 81.900 378.20 0.4220 –48.6
85.300 338.30 0.6050 –127.1 82.500 378.20 0.4170 –52.9
85.600 338.30 0.5960 –126.2 82.700 378.20 0.4000 –50.2
87.400 338.30 0.5240 –135.7 82.600 378.20 0.3670 –49.2
87.200 338.30 0.5070 –137.4 83.300 393.20 0.5540 –42.3
86.400 338.30 0.4370 –132.5 83.400 393.20 0.5370 –43.0
85.400 353.20 0.6080 –88.8 83.300 393.20 0.5310 –39.6
85.400 353.20 0.5950 –90.0 83.500 393.20 0.5300 –41.4

Uncertainties: σ (P)/103Pa = 0.1; σ (T)/K = 0.1; σ (x1) = 0.0010; σrel(HE) = 0.020 See SELF for the totality of data
Doyle, J. A.; Mayr, J. C.; Wormald, C. J. The enthalpy of mixing of (diethyl ether + trichloromethane) vapour Z. Phys. Chem.
(Frankfurt/Main) 1981, 124, 1-12

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0190

Components: 1. CHCl3, Trichloromethane [67-66-3]
2. C3H6O, Propan-2-one [67-64-1]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
0.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
323.30 –276.80
327.80 –217.00
333.20 –193.80
336.50 –172.30
338.20 –162.70 –70.0
343.20 –147.20
353.20 –113.30
363.20 –91.30
373.20 –71.20
378.20 –62.40 –140.0
393.20 –45.70

–210.0

–280.0
340. 360. 380.
T/K
Uncertainties: σrel(HE)
= 0.02
Doyle, J. A.; Hutchings, D. J.; Mayr, J. C.; Wormald, C. J. The enthalpy of mixing of (acetone + trichloromethane) vapour J.
Chem. Thermodyn. 1981, 13, 261-272

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0020

Components: 1. CHCl3, Trichloromethane [67-66-3]
2. C3H6O, Propan-2-one [67-64-1]
P/103Pa T/K x1 HE/J mol-1 P/Pa T/K x1 HE/J mol-1
46.100 323.30 0.6080 –123.8 66.500 343.20 0.4740 –95.3
44.900 323.30 0.6050 –118.4 67.000 343.20 0.4640 –94.6
43.100 323.30 0.5300 –122.2 66.600 343.20 0.4050 –90.8
44.100 323.30 0.4980 –117.0 88.900 343.20 0.5680 –125.5
43.500 323.30 0.3810 –108.6 88.900 343.20 0.5660 –125.8
45.200 323.30 0.3750 –113.6 88.000 343.20 0.5450 –125.6
34.000 343.20 0.5460 –48.6 88.000 343.20 0.5320 –126.5
36.100 343.20 0.5340 –49.5 88.000 343.20 0.5240 –126.9
34.200 343.20 0.5170 –46.1 104.500 343.20 0.5520 –149.8
33.900 343.20 0.5000 –47.4 104.500 343.20 0.5070 –152.4
34.300 343.20 0.4690 –46.5 105.100 343.20 0.5040 –153.8
34.000 343.20 0.4350 –46.4 105.000 343.20 0.4690 –153.1
33.800 343.20 0.4070 –46.6 103.900 343.20 0.4560 –150.7
44.300 343.20 0.6040 –61.8 104.000 343.20 0.4250 –148.2
45.400 343.20 0.5730 –64.4 101.300 363.20 0.6790 –76.8
45.900 343.20 0.5540 –64.1 101.300 363.20 0.6060 –85.7
46.100 343.20 0.5270 –64.5 101.300 363.20 0.5610 –92.5
46.800 343.20 0.5020 –67.1 101.300 363.20 0.5110 –93.8
47.300 343.20 0.4860 –66.1 101.300 363.20 0.4970 –91.3
46.000 343.20 0.4750 –65.5 101.300 363.20 0.4460 –91.2
45.500 343.20 0.4410 –63.7 101.300 363.20 0.4400 –89.5
68.100 343.20 0.5990 –93.8 101.300 363.20 0.3380 –82.0
69.000 343.20 0.5680 –95.9 101.300 363.20 0.2680 –70.8
67.200 343.20 0.5230 –95.1 80.200 393.20 0.5290 –36.0
66.500 343.20 0.5060 –93.6 80.200 393.20 0.5180 –37.1
66.300 343.20 0.4970 –93.5 80.000 393.20 0.4780 –36.4

Uncertainties: σ (P)/103Pa = 1.0; σ (T)/K = 0.1; σ (x1) = 0.001; σrel(HE) = 0.02 See SELF for the totality of data
Doyle, J. A.; Hutchings, D. J.; Mayr, J. C.; Wormald, C. J. The enthalpy of mixing of (acetone + trichloromethane) vapour J.
Chem. Thermodyn. 1981, 13, 261-272

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0426

Components: 1. C2H3N, Ethanenitrile [75-05-8]
2. C2H6, Ethane [74-84-0]
P/106Pa = 7.500 P/106Pa = 15.000
T/K = 298.150 T/K = 298.150 HE/J mol-1
1000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 298.15
0.024700 254.00 0.013700 177.00
0.048900 a 274.00 0.027300 288.00 P/106Pa = 15.0; T/K = 298.15
0.072800 a 275.00 0.034100 329.00
0.142200 a 328.00 0.045400 a 368.00
0.208400 a 339.00 0.067600 a 383.00 750.
0.271700 a 390.00 0.089600 a 386.00
0.332200 a 401.00 0.132800 a 415.00
0.390100 a 445.00 0.195600 a 458.00
0.445500 a 458.00 0.216000 a 465.00
0.498700 a 505.00 0.256200 a 481.00 500.
0.549700 a 499.00 0.314700 a 525.00
0.598800 a 553.00 0.407900 a 582.00
0.645900 a 563.00 0.496000 a 636.00
0.691200 a 585.00 0.579400 a 686.00
0.734800 a 611.00 0.647500 a 739.00
0.776900 a 629.00 0.719000 a 782.00 250.
0.817400 553.00 0.747900 a 799.00
0.856500 434.00 0.775000 760.00
0.894200 338.00 0.805200 676.00
0.930700 224.00 0.821200 623.00
0.965900 111.00 0.846400 549.00
0.977400 70.00 0.886500 411.00 0.
0.988800 36.00 0.906100 346.00 0.50
0.963200 133.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE) = 0.01–0.02 a Two-phase region; See SELF for the totality of data
Ott, J. B.; Neely, B. J.; Purdy, J. E.; Owen, R. L. Excess enthalpies for ethane + acetonitrile at 298.15, 323.15, and 348.15 K
and at 7.5 and 15 MPa Thermochim. Acta 1989, 154, 71-79

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0427

Components: 1. C2H6, Ethane [74-84-0]
2. C2H3N, Ethanenitrile [75-05-8]
P/106Pa = 7.500 P/106Pa = 15.000
T/K = 323.150 T/K = 323.150 HM/J mol-1
1200.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 323.15
0.011200 17.00 0.012200 38.00 P/106Pa = 7.5; T/K = 348.15
0.034100 64.00 0.036800 124.00 P/106Pa = 15.0; T/K = 323.15
0.069300 125.00 0.049300 177.00
0.105800 179.00 0.074600 267.00
0.143500 229.00 0.113500 407.00 800.
0.182600 268.00 0.153600 523.00
0.223100 310.00 0.194800 631.00
0.237000 316.00 0.237300 739.00
0.265200 a 321.00 0.281000 822.00
0.279500 a 316.00 0.372600 867.00 400.
0.308800 a 305.00 0.420600 a 833.00
0.354100 a 290.00 0.470100 a 818.00
0.401200 a 262.00 0.521200 a 769.00
0.450300 a 241.00 0.574100 a 749.00
0.501300 a 217.00 0.628700 a 712.00
0.554500 a 184.00 0.685300 a 683.00 0.
0.609900 a 156.00 0.743800 a 657.00
0.667800 a 129.00 0.804400 a 619.00
0.728300 a 103.00 0.867200 a 590.00
0.791600 a 69.00 0.910400 a 553.00
0.857800 a 37.00 0.923600 514.00
0.927200 a 5.00 0.932400 467.00 –400.
0.951100 a –6.00 0.954600 268.00 0.50
0.975300 –17.00 0.977200 128.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.01–0.02 a Two-phase region; See SELF for the totality of data
Ott, J. B.; Neely, B. J.; Purdy, J. E.; Owen, R. L. Excess enthalpies for ethane + acetonitrile at 298.15, 323.15, and 348.15 K
and at 7.5 and 15 MPa Thermochim. Acta 1989, 154, 71-79

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0263

Components: 1. CHClF2, Chlorodifluoromethane [75-45-6]
2. C4H9NO, N,N-Dimethylethanamide [127-19-5]
P/106Pa = 5.5 P/106Pa = 5.5
T/K = 373.15 T/K = 403.15 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1
0.025800 –262.00 0.025800 –284.00
0.101500 –1053.00 0.076600 –1127.00
0.174600 –1802.00 0.126200 –1907.00
0.245200 –2459.00 0.174600 –2617.00
0.313500 –3100.00 0.221900 –3354.00 –2500.
0.379500 –3656.00 0.268200 –4027.00
0.443400 –4135.00 0.313500 –4640.00
0.505200 –4483.00 0.357700 –5268.00
0.565100 –4701.00 0.401000 –5767.00
0.623200 –4836.00 0.443400 –6300.00 –5000.
0.679500 –4806.00 0.484800 –6690.00
0.734100 –4649.00 0.525400 –7128.00
0.787200 –4370.00 0.565100 –7509.00
0.838700 –3898.00 0.642200 –7967.00
0.888700 –3269.00 0.679500 –8163.00
0.937300 –2330.00 0.716100 –8282.00 –7500.
0.984500 –785.00 0.752000 –8298.00
0.787200 –8183.00
0.821700 –7900.00 P/106Pa = 5.5; T/K = 373.15
0.855500 a –6461.00 P/106Pa = 5.5; T/K = 393.15
0.888700 a –5093.00 P/106Pa = 5.5; T/K = 413.15
0.921200 a –3335.00 –10000.
0.953200 a –1684.00 0.50
0.984500 –248.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 10 + 0.008 |HE/J mol-1|a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Christensen, S. P.; Schofield, R. S.; Faux, P. W.; Harding, P. R.; Izatt, R. M. The excess enthalpies of
liquid Freon-22 + N,N-dimethylacetamide mixtures from 373 to 423 K at 5.5 MPa Thermochim. Acta 1983, 67, 315-325

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0049

Components: 1. CH4, Methane [74-82-8]
2. CO2, Carbon dioxide [124-38-9]
P/103Pa = 1013.0 P/103Pa = 1114.0
T/K = 313.15 T/K = 293.15 HE/J mol-1
60.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 1114.0; T/K = 293.15
0.248000 30.94 0.169000 29.30
0.487000 35.87 0.317000 46.98 P/103Pa = 1013.0; T/K = 313.15
0.490000 33.94 0.393000 48.21
0.491000 34.58 0.445000 47.72
0.500000 34.71 0.707000 42.78 45.
0.503000 34.83 0.883000 21.95
0.504000 34.38
0.508000 34.80
0.520000 33.54
0.679000 31.56 30.
0.784000 19.83

15.

0.
0.50
x1
Uncertainties: σ (x1) = 0.005; σrel
(HE)
= 0.06 See SELF for the totality of data
Barry, A. O.; Kaliaguine, S. C.; Ramalho, R. S. Direct determination of enthalpy of mixing for the binary gaseous system
methane-carbon dioxide by an isothermal flow calorimeter J. Chem. Eng. Data 1982, 27, 258-264

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1222] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable x1 and constant P and T, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0437

Components: 1. CH4, Methane [74-82-8]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 4.053 P/106Pa = 10.1325
T/K = 313.150 T/K = 313.150 HE/J mol-1
4000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.0530; T/K = 313.15
0.100000 80.00 0.100000 2460.00 P/106Pa = 6.0795; T/K = 313.15
0.200000 128.00 0.200000 3000.00 P/106Pa = 8.1060; T/K = 313.15
0.300000 161.00 0.300000 3045.00
0.400000 180.00 0.400000 2890.00
P/106Pa = 10.1325; T/K = 313.15
0.500000 180.00 0.500000 2550.00 3000.
0.600000 165.00 0.600000 2130.00
0.700000 141.00 0.700000 1680.00
0.800000 103.00 0.800000 1150.00
0.900000 55.00 0.900000 611.00
2000.

1000.

0.
0.50
x1
Uncertainties: σrel(HE)
= 0.04 See SELF for the totality of data
Lee, J. I.; Mather, A. E. The excess enthalpy of gaseous mixtures of carbon dioxide with methane Can. J. Chem. Eng. 1972, 50
, 95-100

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0239

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
P/106Pa = 3.0 P/106Pa = 4.5
T/K = 248.1 T/K = 272.1 HE/J mol-1
3200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 11.0; T/K = 272.1
0.153000 671.00 0.041000 137.00 P/106Pa = 7.5; T/K = 300.1
0.410000 1301.00 0.125000 429.00 P/106Pa = 3.0; T/K = 248.1
0.459000 1465.00 0.172000 792.00
0.509000 1509.00 0.213000 1055.00
0.609000 1514.00 0.256000 1264.00 2400.
0.709000 1365.00 0.299000 1328.00
0.807000 1048.00 0.340000 1519.00
0.904000 519.00 0.425000 1641.00
0.465000 1655.00
0.508000 1670.00 1600.
0.525000 1702.00
0.592000 1626.00
0.633000 1595.00
0.673000 1475.00
0.714000 1416.00
0.796000 1075.00 800.
0.838000 906.00
0.870000 725.00
0.918000 432.00
0.959000 194.00
0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies and excess molar volumes of {xCO2 + (1-x)C2H6} up to 308.4 K and
11.0 MPa J. Chem. Thermodyn. 1988, 20, 323-331

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1161] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0387

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
P/106Pa = 5.600 P/106Pa = 6.200
T/K = 291.650 T/K = 291.650 HE/J mol-1
8000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 5.85; T/K = 291.65
0.158000 873.00 0.166000 890.00
0.256000 1366.00 0.225000 1143.00
0.307000 1601.00 0.284000 1426.00
0.355000 1875.00 0.405000 1884.00
0.406000 2183.00 0.465000 2077.00 6000.
0.456000 2804.00 0.524000 2236.00
0.505000 5162.00 0.584000 2369.00
0.555000 5587.00 0.645000 2440.00
0.606000 5848.00 0.705000 2297.00
0.654000 6220.00 0.764000 1945.00 4000.
0.705000 6402.00 0.824000 1495.00
0.755000 6450.00 0.884000 1035.00
0.804000 6415.00 0.941000 534.00
0.854000 6514.00 0.977000 220.00
0.904000 6496.00 0.979000 205.00
0.951000 a 750.00 2000.
0.978000 211.00

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE) = 0.02 a Two-phase region; See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Excess enthalpies and volumes for (carbon dioxide + ethane) at T = 291.6 K, close to the
minimum in the critical locus J. Chem. Thermodyn. 1997, 29, 75-85

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0394

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
P/106Pa = 3.10
T/K = 291.60 HE/J mol-1
600.
x1 HE/J mol-1
P/106Pa = .310; T/K = 291.6
0.056000 129.00
0.118000 233.00
0.176000 310.00
0.235000 354.00
0.297000 394.00 450.
0.355000 434.00
0.414000 438.00
0.476000 437.00
0.535000 434.00
0.655000 377.00 300.
0.714000 324.00
0.774000 256.00
0.834000 217.00
0.978000 49.00

150.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE) = 0.02
Wormald, C. J.; Hodgetts, R. W. Excess enthalpies and volumes for (carbon dioxide + ethane) at T = 291.6 K, close to the
minimum in the critical locus J. Chem. Thermodyn. 1997, 29, 75-85

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0093

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
P/106Pa = 7.5 P/106Pa = 11.0
T/K = 306.400 T/K = 308.400 HE/J mol-1
4000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 11.0; T/K = 308.4
0.096000 188.00 0.095000 393.00 P/106Pa = 5.5; T/K = 308.4
0.194000 302.00 0.193000 759.00 P/106Pa = 7.5; T/K = 308.4
0.243000 415.00 0.292000 1061.00
0.294000 542.00 0.392000 1307.00
P/106Pa = 4.0; T/K = 308.4
0.334000 683.00 0.445000 1397.00 3000.
0.398000 898.00 0.486000 1404.00
0.450000 1078.00 0.495000 1438.00
0.504000 1301.00 0.520000 1465.00
0.555000 1438.00 0.543000 1470.00
0.607000 1523.00 0.570000 1476.00 2000.
0.660000 1519.00 0.593000 1478.00
0.747000 1415.00 0.618000 1454.00
0.798000 1271.00 0.643000 1454.00
0.850000 1051.00 0.694000 1355.00
0.901000 809.00 0.795000 1121.00
0.952000 460.00 0.898000 527.00 1000.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies and excess molar volumes of {xCO2 + (1-x)C2H6} up to 308.4 K and
11.0 MPa J. Chem. Thermodyn. 1988, 20, 323-331

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0145

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
P/106Pa = 7.58 P/106Pa = 7.58
T/K = 293.15 T/K = 323.15 HE/J mol-1
2400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.58; T/K = 293.15
0.054000 498.00 0.106500 1102.00 P/106Pa = 7.58; T/K = 308.15
0.106500 828.00 0.157500 1360.00
0.157500 1032.00 0.207100 1479.00
0.207100 1251.00 0.255300 1608.00
0.255200 1411.00 0.302200 1627.00 1800.
0.278900 1533.00 0.347800 1639.00
0.347800 1760.00 0.392200 1629.00
0.435500 1953.00 0.435400 1585.00
0.456700 2032.00 0.518600 1420.00
0.518600 2051.00 0.558600 1294.00 1200.
0.578300 1978.00 0.597700 1187.00
0.597700 1940.00 0.635700 1116.00
0.657200 1781.00 0.672900 1024.00
0.672900 1815.00 0.709100 953.00
0.711700 1607.00 0.744500 766.00
0.744500 1456.00 0.812800 574.00 600.
0.781200 1301.00 0.878000 411.00
0.812800 1196.00 0.909500 350.00
0.847400 1046.00 0.940400 212.00
0.879400 851.00 P/106Pa = 7.58; T/K = 323.15
0.910600 653.00
0.
0.50
x1
Uncertainties: σ (x1) = 0.00020; σrel
(HE) = 0.020 See SELF for the totality of data
Pando, C.; Renuncio, J. A. R.; Izatt, R. M.; Christensen, J. J. The excess molar enthalpies of {xCO2 + (1-x)C2H6} from
293.15 to 323.15 K at 7.58 MPa J. Chem. Thermodyn. 1983, 15, 231-235

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0063

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
T/K = 308.400 T/K = 316.150
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
3200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 308.40; x1 = 0.500
4.010 410.000 3.970 292.000
5.000 1170.000 4.270 336.000 T/K = 312.16; x1 = 0.500
5.200 1956.000 4.680 410.000 T/K = 323.15; x1 = 0.500
5.310 2341.000 5.070 501.000
5.500 2380.000 5.480 563.000 2400.
5.750 2410.000 5.680 596.000
6.000 2416.000 5.880 687.000
6.500 2100.000 6.670 1290.000
7.190 1638.000 7.050 1380.000
7.500 1490.000 7.450 1414.000 1600.
7.690 1451.000 8.040 1356.000
7.900 1472.000 8.240 1330.000
8.010 1591.000 8.440 1318.000
8.050 1769.000 8.640 1317.000
8.090 1904.000 8.850 1334.000
8.390 1991.000 9.060 1369.000 800.
8.610 1883.000 9.460 1501.000
9.000 1763.000 9.960 1556.000
10.000 1524.000 11.300 1268.000
11.000 1450.000
0.
0. 4. 8. 12. 16.
P/106Pa
Uncertainties: σrel(P) = 0.0025; σrel(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess enthalpies and excess volumes of (0.5CO2 + 0.5C2H6) in the supercritical region J.
Chem. Soc., Faraday Trans. 1 1988, 84, 1437-1445

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0240

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
P/106Pa = 5.5
T/K = 300.1 HM/J mol-1
3600.
x1 HM/J mol-1
P/106Pa = 5.5; T/K = 300.1
0.046000 8.00
0.095000 82.00
0.122000 128.00
0.134000 318.00
0.153000 449.00 2700.
0.169000 754.00
0.199000 1142.00
0.248000 2459.00
0.299000 2982.00
0.371000 2912.00 1800.
0.398000 2861.00
0.413000 2769.00
0.559000 2481.00
0.598000 2350.00
0.648000 2147.00
0.699000 1893.00 900.
0.747000 1615.00
0.799000 1330.00
0.848000 990.00
0.899000 681.00
0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HM)
= 0.02
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies and excess molar volumes of {xCO2 + (1-x)C2H6} up to 308.4 K and
11.0 MPa J. Chem. Thermodyn. 1988, 20, 323-331

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0395

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6, Ethane [74-84-0]
P/106Pa = 4.000 P/106Pa = 5.400
T/K = 291.650 T/K = 291.650 HM/J mol-1
3000.
x1 HM/J mol-1 x1 HM/J mol-1
0.061000 27.00 0.107000 –138.00
0.119000 5431.00 0.166000 –184.00
0.178000 5424.00 0.225000 –274.00
0.237000 5220.00 0.287000 –373.00
0.296000 4923.00 0.346000 –366.00 2000.
0.358000 4656.00 0.382000 –346.00
0.417000 4352.00 0.464000 2414.00
0.476000 4003.00 0.525000 2473.00
0.537000 3607.00 0.584000 2379.00
0.597000 3219.00 0.644000 2179.00 1000.
0.656000 2781.00 0.703000 1931.00
0.716000 2339.00 0.762000 1624.00
0.775000 1899.00 0.823000 1277.00
0.834000 1431.00 0.882000 877.00
0.893000 942.00 0.942000 460.00
0.952000 462.00 0.977000 242.00 0.
0.978000 235.00 0.978000 243.00
0.979000 207.00

P/106Pa = 5.40; T/K = 291.65

–1000.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM) = 0.02 See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Excess enthalpies and volumes for (carbon dioxide + ethane) at T = 291.6 K, close to the
minimum in the critical locus J. Chem. Thermodyn. 1997, 29, 75-85

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0238

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H12, Pentane [109-66-0]
P/106Pa = 7.58 P/106Pa = 7.58
T/K = 470.15 T/K = 470.15 HE/J mol-1
5200.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 7.58; T/K = 470.15
0.038700 291.00 0.627000 3700.00 P/106Pa = 10.37; T/K = 470.15
0.076000 550.00 0.663600 3500.00 P/106Pa = 12.45; T/K = 470.15
0.111800 790.00 0.698400 3250.00
0.146400 1280.00 0.763000 2700.00
0.179800 1710.00 0.821500 1960.00 3900.
0.179800 1710.00 0.874900 1450.00
0.243100 2720.00 0.946700 549.00
0.273100 3190.00 0.989800 67.00
0.302200 3530.00
0.330300 3850.00 2600.
0.330300 3820.00
0.357500 4190.00
0.383900 4270.00
0.409400 4330.00
0.434100 4410.00
0.458000 4460.00 1300.
0.458200 4450.00
0.481400 4360.00
0.504100 4320.00
0.547400 4260.00
0.568100 4080.00
0.588300 3950.00 0.
0.627000 3690.00 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 5.00 + 0.020 |HE/J mol-1| See SELF for the totality of data
Christensen, J. J.; Faux, P. W.; Cordray, D.; Izatt, R. M. The excess enthalpies of (carbon dioxide + pentane) at 348.15,
373.15, 413.15, 470.15, and 573.15 K from 7.58 to 12.45 MPa J. Chem. Thermodyn. 1986, 18, 1053-1064

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0087

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H12, Pentane [109-66-0]
T/K = 448.2 T/K = 473.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
1800.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 448.20; x1 = 0.500
0.206 42.000 0.205 37.000
0.306 61.000 0.297 53.000 T/K = 473.20; x1 = 0.500
0.504 115.000 0.401 74.000
0.703 168.000 0.611 119.000
0.901 243.000 0.816 167.000 1350.0
1.104 336.000 1.002 220.000
1.292 427.000 1.216 299.000
1.514 546.000 1.408 379.000
1.712 685.000 1.621 461.000
1.910 851.000 1.816 550.000 900.0
2.023 983.000 2.036 668.000
2.105 1074.000 2.060 694.000
2.219 1225.000 2.268 805.000
2.307 1368.000 2.407 941.000
2.410 1610.000 2.594 1081.000
450.0

0.0
0.0 0.6 1.3 1.9 2.6
P/106Pa
Uncertainties: σ (P)/106Pa = 0.00200; σ (HE)/J mol-1 = 2.00 + 0.020 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Smith, G. R. Excess enthalpies of (carbon dioxide + pentane or hexane or heptane or cyclohexane or
benzene)(g) at temperatures from 432.2 K to 573.2 K and pressures up to 2.71 MPa J. Chem. Thermodyn. 1992, 24, 481-492

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0146

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H12, Pentane [109-66-0]
P/106Pa = 12.45 P/106Pa = 7.58
T/K = 308.15 T/K = 323.15 HM/J mol-1
2000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 12.45; T/K = 308.15
0.082100 284.00 0.270900 –1348.00
0.157400 481.00 0.327800 –1628.00
0.226600 633.00 0.431400 –2156.00
0.290400 746.00 0.478800 –2448.00
0.349400 839.00 0.523300 –2720.00 0.
0.404200 882.00 0.565500 –2954.00
0.455100 892.00 0.605400 –3209.00
0.502700 910.00 0.643100 –3488.00
0.547200 901.00 0.679000 –3727.00
0.588800 900.00 0.713000 –3864.00 –2000.
0.627900 876.00 0.745500 –3943.00
0.664700 825.00 0.805800 –3464.00
0.699400 794.00 0.820000 –3198.00
0.732200 735.00 0.833800 a –2871.00
0.763100 685.00 0.847400 a –2496.00
0.792500 635.00 0.873700 a –1852.00 –4000.
0.820300 581.00 0.886400 a –1526.00
0.871800 446.00 0.898900 a –1221.00
0.895700 370.00 0.911100 a –919.00 P/106Pa = 10.37; T/K = 323.15
0.918500 298.00 0.923000 –558.00 P/106Pa = 7.58; T/K = 323.15
0.961100 150.00 0.934700 –332.00
0.981000 73.00 0.957300 51.00 –6000.
0.979100 80.00 0.50
x1
Uncertainties: σ (x1) = 0.00020; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Pando, C.; Renuncio, J. A. R.; Izatt, R. M.; Christensen, J. J. The excess enthalpies of (carbon dioxide + pentane) at 308.15
and 323.15 K from 7.58 to 12.45 MPa J. Chem. Thermodyn. 1983, 15, 259-266

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0237

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H12, Pentane [109-66-0]
P/106Pa = 7.58 P/106Pa = 7.58
T/K = 373.15 T/K = 373.15 HM/J mol-1
1800.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.58; T/K = 373.15
0.076000 –285.00 0.821500 1730.00
0.111800 –379.00 0.821500 1730.00
0.179800 –621.00 0.848800 1520.00
0.243100 –768.00 0.874900 1330.00
0.302200 –932.00 0.899900 1050.00 900.
0.357500 –1080.00 0.923800 807.00
0.383900 –1130.00 0.946700 529.00
0.409400 –1130.00 0.968700 228.00
0.409400 –1140.00
0.434100 –1190.00 0.
0.458200 –1180.00
0.481400 a –1040.00
0.504100 a –847.00
0.547400 a –491.00
0.588300 a –173.00
0.627000 a 215.00 –900.
0.663600 a 533.00
0.698400 a 856.00
0.731500 a 1080.00 P/106Pa = 10.37; T/K = 373.15
0.763000 a 1420.00
0.793000 a 1600.00 P/106Pa = 12.45; T/K = 373.15
0.807400 a 1720.00 –1800.
0.814500 a 1780.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 5.00 + 0.020 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Faux, P. W.; Cordray, D.; Izatt, R. M. The excess enthalpies of (carbon dioxide + pentane) at 348.15,
373.15, 413.15, 470.15, and 573.15 K from 7.58 to 12.45 MPa J. Chem. Thermodyn. 1986, 18, 1053-1064

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0260

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H14, Hexane [110-54-3]
P/106Pa = 7.500 P/106Pa = 10.500
T/K = 510.150 T/K = 510.150 HE/J mol-1
6800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.50; T/K = 510.15
0.084900 1170.00 0.046900 173.00
0.124500 1600.00 0.133500 542.00 P/106Pa = 7.50; T/K = 573.15
0.162300 2150.00 0.211500 991.00 P/106Pa = 12.50; T/K = 573.15
0.198400 2500.00 0.282100 1560.00
0.266200 3460.00 0.346300 2090.00 5100.
0.328400 4140.00 0.405000 2630.00
0.357700 4520.00 0.458900 2960.00
0.385900 4610.00 0.484200 3140.00
0.413000 4700.00 0.508500 3240.00
0.439100 4840.00 0.531800 3290.00 3400.
0.464200 5050.00 0.554300 3310.00
0.488400 4990.00 0.575900 3330.00
0.511800 4850.00 0.596700 3280.00
0.534400 4880.00 0.636100 3230.00
0.577300 4550.00 0.672800 3040.00
0.617300 4340.00 0.707100 2890.00 1700.
0.654900 4080.00 0.739100 2710.00
0.690200 3730.00 0.797500 2230.00
0.723400 3470.00 0.849200 1720.00
0.784300 2780.00 0.895400 1230.00
0.838700 2140.00 0.936800 751.00
0.887600 1530.00 0.956000 500.00 0.
0.952500 562.00 0.991600 61.00 0.50
0.990900 127.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE)= 0.02 See SELF for the totality of data
Christensen, J. J.; Zebolsky, D. M.; Izatt, R. M. The excess enthalpies of (carbon dioxide + hexane) at 470.15, 510.15, and
573.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1985, 17, 183-192

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0088

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H14, Hexane [110-54-3]
T/K = 473.2 T/K = 498.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
1600.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 473.20; x1 = 0.500
0.403 145.000 0.296 86.000
0.501 186.000 0.401 116.000 T/K = 498.20; x1 = 0.500
0.517 191.000 0.506 156.000
0.616 247.000 0.599 195.000
0.701 281.000 0.730 248.000 1200.0
0.801 331.000 0.821 282.000
0.901 399.000 1.119 436.000
0.996 482.000 1.241 496.000
1.091 532.000 1.327 559.000
1.216 636.000 1.434 623.000 800.0
1.317 729.000 1.530 698.000
1.418 831.000 1.621 761.000
1.520 962.000 1.702 845.000
1.530 955.000 1.826 951.000
1.631 1106.000 1.925 1086.000
2.021 1199.000 400.0
2.128 1358.000
2.229 1512.000

0.0
0.0 0.6 1.2 1.8 2.4
P/106Pa
Uncertainties: σ (P)/106Pa = 0.00200; σ (HE)/J mol-1 = 2.00 + 0.020 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Smith, G. R. Excess enthalpies of (carbon dioxide + pentane or hexane or heptane or cyclohexane or
benzene)(g) at temperatures from 432.2 K to 573.2 K and pressures up to 2.71 MPa J. Chem. Thermodyn. 1992, 24, 481-492

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0171

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H14, Hexane [110-54-3]
P/106Pa = 7.50 P/106Pa = 7.50
T/K = 413.15 T/K = 413.15 HM/J mol-1
4200.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.500; T/K = 413.15
0.043800 –53.00 0.864800 2040.00 P/106Pa = 10.500; T/K = 308.15
0.085600 –169.00 0.888500 1700.00 P/106Pa = 7.500; T/K = 308.15
0.125400 –248.00 0.911000 1330.00
0.199800 –387.00 0.932400 951.00
0.267800 –521.00 0.952900 717.00 2100.
0.330300 –588.00 0.972400 330.00
0.357700 –593.00 0.991000 104.00
0.387900 a –583.00
0.415000 a –399.00
0.441100 a –185.00 0.
0.490500 a 113.00
0.490500 a 110.00
0.536500 a 498.00
0.579300 a 880.00
0.619300 a 1080.00
0.656800 a 1340.00 –2100.
0.692000 a 1550.00
0.725100 a 1830.00
0.756200 a 2020.00
0.785700 a 2280.00
0.799800 a 2200.00
0.813500 2310.00 –4200.
0.839800 2160.00 0.50
0.864800 2040.00
x1
Uncertainties: σ (x1) = 0.00050; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Walker, T. A. C.; Schofield, R. S.; Faux, P. W.; Harding, P. R.; Izatt, R. M. The excess enthalpies of
(carbon dioxide + hexane) at 308.15, 358.15, and 413.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1984, 16, 445-451

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0261

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H14, Hexane [110-54-3]
P/106Pa = 10.500 P/106Pa = 10.500
T/K = 470.15 T/K = 470.15 HM/J mol-1
4800.
x1 HM/J mol-1 x1 HM/J mol-1
0.046900 91.00 0.769200 2460.00
0.133500 178.00 0.769200 2480.00
0.211500 304.00 0.797500 2220.00
0.247600 399.00 0.824100 2010.00
0.282100 508.00 0.849200 1810.00 3200.
0.315000 700.00 0.872900 1610.00
0.346300 824.00 0.895400 1350.00
0.376300 1080.00 0.916600 1120.00
0.405000 1200.00 0.936800 851.00
0.432500 1440.00 0.956000 628.00 1600.
0.458900 1690.00 0.974200 358.00
0.484200 1930.00 0.991600 128.00
0.508500 2100.00
0.531800 2330.00
0.531800 2350.00
0.554300 2380.00 0.
0.554300 2350.00
0.575900 2560.00 P/106Pa = 7.50; T/K = 470.15
0.596700 2690.00 P/106Pa = 10.50; T/K = 470.15
0.616700 2770.00 P/106Pa = 12.50; T/K = 470.15
0.636100 2750.00
0.672800 2760.00 –1600.
0.707100 2700.00 0.50
x1
Uncertainties: σ (x1) = 0.00050; σrel
(HM) = 0.02 See SELF for the totality of data
Christensen, J. J.; Zebolsky, D. M.; Izatt, R. M. The excess enthalpies of (carbon dioxide + hexane) at 470.15, 510.15, and
573.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1985, 17, 183-192

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0089

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H16, Heptane [142-82-5]
T/K = 523.3 T/K = 538.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
2000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 523.3; x1 = 0.500
0.204 80.000 0.401 156.000
0.301 116.000 0.498 194.000 T/K = 538.2; x1 = 0.500
0.302 118.000 0.599 246.000
0.404 169.000 0.698 294.000
0.406 166.000 0.805 346.000 1500.0
0.501 218.000 0.901 400.000
0.600 267.000 1.002 470.000
0.606 279.000 1.102 535.000
0.703 322.000 1.211 605.000
0.808 392.000 1.307 680.000 1000.0
1.006 537.000 1.419 782.000
1.125 625.000 1.510 855.000
1.226 708.000 1.640 966.000
1.327 817.000 1.707 1079.000
1.426 912.000
1.524 1033.000 500.0
1.628 1166.000
1.721 1297.000
1.824 1515.000
1.931 1731.000
0.0
0.0 0.5 1.0 1.5 2.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.00200; σ (HE)/J mol-1 = 2.00 + 0.020 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Smith, G. R. Excess enthalpies of (carbon dioxide + pentane or hexane or heptane or cyclohexane or
benzene)(g) at temperatures from 432.2 K to 573.2 K and pressures up to 2.71 MPa J. Chem. Thermodyn. 1992, 24, 481-492

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0279

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C9H20, Nonane [111-84-2]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 373.150 T/K = 373.150 HM/J mol-1
700.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.50; T/K = 373.15
0.112900 –395.00 0.058400 –64.70
0.209900 –816.00 0.112300 –196.00 P/106Pa = 12.50; T/K = 373.15
0.253400 –987.00 0.252300 –602.00
0.332100 –1330.00 0.330800 –850.00
0.401400 –1620.00 0.400000 –1080.00 0.
0.462800 –1570.00 0.461400 –1280.00
0.517700 a–1420.00 0.516200 –1490.00
0.567000 a–1250.00 0.565500 –1690.00
0.670700 a –895.00 0.610000 –1820.00
0.722400 a –705.00 0.630800 –1910.00 –700.
0.753400 a –600.00 0.650500 –1950.00
0.753400 a –570.00 0.669400 –1860.00
0.782000 a –454.00 0.687400 a–1730.00
0.820900 a –329.00 0.721200 a–1500.00
0.877000 a –151.00 0.752300 a–1290.00
0.877000 a –133.00 0.780900 a–1100.00 –1400.
0.924400 a 37.90 0.820000 a –871.00
0.941300 a 114.00 0.876300 a –532.00
0.964900 a 169.00 0.923900 a –206.00
0.964900 a 185.00 0.964700 a 25.70
0.979500 242.00 0.972200 57.20
0.986500 252.00 0.979400 84.90 –2100.
0.993400 128.00 0.986500 56.00 0.50
0.986500 64.30
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 0.50 + 0.020 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Cordray, D. R.; Gunderson, L. D.; Christensen, J. J.; Oscarson, J. L.; Izatt, R. M. The excess molar enthalpies of [xCO2 +
(1 - x){0.5CH3(CH2)4CH3 + 0.5CH3(CH2)10CH3}] at the temperatures (308.15, 323.15, 373.15, and 413.15) K and at the
pressures 7.50 MPa and 12.50 MPa, and of {xCO2 + (1 - x)CH3(CH2)7CH3} at 373.15 K and 7.50 MPa and 12.50 MPa J. Chem.
Thermodyn. 1991, 23, 941-949

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0147

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C10H22, Decane [124-18-5]
P/106Pa = 7.58 P/106Pa = 7.58
T/K = 303.15 T/K = 303.15 HE/J mol-1
1800.
x1 HE/J mol-1
P/106Pa = 7.58; T/K = 283.15
0.063100 127.00 0.974300 –412.00
0.148000 281.00 0.993900 –94.00
0.223000 389.00
0.289700 444.00
0.349500 465.00 1200.
0.349500 473.00
0.403300 489.00
0.403300 486.00
0.452100 474.00
0.496400 458.00 600.
0.496400 462.00
0.536900 433.00
0.608300 347.00
0.669200 220.00
0.721700 102.00
0.767400 –45.00 0.
0.767400 –50.00
0.807700 –176.00
0.843400 –261.00
0.875200 –368.00 P/106Pa = 7.58; T/K = 303.15
0.903800 –457.00
0.929600 –502.00 –600.
0.953000 –506.00 0.50
x1
Uncertainties: σ (x1) = 0.0002; σrel
(HE)= 0.02 See SELF for the totality of data
Pando, C.; Renuncio, J. A. R.; McFall, T. A.; Izatt, R. M.; Christensen, J. J. The excess enthalpies of (carbon dioxide +
decane) from 283.15 to 323.15 K at 7.58 MPa J. Chem. Thermodyn. 1983, 15, 173-180

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0266

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C10H22, Decane [124-18-5]
P/106Pa = 12.500 P/106Pa = 12.500
T/K = 293.150 T/K = 303.150 HE/J mol-1
1600.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 12.5; T/K = 293.15
0.070500 243.00 0.070500 184.00
0.134000 394.00 0.134000 385.00 P/106Pa = 12.5; T/K = 303.15
0.191700 598.00 0.191700 543.00
0.244200 782.00 0.244200 670.00
0.292200 897.00 0.292200 773.00 1200.
0.336300 1030.00 0.336300 856.00
0.396000 1130.00 0.396000 946.00
0.449200 1240.00 0.449200 988.00
0.496900 1270.00 0.511700 1050.00
0.553300 1320.00 0.566200 1050.00 800.
0.614300 1280.00 0.614200 1030.00
0.666700 1250.00 0.656800 1000.00
0.712400 1190.00 0.694800 949.00
0.752500 1130.00 0.729000 903.00
0.787900 1030.00 0.759900 841.00
0.819500 953.00 0.787900 769.00 400.
0.847900 848.00 0.813500 703.00
0.873400 755.00 0.836900 629.00
0.896600 648.00 0.868500 529.00
0.917700 549.00 0.896600 425.00
0.937000 440.00 0.929400 293.00
0.954700 339.00 0.951200 203.00 0.
0.971000 230.00 0.971000 116.00 0.50
0.986000 115.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 10.00 + 0.008 |HE/J mol-1|
Christensen, J. J.; Cordray, D. R.; Izatt, R. M. The excess enthalpies of (carbon dioxide + decane) from 293.15 to 573.15 K at
12.50 MPa J. Chem. Thermodyn. 1986, 18, 53-61

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0204

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C10H22, Decane [124-18-5]
P/106Pa = 7.58 P/106Pa = 7.58
T/K = 308.15 T/K = 308.15 HM/J mol-1
1600.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.58; T/K = 323.15
0.063100 –246.00 0.960300 a–3761.00
0.063100 –182.00 0.960300 a–3761.00 P/106Pa = 7.58; T/K = 313.15
0.120900 –457.00 0.967500 a–3010.00 P/106Pa = 7.58; T/K = 308.15
0.120900 –354.00 0.984300 a–1276.00
0.148000 –563.00 0.993900 –5.10 0.
0.148000 –442.00
0.223000 –723.00
0.289700 –1097.00
0.349500 –1205.00
0.403300 –1442.00 –1600.
0.452200 –1612.00
0.499600 –1870.00
0.537100 –2117.00
0.608300 –2572.00
0.669300 –2920.00
0.721800 –3228.00 –3200.
0.767600 –3516.00
0.807800 –3839.00
0.843500 –4064.00
0.875300 –4291.00
0.903800 –4434.00
0.929600 –4750.00 –4800.
0.953000 a–4490.00 0.50
x1
Uncertainties: σ (x1) = 0.00020; σrel
(HM)= 0.02 a Two-phase region; See SELF for the totality of data
Pando, C.; Renuncio, J. A. R.; McFall, T. A.; Izatt, R. M.; Christensen, J. J. The excess enthalpies of (carbon dioxide +
decane) from 283.15 to 323.15 K at 7.58 MPa J. Chem. Thermodyn. 1983, 15, 173-180

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0267

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C10H22, Decane [124-18-5]
P/106Pa = 12.500 P/106Pa = 12.500
T/K = 363.15 T/K = 363.15 HM/J mol-1
500.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 12.50; T/K = 323.15
0.070500 –84.00 0.744800 a–1790.00
0.134000 –246.00 0.759900 a–1680.00
0.191700 –405.00 0.787900 a–1460.00
0.244200 –574.00 0.787900 a–1470.00
0.292200 –699.00 0.813500 a–1310.00 0.
0.336300 –801.00 0.836900 a–1080.00
0.373900 –935.00 0.858400 a –974.00
0.414400 –1030.00 0.878200 a –782.00
0.449200 –1200.00 0.896600 a –694.00
0.511700 –1360.00 0.913600 a –562.00 –500.
0.566200 –1570.00 0.929400 a –412.00
0.591000 –1650.00 0.944200 a –341.00
0.614200 –1680.00 0.958000 a –214.00
0.636100 –1820.00 0.971000 a –159.00
0.656800 –1880.00 0.983100 a –42.00
0.666700 –1940.00 0.988900 a –13.00 –1000.
0.676400 –1970.00
0.685700 –2010.00
0.694800 a–2060.00
0.703700 a–2090.00
0.712400 a–2030.00 P/106Pa = 12.50; T/K = 413.15
0.720800 a–1980.00 –1500.
0.729000 a–1860.00 0.50
0.744800 a–1790.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 10.00 + 0.008 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Izatt, R. M. The excess enthalpies of (carbon dioxide + decane) from 293.15 to 573.15 K at
12.50 MPa J. Chem. Thermodyn. 1986, 18, 53-61

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0219

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.3 P/103Pa = 101.3
T/K = 354.5 T/K = 398.6 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.3; T/K = 354.5
0.420000 65.00 0.447000 44.60
0.445000 65.30 0.464000 43.80 P/103Pa = 101.3; T/K = 398.6
0.461000 65.10 0.490000 44.10
0.498000 66.20 0.555000 44.50
0.532000 65.10 0.571000 43.00 60.
0.544000 65.40 0.583000 43.00
0.590000 63.20 0.608000 41.70
0.620000 61.30 0.630000 41.00
0.644000 60.00 0.672000 39.90
0.700000 55.00 0.711000 37.10 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W.; Smith, G. R. Excess enthalpies of (carbon dioxide + cyclohexane)(g) and of (carbon dioxide
+ benzene)(g) at the pressure 101.3 kPa over the temperature range 354 K to 399 K J. Chem. Thermodyn. 1992, 24, 943-952

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0185

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H12, Cyclohexane [110-82-7]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 553.150 T/K = 553.150 HE/J mol-1
8000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 553.15
0.071400 1460.00 0.040300 295.00 P/106Pa = 10.5; T/K = 553.15
0.105400 2400.00 0.116100 910.00 P/106Pa = 12.5; T/K = 553.15
0.138300 3140.00 0.151700 1110.00
0.201100 4700.00 0.186000 1460.00
0.231100 5280.00 0.219100 1700.00 6000.
0.288400 6170.00 0.250900 2070.00
0.315800 6390.00 0.281500 2370.00
0.342400 6420.00 0.311100 2630.00
0.368300 6510.00 0.367200 3210.00
0.393400 6510.00 0.393800 3470.00 4000.
0.441700 6390.00 0.419500 3680.00
0.487400 6200.00 0.444400 3830.00
0.530800 5950.00 0.468500 3890.00
0.574000 5490.00 0.491900 3960.00
0.611300 5170.00 0.514500 4000.00
0.648600 4780.00 0.557700 3940.00 2000.
0.718200 3930.00 0.598300 3860.00
0.781800 3080.00 0.636700 3690.00
0.811600 2790.00 0.672900 3520.00
0.867500 1990.00 0.739600 3030.00
0.919000 1210.00 0.827600 2200.00
0.943200 898.00 0.879400 1590.00 0.
0.966600 444.00 0.948800 694.00 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 5.00 + 0.020 |HE/J mol-1| See SELF for the totality of data
Christensen, J. J.; Walker, T. A. C.; Cordray, D. R.; Izatt, R. M. The excess enthalpies of (carbon dioxide + cyclohexane) at
470.15, 553.15, and 573.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1987, 19, 47-56

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0085

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H12, Cyclohexane [110-82-7]
T/K = 523.2 T/K = 548.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
1000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 523.2; x1 = 0.500
0.311 66.000 0.301 55.000
0.504 113.000 0.399 76.000 T/K = 548.2; x1 = 0.500
0.705 168.000 0.599 124.000
0.706 169.000 0.697 144.000
0.901 225.000 0.901 210.000 750.0
0.906 231.000 1.094 245.000
1.113 316.000 1.301 325.000
1.295 392.000 1.712 473.000
1.403 435.000 1.917 594.000
1.502 490.000 2.207 738.000 500.0
1.701 601.000
1.727 621.000
1.895 730.000
2.045 821.000
2.123 893.000
250.0

0.0
0.0 0.6 1.2 1.8 2.4
P/106Pa
Uncertainties: σ (P)/106Pa = 0.00200; σ (HE)/J mol-1 = 2.00 + 0.020 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Smith, G. R. Excess enthalpies of (carbon dioxide + pentane or hexane or heptane or cyclohexane or
benzene)(g) at temperatures from 432.2 K to 573.2 K and pressures up to 2.71 MPa J. Chem. Thermodyn. 1992, 24, 481-492

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0184

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H12, Cyclohexane [110-82-7]
P/106Pa = 7.5 P/106Pa = 7.5
T/K = 470.15 T/K = 470.15 HM/J mol-1
6000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 470.15
0.105400 79.00 0.684300 4770.00 P/106Pa = 10.5; T/K = 470.15
0.105400 98.00 0.684300 4770.00 P/106Pa = 12.5; T/K = 470.15
0.170200 203.00 0.684300 4710.00
0.170200 207.00 0.684300 4740.00
0.231100 433.00 0.701500 4670.00 4500.
0.260200 a 716.00 0.701500 4730.00
0.260200 a 648.00 0.718300 4540.00
0.288400 a 947.00 0.734700 4530.00
0.315800 a 1190.00 0.750700 4230.00
0.315800 a 1270.00 0.781800 3890.00 3000.
0.368300 a 1750.00 0.796900 3690.00
0.368300 a 1780.00 0.811600 3390.00
0.393400 a 2080.00 0.853900 2610.00
0.417900 a 2130.00 0.867500 2350.00
0.441700 a 2560.00 0.893700 1920.00
0.441700 a 2540.00 0.919000 1510.00 1500.
0.509400 a 3120.00 0.943200 1050.00
0.530900 a 3300.00 0.943200 1030.00
0.530900 a 3360.00 0.966600 601.00
0.551800 a 3600.00 0.989100 166.00
0.572000 a 3760.00
0.620800 a 4240.00 0.
0.648700 a 4460.00 0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HM)/J mol-1
= 20 + 0.020 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Walker, T. A. C.; Cordray, D. R.; Izatt, R. M. The excess enthalpies of (carbon dioxide + cyclohexane) at
470.15, 553.15, and 573.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1987, 19, 47-56

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0188

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H12, Cyclohexane [110-82-7]
P/106Pa = 7.500 P/106Pa = 7.500
T/K = 308.15 T/K = 308.15 HM/J mol-1
1500.
x1 HM/J mol-1 x1 HM/J mol-1
0.036400 –52.00 0.950300 –4036.00
0.105700 –150.00 0.956000 a –4019.00
0.173600 –318.00 0.967300 a –3714.00
0.231600 –506.00 0.972900 a –2889.00
0.293300 –663.00 0.978400 a –1747.00 0.
0.343000 –868.00 0.989300 a –251.00
0.394100 –1085.00
0.442400 –1358.00
0.488100 –1583.00
0.531500 –1795.00 –1500.
0.597700 –2210.00
0.649300 –2576.00
0.689400 –2695.00
0.723100 –2999.00
0.770700 –3237.00
0.815200 –3482.00 –3000.
0.856900 –3726.00
0.870200 –3850.00 P/106Pa = 12.50; T/K = 308.15
0.896000 –3992.00 P/106Pa = 10.50; T/K = 308.15
0.920700 –4055.00
0.932700 –4191.00 P/106Pa = 7.50; T/K = 308.15
0.944500 –4212.00 –4500.
0.950300 –4151.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Christensen, S. P.; Schofield, R. S.; Faux, P. W.; Harding, P. R.; Izatt, R. M. The excess enthalpies of
(carbon dioxide + cyclohexane) at 308.15, 358.15, and 413.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1983, 15
, 1151-1157

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0276

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H12, Cyclohexane [110-82-7]
P/106Pa = 14.390 P/106Pa = 14.390
T/K = 390.15 T/K = 390.15 HM/J mol-1
7500.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.50; T/K = 508.15
0.081000 –37.00 0.775300 a –270.00
0.118900 –83.40 0.775300 a –270.00
0.118900 –94.70 0.804100 a –96.60
0.155300 –133.00 0.831500 a 45.80
0.190200 –180.00 0.831500 a 70.60 5000.
0.256100 –265.00 0.857500 a 202.00
0.256100 –241.00 0.870100 a 282.00
0.317000 –326.00 0.882300 327.00
0.317000 –331.00 0.906000 366.00
0.373600 –427.00 0.928500 390.00 2500.
0.426300 –544.00 0.939400 382.85
0.475400 –605.00 0.950100 325.00
0.475400 –621.00 0.970700 261.00
0.498800 –665.00 0.980700 188.00
0.521400 –702.00
0.545400 –747.00 0.
0.585000 –763.00
0.604900 –773.00
0.604900 –759.00 P/106Pa = 10.50; T/K = 498.15
0.643000 –752.00 P/106Pa = 14.39; T/K = 390.15
0.678900 –695.00 P/106Pa = 14.39; T/K = 438.15
0.712800 –575.00 –2500.
0.744900 –440.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 0.50 + 0.020 |HM/J mol-1|a Two-phase region; See SELF for the totality of data
Cordray, D. R.; Izatt, R. M.; Christensen, J. J. The excess enthalpies of (cerbon dioxide + cyclohexane) at 390.15, 413.15,
438.15, 498.15, and 508.15 K from 7.50 to 14.39 MPa J. Chem. Thermodyn. 1988, 20, 225-234

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0407

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H12, Cyclohexane [110-82-7]
T/K H°sol/103J mol-1
298.15 –6.660 H°sol/103J mol-1
318.15 –6.220 –6.0

–6.2

–6.4

–6.6

–6.8
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.15
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0178

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H4, Ethene [74-85-1]
P/106Pa = 4.75 P/106Pa = 11.00
T/K = 276.65 T/K = 276.65 HE/J mol-1
1200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.75; T/K = 276.65
0.158000 507.00 0.149000 338.00
0.199000 604.00 0.297000 602.00 P/106Pa = 11.00; T/K = 276.65
0.239000 691.00 0.349000 645.00
0.320000 822.00 0.393000 700.00
0.360000 851.00 0.447000 720.00 900.
0.403000 853.00 0.497000 734.00
0.447000 885.00 0.548000 734.00
0.484000 886.00 0.598000 722.00
0.523000 858.00 0.648000 688.00
0.563000 855.00 0.699000 631.00 600.
0.602000 811.00 0.750000 584.00
0.643000 780.00 0.799000 499.00
0.682000 720.00 0.849000 377.00
0.723000 646.00 0.899000 246.00
0.762000 590.00 0.948000 126.00
0.802000 500.00 300.
0.841000 429.00
0.880000 332.00
0.920000 217.00
0.959000 102.00
0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies of (carbon dioxide + ethene) in the liquid and near-critical regions J.
Chem. Thermodyn. 2001, 33, 775-786

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0248

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H4, Ethene [74-85-1]
P/106Pa = 8.05 P/106Pa = 11.00
T/K = 305.75 T/K = 306.62 HE/J mol-1
2800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.570; T/K = 300.45
0.165000 613.00 0.099000 305.00 P/106Pa = 8.050; T/K = 305.75
0.205000 904.00 0.148000 442.00 P/106Pa = 11.000; T/K = 306.62
0.249000 991.00 0.199000 544.00
0.291000 1304.00 0.249000 641.00
0.332000 1360.00 0.298000 739.00 2100.
0.375000 1580.00 0.348000 824.00
0.417000 1681.00 0.399000 880.00
0.458000 1833.00 0.447000 940.00
0.500000 1943.00 0.499000 981.00
0.542000 2076.00 0.599000 989.00 1400.
0.585000 2157.00 0.650000 968.00
0.626000 2194.00 0.699000 898.00
0.666000 2204.00 0.749000 799.00
0.707000 2240.00 0.799000 701.00
0.750000 2223.00 0.847000 599.00
0.791000 2176.00 0.899000 337.00 700.
0.833000 2028.00 0.950000 155.00
0.875000 1764.00
0.916000 1254.00
0.928000 887.00
0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies of (carbon dioxide + ethene) in the liquid and near-critical regions J.
Chem. Thermodyn. 2001, 33, 775-786

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0250

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H4, Ethene [74-85-1]
T/K = 306.25 T/K = 315.75
x1 = 0.500 x1 = 0.500 HE/J mol-1
2800.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 285.85; x1 = 0.500
3.480 109.0 3.000 75.0 T/K = 300.45; x1 = 0.500
5.080 181.0 4.000 109.0 T/K = 306.25; x1 = 0.500
5.280 184.0 5.010 149.0
5.480 202.0 6.050 208.0
T/K = 315.75; x1 = 0.500
5.690 226.0 7.080 313.0 2100.
5.890 242.0 7.680 408.0
6.950 486.0 8.300 516.0
7.450 862.0 8.910 722.0
7.940 2139.0 9.520 1053.0
8.440 1741.0 10.100 1099.0 1400.
8.940 1591.0 10.700 1016.0
9.500 1340.0 11.300 896.0
10.000 1208.0 12.000 846.0
11.000 956.0 12.600 765.0
12.500 818.0
700.

0.
2. 5. 8. 11. 14.
P/106Pa
Uncertainties: σ (P)/106Pa = 0.02; σrel(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies of (carbon dioxide + ethene) in the liquid and near-critical regions J.
Chem. Thermodyn. 2001, 33, 775-786

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0448

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H4, Ethene [74-85-1]
P/106Pa T/K x1 HE/J mol-1 P/103Pa T/K x1 HE/J mol-1
1.031 298.23 0.7970 8.421 1.038 318.15 0.6730 8.643
1.028 298.18 0.6820 9.563 1.042 318.23 0.5340 9.399
1.025 298.12 0.5680 11.030 1.043 318.23 0.4680 9.263
1.023 298.15 0.5200 13.060 1.032 318.24 0.3870 8.594
1.030 298.23 0.4660 11.050 1.037 318.25 0.1900 5.562
1.032 298.31 0.3520 9.596 2.070 318.24 0.8220 10.030
1.033 298.12 0.2500 8.387 2.073 318.13 0.7110 13.550
2.070 298.14 0.8670 9.642 2.075 318.15 0.6250 16.360
2.065 298.14 0.7220 15.780 2.072 318.22 0.5390 16.070
2.075 298.21 0.6370 20.960 2.068 318.23 0.4310 16.090
2.078 298.26 0.5680 20.030 2.069 318.27 0.3020 15.210
2.062 298.15 0.3700 20.030 3.452 318.19 0.7920 23.340
2.069 298.16 0.1660 11.600 3.457 318.18 0.6850 29.660
3.452 298.15 0.7870 28.610 3.460 318.16 0.5680 32.690
3.460 298.13 0.7170 35.830 3.464 318.12 0.4170 35.380
3.461 298.23 0.6580 37.040 3.455 318.14 0.3220 31.460
3.465 298.36 0.5590 41.250 3.462 318.12 0.2680 27.760
3.448 298.16 0.4080 43.020 3.455 318.13 0.1750 20.240
3.466 298.13 0.3150 41.130 4.832 318.14 0.8240 38.690
4.837 298.15 0.8470 55.340 4.833 318.15 0.6970 53.870
4.840 298.14 0.7660 77.550 4.840 318.32 0.5620 58.150
4.842 298.18 0.5970 90.210 4.838 318.24 0.4330 61.470
4.837 298.21 0.4300 97.060 4.843 318.25 0.3350 58.780
4.840 298.23 0.3500 95.750 4.829 318.24 0.2650 54.880
4.850 298.13 0.2530 90.100 1.040 338.15 0.8170 5.642
1.040 318.14 0.7680 6.502 1.038 338.16 0.7650 6.093

Uncertainties: σ (P)/106Pa = 0.001; σ (T)/K = 0.01; σ (x1) = 0.002; σrel(HE) = 0.02 See SELF for the totality of data
Ba, L. B.; Kaliaguine, S. C.; Ramalho, R. S. Excess enthalpies of binary gaseous system ethylene + carbon dioxide by flow
calorimetry Can. J. Chem. Eng. 1979, 57, 363-366

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0249

Components: 1. C2H4, Ethene [74-85-1]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.500 P/106Pa = 11.000
T/K = 300.450 T/K = 300.450 HM/J mol-1
2800.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.50; T/K = 300.45
0.042000 210.00 0.052000 139.00 P/106Pa = 6.25; T/K = 285.85
0.081000 415.00 0.101000 300.00 P/106Pa = 11.00; T/K = 285.50
0.122000 675.00 0.151000 452.00
0.161000 954.00 0.201000 561.00
0.201000 1295.00 0.250000 659.00 2100.
0.241000 1639.00 0.301000 726.00
0.281000 1925.00 0.352000 812.00
0.321000 2148.00 0.402000 847.00
0.361000 2249.00 0.451000 830.00
0.402000 2309.00 0.503000 831.00 1400.
0.441000 2286.00 0.553000 830.00
0.481000 2200.00 0.601000 792.00
0.523000 2131.00 0.651000 730.00
0.563000 2043.00 0.703000 665.00
0.601000 1895.00 0.753000 592.00
0.643000 1762.00 0.801000 473.00 700.
0.683000 1586.00 0.851000 373.00
0.721000 1422.00 0.902000 229.00
0.763000 1224.00 0.951000 103.00
0.803000 1021.00
0.844000 768.00
0.881000 600.00 0.
0.925000 328.00 0.50
0.964000 131.00
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies of (carbon dioxide + ethene) in the liquid and near-critical regions J.
Chem. Thermodyn. 2001, 33, 775-786

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0251

Components: 1. C2H4, Ethene [74-85-1]
2. CO2, Carbon dioxide [124-38-9]
T/K = 285.85 T/K = 300.45
x1 = 0.500 x1 = 0.500 HM/J mol-1
4800.
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
T/K = 285.85; x1 = 0.500
4.840 4284.0 6.820 3056.0
5.030 4195.0 7.020 2840.0 T/K = 300.45; x1 = 0.500
5.180 4262.0 7.230 2579.0
5.390 3944.0 7.440 2327.0
5.600 4109.0 7.640 2050.0 3600.
5.810 1168.0 7.790 1922.0
7.010 873.0 8.300 1540.0
8.510 736.0 8.610 1300.0
10.000 575.0 9.030 1121.0
11.500 662.0 10.100 940.0 2400.
11.100 854.0
12.100 716.0

1200.

0.
4.0 6.1 8.2 10.3 12.4
P/106Pa
Uncertainties: σ (P)/106Pa = 0.02; σrel(HM) = 0.02
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies of (carbon dioxide + ethene) in the liquid and near-critical regions J.
Chem. Thermodyn. 2001, 33, 775-786

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0218

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.3 P/103Pa = 101.3
T/K = 354.5 T/K = 398.6 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.3; T/K = 354.5
0.391000 49.10 0.359000 32.30
0.424000 51.30 0.381000 32.00 P/103Pa = 101.3; T/K = 398.6
0.434000 51.20 0.455000 34.20
0.477000 52.10 0.473000 33.80
0.490000 51.70 0.483000 35.00 60.
0.502000 52.50 0.516000 33.50
0.524000 51.40 0.530000 35.00
0.530000 51.90 0.549000 33.70
0.585000 50.00 0.600000 31.90
0.603000 49.40 0.621000 32.30 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W.; Smith, G. R. Excess enthalpies of (carbon dioxide + cyclohexane)(g) and of (carbon dioxide
+ benzene)(g) at the pressure 101.3 kPa over the temperature range 354 K to 399 K J. Chem. Thermodyn. 1992, 24, 943-952

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0086

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H6, Benzene [71-43-2]
T/K = 498.2 T/K = 548.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
600.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 498.2; x1 = 0.500
0.418 86.000 0.411 30.000
0.651 151.000 0.596 103.000 T/K = 548.2; x1 = 0.500
0.901 228.000 0.894 161.000
1.241 357.000 1.229 253.000
1.566 508.000 1.616 358.000 450.0
2.239 580.000

300.0

150.0

0.0
0.0 0.6 1.2 1.8 2.4
P/106Pa
Uncertainties: σ (P)/106Pa = 0.00200; σ (HE)/J mol-1 = 2.00 + 0.020 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Smith, G. R. Excess enthalpies of (carbon dioxide + pentane or hexane or heptane or cyclohexane or
benzene)(g) at temperatures from 432.2 K to 573.2 K and pressures up to 2.71 MPa J. Chem. Thermodyn. 1992, 24, 481-492

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0415

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
298.15 –9.040 H°sol/103J mol-1
318.15 –8.350 –8.0

–8.3

–8.6

–8.9

–9.2
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.08 – 0.17
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0295

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
288.15 –14.390 H°sol/103J mol-1
298.15 –8.700 –8.

–10.

–12.

–14.

–16.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.30
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0396

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H8, Toluene [108-88-3]
P/106Pa = 7.600 P/106Pa = 9.500
T/K = 413.150 T/K = 307.650 HE/J mol-1
3800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.6; T/K = 470.15
0.103300 –426.00 0.109700 52.00
0.212100 –879.00 0.223500 53.00
0.244300 –959.00 0.256900 50.00
0.287600 –1129.00 0.301500 43.00
0.309400 a –1055.00 0.323900 37.00 1900.
0.392200 a –723.00 0.408300 0.00
0.414200 a –659.00 0.430500 a –42.00
0.533900 a –189.00 0.550600 a –151.00
0.626300 a 160.00 0.641800 a –265.00
0.696200 a 457.00 0.710100 a –366.00 0.
0.754200 a 715.00 0.766400 a –428.00
0.804400 a 901.00 0.814800 –471.00
0.838000 a 1029.00 0.846900 –496.00
0.900500 a 1258.00 0.889900 –510.00
0.933200 1209.00 0.930500 –486.00
0.940100 1058.00 0.943800 –467.00 –1900.
0.968400 560.00 0.970400 –336.00
0.976800 433.00 P/106Pa = 9.5; T/K = 307.65
P/106Pa = 7.6; T/K = 413.15
P/106Pa = 7.6; T/K = 358.15
–3800.
0.50
x1
Uncertainties: σ (x1) = 0.0002; σ (HE)/J mol-1
= 2.0 + 0.02 |HE/J mol-1|
a Two-phase region; See SELF for the totality of data
Mathonat, C.; Hynek, V.; Majer, V.; Grolier, J.-P. E. Measurements of excess enthalpies at high temperature and pressure
using a new type of mixing unit J. Solution Chem. 1994, 23, 1161-1182

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0094

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H8, Toluene [108-88-3]
P/106Pa = 7.500 P/106Pa = 10.600
T/K = 298.150 T/K = 298.150 HE/J mol-1
450.
x1 HE/J mol-1 x1 HE/J mol-1
0.115000 100.00 0.131000 176.00
0.182000 140.00 0.221000 250.00
0.207000 159.00 0.321000 324.00
0.312000 191.00 0.368000 359.00
0.373000 180.00 0.421000 375.00 0.
0.394000 179.00 0.454000 389.00
0.479000 149.00 0.474000 388.00
0.516000 137.00 0.484000 397.00
0.538000 81.00 0.496000 382.00
0.576000 59.00 0.523000 370.00 –450.
0.577000 24.00 0.548000 367.00
0.651000 –26.00 0.577000 352.00
0.693000 –108.00 0.623000 319.00
0.731000 –111.00 0.703000 242.00
0.743000 –140.00 0.800000 134.00
0.762000 –169.00 0.834000 82.00 –900.
0.793000 –219.00 0.869000 36.00 P/106Pa = 7.5; T/K = 298.15
0.820000 –263.00 0.897000 0.00
0.867000 –303.00 0.908000 –23.00 P/106Pa = 10.6; T/K = 298.15
0.888000 –310.00 0.941000 –38.00 P/106Pa = 7.6; T/K = 304.10
0.889000 –291.00 0.962000 –48.00
0.895000 –308.00 0.986000 –28.00 –1350.
0.896000 –301.00 0.50
0.908000 –268.00
x1
Uncertainties: σ (x1) = 0.002; σ (HE)/J mol-1
= 2.0 + 0.02 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies and excess molar volumes of {xCO2 + (1-x)C6H5CH3} at 298.15,
304.10, and 308.15 K from 7.5 to 12.6 MPa J. Chem. Thermodyn. 1987, 19, 845-856

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0136

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H8, Toluene [108-88-3]
P/106Pa = 9.500 P/106Pa = 10.600
T/K = 308.150 T/K = 308.150 HM/J mol-1
200.
x1 HM/J mol-1 x1 HM/J mol-1
0.098000 34.00 0.190000 104.00
0.223000 38.00 0.195000 110.00
0.232000 39.00 0.302000 136.00
0.259000 41.00 0.390000 113.00
0.298000 41.00 0.446000 97.00 0.
0.390000 0.00 0.622000 –35.00
0.451000 –75.00 0.691000 –137.00
0.522000 –115.00 0.714000 –179.00
0.545000 –165.00 0.748000 –208.00
0.595000 –207.00 0.777000 –243.00 –200.
0.650000 –311.00 0.787000 –277.00
0.706000 –331.00 0.834000 –344.00
0.753000 –423.00 0.841000 –319.00
0.837000 –520.00 0.842000 –323.00
0.884000 –550.00 0.848000 –330.00
0.889000 –547.00 0.857000 –324.00 –400.
0.903000 –543.00 0.860000 –338.00
0.916000 –530.00 0.916000 –360.00
0.936000 –295.00 P/106Pa = 9.5; T/K = 308.15
0.937000 –310.00 P/106Pa = 10.6; T/K = 308.15
–600.
0.50
x1
Uncertainties: σ (x1) = 0.002; σ (HM)/J mol-1
= 2.0 + 0.02 |HM/J mol-1|
Wormald, C. J.; Eyears, J. M. Excess molar enthalpies and excess molar volumes of {xCO2 + (1-x)C6H5CH3} at 298.15,
304.10, and 308.15 K from 7.5 to 12.6 MPa J. Chem. Thermodyn. 1987, 19, 845-856

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0275

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H8, Toluene [108-88-3]
P/106Pa = 8.010 P/106Pa = 13.880
T/K = 573.150 T/K = 358.150 HM/J mol-1
8000.
x1 HM/J mol-1 x1 HM/J mol-1
0.036600 438.00 0.079600 –172.00
0.106200 1700.00 0.116900 –299.00
0.171400 2850.00 0.187300 –493.00
0.232600 4010.00 0.252500 –649.00
0.261800 4700.00 0.312900 –832.00 4000.
0.317600 5920.00 0.369100 –1020.00
0.344300 6140.00 0.421600 –1150.00
0.370200 6690.00 0.470600 –1320.00
0.395400 6780.00 0.516600 –1440.00
0.443800 6910.00 0.559800 –1590.00 0.
0.467000 6880.00 0.600400 –1700.00
0.489200 7060.00 0.638600 –1810.00
0.511500 6890.00 0.674700 –1910.00
0.613300 6050.00 0.674700 –1880.00
0.650600 5530.00 0.708900 –1960.00
0.686100 5040.00 0.741300 –1970.00 –4000.
0.752300 4210.00 0.771900 –1980.00
0.812900 3220.00 0.801100 –1940.00 P/106Pa = 6.98; T/K = 308.15
0.841200 2770.00 0.828800 –1900.00
0.894500 1910.00 0.855200 –1760.00 P/106Pa = 8.01; T/K = 573.15
0.943700 1060.00 0.880300 –1540.00 P/106Pa = 14.91; T/K = 358.15
0.989200 241.00 0.904300 –1330.00 –8000.
0.927200 –962.00 0.50
0.949200 –644.00
x1
Uncertainties: σ (x1) = 0.00050; σrel
(HM) = 0.02 See SELF for the totality of data
Cordray, D. R.; Christensen, J. J.; Izatt, R. M. The excess enthalpies of (carbon dioxide + toluene) at 308.15, 358.15, and
573.15 K from 6.98 to 16.63 MPa J. Chem. Thermodyn. 1986, 18, 647-656

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0179

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H8, Toluene [108-88-3]
P/106Pa = 10.64 P/106Pa = 10.64
T/K = 470.15 T/K = 470.15 HM/J mol-1
3600.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.600; T/K = 470.15
0.033800 –39.00 0.923900 1370.00
0.112000 –136.00 0.923900 1370.00
0.180100 –226.00 0.946800 995.00
0.243400 –259.00 0.968700 616.00
0.302600 –232.00 0.989800 210.00 2400.
0.357900 a –53.00
0.409800 a 203.00
0.458600 a 535.00
0.504500 a 794.00
0.547800 a 1050.00 1200.
0.588700 a 1310.00
0.627400 a 1520.00
0.664000 a 1720.00
0.698800 a 1900.00
0.731900 a 2110.00
0.763300 a 2370.00 0.
0.793200 a 2490.00
0.793200 a 2500.00
0.821800 2710.00 P/106Pa = 10.640; T/K = 470.15
0.835600 2580.00 P/106Pa = 12.670; T/K = 470.15
0.849100 2380.00
0.875100 2140.00 –1200.
0.900000 1750.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 0.50 + 0.020 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Zebolsky, D. M.; Izatt, R. M. The excess enthalpies of (carbon dioxide + toluene) at 470.15 and 573.15 K
from 7.60 to 12.67 MPa J. Chem. Thermodyn. 1985, 17, 1-10

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0183

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H8, Toluene [108-88-3]
P/106Pa = 10.64 P/106Pa = 10.64
T/K = 358.15 T/K = 358.15 HM/J mol-1
900.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.60; T/K = 358.15
0.038900 –154.00 0.958000 a 30.00 P/106Pa = 10.64; T/K = 358.15
0.094600 –357.00 0.958000 30.00 P/106Pa = 12.67; T/K = 358.15
0.147200 –581.00 0.974200 84.00
0.197000 –778.00 0.989800 37.00
0.244300 –988.00 0.
0.289100 –1206.00
0.331700 –1397.00
0.372300 –1567.00
0.410900 –1742.00
0.447800 –1891.00 –900.
0.483000 –1991.00
0.516700 –2203.00
0.548900 –2311.00
0.579800 –2396.00
0.609400 –2497.00
0.637800 –2484.00 –1800.
0.665000 a –2324.00
0.716500 a –1925.00
0.764100 a –1551.00
0.808400 a –1157.00
0.849600 a –835.00
0.888200 a –508.00 –2700.
0.924200 a –224.00 0.50
x1
Uncertainties: σ (x1) = 0.0002; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Pando, C.; Renuncio, J. A. R.; Schofield, R. S.; Izatt, R. M.; Christensen, J. J. The excess enthalpies of (carbon dioxide +
toluene) at 308.15, 385.15, and 413.15 K from 7.60 to 12.67 MPa J. Chem. Thermodyn. 1983, 15, 747-755

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0278

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H8, Toluene [108-88-3]
P/106Pa = 12.670 P/106Pa = 14.910
T/K = 508.150 T/K = 413.150 HM/J mol-1
9000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.60; T/K = 508.15
0.114800 49.30 0.080300 –151.00
0.184100 138.00 0.118000 –269.00 P/106Pa = 14.91; T/K = 390.15
0.248500 240.00 0.188900 –427.00 P/106Pa = 15.60; T/K = 470.15
0.308400 470.00 0.254400 –641.00
0.364800 847.00 0.315100 –733.00 6000. P/106Pa = 17.50; T/K = 413.15
0.416500 a 1210.00 0.371500 –872.00
0.465400 a 1640.00 0.424100 –946.00
0.511400 a 1960.00 0.473200 –1070.00
0.554600 a 2350.00 0.562300 –1110.00
0.595300 a 2720.00 0.602800 –1090.00 3000.
0.633800 a 3090.00 0.641000 a –977.00
0.670100 3310.00 0.677000 a –806.00
0.704500 3360.00 0.711000 a –558.00
0.737200 3270.00 0.743200 a –330.00
0.768200 3090.00 0.758700 a –251.00
0.797700 2790.00 0.773700 a –149.00 0.
0.825800 2600.00 0.802700 a –8.02
0.852500 2290.00 0.830200 a 166.00
0.878100 1940.00 0.856400 a 305.00
0.902500 1620.00 0.893400 511.00
0.925800 1250.00 0.905200 532.00
0.969500 549.00 0.927900 487.00 –3000.
0.949700 403.00 0.50
0.970400 287.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 0.50 + 0.020 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Cordray, D. R.; Christensen, J. J.; Izatt, R. M.; Oscarson, J. L. The excess enthalpies of (carbon dioxide + toluene) at 390.15,
413.15, 470.15, and 508.15 K from 7.60 to 17.50 MPa J. Chem. Thermodyn. 1988, 20, 877-888

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0305

Components: 1. CO2, Carbon dioxide [124-38-9]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
288.15 –13.340 H°sol/103J mol-1
298.15 –9.640 –8.

–10.

–12.

–14.

–16.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10–0.80
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0421

Components: 1. CO2, Carbon dioxide [124-38-9]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
298.15 –9.420 H°sol/103J mol-1
318.15 –8.630 –8.4

–8.7

–9.0

–9.3

–9.6
298. 308. 318.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.09 – 0.16
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0377

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H10O2, 2,5-Dioxahexane [110-71-4]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 298.150 T/K = 298.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 12.5; T/K = 298.15
0.086600 –332.60 0.088500 –250.30 P/106Pa = 10.0; T/K = 298.15
0.165400 –655.80 0.168800 –540.90 P/106Pa = 7.5; T/K = 298.15
0.237500 –927.50 0.242000 –775.30
0.306200 –1152.90 0.308900 –946.00
0.364600 –1342.40 0.370300 –1094.00 –500.
0.420900 –1514.00 0.426900 –1198.60
0.473000 –1643.80 0.479200 –1263.20
0.521500 –1699.90 0.527700 –1341.20
0.566700 –1775.80 0.572800 –1380.20
0.608900 –1804.30 0.614800 –1402.90 –1000.
0.648500 –1876.30 0.654100 –1408.70
0.685500 –1863.80 0.690800 –1395.20
0.720400 –1865.90 0.725300 –1354.50
0.753200 –1826.20 0.757600 –1309.60
0.784200 –1767.40 0.788300 –1244.30
0.813400 –1672.70 0.817100 –1170.90 –1500.
0.841100 –1572.80 0.844400 –1086.90
0.867400 –1451.30 0.870200 –977.50
0.892300 –1296.00 0.894600 –861.40
0.916000 –1130.20 0.917800 –716.30
0.938500 –953.70 0.939900 –561.40
0.960000 –679.10 0.960900 –381.10 –2000.
0.980500 –437.80 0.980900 –184.40 0.50
x1
Uncertainties: σ (x1) = 0.00075; σrel
(HE) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess molar enthalpies of (carbon dioxide + ethylene glycol dimethyl ether or 2-methoxyethyl
ether) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn. 1996, 28
, 577-587

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0380

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H10O2, 2,5-Dioxahexane [110-71-4]
P/106Pa = 7.500 P/106Pa = 10.000
T/K = 308.150 T/K = 308.150 HM/J mol-1
0.
x1 HM/J mol-1 x1 HM/J mol-1
0.084800 –878.00 0.104700 –273.60
0.162000 –1528.60 0.168100 –553.70
0.232600 –2029.00 0.226900 –758.30
0.297400 –2562.70 0.281700 –970.90
0.357200 –3057.00 0.332900 –1134.00 –1700.
0.412400 –3482.30 0.380700 –1275.60
0.463600 –3860.90 0.425600 –1400.60
0.511200 –4130.90 0.467700 –1508.50
0.555600 –4349.60 0.507400 –1595.70
0.597000 –4707.10 0.544800 –1651.50 –3400.
0.635900 –4882.70 0.580100 –1693.60
0.672300 –5104.10 0.613500 –1734.50
0.709300 –5192.90 0.645200 –1748.00
0.744000 –5176.00 0.689700 –1754.60
0.776600 –5210.80 0.756800 –1711.20
0.807300 –5456.30 0.816300 –1582.50 –5100.
0.836200 –5274.80 0.843700 –1499.50
0.863500 –5278.70 0.869600 –1392.70
0.889200 –5290.90 0.894100 –1251.90 P/106Pa = 12.5; T/K = 308.15
0.913800 –4860.60 0.917400 –1090.10 P/106Pa = 7.5; T/K = 308.15
0.937000 –3841.30 0.939600 –871.60
0.959100 –2480.70 0.960700 –600.20 –6800.
0.980300 –1031.60 0.980800 –280.10 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess molar enthalpies of (carbon dioxide + ethylene glycol dimethyl ether or 2-methoxyethyl
ether) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn. 1996, 28
, 577-587

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0378

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H14O3, 2,5,8-Trioxanonane [111-96-6]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 298.150 T/K = 298.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 298.15
0.115500 –219.10 0.119100 –423.60 P/106Pa = 10.0; T/K = 298.15
0.214500 –470.60 0.220500 –747.10 P/106Pa = 12.5; T/K = 298.15
0.300200 –835.10 0.307700 –1009.10
0.375300 –1059.70 0.383500 –1197.60
0.441500 –1337.40 0.450100 –1357.00 –550.
0.500300 –1536.60 0.509100 –1496.00
0.552900 –1663.70 0.561600 –1566.60
0.600300 –1794.80 0.608700 –1613.60
0.643100 –1885.90 0.651100 –1639.70
0.682100 –1907.70 0.689600 –1616.20 –1100.
0.717600 –1953.00 0.724700 –1589.10
0.750200 –1931.00 0.756700 –1555.80
0.780200 –1930.90 0.786200 –1497.90
0.807900 –1876.40 0.813300 –1430.80
0.833500 –1810.00 0.838300 –1345.50
0.857300 –1729.10 0.861500 –1236.00 –1650.
0.879400 –1637.10 0.883100 –1152.60
0.900100 –1496.80 0.903200 –1015.80
0.919400 –1342.20 0.922000 –860.60
0.937600 –1177.60 0.939600 –710.00
0.954600 –1000.60 0.956100 –545.50
0.970600 –694.60 0.971600 –382.00 –2200.
0.985800 –380.50 0.986200 –192.40 0.50
x1
Uncertainties: σ (x1) = 0.00050; σrel
(HE) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess molar enthalpies of (carbon dioxide + ethylene glycol dimethyl ether or 2-methoxyethyl
ether) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn. 1996, 28
, 577-587

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0379

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H14O3, 2,5,8-Trioxanonane [111-96-6]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 308.150 T/K = 308.150 HM/J mol-1
0.
x1 HM/J mol-1 x1 HM/J mol-1
0.096000 –480.30 0.139400 –237.20
0.180200 –1088.20 0.218700 –528.90
0.254900 –1827.70 0.289000 –800.50
0.321400 –2126.20 0.352000 –1030.10
0.381100 –2394.80 0.408600 –1168.30 –1700.
0.434900 –2927.10 0.459900 –1350.20
0.483700 –3112.60 0.506400 –1492.20
0.528200 –3738.50 0.559000 –1591.70
0.568800 –3925.70 0.606200 –1670.40
0.620300 –4423.30 0.648700 –1724.30 –3400.
0.666200 –4854.30 0.687400 –1758.20
0.707500 –4882.90 0.754800 –1703.30
0.744800 –5122.10 0.811700 –1594.20
0.778700 –5087.00 0.860300 –1431.00
0.809600 –5296.40 0.902200 –1202.30
0.837800 –5256.40 0.921200 –1070.50 –5100.
0.863900 –5144.40 0.939000 –914.80
0.887800 –5127.10 0.955700 –737.00
0.910000 –4978.60 0.971300 –528.00 P/106Pa = 7.5; T/K = 308.15
0.930600 –5177.00 0.986100 –290.00 P/106Pa = 12.5; T/K = 308.15
0.949700 –4715.90
0.967600 –4118.60 –6800.
0.984400 –3015.30 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess molar enthalpies of (carbon dioxide + ethylene glycol dimethyl ether or 2-methoxyethyl
ether) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn. 1996, 28
, 577-587

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0294

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H8O, Oxolane [109-99-9]
T/K H°sol/103J mol-1
288.15 –23.850 H°sol/103J mol-1
298.15 –17.020 –16.

–18.

–20.

–22.

–24.
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.30–0.40
Cone, J.; Smith, L. E. S.; Van Hook, W. A. Enthalpies of solution of gases in liquids. The calorimeter and measurements on
lower hydrocarbons and CO2 in C6H6, CCl4 and THF J. Chem. Thermodyn. 1979, 11, 277-285

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0111

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H8O2, 1,4-Dioxane [123-91-1]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
58.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 54.70
383.20 50.90
393.20 45.50
403.20 43.70
413.20 38.70 51.
423.20 36.70
433.20 33.80

44.

37.

30.
385. 405. 425.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Johnson, P. W. Quadrupole coupling in (carbon dioxide + dioxane)(g). The excess molar enthalpy and second
cross-coefficient of (dioxane + carbon dioxide or propane) (g) J. Chem. Thermodyn. 1999, 31, 1085-1091

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0431

Components: 1. CH4O, Methanol [67-56-1]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.500 P/106Pa = 12.600
T/K = 298.150 T/K = 298.150 HE/J mol-1
230.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 298.15
0.062000 –39.00 0.060000 151.00 P/106Pa = 10.6; T/K = 298.15
0.121000 –172.50 0.118000 113.00 P/106Pa = 12.6; T/K = 298.15
0.235000 –397.90 0.230000 –54.80
0.344000 –542.40 0.337000 –206.50
0.449000 –640.60 0.442000 –331.30 0.
0.647000 –654.20 0.542000 –465.50
0.740000 –555.60 0.640000 –511.60
0.830000 –398.20 0.734000 –456.60
0.916000 –202.80 0.825000 –306.70
0.958000 –111.20 0.914000 –145.50 –230.
0.957000 –70.30

–460.

–690.
0.50
x1
Uncertainties: σ (x1) = 0.0010; σ (HE)/J mol-1
= 3.0 + 0.030 |HE/J mol-1| See SELF for the totality of data
Hauser, R. A.; Zhao, J. P.; Tremaine, P. R.; Mather, A. E. Excess molar enthalpies of six (carbon dioxide + a polar solvent)
mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa J. Chem. Thermodyn. 1996, 28
, 1303-1317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0446

Components: 1. CH4O, Methanol [67-56-1]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.500 P/106Pa = 7.700
T/K = 308.150 T/K = 308.150 HE/J mol-1
1500.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.50; T/K = 308.15
0.027000 –1524.84 0.033700 –839.63
0.040300 –2276.83 0.066700 –1488.57 P/106Pa = 7.70; T/K = 308.15
0.053600 –2895.51 0.131200 –2367.67 P/106Pa = 7.90; T/K = 308.15
0.066700 –3319.95 0.193400 –2855.03
0.131200 –4280.12 0.253500 –3010.30 0.
0.193400 –4429.59 0.311700 –2887.35
0.253500 –4308.82 0.368000 –2656.80
0.311700 –4200.77 0.422500 –2489.24
0.368000 –3918.93 0.475300 –2266.53
0.422500 –3648.10 0.526400 –2038.11 –1500.
0.475300 –3428.23 0.576000 –1656.07
0.526400 –3129.42 0.624100 –1384.03
0.576000 –2893.18 0.670800 –1083.07
0.624100 –2592.18 0.716200 –803.45
0.670800 –2324.38 0.760200 –533.39
0.716200 –1996.16 0.803000 –277.63 –3000.
0.760200 –1708.59 0.844600 –199.62
0.803000 –1452.79
0.844600 –1236.58
0.885000 –872.37
0.924400 –578.19
–4500.
0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 10.00 + 0.008 |HE/J mol-1| See SELF for the totality of data
Dai, W.; Ochi, K.; Kurihara, K.; Kojima, K.; Hongo, M. Measurement and correlation of excess enthalpy for the system (CO2
+ CH3OH) containing supercritical carbon dioxide Netsu Bussei 1998, 12, 64-69

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0005

Components: 1. CH4O, Methanol [67-56-1]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.5 P/106Pa = 7.0
T/K = 303.150 T/K = 308.150 HE/J mol-1
1500.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 6.50; T/K = 303.150
0.065800 –141.00 0.066500 91.00
0.129400 –278.00 0.130700 –721.00 P/106Pa = 7.50; T/K = 303.150
0.191000 –429.00 0.180500 –1408.00
0.250600 –617.00 0.192800 –1704.00
0.308400 –770.00 0.252800 –2572.00 0.
0.364400 –855.00 0.299400 –3142.00
0.418700 –893.00 0.367100 –3779.00
0.471400 –919.00 0.410800 –3794.00
0.522600 –917.00 0.474300 –3628.00
0.572300 –914.00 0.525500 –3418.00 –1500.
0.620500 –902.00 0.575100 –3229.00
0.667400 –857.00 0.623200 –2981.00
0.713000 –788.00 0.670000 –2669.00
0.757400 –720.00 0.715400 –2347.00
0.800500 –623.00 0.759500 –2051.00
0.842600 –521.00 0.802400 –1732.00 –3000.
0.883500 –409.00 0.844100 –1384.00
0.923300 –285.00 0.884600 –1038.00
0.942900 –220.00 0.924100 –698.00
0.962200 –115.00 0.962600 –294.00
0.981200 –25.00 P/106Pa = 7.00; T/K = 308.150
–4500.
0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 10.00 + 0.008 |HE/J mol-1| See SELF for the totality of data
Dai, W.; Kojima, K.; Ochi, K. Measurement and correlation of excess molar enthalpies of CO2 + CH3OH system in the vicinity
of critical point of carbon dioxide J. Chem. Eng. Data 1999, 44, 161-164

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0272

Components: 1. CH4O, Methanol [67-56-1]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 523.150 T/K = 573.150 HE/J mol-1
2800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 523.15
0.084400 532.00 0.025800 146.00 P/106Pa = 12.5; T/K = 573.15
0.138300 752.00 0.076500 380.00
0.164600 931.00 0.126000 673.00
0.190400 1150.00 0.174300 910.00
0.240800 1440.00 0.221600 1170.00 2100.
0.289500 1490.00 0.267800 1310.00
0.313300 1660.00 0.290600 1440.00
0.382400 2000.00 0.313000 1600.00
0.404700 2110.00 0.335300 1640.00
0.426700 2160.00 0.357300 1800.00 1400.
0.469600 2370.00 0.379000 1780.00
0.490600 2400.00 0.400500 1800.00
0.531600 2410.00 0.442900 2010.00
0.551700 2380.00 0.484300 2200.00
0.590900 2350.00 0.524900 2220.00
0.629100 2340.00 0.641700 2300.00 700.
0.666100 2260.00 0.679100 2240.00
0.702100 2270.00 0.751600 2080.00
0.737100 2180.00 0.786800 1910.00
0.787900 1880.00 0.855200 1560.00
0.804400 1830.00 0.871900 1480.00
0.898700 954.00 0.888500 1280.00 0.
0.928600 656.00 0.953100 716.00 0.50
0.957700 412.00 0.984500 224.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE)= 0.02 See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Oscarson, J. L.; Izatt, R. M. The excess enthalpies of four (carbon dioxide + an alkanol)
mixtures from 308.15 to 573.15 K at 7.50 to 12.50 MPa J. Chem. Thermodyn. 1988, 20, 867-875

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0227

Components: 1. CO2, Carbon dioxide [124-38-9]
2. CH4O, Methanol [67-56-1]
P/106Pa = 7.500 P/106Pa = 7.500
T/K = 308.15 T/K = 308.15 HM/J mol-1
15000.
x1 HM/J mol-1 x1 HM/J mol-1 P/106Pa = 7.5; T/K = 308.15
0.028000 –286.00 0.861700 –4330.00 P/106Pa = 7.5; T/K = 473.15
0.042300 –377.00 0.915600 –3800.00 P/106Pa = 12.5; T/K = 308.15
0.071400 –660.00 0.943200 –2840.00
0.101300 –809.00
0.131900 –1130.00 10000.
0.163300 –1290.00
0.195600 –1600.00
0.222800 –1820.00
0.262900 –2010.00
0.297900 –2180.00 5000.
0.333900 –2470.00
0.370900 –2630.00
0.409100 –3020.00
0.448300 –3200.00
0.488700 –3440.00 P/106Pa = 12.5; T/K = 473.15
0.530400 –3620.00 0.
0.573300 –3790.00
0.617600 –4010.00
0.663300 –4290.00
0.663300 –4130.00
0.759200 –4450.00
0.835400 –4450.00 –5000.
0.835400 –4400.00 0.50
0.861700 –4330.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Oscarson, J. L.; Izatt, R. M. The excess enthalpies of four (carbon dioxide + an alkanol)
mixtures from 308.15 to 573.15 K at 7.50 to 12.50 MPa J. Chem. Thermodyn. 1988, 20, 867-875

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0432

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 298.150 T/K = 298.150 HE/J mol-1
240.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 298.15
0.050800 –78.80 0.052600 –30.20 P/106Pa = 10.0; T/K = 298.15
0.100600 –131.90 0.104100 –43.40 P/106Pa = 12.5; T/K = 298.15
0.149500 –171.70 0.154300 –50.30
0.197500 –200.00 0.203500 –49.90
0.244700 –214.20 0.251600 –44.50 120.
0.290900 –220.60 0.298700 –34.70
0.336300 –218.90 0.344700 –22.10
0.381000 –215.40 0.389800 –7.00
0.424800 –195.50 0.433900 10.70
0.467800 –179.60 0.477100 29.60 0.
0.510200 –159.70 0.519500 47.10
0.551700 –139.00 0.560900 62.90
0.592600 –117.30 0.601600 77.90
0.632800 –92.40 0.641400 90.00
0.672300 –67.90 0.680400 103.40
0.711100 –41.70 0.718700 118.90 –120.
0.749300 –15.40 0.756200 129.30
0.786900 11.90 0.793100 137.50
0.823900 38.10 0.829200 141.60
0.860200 60.50 0.864600 143.20
0.896000 80.50 0.899400 138.20
0.931200 89.00 0.933600 117.40 –240.
0.965900 84.50 0.967100 74.20 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HE)/J mol-1
= 3.0 + 0.030 |HE/J mol-1| See SELF for the totality of data
Hauser, R. A.; Zhao, J. P.; Tremaine, P. R.; Mather, A. E. Excess molar enthalpies of six (carbon dioxide + a polar solvent)
mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa J. Chem. Thermodyn. 1996, 28
, 1303-1317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0436

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 10.000 P/106Pa = 12.500
T/K = 308.150 T/K = 308.150 HM/J mol-1
1500.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 308.15
0.050800 –72.00 0.052600 –63.50
0.100600 –150.40 0.104100 –127.50 P/106Pa = 10.0; T/K = 308.15
0.149500 –206.30 0.154300 –146.20 P/106Pa = 12.5; T/K = 308.15
0.197500 –244.50 0.203500 –158.20
0.244700 –267.40 0.251600 –161.60 0.
0.290900 –282.10 0.298700 –149.90
0.336300 –290.00 0.344700 –136.20
0.381000 –289.80 0.389800 –113.30
0.424800 –289.40 0.433900 –87.80
0.467800 –284.80 0.477100 –57.10 –1500.
0.510200 –275.00 0.519400 –31.50
0.551700 –257.50 0.560900 8.70
0.592600 –237.10 0.601600 39.00
0.632800 –213.30 0.641400 69.90
0.672300 –192.90 0.680400 96.40
0.711100 –169.10 0.718700 125.50 –3000.
0.749300 –142.60 0.756200 151.80
0.786900 –115.00 0.793100 173.30
0.823900 –86.70 0.829200 192.00
0.860200 –59.50 0.864600 206.70
0.896000 –23.40 0.899400 214.70
0.931200 6.40 0.933600 201.60 –4500.
0.965900 22.30 0.967100 144.30 0.50
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 3.0 + 0.030 |HM/J mol-1| See SELF for the totality of data
Hauser, R. A.; Zhao, J. P.; Tremaine, P. R.; Mather, A. E. Excess molar enthalpies of six (carbon dioxide + a polar solvent)
mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa J. Chem. Thermodyn. 1996, 28
, 1303-1317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0277

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 5.000 P/106Pa = 12.500
T/K = 325.150 T/K = 325.150 HM/J mol-1
6000.
x1 HM/J mol-1 x1 HM/J mol-1
0.042000 –272.00 0.064500 –103.00
0.082800 –650.00 0.107200 –167.00
0.112600 –882.00 0.149500 –218.00
0.112600 –817.00 0.191700 –274.00
0.129900 –1050.00 0.233500 –319.00 3000.
0.149100 –1230.00 0.275100 –369.00
0.194800 –1480.00 0.316400 –386.00
0.222300 –1690.00 0.357500 –406.00
0.237500 –1820.00 0.398300 –433.00
0.253800 a–1900.00 0.438900 –466.00 0.
0.271300 a–1850.00 0.479200 –481.00
0.310600 a–1760.00 0.519300 –493.00
0.332800 a–1680.00 0.559100 –492.00
0.332800 a–1680.00 0.598700 –489.00
0.412100 a–1480.00 0.638000 –481.00
0.443900 a–1390.00 0.677100 –480.00 –3000.
0.518400 a–1150.00 0.715900 –469.00
0.562400 a–1020.00 0.754600 –451.00 P/106Pa = 7.50; T/K = 308.15
0.668300 a –694.00 0.792900 –419.00 P/106Pa = 7.50; T/K = 373.15
0.733000 a –515.00 0.831100 –368.00 P/106Pa = 10.00; T/K = 413.15
0.769000 a –423.00 0.869000 –321.00 P/106Pa = 12.50; T/K = 473.15
0.807900 a –274.00 0.869000 –312.00 –6000.
0.895700 a –17.90 0.906700 –236.00 0.50
0.945500 a 139.00 0.944200 –166.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 0.50 + 0.020 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Cordray, D. R.; Izatt, R. M.; Christensen, J. J.; Oscarson, J. L. The excess enthalpies of (carbon dioxide + ethanol) at 308.15,
325.15, 373.15, 413.15, and 473.15 K from 5.00 to 14.91 MPa J. Chem. Thermodyn. 1988, 20, 655-663

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0269

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C3H8O, Propan-1-ol [71-23-8]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 473.150 T/K = 473.150 HM/J mol-1
9000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 473.15
0.075500 297.00 0.083500 304.00
0.124400 567.00 0.136800 509.00
0.172400 979.00 0.188500 843.00
0.219200 1560.00 0.238500 1100.00
0.265100 2270.00 0.286900 1370.00 6000.
0.310100 3260.00 0.333900 1790.00
0.354100 3750.00 0.379400 2350.00
0.397200 4560.00 0.423600 2990.00
0.480900 5880.00 0.466500 3430.00
0.521500 6290.00 0.508100 3890.00 3000.
0.561300 6980.00 0.548600 4350.00
0.561300 7130.00 0.626100 4860.00
0.600300 7250.00 0.663300 4840.00
0.638500 7550.00 0.699500 4770.00
0.712900 6750.00 0.717200 4630.00
0.749100 5940.00 0.734700 4420.00 0.
0.784500 5140.00 0.769000 4100.00
0.819300 4350.00 0.802400 3720.00 P/106Pa = 12.5; T/K = 473.15
0.853600 3570.00 0.818800 3560.00
0.920100 2110.00 0.834900 3100.00 P/106Pa = 12.5; T/K = 308.15
0.952500 1210.00 0.866700 2940.00 P/106Pa = 7.5; T/K = 308.15
0.897600 2160.00 –3000.
0.957200 961.00 0.50
0.971600 635.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Oscarson, J. L.; Izatt, R. M. The excess enthalpies of four (carbon dioxide + an alkanol)
mixtures from 308.15 to 573.15 K at 7.50 to 12.50 MPa J. Chem. Thermodyn. 1988, 20, 867-875

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0270

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H10O, Butan-1-ol [71-36-3]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 473.150 T/K = 473.150 HM/J mol-1
7000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 308.15
0.061300 239.00 0.067900 167.00
0.203200 788.00 0.162600 289.00
0.255900 993.00 0.221500 517.00
0.306500 1500.00 0.277300 691.00
0.355000 1930.00 0.330200 868.00 3500.
0.401700 2350.00 0.380500 1180.00
0.424400 2640.00 0.428300 1510.00
0.446600 2830.00 0.473800 1800.00
0.489900 3220.00 0.517200 2190.00
0.531500 3670.00 0.558600 2440.00 0.
0.531500 3670.00 0.598200 2750.00
0.571700 4000.00 0.636100 3010.00
0.591200 4160.00 0.672300 3330.00
0.629300 4670.00 0.707100 3480.00
0.647800 4880.00 0.740400 3640.00
0.683900 5150.00 0.772400 3580.00 –3500.
0.718800 5450.00 0.803100 3450.00 P/106Pa = 7.5; T/K = 473.15
0.752600 5560.00 0.832600 3220.00
0.785200 5400.00 0.847000 3140.00 P/106Pa = 12.5; T/K = 308.15
0.801100 5200.00 0.888400 2350.00 P/106Pa = 12.5; T/K = 473.15
0.847400 4400.00 0.901700 2230.00
0.877100 3320.00 0.927600 1630.00 –7000.
0.905900 2580.00 0.940200 1370.00 0.50
0.960900 1050.00 0.976700 516.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Oscarson, J. L.; Izatt, R. M. The excess enthalpies of four (carbon dioxide + an alkanol)
mixtures from 308.15 to 573.15 K at 7.50 to 12.50 MPa J. Chem. Thermodyn. 1988, 20, 867-875

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0271

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C8H18O, Octan-1-ol [111-87-5]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 473.150 T/K = 473.150 HM/J mol-1
1500.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 473.15
0.101100 –126.00 0.058000 –102.00
0.147100 –160.00 0.161500 –135.00 P/106Pa = 12.5; T/K = 308.15
0.190200 –201.00 0.251100 –149.00 P/106Pa = 12.5; T/K = 473.15
0.269200 –214.00 0.364900 –139.00
0.305500 –158.00 0.398400 –106.00 1000.
0.372300 a –19.20 0.459700 –46.30
0.487000 a 249.00 0.514600 63.00
0.536600 a 359.00 0.563900 143.00
0.581900 a 458.00 0.649000 359.00
0.623500 a 540.00 0.686000 469.00 500.
0.661800 a 644.00 0.719900 545.00
0.697100 a 719.00 0.751000 612.00
0.729900 a 806.00 0.779800 715.00
0.788600 a 941.00 0.806400 755.00
0.827700 a 1040.00 0.854100 889.00
0.863100 a 1110.00 0.875600 936.00 0.
0.884900 a 1190.00 0.914500 1020.00
0.915300 a 1280.00 0.932200 1040.00
0.924900 a 1280.00 0.940600 1020.00
0.943200 1290.00 0.956800 999.00
0.960500 1240.00 0.964500 943.00
0.968800 1170.00 0.972000 823.00 –500.
0.976900 802.00 0.979300 593.00 0.50
0.984800 571.00 0.986400 384.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 2.0 + 0.020 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Cordray, D. R.; Oscarson, J. L.; Izatt, R. M. The excess enthalpies of four (carbon dioxide + an alkanol)
mixtures from 308.15 to 573.15 K at 7.50 to 12.50 MPa J. Chem. Thermodyn. 1988, 20, 867-875

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0002

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C3H8O, Propan-2-ol [67-63-0]
P/106Pa = 8.50 P/106Pa = 7.50
T/K = 303.150 T/K = 308.150 HE/J mol-1
1500.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 8.50; T/K = 303.150
0.070500 93.00 0.069300 –186.00
0.138100 254.00 0.135800 –395.00 P/106Pa = 7.50; T/K = 303.150
0.202800 368.00 0.199700 –599.00
0.264900 463.00 0.261100 –831.00
0.324600 526.00 0.320300 –1063.00 0.
0.381900 573.00 0.377300 –1315.00
0.437000 601.00 0.432200 –1594.00
0.490100 614.00 0.485200 –1846.00
0.541200 611.00 0.536300 –2132.00
0.590400 597.00 0.585700 –2449.00 –1500.
0.637900 571.00 0.633400 –2746.00
0.683800 539.00 0.675000 –3074.00
0.728100 488.00 0.724200 –3416.00
0.770800 431.00 0.767400 –3698.00
0.812200 381.00 0.809200 –3983.00
0.852200 323.00 0.849700 –4066.00 –3000.
0.890900 255.00 0.889000 –4059.00
0.928400 175.00 0.927100 –3893.00
0.964800 82.00 0.964100 –3240.00
P/106Pa = 8.00; T/K = 308.150
P/106Pa = 7.50; T/K = 308.150
–4500.
0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 10.00 + 0.008 |HE/J mol-1| See SELF for the totality of data
Dai, W.; Kojima, K.; Ochi, K. Measurement and correlation of excess molar enthalpies of carbon dioxide + 2-butanol and
2-propanol systems at the temperatures 303.15 K and 308.15 K and at pressures from 7.0 to 8.5 MPa J. Chem. Eng. Data 2000, 45
, 6-10

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0001

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H10O, Butan-2-ol [78-92-2]
P/106Pa = 8.50 P/106Pa = 7.50
T/K = 303.150 T/K = 308.150 HE/J mol-1
1500.
x1 HE/J mol-1 x1 HE/J mol-1
0.042500 81.00 0.082100 –97.00
0.083600 253.00 0.158800 –185.00
0.123200 450.00 0.230600 –322.00
0.161400 663.00 0.298100 –433.00
0.234200 874.00 0.361500 –591.00 0.
0.302200 958.00 0.421300 –735.00
0.366100 1021.00 0.477700 –901.00
0.426100 1047.00 0.531100 –1064.00
0.482700 1052.00 0.581600 –1255.00
0.536000 1033.00 0.629500 –1435.00 –1500.
0.586400 1000.00 0.674900 –1677.00
0.634100 944.00 0.718200 –1929.00
0.679300 875.00 0.759300 –2249.00
0.722100 793.00 0.798500 –2607.00
0.762900 702.00 0.836000 –2899.00
0.801700 607.00 0.871700 –2895.00 –3000. P/106Pa = 8.50; T/K = 303.150
0.838700 510.00 0.905900 –2530.00 P/106Pa = 7.50; T/K = 303.150
0.873900 423.00 0.938600 –1381.00
0.907600 328.00 0.959600 –669.00 P/106Pa = 8.00; T/K = 308.150
0.939700 231.00 P/106Pa = 7.50; T/K = 308.150
0.970500 107.00
–4500.
0.50
x1
Uncertainties: σ (x1) = 0.00050; σ (HE)/J mol-1
= 10.00 + 0.008 |HE/J mol-1| See SELF for the totality of data
Dai, W.; Kojima, K.; Ochi, K. Measurement and correlation of excess molar enthalpies of carbon dioxide + 2-butanol and
2-propanol systems at the temperatures 303.15 K and 308.15 K and at pressures from 7.0 to 8.5 MPa J. Chem. Eng. Data 2000, 45
, 6-10

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0399

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H6O3, (+,–)-Methyl-1,3-dioxolan-2-one [108-32-7]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 298.150 T/K = 298.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 12.5; T/K = 298.15
0.075500 –213.80 0.075300 –114.70 P/106Pa = 10.0; T/K = 298.15
0.145800 –392.20 0.145500 –286.60 P/106Pa = 7.5; T/K = 298.15
0.211500 –607.40 0.211100 –415.20
0.273000 –836.60 0.272500 –539.90
0.330700 –950.10 0.330100 –655.00 –400.
0.384900 –1064.80 0.384300 –755.10
0.436000 –1190.40 0.435400 –840.60
0.484200 –1295.00 0.483600 –918.10
0.529700 –1373.80 0.529100 –974.40
0.572800 –1483.10 0.572200 –1023.80 –800.
0.613700 –1501.50 0.613100 –1066.30
0.652500 –1538.90 0.651900 –1094.20
0.689300 –1549.40 0.688800 –1088.70
0.724400 a–1504.20 0.723900 –1062.50
0.757800 a–1384.30 0.757300 –1024.40
0.789700 a–1240.60 0.789300 a –963.70 –1200.
0.820100 a–1098.40 0.819700 a –876.30
0.849200 a –955.90 0.848900 a –770.60
0.877100 a –802.10 0.876800 a –679.40
0.903700 a –690.80 0.903500 a –554.00
0.929300 a –539.50 0.929100 a –437.80
0.953800 a –403.80 0.953700 a –306.70 –1600.
0.977300 –268.20 0.977900 –200.70 0.50
x1
Uncertainties: σ (x1) = 0.0010; σrel
(HE) = 0.03 a Two-phase region; See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess enthalpies of (carbon dioxide + propylene carbonate or N-methyl-.epsilon.-caprolactam or
1-formylpiperidine) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn.
1995, 27, 1169-1185

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0402

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H6O3, (+,–)-Methyl-1,3-dioxolan-2-one [108-32-7]
P/106Pa = 10.000 P/106Pa = 12.500
T/K = 308.150 T/K = 308.150 HM/J mol-1
0.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 10.0; T/K = 308.15
0.074000 –215.50 0.073800 –120.80 P/106Pa = 7.5; T/K = 308.15
0.143200 –396.20 0.142800 –308.40
0.208000 –576.90 0.207500 –495.90
0.268800 –763.20 0.268200 –662.30
0.326000 –924.30 0.325400 –819.40 –1100.
0.379900 –1084.00 0.379200 –919.40
0.430800 –1190.30 0.430100 –1066.40
0.478900 –1331.20 0.478200 –1157.90
0.524400 –1420.00 0.523700 –1246.70
0.567600 –1539.70 0.566900 –1349.20 –2200.
0.608600 –1600.30 0.608000 –1428.50
0.647600 –1635.40 0.647000 –1466.10
0.684700 –1638.00 0.684200 –1471.80
0.720100 a–1558.40 0.719600 –1438.90
0.753900 a–1421.50 0.753400 a–1327.50
0.786100 a–1253.50 0.785700 a–1203.70 –3300.
0.817000 a–1065.00 0.816600 a–1062.80
0.846500 a –930.90 0.846100 a –927.30
0.874700 a –776.50 0.874400 a –803.40
0.901900 a –632.20 0.901600 a –674.10
0.927900 a –493.70 0.927700 a –525.50
0.952900 a –340.10 0.952700 a –398.20 –4400.
0.977500 –169.10 0.976800 –253.80 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.03 a Two-phase region; See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess enthalpies of (carbon dioxide + propylene carbonate or N-methyl-.epsilon.-caprolactam or
1-formylpiperidine) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn.
1995, 27, 1169-1185

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0186

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H5N, Pyridine [110-86-1]
P/106Pa = 7.50 P/106Pa = 7.50
T/K = 358.15 T/K = 358.15 HM/J mol-1
1200.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.500; T/K = 358.15
0.027400 20.00 0.727900 a –1200.00 P/106Pa = 10.500; T/K = 358.15
0.027400 18.00 0.762800 a –982.00 P/106Pa = 12.500; T/K = 358.15
0.080800 –528.00 0.762800 a –984.00
0.132800 –1000.00 0.796800 a –790.00
0.183200 –1430.00 0.796800 a –772.00 0.
0.232200 –1770.00 0.830100 a –614.00
0.279900 –2120.00 0.830100 a –592.00
0.326200 –2480.00 0.830100 a –585.00
0.371300 –2780.00 0.862600 a –394.00
0.393400 –2880.00 0.862600 a –404.00 –1200.
0.415200 –2940.00 0.894400 a –204.00
0.426000 –2950.00 0.925400 a –25.00
0.457900 a –2800.00 0.925400 a –23.00
0.478800 a –2660.00 0.955700 a 155.00
0.499500 a –2540.00 0.985400 338.00
0.519900 a –2420.00 0.985400 325.00 –2400.
0.540000 a –2310.00
0.579500 a –2140.00
0.579500 a –2050.00
0.618000 a –1870.00
0.655500 a –1610.00
0.655500 a –1620.00 –3600.
0.692200 a –1410.00 0.50
0.727900 a –1200.00
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Christensen, S. P.; Schofield, R. S.; Faux, P. W.; Harding, P. R.; Izatt, R. M. The excess enthalpies of
(carbon dioxide + pyridine) at 308.15, 358.15, and 413.15 K from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1984, 16, 249-255

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0265

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H5N, Pyridine [110-86-1]
P/106Pa = 7.500 P/106Pa = 10.500
T/K = 573.150 T/K = 573.150 HM/J mol-1
12000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 7.5; T/K = 573.15
0.027400 23.00 0.029600 156.00
0.132800 a 1660.00 0.087100 518.00 P/106Pa = 10.5; T/K = 573.15
0.158200 a 2650.00 0.142500 1290.00 P/106Pa = 12.5; T/K = 573.15
0.183200 a 3500.00 0.195800 1950.00
0.256200 a 5950.00 0.221600 2530.00 9000.
0.268100 a 6140.00 0.247100 3010.00
0.279900 a 6540.00 0.296600 4070.00
0.303200 a 7510.00 0.367700 5720.00
0.314800 a 7800.00 0.390600 5950.00
0.326200 a 8430.00 0.435100 6670.00 6000.
0.348900 a 9470.00 0.456900 6730.00
0.360200 9540.00 0.478200 6790.00
0.382400 9520.00 0.519900 6700.00
0.393400 9430.00 0.560200 6560.00
0.415200 9300.00 0.599300 6180.00
0.436700 9100.00 0.637100 5610.00 3000.
0.457900 8940.00 0.673700 5210.00
0.540000 7890.00 0.709300 4820.00
0.618000 6760.00 0.777200 3790.00
0.762800 4630.00 0.841300 2850.00
0.830100 3310.00 0.901800 1850.00
0.862600 2800.00 0.930800 1296.00 0.
0.925400 1530.00 0.986500 302.00 0.50
0.985400 266.00
x1
Uncertainties: σ (x1) = 0.0005; σ (HM)/J mol-1
= 10.00 + 0.008 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Christensen, J. J.; Zebolsky, D. M.; Izatt, R. M. The excess enthalpies of (carbon dioxide + pyridine) at 470.15 and 573.15 K
from 7.50 to 12.50 MPa J. Chem. Thermodyn. 1985, 17, 785-795

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0433

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C4H5NO2, Methyl cyanoethanoate [105-34-0]
P/106Pa = 7.500 P/106Pa = 12.600
T/K = 298.150 T/K = 298.150 HE/J mol-1
400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 298.15
0.168000 –40.10 0.172000 –21.70
0.311000 –450.30 0.318000 –264.50 P/106Pa = 10.6; T/K = 298.15
0.437000 –735.00 0.444000 –586.50 P/106Pa = 12.6; T/K = 298.15
0.546000 –940.30 0.554000 –718.80
0.643000 –1097.50 0.651000 –786.50 0.
0.730000 –1167.10 0.736000 –776.30
0.808000 –1112.80 0.813000 –694.90
0.878000 –957.80 0.881000 –561.50
0.941000 –670.40 0.943000 –348.40
0.971000 –434.70 0.972000 –203.70 –400.

–800.

–1200.
0.50
x1
Uncertainties: σ (x1) = 0.0010; σrel
(HE) = 0.03 See SELF for the totality of data
Hauser, R. A.; Zhao, J. P.; Tremaine, P. R.; Mather, A. E. Excess molar enthalpies of six (carbon dioxide + a polar solvent)
mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa J. Chem. Thermodyn. 1996, 28
, 1303-1317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0434

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H9NO, 1-Methylpyrrolidin-2-one [872-50-4]
P/106Pa = 7.500 P/106Pa = 12.600
T/K = 298.150 T/K = 298.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.5; T/K = 298.15
0.179000 –554.60 0.185000 –430.20 P/106Pa = 10.6; T/K = 298.15
0.329000 –933.30 0.337000 –738.00 P/106Pa = 12.6; T/K = 298.15
0.456000 –1234.70 0.465000 –1002.80
0.566000 –1472.90 0.575000 –1170.00
0.662000 –1591.40 0.670000 –1244.40 –450.
0.705000 –1613.90 0.752000 –1185.80
0.746000 –1605.20 0.825000 –1038.60
0.820000 –1482.00 0.890000 –825.70
0.886000 –1262.10 0.947000 –498.80
0.946000 –856.70 –900.

–1350.

–1800.
0.50
x1
Uncertainties: σ (x1) = 0.0010; σrel
(HE) = 0.03 See SELF for the totality of data
Hauser, R. A.; Zhao, J. P.; Tremaine, P. R.; Mather, A. E. Excess molar enthalpies of six (carbon dioxide + a polar solvent)
mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa J. Chem. Thermodyn. 1996, 28
, 1303-1317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0400

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H13NO, 1-Methylhexahydroazepin-2-one [2556-73-2]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 298.150 T/K = 298.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 12.5; T/K = 298.15
0.104800 –343.30 0.108300 –266.50 P/106Pa = 10.0; T/K = 298.15
0.196600 –608.40 0.202500 –476.70 P/106Pa = 7.5; T/K = 298.15
0.277700 –835.90 0.285300 –659.60
0.350000 –1002.10 0.358500 –826.50
0.414600 –1153.70 0.423700 –945.00 –400.
0.472900 –1263.60 0.488200 –1011.80
0.525700 –1358.10 0.535000 –1077.10
0.573700 –1429.00 0.582800 –1127.80
0.617600 –1488.20 0.626300 –1171.00
0.657800 –1528.80 0.666200 –1171.00 –800.
0.694900 –1520.80 0.702700 –1151.00
0.729100 –1528.60 0.736400 –1146.30
0.760800 –1515.40 0.767500 –1127.40
0.790300 –1479.30 0.796400 –1080.00
0.817700 –1435.80 0.823200 –1038.90
0.843300 –1383.40 0.848200 –975.10 –1200.
0.867300 –1337.20 0.871500 –909.30
0.889800 –1257.50 0.893400 –811.90
0.910900 –1148.60 0.913900 –719.00
0.930800 –1014.10 0.933200 –606.80
0.949600 –857.20 0.951400 –517.70
0.967300 –653.80 0.968500 –364.20 –1600.
0.984100 –412.30 0.984700 –260.00 0.50
x1
Uncertainties: σ (x1) = 0.0010; σrel
(HE) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess enthalpies of (carbon dioxide + propylene carbonate or N-methyl-.epsilon.-caprolactam or
1-formylpiperidine) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn.
1995, 27, 1169-1185

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0403

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C7H13NO, 1-Methylhexahydroazepin-2-one [2556-73-2]
P/106Pa = 10.000 P/106Pa = 12.500
T/K = 308.150 T/K = 308.150 HM/J mol-1
0.
x1 HM/J mol-1 x1 HM/J mol-1
0.107100 –315.10 0.108300 –225.98
0.200500 –577.10 0.202500 –509.20
0.282700 –790.10 0.285300 –695.90
0.355600 –1028.20 0.358500 –862.50
0.420600 –1211.10 0.423700 –1022.50 –1500.
0.479100 –1341.60 0.482200 –1115.00
0.531800 –1467.40 0.535000 –1193.70
0.579700 –1584.20 0.582800 –1275.40
0.623400 –1640.40 0.626300 –1316.20
0.663400 –1653.00 0.666200 –1343.60 –3000.
0.700100 –1691.30 0.702700 –1359.00
0.734000 –1703.00 0.736400 –1334.60
0.765300 –1681.70 0.767500 –1326.40
0.794300 –1689.90 0.796400 –1283.70
0.821400 –1658.90 0.823200 –1250.40
0.846600 –1605.60 0.848200 –1192.40 –4500.
0.870100 –1537.20 0.871500 –1105.00
0.892200 –1436.50 0.893400 –1025.60
0.912900 –1315.30 0.913900 –929.20
0.932400 –1193.70 0.932200 –829.20 P/106Pa = 12.5; T/K = 308.15
0.950800 –987.70 0.951400 –680.90 P/106Pa = 7.5; T/K = 308.15
0.968100 –807.80 0.968500 –502.70 –6000.
0.984500 –496.80 0.984700 –294.00 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess enthalpies of (carbon dioxide + propylene carbonate or N-methyl-.epsilon.-caprolactam or
1-formylpiperidine) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn.
1995, 27, 1169-1185

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0401

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H11NO, N-Formylpiperidine [2591-86-8]
P/106Pa = 7.500 P/106Pa = 12.500
T/K = 298.150 T/K = 298.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 12.5; T/K = 298.15
0.091800 –304.80 0.095000 –242.60 P/106Pa = 10.0; T/K = 298.15
0.174500 –526.20 0.179900 –448.50 P/106Pa = 7.5; T/K = 298.15
0.249400 –715.00 0.256400 –677.00
0.317500 –879.70 0.325600 –816.30
0.379700 –991.40 0.388500 –928.60 –400.
0.436700 –1120.80 0.445900 –1024.10
0.489200 –1224.30 0.498500 –1114.40
0.537600 –1313.10 0.546900 –1171.90
0.582500 –1401.60 0.591600 –1191.20
0.624200 –1459.20 0.632900 –1196.70 –800.
0.663000 –1495.50 0.671300 –1218.30
0.699300 –1540.10 0.707100 –1207.20
0.733200 –1555.90 0.740400 –1195.20
0.765000 –1545.60 0.771700 –1155.80
0.794900 –1518.30 0.800900 –1126.80
0.823000 –1481.00 0.828400 –1068.30 –1200.
0.849600 –1425.50 0.854300 –1006.80
0.874600 –1374.50 0.878700 –932.70
0.898300 –1253.20 0.901700 –845.90
0.920800 –1164.50 0.923500 –727.50
0.942100 –977.50 0.944100 –609.70
0.962400 –781.60 0.963700 –405.00 –1600.
0.981600 –483.20 0.982300 –219.90 0.50
x1
Uncertainties: σ (x1) = 0.0010; σrel
(HE) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess enthalpies of (carbon dioxide + propylene carbonate or N-methyl-.epsilon.-caprolactam or
1-formylpiperidine) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn.
1995, 27, 1169-1185

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0404

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C6H11NO, N-Formylpiperidine [2591-86-8]
P/106Pa = 10.000 P/106Pa = 12.500
T/K = 308.150 T/K = 308.150 HM/J mol-1
0.
x1 HM/J mol-1 x1 HM/J mol-1
0.093900 –351.20 0.067900 –198.30
0.178100 –664.20 0.132200 –340.50
0.254000 –940.90 0.193100 –510.00
0.322800 –1139.30 0.251000 –664.60
0.385500 –1309.40 0.306000 –791.10 –1400.
0.442700 –1452.60 0.358400 –864.00
0.495300 –1600.40 0.408300 –960.70
0.543700 –1693.60 0.455900 –1044.60
0.588500 –1749.50 0.501300 –1125.30
0.623000 –1828.10 0.544800 –1177.00 –2800.
0.668500 –1846.60 0.586400 –1237.20
0.704500 –1892.80 0.626300 –1257.00
0.738000 –1884.80 0.664500 –1255.80
0.769400 –1863.30 0.701100 –1245.40
0.798900 –1840.10 0.736300 –1235.80
0.826600 –1778.60 0.770200 –1218.90 –4200.
0.852700 –1703.30 0.802700 –1146.10
0.877300 –1600.70 0.834100 –1074.00 P/106Pa = 12.5; T/K = 308.15
0.900600 –1495.90 0.864300 –988.60
0.922900 –1317.40 0.893400 –871.80 P/106Pa = 10.0; T/K = 308.15
0.943500 –1111.50 0.921400 –732.20 P/106Pa = 7.5; T/K = 308.15
0.963300 –902.80 0.948500 –538.00 –5600.
0.982100 –521.00 0.974700 –301.40 0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HM) = 0.03 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess enthalpies of (carbon dioxide + propylene carbonate or N-methyl-.epsilon.-caprolactam or
1-formylpiperidine) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn.
1995, 27, 1169-1185

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0435

Components: 1. CO2, Carbon dioxide [124-38-9]
2. C5H9NO2, N-Formylmorpholine [4394-85-8]
P/106Pa = 7.500
T/K = 298.15 HE/J mol-1
0.
x1 HE/J mol-1
P/106Pa = 7.5; T/K = 298.15
0.576000 –1588.70
0.670000 –1791.30
0.753000 –1812.80
0.825000 –1645.90
0.890000 –1370.00 –500.
0.947000 –881.40
0.974000 –498.10

–1000.

–1500.

–2000.
0.50
x1
Uncertainties: σ (x1) = 0.0010; σrel
(HE) = 0.03
Hauser, R. A.; Zhao, J. P.; Tremaine, P. R.; Mather, A. E. Excess molar enthalpies of six (carbon dioxide + a polar solvent)
mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa J. Chem. Thermodyn. 1996, 28
, 1303-1317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0225

Components: 1. H2O, Water [7732-18-5]
2. CH4, Methane [74-82-8]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 393.2 T/K = 423.2 HE/J mol-1
60.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 393.2
0.373000 37.40 0.399000 28.30
0.395000 39.20 0.407000 29.80 P/103Pa = 101.325; T/K = 403.2
0.419000 39.30 0.424000 29.70 P/103Pa = 101.325; T/K = 423.2
0.444000 39.70 0.473000 31.60
0.466000 40.30 0.501000 30.90 45.
0.467000 40.50 0.512000 29.80
0.471000 42.90 0.560000 29.20
0.475000 37.80 0.592000 29.80
0.491000 38.30 0.633000 28.30
0.519000 40.90 0.658000 26.70 30.
0.527000 41.30
0.528000 39.60
0.548000 40.70
0.552000 41.70
0.592000 36.00
0.607000 42.70 15.
0.628000 34.60
0.631000 37.60
0.670000 35.60
0.671000 35.50
0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE) = 0.02 See SELF for the totality of data
Smith, G. R.; Sellars, A. J.; Yerlett, T. K.; Wormald, C. J. The excess enthalpy of (water + hydrogen) vapour and (water +
methane) vapour J. Chem. Thermodyn. 1983, 15, 29-35

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0154

Components: 1. H2O, Water [7732-18-5]
2. CH4, Methane [74-82-8]
P/106Pa = 4.980 P/106Pa = 10.510
T/K = 548.200 T/K = 648.200 HE/J mol-1
2000.
x1 HE/J mol-1 x1 HE/J mol-1
0.304000 699.00 0.304000 822.00
0.408000 836.00 0.412000 958.00
0.508000 893.00 0.524000 1020.00
0.612000 895.00 0.637000 1036.00
0.717000 809.00 0.759000 894.00 1500.

1000.

500.

P/106Pa = 4.980; T/K = 548.20

P/106Pa = 10.440; T/K = 598.20
P/106Pa = 10.510; T/K = 648.20
0.
0.50
x1
Uncertainties: σ (x1) = 0.0020; σ (HE)/J mol-1
= 15 – 38 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0164

Components: 1. H2O, Water [7732-18-5]
2. CH4, Methane [74-82-8]
T/K = 598.20 T/K = 648.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
2000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 548.20; x1 = 0.500
0.80 54.00 1.41 78.00
2.16 190.00 2.82 187.00 T/K = 598.20; x1 = 0.500
3.53 371.00 2.86 229.00 T/K = 648.20; x1 = 0.500
5.00 553.00 4.27 318.00
6.27 755.00 5.65 455.00 1500.0
6.31 785.00 6.86 605.00
7.69 1076.00 7.06 595.00
9.20 1410.00 8.44 896.00
10.44 1727.00 9.79 1008.00
10.51 1754.00 10.03 1010.00 1000.0
10.51 1043.00
11.31 1202.00
12.62 1458.00

500.0

0.0
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.003 – 0.015; σ (HE)/J mol-1 = 3.20 – 37 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0439

Components: 1. H2O, Water [7732-18-5]
2. CH4, Methane [74-82-8]
P/106Pa T/K x1 HE/J mol-1
3.670 583.70 0.4910 389.0
6.540 584.90 0.5020 896.0
9.590 587.80 0.5070 1720.0
3.910 692.50 0.4930 209.0
7.190 691.50 0.5080 446.0
7.360 687.60 0.4950 475.0
10.310 692.50 0.5080 731.0
10.310 688.40 0.5110 756.0
14.250 689.80 0.5080 1151.0
16.530 689.80 0.4990 1438.0
3.680 800.40 0.4910 132.0
7.360 801.70 0.4960 289.0
10.690 801.70 0.4940 454.0
10.790 803.10 0.5180 457.0

Uncertainties: σrel(P) = 0.002; σ (T)/K = 1.0; σ (x1) = 0.0010; σrel(HE) = 0.030

Wilson, G. M.; Brady, C. J. Heats of mixing of steam with N2, CO2, H2, CH4, and CO at high temperatures and pressures using
a new high temperature calorimeter Gas Process. Assoc., Res. Rep. (cf. August 1995 List of Publications (CD-ROM available:
call 1-800-241-7842; fax 1-303-397-2599) 1983, (RR-73), 1-46

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0325

Components: 1. CH4, Methane [74-82-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –15.450 H°sol/103J mol-1
308.15 –11.090 –9.

–11.

–13.

–15.

–17.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.05–0.10
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0347

Components: 1. CH4, Methane [74-82-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
273.24 –18.530 H°sol/103J mol-1
274.00 –18.160 –5.
276.29 –17.740
278.15 –17.560
283.15 –16.340
293.17 –14.290
303.39 –11.780 –9.
308.17 –10.700
313.20 –9.880
318.28 –9.040
323.17 –8.430

–13.

–17.

–21.
280. 300. 320.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.05–0.15
Naghibi, H.; Dec, S. F.; Gill, S. J. Heat of solution of methane in water from 0 to 50.deg.C J. Phys. Chem. 1986, 90, 4621-4623

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0351

Components: 1. CH4, Methane [74-82-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –13.180 H°sol/103J mol-1
–9.
T/K = 298.15

–11.

–13.

–15.

–17.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.07
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0311

Components: 1. CH4, Methane [74-82-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –15.530 H°sol/103J mol-1
298.15 –13.060
308.15 –10.700

–10.00

–12.00

–14.00

–16.00
290.00 300.00 310.00
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.15
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0040

Components: 1. H2O, Water [7732-18-5]
2. C2H6, Ethane [74-84-0]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.4 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.386000 60.10 0.337000 39.70
0.411000 60.50 0.409000 41.90 P/103Pa = 101.325; T/K = 393.4
0.465000 63.10 0.438000 46.00
0.486000 63.10 0.490000 45.20
0.513000 62.70 0.498000 44.60 60.
0.534000 63.00 0.506000 43.50
0.546000 65.20 0.580000 43.70
0.587000 63.90 0.615000 42.90
0.593000 62.60 0.657000 39.00
0.633000 60.60 0.700000 36.20 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Lancaster, N. M.; Wormald, C. J. The excess molar enthalpies of {xH2O + (1-x)C2H6}(g) and {xH2O + (1-x)C2H4}(g) J.
Chem. Thermodyn. 1985, 17, 295-299

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0124

Components: 1. H2O, Water [7732-18-5]
2. C2H6, Ethane [74-84-0]
T/K = 598.000 T/K = 674.200
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
12000.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 598.00; x1 = .500
5.050 681.000 9.500 836.000
5.850 1028.000 11.250 1102.000 T/K = 650.70; x1 = .500
6.150 997.000 12.400 1245.000 T/K = 674.20; x1 = .500
6.650 1073.000 14.150 1455.000
7.150 1199.000 15.450 1730.000 9000.
7.250 1152.000 15.650 1696.000
7.700 1311.000 16.360 1893.000
8.150 1336.000 17.200 2089.000
8.600 1575.000 17.250 2017.000
9.200 1728.000 17.850 2095.000 6000.
9.250 1737.000 18.300 2251.000
10.100 1844.000 18.800 2478.000
11.050 2349.000 19.800 2651.000
11.900 2909.000 19.900 2659.000
22.100 3330.000
23.100 3592.000 3000.
24.400 4174.000
25.300 4581.000

0.
0. 8. 16. 24. 32.
P/106Pa
Uncertainties: σ (P)/106Pa = 0.02; σrel(HE) = 0.04 – 0.06 See SELF for the totality of data
Wormald, C. J.; Lloyd, M. J.; Fenghour, A. The excess enthalpy of (steam + ethane) in the supercritical region up to T = 699.4
K and p = 25.3 MPa Int. J. Thermophys. 2000, 21, 85-93

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0166

Components: 1. H2O, Water [7732-18-5]
2. C2H6, Ethane [74-84-0]
T/K = 573.20 T/K = 648.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
2000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 573.20; x1 = 0.500
1.01 115.00 0.80 63.00
1.98 238.00 1.86 151.00 T/K = 648.20; x1 = 0.500
2.95 392.00 2.48 209.00 T/K = 698.20; x1 = 0.500
3.82 559.00 3.53 320.00
4.53 699.00 4.05 384.00 1500.0
5.19 828.00 5.25 517.00
5.80 1007.00 5.80 592.00
6.04 1085.00 6.10 636.00
6.67 1275.00 6.79 710.00
7.07 1389.00 7.03 753.00 1000.0
7.96 884.00
8.62 961.00
9.00 1039.00
9.13 1074.00
9.96 1188.00
11.40 1368.00 500.0
12.10 1478.00
12.90 1558.00
13.20 1692.00
13.40 1765.00
0.0
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.003 – 0.016; σ (HE)/J mol-1 = 3.0 – 45 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0352

Components: 1. C2H6, Ethane [74-84-0]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –19.520 H°sol/103J mol-1
–13.
T/K = 298.15

–16.

–18.

–21.

–23.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 1.2
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0326

Components: 1. C2H6, Ethane [74-84-0]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –22.310 H°sol/103J mol-1
308.15 –16.650 –15.

–17.

–19.

–21.

–23.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.06–0.11
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0345

Components: 1. C2H6, Ethane [74-84-0]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
273.24 –26.590 H°sol/103J mol-1
278.15 –25.160 –12.
283.15 –23.840
288.15 –22.520
293.15 –20.590
303.15 –18.300
308.15 –16.590 –16.
313.15 –15.280
318.15 –13.980
323.15 –13.380

–20.

–24.

–28.
280. 300. 320.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10–0.30
Naghibi, H.; Dec, S. F.; Gill, S. J. Heats of solution of ethane and propane in water from 0 to 50.deg.C J. Phys. Chem. 1987, 91
, 245-248

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0312

Components: 1. C2H6, Ethane [74-84-0]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –22.560 H°sol/103J mol-1
298.15 –19.300 –16.
308.15 –16.210

–18.

–20.

–22.

–24.
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.12
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0037

Components: 1. H2O, Water [7732-18-5]
2. C3H8, Propane [74-98-6]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.2 HE/J mol-1
100.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.412000 67.70 0.308000 43.30
0.451000 69.80 0.419000 48.80 P/103Pa = 101.325; T/K = 393.2
0.459000 68.90 0.425000 48.30
0.481000 68.50 0.434000 50.50
0.503000 71.70 0.497000 50.00 75.
0.520000 71.80 0.512000 50.00
0.529000 70.20 0.580000 49.40
0.547000 71.20 0.605000 50.40
0.569000 71.10 0.651000 46.00
0.621000 67.10 0.697000 44.80 50.

25.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Lancaster, N. M.; Wormald, C. J. The molar enthalpies for {xH2O + (1-x)C3H6}(g), {xH2O + (1-x)C3H8}(g), and {xH2O +
(1-x)C4H10}(g) J. Chem. Thermodyn. 1986, 18, 545-550

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0167

Components: 1. H2O, Water [7732-18-5]
2. C3H8, Propane [74-98-6]
T/K = 573.20 T/K = 648.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
2400.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 573.20; x1 = 0.500
0.77 110.00 1.17 118.00
1.03 151.00 1.51 160.00 T/K = 598.20; x1 = 0.500
1.92 303.00 1.62 172.00 T/K = 648.20; x1 = 0.500
2.28 376.00 3.02 325.00
2.47 395.00 3.26 358.00 1800.0
2.50 405.00 3.79 406.00
2.71 436.00 5.08 577.00
2.80 448.00 6.43 781.00
4.05 736.00 8.10 1007.00
4.12 733.00 8.20 1005.00 1200.0
4.90 927.00 8.72 1107.00
5.09 990.00 9.79 1344.00
5.42 1063.00 11.50 1621.00
5.97 1194.00 13.10 1988.00
6.88 1479.00 13.70 2092.00
600.0

0.0
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.0031 – 0.036; σ (HE)/J mol-1 = 4.0 – 47 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1332] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
Variables: T/K, Temperature
H∞ -1
sol/J mol , Molar enthalpy of solution at infinite dilution of component 1
Method: H∞sol calculated by extrapolation to infinite dilution of direct calorimetric measurements of the molar enthalpy of
solution at variable T and constant P

File Number: LB0323

Components: 1. C3H8, Propane [74-98-6]
2. H2O, Water [7732-18-5]
P/103Pa = 100.000
T/K H∞ 3 -1 H∞ 3
sol/10 J mol
-1
sol/10 J mol
29815 –22.61
P/103Pa = 100.

–21.0

–22.0

–23.0

–24.0
293.0 298.0 303.0
T/K
Uncertainties: σ (T)/K = 0.02; σ (H∞ 3 -1
sol)/10 J mol = 0.06
Hallen, D.; Wadsoe, I. A new microcalorimetric vessel for dissolution of slightly soluble gases. Enthalpies of solution in water of
carbon tetrafluoride and sulphur hexafluoride at 288.15, 298.15, and 308.15 K J. Chem. Thermodyn. 1989, 21, 519-527

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0353

Components: 1. C3H8, Propane [74-98-6]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –23.270 H°sol/103J mol-1
–16.
T/K = 298.15

–19.

–22.

–25.

–28.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 2.6
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0346

Components: 1. C3H8, Propane [74-98-6]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
273.24 –31.190 H°sol/103J mol-1
278.15 –29.830 –13.
283.15 –27.930
288.15 –26.250
293.15 –24.420
303.15 –21.720
308.15 –19.720 –18.
313.15 –18.600
318.15 –16.570
323.15 –15.580

–23.

–28.

–33.
280. 300. 320.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10–0.30
Naghibi, H.; Dec, S. F.; Gill, S. J. Heats of solution of ethane and propane in water from 0 to 50.deg.C J. Phys. Chem. 1987, 91
, 245-248

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0313

Components: 1. C3H8, Propane [74-98-6]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –26.620 H°sol/103J mol-1
298.15 –22.900 –16.
308.15 –18.840

–19.

–22.

–25.

–28.
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.14
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0327

Components: 1. C3H8, Propane [74-98-6]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –25.840 H°sol/103J mol-1
308.15 –19.190 –16.

–19.

–22.

–25.

–28.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10–0.16
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0038

Components: 1. H2O, Water [7732-18-5]
2. C4H10, Butane [106-97-8]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.2 HE/J mol-1
120.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.354000 78.50 0.298000 51.60
0.402000 82.50 0.365000 58.50 P/103Pa = 101.325; T/K = 393.2
0.438000 85.60 0.434000 60.20
0.480000 88.40 0.459000 61.50
0.482000 85.30 0.505000 61.60 90.
0.485000 87.70 0.542000 61.00
0.530000 85.70 0.569000 60.20
0.558000 86.90 0.601000 57.40
0.564000 84.70 0.639000 56.40
0.600000 81.30 0.682000 54.30 60.

30.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Lancaster, N. M.; Wormald, C. J. The molar enthalpies for {xH2O + (1-x)C3H6}(g), {xH2O + (1-x)C3H8}(g), and {xH2O +
(1-x)C4H10}(g) J. Chem. Thermodyn. 1986, 18, 545-550

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0168

Components: 1. H2O, Water [7732-18-5]
2. C4H10, Butane [106-97-8]
T/K = 598.20 T/K = 698.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
3000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 598.20; x1 = 0.500
1.31 232.00 1.62 187.00
2.27 425.00 2.85 342.00 T/K = 648.20; x1 = 0.500
2.33 430.00 4.60 571.00 T/K = 698.20; x1 = 0.500
3.67 717.00 6.14 755.00
5.14 1084.00 7.63 1012.00 2250.0
6.59 1500.00 7.69 959.00
7.89 1934.00 8.03 999.00
8.13 2011.00 9.55 1233.00
9.34 2391.00 11.30 1431.00
10.60 2853.00 13.00 1706.00 1500.0

750.0

0.0
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.003 – 0.016; σ (HE)/J mol-1 = 4.0 – 45 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0328

Components: 1. C4H10, Butane [106-97-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –29.200 H°sol/103J mol-1
308.15 –21.400 –19.

–22.

–25.

–28.

–31.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.13–0.21
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0354

Components: 1. C4H10, Butane [106-97-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –25.920 H°sol/103J mol-1
–19.
T/K = 298.15

–22.

–25.

–28.

–31.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 1.7
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0291

Components: 1. C4H10, Butane [106-97-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
273.25 –35.680 H°sol/103J mol-1
278.15 –33.620 –16.
283.15 –31.600
288.15 –29.260
293.15 –27.380
303.15 –23.670
308.15 –22.150 –21.
313.15 –20.150
318.15 –17.810

–26.

–31.

–36.
270. 290. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.15–0.43
Naghibi, H.; Ownby, D. W.; Gill, S. J. Enthalpies of solution of butanes in water from 5 to 45.deg.C J. Chem. Eng. Data 1987,
32, 422-425

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0314

Components: 1. C4H10, Butane [106-97-8]
2. H2O, Water [7732-18-5]
T/K H°sol/10 3J mol-1
288.15 –29.730 H°sol/10 3J mol-1
298.15 –25.930 –19.
308.15 –21.230

–22.

–25.

–28.

–31.
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.22
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0220

Components: 1. H2O, Water [7732-18-5]
2. C5H12, Pentane [109-66-0]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.2 HE/J mol-1
160.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.395000 103.80 0.312000 66.20
0.401000 106.60 0.380000 73.20 P/103Pa = 101.325; T/K = 393.2
0.466000 112.80 0.424000 78.60
0.533000 111.80 0.486000 81.30
0.569000 107.00 0.499000 79.70 120.
0.572000 102.80 0.510000 79.00
0.629000 104.40 0.553000 76.40
0.643000 101.20 0.582000 83.70
0.691000 96.90 0.615000 75.90
0.697000 92.70 0.618000 74.60 80.

40.

0.
0.50
x1
Uncertainties: σ (x1) = 0.0020; σrel
(HE)
= 0.02 See SELF for the totality of data
Smith, G. R.; Fahy, M. J.; Wormald, C. J. The excess molar enthalpy of {xH2O + (1-x)CnH2n+2}(g) for n = 5,6,7, and 8 J.
Chem. Thermodyn. 1984, 16, 825-831

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0155

Components: 1. H2O, Water [7732-18-5]
2. C5H12, Pentane [109-66-0]
P/106Pa = 4.600 P/106Pa = 4.400
T/K = 548.200 T/K = 598.200 HE/J mol-1
2200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.600; T/K = 548.20
0.252000 1609.00 0.408000 1240.00
0.390000 1877.00 0.458000 1265.00
0.498000 1877.00 0.602000 1190.00
0.611000 1809.00 0.699000 1029.00
0.719000 1535.00 0.798000 757.00 1650.

1100.

550.

P/106Pa = 4.500; T/K = 573.20

P/106Pa = 4.400; T/K = 598.20
P/106Pa = 4.460; T/K = 698.20
0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σ (HE)/J mol-1
= 15 – 38 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0169

Components: 1. H2O, Water [7732-18-5]
2. C5H12, Pentane [109-66-0]
T/K = 523.20 T/K = 573.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
3600.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
0.76 272.00 0.66 176.00
1.44 547.00 0.88 238.00
2.22 923.00 2.13 629.00
2.81 1316.00 2.76 832.00
3.67 1915.00 2.96 915.00 2700.0
3.64 1216.00
4.87 1738.00
4.88 1758.00
5.01 1844.00
5.64 2171.00 1800.0
5.95 2321.00
6.72 2690.00
7.05 2847.00
8.01 3366.00
8.02 3407.00
900.0
T/K = 573.20; x1 = 0.500
T/K = 648.20; x1 = 0.500
T/K = 698.20; x1 = 0.500
0.0
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.003 – 0.017; σ (HE)/J mol-1 = 6.0 – 73 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0221

Components: 1. H2O, Water [7732-18-5]
2. C6H14, Hexane [110-54-3]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 373.200 T/K = 393.200 HE/J mol-1
180.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 373.2
0.382000 120.90 0.420000 107.60
0.416000 131.00 0.433000 105.40 P/103Pa = 101.325; T/K = 393.2
0.425000 129.50 0.455000 108.70
0.430000 127.70 0.469000 109.00
0.458000 131.90 0.526000 106.50 135.
0.477000 135.20 0.527000 106.30
0.491000 134.60 0.567000 106.80
0.525000 133.20 0.582000 105.10
0.585000 126.40 0.598000 103.60
0.614000 124.90 90.

45.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Smith, G. R.; Fahy, M. J.; Wormald, C. J. The excess molar enthalpy of {xH2O + (1-x)CnH2n+2}(g) for n = 5,6,7, and 8 J.
Chem. Thermodyn. 1984, 16, 825-831

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0156

Components: 1. H2O, Water [7732-18-5]
2. C6H14, Hexane [110-54-3]
P/106Pa = 4.930 P/106Pa = 11.480
T/K = 548.200 T/K = 648.200 HE/J mol-1
6000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.930; T/K = 548.20
0.299000 4296.00 0.303000 2925.00
0.402000 4467.00 0.400000 3249.00 P/106Pa = 9.410; T/K = 598.20
0.497000 4249.00 0.500000 3306.00 P/106Pa = 11.480; T/K = 648.20
0.602000 3709.00 0.599000 3136.00
0.702000 2950.00 0.702000 2672.00 4500.

3000.

1500.

0.
0.50
x1
Uncertainties: σ (x1) = 0.0020; σ (HE)/J mol-1
= 50 – 90 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0170

Components: 1. H2O, Water [7732-18-5]
2. C6H14, Hexane [110-54-3]
T/K = 623.20 T/K = 648.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
5000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
1.13 372.00 1.03 301.00
1.98 659.00 1.79 536.10
2.67 908.00 2.67 786.00
3.45 1199.00 3.45 1034.00
4.11 1534.00 4.10 1287.00 3750.0
4.91 1844.00 4.87 1513.00
5.58 2168.00 5.74 1862.00
6.17 2388.00 6.07 2022.00
6.65 2666.00 6.47 2171.00
7.06 2857.00 7.12 2373.00 2500.0
7.64 3056.00 7.89 2646.00
8.29 3309.00 8.58 2930.00
9.02 3509.00 9.42 3017.00
9.71 3625.00 10.10 3143.00
10.20 3686.00
1250.0
T/K = 573.20; x1 = 0.500
T/K = 623.20; x1 = 0.500
T/K = 648.20; x1 = 0.500
0.0
0.0 3.0 6.0 9.0 12.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.003 – 0.013; σ (HE)/J mol-1 = 16 – 160 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0157

Components: 1. H2O, Water [7732-18-5]
2. C7H16, Heptane [142-82-5]
P/106Pa = 4.580 P/106Pa = 7.680
T/K = 548.200 T/K = 598.200 HE/J mol-1
12000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.580; T/K = 548.20
0.301000 8428.00 0.300000 4780.00
0.400000 8351.00 0.398000 5310.00 P/106Pa = 6.000; T/K = 573.20
0.498000 7672.00 0.502000 5298.00 P/106Pa = 7.680; T/K = 598.20
0.600000 6616.00 0.601000 4833.00
0.701000 5318.00 0.700000 4061.00 9000.

6000.

3000.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σ (HE)/J mol-1
= 100 – 170 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0222

Components: 1. H2O, Water [7732-18-5]
2. C7H16, Heptane [142-82-5]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 373.200 T/K = 393.200 HE/J mol-1
240.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 373.2
0.415000 178.20 0.422000 144.60
0.431000 182.50 0.438000 152.30 P/103Pa = 101.325; T/K = 393.2
0.445000 181.40 0.449000 151.70
0.479000 187.50 0.498000 150.00
0.482000 188.80 0.520000 150.80 180.
0.493000 186.20 0.537000 152.90
0.503000 184.70 0.551000 149.00
0.562000 181.20 0.590000 144.50
0.590000 177.30 0.608000 144.30
0.644000 169.20 0.617000 142.20 120.

60.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Smith, G. R.; Fahy, M. J.; Wormald, C. J. The excess molar enthalpy of {xH2O + (1-x)CnH2n+2}(g) for n = 5,6,7, and 8 J.
Chem. Thermodyn. 1984, 16, 825-831

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0193

Components: 1. H2O, Water [7732-18-5]
2. C7H16, Heptane [142-82-5]
T/K = 548.2 T/K = 598.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
8000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
0.69 369.00 0.79 302.00
1.38 859.00 1.44 649.00
2.48 2206.00 2.79 1576.00
3.02 4729.00 4.24 3180.00
3.55 7242.00 5.62 4784.00 6000.0
4.58 7654.00 7.06 5279.00
4.58 7657.00 7.68 5301.00
5.62 7246.00 8.44 5177.00
9.82 4890.00
11.20 4617.00 4000.0

2000.0

T/K = 548.2; x1 = 0.500

T/K = 598.2; x1 = 0.500
0.0
0.0 3.0 6.0 9.0 12.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σ (HE)/J mol-1 = 10 – 160 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0206

Components: 1. H2O, Water [7732-18-5]
2. C7H16, Heptane [142-82-5]
T/K = 448.2 T/K = 523.2
x1 = 0.500 x1 = 0.500 HM/J mol-1
16000
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
T/K = 448.20; x1 = 0.500
0.79 13515.00 2.48 9453.00
1.00 13400.00 2.82 9430.00 T/K = 523.20; x1 = 0.500
3.20 9259.00
3.54 9119.00
14000

12000

10000

8000
0.0 0.9 1.8 2.7 3.6
P/106Pa
Uncertainties: σ (P)/106Pa = 0.011 – 0.014; σ (HM)/J mol-1 = 180 – 270 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0223

Components: 1. H2O, Water [7732-18-5]
2. C8H18, Octane [111-65-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.200 T/K = 393.200 HE/J mol-1
400.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.425000 281.50 0.409000 209.30
0.438000 280.60 0.490000 211.30 P/103Pa = 101.325; T/K = 393.2
0.450000 298.80 0.498000 212.00
0.491000 297.40 0.515000 212.30
0.522000 287.50 0.540000 211.20 300.
0.547000 288.80 0.543000 212.60
0.596000 281.60 0.548000 208.80
0.602000 277.50 0.569000 208.10
0.615000 275.50 0.576000 210.70
0.630000 274.10 200.

100.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Smith, G. R.; Fahy, M. J.; Wormald, C. J. The excess molar enthalpy of {xH2O + (1-x)CnH2n+2}(g) for n = 5,6,7, and 8 J.
Chem. Thermodyn. 1984, 16, 825-831

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0158

Components: 1. H2O, Water [7732-18-5]
2. C8H18, Octane [111-65-9]
P/106Pa = 5.000 P/106Pa = 5.200
T/K = 573.20 T/K = 648.20 HE/J mol-1
10000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 5.000; T/K = 573.20
0.241000 5755.00 0.233000 3268.00 P/106Pa = 5.000; T/K = 598.20
0.382000 7700.00 0.402000 4007.00 P/106Pa = 7.000; T/K = 598.20
0.497000 7483.00 0.502000 3873.00 P/106Pa = 5.200; T/K = 648.20
0.667000 5782.00 0.699000 3082.00
0.761000 4481.00 0.760000 2395.00 7500.

5000.

2500.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σ (HE)/J mol-1
= 40 – 150 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0192

Components: 1. H2O, Water [7732-18-5]
2. C8H18, Octane [111-65-9]
T/K = 573.2 T/K = 598.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
10000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 573.2; x1 = 0.500
1.48 1302.00 0.55 327.00
1.86 1875.00 1.31 905.00 T/K = 598.2; x1 = 0.500
2.40 3240.00 2.00 1640.00
2.72 6656.00 2.14 1792.00
2.83 7716.00 2.46 2261.00 7500.0
3.05 8014.00 2.65 2577.00
3.29 8105.00 3.36 4587.00
3.79 8100.00 3.84 5890.00
4.41 7853.00 4.15 6503.00
4.98 7550.00 4.91 6561.00 5000.0
5.41 7071.00 5.03 6544.00
5.87 6970.00 5.65 6451.00
6.34 6633.00 6.20 6258.00
7.10 6167.00 6.86 5925.00
7.08 5833.00
7.34 5610.00 2500.0
8.09 5378.00
8.13 5435.00
9.03 4906.00
10.00 4610.00
0.0
0.0 2.5 5.0 7.5 10.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σ (HE)/J mol-1 = 6 – 28 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0207

Components: 1. H2O, Water [7732-18-5]
2. C8H18, Octane [111-65-9]
T/K = 498.2 T/K = 548.2
x1 = 0.500 x1 = 0.500 HM/J mol-1
16000.0
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
T/K = 498.20; x1 = 0.500
0.88 13400.00 1.86 9491.00
0.92 13179.00 1.90 9680.00 T/K = 523.20; x1 = 0.500
1.07 12988.00 1.98 9838.00 T/K = 548.20; x1 = 0.500
1.31 12838.00 2.26 9767.00
1.50 12461.00 2.57 9700.00 14000.0

12000.0

10000.0

8000.0
0.0 0.6 1.3 1.9 2.6
P/106Pa
Uncertainties: σ (P)/106Pa = 0.011 – 0.013; σ (HM)/J mol-1 = 190 – 270 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0361

Components: 1. C4H10, 2-Methylpropane [75-28-5]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –24.190 H°sol/103J mol-1
–18.
T/K = 298.15

–21.

–24.

–27.

–30.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 2.5
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0292

Components: 1. C4H10, 2-Methylpropane [75-28-5]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
273.24 –33.100 H°sol/103J mol-1
278.15 –31.240 –18.
283.15 –29.900
288.15 –27.180
293.15 –25.420
303.15 –22.280
308.15 –20.330 –22.

–26.

–30.

–34.
280. 290. 300.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10–0.70
Naghibi, H.; Ownby, D. W.; Gill, S. J. Enthalpies of solution of butanes in water from 5 to 45.deg.C J. Chem. Eng. Data 1987,
32, 422-425

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0335

Components: 1. C4H10, 2-Methylpropane [75-28-5]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –28.230 H°sol/103J mol-1
308.15 –20.670 –18.

–21.

–24.

–27.

–30.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.12–0.23
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0355

Components: 1. C5H12, 2,2-Dimethylpropane [463-82-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –25.110 H°sol/103J mol-1
–16.
T/K = 298.15

–20.

–24.

–28.

–32.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 1.7
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0329

Components: 1. C5H12, 2,2-Dimethylpropane [463-82-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –29.230 H°sol/103J mol-1
308.15 –19.520 –16.

–20.

–24.

–28.

–32.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.24–0.57
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0332

Components: 1. C3H6, Cyclopropane [75-19-4]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –26.060 H°sol/103J mol-1
308.15 –20.010 –19.

–21.

–23.

–25.

–27.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.11–0.19
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0358

Components: 1. C3H6, Cyclopropane [75-19-4]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –23.260 H°sol/103J mol-1
–19.
T/K = 298.15

–21.

–23.

–25.

–27.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.06
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0118

Components: 1. H2O, Water [7732-18-5]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 433.200 HE/J mol-1
100.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.352000 77.50 0.380000 63.00 P/103Pa = 101.325; T/K = 423.2
0.431000 82.50 0.427000 63.80 P/103Pa = 101.325; T/K = 433.2
0.480000 83.50 0.465000 65.80
0.575000 80.90 0.508000 68.00
0.633000 79.90 0.586000 65.10 75.

50.

25.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Lancaster, N. M.; Sowden, C. J. Benzene-water association. Excess molar enthalpy and second virial
cross-coefficients for (benzene + water)(g) and (cyclohexane + water)(g) J. Chem. Soc., Faraday Trans. 1997, 93, 1921-1926

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0233

Components: 1. H2O, Water [7732-18-5]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.2 HE/J mol-1
160.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.379000 120.80 0.407000 92.20
0.403000 120.80 0.476000 92.90 P/103Pa = 101.325; T/K = 393.2
0.457000 125.80 0.477000 94.00
0.487000 125.70 0.501000 94.70
0.508000 126.30 0.509000 93.60 120.
0.510000 126.70 0.510000 95.80
0.534000 125.20 0.516000 92.20
0.552000 126.10 0.533000 96.20
0.583000 123.80 0.570000 91.50
0.599000 121.80 0.571000 94.80 80.
0.586000 88.50
0.591000 89.70
0.616000 87.30
0.633000 86.20
0.641000 83.70
0.647000 85.50 40.
0.661000 86.20
0.728000 76.00

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Lancaster, N. M. Excess molar enthalpies for (water + benzene)(g) and (water + cyclohexane)(g) J. Chem.
Thermodyn. 1985, 17, 903-908

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0194

Components: 1. H2O, Water [7732-18-5]
2. C6H12, Cyclohexane [110-82-7]
T/K = 573.2 T/K = 648.2
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
8000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 573.2; x1 = 0.500
0.79 225.00 0.72 141.00 T/K = 648.2; x1 = 0.500
2.17 810.00 1.48 331.00
3.45 1719.00 2.72 714.00
4.93 3825.00 4.20 1238.00
6.37 6530.00 5.63 1905.00 6000.0
7.00 6648.00 6.93 2573.00
7.34 6632.00 8.37 3372.00
7.72 6647.00 9.79 3954.00
8.44 6573.00 11.20 4323.00
12.58 4380.00 4000.0

2000.0

0.0
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σ (HE)/J mol-1 = 6 – 130 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0205

Components: 1. H2O, Water [7732-18-5]
2. C6H12, Cyclohexane [110-82-7]
T/K = 448.2 T/K = 548.2
x1 = 0.500 x1 = 0.500 HM/J mol-1
14000
P/106Pa HM/J mol-1 P/106Pa HM/J mol-1
0.89 12088.00 4.24 7591.00
4.83 7846.00
5.62 7815.00
10500

7000

3500
T/K = 448.2; x1 = 0.500
T/K = 523.2; x1 = 0.500
T/K = 548.2; x1 = 0.500
0.0
0.0 2.0 4.0 6.0 8.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.015; σ (HM)/J mol-1 = 150–240 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0041

Components: 1. H2O, Water [7732-18-5]
2. C2H4, Ethene [74-85-1]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.4 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.357000 52.00 0.366000 34.90
0.407000 53.60 0.413000 37.70 P/103Pa = 101.325; T/K = 393.4
0.424000 55.40 0.448000 38.90
0.456000 55.40 0.473000 38.10
0.483000 56.60 0.499000 39.40 60.
0.521000 59.20 0.520000 39.20
0.533000 56.40 0.563000 38.60
0.573000 56.40 0.576000 38.40
0.588000 55.50 0.611000 37.80
0.628000 52.90 0.664000 34.10 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Lancaster, N. M.; Wormald, C. J. The excess molar enthalpies of {xH2O + (1-x)C2H6}(g) and {xH2O + (1-x)C2H4}(g) J.
Chem. Thermodyn. 1985, 17, 295-299

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0165

Components: 1. H2O, Water [7732-18-5]
2. C2H4, Ethene [74-85-1]
T/K = 573.20 T/K = 648.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
1200.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 498.20; x1 = 0.500
1.22 115.00 1.17 67.00
2.55 280.00 2.39 154.00 T/K = 573.20; x1 = 0.500
3.49 412.00 3.77 265.00 T/K = 648.20; x1 = 0.500
4.51 570.00 4.51 337.00
5.47 775.00 900.0
6.65 1090.00

600.0

300.0

0.0
0.0 2.0 4.0 6.0 8.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.003 – 0.009; σ (HE)/J mol-1 = 3.60 – 24 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0331

Components: 1. C2H4, Ethene [74-85-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –18.920 H°sol/103J mol-1
308.15 –14.180 –12.

–14.

–16.

–18.

–20.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.03
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0357

Components: 1. C2H4, Ethene [74-85-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –16.460 H°sol/103J mol-1
–12.
T/K = 298.15

–14.

–16.

–18.

–20.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.07
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0039

Components: 1. H2O, Water [7732-18-5]
2. C3H6, Propene [115-07-1]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.2 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.404000 59.50 0.404000 42.10
0.436000 61.10 0.438000 42.00 P/103Pa = 101.325; T/K = 393.2
0.454000 62.00 0.473000 44.40
0.493000 61.40 0.478000 45.00
0.497000 63.10 0.497000 44.30 60.
0.525000 63.80 0.506000 45.10
0.529000 64.10 0.532000 43.10
0.556000 63.60 0.555000 43.00
0.572000 62.50 0.589000 42.20
0.602000 60.10 0.631000 41.00 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Lancaster, N. M.; Wormald, C. J. The molar enthalpies for {xH2O + (1-x)C3H6}(g), {xH2O + (1-x)C3H8}(g), and {xH2O +
(1-x)C4H10}(g) J. Chem. Thermodyn. 1986, 18, 545-550

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0359

Components: 1. C3H6, Propene [115-07-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –21.640 H°sol/103J mol-1
–17.
T/K = 298.15

–19.

–21.

–23.

–25.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 1.2
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0333

Components: 1. C3H6, Propene [115-07-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –23.920 H°sol/103J mol-1
308.15 –18.420 –17.

–19.

–21.

–23.

–25.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.16
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0360

Components: 1. C4H8, But-1-ene [106-98-9]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –24.880 H°sol/103J mol-1
–18.
T/K = 298.15

–21.

–24.

–27.

–30.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 1.1
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0334

Components: 1. C4H8, But-1-ene [106-98-9]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –27.910 H°sol/103J mol-1
308.15 –20.380 –18.

–21.

–24.

–27.

–30.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.16–0.20
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0330

Components: 1. C2H2, Ethyne [74-86-2]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –16.170 H°sol/103J mol-1
308.15 –13.090 –10.

–12.

–14.

–16.

–18.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.09–0.12
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 15, 25, and 35.deg.C J. Solution Chem. 1985, 14
, 827-836

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0356

Components: 1. C2H2, Ethyne [74-86-2]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –14.620 H°sol/103J mol-1
–10.
T/K = 298.15

–12.

–14.

–16.

–18.
288. 298. 308.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.02
Dec, S. F.; Gill, S. J. Heats of solution of gaseous hydrocarbons in water at 25.deg.C J. Solution Chem. 1984, 13, 27-41

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0375

Components: 1. H2O, Water [7732-18-5]
2. C6H6, Benzene [71-43-2]
P/106Pa = 16.400 P/106Pa = 16.400
T/K = 503.000 T/K = 521.000 HE/J mol-1
10000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 16.4; T/K = 560
0.210000 4194.00 0.254000 5006.00 P/106Pa = 16.4; T/K = 544
0.252000 4709.00 0.328000 5981.00
0.271000 4858.00 0.344000 6156.00
0.290000 a 4724.00 0.360000 6160.00
0.326000 a 4520.00 0.420000 a 5602.00 7500.
0.361000 a 4294.00 0.483000 a 5064.00
0.418000 a 3959.00 0.539000 a 4566.00
0.484000 a 3575.00 0.587000 a 4199.00
0.537000 a 3250.00 0.620000 a 3843.00
0.585000 a 2971.00 0.665000 a 3438.00 5000.
0.627000 a 2707.00 0.698000 a 3260.00
0.663000 a 2473.00 0.752000 a 2772.00
0.696000 a 2294.00 0.797000 a 2358.00
0.750000 a 1967.00 0.834000 a 2047.00
0.797000 a 1681.00 0.894000 a 1465.00
0.834000 a 1434.00 0.938000 a 1012.00 2500.
0.893000 a 1020.00 0.972000 587.00
0.938000 692.00 0.987000 355.00
0.972000 395.00
P/106Pa = 16.4; T/K = 503
0.
0.50
x1
Uncertainties: σ (x1) = 0.0010; σ (HE)/J mol-1
= 0.70 + 0.020 |HE/J mol-1| a Two-phase region; See SELF for the totality of data
Wormald, C. J.; Slater, J. Excess enthalpies for (water + benzene) in the liquid and supercritical regions at T = 503 K to T = 592
K and p = 16.4 Pa J. Chem. Thermodyn. 1996, 28, 627-636

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0232

Components: 1. H2O, Water [7732-18-5]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.2 T/K = 393.2 HE/J mol-1
140.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.2
0.382000 93.90 0.403000 69.80
0.431000 97.30 0.445000 71.20 P/103Pa = 101.325; T/K = 393.2
0.464000 97.60 0.483000 72.50
0.499000 98.70 0.484000 70.60
0.503000 100.90 0.504000 70.40 105.
0.506000 102.30 0.528000 71.50
0.522000 99.80 0.566000 71.90
0.536000 99.10 0.575000 69.50
0.537000 100.20 0.616000 68.40
0.608000 96.30 0.638000 64.80 70.

35.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Lancaster, N. M. Excess molar enthalpies for (water + benzene)(g) and (water + cyclohexane)(g) J. Chem.
Thermodyn. 1985, 17, 903-908

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0117

Components: 1. H2O, Water [7732-18-5]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 403.200 T/K = 433.200 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 403.2
0.399000 63.60 0.440000 47.60
0.453000 64.50 0.502000 50.40 P/103Pa = 101.325; T/K = 433.2
0.494000 65.40 0.509000 49.20
0.557000 65.20 0.573000 48.60
0.618000 62.00 0.613000 48.00 60.

40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Lancaster, N. M.; Sowden, C. J. Benzene-water association. Excess molar enthalpy and second virial
cross-coefficients for (benzene + water)(g) and (cyclohexane + water)(g) J. Chem. Soc., Faraday Trans. 1997, 93, 1921-1926

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0203

Components: 1. H2O, Water [7732-18-5]
2. C6H6, Benzene [71-43-2]
T/K = 573.20 T/K = 648.20
x1 = 0.500 x1 = 0.500 HE/J mol-1
8000.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 573.20; x1 = 0.500
0.81 172.00 1.47 247.00 T/K = 598.20; x1 = 0.500
2.17 568.00 2.82 535.00 T/K = 648.20; x1 = 0.500
3.58 1217.00 4.96 1120.00
4.93 2435.00 7.03 1895.00
4.94 2387.00 9.13 2862.00 6000.0
5.62 4000.00 9.83 3148.00
6.34 6128.00 10.56 3385.00
6.65 6459.00 11.89 3697.00
7.00 6501.00 12.58 3759.00
7.34 6528.00 13.96 3771.00 4000.0
7.35 6544.00
7.68 6438.00
8.03 6418.00
8.37 6340.00

2000.0

T/K = 698.20; x1 = 0.500

0.0
0.0 4.0 8.0 12.0 16.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σ (HE)/J mol-1 = 5.4 – 130 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0376

Components: 1. C6H6, Benzene [71-43-2]
2. H2O, Water [7732-18-5]
P/106Pa = 16.400 P/106Pa = 16.400
T/K = 576.000 T/K = 581.000 HM/J mol-1
16000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 16.4; T/K = 576
0.051000 2407.00 0.027000 1413.00
0.100000 4244.00 0.061000 2932.00 P/106Pa = 16.4; T/K = 581
0.148000 5627.00 0.104000 4626.00
0.161000 5947.00 0.163000 6594.00
0.199000 7167.00 0.200000 7771.00 12000.
0.242000 8073.00 0.246000 9192.00
0.296000 9199.00 0.300000 10315.00
0.332000 9779.00 0.301000 10458.00
0.363000 10132.00 0.369000 10998.00
0.364000 10060.00 0.410000 11162.00 8000.
0.400000 10175.00 0.458000 10846.00
0.461000 9971.00 0.513000 10097.00
0.514000 9599.00 0.577000 9229.00
0.571000 8869.00 0.670000 7637.00
0.573000 8958.00 0.744000 6165.00
0.653000 7676.00 4000.
0.743000 6009.00

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HM)/J mol-1
= 0.70 + 0.02 |HM/J mol-1| See SELF for the totality of data
Wormald, C. J.; Slater, J. Excess enthalpies for (water + benzene) in the liquid and supercritical regions at T = 503 K to T = 592
K and p = 16.4 Pa J. Chem. Thermodyn. 1996, 28, 627-636

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0042

Components: 1. H2O, Water [7732-18-5]
2. C6H6, Benzene [71-43-2]
T/K = 548.200
x1 = 0.500 HM/J mol-1
9000
P/106Pa HM/J mol-1
T/K = 548.2; x1 = 0.50
4.93 8077.00

8500

8000

7500

7000
4.0 4.5 5.0 5.5 6.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σ (HM)/J mol-1 = 160
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1332] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
Variables: T/K, Temperature
H∞ -1
sol/J mol , Molar enthalpy of solution at infinite dilution of component 1
Method: H∞sol calculated by extrapolation to infinite dilution of direct calorimetric measurements of the molar enthalpy of
solution at variable T and constant P

File Number: LB0320

Components: 1. CF4, Tetrafluoromethane [75-73-0]
2. H2O, Water [7732-18-5]
P/103Pa = 100.000
T/K H∞ 3 -1 H∞ 3
sol/10 J mol
-1
sol/10 J mol
28815 –17.44
29815 –14.54 P/103Pa = 100.
30815 –12.37

–13.0

–15.0

–17.0

–19.0
288.0 298.0 308.0
T/K
Uncertainties: σ (T)/K = 0.02; σ (H∞ 3 -1
sol)/10 J mol = 0.10 – 0.40
Hallen, D.; Wadsoe, I. A new microcalorimetric vessel for dissolution of slightly soluble gases. Enthalpies of solution in water of
carbon tetrafluoride and sulphur hexafluoride at 288.15, 298.15, and 308.15 K J. Chem. Thermodyn. 1989, 21, 519-527

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0341

Components: 1. CF4, Tetrafluoromethane [75-73-0]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –15.770 H°sol/103J mol-1
308.15 –12.340 –12.

–13.

–14.

–15.

–16.
296. 303. 311.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.15–0.50
Naghibi, H.; Ownby, D. W.; Gill, S. J. Heats of solution of several freons in water from 5 to 45.deg.C J. Solution Chem. 1987,
16, 171-179

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0123

Components: 1. H2O, Water [7732-18-5]
2. C6F6, Hexafluorobenzene [392-56-3]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
145.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
378.20 140.00
383.20 131.00
388.20 123.00
393.20 117.00
398.20 113.00 125.
403.20 108.00
413.20 97.00
423.20 89.00
433.20 82.00
443.20 75.00 105.
453.20 68.00

85.

65.
394. 416. 438.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Wurzberger, B. The water-hexafluorobenzene interaction. Second virial cross coefficients for water -
hexafluorobenzene derived from gas phase excess enthalpy measurements Phys. Chem. Chem. Phys. 2000, 2, 5133-5137

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0234

Components: 1. H2O, Water [7732-18-5]
2. CH3Cl, Chloromethane [74-87-3]
P/103Pa T/K x1 HE/J mol-1 P/103Pa T/K x1 HE/J mol-1
62.800 363.20 0.4690 30.8 63.200 413.20 0.4970 16.3
62.600 363.20 0.5040 29.9 63.200 413.20 0.5090 16.6
62.800 363.20 0.5060 30.2 63.300 413.20 0.5150 16.0
63.200 363.20 0.5100 29.2 63.100 413.20 0.5320 15.7
63.200 363.20 0.5240 30.2 62.100 423.20 0.4700 14.1
63.900 373.20 0.4690 25.5 61.700 423.20 0.4750 14.1
63.700 373.20 0.4720 26.5 61.600 423.20 0.4910 13.4
63.900 373.20 0.4980 26.2 61.600 423.20 0.5190 13.7
63.700 373.20 0.4990 26.6 61.500 423.20 0.5390 14.3
63.900 373.20 0.5220 26.7
63.700 383.20 0.4590 23.3
63.700 383.20 0.4620 21.7
63.700 383.20 0.4830 23.3
63.700 383.20 0.4960 21.9
63.800 383.20 0.5340 23.1
60.500 393.20 0.4570 18.3
60.000 393.20 0.4780 19.3
60.400 393.20 0.4840 18.8
60.000 393.20 0.5230 19.3
60.400 393.20 0.5310 18.8
64.000 403.20 0.4750 17.7
64.000 403.20 0.4900 18.2
61.800 403.20 0.5090 18.0
61.700 403.20 0.5140 17.0
61.700 403.20 0.5340 17.2
63.500 413.20 0.4880 15.9

Uncertainties: σ (P)/103Pa = 0.1; σ (T)/K = 0.1; σ (x1) = 0.001; σ (HE)/J mol-1 = 0.10 + 0.020 |HE/J mol-1|
Wormald, C. J.; Lancaster, N. M. Excess enthalpies and cross-term second virial coefficients for mixtures containing water
vapour J. Chem. Soc., Faraday Trans. 1 1988, 84, 3141-3158

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0235

Components: 1. H2O, Water [7732-18-5]
2. C2H5Cl, Chloroethane [75-00-3]
P/103Pa T/K x1 HE/J mol-1 P/103Pa T/K x1 HE/J mol-1
54.200 363.20 0.4150 28.3 61.100 413.20 0.4910 18.0
54.000 363.20 0.4500 29.3 61.100 413.20 0.5050 19.1
54.100 363.20 0.4880 30.2 61.100 413.20 0.5120 19.3
58.200 363.20 0.4930 33.2 61.000 413.20 0.5240 19.4
58.300 363.20 0.5150 32.6 62.100 423.20 0.4930 17.4
55.100 373.20 0.4470 26.6 62.100 423.20 0.4950 15.9
54.900 373.20 0.5000 26.2 62.100 423.20 0.5030 15.7
54.800 373.20 0.5180 27.3 62.100 423.20 0.5140 17.2
54.900 373.20 0.5270 26.4 62.100 423.20 0.5380 17.0
54.900 373.20 0.5370 25.9
63.700 383.20 0.4720 26.7
63.700 383.20 0.4790 27.2
63.700 383.20 0.4960 26.6
63.700 383.20 0.5250 26.7
63.600 383.20 0.5300 27.3
66.000 393.20 0.4370 24.5
65.200 393.20 0.4680 25.4
65.200 393.20 0.4730 24.7
65.900 393.20 0.4940 25.0
64.300 393.20 0.5460 22.5
63.900 403.20 0.4490 19.6
63.600 403.20 0.4930 20.7
63.500 403.20 0.5260 21.5
63.600 403.20 0.5500 21.1
63.600 403.20 0.5640 21.3
61.000 413.20 0.4900 18.9

Uncertainties: σ (P)/103Pa = 0.1; σ (T)/K = 0.1; σ (x1) = 0.001; σ (HE)/J mol-1 = 0.10 + 0.020 |HE/J mol-1|
Wormald, C. J.; Lancaster, N. M. Excess enthalpies and cross-term second virial coefficients for mixtures containing water
vapour J. Chem. Soc., Faraday Trans. 1 1988, 84, 3141-3158

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0236

Components: 1. H2O, Water [7732-18-5]
2. CHCl3, Trichloromethane [67-66-3]
P/103Pa T/K x1 HE/J mol-1 P/103Pa T/K x1 HE/J mol-1
31.700 353.20 0.4220 17.7 99.000 403.20 0.3920 39.2
34.300 353.20 0.4460 19.1 100.200 403.20 0.4400 41.3
35.300 353.20 0.4900 20.9 100.500 403.20 0.4520 42.5
33.100 353.20 0.5230 18.7 99.800 403.20 0.4880 43.6
34.100 353.20 0.5250 18.6 100.300 403.20 0.5020 43.3
35.100 353.20 0.5820 19.4 100.100 403.20 0.4900 42.7
64.900 373.20 0.3250 28.3
65.000 373.20 0.3740 32.1
63.600 373.20 0.4040 29.7
63.800 373.20 0.4750 30.9
81.800 373.20 0.4930 40.7
63.600 373.20 0.5830 30.9
73.600 383.20 0.4300 33.5
75.000 383.20 0.4740 34.1
75.800 383.20 0.4970 34.9
76.400 383.20 0.5200 36.2
74.500 383.20 0.5250 35.1
75.900 383.20 0.5830 34.6
80.400 393.20 0.2460 25.6
80.400 393.20 0.2820 28.0
80.200 393.20 0.3220 30.3
80.600 393.20 0.4330 34.9
80.600 393.20 0.4630 35.1
80.200 393.20 0.4850 35.8
80.000 393.20 0.5540 34.4
80.800 393.20 0.6240 31.9

Uncertainties: σ (P)/103Pa = 0.100; σ (T)/K = 0.1; σ (x1) = 0.0010; σrel(HE) = 0.020 See SELF for the totality of data
Lancaster, N. M.; Wormald, C. J. The enthalpy of mixing of (water + trichloromethane) vapour Z. Phys. Chem.
(Frankfurt/Main) 1981, 128, 43-49

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0342

Components: 1. CClF3, Chlorotrifluoromethane [75-72-9]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
278.15 –26.740 H°sol/103J mol-1
288.15 –24.270 –15.
298.15 –21.530
308.15 –17.340
318.15 –16.210

–18.

–21.

–24.

–27.
283. 298. 313.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.20–0.40
Naghibi, H.; Ownby, D. W.; Gill, S. J. Heats of solution of several freons in water from 5 to 45.deg.C J. Solution Chem. 1987,
16, 171-179

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0343

Components: 1. CCl2F2, Dichlorodifluoromethane [75-71-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
278.15 –33.300 H°sol/103J mol-1
288.15 –29.690 –18.
298.15 –26.030
308.15 –23.340
318.15 –20.830

–22.

–26.

–30.

–34.
283. 298. 313.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10–0.50
Naghibi, H.; Ownby, D. W.; Gill, S. J. Heats of solution of several freons in water from 5 to 45.deg.C J. Solution Chem. 1987,
16, 171-179

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0344

Components: 1. CBrF3, Bromotrifluoromethane [75-63-8]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
278.15 –29.710 H°sol/103J mol-1
288.15 –26.910 –15.
298.15 –23.800
308.15 –20.320
318.15 –17.580

–19.

–23.

–27.

–31.
283. 298. 313.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.30–0.40
Naghibi, H.; Ownby, D. W.; Gill, S. J. Heats of solution of several freons in water from 5 to 45.deg.C J. Solution Chem. 1987,
16, 171-179

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0230

Components: 1. H2O, Water [7732-18-5]
2. CO, Carbon oxide [630-08-0]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.5 T/K = 403.2 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.5
0.438000 61.90 0.416000 34.50
0.455000 61.50 0.433000 34.00 P/103Pa = 101.325; T/K = 403.2
0.473000 58.60 0.460000 39.30
0.490000 60.00 0.492000 34.30
0.518000 59.40 0.507000 35.20 60.
0.532000 59.40 0.554000 37.80
0.578000 55.70 0.591000 34.80
0.590000 55.50 0.608000 34.40
0.598000 56.90 0.640000 32.80
0.645000 36.90 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Smith, G. R.; Wormald, C. J. The excess molar enthalpies of {xH2O + (1-x)CO}(g) and {xH2O + (1-x)CO2}(g) J. Chem.
Thermodyn. 1984, 16, 543-550

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0162

Components: 1. H2O, Water [7732-18-5]
2. CO, Carbon oxide [630-08-0]
T/K = 573.20 T/K = 473.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
1400.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
3.58 470.00 0.76 170.00
4.79 688.00 1.40 351.00
5.75 861.00 1.91 525.00
6.99 1201.00
1050.

700.

350.
T/K = 473.20; x1 = 0.500
T/K = 573.20; x1 = 0.500
T/K = 698.20; x1 = 0.500
0.
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.30 – 0.22; σ (HE)/J mol-1 = 4.5 – 26 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0440

Components: 1. H2O, Water [7732-18-5]
2. CO, Carbon oxide [630-08-0]
P/106Pa T/K x1 HE/J mol-1
3.600 584.30 0.4910 361.0
6.470 586.50 0.5050 832.0
9.420 587.40 0.5030 1617.0
3.630 690.10 0.4950 165.0
6.390 690.00 0.5000 329.0
6.190 692.20 0.5290 320.0
6.120 693.70 0.5520 306.0
9.010 689.50 0.5140 545.0
9.010 691.90 0.5200 541.0
9.310 693.40 0.5200 538.0
10.860 689.30 0.4990 733.0
11.000 691.80 0.5050 711.0
10.860 691.50 0.5170 685.0
12.980 690.50 0.5000 953.0

Uncertainties: σrel(P) = 0.002; σ (T)/K = 1.0; σ (x1) = 0.0010; σrel(HE) = 0.030

Wilson, G. M.; Brady, C. J. Heats of mixing of steam with N2, CO2, H2, CH4, and CO at high temperatures and pressures using
a new high temperature calorimeter Gas Process. Assoc., Res. Rep. (cf. August 1995 List of Publications (CD-ROM available:
call 1-800-241-7842; fax 1-303-397-2599) 1983, (RR-73), 1-46

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0231

Components: 1. H2O, Water [7732-18-5]
2. CO2, Carbon dioxide [124-38-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.4 T/K = 392.6 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.4
0.420000 47.00 0.388000 37.80
0.443000 49.80 0.413000 35.10 P/103Pa = 101.325; T/K = 392.6
0.487000 58.40 0.425000 33.30
0.494000 55.10 0.451000 39.10
0.514000 57.30 0.469000 40.40 60.
0.517000 51.20 0.492000 35.30
0.563000 52.60 0.523000 40.50
0.579000 54.20 0.531000 37.70
0.582000 55.80 0.660000 31.80
0.609000 54.60 0.683000 30.00 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.02 See SELF for the totality of data
Smith, G. R.; Wormald, C. J. The excess molar enthalpies of {xH2O + (1-x)CO}(g) and {xH2O + (1-x)CO2}(g) J. Chem.
Thermodyn. 1984, 16, 543-550

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0153

Components: 1. H2O, Water [7732-18-5]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 4.960 P/106Pa = 5.000
T/K = 548.200 T/K = 648.200 HE/J mol-1
1000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.960; T/K = 548.20
0.301000 559.00 0.305000 253.00
0.405000 665.00 0.408000 296.00 P/106Pa = 4.960; T/K = 598.20
0.505000 718.00 0.511000 313.00 P/106Pa = 5.000; T/K = 648.20
0.608000 723.00 0.611000 301.00
0.716000 640.00 0.713000 266.00 750.

500.

250.

0.
0.50
x1
Uncertainties: σ (x1) = 0.0020; σ (HE)/J mol-1
= 5 – 14 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0163

Components: 1. H2O, Water [7732-18-5]
2. CO2, Carbon dioxide [124-38-9]
T/K = 573.20 T/K = 598.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
1800.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 548.20; x1 = 0.500
0.74 61.00 1.40 99.00
1.48 124.00 2.68 203.00 T/K = 573.20; x1 = 0.500
2.33 214.00 3.91 331.00 T/K = 698.20; x1 = 0.500
3.09 312.00 4.19 381.00
4.49 512.00 5.01 474.00 1350.0
5.18 623.00 5.37 528.00
5.32 665.00 5.69 559.00
5.69 742.00 5.90 606.00
6.10 830.00 6.81 763.00
6.42 912.00 7.34 825.00 900.0
6.53 943.00 7.76 947.00
6.60 977.00 8.22 1033.00
6.81 1028.00 8.79 1183.00
6.96 1082.00 8.92 1195.00
7.21 1161.00 9.24 1289.00
9.62 1413.00 450.0
10.20 1694.00
10.41 1859.00
10.60 1844.00
11.10 1885.00
11.10 2111.00
11.49 2355.00 0.0
0.0 5.5 11.0 16.5 22.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.003 – 0.03; σ (HE)/J mol-1 = 3.50 – 150 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0043

Components: 1. H2O, Water [7732-18-5]
2. CO2, Carbon dioxide [124-38-9]
T/K = 649.40 T/K = 698.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
11500.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 649.4; x1 = 0.500
20.00 3617.00 20.25 1775.00 T/K = 654.3; x1 = 0.500
20.25 3965.00 20.60 1823.00 T/K = 698.2; x1 = 0.500
20.70 4031.00 20.70 1824.00
21.70 5162.00 21.00 1916.00
22.35 6568.00 22.40 2167.00 9000.
23.30 9258.00 23.20 2290.00
23.35 9640.00 24.30 2540.00
24.95 10146.00 25.20 2680.00
25.20 9915.00
25.55 9944.00 6500.

4000.

1500.
20.0 21.5 23.0 24.5 26.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.050; σrel(HE) = 0.020 See SELF for the totality of data
Wormald, C. J.; Lloyd, M. J.; Fenghour, A. The excess molar enthalpy of (steam + carbon dioxide) in the supercritical region
up to T = 698.2 K and p = 25.5 MPa J. Chem. Thermodyn. 1997, 29, 1253-1260

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0441

Components: 1. H2O, Water [7732-18-5]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa T/K x1 HE/J mol-1
3.370 694.00 0.4840 131.0
6.900 692.70 0.4960 320.0
10.290 692.30 0.4840 525.0
13.780 693.50 0.4780 822.0
17.090 692.70 0.4720 1148.0
3.520 804.30 0.4800 112.0
6.880 804.00 0.5120 206.0
10.390 803.80 0.4900 299.0
13.840 803.50 0.4820 417.0
17.090 802.10 0.4760 542.0
17.120 801.90 0.4740 539.0
3.430 914.40 0.4810 99.0
6.880 913.80 0.5080 148.0
10.320 913.10 0.4940 216.0
13.710 912.80 0.4800 285.0
17.190 910.90 0.4760 335.0

Uncertainties: σrel(P) = 0.002; σ (T)/K = 1.0; σ (x1) = 0.0010; σrel(HE) = 0.030

Wilson, G. M.; Brady, C. J. Heats of mixing of steam with N2, CO2, H2, CH4, and CO at high temperatures and pressures using
a new high temperature calorimeter Gas Process. Assoc., Res. Rep. (cf. August 1995 List of Publications (CD-ROM available:
call 1-800-241-7842; fax 1-303-397-2599) 1983, (RR-73), 1-46

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0226

Components: 1. CO2, Carbon dioxide [124-38-9]
2. H2O, Water [7732-18-5]
P/106Pa = 11.000 P/106Pa = 12.400
T/K = 498.150 T/K = 548.150 HM/J mol-1
20000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 11.0; T/K = 573.15
0.017300 186.00 0.034900 1181.00 P/106Pa = 12.4; T/K = 548.15
0.034000 381.00 0.066700 2339.00
0.044700 509.00 0.084100 2354.00
0.050100 575.00 0.102700 3741.00
0.061800 735.00 0.122500 3998.00 15000.
0.085700 1038.00 0.166400 5993.00
0.116400 1383.00 0.217200 7200.00
0.149400 1813.00 0.245700 8200.00
0.180100 2175.00 0.276600 9318.00
0.226500 2722.00 0.310200 10002.00 10000.
0.305200 3710.00 0.347000 11384.00
0.397200 4816.00 0.387300 12026.00
0.467700 5650.00 0.431800 14026.00
0.523400 6435.00 0.455800 13206.00
0.637300 8002.00 0.481000 12855.00
0.724900 7853.00 0.535900 11688.00 5000.
0.737600 7520.00 0.565700 11130.00
0.759800 6856.00 0.597300 10301.00
0.778500 6245.00 0.666700 7725.00
0.814600 5303.00 0.745600 6658.00 P/106Pa = 10.4; T/K = 523.15
0.840500 4548.00 0.836100 4406.00 P/106Pa = 10.4; T/K = 498.15
0.875400 3264.00 0.886600 3062.00 0.
0.913400 2270.00 0.941000 1523.00 0.50
0.921300 2094.00
x1
Uncertainties: σ (x1) = 0.00020; σrel
(HM) = 0.03 [Undefined two-phase regions]; See SELF for the totality of data
Chen, X.; Gillespie, S. E.; Oscarson, J. L.; Izatt, R. M. Calorimetric determination of thermodynamic quantities for chemical
reactions in the system CO2 - NaOH - H2O from 225 to 325.deg.C J. Solution Chem. 1992, 21, 825-848

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1222] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable x1 and constant P and T, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0444

Components: 1. H2O, Water [7732-18-5]
2. CH4O, Methanol [67-56-1]
P/106Pa = 7.000 P/106Pa = 40.000
T/K = 373.150 T/K = 573.150 HE/J mol-1
1500.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 40.0; T/K = 573.15
0.100000 –105.00 0.100000 440.00 P/106Pa = 20.0; T/K = 523.15
0.200000 –158.00 0.200000 790.00
0.300000 –184.00 0.300000 1050.00
0.400000 –199.00 0.400000 1225.00
0.500000 –214.00 0.500000 1290.00 1000.
0.600000 –230.00 0.600000 1260.00
0.700000 –239.00 0.700000 1130.00
0.800000 –225.00 0.800000 870.00
0.900000 –159.00 0.900000 495.00
500.

0.

P/106Pa = 20.0; T/K = 423.15

P/106Pa = 7.0; T/K = 373.15
–500.
0.50
x1
Uncertainties: σrel(HE)
= 0.03 See SELF for the totality of data
Simonson, J. M.; Bradley, D. J.; Busey, R. H. Excess molar enthalpies and the thermodynamics of (methanol + water) to 573 K
and 40 MPa J. Chem. Thermodyn. 1987, 19, 479-492

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0382

Components: 1. CH4O, Methanol [67-56-1]
2. H2O, Water [7732-18-5]
P/106Pa = 20.000
T/K = 523.00 HM/J mol-1
1000.
x1 HM/J mol-1
P/106Pa = 20.0; T/K = 523
0.162000 478.00
0.203000 565.00
0.280000 690.00
0.354000 773.00
0.393000 795.00 750.
0.483000 818.00
0.560000 808.00
0.648000 737.00
0.687000 675.00
0.750000 590.00 500.

250.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM)
= 0.03
Wormald, C. J.; Badock, L.; Lloyd, M. J. Excess enthalpies for (water + methanol) at T = 423 K to T = 523 K and pressures up
to 20 MPa. A new flow mixing calorimeter J. Chem. Thermodyn. 1996, 28, 603-613

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1351] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable P and constant T and x1

File Number: LB0381

Components: 1. CH4O, Methanol [67-56-1]
2. H2O, Water [7732-18-5]
T/K = 523.
x1 = 0.500 HM/J mol-1
1000.
P/106Pa HM/J mol-1
T/K = 523.00; x1 = .500
10.100 6.100
11.700 237.000
11.900 272.000
12.400 387.000
14.400 490.000 750.
16.100 640.000
16.500 680.000
18.000 750.000
20.100 820.000
500.

250.

0.
8. 12. 16. 20. 24.
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HM) = 0.03
Wormald, C. J.; Badock, L.; Lloyd, M. J. Excess enthalpies for (water + methanol) at T = 423 K to T = 523 K and pressures up
to 20 MPa. A new flow mixing calorimeter J. Chem. Thermodyn. 1996, 28, 603-613

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0398

Components: 1. H2O, Water [7732-18-5]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 0.400 P/106Pa = 10.000
T/K = 298.150 T/K = 298.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 5.0; T/K = 298.15
0.054800 –103.90 0.062300 –118.80
0.105600 –150.10 0.105600 –165.10
0.184600 –202.40 0.184600 –227.10
0.254800 –242.40 0.254800 –260.30
0.317500 –270.10 0.314200 –296.70 –200.
0.382800 –313.30 0.382800 –336.10
0.448800 –361.00 0.448800 –384.90
0.507000 –416.80 0.507000 –436.30
0.558800 –469.90 0.558800 –487.40
0.605100 –523.60 0.605100 –539.10 –400.
0.646900 –572.10 0.646900 –588.10
0.684700 –616.20 0.684700 –632.10
0.719000 –654.20 0.719000 –671.00
0.750400 –691.90 0.750400 –706.90
0.779200 –724.70 0.779200 –734.40
0.805600 –746.30 0.805600 –753.80 –600.
0.830100 –762.70 0.830100 –765.20
0.852700 –765.90 0.852700 –765.00
0.873700 –756.40 0.873700 –747.90
0.893300 –715.90 0.893300 –715.00
0.928700 –575.40 0.908600 –673.60
0.944700 –478.10 0.936900 –536.50 –800.
0.959800 –350.20 0.949900 –446.50 0.50
0.987400 –113.00 0.974000 –241.30
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE) = 0.02 See SELF for the totality of data
Zhao, J. P.; Tremaine, P. R. Excess enthalpies of (carbon dioxide + propylene carbonate or N-methyl-.epsilon.-caprolactam or
1-formylpiperidine) at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.5 MPa J. Chem. Thermodyn.
1995, 27, 1169-1185

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0383

Components: 1. H2O, Water [7732-18-5]
2. C2H6O, Ethanol [64-17-5]
P/106Pa = 15.000 P/106Pa = 15.000
T/K = 448.000 T/K = 513.000 HE/J mol-1
2000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 15.0; T/K = 423
0.150000 484.00 0.200000 928.00 P/106Pa = 15.0; T/K = 473
0.200000 623.00 0.250000 1102.00 P/106Pa = 15.0; T/K = 513
0.250000 742.00 0.300000 1257.00
0.300000 849.00 0.350000 1380.00
0.350000 951.00 0.400000 1483.00 1500.
0.400000 997.00 0.450000 1504.00
0.500000 1078.00 0.500000 1581.00
0.550000 1084.00 0.550000 1584.00
0.600000 1079.00 0.600000 1575.00
0.650000 1045.00 0.650000 1515.00 1000.
0.700000 980.00 0.700000 1454.00
0.750000 882.00 0.750000 1336.00
0.800000 780.00 0.800000 1167.00
0.850000 632.00 0.850000 964.00
0.900000 703.00
500.

0.
0.50
x1
Uncertainties: σ (x1) = 0.0010; σrel
(HE)
= 0.03 See SELF for the totality of data
Wormald, C. J.; Lloyd, M. J. Excess enthalpies for (water + ethanol) at T = 398 K to T = 548 K and p = 15 MPa J. Chem.
Thermodyn. 1996, 28, 615-626

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0384

Components: 1. C2H6O, Ethanol [64-17-5]
2. H2O, Water [7732-18-5]
P/106Pa = 15.000 P/106Pa = 15.000
T/K = 523.000 T/K = 538.000 HM/J mol-1
2400.
x1 HM/J mol-1 x1 HM/J mol-1
0.100000 730.00 0.200000 1354.00
0.150000 1020.00 0.250000 1550.00
0.200000 1236.00 0.300000 1705.00
0.250000 1416.00 0.350000 1800.00
0.300000 1535.00 0.400000 1868.00 1800.
0.350000 1623.00 0.450000 1917.00
0.400000 1699.00 0.500000 1920.00
0.400000 1705.00 0.550000 1861.00
0.450000 1726.00 0.600000 1797.00
0.450000 1696.00 0.650000 1705.00 1200.
0.500000 1714.00 0.700000 1529.00
0.500000 1702.00 0.750000 1382.00
0.550000 1656.00 0.800000 1096.00
0.550000 1685.00 0.850000 916.00
0.600000 1609.00 0.900000 650.00
0.600000 1583.00 600.
0.600000 1614.00
0.650000 1485.00 P/106Pa = 15.0; T/K = 548
0.650000 1504.00
0.750000 1199.00 P/106Pa = 15.0; T/K = 538
P/106Pa = 15.0; T/K = 523
0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM)= 0.03 See SELF for the totality of data
Wormald, C. J.; Lloyd, M. J. Excess enthalpies for (water + ethanol) at T = 398 K to T = 548 K and p = 15 MPa J. Chem.
Thermodyn. 1996, 28, 615-626

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0106

Components: 1. H2O, Water [7732-18-5]
2. C3H6O, Propan-2-one [67-64-1]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
–4.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
383.20 –36.00
388.20 –30.00
393.20 –28.00
398.20 –27.00
403.20 –23.00 –13.
408.20 –20.00
413.20 –17.00
418.20 –14.00
423.20 –15.00
428.20 –12.00 –22.
433.20 –10.00
438.20 –11.00
443.20 –8.00

–31.

–40.
400. 420. 440.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.00
Wormald, C. J. Water-acetone association. Second virial cross coefficients for water-acetone derived from gas phase excess
enthalpy measurements J. Chem. Thermodyn. 2002, 34, 1639-1646

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0006

Components: 1. Ar, Argon [7440-37-1]
2. H2, Dihydrogen [1333-74-0]
T/K = 169.000 T/K = 293.000
x1 = 0.5400 x1 = 0.5400 HE/J mol-1
1200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 169.00; x1 = 0.540
4.590 220.000 1.885 20.600
4.945 252.000 2.249 24.100 T/K = 201.00; x1 = 0.540
5.239 285.000 2.634 27.800 T/K = 231.00; x1 = 0.540
5.522 319.000 2.979 32.200
5.887 350.000 3.810 42.200 900. T/K = 293.00; x1 = 0.540
7.062 555.000 4.266 48.200
7.224 589.000 4.671 53.000
8.076 761.000 5.299 59.900
8.228 787.000 5.765 66.500
9.525 989.000 6.475 74.500 600.
9.707 1003.000 7.062 80.500
10.943 1043.000 7.376 86.000
11.055 1058.000 7.924 93.800
12.179 1052.000 7.944 92.200
12.625 1029.000 8.481 99.500
12.676 1061.000 8.684 103.000 300.
13.101 1029.000 9.069 110.000

0.
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Knoester, M.; Taconis, K. W.; Beenakker, J. J. M. Excess enthalpies of gaseous mixtures of hydrogen, nitrogen and argon
between 150 and 293.deg.K and at pressures up to 130 atm Physica (Amsterdam) 1967, 33, 389-409

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0003

Components: 1. H2, Dihydrogen [1333-74-0]
2. H2O, Water [7732-18-5]
P/106Pa = 10.51 P/106Pa = 11.13
T/K = 598.200 T/K = 698.200 HE/J mol-1
2800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 10.51; T/K = 598.200
0.263000 1789.00 0.257000 804.00
0.371000 2025.00 0.370000 878.00 P/106Pa = 11.13; T/K = 698.200
0.481000 1990.00 0.482000 941.00
0.588000 1783.00 0.591000 852.00
0.690000 1482.00 0.693000 743.00 2100.

1400.

700.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.020
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0224

Components: 1. H2, Dihydrogen [1333-74-0]
2. H2O, Water [7732-18-5]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 393.2 T/K = 423.2 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 383.2
0.263000 33.50 0.359000 29.40
0.362000 40.30 0.392000 30.50 P/103Pa = 101.325; T/K = 393.2
0.481000 45.40 0.420000 31.40 P/103Pa = 101.325; T/K = 423.2
0.588000 42.80 0.425000 31.70
0.598000 42.30 0.447000 30.50 60.
0.649000 39.40 0.501000 32.40
0.738000 32.00 0.516000 32.90
0.542000 32.20
0.553000 32.40
0.570000 30.70 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE) = 0.02 See SELF for the totality of data
Smith, G. R.; Sellars, A. J.; Yerlett, T. K.; Wormald, C. J. The excess enthalpy of (water + hydrogen) vapour and (water +
methane) vapour J. Chem. Thermodyn. 1983, 15, 29-35

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0160

Components: 1. H2, Dihydrogen [1333-74-0]
2. H2O, Water [7732-18-5]
T/K = 523.20 T/K = 698.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
2400.0
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 523.2; x1 = 0.500
0.76 108.00 0.79 41.00
1.06 182.00 2.09 149.00 T/K = 573.2; x1 = 0.500
1.44 228.00 2.93 173.00 T/K = 648.2; x1 = 0.500
2.00 386.00 2.93 173.00
2.13 372.00 4.05 292.00 1800.0
2.86 540.00 4.96 322.00
2.90 609.00 4.96 321.00
3.31 736.00 5.85 433.00
3.55 750.00 7.06 492.00
3.55 750.00 7.80 594.00 1200.0
9.20 687.00
9.20 687.00
9.84 785.00
11.10 884.00
11.10 891.00
11.13 891.00 600.0
11.90 992.00

0.0
0.0 3.0 6.0 9.0 12.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.004 – 0.015; σ (HE)/J mol-1 = 3 – 35 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0442

Components: 1. H2, Dihydrogen [1333-74-0]
2. H2O, Water [7732-18-5]
P/106Pa T/K x1 HE/J mol-1
3.510 689.10 0.4940 229.0
7.010 689.50 0.4930 525.0
10.470 689.00 0.5120 865.0
13.670 689.10 0.4930 1212.0
16.610 688.40 0.5060 1556.0
3.580 801.90 0.4930 151.0
3.700 802.80 0.5010 161.0
6.800 799.00 0.4980 323.0
10.370 797.20 0.4950 515.0
13.650 799.20 0.4970 708.0
16.780 800.30 0.4840 860.0
3.430 912.80 0.4940 119.0
5.560 911.70 0.4960 181.0
8.320 912.10 0.5010 284.0
11.270 908.70 0.4940 382.0
13.590 912.40 0.4970 462.0

Uncertainties: σrel(P) = 0.002; σ (T)/K = 1.0; σ (x1) = 0.0010; σrel(HE) = 0.030

Wilson, G. M.; Brady, C. J. Heats of mixing of steam with N2, CO2, H2, CH4, and CO at high temperatures and pressures using
a new high temperature calorimeter Gas Process. Assoc., Res. Rep. (cf. August 1995 List of Publications (CD-ROM available:
call 1-800-241-7842; fax 1-303-397-2599) 1983, (RR-73), 1-46

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0033

Components: 1. H2, Dihydrogen [1333-74-0]
2. N2, Dinitrogen [7727-37-9]
P/106Pa = 2.130 P/106Pa = 10.240
T/K = 298.000 T/K = 298.000 HE/J mol-1
360.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.190; T/K = 201
0.252000 13.00 0.206000 66.00 P/106Pa = 11.240; T/K = 201
0.390000 17.00 0.317000 90.00 P/106Pa = 2.130; T/K = 298
0.420000 18.00 0.400000 94.00
0.450000 18.00 0.544000 94.00
P/106Pa = 10.240; T/K = 298
0.489000 21.00 0.621000 85.00 270.
0.514000 22.00 0.628000 87.00
0.540000 18.00 0.723000 67.00
0.592000 20.00 0.785000 58.00
0.654000 18.00
0.701000 13.00 180.

90.

0.
0.50
x1
Uncertainties: σ (x1) = 0.003; σrel
(HE)= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, K. L.; Mosedale, S. The excess enthalpies of hydrogen + methane, hydrogen + nitrogen, methane +
nitrogen, methane + argon, and nitrogen + argon at 298 and 201 K at pressures up to 10.2 MPa J. Chem. Thermodyn. 1977, 9
, 27-42

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0397

Components: 1. H2, Dihydrogen [1333-74-0]
2. N2, Dinitrogen [7727-37-9]
T/K = 279.95 T/K = 279.95
x1 = 0.4900 x1 = 0.4900 HE/J mol-1
400.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 200.49; x1 = 0.49
1.99 23.20 6.51 74.00
2.36 27.50 6.54 74.90 T/K = 279.95; x1 = 0.49
2.67 30.30 6.78 78.20
2.85 32.30 7.08 80.00
3.02 34.40 7.17 81.60 300.
3.26 37.60 7.27 83.00
3.26 37.70 7.43 85.00
3.58 41.20 7.60 86.50
3.71 42.00 8.07 92.40
3.95 45.20 8.23 93.50 200.
3.98 45.70 8.33 95.50
4.30 46.90 8.60 99.80
4.33 49.30 8.74 99.70
4.51 51.80 9.08 103.50
4.74 54.30 9.44 107.30
4.78 54.60 9.67 111.50 100.
5.02 56.90 10.66 119.50
5.16 59.30 10.98 124.00
5.23 59.50 11.79 132.00
5.50 62.20 11.82 133.00
5.61 65.10 12.17 135.40
5.67 65.40 12.47 139.00 0.
5.99 68.10 12.76 142.90 0.0 3.5 7.0 10.5 14.0
5.99 68.50 12.86 146.00
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.04 See SELF for the totality of data
Lee, J. I. The excess enthalpy of gaseous mixtures M. Sc. Thesis (Univ. Alberta, Edmonton, Canada) 1970, , 1-121

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0008

Components: 1. H2, Dihydrogen [1333-74-0]
2. N2, Dinitrogen [7727-37-9]
T/K = 147.000 T/K = 147.000
x1 = 0.7500 x1 = 0.2200 HE/J mol-1
1000.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 147.0; x1 = 0.475
5.938 329.000 3.506 162.000 T/K = 170.0; x1 = 0.475
6.302 354.000 3.810 185.000 T/K = 201.0; x1 = 0.475
6.617 379.000 4.104 204.000
6.819 403.000 4.347 230.000
T/K = 293.0; x1 = 0.475
7.174 420.000 5.816 466.000 750.
7.316 433.000 6.090 505.000
7.478 430.000 6.333 539.000
7.640 448.000 6.576 572.000
7.660 450.000 6.769 608.000
8.045 463.000 6.981 629.000 500.
8.106 453.000 7.184 652.000
8.410 460.000 7.376 683.000
8.572 470.000 7.528 662.000
8.663 486.000 7.610 695.000
8.724 468.000 7.701 675.000
8.927 486.000 7.974 691.000 250.
9.038 492.000 8.197 696.000
9.352 494.000 8.876 698.000
9.707 494.000 9.160 688.000
9.991 498.000 9.403 676.000
10.193 488.000 10.892 650.000
10.507 491.000 11.511 599.000 0.
11.115 482.000 0.0 3.5 7.0 10.5 14.0
11.348 479.000
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Knoester, M.; Taconis, K. W.; Beenakker, J. J. M. Excess enthalpies of gaseous mixtures of hydrogen, nitrogen and argon
between 150 and 293.deg.K and at pressures up to 130 atm Physica (Amsterdam) 1967, 33, 389-409

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0030

Components: 1. H2, Dihydrogen [1333-74-0]
2. CH4, Methane [74-82-8]
P/106Pa = 2.130 P/106Pa = 7.700
T/K = 201.000 T/K = 298.000 HE/J mol-1
2400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 3.18; T/K = 201
0.116000 69.00 0.218000 187.00 P/106Pa = 9.14; T/K = 201
0.240000 114.00 0.369000 234.00 P/106Pa = 1.62; T/K = 298
0.351000 134.00 0.425000 241.00
0.491000 145.00 0.430000 244.00
0.655000 124.00 0.674000 193.00 1800.
0.675000 191.00

1200.

600.

0.
0.50
x1
Uncertainties: σ (x1) = 0.003; σrel
(HE)= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, K. L.; Mosedale, S. The excess enthalpies of hydrogen + methane, hydrogen + nitrogen, methane +
nitrogen, methane + argon, and nitrogen + argon at 298 and 201 K at pressures up to 10.2 MPa J. Chem. Thermodyn. 1977, 9
, 27-42

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0101

Components: 1. H2, Dihydrogen [1333-74-0]
2. CH4, Methane [74-82-8]
P/106Pa = 3.150 P/106Pa = 3.640
T/K = 183.000 T/K = 183.000 HE/J mol-1
1000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 2.13; T/K = 183
0.146000 303.00 0.130000 529.00
0.262000 376.00 0.225000 649.00 P/106Pa = 3.15; T/K = 183
0.442000 388.00 0.472000 619.00 P/106Pa = 3.64; T/K = 183
0.579000 343.00 0.748000 365.00
0.699000 278.00 750.

500.

250.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.04 See SELF for the totality of data
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpies of mixing of methane + argon, methane + nitrogen, and methane
+ hydrogen in the gaseous and two-phase regions J. Chem. Thermodyn. 1977, 9, 121-131

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0074

Components: 1. H2, Dihydrogen [1333-74-0]
2. CH4, Methane [74-82-8]
T/K = 201.200 T/K = 292.500
x1 = 0.4400 x1 = 0.4400 HE/J mol-1
1200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 201.2; x1 = 0.440
1.459 81.500 0.993 28.000
1.652 100.000 1.408 39.800 T/K = 230.6; x1 = 0.440
1.844 111.000 2.077 58.100 T/K = 292.5; x1 = 0.440
2.128 141.000 2.351 66.500
2.341 160.000 2.726 80.900 900.
2.533 188.000 3.303 101.000
2.766 217.000 4.306 134.000
4.580 552.000 4.833 153.000
4.732 592.000 5.299 171.000
4.874 655.000 5.360 168.000 600.
5.056 729.000 5.705 189.000
5.228 816.000 5.796 185.000
6.313 213.000
6.880 242.000
7.995 285.000
8.461 298.000 300.
8.927 308.000
10.710 381.000
11.196 392.000

0.0
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Van Eijnsbergen, B.; Beenakker, J. J. M. Measurements of the isobaric heat of mixing for gaseous mixtures CH4-Ar, CH4-N2,
H2-CH4, He-CH4 and He-Ar between 170 and 293 K and at pressures up to 120 atm Physica (Amsterdam) 1968, 39, 499-518

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0282

Components: 1. H2, Dihydrogen [1333-74-0]
2. CH4, Methane [74-82-8]
P/106Pa = 5.160 P/106Pa = 7.710
T/K = 183.000 T/K = 183.000 HM/J mol-1
4000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 4.14; T/K = 183
0.138000 2863.00 0.201000 1434.00
0.258000 2831.00 0.332000 2109.00 P/106Pa = 6.17; T/K = 183
0.412000 2300.00 0.493000 1813.00 P/106Pa = 9.13; T/K = 183
0.562000 1809.00 0.628000 1471.00
0.675000 1340.00 0.728000 1091.00 3000.

2000.

1000.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HM)= 0.04 See SELF for the totality of data
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpies of mixing of methane + argon, methane + nitrogen, and methane
+ hydrogen in the gaseous and two-phase regions J. Chem. Thermodyn. 1977, 9, 121-131

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0044

Components: 1. Ar, Argon [7440-37-1]
2. He, Helium [7440-59-7]
P/103Pa = 1000
T/K = 303.150 HE/J mol-1
32.
x1 HE/J mol-1
P/103Pa = 1000.; T/K = 303.150
0.182000 13.70
0.201000 14.00
0.347000 19.80
0.427000 23.10
0.478000 25.00 24.
0.594000 23.30
0.772000 19.00
0.787000 18.20
0.893000 12.80
16.

8.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.020
Naumowicz, E.; Olesiak, K.; Woycicki, W. Excess enthalpy of (argon + helium) J. Chem. Thermodyn. 1981, 13, 899-900

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0077

Components: 1. Ar, Argon [7440-37-1]
2. He, Helium [7440-59-7]
T/K = 169.600 T/K = 169.600
x1 = 0.2600 x1 = 0.2600 HE/J mol-1
1200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 169.6; x1 = 0.540
2.361 104.000 10.001 743.000
2.624 119.000 10.031 764.000 T/K = 201.1; x1 = 0.540
2.898 133.000 10.396 791.000 T/K = 231.0; x1 = 0.540
3.131 149.000 10.578 817.000
3.405 164.000 900. T/K = 293.0; x1 = 0.540
4.418 219.000
4.641 242.000
4.894 267.000
5.137 290.000
7.093 483.000 600.
7.235 518.000
7.437 543.000
7.610 568.000
7.792 596.000
7.995 637.000
7.995 588.000 300.
8.288 686.000
8.288 625.000
8.420 638.000
8.744 628.000
8.866 665.000
9.048 668.000 0.
9.150 739.000 0. 3. 6. 9. 12.
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Van Eijnsbergen, B.; Beenakker, J. J. M. Measurements of the isobaric heat of mixing for gaseous mixtures CH4-Ar, CH4-N2,
H2-CH4, He-CH4 and He-Ar between 170 and 293 K and at pressures up to 120 atm Physica (Amsterdam) 1968, 39, 499-518

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1332] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
Variables: T/K, Temperature
H∞ -1
sol/J mol , Molar enthalpy of solution at infinite dilution of component 1
Method: H∞sol calculated by extrapolation to infinite dilution of direct calorimetric measurements of the molar enthalpy of
solution at constant P and variable T

File Number: LB0322

Components: 1. He, Helium [7440-59-7]
2. H2O, Water [7732-18-5]
P/103Pa = 100.000
T/K H∞ 3 -1 H∞ 3
sol/10 J mol
-1
sol/10 J mol
29815 –0.78
P/103Pa = 100.

–0.6

–0.7

–0.8

–0.9
293.0 298.0 303.0
T/K
Uncertainties: σ (T)/K = 0.02; σ (H∞ 3 -1
sol)/10 J mol = 0.04
Hallen, D.; Wadsoe, I. A new microcalorimetric vessel for dissolution of slightly soluble gases. Enthalpies of solution in water of
carbon tetrafluoride and sulphur hexafluoride at 288.15, 298.15, and 308.15 K J. Chem. Thermodyn. 1989, 21, 519-527

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0315

Components: 1. He, Helium [7440-59-7]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –1.940 H°sol/103J mol-1
298.15 –0.650 0.8
308.15 0.760

0.0

–0.8

–1.6

–2.4
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.16
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0337

Components: 1. He, Helium [7440-59-7]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –0.520 H°sol/103J mol-1
–0.40

–0.45

–0.50

–0.55

–0.60
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.04
Dec, S. F.; Gill, S. J. Enthalpies of aqueous solutions of noble gases at 25.deg.C J. Solution Chem. 1985, 14, 417-428

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0075

Components: 1. He, Helium [7440-59-7]
2. CH4, Methane [74-82-8]
T/K = 201.200 T/K = 293.100
x1 = 0.7200 x1 = 0.7200 HE/J mol-1
2400.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 201.20; x1 = 0.440
3.293 281.000 1.307 62.600 T/K = 231.40; x1 = 0.440
3.506 312.000 1.641 74.000 T/K = 293.10; x1 = 0.440
3.749 339.000 2.067 84.700
4.539 461.000 2.523 105.000
4.833 541.000 3.242 134.000 1800.
5.076 593.000 4.063 169.000
5.320 659.000 4.519 188.000
6.465 1073.000 4.904 204.000
6.606 1123.000 5.553 232.000
6.829 1163.000 6.687 289.000 1200.
6.951 1206.000 7.346 307.000
7.832 326.000
8.309 353.000
9.423 401.000
9.829 410.000
10.143 433.000 600.

0.
0. 3. 6. 9. 12.
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Van Eijnsbergen, B.; Beenakker, J. J. M. Measurements of the isobaric heat of mixing for gaseous mixtures CH4-Ar, CH4-N2,
H2-CH4, He-CH4 and He-Ar between 170 and 293 K and at pressures up to 120 atm Physica (Amsterdam) 1968, 39, 499-518

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0317

Components: 1. Ne, Neon [7440-01-9]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –5.090 H°sol/103J mol-1
298.15 –3.640 –1.5
308.15 –2.180

–2.5

–3.5

–4.5

–5.5
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.12
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0339

Components: 1. Ne, Neon [7440-01-9]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –3.950 H°sol/103J mol-1
–2.

–3.

–4.

–5.

–6.
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.09
Dec, S. F.; Gill, S. J. Enthalpies of aqueous solutions of noble gases at 25.deg.C J. Solution Chem. 1985, 14, 417-428

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0392

Components: 1. Ar, Argon [7440-37-1]
2. ClH, Hydrogen chloride [7647-01-0]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
24.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
210.15 19.40
230.15 13.20
250.15 9.50
270.15 7.30
290.15 5.50 18.0
330.15 3.70
370.15 2.30

12.0

6.0

0.0
250. 300. 350.
T/K
Uncertainties: σ (T)/K = 0.02; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Massucci, M. The excess enthalpy of {y Ar + (1 - y) HCl} (g) and the second virial coefficient of HCl from T =
210 K to T = 370 K J. Chem. Thermodyn. 1997, 29, 3-14

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0393

Components: 1. Ar, Argon [7440-37-1]
2. ClH, Hydrogen chloride [7647-01-0]
P/103Pa T/K x1 HE/J mol-1 P/103Pa T/K x1 HE/J mol-1
110.400 210.15 0.5010 21.8 111.900 250.15 0.5070 11.2
112.700 210.15 0.5010 21.0 112.500 250.15 0.5120 11.4
110.700 210.15 0.5140 21.5 114.000 270.15 0.4910 7.9
112.200 210.15 0.5170 21.0 114.200 270.15 0.4960 8.5
113.100 210.15 0.5180 21.1 114.500 270.15 0.4970 7.7
113.500 210.15 0.5200 22.1 112.900 270.15 0.5020 8.9
110.100 210.15 0.5380 21.9 112.400 270.15 0.5030 8.4
112.300 230.15 0.4280 15.1 114.200 270.15 0.5060 8.7
113.700 230.15 0.4690 13.9 113.400 270.15 0.5090 6.5
113.700 230.15 0.4770 14.7 115.000 270.15 0.5110 8.5
115.200 230.15 0.4840 14.5 114.000 270.15 0.5240 8.4
113.400 230.15 0.4850 14.8 113.600 290.15 0.4530 6.1
110.900 230.15 0.4860 15.7 114.400 290.15 0.4640 6.4
113.600 230.15 0.4870 13.7 114.200 290.15 0.4810 6.0
115.500 230.15 0.5000 13.6 114.400 290.15 0.4870 6.4
112.600 230.15 0.5080 14.6 114.100 290.15 0.4950 6.0
113.400 230.15 0.5200 15.6 114.300 290.15 0.5110 6.1
112.500 230.15 0.5250 15.3 114.400 290.15 0.5300 6.2
112.100 230.15 0.5280 14.2 115.200 290.15 0.5310 6.1
115.100 250.15 0.4790 11.2 116.500 370.15 0.4410 2.8
113.500 250.15 0.4910 10.5 115.200 370.15 0.4800 2.4
114.400 250.15 0.4920 10.6 115.900 370.15 0.4970 2.6
114.100 250.15 0.4950 10.8 116.100 370.15 0.4970 2.6
113.600 250.15 0.5040 10.0 116.600 370.15 0.5040 2.6
114.400 250.15 0.5050 11.1 115.700 370.15 0.5070 2.7
113.400 250.15 0.5060 9.8

Uncertainties: σ (P)/103Pa = 0.10; σ (T)/K = 0.02; σ (x1) = 0.001; σrel(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Massucci, M. The excess enthalpy of {y Ar + (1 - y) HCl} (g) and the second virial coefficient of HCl from T =
210 K to T = 370 K J. Chem. Thermodyn. 1997, 29, 3-14

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0229

Components: 1. Ar, Argon [7440-37-1]
2. H2O, Water [7732-18-5]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 373.2 T/K = 423.2 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 373.2
0.354000 52.00 0.280000 24.50
0.377000 54.00 0.313000 26.00 P/103Pa = 101.325; T/K = 403.2
0.409000 50.60 0.337000 26.70 P/103Pa = 101.325; T/K = 423.2
0.423000 54.90 0.386000 29.50
0.462000 54.70 0.398000 31.50 60.
0.495000 56.10 0.414000 28.70
0.538000 54.00 0.470000 30.50
0.555000 54.40 0.475000 29.40
0.563000 52.70 0.519000 31.60
0.580000 53.80 0.534000 31.10 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.0020; σrel
(HE)
= 0.02 See SELF for the totality of data
Richards, P.; Wormald, C. J. The enthalpy of mixing of (water + argon) vapour Z. Phys. Chem. (Frankfurt/Main) 1981, 128
, 35-42

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0159

Components: 1. Ar, Argon [7440-37-1]
2. H2O, Water [7732-18-5]
T/K = 648.200 T/K = 698.200
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
2400.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 598.2; x1 = 0.500
0.76 54.0 0.78 42.0
2.93 220.0 2.86 159.0 T/K = 648.2; x1 = 0.500
4.96 420.0 4.96 305.0 T/K = 698.2; x1 = 0.500
7.05 643.0 6.91 450.0
9.08 896.0 9.13 644.0 1800.
11.27 1234.0 11.24 871.0
13.20 1561.0 13.30 1085.0

1200.

600.

0.
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.004 – 0.016; σ (HE)/J mol-1 = 4 – 36 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0300

Components: 1. Ar, Argon [7440-37-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –13.960 H°sol/103J mol-1
298.15 –12.010
308.15 –9.970

–10.00

–12.00

–14.00

–16.00
290.00 300.00 310.00
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.20
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0336

Components: 1. Ar, Argon [7440-37-1]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –11.940 H°sol/103J mol-1
–10.

–11.

–12.

–13.

–14.
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.05
Dec, S. F.; Gill, S. J. Enthalpies of aqueous solutions of noble gases at 25.deg.C J. Solution Chem. 1985, 14, 417-428

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0046

Components: 1. Ar, Argon [7440-37-1]
2. H3N, Ammonia [7664-41-7]
P/106Pa = 0.811 P/106Pa = 1.115
T/K = 313.15 T/K = 313.15 HE/J mol-1
240.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 1.115; T/K = 313.15
0.186000 97.70 0.191000 163.70 P/106Pa = 0.811; T/K = 313.15
0.224000 105.10 0.227000 180.20
0.308000 121.80 0.283000 193.30
0.375000 131.60 0.289000 195.40
0.457000 127.30 0.292000 195.00 180.
0.465000 130.60 0.327000 196.50
0.480500 124.90 0.400000 205.20
0.495000 124.40 0.464000 198.40
0.533000 119.60 0.470000 198.30
0.592000 113.40 0.480000 197.80 120.
0.595000 110.80 0.542000 180.90
0.626000 105.10 0.589000 176.00
0.647000 91.70 0.684000 125.10
0.727000 76.20 0.725000 105.60
0.768000 69.70 0.744000 105.00
0.970000 2.80 0.837000 56.60 60.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.023 See SELF for the totality of data
Naumowicz, E.; Woycicki, W. Excess enthalpies of gaseous mixtures containing ammonia. 1. (Ammonia + argon) J. Chem.
Thermodyn. 1984, 16, 1081-1088

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0385

Components: 1. Ar, Argon [7440-37-1]
2. N2, Dinitrogen [7727-37-9]
P/106Pa = 4.560 P/106Pa = 7.100
T/K = 123.000 T/K = 123.000 HE/J mol-1
60.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 9.06; T/K = 123
0.091000 –14.00 0.133000 0.00 P/106Pa = 7.10; T/K = 123
0.132000 –18.00 0.225000 6.00
0.224000 –43.00 0.313000 13.00
0.388000 –21.00 0.482000 22.00
0.490000 –6.00 0.540000 31.00 30.
0.599000 0.00 0.737000 24.00
0.682000 4.00
0.731000 5.00

0.

–30.

P/106Pa = 6.08; T/K = 123

P/106Pa = 4.56; T/K = 123
–60.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HE)/J mol-1
= 2 + 0.05 |HE/J mol-1| See SELF for the totality of data
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpy of mixing of argon + nitrogen at 123, 130, and 140 K at pressures
up to 10.1 MPa J. Chem. Thermodyn. 1977, 9, 221-229

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0032

Components: 1. Ar, Argon [7440-37-1]
2. N2, Dinitrogen [7727-37-9]
P/106Pa = 7.130 P/106Pa = 10.220
T/K = 201.000 T/K = 298.000 HE/J mol-1
6.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.130; T/K = 201
0.226000 3.00 0.224000 –3.00
0.485000 4.00 0.287000 –2.00 P/106Pa = 10.220; T/K = 298
0.690000 3.00 0.478000 –4.00
0.663000 –0.80
0.797000 –0.60 3.

0.

–3.

–6.
0.50
x1
Uncertainties: σ (x1) = 0.003; σ (HE)/J mol-1
= 1.0 – 2.0
Wormald, C. J.; Lewis, K. L.; Mosedale, S. The excess enthalpies of hydrogen + methane, hydrogen + nitrogen, methane +
nitrogen, methane + argon, and nitrogen + argon at 298 and 201 K at pressures up to 10.2 MPa J. Chem. Thermodyn. 1977, 9
, 27-42

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0007

Components: 1. Ar, Argon [7440-37-1]
2. N2, Dinitrogen [7727-37-9]
T/K = 169.000 T/K = 169.000
x1 = 0.5200 x1 = 0.7800 HE/J mol-1
200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 169.0; x1 = 0.520
2.026 0.000 4.286 3.000 T/K = 201.0; x1 = 0.520
3.850 3.000 5.157 12.000 T/K = 231.0; x1 = 0.520
4.681 3.000 5.715 22.000
5.431 12.000 6.262 40.000
6.566 44.000 6.627 58.000 150.
6.748 57.000 7.123 71.000
7.346 88.000 7.528 92.000
8.065 136.000 7.812 109.000
8.329 154.000 8.157 126.000
8.602 168.000 8.461 136.000 100.
8.765 177.000 8.744 148.000
9.170 179.000 9.292 145.000
9.646 176.000 11.825 94.000
11.318 136.000
11.774 127.000
12.524 113.000 50.

0.
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σ (HE)/J mol-1 = 10 + 0.05 |HE/J mol-1| See SELF for the totality of data
Knoester, M.; Taconis, K. W.; Beenakker, J. J. M. Excess enthalpies of gaseous mixtures of hydrogen, nitrogen and argon
between 150 and 293.deg.K and at pressures up to 130 atm Physica (Amsterdam) 1967, 33, 389-409

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0386

Components: 1. N2, Dinitrogen [7727-37-9]
2. Ar, Argon [7440-37-1]
P/106Pa = 3.650 P/106Pa = 4.560
T/K = 140.000 T/K = 140.000 HM/J mol-1
2400.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 3.65; T/K = 140
0.221000 a 2044.00 0.078000 –73.00
0.301000 2070.00 0.236000 –271.00
0.552000 1428.00 0.270000 –297.00
0.681000 1009.00 0.340000 –323.00
0.805000 765.00 0.486000 –87.00 1600.
0.529000 348.00
0.584000 627.00
0.834000 311.00
0.962000 35.00
0.997000 17.00 800.

0.

P/106Pa = 4.05; T/K = 140

P/106Pa = 4.56; T/K = 140
–800.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HM)/J mol-1
= 2 + 0.03 |HM/J mol-1|
a Two-phase region; See SELF for the totality of data
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpy of mixing of argon + nitrogen at 123, 130, and 140 K at pressures
up to 10.1 MPa J. Chem. Thermodyn. 1977, 9, 221-229

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0100

Components: 1. Ar, Argon [7440-37-1]
2. CH4, Methane [74-82-8]
P/106Pa = 0.400 P/106Pa = 3.560
T/K = 140.000 T/K = 183.000 HE/J mol-1
400.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 0.40; T/K = 140
0.123000 4.80 0.142000 228.00 P/106Pa = 1.20; T/K = 160
0.501000 10.40 0.242000 266.00 P/106Pa = 2.54; T/K = 183
0.626000 10.00 0.448000 302.00 P/106Pa = 3.56; T/K = 183
0.858000 4.30 0.769000 174.00
0.895000 3.10 300.

200.

100.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)= 0.04 See SELF for the totality of data
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpies of mixing of methane + argon, methane + nitrogen, and methane
+ hydrogen in the gaseous and two-phase regions J. Chem. Thermodyn. 1977, 9, 121-131

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0029

Components: 1. Ar, Argon [7440-37-1]
2. CH4, Methane [74-82-8]
P/106Pa = 6.080 P/106Pa = 8.110
T/K = 201.000 T/K = 298.000 HE/J mol-1
1200.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 5.100; T/K = 201
0.105000 569.00 0.257000 59.00 P/106Pa = 7.100; T/K = 201
0.201000 771.00 0.364000 73.00 P/106Pa = 4.080; T/K = 298
0.317000 795.00 0.508000 73.00 P/106Pa = 10.170; T/K = 298
0.540000 655.00 0.639000 66.00
0.775000 361.00 0.830000 36.00 900.

600.

300.

0.
0.50
x1
Uncertainties: σ (x1) = 0.003; σrel
(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, K. L.; Mosedale, S. The excess enthalpies of hydrogen + methane, hydrogen + nitrogen, methane +
nitrogen, methane + argon, and nitrogen + argon at 298 and 201 K at pressures up to 10.2 MPa J. Chem. Thermodyn. 1977, 9
, 27-42

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0073

Components: 1. Ar, Argon [7440-37-1]
2. CH4, Methane [74-82-8]
T/K = 201.000 T/K = 201.000
x1 = 0.4800 x1 = 0.4800 HE/J mol-1
1200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 201.0; x1 = 0.480
1.408 23.300 9.768 412.000
1.682 29.100 10.720 280.000 T/K = 230.5; x1 = 0.480
1.895 36.000 10.933 255.000
2.128 44.600 11.105 230.000
3.516 107.000 11.196 211.000 900.
3.759 122.000 11.318 201.000
3.942 136.000 11.409 205.000
4.114 148.000 11.419 188.000
5.005 296.000
5.147 333.000 600.
5.279 367.000
5.461 429.000
5.583 471.000
6.627 903.000
6.769 947.000
6.860 981.000 300.
6.991 977.000
7.072 963.000
7.387 945.000
8.582 711.000
8.673 685.000
8.795 638.000 0.
0.0 3.0 6.0 9.0 12.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Van Eijnsbergen, B.; Beenakker, J. J. M. Measurements of the isobaric heat of mixing for gaseous mixtures CH4-Ar, CH4-N2,
H2-CH4, He-CH4 and He-Ar between 170 and 293 K and at pressures up to 120 atm Physica (Amsterdam) 1968, 39, 499-518

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0281

Components: 1. Ar, Argon [7440-37-1]
2. CH4, Methane [74-82-8]
P/106Pa = 1.020 P/106Pa = 9.120
T/K = 140.000 T/K = 183.000 HM/J mol-1
4800.
x1 HM/J mol-1 x1 HM/J mol-1
0.052000 –130.00 0.055000 6.00
0.173000 a 0.00 0.114000 –46.00
0.226000 a 741.00 0.212000 –108.00
0.235000 a 888.00 0.380000 –112.00
0.292000 a 1909.00 0.536000 –94.00 3200.
0.412000 3376.00 0.605000 –23.00
0.497000 3106.00 0.697000 58.00
0.616000 2631.00 0.777000 88.00
0.815000 1380.00
1600.

0.

P/106Pa = 9.12; T/K = 183.0

P/106Pa = 2.04; T/K = 160.0
P/106Pa = 1.02; T/K = 140.0
–1600.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HM)= 0.04 a Two-phase region; See SELF for the totality of data
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpies of mixing of methane + argon, methane + nitrogen, and methane
+ hydrogen in the gaseous and two-phase regions J. Chem. Thermodyn. 1977, 9, 121-131

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0405

Components: 1. Ar, Argon [7440-37-1]
2. C6H12, Cyclohexane [110-82-7]
T/K H°sol/103J mol-1
298.15 –1.810 H°sol/103J mol-1
–1.90

–1.85

–1.80

–1.75

–1.70
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.40
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0413

Components: 1. Ar, Argon [7440-37-1]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
298.15 –2.790 H°sol/103J mol-1
–2.70

–2.75

–2.80

–2.85

–2.90
296. 303. 311.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.42
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0419

Components: 1. Ar, Argon [7440-37-1]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
298.15 –0.520 H°sol/103J mol-1
–0.50

–0.51

–0.52

–0.53

–0.54
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.17
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0316

Components: 1. Kr, Krypton [7439-90-9]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –17.520 H°sol/103J mol-1
298.15 –15.290 –12.
308.15 –13.120

–14.

–16.

–18.

–20.
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.13
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0338

Components: 1. Kr, Krypton [7439-90-9]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –15.280 H°sol/103J mol-1
–13.

–14.

–15.

–16.

–17.
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.04
Dec, S. F.; Gill, S. J. Enthalpies of aqueous solutions of noble gases at 25.deg.C J. Solution Chem. 1985, 14, 417-428

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0319

Components: 1. Xe, Xenon [7440-63-3]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –21.440 H°sol/103J mol-1
298.15 –18.870 –15.
308.15 –16.450

–17.

–19.

–21.

–23.
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.20
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0340

Components: 1. Xe, Xenon [7440-63-3]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –19.100 H°sol/103J mol-1
–17.

–18.

–19.

–20.

–21.
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.12
Dec, S. F.; Gill, S. J. Enthalpies of aqueous solutions of noble gases at 25.deg.C J. Solution Chem. 1985, 14, 417-428

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0129

Components: 1. ClH, Hydrogen chloride [7647-01-0]
2. H2O, Water [7732-18-5]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
7.5
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
383.15 6.00
393.15 3.90
403.15 2.10
413.15 1.30
423.15 0.10 5.0
433.15 1.00
443.15 –0.20
453.15 –0.10
463.15 –0.70
473.15 –0.30 2.5
483.15 –1.00

0.0

–2.5
400. 430. 460.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.0 – 2.0
Wormald, C. J. Water - hydrogen chloride association. Second virial cross coefficients for water - hydrogen chloride from gas
phase excess enthalpy measurements J. Chem. Thermodyn. 2003, 35, 417-431

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1332] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
Variables: T/K, Temperature
H∞ -1
sol/J mol , Molar enthalpy of solution at infinite dilution of component 1
Method: H∞sol calculated by extrapolation to infinite dilution of direct calorimetric measurements of the molar enthalpy of
solution at variable T and constant P

File Number: LB0290

Components: 1. O2, Dioxygen [7782-44-7]
2. H2O, Water [7732-18-5]
P/103Pa = 100.000
T/K H∞ 3 -1 H∞ 3
sol/10 J mol
-1
sol/10 J mol
298.15 –12.056
P/103Pa = 100.

–11.0

–12.0

–13.0

–14.0
250.0 300.0 350.0
T/K
Uncertainties: σ (T)/K = 0.02; σ (H∞ 3 -1
sol)/10 J mol = 0.019
Gill, S. J.; Wadsoe, I. Flow-microcalorimetric techniques for solution of slightly soluble gases. Enthalpy of solution of oxygen in
water at 298.15 K J. Chem. Thermodyn. 1982, 14, 905-919

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1332] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
Variables: T/K, Temperature
H∞ -1
sol/J mol , Molar enthalpy of solution at infinite dilution of component 1
Method: H∞sol calculated by extrapolation to infinite dilution of direct calorimetric measurements of the molar enthalpy of
solution at variable T and constant P

File Number: LB0324

Components: 1. O2, Dioxygen [7782-44-7]
2. H2O, Water [7732-18-5]
P/103Pa = 100.000
T/K H∞ 3 -1 H∞ 3
sol/10 J mol
-1
sol/10 J mol
308.15 –10.10
P/103Pa = 100.

–9.0

–10.0

–11.0

–12.0
303.0 308.0 313.0
T/K
Uncertainties: σ (T)/K = 0.02; σ (H∞ 3 -1
sol)/10 J mol = 0.07
Hallen, D.; Wadsoe, I. A new microcalorimetric vessel for dissolution of slightly soluble gases. Enthalpies of solution in water of
carbon tetrafluoride and sulphur hexafluoride at 288.15, 298.15, and 308.15 K J. Chem. Thermodyn. 1989, 21, 519-527

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0318

Components: 1. O2, Dioxygen [7782-44-7]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
288.15 –14.030 H°sol/103J mol-1
298.15 –12.000 –8.
308.15 –9.920

–10.

–12.

–14.

–16.
290. 300. 310.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10
Olofsson, G.; Oshodj, A. A.; Qvarnstroem, E.; Wadsoe, I. Calorimetric measurements on slightly soluble gases in water.
Enthalpies of solution of helium, neon, argon, krypton, xenon, methane, ethane, propane, n-butane, and oxygen at 288.15, 298.15,
and 308.15 K J. Chem. Thermodyn. 1984, 16, 1041-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0018

Components: 1. N2, Dinitrogen [7727-37-9]
2. O2, Dioxygen [7782-44-7]
P/106Pa = 3.550 P/106Pa = 7.600
T/K = 298.150 T/K = 283.150 HE/J mol-1
0.
x1 HE/J mol-1 x1 HE/J mol-1
0.329000 –1.44 0.249000 –2.35
0.435000 –1.72 0.395000 –2.93
0.481000 –1.81 0.498000 –2.98
0.718000 –1.60 0.598000 –3.09
0.649000 –2.91 –1.
0.795000 –1.95

–2.

–3.

P/106Pa = 3.550; T/K = 298.15

P/106Pa = 6.900; T/K = 298.15
–4.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE) = 0.02 See SELF for the totality of data
Ba, L. B.; Nain, V. P. S.; Kaliaguine, S. C.; Ramalho, R. S. Direct determination of enthalpy of mixing of the binary gaseous
system N2 - O2 by flow calorimetry J. Chem. Eng. Data 1977, 22, 171-177

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1332] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
Variables: T/K, Temperature
H∞ -1
sol/J mol , Molar enthalpy of solution at infinite dilution of component 1
Method: H∞sol calculated by extrapolation to infinite dilution of direct calorimetric measurements of the molar enthalpy of
solution at variable T and constant P

File Number: LB0321

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. H2O, Water [7732-18-5]
P/103Pa = 100.000
T/K H∞ -1 H∞
sol/J mol
-1
sol/J mol
288.15 –24.02
298.15 –20.66 P/103Pa = 100.
308.15 –17.89

–19.0

–21.0

–23.0

–25.0
288.0 298.0 308.0
T/K
Uncertainties: σ (T)/K = 0.02; σ (H∞ 3 -1
sol)/10 J mol = 0.20 – 0.40
Hallen, D.; Wadsoe, I. A new microcalorimetric vessel for dissolution of slightly soluble gases. Enthalpies of solution in water of
carbon tetrafluoride and sulphur hexafluoride at 288.15, a98.15, and 308.15 K J. Chem. Thermodyn. 1989, 21, 519-527

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0127

Components: 1. H2O, Water [7732-18-5]
2. H2S, Dihydrogen sulfide [7783-06-4]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
38.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
383.15 35.50
393.15 30.00
403.15 26.80
413.15 22.90
423.15 22.60 31.
433.15 19.00
443.15 17.50
453.15 16.00
463.15 14.40
473.15 12.50 24.
483.15 12.00

17.

10.
400. 430. 460.
T/K
Uncertainties: σ (T)/K = 0.1; σrel
(HE)
= 0.02
Wormald, C. J. (Water + hydrogen sulphide) association. Second virial cross coefficients for (water + hydrogen sulphide) from
gas phase excess enthalpy measurements J. Chem. Thermodyn. 2003, 35, 1019-1030

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0105

Components: 1. H2O, Water [7732-18-5]
2. H3N, Ammonia [7664-41-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
–4.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
383.15 –35.50
388.15 –33.00
393.15 –28.00
403.15 –24.00
413.15 –22.00 –13.
423.15 –19.00
433.15 –15.00
443.15 –12.50
453.15 –10.00
463.15 –9.00 –22.
473.15 –8.00
483.15 –7.00
493.15 –6.50

–31.

–40.
410. 440. 470.
T/K
Uncertainties: σ (T)/K = 0.05; σ (HE)/J mol-1
= 1.5
Wormald, C. J.; Wurzberger, B. Second virial cross coefficients for (ammonia + water) derived from gas phase excess enthalpy
measurements J. Chem. Thermodyn. 2001, 33, 1193-1210

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0348

Components: 1. H3N, Ammonia [7664-41-7]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –35.346 H°sol/103J mol-1
–34.0

–34.5

–35.0

–35.5

–36.0
286. 293. 301.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.063
Vanderzee, C. E.; King, D. L. The enthalpies of solution and formation of ammonia J. Chem. Thermodyn. 1972, 4, 675-683

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol at variable T, obtained by correcting, for gas phase nonideality, calorimetric measurements of the molar
enthalpy of solution at infinite dilution

File Number: LB0349

Components: 1. H3N, Ammonia [7664-41-7]
2. H2O, Water [7732-18-5]
T/K H°sol/103J mol-1
298.15 –35.380 H°sol/103J mol-1
–33.

–34.

–35.

–36.

–37.
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.10
Worswick, R. D.; Dunn, A. G.; Staveley, L. A. K. The enthalpy of solution of ammonia in water and in aqueous solutions of
ammonium chloride and ammonium bromide J. Chem. Thermodyn. 1974, 6, 565-570

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0228

Components: 1. H2O, Water [7732-18-5]
2. N2, Dinitrogen [7727-37-9]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 373.150 T/K = 423.150 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 373.15
0.429000 51.40 0.434000 30.10
0.432000 52.30 0.451000 30.30 P/103Pa = 101.325; T/K = 423.15
0.459000 53.60 0.466000 29.80
0.478000 54.10 0.474000 29.60
0.480000 53.20 0.511000 30.40 60.
0.497000 53.90 0.535000 31.80
0.529000 53.80 0.567000 31.40
0.537000 54.00 0.594000 29.80
0.557000 53.20 0.606000 30.90
0.610000 50.70 0.645000 27.70 40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Richards, P.; Wormald, C. J.; Yerlett, T. K. The excess enthalpy of (water + nitrogen) vapour and (water + n-heptane) vapour
J. Chem. Thermodyn. 1981, 13, 623-628

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0152

Components: 1. H2O, Water [7732-18-5]
2. N2, Dinitrogen [7727-37-9]
P/106Pa = 10.030 P/106Pa = 12.580
T/K = 648.20 T/K = 648.20 HE/J mol-1
1600.
x1 HE/J mol-1 x1 HE/J mol-1
0.307000 850.00 0.308000 1178.00
0.407000 992.00 0.415000 1401.00
0.518000 1058.00 0.523000 1461.00
0.628000 1038.00 0.637000 1460.00
0.743000 921.00 0.752000 1314.00 1200.

800.

400.

P/106Pa = 12.580; T/K = 648.20

P/106Pa = 10.030; T/K = 648.20
0.
0.50
x1
Uncertainties: σ (x1) = 0.0050; σ (HE)/J mol-1
= 13 – 33 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0161

Components: 1. H2O, Water [7732-18-5]
2. N2, Dinitrogen [7727-37-9]
T/K = 573.20 T/K = 648.20
x1 = 0.5000 x1 = 0.5000 HE/J mol-1
2200.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 573.20; x1 = 0.500
0.72 67.00 1.47 104.00
2.10 225.00 2.89 222.00 T/K = 598.20; x1 = 0.500
3.51 452.00 4.20 327.00 T/K = 648.20; x1 = 0.500
4.87 741.00 4.40 343.00
4.89 696.00 5.48 476.00 1650.
5.45 856.00 5.51 477.00
5.62 817.00 7.06 611.00
6.31 1065.00 7.08 663.00
7.16 1240.00 7.87 736.00
7.19 1301.00 8.31 812.00 1100.
7.19 1273.00 8.44 849.00
7.72 1470.00 9.06 900.00
10.30 1020.00
11.13 1240.00
12.58 1460.00
12.58 1471.00 550.

0.
0.0 3.5 7.0 10.5 14.0
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01 – 0.23; σ (HE)/J mol-1 = 5 – 42 See SELF for the totality of data
Wormald, C. J. Selected experimental high temperature-high pressure excess enthalpy data for 16 binary systems containing
steam ELDATA Int. Electron. J. Phys.-Chem. Data 1995, 1, 95-112

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0443

Components: 1. H2O, Water [7732-18-5]
2. N2, Dinitrogen [7727-37-9]
P/106Pa T/K x1 HE/J mol-1
3.420 696.80 0.4880 194.0
6.960 696.40 0.4870 424.0
10.330 696.30 0.4910 749.0
13.740 696.30 0.5010 1128.0
17.350 689.90 0.4940 1598.0
3.380 805.30 0.4890 157.0
3.560 805.30 0.4900 163.0
6.940 805.30 0.4940 289.0
10.270 804.70 0.4930 450.0
13.810 799.30 0.4940 607.0
17.020 798.80 0.4880 783.0
3.440 910.90 0.4870 106.0
6.920 910.70 0.4950 206.0
10.470 910.90 0.4980 309.0
13.840 910.90 0.4990 411.0
16.980 910.10 0.4860 523.0

Uncertainties: σrel(x1) = 0.002; σ (T)/K = 1.0; σ (x1) = 0.0010; σrel(HE) = 0.030

Wilson, G. M.; Brady, C. J. Heats of mixing of steam with N2, CO2, H2, CH4, and CO at high temperatures and pressures using
a new high temperature calorimeter Gas Process. Assoc., Res. Rep. (cf. August 1995 List of Publications (CD-ROM available:
call 1-800-241-7842; fax 1-303-397-2599) 1983, (RR-73), 1-46

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0110

Components: 1. H2O, Water [7732-18-5]
2. O2S, Sulfur dioxide [7446-09-5]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
22.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
383.20 20.50
393.20 17.10
403.20 14.20
413.20 13.60
423.20 11.40 18.
433.20 10.50
443.20 9.20
453.20 8.00
463.20 7.80
473.20 7.00 14.
483.20 6.50

10.

6.
400. 430. 460.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.0 – 2.0
Wormald, C. J. Water-sulphur dioxide association. Second virial cross coefficients for water-sulphur dioxide derived from gas
phase excess enthalpy measurements J. Chem. Thermodyn. 2003, 35, 91-100

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0366

Components: 1. H2S, Dihydrogen sulfide [7783-06-4]
2. CH4, Methane [74-82-8]
P/106Pa = 0.507 P/106Pa = 1.013
T/K = 293.150 T/K = 313.150 HE/J mol-1
240.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 1.520; T/K = 293.15
0.223000 38.80 0.220000 64.70 P/106Pa = 1.013; T/K = 313.15
0.290000 40.50 0.308000 83.60 P/106Pa = 0.507; T/K = 293.15
0.328000 41.20 0.517000 90.40
0.440000 44.80 0.649000 78.80
0.601000 43.60 0.763000 68.00 180.
0.797000 28.30

120.

60.

0.
0.50
x1
Uncertainties: σ (x1) = 0.005; σrel
(HE)
= 0.03 See SELF for the totality of data
Barry, A. O.; Kaliaguine, S. C.; Ramalho, R. S. Excess enthalpies of the binary system methane - hydrogen sulfide by flow
calorimetry J. Chem. Eng. Data 1982, 27, 436-439

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0180

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. C2H6, Ethane [74-84-0]
P/106Pa = 4.320 P/106Pa = 4.880
T/K = 290.150 T/K = 290.150 HE/J mol-1
6000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.320; T/K = 298.15
0.022000 199.00 0.022000 165.00 P/106Pa = 4.880; T/K = 250.15
0.057000 445.00 0.058000 397.00 P/106Pa = 4.880; T/K = 298.15
0.126000 862.00 0.127000 790.00
0.197000 1198.00 0.196000 1083.00
0.267000 1405.00 0.266000 1293.00 4500.
0.336000 1535.00 0.336000 1430.00
0.406000 1590.00 0.407000 1477.00
0.477000 1568.00 0.476000 1457.00
0.546000 1494.00 0.546000 1470.00
0.614000 1385.00 0.616000 1378.00 3000.
0.685000 1242.00 0.684000 1223.00
0.755000 1033.00 0.755000 1024.00
0.826000 780.00 0.825000 758.00
0.893000 434.00 0.893000 402.00

1500.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE) = 0.02 See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Measurements of HmE and VmE for {x C2H6 + (1 - x) SF6} in the liquid and near-critical
region Fluid Phase Equilib. 2001, 192, 121-129

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0174

Components: 1. C2H6, Ethane [74-84-0]
2. F6S, Sulfur hexafluoride [2551-62-4]
P/106Pa = 3.760 P/106Pa = 6.000
T/K = 305.650 T/K = 305.650 HM/J mol-1
6000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 3.76; T/K = 305.65
0.127000 81.00 0.056000 265.00
0.198000 406.00 0.127000 579.00 P/106Pa = 4.32; T/K = 305.65
0.213000 1520.00 0.195000 847.00 P/106Pa = 4.88; T/K = 305.65
0.337000 4261.00 0.266000 1086.00
0.408000 4114.00 0.335000 1287.00 4500. P/106Pa = 6.00; T/K = 305.65
0.478000 3822.00 0.406000 1470.00
0.546000 3489.00 0.476000 1602.00
0.686000 2613.00 0.545000 1684.00
0.755000 2058.00 0.586000 1706.00
0.825000 1508.00 0.684000 1651.00 3000.
0.894000 967.00 0.755000 1495.00
0.962000 357.00 0.824000 1321.00
0.894000 839.00
0.964000 328.00
0.978000 211.00
1500.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Near-critical measurements of HmE and VmE for (ethane + sulphur hexafluoride) J. Chem.
Thermodyn. 2002, 34, 875-884

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0246

Components: 1. C2H6, Ethane [74-84-0]
2. F6S, Sulfur hexafluoride [2551-62-4]
P/106Pa = 4.320
T/K = 302.15 HM/J mol-1
2800.
x1 HM/J mol-1
P/106Pa = 4.32; T/K = 302.15
0.174000 1.80
0.229000 5.10
0.315000 27.50
0.386000 192.00
0.454000 871.00 2100.
0.523000 2253.00
0.609000 2405.00
0.664000 2269.00
0.733000 1969.00
0.803000 1569.00 1400.
0.874000 1083.00
0.943000 547.00

700.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM) = 0.02
Wormald, C. J.; Hodgetts, R. W. Measurements of HmE and VmE for {x C2H6 + (1 - x) SF6} in the liquid and near-critical
region Fluid Phase Equilib. 2001, 192, 121-129

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0252

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. C3H8, Propane [74-98-6]
P/106Pa = 3.75 P/106Pa = 4.30
T/K = 314.56 T/K = 318.68 HE/J mol-1
2400.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 3.75; T/K = 314.56
0.101000 494.00 0.098000 502.00
0.200000 973.00 0.198000 935.00 P/106Pa = 4.30; T/K = 318.68
0.300000 1247.00 0.299000 1265.00
0.399000 1522.00 0.399000 1483.00
0.499000 1661.00 0.498000 1658.00 1800.
0.600000 1749.00 0.599000 1825.00
0.700000 1751.00 0.699000 1740.00
0.799000 1504.00 0.800000 1489.00
0.900000 972.00 0.900000 923.00
1200.

600.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for (propane + sulphur hexafluoride) in the near-critical region
J. Chem. Thermodyn. 2002, 34, 1317-1327

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0176

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. C3H8, Propane [74-98-6]
P/106Pa = 5.00
T/K = 373.95 HE/J mol-1
4800.
x1 HE/J mol-1
0.099000 3679.00
0.199000 4442.00
0.300000 4445.00
0.401000 4214.00
0.501000 3698.00 3600.
0.601000 3159.00
0.700000 2481.00
0.800000 1698.00
0.901000 870.00
2400.

1200.

P/106Pa = 5.00; T/K = 373.95

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE)
= 0.02
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for (propane + sulphur hexafluoride) in the near-critical region
J. Chem. Thermodyn. 2002, 34, 1317-1327

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0253

Components: 1. C3H8, Propane [74-98-6]
2. F6S, Sulfur hexafluoride [2551-62-4]
P/106Pa = 4.300 P/106Pa = 4.300
T/K = 324.510 T/K = 363.980 HM/J mol-1
8000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 4.30; T/K = 324.51
0.098000 1570.00 0.099000 1041.00
0.200000 1779.00 0.199000 2039.00 P/106Pa = 4.30; T/K = 344.40
0.300000 1558.00 0.300000 2954.00 P/106Pa = 4.30; T/K = 363.98
0.400000 1219.00 0.400000 3825.00
0.501000 1049.00 0.500000 4654.00 6000.
0.601000 959.00 0.601000 5257.00
0.700000 737.00 0.701000 5744.00
0.800000 549.00 0.800000 6046.00
0.899000 257.00 0.900000 5386.00
4000.

2000.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for (propane + sulphur hexafluoride) in the near-critical region
J. Chem. Thermodyn. 2002, 34, 1317-1327

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0132

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. C4H10, Butane [106-97-8]
P/106Pa = 6.000
T/K = 311.25 HE/J mol-1
1600.
x1 HE/J mol-1
P/106Pa = 6.00; T/K = 311.25
0.102000 455.00
0.204000 794.00
0.305000 1068.00
0.406000 1236.00
0.506000 1301.00 1200.
0.606000 1249.00
0.705000 1166.00
0.804000 954.00
0.902000 549.00
800.

400.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)= 0.02
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for (n-butane + sulphur hexafluoride) in the supercritical
region at the pressure 6.00 MPa J. Chem. Thermodyn. 2003, 35, 393-403

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0134

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. C4H10, Butane [106-97-8]
P/106Pa = 8.000
T/K = 311.25 HE/J mol-1
1400.
x1 HE/J mol-1
0.103000 306.00
0.206000 736.00
0.308000 1140.00
0.409000 1197.00
0.509000 1293.00 1050.
0.609000 1260.00
0.707000 1177.00
0.805000 915.00
0.903000 490.00
700.

350.

P/106Pa = 8.000; T/K = 311.25

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for {x C4H10 + (1 - x) SF6} in the supercritical region at the
pressure 8.00 MPa Fluid Phase Equilib. 2003, 204, 143-153

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0130

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. C4H10, Butane [106-97-8]
P/106Pa = 8.000
T/K = 425.75 HE/J mol-1
3200.
x1 HE/J mol-1
0.103000 688.00
0.206000 1547.00
0.308000 2341.00
0.409000 2683.00
0.509000 2945.00 2400.
0.609000 2628.00
0.707000 2272.00
0.805000 1606.00
0.903000 830.00
1600.

800.

P/106Pa = 8.000; T/K = 425.750

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for {x C4H10 + (1 - x) SF6} in the supercritical region at the
pressure 8.00 MPa Fluid Phase Equilib. 2003, 204, 143-153

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0128

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. C4H10, Butane [106-97-8]
P/106Pa = 6.000
T/K = 425.55 HE/J mol-1
4800.
x1 HE/J mol-1
P/106Pa = 6.00; T/K = 425.55
0.102000 1029.00
0.204000 2824.00
0.305000 4047.00
0.406000 4386.00
0.507000 4316.00 3600.
0.606000 3665.00
0.705000 3033.00
0.804000 2054.00
0.902000 1009.00
2400.

1200.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)= 0.02
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for (n-butane + sulphur hexafluoride) in the supercritical
region at the pressure 6.00 MPa J. Chem. Thermodyn. 2003, 35, 393-403

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0135

Components: 1. C4H10, Butane [106-97-8]
2. F6S, Sulfur hexafluoride [2551-62-4]
P/106Pa = 8.000 P/106Pa = 8.000
T/K = 351.240 T/K = 410.860 HM/J mol-1
3000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 8.000; T/K = 331.250
0.097000 310.00 0.097000 721.00
0.195000 620.00 0.195000 1452.00 P/106Pa = 8.000; T/K = 371.110
0.293000 780.00 0.293000 1883.00 P/106Pa = 8.000; T/K = 410.860
0.391000 869.00 0.391000 2217.00
0.491000 910.00 0.491000 2327.00 2250.
0.591000 886.00 0.591000 2033.00
0.692000 750.00 0.692000 1500.00
0.794000 512.00 0.794000 983.00
0.897000 329.00 0.897000 448.00
1500.

750.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel(HM)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for {x C4H10 + (1 - x) SF6} in the supercritical region at the
pressure 8.00 MPa Fluid Phase Equilib. 2003, 204, 143-153

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0133

Components: 1. C4H10, Butane [106-97-8]
2. F6S, Sulfur hexafluoride [2551-62-4]
P/106Pa = 6.000 P/106Pa = 6.000
T/K = 331.220 T/K = 410.750 HM/J mol-1
5000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 6.000; T/K = 331.22
0.098000 386.00 0.098000 979.00
0.196000 639.00 0.196000 1945.00 P/106Pa = 6.000; T/K = 371.11
0.295000 820.00 0.295000 2714.00 P/106Pa = 6.000; T/K = 410.75
0.394000 880.00 0.394000 3350.00
0.493000 920.00 0.493000 3600.00 3750.
0.594000 910.00 0.594000 3526.00
0.695000 790.00 0.695000 2680.00
0.796000 618.00 0.796000 1234.00
0.898000 314.00 0.898000 501.00
2500.

1250.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HM) = 0.02 See SELF for the totality of data
Wormald, C. J.; Du’Gay, A. P. Measurements of HmE and VmE for (n-butane + sulphur hexafluoride) in the supercritical
region at the pressure 6.00 MPa J. Chem. Thermodyn. 2003, 35, 393-403

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0175

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.38 P/106Pa = 7.38
T/K = 250.15 T/K = 290.15 HE/J mol-1
2000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.38; T/K = 250.15
0.018000 188.00 0.018000 204.00
0.096000 720.00 0.096000 787.00 P/106Pa = 7.38; T/K = 290.15
0.177000 1105.00 0.177000 1190.00
0.255000 1347.00 0.255000 1435.00
0.335000 1502.00 0.335000 1560.00 1500.
0.415000 1562.00 0.415000 1585.00
0.495000 1549.00 0.495000 1553.00
0.623000 1407.00 0.574000 1434.00
0.654000 1319.00 0.654000 1250.00
0.732000 1117.00 0.733000 1069.00 1000.
0.812000 816.00 0.812000 811.00
0.891000 522.00

500.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Measurements of HmE and VmE for {x CO2 + (1 - x) SF6} in the near-critical region Fluid
Phase Equilib. 2001, 187-188, 391-401

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0177

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.38
T/K = 302.15 HE/J mol-1
1800.
x1 HE/J mol-1
P/106Pa = 7.38; T/K = 302.15
0.018000 243.00
0.096000 1047.00
0.177000 1420.00
0.255000 1550.00
0.335000 1560.00 1350.
0.415000 1495.00
0.495000 1368.00
0.574000 1230.00
0.653000 1064.00
0.732000 884.00 900.
0.812000 619.00
0.891000 385.00

450.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE) = 0.02
Wormald, C. J.; Hodgetts, R. W. Near-critical measurements of HmE and VmE for {x CO2 + (1 - x) SF6} and measurements
made over the pressure range 2.5 to 10.0 MPa at the temperature T = 301.95 K J. Chem. Thermodyn. 2002, 34, 303-317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0189

Components: 1. F6S, Sulfur hexafluoride [2551-62-4]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 3.76 P/106Pa = 7.38
T/K = 319.60 T/K = 319.60 HE/J mol-1
4000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 3.76; T/K = 319.60
0.021000 199.00 0.018000 86.00 P/106Pa = 5.20; T/K = 319.60
0.096000 547.00 0.095000 445.00 P/106Pa = 7.38; T/K = 319.60
0.177000 957.00 0.178000 803.00
0.257000 1307.00 0.254000 1077.00
0.337000 1482.00 0.335000 1154.00 3000.
0.417000 1763.00 0.450000 1120.00
0.494000 1882.00 0.495000 994.00
0.516000 2122.00 0.620000 652.00
0.654000 2232.00 0.655000 548.00
0.733000 2196.00 0.732000 381.00 2000.
0.815000 2142.00 0.811000 248.00
0.892000 1861.00 0.891000 120.00

1000.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE)
= 0.02 See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Measurements of HmE and VmE for {x CO2 + (1 - x) SF6} in the near-critical region Fluid
Phase Equilib. 2001, 187-188, 391-401

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0247

Components: 1. CO2, Carbon dioxide [124-38-9]
2. F6S, Sulfur hexafluoride [2551-62-4]
P/106Pa = 3.760 P/106Pa = 7.380
T/K = 302.150 T/K = 305.650 HM/J mol-1
5400.
x1 HM/J mol-1 x1 HM/J mol-1
0.109000 –310.00 0.188000 –6.00
0.181000 a 1960.00 0.268000 –25.00
0.266000 a 4650.00 0.346000 –121.00
0.345000 4600.00 0.426000 –172.00
0.425000 4200.00 0.505000 –293.00 3600.
0.505000 3701.00 0.585000 –422.00
0.583000 3252.00 0.665000 –468.00
0.665000 2710.00 0.745000 –531.00
0.745000 2202.00 0.823000 –367.00
0.823000 1526.00 0.904000 –24.00 1800.
0.901000 917.00 0.979000 103.00
0.980000 193.00 0.982000 112.00

0.

P/106Pa = 3.76; T/K = 305.65

P/106Pa = 5.20; T/K = 305.65
–1800. P/106Pa = 7.38; T/K = 305.65
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HM) = 0.02 a Two-phase region; See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Near-critical measurements of HmE and VmE for {x CO2 + (1 - x) SF6} and measurements
made over the pressure range 2.5 to 10.0 MPa at the temperature T = 301.95 K J. Chem. Thermodyn. 2002, 34, 303-317

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0245

Components: 1. CO2, Carbon dioxide [124-38-9]
2. F6S, Sulfur hexafluoride [2551-62-4]
P/106Pa = 3.760 P/106Pa = 5.200
T/K = 290.150 T/K = 290.150 HM/J mol-1
4400.
x1 HM/J mol-1 x1 HM/J mol-1
0.109000 –490.00 0.109000 –281.00
0.187000 –884.00 0.187000 –564.00
0.265000 –1310.00 0.266000 –857.00
0.348000 a –1505.00 0.348000 –1152.00
0.430000 a 550.00 0.426000 –1557.00 2200.
0.505000 a 3950.00 0.505000 –2061.00
0.585000 3612.00 0.584000 –2496.00
0.664000 2912.00 0.665000 –3065.00
0.745000 2357.00 0.744000 a –3557.00
0.822000 1700.00 0.823000 a –799.00 0.
0.903000 948.00 0.903000 613.00
0.980000 293.00 0.982000 183.00

–2200.

P/106Pa = 3.76; T/K = 290.15

–4400. P/106Pa = 5.20; T/K = 290.15
0.50
x1
Uncertainties: σ (x1) = 0.00100; σrel(HM)
= 0.02 a Two-phase region; See SELF for the totality of data
Wormald, C. J.; Hodgetts, R. W. Measurements of HmE and VmE for {x CO2 + (1 - x) SF6} in the near-critical region Fluid
Phase Equilib. 2001, 187-188, 391-401

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0125

Components: 1. O2S, Sulfur dioxide [7446-09-5]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
60.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.15 54.90
373.15 50.20
383.15 48.10
393.15 43.20
403.15 41.30 50.
413.15 35.10
423.15 33.90
433.15 33.10
443.15 29.60
453.15 26.30 40.
463.15 27.70
473.15 24.40

30.

20.
385. 420. 455.
T/K
Uncertainties: σ (T)/K = 0.1; σrel(HE)
= 0.02
Wormald, C. J. Sulfur dioxide-benzene association. Second virial cross coefficients for sulfur dioxide - benzene and sulfur
dioxide - cyclohexane derived from gas phase excess enthalpy measurements Phys. Chem. Chem. Phys. 2002, 4, 4008-4013

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0126

Components: 1. O2S, Sulfur dioxide [7446-09-5]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
22.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.15 19.20
373.15 16.70
383.15 14.60
393.15 12.80
403.15 11.40 17.
413.15 10.00
423.15 8.90
433.15 7.90
443.15 7.00
453.15 6.30 12.
463.15 5.60
473.15 5.00

7.

2.
385. 420. 455.
T/K
Uncertainties: σ (T)/K = 0.1; σrel(HE)
= 0.02
Wormald, C. J. Sulfur dioxide-benzene association. Second virial cross coefficients for sulfur dioxide - benzene and sulfur
dioxide - cyclohexane derived from gas phase excess enthalpy measurements Phys. Chem. Chem. Phys. 2002, 4, 4008-4013

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0048

Components: 1. H3N, Ammonia [7664-41-7]
2. N2, Dinitrogen [7727-37-9]
P/106Pa = 0.811 P/106Pa = 1.115
T/K = 313.15 T/K = 313.15 HE/J mol-1
260.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 0.811; T/K = 333.15
0.240000 87.40 0.308000 160.40
0.291000 93.60 0.383000 194.70 P/106Pa = 1.419; T/K = 333.15
0.366000 124.90 0.439000 198.20
0.417000 129.50 0.565000 213.30
0.497000 142.70 0.629000 213.20 195.
0.577000 149.50 0.791000 167.00
0.666000 135.90 0.815000 152.80
0.715000 130.40 0.855000 137.50
0.804000 110.40
0.878000 81.90 130.

65.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.023 See SELF for the totality of data
Naumowicz-Weglinska, E.; Woycicki, W. Excess enthalpies of gaseous mixtures containing ammonia. 2. (Ammonia + nitrogen)
and (ammonia + methane) J. Chem. Thermodyn. 1986, 18, 1047-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0031

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH4, Methane [74-82-8]
P/106Pa = 7.140 P/106Pa = 10.230
T/K = 201.000 T/K = 298.000 HE/J mol-1
1600.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.140; T/K = 201
0.209000 1178.00 0.279000 109.00
0.214000 1143.00 0.401000 122.00 P/106Pa = 5.560; T/K = 201
0.270000 1226.00 0.526000 120.00 P/106Pa = 3.050; T/K = 201
0.305000 1212.00 0.642000 107.00
0.368000 1203.00 0.757000 81.00 1200.
0.494000 1114.00
0.519000 1100.00
0.615000 901.00
0.701000 725.00
0.784000 480.00 800.

400.

0.
0.50
x1
Uncertainties: σ (x1) = 0.003; σrel
(HE)= 0.02 See SELF for the totality of data
Wormald, C. J.; Lewis, K. L.; Mosedale, S. The excess enthalpies of hydrogen + methane, hydrogen + nitrogen, methane +
nitrogen, methane + argon, and nitrogen + argon at 298 and 201 K at pressures up to 10.2 MPa J. Chem. Thermodyn. 1977, 9
, 27-42

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0102

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH4, Methane [74-82-8]
P/106Pa = 2.140 P/106Pa = 3.130
T/K = 183.000 T/K = 183.000 HE/J mol-1
240.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 2.14; T/K = 183
0.220000 53.00 0.333000 184.00
0.332000 67.00 0.450000 187.00 P/106Pa = 3.13; T/K = 183
0.443000 70.00 0.560000 173.00
0.567000 69.00 0.705000 131.00
0.721000 53.00 180.

120.

60.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.04
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpies of mixing of methane + argon, methane + nitrogen, and methane
+ hydrogen in the gaseous and two-phase regions J. Chem. Thermodyn. 1977, 9, 121-131

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0076

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH4, Methane [74-82-8]
T/K = 201.200 T/K = 293.100
x1 = 0.1900 x1 = 0.1900 HE/J mol-1
1400.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 201.2; x1 = 0.440
3.344 92.000 1.419 4.100 T/K = 231.7; x1 = 0.440
3.688 117.000 2.148 9.500 T/K = 293.1; x1 = 0.440
3.952 142.000 3.952 23.700
4.246 176.000 3.972 19.600
4.499 221.000 6.161 43.700 1050.
4.975 355.000 6.870 51.700
5.127 415.000 7.528 58.200
5.309 496.000 9.312 79.100
5.441 574.000 10.112 88.600
5.583 668.000 10.984 108.000 700.
5.725 789.000
6.282 124.100
6.475 131.100
6.657 130.300
7.701 975.000
7.984 882.000 350.
8.147 828.000
8.552 695.000
10.447 421.000
10.892 366.000
0.
0. 3. 6. 9. 12.
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Van Eijnsbergen, B.; Beenakker, J. J. M. Measurements of the isobaric heat of mixing for gaseous mixtures CH4-Ar, CH4-N2,
H2-CH4, He-CH4 and He-Ar between 170 and 293 K and at pressures up to 120 atm Physica (Amsterdam) 1968, 39, 499-518

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0430

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH4, Methane [74-82-8]
P/103Pa = 20.265 P/103Pa = 101.325
x1 = 0.500 x1 = 0.500 HE/J mol-1
1600.
T/K HE/J mol-1 T/K HE/J mol-1
P/103Pa = 101.325; x1 = .500
195.15 48.00 195.15 733.00 P/103Pa = 60.795; x1 = .500
213.15 39.10 213.15 777.70 P/103Pa = 20.265; x1 = .500
233.15 28.10 233.15 420.10
253.15 21.10 253.15 251.60
273.15 17.80 313.15 93.00 1200.
313.15 13.60

800.

400.

0.
210. 250. 290.
T/K
Uncertainties: σrel(HE)
= 0.05 See SELF for the totality of data
Klein, R. R.; Bennett, C. O.; Dodge, B. F. Experimental heats of mixing for gaseous nitrogen and methane AIChE J. 1971, 17
, 958-965

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0280

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH4, Methane [74-82-8]
P/106Pa = 4.080 P/106Pa = 8.210
T/K = 183.000 T/K = 183.000 HM/J mol-1
4000.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 4.08; T/K = 183
0.106000 2006.00 0.287000 251.00 P/106Pa = 5.55; T/K = 183
0.177000 3059.00 0.359000 369.00 P/106Pa = 7.16; T/K = 183
0.298000 2823.00 0.476000 639.00
0.324000 2747.00 0.589000 765.00
P/106Pa = 8.21; T/K = 183
0.361000 2688.00 0.717000 610.00 3000.
0.418000 2425.00 0.778000 515.00
0.455000 2137.00 0.832000 396.00
0.666000 1422.00

2000.

1000.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HM)= 0.04 See SELF for the totality of data
Lewis, K. L.; Mosedale, S. E.; Wormald, C. J. The enthalpies of mixing of methane + argon, methane + nitrogen, and methane
+ hydrogen in the gaseous and two-phase regions J. Chem. Thermodyn. 1977, 9, 121-131

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0367

Components: 1. N2, Dinitrogen [7727-37-9]
2. C3H8, Propane [74-98-6]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 241.200 T/K = 393.400 HE/J mol-1
48.
x1 HE/J mol-1 x1 HE/J mol-1 P/103Pa = 101.325; T/K = 241.2
0.302000 33.80 0.307000 9.50 P/103Pa = 101.325; T/K = 273.5
0.451000 37.70 0.429000 10.50 P/103Pa = 101.325; T/K = 323.1
0.505000 38.40 0.530000 10.70 P/103Pa = 101.325; T/K = 393.4
0.637000 36.00 0.614000 9.10
0.690000 31.70 0.719000 8.30 36.

24.

12.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HE)/J mol-1
= 0.70 + 0.020 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Hutchings, D. J.; Lewis, E. J. The excess molar enthalpy and cross-term second virial coefficients of (nitrogen
+ propane) and (nitrogen + butane) from T = (241.2 to 393.4) K J. Chem. Thermodyn. 1996, 28, 371-378

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0368

Components: 1. N2, Dinitrogen [7727-37-9]
2. C3H8, Propane [74-98-6]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
40.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
241.20 36.50
253.60 30.90
262.90 28.50
273.50 26.00
283.20 23.90 32.
293.20 21.60
303.40 19.90
323.10 16.20
343.20 14.50
363.20 13.30 24.
383.20 11.00
393.40 10.50

16.

8.
280. 320. 360.
T/K
Uncertainties: σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Hutchings, D. J.; Lewis, E. J. The excess molar enthalpy and cross-term second virial coefficients of (nitrogen
+ propane) and (nitrogen + butane) from T = (241.2 to 393.4) K J. Chem. Thermodyn. 1996, 28, 371-378

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0370

Components: 1. N2, Dinitrogen [7727-37-9]
2. C4H10, Butane [106-97-8]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 283.400 T/K = 393.200 HE/J mol-1
80.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 283.4
0.314000 52.90 0.331000 20.50 P/103Pa = 101.325; T/K = 323.2
0.425000 56.70 0.424000 21.70 P/103Pa = 101.325; T/K = 363.3
0.514000 59.20 0.505000 22.80
0.601000 57.70 0.592000 23.00
P/103Pa = 101.325; T/K = 393.2
0.690000 50.50 0.712000 19.20 60.

40.

20.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HE)/J mol-1
= 0.70 + 0.020 |HE/J mol-1| See SELF for the totality of data
Wormald, C. J.; Hutchings, D. J.; Lewis, E. J. The excess molar enthalpy and cross-term second virial coefficients of (nitrogen
+ propane) and (nitrogen + butane) from T = (241.2 to 393.4) K J. Chem. Thermodyn. 1996, 28, 371-378

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0369

Components: 1. N2, Dinitrogen [7727-37-9]
2. C4H10, Butane [106-97-8]
P/100Pa = 101.325
x1 = 0.500 HE/J mol-1
64.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
283.40 59.60
293.20 53.90
303.30 48.30
323.20 40.40
343.50 33.20 53.
363.30 28.10
383.20 25.10
393.20 22.40

42.

31.

20.
310. 340. 370.
T/K
Uncertainties: σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Hutchings, D. J.; Lewis, E. J. The excess molar enthalpy and cross-term second virial coefficients of (nitrogen
+ propane) and (nitrogen + butane) from T = (241.2 to 393.4) K J. Chem. Thermodyn. 1996, 28, 371-378

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0391

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.150 T/K = 383.150 HE/J mol-1
100.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.15
0.230000 57.00 0.240000 48.00
0.320000 67.00 0.310000 56.00 P/103Pa = 101.325; T/K = 373.15
0.420000 73.00 0.440000 66.00 P/103Pa = 101.325; T/K = 383.15
0.490000 76.00 0.530000 67.00
0.600000 75.00 0.690000 62.00 75.
0.710000 70.00 0.830000 44.00
0.810000 55.00

50.

25.

0.
0.50
x1
Uncertainties: σ (x1) = 0.01; σ (HE)/J =2mol-1 See SELF for the totality of data
Wormald, C. J. Measurements of the heat of mixing of vapours using a new flow calorimetric technique Proc. Int. Conf.
Calorim. Thermodyn., 1st, Warsaw, Poland, 1969 1969, , 601-607

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0150

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
120.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = .500
333.20 99.00
338.20 94.20
343.20 88.20
348.20 82.90
353.20 80.00 100.0
358.20 78.30
363.20 72.90
368.20 71.00
373.20 68.00
383.20 63.70 80.0
393.20 59.00
403.20 54.50
413.20 50.70
423.20 47.60
433.20 45.50
60.0

40.0
350. 380. 410.
T/K
Uncertainties: σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Lewis, E. J.; Terry, A. J. Second virial coefficients of benzene and cyclohexane from measurements of the
excess molar enthalpy of (0.5 N2 + 0.5 C6H6) and (0.5 N2 + 0.5 C6H12) from 333.2 K to 433.2 K J. Chem. Thermodyn. 1996, 28
, 17-27

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0149

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa T/K x1 HE/J mol-1
44.100 333.20 0.5000 40.3
63.000 338.20 0.5000 56.1
63.900 343.20 0.5000 53.5
85.600 348.20 0.5000 68.9
94.400 353.20 0.5000 74.5
97.200 358.20 0.5000 75.1
101.000 363.20 0.5000 72.9
101.800 368.20 0.5000 71.3
100.900 373.20 0.5000 67.7
102.000 383.20 0.5000 64.1
101.200 393.20 0.5000 58.9
100.900 403.20 0.5000 54.3
101.600 413.20 0.5000 45.1
101.800 423.20 0.5000 47.8
100.900 433.20 0.5000 45.3

Uncertainties: σ (P)/103Pa = 0.1; σ (T)/K = 0.1; σ (x1) = 0.0010; σ (HE)/J mol-1 = 0.70 + 0.01 |HE/J mol-1|
Wormald, C. J.; Lewis, E. J.; Terry, A. J. Second virial coefficients of benzene and cyclohexane from measurements of the
excess molar enthalpy of (0.5 N2 + 0.5 C6H6) and (0.5 N2 + 0.5 C6H12) from 333.2 K to 433.2 K J. Chem. Thermodyn. 1996, 28
, 17-27

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0406

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H12, Cyclohexane [110-82-7]
T/K H°sol/103J mol-1
298.15 2.090 H°sol/103J mol-1
2.20

2.15

2.10

2.05

2.00
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.18
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase or two-phase fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0019

Components: 1. N2, Dinitrogen [7727-37-9]
2. C2H4, Ethene [74-85-1]
P/106Pa = 2.072 P/106Pa = 4.835
T/K = 298.150 T/K = 298.150 HE/J mol-1
800.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.835; T/K = 298.15
0.206000 83.42 0.229000 537.30
0.323000 116.00 0.305000 598.60 P/106Pa = 3.454; T/K = 298.15
0.415000 118.90 0.448000 597.60 P/106Pa = 2.072; T/K = 298.15
0.539000 142.70 0.551000 567.20
0.718000 101.10 0.710000 411.50 600.
0.779000 71.23 0.895000 154.80

400.

200.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)
= 0.02 See SELF for the totality of data
Ba, L. B.; Kaliaguine, S. C.; Ramalho, R. S. Excess enthalpies for gaseous ethylene + nitrogen by flow calorimetry J. Chem.
Thermodyn. 1978, 10, 603-612

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0390

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 363.150 T/K = 373.150 HE/J mol-1
100.
x1 HE/J mol-1 x1 HE/J mol-1
P/103Pa = 101.325; T/K = 363.15
0.230000 53.00 0.150000 29.00
0.270000 57.00 0.250000 47.00 P/103Pa = 101.325; T/K = 373.15
0.310000 62.00 0.320000 56.00 P/103Pa = 101.325; T/K = 383.15
0.370000 66.00 0.400000 63.00
0.430000 68.00 0.500000 66.00 75.
0.500000 71.00 0.630000 64.00
0.550000 71.00 0.660000 63.00
0.640000 68.00 0.680000 62.00
0.710000 64.00 0.780000 49.00
0.790000 55.00 0.890000 30.00 50.

25.

0.
0.50
x1
Uncertainties: σ (x1) = 0.01; σ (HE)/J =2mol-1 See SELF for the totality of data
Wormald, C. J. Measurements of the heat of mixing of vapours using a new flow calorimetric technique Proc. Int. Conf.
Calorim. Thermodyn., 1st, Warsaw, Poland, 1969 1969, , 601-607

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1242] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable T and constant P and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0151

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
120.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
333.20 94.80
338.20 88.70
343.20 83.90
348.20 79.40
353.20 75.90 100.0
358.20 72.90
363.20 69.80
368.20 66.10
373.20 64.20
383.20 59.80 80.0
393.20 54.50
403.20 51.50
413.20 47.50
423.20 45.50
433.20 41.50
60.0

40.0
350. 380. 410.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Lewis, E. J.; Terry, A. J. Second virial coefficients of benzene and cyclohexane from measurements of the
excess molar enthalpy of (0.5 N2 + 0.5 C6H6) and (0.5 N2 + 0.5 C6H12) from 333.2 K to 433.2 K J. Chem. Thermodyn. 1996, 28
, 17-27

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0148

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H6, Benzene [71-43-2]
P/103Pa T/K x1 HE/J mol-1
46.700 333.20 0.5000 41.4
61.200 338.20 0.5000 51.7
66.700 343.20 0.5000 53.5
81.300 348.20 0.5000 62.7
96.000 353.20 0.5000 71.7
98.600 358.20 0.5000 71.0
101.000 363.20 0.5000 69.6
101.300 368.20 0.5000 66.1
102.000 373.20 0.5000 64.7
101.800 383.20 0.5000 60.1
101.800 393.20 0.5000 54.8
101.100 403.20 0.5000 51.5
100.900 413.20 0.5000 46.9
100.600 423.20 0.5000 45.2
100.600 433.20 0.5000 41.0

Uncertainties: σ (P)/103Pa = 0.1; σ (T)/K = 0.1; σ (x1) = 0.0010; σ (HE)/J mol-1 = 0.70 + 0.01 |HE/J mol-1|
Wormald, C. J.; Lewis, E. J.; Terry, A. J. Second virial coefficients of benzene and cyclohexane from measurements of the
excess molar enthalpy of (0.5 N2 + 0.5 C6H6) and (0.5 N2 + 0.5 C6H12) from 333.2 K to 433.2 K J. Chem. Thermodyn. 1996, 28
, 17-27

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0414

Components: 1. N2, Dinitrogen [7727-37-9]
2. C6H6, Benzene [71-43-2]
T/K H°sol/103J mol-1
298.15 2.820 H°sol/103J mol-1
3.0

2.9

2.8

2.7

2.6
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.42
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1251] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Variables: P/Pa, Pressure
T/K, Temperature
x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P, T and x1

File Number: LB0004

Components: 1. N2, Dinitrogen [7727-37-9]
2. CCl4, Tetrachloromethane [56-23-5]
P/103Pa T/K x1 HE/J mol-1 P/Pa T/K x1 HE/J mol-1
47.900 333.20 0.3050 34.2 95.200 413.20 0.4590 46.3
48.300 333.20 0.4040 38.4 95.000 413.20 0.4910 47.1
48.200 333.20 0.4630 39.1 94.200 413.20 0.5440 46.8
50.300 333.20 0.4920 41.8
49.500 333.20 0.5880 38.3
74.300 343.20 0.4150 54.5
74.600 343.20 0.4710 57.5
74.600 343.20 0.4830 55.8
73.800 343.20 0.4970 55.7
73.700 343.20 0.5390 54.5
77.400 353.20 0.3000 42.7
72.500 353.20 0.3570 46.9
73.900 353.20 0.4370 52.5
79.700 353.20 0.4850 54.8
74.100 353.20 0.5250 51.4
75.000 383.20 0.2820 34.7
74.900 383.20 0.4530 42.8
75.100 383.20 0.4900 43.4
74.800 383.20 0.5650 42.1
78.900 393.20 0.2850 35.8
72.900 393.20 0.3830 37.1
79.600 393.20 0.4550 41.8
79.600 393.20 0.5260 41.4
76.300 393.20 0.5800 40.3
93.200 413.20 0.3850 42.6
94.100 413.20 0.4000 45.0

Uncertainties: σ (P)/103Pa = 0.1; σ (T)/K = 0.1; σ (x1) = 0.0010; σ (HE)/J mol-1 = 1.00 + 0.010 |HE/J mol-1|
Wormald, C. J.; Lancaster, N. M. The second virial coefficients of tetrachloromethane from measurements of the excess molar
enthalpy of y N2 + (1 - y) CCl4 over the temperature range 333.2 K to 413.2 K J. Chem. Thermodyn. 1996, 28, 245-254

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1333] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Variables: T/K, Temperature
H°sol/J mol-1, Standard molar enthalpy of solution of component 1
Method: H°sol obtained by correcting for gas phase nonideality calorimetric measurements of the molar enthalpy of
solution at infinite dilution at constant P and variable T

File Number: LB0420

Components: 1. N2, Dinitrogen [7727-37-9]
2. CCl4, Tetrachloromethane [56-23-5]
T/K H°sol/103J mol-1
298.15 1.030 H°sol/103J mol-1
1.2

1.1

1.0

0.9

0.8
293. 298. 303.
T/K
Uncertainties: σ (T)/K = 0.02; σ (H°sol)/103J mol-1 = 0.53
Battino, R.; Marsh, K. N. An isothermal displacement calorimeter for the measurement of the enthalpy of solution of gases Aust.
J. Chem. 1980, 33, 1997-2003

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0113

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH3Cl, Chloromethane [74-87-3]
P/103Pa = 101.3
x1 = 0.500 HE/J mol-1
50.
T/K HE/J mol-1
P/103Pa = 101.3; x1 = 0.500
250.20 46.80
270.20 34.00
290.20 26.00
295.20 24.30
310.20 20.10 39.
330.20 16.00
350.20 14.30
370.20 11.70
390.20 10.40
28.

17.

6.
240. 280. 320. 360. 400.
T/K
Uncertainties: σ (T)/K = 0.1; σrel
(HE) = 0.02
Massucci, M.; Wormald, C. J. Second virial coefficients of chloromethane and chloroethane from measurements of the excess
enthalpy of (0.5N2 + 0.5CH3Cl)(g), and (0.5N2 + C2H5Cl)(g). The excess enthalpy of (0.5CH3Cl + 0.5C2H5Cl)(g) J. Chem.
Thermodyn. 1998, 30, 919-927

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0114

Components: 1. N2, Dinitrogen [7727-37-9]
2. C2H5Cl, Chloroethane [75-00-3]
P/103Pa = 101.3
x1 = 0.500 HE/J mol-1
56.
T/K HE/J mol-1
P/103Pa = 101.3; x1 = 0.500
295.20 52.90
300.20 49.00
305.20 46.50
310.20 44.60
320.20 37.90 46.
330.20 34.70
350.20 28.70
370.20 23.10
390.20 19.00
36.

26.

16.
280. 310. 340. 370. 400.
T/K
Uncertainties: σ (T)/K = 0.1; σrel
(HE)= 0.02
Massucci, M.; Wormald, C. J. Second virial coefficients of chloromethane and chloroethane from measurements of the excess
enthalpy of (0.5N2 + 0.5CH3Cl)(g), and (0.5N2 + C2H5Cl)(g). The excess enthalpy of (0.5CH3Cl + 0.5C2H5Cl)(g) J. Chem.
Thermodyn. 1998, 30, 919-927

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0013

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH2Cl2, Dichloromethane [75-09-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
70.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
323.2000 58.80
333.2000 49.00
343.2000 45.50
353.2000 40.20
363.2000 34.70 55.
373.2000 31.60
383.2000 29.70
393.2000 27.90
403.2000 25.50
413.2000 23.00 40.
423.2000 20.50

25.

10.
340. 380. 420.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.0–2.0
Wormald, C. J.; Johnson, P. W. The second virial coefficient of dichloromethane from measurements of the excess molar
enthalpy of (nitrogen + dichloromethane)(g) J. Chem. Thermodyn. 1998, 30, 1235-1241

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0388

Components: 1. N2, Dinitrogen [7727-37-9]
2. CHCl3, Trichloromethane [67-66-3]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 343.150 T/K = 353.150 HE/J mol-1
88.
x1 HE/J mol-1 x1 HE/J mol-1 P/103Pa = 101.325; T/K = 363.15
0.330000 67.00 0.350000 52.00 P/103Pa = 101.325; T/K = 373.15
0.400000 70.00 0.400000 58.00 P/103Pa = 101.325; T/K = 383.15
0.420000 71.00 0.450000 60.00
0.460000 74.00 0.490000 60.00
0.540000 73.00 0.540000 61.00 66.
0.570000 72.00 0.600000 58.00
0.610000 68.00 0.650000 55.00
0.720000 47.00

44.

22.

0.
0.50
x1
Uncertainties: σ (x1) = 0.01; σ (HE)/J =2mol-1 See SELF for the totality of data
Wormald, C. J. Measurements of the heat of mixing of vapours using a new flow calorimetric technique Proc. Int. Conf.
Calorim. Thermodyn., 1st, Warsaw, Poland, 1969 1969, , 601-607

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0116

Components: 1. N2, Dinitrogen [7727-37-9]
2. CHCl3, Trichloromethane [67-66-3]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
90.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
333.20 80.50
338.20 72.80
343.20 70.70
348.20 69.20
353.20 61.90 75.
363.20 54.50
373.20 51.30
383.20 46.10
393.20 42.60
403.20 37.60 60.
413.20 36.30
423.20 31.50

45.

30.
330. 355. 380. 405. 430.
T/K
Uncertainties: σ (T)/K = 0.10; σrel
(HE) = 0.020
Doyle, J. A.; Hutchings, D. J.; Lancaster, N. M.; Wormald, C. J. Second virial coefficient of chloroform from measurements
of the excess molar enthalpy of (nitrogen + chloroform)(g) J. Chem. Soc., Faraday Trans. 1998, 94, 1263-1265

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0010

Components: 1. N2, Dinitrogen [7727-37-9]
2. C4H8O2, 1,4-Dioxane [123-91-1]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
100.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 86.30
378.20 80.60
383.20 77.50
393.20 70.50
403.20 64.90 87.5
413.20 61.00
423.20 57.50

75.0

62.5

50.0
350 375 400 425 450
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1 = 1.0–2.0
Parker, A. P.; Rieger, F.; Wormald, C. J. The second virial coefficient of dioxane from measurements of the excess molar
enthalpy of (nitrogen + dioxane)(g) J. Chem. Thermodyn. 1998, 30, 1221-1226

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0080

Components: 1. N2, Dinitrogen [7727-37-9]
2. CH4O, Methanol [67-56-1]
T/K = 343.2 T/K = 373.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
440.
P/103Pa HE/J mol-1 P/103Pa HE/J mol-1
T/K = 338.2; x1 = 0.500
53.770 86.000 67.160 51.000
57.910 98.000 71.240 54.000 T/K = 343.2; x1 = 0.500
59.080 98.000 75.080 58.000 T/K = 373.2; x1 = 0.500
63.750 118.000 79.260 62.000
65.120 115.000 79.920 62.000 330. T/K = 398.2; x1 = 0.500
71.300 141.000 81.320 62.000
71.900 141.000 81.490 63.000
74.060 145.000 91.600 73.000
78.110 170.000 92.390 72.000
79.370 168.000 96.130 74.000 220.
79.420 176.000 99.110 80.000
81.160 174.000
84.670 200.000
84.720 196.000
85.100 196.000
86.700 207.000 110.
93.290 239.000
94.660 254.000
99.800 313.000

0.
50.0 62.5 75.0 87.5 100.0
P/103Pa
Uncertainties: σ (P)/103Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Massucci, M.; Du’Gay, A. P.; Diaz-Laviada, A. M.; Wormald, C. J. Second virial coefficient of methanol from measurements
of the excess molar enthalpy of methanol - nitrogen J. Chem. Soc., Faraday Trans. 1992, 88, 427-432

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0081

Components: 1. N2, Dinitrogen [7727-37-9]
2. C2H6O, Ethanol [64-17-5]
T/K = 338.1 T/K = 412.2
x1 = 0.500 x1 = 0.500 HE/J mol-1
260.
P/103Pa HE/J mol-1 P/103Pa HE/J mol-1
T/K = 338.10; x1 = 0.500
32.740 72.000 67.840 36.000 T/K = 353.90; x1 = 0.500
35.890 84.000 72.000 38.000
38.400 95.000 74.760 40.000
41.310 110.000 77.940 42.000
45.460 133.000 80.550 43.000 200.
49.050 153.000 83.500 45.000
52.030 174.000 86.440 47.000
55.340 199.000 90.760 50.000
59.310 226.000 95.110 53.000
140.

80.

T/K = 373.90; x1 = 0.500

20. T/K = 412.20; x1 = 0.500

30. 50. 70. 90. 110.
P/103Pa
Uncertainties: σ (P)/103Pa = 0.01; σrel(HE) = 0.02 See SELF for the totality of data
Massucci, M.; Von Kralik, M. M.; Wormald, C. J. Second virial coefficient of ethanol from measurements of the excess molar
enthalpy of ethanol - nitrogen J. Chem. Soc., Faraday Trans. 1992, 88, 985-989

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1131] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at saturation pressure, variable x1 and constant T

File Number: LB0445

Components: 1. N2, Dinitrogen [7727-37-9]
2. CO, Carbon oxide [630-08-0]
T/K = 83.820
x1 HE/J mol-1 HE/J mol-1
48.
0.266000 31.20
0.391000 40.70 T/K = 83.82
0.405000 40.00
0.497000 42.10
0.517000 41.80
0.557000 40.10 36.
0.630000 39.70
0.727000 30.30

24.

12.

0.
0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE)
= 0.03
Gopal, P.; Chapman, W. G.; Zollweg, J. A.; Clancy, P.; Streett, W. B. Excess enthalpies of {xN2 + (1-x)CO}(l) at 83.82 K:
experiment and theory J. Chem. Thermodyn. 1987, 19, 527-534

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0350

Components: 1. N2, Dinitrogen [7727-37-9]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 3.447 P/106Pa = 6.550
T/K = 313.150 T/K = 313.150 HE/J mol-1
1200.
x1 HE/J mol-1 x1 HE/J mol-1 P/106Pa = 6.550; T/K = 304.15
0.288000 178.30 0.220000 627.20 P/106Pa = 6.550; T/K = 313.15
0.339000 187.50 0.358000 705.50 P/106Pa = 3.447; T/K = 313.15
0.437000 195.90 0.516000 662.70
0.481000 194.80 0.732000 444.00
0.482000 195.10 900.
0.484000 195.60
0.491000 195.00
0.503000 193.50
0.508000 194.50
0.509000 194.30 600.
0.510000 194.20
0.518000 192.40
0.525000 192.40
0.575000 185.50
0.670000 161.60
300.

0.
0.50
x1
Uncertainties: σ (x1) = 0.003; σ (HE)/J mol-1
= 2.00 See SELF for the totality of data
Hejmadi, A. V.; Katz, D. L.; Powers, J. E. Experimental determination of the enthalpy of mixing of N + CO2 under pressure J.
Chem. Thermodyn. 1971, 3, 483-496

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0365

Components: 1. N2, Dinitrogen [7727-37-9]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 9.109 P/106Pa = 11.156
T/K = 305.150 T/K = 333.150 HE/J mol-1
5200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 9.109; T/K = 305.15
0.171800 4261.00 0.114400 1128.00 P/106Pa = 5.066; T/K = 313.15
0.228000 4310.00 0.161800 1284.00 P/106Pa = 11.156; T/K = 333.15
0.297800 4243.00 0.278100 1541.00
0.312800 4136.00 0.298600 1558.00
0.469700 3477.00 0.408900 1504.00 3900.
0.588300 2839.00 0.607700 1207.00
0.761100 1686.00 0.698100 996.00

2600.

1300.

0.
0.50
x1
Uncertainties: σ (x1) = 0.0005; σrel
(HE) = 0.04 See SELF for the totality of data
Lee, J. I. The excess enthalpy of gaseous mixtures M. Sc. Thesis (Univ. Alberta, Edmonton, Canada) 1970, , 1-121

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1222] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable x1 and constant P and T, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0438

Components: 1. N2, Dinitrogen [7727-37-9]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 4.053 P/106Pa = 10.132
T/K = 305.150 T/K = 305.150 HE/J mol-1
6000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 4.053; T/K = 305.15
0.100000 129.00 0.100000 2995.00
0.200000 219.00 0.200000 3910.00 P/106Pa = 6.080; T/K = 305.15
0.300000 270.00 0.300000 3970.00 P/106Pa = 7.093; T/K = 305.15
0.400000 280.00 0.400000 3750.00
0.500000 275.00 0.500000 3300.00 4500. P/106Pa = 10.132; T/K = 305.15
0.600000 252.00 0.600000 2720.00
0.700000 205.00 0.700000 2080.00
0.800000 153.00 0.800000 1400.00
0.900000 85.00 0.900000 720.00
3000.

1500.

0.
0.50
x1
Uncertainties: σrel(HE)
= 0.04 See SELF for the totality of data
Lee, J. I.; Mather, A. E. Excess enthalpy of gaseous mixtures of nitrogen and carbon dioxide J. Chem. Eng. Data 1972, 17
, 189-192

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1232] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Smoothed HE data at variable P and constant T and x1, obtained from direct calorimetric measurements of HE at
variable P, T and x1

File Number: LB0362

Components: 1. N2, Dinitrogen [7727-37-9]
2. CO2, Carbon dioxide [124-38-9]
T/K = 313.15 T/K = 313.15
x1 = 0.1000 x1 = 0.5000 HE/J mol-1
4000.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
T/K = 313.15; x1 = 0.1
1.01 15.00 1.01 43.00 T/K = 313.15; x1 = 0.3
2.03 37.00 2.03 96.00 T/K = 313.15; x1 = 0.6
3.04 67.00 3.04 163.00
4.05 110.00 4.05 255.00
T/K = 313.15; x1 = 0.9
5.07 169.00 5.07 365.00 3000.
6.08 277.00 6.08 544.00
7.09 492.00 7.09 818.00
8.11 1021.00 8.11 1243.00
9.12 2349.00 9.12 2319.00
10.13 2891.00 10.13 2816.00 2000.
11.15 2404.00 11.15 2880.00
12.16 1883.00 12.16 2879.00

1000.

0.
0. 4. 8. 12. 16.
P/106Pa
Uncertainties: σrel(HE) = 0.04 See SELF for the totality of data
Lee, J. I.; Mather, A. E. The excess enthalpy of gaseous mixtures of nitrogen and carbon dioxide J. Chem. Thermodyn. 1970, 2
, 881-895

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0389

Components: 1. N2, Dinitrogen [7727-37-9]
2. C3H6O, Propan-2-one [67-64-1]
P/103Pa = 101.325 P/103Pa = 101.325
T/K = 343.150 T/K = 353.150 HE/J mol-1
160.
x1 HE/J mol-1 x1 HE/J mol-1 P/103Pa = 101.325; T/K = 343.15
0.310000 118.00 0.220000 82.00 P/103Pa = 101.325; T/K = 353.15
0.370000 130.00 0.300000 102.00 P/103Pa = 101.325; T/K = 363.15
0.460000 136.00 0.340000 104.00
0.530000 137.00 0.440000 110.00
0.600000 133.00 0.500000 112.00 120.
0.670000 126.00 0.510000 114.00
0.570000 113.00
0.640000 107.00
0.700000 101.00
0.760000 89.00 80.

40.

0.
0.50
x1
Uncertainties: σ (x1) = 0.01; σ (HE)/J =2mol-1 See SELF for the totality of data
Wormald, C. J. Measurements of the heat of mixing of vapours using a new flow calorimetric technique Proc. Int. Conf.
Calorim. Thermodyn., 1st, Warsaw, Poland, 1969 1969, , 601-607

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0009

Components: 1. N2, Dinitrogen [7727-37-9]
2. C3H6O, Propan-2-one [67-64-1]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
200.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
333.20 155.10
343.20 130.30
353.20 113.00
363.20 96.50
373.20 86.70 150.0
383.20 75.20
393.20 69.10
403.20 63.40
413.20 56.80
423.20 50.70 100.0

50.0

0.0
330. 355. 380. 405. 430.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 1.00
Doyle, J. A.; Hutchings, D. J.; Lancaster, N. M.; Wormald, C. J. The excess molar enthalpy of (nitrogen + dimethyl ketone)
(g) from temperatures of 333.2 K to 423.2.K J. Chem. Thermodyn. 1997, 29, 677-685

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0066

Components: 1. N2, Dinitrogen [7727-37-9]
2. C5H10O, Pentan-3-one [96-22-0]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
200.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
373.20 166.40
379.20 154.00
383.20 145.10
393.20 129.80
403.20 115.30 170.0
413.20 103.50
423.20 94.50

140.0

110.0

80.0
375. 400. 425.
T/K
Uncertainties: σ (T)/K = 0.10; σ (HE)/J mol-1
= 2.00
Mathonat, C.; Wilson, J.; Wormald, C. J. The second virial coefficient of diethyl ketone from measurements of the excess
molar enthalpy of (nitrogen + diethyl ketone)(g) J. Chem. Thermodyn. 1998, 30, 951-957

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0047

Components: 1. H3N, Ammonia [7664-41-7]
2. CH4, Methane [74-82-8]
P/106Pa = 0.811 P/106Pa = 0.811
T/K = 313.15 T/K = 333.15 HE/J mol-1
200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 0.811; T/K = 313.15
0.172000 61.60 0.088000 29.80
0.276000 84.40 0.260000 81.10 P/106Pa = 1.114; T/K = 313.15
0.418000 108.60 0.272000 80.10
0.550000 114.90 0.405000 101.40
0.555000 117.60 0.485000 106.70 150.
0.588000 111.00 0.508000 107.00
0.697000 99.10 0.618000 101.40
0.741000 86.80 0.665000 84.60
0.925000 26.50 0.764000 75.30
0.795000 59.30 100.

50.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00200; σrel
(HE)
= 0.023 See SELF for the totality of data
Naumowicz-Weglinska, E.; Woycicki, W. Excess enthalpies of gaseous mixtures containing ammonia. 2. (Ammonia + nitrogen)
and (ammonia + methane) J. Chem. Thermodyn. 1986, 18, 1047-1052

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0109

Components: 1. H3N, Ammonia [7664-41-7]
2. C6H12, Cyclohexane [110-82-7]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
85.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.15 75.40
373.17 68.20
383.15 61.60
393.15 58.50
403.15 55.50 70.
413.15 48.70
423.15 46.30
433.15 42.90
453.15 38.90
473.15 34.50 55.
493.15 31.90

40.

25.
395. 430. 465.
T/K
Uncertainties: σ (T)/K = 0.05; σ (HE)/J mol-1
= 1.5
Wormald, C. J.; Wurzberger, B. Ammonia-benzene association. Second virial cross coefficients for ammonia-benzene and
ammonia-cyclohexane derived from gas phase excess enthalpy measurements J. Chem. Thermodyn. 2002, 34, 1279-1288

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0045

Components: 1. H3N, Ammonia [7664-41-7]
2. C2H4, Ethene [74-85-1]
P/106Pa = 0.811 P/106Pa = 1.115
T/K = 313.15 T/K = 313.15 HE/J mol-1
200.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 1.115; T/K = 313.15
0.330000 78.60 0.390000 121.40
0.450000 95.30 0.470000 136.60 P/106Pa = 0.811; T/K = 313.15
0.500000 98.00 0.480000 135.50
0.520000 95.60 0.560000 140.40
0.660000 91.30 0.590000 141.70 150.
0.670000 93.80 0.670000 135.60
0.730000 83.40 0.770000 111.10
0.810000 67.60

100.

50.

0.
0.50
x1
Uncertainties: σ (x1) = 0.00500; σrel
(HE)
= 0.026 See SELF for the totality of data
Naumowicz-Weglinska, E.; Woycicki, W. Excess enthalpies of gaseous mixtures containing ammonia. 3. (Ammonia + ethene)
J. Chem. Thermodyn. 1992, 24, 1095-1098

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0108

Components: 1. H3N, Ammonia [7664-41-7]
2. C6H6, Benzene [71-43-2]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
68.
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
363.15 61.30
373.15 55.90
383.15 51.10
393.15 44.70
403.15 42.80 56.
413.15 39.90
423.15 35.90
433.15 33.20
453.15 27.60
473.15 25.40 44.
493.15 23.60

32.

20.
395. 430. 465.
T/K
Uncertainties: σ (T)/K = 0.05; σ (HE)/J mol-1
= 1.5
Wormald, C. J.; Wurzberger, B. Ammonia-benzene association. Second virial cross coefficients for ammonia-benzene and
ammonia-cyclohexane derived from gas phase excess enthalpy measurements J. Chem. Thermodyn. 2002, 34, 1279-1288

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1241] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
x1/-, Mole fraction of component 1
Variables: T/K, Temperature
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable T and constant P and x1

File Number: LB0107

Components: 1. H3N, Ammonia [7664-41-7]
2. CO2, Carbon dioxide [124-38-9]
P/103Pa = 101.325
x1 = 0.500 HE/J mol-1
3.0
T/K HE/J mol-1
P/103Pa = 101.325; x1 = 0.500
343.20 2.00
348.20 2.00
353.20 1.60
358.20 1.80
363.20 0.50 1.5
368.20 0.30
373.20 1.10
383.20 0.20
393.20 –0.30
403.20 0.00 0.0
423.20 –0.50
443.20 0.20

–1.5

–3.0
365. 395. 425.
T/K
Uncertainties: σ (T)/K = 0.1; σ (HE)/J mol-1
= 1.00
Wormald, C. J.; Wurzberger, B. Ammonia-carbon dioxide association. Second virial cross coefficients for (ammonia + carbon
dioxide) derived from gas phase excess enthalpy measurements J. Chem. Thermodyn. 2002, 34, 1567-1573

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0363

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. C5H12, Pentane [109-66-0]
P/106Pa = 9.490 P/106Pa = 12.270
T/K = 308.150 T/K = 308.150 HE/J mol-1
390.
x1 HE/J mol-1 x1 HE/J mol-1
0.049000 24.00 0.050000 61.00
0.098000 85.00 0.100000 119.00
0.145000 126.00 0.130000 149.00
0.191000 161.00 0.198000 220.00
0.243000 196.00 0.248000 272.00 260.
0.285000 205.00 0.311000 307.00
0.343000 226.00 0.373000 344.00
0.388000 230.00 0.437000 361.00
0.440000 231.00 0.498000 364.00
0.492000 221.00 0.550000 362.00 130.
0.543000 209.00 0.602000 347.00
0.594000 174.00 0.652000 308.00
0.644000 158.00 0.701000 282.00
0.670000 136.00 0.750000 263.00
0.744000 99.00 0.796000 231.00
0.788000 61.00 0.841000 192.00 0.
0.847000 23.00 0.881000 134.00
0.894000 –24.00 0.950000 59.00
0.978000 –26.00 P/106Pa = 12.270; T/K = 308.15
P/106Pa = 9.490; T/K = 308.15
–130.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HE)/J mol-1
= 1.00 + 0.010 |HE/J mol-1|
Renuncio, J. A. R.; Pando, C.; Menduina, C.; Castells, R. C. Excess enthalpies of nitrous oxide + pentane at 308.15 K and
313.15 K from 7.64 to 12.27 MPa J. Chem. Eng. Data 1995, 40, 642-644

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0364

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. C5H12, Pentane [109-66-0]
P/106Pa = 7.640 P/106Pa = 12.260
T/K = 313.150 T/K = 313.150 HM/J mol-1
600.
x1 HM/J mol-1 x1 HM/J mol-1
0.044000 –81.00 0.047000 43.00
0.089000 –141.00 0.097000 79.00
0.135000 –234.00 0.147000 143.00
0.226000 –374.00 0.195000 180.00
0.324000 –547.00 0.247000 220.00 0.
0.427000 –764.00 0.296000 240.00
0.471000 –812.00 0.345000 266.00
0.518000 –907.00 0.439000 287.00
0.569000 –973.00 0.442000 284.00
0.623000 –1081.00 0.491000 284.00 –600.
0.672000 –1195.00 0.541000 274.00
0.728000 –1314.00 0.542000 275.00
0.779000 –1478.00 0.544000 280.00
0.835000 –1551.00 0.587000 270.00
0.878000 –1642.00 0.638000 246.00
0.922000 –1572.00 0.695000 218.00 –1200.
0.946000 –1511.00 0.698000 205.00
0.969000 –1339.00 0.742000 180.00
0.989000 –929.00 0.800000 125.00 P/106Pa = 12.260; T/K = 313.15
0.844000 85.00 P/106Pa = 9.440; T/K = 313.15
0.896000 44.00 P/106Pa = 7.640; T/K = 313.15
0.951000 1.00 –1800.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HM)/J mol-1
= 1.00 + 0.010 |HM/J mol-1| See SELF for the totality of data
Renuncio, J. A. R.; Pando, C.; Menduina, C.; Castells, R. C. Excess enthalpies of nitrous oxide + pentane at 308.15 K and
313.15 K from 7.64 to 12.27 MPa J. Chem. Eng. Data 1995, 40, 642-644

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0428

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. C6H12, Cyclohexane [110-82-7]
P/106Pa = 12.270 P/106Pa = 15.000
T/K = 308.150 T/K = 308.150 HE/J mol-1
600.
x1 HE/J mol-1 x1 HE/J mol-1
0.052000 122.00 0.046000 144.00
0.105000 208.00 0.094000 226.00
0.161000 309.00 0.139000 290.00
0.207000 351.00 0.171000 354.00
0.299000 451.00 0.215000 395.00 300.
0.316000 458.00 0.273000 456.00
0.360000 472.00 0.284000 482.00
0.417000 502.00 0.311000 500.00
0.467000 510.00 0.405000 545.00
0.515000 500.00 0.428000 552.00 0.
0.534000 481.00 0.472000 556.00
0.560000 467.00 0.508000 559.00
0.580000 455.00 0.612000 514.00
0.619000 441.00 0.667000 476.00
0.639000 414.00 0.720000 429.00
0.663000 395.00 0.780000 356.00 –300.
0.710000 353.00 0.824000 305.00 P/106Pa = 15.00; T/K = 308.15
0.755000 289.00 0.883000 213.00 P/106Pa = 12.27; T/K = 308.15
0.771000 282.00 0.936000 124.00 P/106Pa = 9.48; T/K = 308.15
0.812000 219.00 0.965000 65.00 P/106Pa = 7.60; T/K = 308.15
0.853000 163.00 0.983000 41.00
0.877000 117.00 –600.
0.906000 85.00 0.50
0.953000 18.00
x1
Uncertainties: σ (x1) = 0.0010; σ (HE)/J mol-1
= 1.00 + 0.010 |HE/J mol-1| See SELF for the totality of data
Cabanas, A.; Pando, C.; Menduina, C.; Renuncio, J. A. R. The excess enthalpies of nitrous oxide + cyclohexane at 308.15 and
318.15 K from 7.60 to 15.00 MPa J. Supercrit. Fluids 1997, 10, 75-86

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0429

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. C6H12, Cyclohexane [110-82-7]
P/106Pa = 7.600 P/106Pa = 12.270
T/K = 318.150 T/K = 318.150 HM/J mol-1
1400.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 15.00; T/K = 318.15
0.047000 –144.00 0.035000 70.00 P/106Pa = 9.48; T/K = 318.15
0.094000 –178.00 0.052000 114.00
0.144000 –447.00 0.106000 206.00
0.187000 –572.00 0.132000 249.00
0.240000 –703.00 0.160000 278.00 0.
0.290000 –960.00 0.210000 327.00
0.332000 –1140.00 0.262000 350.00
0.386000 –1459.00 0.311000 371.00
0.436000 –1800.00 0.359000 361.00
0.484000 –1954.00 0.413000 346.00 –1400.
0.505000 –2159.00 0.466000 311.00
0.548000 –2454.00 0.513000 251.00
0.589000 –2545.00 0.562000 203.00
0.648000 –2865.00 0.618000 147.00
0.683000 –3065.00 0.662000 71.00
0.749000 –3351.00 0.713000 8.00 –2800.
0.793000 –3630.00 0.758000 –40.00
0.837000 –3755.00 0.811000 –129.00
0.895000 –3890.00 0.832000 –157.00
0.947000 –3759.00 0.857000 –162.00
0.969000 –3094.00 0.906000 –187.00 P/106Pa = 7.60; T/K = 318.15
0.980000 –1669.00 0.953000 –148.00 –4200.
0.990000 –221.00 0.963000 –125.00 0.50
0.982000 –72.00
x1
Uncertainties: σ (x1) = 0.0010; σ (HM)/J mol-1
= 1.00 + 0.010 |HM/J mol-1| See SELF for the totality of data
Cabanas, A.; Pando, C.; Menduina, C.; Renuncio, J. A. R. The excess enthalpies of nitrous oxide + cyclohexane at 308.15 and
318.15 K from 7.60 to 15.00 MPa J. Supercrit. Fluids 1997, 10, 75-86

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0309

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. C7H8, Toluene [108-88-3]
P/106Pa = 9.490 P/106Pa = 15.000
T/K = 308.150 T/K = 308.150 HE/J mol-1
160.
x1 HE/J mol-1 x1 HE/J mol-1
0.050000 1.60 0.053000 32.00
0.101000 –1.40 0.104000 56.00
0.151000 –18.00 0.156000 82.00
0.202000 –24.00 0.207000 92.00
0.302000 –60.00 0.262000 108.00 0.
0.401000 –85.00 0.358000 120.00
0.451000 –120.00 0.386000 120.00
0.505000 –165.00 0.438000 114.00
0.551000 –223.00 0.463000 112.00
0.601000 –271.00 0.510000 100.00 –160.
0.649000 –298.00 0.558000 86.00
0.701000 –359.00 0.612000 63.00
0.749000 –386.00 0.665000 37.00
0.802000 –405.00 0.719000 –0.10
0.822000 –425.00 0.766000 –29.00
0.874000 –426.00 0.809000 –51.00 –320.
0.898000 –418.00 0.854000 –69.00
0.927000 –373.00 0.879000 –79.00
0.949000 –307.00 0.890000 –81.00 P/106Pa = 15.00; T/K = 308.15
0.980000 –168.00 0.909000 –80.00 P/106Pa = 12.27; T/K = 308.15
0.931000 –78.00 P/106Pa = 9.49; T/K = 308.15
0.952000 –63.00 –480.
0.981000 –34.00 0.50
x1
Uncertainties: σ (x1) = 0.001; σrel
(HE) = 0.01 See SELF for the totality of data
Castells, R. C.; Menduina, C.; Pando, C.; Renuncio, J. A. R. Excess molar enthalpies of nitrous oxide - toluene in the liquid
and supercritical regions J. Chem. Soc., Faraday Trans. 1994, 90, 2677-2681

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0191

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. C7H8, Toluene [108-88-3]
P/106Pa = 7.60 P/106Pa = 15.00
T/K = 313.15 T/K = 313.15 HM/J mol-1
800.
x1 HM/J mol-1 x1 HM/J mol-1
P/106Pa = 15.000; T/K = 313.15
0.090700 –206.00 0.051000 19.00 P/106Pa = 12.270; T/K = 313.15
0.142000 –402.00 0.101000 42.00 P/106Pa = 9.490; T/K = 313.15
0.189000 –451.00 0.152000 53.00
0.240000 –630.00 0.202000 60.00
P/106Pa = 7.600; T/K = 313.15
0.289000 –739.00 0.256000 65.00 0.
0.337000 –988.00 0.307000 65.00
0.390000 –1047.00 0.351000 65.00
0.430000 –1249.00 0.405000 55.00
0.530000 –1610.00 0.456000 53.00
0.634000 –1895.00 0.503000 42.00 –800.
0.738000 –2129.00 0.550000 21.00
0.840000 –2319.00 0.605000 –8.50
0.892000 –2318.00 0.713000 –64.00
0.946000 –2293.00 0.804000 –111.00
0.990000 –1466.00 0.857000 –133.00
0.882000 –143.00 –1600.
0.906000 –135.00
0.929000 –125.00
0.950000 –104.00
0.971000 –77.00
0.990000 –27.00
–2400.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HM)/J mol-1
= 2.0 + 0.01 |HM/J mol-1| See SELF for the totality of data
Castells, R. C.; Menduina, C.; Pando, C.; Renuncio, J. A. R. The excess enthalpies of (dinitrogen oxide + toluene) at the
temperature 313.15 K and at pressures from 7.60 MPa to 15.00 MPa J. Chem. Thermodyn. 1994, 26, 641-646

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1311] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HM/J mol-1, Molar enthalpy of mixing
Method: Direct calorimetric measurement of HM at variable x1 and constant P and T

File Number: LB0310

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. C7H8, Toluene [108-88-3]
P/106Pa = 7.640 P/106Pa = 9.490
T/K = 323.150 T/K = 323.150 HM/J mol-1
0.
x1 HM/J mol-1 x1 HM/J mol-1
0.050000 –223.00 0.051000 –113.00
0.099000 –580.00 0.103000 –176.00
0.151000 –792.00 0.154000 –338.00
0.204000 –1142.00 0.205000 –419.00
0.252000 –1320.00 0.258000 –546.00 –1300.
0.300000 –1635.00 0.306000 –668.00
0.352000 –1872.00 0.347000 –729.00
0.399000 –2155.00 0.348000 –749.00
0.496000 –2587.00 0.405000 –850.00
0.546000 –2953.00 0.406000 –922.00 –2600.
0.549000 –3016.00 0.478000 –1062.00
0.603000 –3354.00 0.510000 –1126.00
0.649000 –3471.00 0.547000 –1207.00
0.698000 –3833.00 0.557000 –1265.00
0.750000 –4125.00 0.654000 –1474.00
0.798000 –4291.00 0.707000 –1598.00 –3900.
0.848000 –4482.00 0.754000 –1694.00
0.892000 –4435.00 0.806000 –1796.00 P/106Pa = 12.27; T/K = 323.15
0.953000 –2099.00 0.876000 –1718.00
0.970000 –1255.00 0.929000 –1620.00 P/106Pa = 9.49; T/K = 323.15
0.975000 –968.00 0.950000 –1443.00 P/106Pa = 7.64; T/K = 323.15
0.990000 –155.00 0.971000 –1139.00 –5200.
0.50
x1
Uncertainties: σ (x1) = 0.001; σ (HM)/J mol-1
= 2.0 + 0.01 |HM/J mol-1| See SELF for the totality of data
Castells, R. C.; Menduina, C.; Pando, C.; Renuncio, J. A. R. Excess molar enthalpies of nitrous oxide - toluene in the liquid
and supercritical regions J. Chem. Soc., Faraday Trans. 1994, 90, 2677-2681

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1121] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase liquid or two-phase liquid-liquid
Pure component 1, liquid
Pure component 2, liquid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0091

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.000 P/106Pa = 11.030
T/K = 298.800 T/K = 298.800 HE/J mol-1
120.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 3.48; T/K = 262.4
0.080000 33.00 0.009000 9.00
0.100000 42.00 0.100000 28.00 P/106Pa = 7.00; T/K = 298.8
0.147000 53.00 0.149000 39.00
0.196000 65.00 0.191000 49.00
0.248000 81.00 0.297000 58.00 90.
0.297000 84.00 0.347000 66.00
0.346000 93.00 0.396000 71.00
0.396000 96.00 0.496000 68.00
0.446000 99.00 0.544000 75.00
0.496000 97.00 0.644000 67.00 60.
0.544000 93.00 0.695000 62.00
0.644000 85.00 0.746000 59.00
0.695000 79.00 0.796000 48.00
0.746000 64.00 0.847000 33.00
0.796000 57.00 0.898000 20.00
0.849000 42.00 0.949000 8.00 30.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)= 0.02 See SELF for the totality of data
Wormald, C. J.; Eyears, J. M. Excess enthalpies and excess volumes of [xCO2 + (1-x)N2O] in the liquid and supercritical
regions J. Chem. Soc., Faraday Trans. 1 1988, 84, 3097-3106

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1221] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: P/Pa, Pressure
T/K, Temperature
Variables: x1/-, Mole fraction of component 1
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable x1 and constant P and T

File Number: LB0092

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. CO2, Carbon dioxide [124-38-9]
P/106Pa = 7.780 P/106Pa = 8.080
T/K = 312.600 T/K = 312.600 HE/J mol-1
1000.
x1 HE/J mol-1 x1 HE/J mol-1
P/106Pa = 7.78; T/K = 312.6
0.196000 250.00 0.196000 419.00
0.295000 365.00 0.295000 594.00 P/106Pa = 8.08; T/K = 312.6
0.394000 465.00 0.396000 725.00
0.496000 527.00 0.496000 783.00
0.596000 578.00 0.594000 759.00 750.
0.695000 578.00 0.697000 556.00
0.796000 533.00 0.796000 296.00
0.898000 344.00 0.898000 60.00

500.

250.

0.
0.50
x1
Uncertainties: σ (x1) = 0.002; σrel
(HE)= 0.02
Wormald, C. J.; Eyears, J. M. Excess enthalpies and excess volumes of [xCO2 + (1-x)N2O] in the liquid and supercritical
regions J. Chem. Soc., Faraday Trans. 1 1988, 84, 3097-3106

Landolt-Börnstein
New Series IV/10B
 Property Type: [HMSD1231] HEAT OF MIXING AND SOLUTION
State: Two-component system, single-phase fluid or two-phase fluid-fluid
Pure component 1, gas or supercritical fluid
Pure component 2, gas or supercritical fluid
Parameters: T/K, Temperature
x1/-, Mole fraction of component 1
Variables: P/Pa, Pressure
HE/J mol-1, Molar excess enthalpy
Method: Direct calorimetric measurement of HE at variable P and constant T and x1

File Number: LB0131

Components: 1. N2O, Dinitrogen oxide [10024-97-2]
2. CO2, Carbon dioxide [124-38-9]
T/K = 312.500 T/K = 324.700
x1 = 0.4940 x1 = 0.4940 HE/J mol-1
900.
P/106Pa HE/J mol-1 P/106Pa HE/J mol-1
3.490 20.000 6.010 3.000
5.020 38.000 7.000 18.000
6.550 70.000 7.970 65.000
7.210 126.000 8.180 84.000
7.410 184.000 8.380 101.000 600.
7.630 324.000 8.580 125.000
7.780 551.000 8.800 144.000
7.980 803.000 9.000 183.000
8.180 593.000 9.210 214.000
8.380 230.000 9.420 252.000 300.
8.400 153.000 9.520 255.000
8.590 –27.000 9.640 262.000
8.790 –50.000 9.840 259.000
9.000 14.000 10.040 229.000
11.000 59.000 10.060 219.000
10.240 197.000 0.
10.400 165.000
10.610 126.000
10.820 103.000 T/K = 312.5; x1 = 0.494
11.020 90.000 T/K = 324.7; x1 = 0.494
11.240 74.000
11.460 73.000 –300.
11.860 66.000 0. 4. 8. 12. 16.
12.080 62.000
P/106Pa
Uncertainties: σ (P)/106Pa = 0.01; σrel(HE) = 0.03
Wormald, C. J.; Eyears, J. M. Excess enthalpies and excess volumes of [xCO2 + (1-x)N2O] in the liquid and supercritical
regions J. Chem. Soc., Faraday Trans. 1 1988, 84, 3097-3106

Landolt-Börnstein
New Series IV/10B