PUREMEG

Monoethylene glycol reclamation

and regeneration system
 Monoethylene glycol (MEG) is widely used by the oil and gas markets The production fluid containing natural gas with associated condensate,
in wellheads and pipelines to prevent hydrate formation at pipeline produced water, and the injected MEG enters the production facility, where
conditions. In offshore deepwater gas production facilities, where the the fluids undergo phase separation. The produced fluids pass through a
exposure to lower temperatures in subsea pipelines is common, MEG is slug catcher and are then flashed in a three-phase production separator
used for hydrate inhibition. to separate gas, hydrocarbon liquids, and the produced water and MEG
mixture, commonly known as rich MEG. The produced gas and hydrocarbon
Hydrate inhibition is achieved by injecting MEG to decrease the hydrate liquids are routed onshore for sales and further processing.
formation temperature below the operating temperature, thereby
preventing hydrate blockage of the pipeline. During the gas production The rich MEG is regenerated by the PUREMEG* MEG reclamation and
process, the lean glycol mixes with the produced water from the formation. regeneration system into a lean, high-purity, salt-free MEG for reuse.
Separated salts are sent to disposal.

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MEG reclamation
MEG reclamation is used to recover the MEG and water components from a MEG-water-salt mixture
by contacting the MEG-water-salt stream with a heated recycle stream of MEG. The MEG and water
components are vaporized and subsequently separated by distillation. Salt accumulates in the
concentrated recycle stream, crystallizes, and is discharged from the process. MEG reclamation is
unusual compared with other equipment used in gas processing in that it occurs under a considerable
vacuum to reduce the processing temperatures and the consequential risk of MEG degradation,
which, if allowed to occur, leads to a sharp increase in MEG losses and equipment fouling.

PUREMEG system pilot plant installed at our

dedicated MEG Reclamation R&D facility at
the University of Manchester in England.
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 Optimized MEG processing with the PUREMEG system
The PUREMEG system is designed to deliver hydrocarbon and salt-free MEG for hydrate inhibition.
The process reduces MEG losses by decreasing the MEG content in the disposed salt. Up to 99.5%
MEG recovery can be achieved—a recovery rate that is unmatched in the industry.

The PUREMEG unit applies specialist experience and patented design features, including
■ use of spiral-type heat exchangers that are more tolerant of salty conditions
compared with other types of exchangers
■ patented design of the flash separator to reduce the population of salt crystals
in the heated recycle stream
■ extraction and cleanup of the salt using a patented salt-management technology.

The result is a design that is best practice in extracting large quantities of salt with reduced MEG
losses, environmental impact, and down time.

The PUREMEG system process comprises five sections:

Pretreatment—In the pretreatment stage, the rich MEG containing some dissolved gas and
hydrocarbon liquids must pass through a three-phase separator vessel. The gas is flashed, and
recovered hydrocarbon liquids are sent to the production separator. The rich MEG is sent to the
flash separator.
The PUREMEG system Flash separation—The rich MEG stream composed of produced water and MEG is fed to the flash
applies specialist separator where it is brought into contact with a hot recycle stream of MEG. The flash separator
operates under vacuum. The MEG and water components of the rich MEG stream are flashed and
experience and patented exit through the top of the flash separator where they are sent to the MEG distillation column for
design features to optimize regeneration. The salt components of the rich MEG stream precipitate in the flash separator.

the extraction of large MEG regeneration—The MEG regeneration section of the PUREMEG system is a refluxed distillation
column. The distillation column also operates under a vacuum and distills the water from the
quantities of salt with MEG-water vapors coming off the top of the flash separator. The salt-free, lean MEG produced at
the bottom of the distillation column is pumped to storage for reuse. The vaporized water passes
reduced MEG losses, overhead from the distillation column. The water is condensed and collected in the reflux drum. A
environmental impact, and small amount is returned to the distillation column as reflux, and the remaining is routed to treatment.

down time. Salt management—The salt crystals that precipitate in the flash separator are separated by gravity
to the bottom of the brine column, where they are transferred to the salt tank. There, the salts are
concentrated before removal through a hydrocyclone. The salts in produced water cover a variety
of species but are generally categorized into monovalent salts (typically sodium and potassium) and
divalent salts (typically calcium and magnesium).

Calcium removal—The divalent salts cannot be effectively precipitated in the same manner as
the monovalent salts, so a separate calcium removal process is installed in the PUREMEG system.
Effective calcium control is accomplished as the divalent salts are collected, reacted, and removed
through a filter, with the filtrate overflow returning to the process.

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 Condenser
Vacuum
Flash drum Flash gas
pump
Rich MEG
HC condensate

Recycle
heater
MEG Reflux drum
distillation
MEG return column
Recycle pump

Reactor Conductivity
probes
Divalent salt Brine
removal system column
Reflux water

Salt-free lean
MEG to storage

Dynamic
crossflow
filter Desalting
Water cyclone
addition
Divalent salt
slurry Chemical Salt pump
addition
Salty produced water
Typical PUREMEG system with full-stream reclamation.

Key process differentiations

Reduced population of salt particles in recycle loops (patented) Divalent salt removal system
■ Solids content is reduced by approximately 80% to 95% in the Schlumberger offers optional modularized divalent salt removal systems
recycle circuit. that provide better reliability and higher MEG recovery overall.
■ Lower particle content reduces erosion and fouling, resulting in reduced Chemical dosing
operating and maintenance costs and longer service life. Our system of chemical dosing controls pH, reduces oxygen, inhibits
Removal of salt crystals corrosion, and has the following results:
■ Salt particles that descend below the drawoff level settle at the bottom ■ significantly less auto-oxidation, which can otherwise cause the glycol
of the flash separator and enter the salt removal system where they are to breakdown into organic acids
stripped of MEG. ■ control of the precipitation and removal of calcium and iron compounds
■ Glycol-depleted waste salt can be disposed of directly into the sea using and other contaminants to reduce the fouling of heat exchangers and
either a batch or continuous process, or dried and disposed of as a cake. other equipment
■ Low overall MEG losses, below 1% by mass, in the waste salt are ■ use of lower-cost construction materials.
typically 10 times better than competing designs.
High-flux heat exchangers
■ The PUREMEG system uses HSE best practices by operating the Our recycle heater uses a low-fouling-, low-scaling-type heat exchanger
centrifuge at ambient temperature. to heat the high-flow salty recycle MEG without fouling, without allowing
suspended particulate matter to settle and without exposing the recycled
MEG to high skin temperatures that might promote thermal degradation.

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 Training
As part of our commitment to providing full-service solutions, we also offer
a diverse educational services program for the oil- and gas-processing
markets. Our training capabilities include both open enrollment and custom
courses that can be designed to meet our customers’ specific needs as well
as hands-on training.

Process solutions
An industry-recognized provider of process solutions, Schlumberger
provides in-house consulting services with an integrated team of
technology and product specialists that routinely deliver solutions for
challenging customer process problems. This unique group of specialists
is available to work with customers to design efficient solutions that meet
project requirements.

Life-of-field support
Schlumberger provides site support using a dedicated team of experienced
service and project representatives. Strategically located throughout the
globe, this network provides turnkey expertise and support for customers
for the duration of a project, from commissioning to operation. From
replacement parts and spares, field service contracts to equipment
repair, our mission is to provide the highest quality support to ensure our
customers’ satisfaction.

Rich-MEG-flow 5-m3/h, 300-tonUK PUREMEG system module for offshore Brazil application.

Schlumberger has a pool of highly trained technicians that operate around the world.

The PUREMEG system applies our engineering expertise to

the core principles of safety, availability, and operability.

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 Aux. boiler

Flash gas
Flash drum MVR compressor
Rich MEG
HC condensate

Noncondensables

Recycle
heater

MEG return MEG

distillation
Recycle pump column
Steam drum
PW cooler
Reactor Conductivity
probes
Divalent salt Brine
removal system column
Reflux water

Salt-free lean
MEG to storage

Dynamic
crossflow
filter Desalting
Water cyclone
addition
Divalent salt
slurry Chemical Salt pump
addition
Salty produced water

Typical PUREMEG system with mechanical vapor recompression.

Key process benefits Process overview

■ Reduce energy consumption by up to 80% The MEG regeneration and reclamation system often demands the largest
heating duty in a gas facility. Efficiency improvements in heat integration
■ Reduce carbon footprint by up to 80%
can significantly affect facility opex for heating and capex for the heating
■ Reduce heating-medium system size by more than 80% medium system.
■ Reduce cooling-medium system size by more than 80%
The Schlumberger advanced heat integration process uses mechanical
vapor recompression (MVR) to transform waste heat from the MEG
regeneration overheads into a usable heating medium for the process.

The MVR compressor boosts overhead vapor from the MEG regeneration
column, a low-grade steam, to a useable low-pressure steam, reducing
heating medium demand by more than 80% which in turn reduces capex,
opex, and greenhouse gas (GHG) emissions associated with the heating
medium system. The compressor increases electrical demand slightly,
<10% of heat duty, with the actual usage engineered for maximum savings
for a specific facility.

The MVR compressor can benefit both slipstream and full-stream MEG
regeneration and reclamation systems. Other industries have proved that
the concept can improve process economics and sustainability.

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PUREMEG

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